KR100500213B1 - Toxicity free lacquer solution and device for producing the same - Google Patents
Toxicity free lacquer solution and device for producing the same Download PDFInfo
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- KR100500213B1 KR100500213B1 KR10-2001-0028569A KR20010028569A KR100500213B1 KR 100500213 B1 KR100500213 B1 KR 100500213B1 KR 20010028569 A KR20010028569 A KR 20010028569A KR 100500213 B1 KR100500213 B1 KR 100500213B1
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- lacquer
- urushiol
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- 239000004922 lacquer Substances 0.000 title claims abstract description 58
- 231100000419 toxicity Toxicity 0.000 title description 6
- 230000001988 toxicity Effects 0.000 title description 6
- RMTXUPIIESNLPW-UHFFFAOYSA-N 1,2-dihydroxy-3-(pentadeca-8,11-dienyl)benzene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1O RMTXUPIIESNLPW-UHFFFAOYSA-N 0.000 claims abstract description 40
- QARRXYBJLBIVAK-UEMSJJPVSA-N 3-[(8e,11e)-pentadeca-8,11-dienyl]benzene-1,2-diol;3-[(8e,11e)-pentadeca-8,11,14-trienyl]benzene-1,2-diol;3-[(8e,11e,13e)-pentadeca-8,11,13-trienyl]benzene-1,2-diol;3-[(e)-pentadec-8-enyl]benzene-1,2-diol;3-pentadecylbenzene-1,2-diol Chemical compound CCCCCCCCCCCCCCCC1=CC=CC(O)=C1O.CCCCCC\C=C\CCCCCCCC1=CC=CC(O)=C1O.CCC\C=C\C\C=C\CCCCCCCC1=CC=CC(O)=C1O.C\C=C\C=C\C\C=C\CCCCCCCC1=CC=CC(O)=C1O.OC1=CC=CC(CCCCCCC\C=C\C\C=C\CC=C)=C1O QARRXYBJLBIVAK-UEMSJJPVSA-N 0.000 claims abstract description 40
- IYROWZYPEIMDDN-UHFFFAOYSA-N 3-n-pentadec-8,11,13-trienyl catechol Natural products CC=CC=CCC=CCCCCCCCC1=CC=CC(O)=C1O IYROWZYPEIMDDN-UHFFFAOYSA-N 0.000 claims abstract description 40
- DQTMTQZSOJMZSF-UHFFFAOYSA-N urushiol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1O DQTMTQZSOJMZSF-UHFFFAOYSA-N 0.000 claims abstract description 40
- 238000010992 reflux Methods 0.000 claims abstract description 14
- 238000010438 heat treatment Methods 0.000 claims abstract description 12
- 238000005273 aeration Methods 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims 2
- 238000001816 cooling Methods 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 16
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 229920000742 Cotton Polymers 0.000 abstract 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 230000000144 pharmacologic effect Effects 0.000 description 6
- 244000044283 Toxicodendron succedaneum Species 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 231100000331 toxic Toxicity 0.000 description 5
- 230000002588 toxic effect Effects 0.000 description 5
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 3
- 238000012790 confirmation Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 241000272525 Anas platyrhynchos Species 0.000 description 2
- 241000287828 Gallus gallus Species 0.000 description 2
- 206010019133 Hangover Diseases 0.000 description 2
- 240000003152 Rhus chinensis Species 0.000 description 2
- 235000014220 Rhus chinensis Nutrition 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 102000004400 Aminopeptidases Human genes 0.000 description 1
- 108090000915 Aminopeptidases Proteins 0.000 description 1
- 240000004160 Capsicum annuum Species 0.000 description 1
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 1
- 235000007862 Capsicum baccatum Nutrition 0.000 description 1
- 241001070941 Castanea Species 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- 206010010774 Constipation Diseases 0.000 description 1
- 208000005171 Dysmenorrhea Diseases 0.000 description 1
- 206010013935 Dysmenorrhoea Diseases 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 244000294411 Mirabilis expansa Species 0.000 description 1
- 235000015429 Mirabilis expansa Nutrition 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 238000005276 aerator Methods 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000000172 allergic effect Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001093 anti-cancer Effects 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 230000000840 anti-viral effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
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- 235000008429 bread Nutrition 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 239000001728 capsicum frutescens Substances 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 229940124600 folk medicine Drugs 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000020510 functional beverage Nutrition 0.000 description 1
- 239000004083 gastrointestinal agent Substances 0.000 description 1
- 229940127227 gastrointestinal drug Drugs 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
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- 235000021109 kimchi Nutrition 0.000 description 1
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- 229940124595 oriental medicine Drugs 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
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- 239000005871 repellent Substances 0.000 description 1
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- 238000001228 spectrum Methods 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/38—Other non-alcoholic beverages
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/70—Clarifying or fining of non-alcoholic beverages; Removing unwanted matter
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2250/00—Food ingredients
- A23V2250/20—Natural extracts
- A23V2250/21—Plant extracts
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2300/00—Processes
- A23V2300/24—Heat, thermal treatment
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2300/00—Processes
- A23V2300/31—Mechanical treatment
Abstract
본 발명은 옻의 가려움증의 원인 물질인 우루시올(Urushiol)을 제거한 옻물을 제조하는 방법 및 옻물 제조장치에 관한 것이다. 잘게 부순 옻나무, 뿌리 및 수피를 직접 넣거나 면으로 만든 자루에 넣어 환류장치와 폭기장치가 부착된 가열조에 넣고 2시간동안 가열한 후 여과하여 우루시올을 제거하는 동시에 옻나무의 다른 성분들을 추출하여 옻물을 제조하는 방법 및 옻물의 제조장치에 관한 것이다.The present invention relates to a method for producing a lacquer from which urushiol (Urushiol) is removed, and a lacquer producing apparatus. Put the crushed lacquer, root and bark directly into a bag made of cotton, put it in a heating tank with reflux and aeration device, heat it for 2 hours, filter it to remove urushiol, and extract other components of the lacquer to make lacquer. It relates to a method and a manufacturing device of lacquer.
Description
본 발명은 옻의 독성성분인 우루시올(Urushiol)을 제거하는 동시에 약리성분을 물로 우려내는 방법 및 그 장치에 관한 것으로써 환류장치를 부착하여 우루시올이 증기와 함께 외부로 전혀 방출되지 않아 옻을 타는 사람도 장치를 조작할 수 있으며, 폭기장치를 부착함으로써 빠른 시간 내에 우루시올을 완벽하게 제거할 수 있어 옻물 추출장치의 가동시간을 단축할 수 있도록 하였다. The present invention relates to a method and a device for removing urushiol (Urushiol), which is a toxic ingredient of lacquer, and at the same time, pharmacological ingredients with water, by attaching a reflux device so that the urushiol is not released to the outside with steam at all. Also, the device can be operated, and by attaching the aeration device, the urushiol can be completely removed in a short time, thereby reducing the running time of the lacquer extracting device.
본 발명의 우루시올 제거방법 및 장치는 옻을 타는 사람도 독성이 제거된 옻물을 제조할 수 있으며, 2시간 이내의 빠른 시간에 우루시올이 완벽하게 제거된 옻물을 제조하여 옻을 타는 사람도 복용할 수 있게 함으로써 질병을 예방하고 건강을 유지할 수 있게 하는 기능성 음료를 개발하고자 하는 것이다.Urushiol removal method and apparatus of the present invention can also produce lacquer from which the lacquer is eliminated toxic, and can also be taken by anyone who burns the lacquer by preparing urethane completely removed urushiol within a short time within 2 hours. The goal is to develop functional drinks that can help prevent illness and stay healthy.
또한 발명의 다른 목적은 독성을 나타내지 않는 우루시올을 회수하여 옻칠이나 다른 목적으로 사용함으로써 상업적인 면에서도 유리한 기능성음료인 옻물 제조방법 및 그 장치를 제공함에 있다.In addition, another object of the present invention is to provide a method and apparatus for preparing lacquer, which is a commercially advantageous functional drink by recovering urushiol which does not exhibit toxicity and using it for lacquer or other purposes.
종래의 옻물의 제조방법으로는 옻나무를 장시간 건조하여 소주를 첨가하여 가열하는 방법과(특1997-009320) 밤나무 잎을 동량 첨가하여 제조하는 방법(특2001-0011345)이 있으나 이들 방법은 첫째, 장시간 가열하여야 하는 점, 둘째로는 옻을 말리는 과정이나 가열 추출시에 옻을 타는 사람은 주변에 접근을 할 수 없는 단점을 지니고 있다. 또한 다른 성분을 추가하여 제조하는 방법은 옻물의 약리성분이 다른 성분으로 변하였거나 다른 성분과 반응하여 제거될 가능성을 배제할 수는 없다.Conventional methods of manufacturing lacquer include drying the lacquer for a long time and adding a soju to heat it (Special 1997-009320) and a method of adding the same amount of chestnut leaf (Special 2001-0011345). Secondly, the person who burns the lacquer during the process of drying the lacquer or during the extraction of the lacquer has a disadvantage that it cannot be approached. In addition, the method of manufacturing by adding other components cannot exclude the possibility that the pharmacological component of the lacquer is changed to another component or is removed by reaction with other components.
옻나무의 약리성분은 항암, 항바이러스, 항산화, 항곰팡이, 숙취해소, 아미노펩티다제 활성저해제 등의 약리작용을 하는 것으로 밝혀진 바 있다.(등록번호 10-0257448, 10-02515260)The pharmacological components of the lacquer tree have been found to act pharmacologically, such as anticancer, antiviral, antioxidant, antifungal, hangover, and aminopeptidase inhibitors. (Registration No. 10-0257448, 10-02515260)
이에 본 발명자들은 옻나무 독성성분인 우루시올을 빠른 시간 내에 제거하는 동시에 옻나무의 성분을 추출하는 방법과 그 제조 장치를 완성하고, 제거된 우루시올은 회수하여 독성성분이 없는 옻칠이나 약제로서 사용할 수 있게 함으로써 작업 안정성과 상업적 가치를 높였다. Accordingly, the present inventors have completed the method and extracting the components of the lacquer tree at the same time to remove urushiol, which is a poisonous component of lacquer, in a short time, and recovers the removed urushiol to be used as a lacquer or a medicament with no toxic component. Increased stability and commercial value.
옻나무는 옛부터 동양에서 한방이나 민간요법에서 약용으로 널리 사용되어 왔고, 변비, 여성의 생리기능 이상, 위장약, 구충제, 혈액순환, 각종 암치료제, 숙취 해소 및 노화 방지 등에 이용되고 있으나, 그 독성 때문에 쉽게 접근할 수 없고, 복용이나 취급이 어렵기 때문에 부분적으로 한의원에서 약재로 취급하거나 옻닭, 옻오리 등의 요리 방법을 통하여 간접적으로 옻을 타지 않는 일부의 사람들만이 옻의 약리 성분을 섭취하고 있는 실정이다. Sumac has been widely used in oriental medicine and folk medicine since ancient times, and has been used for constipation, dysmenorrhea, gastrointestinal drugs, repellents, blood circulation, various cancer treatments, hangovers, and anti-aging. Because it is not easily accessible, and it is difficult to take or handle, only some people who do not use lacquer indirectly through medicinal methods or indirectly through cooking methods such as lacquered chicken or lacquered duck are ingesting pharmacological ingredients of lacquer. It is true.
우루시올의 독성은 사람의 체질에 따라 다르지만 옻을 섭취한 사람과 간접적으로 접촉해도 옻이 오를 정도로 심하게 나타나기 때문에 옻의 약리작용을 알면서도 옻의 독성 때문에 옻나무에 접근하거나 옻을 섭취를 꺼려하고 있는 실정이다.Although the toxicity of urushiol varies depending on the constitution of a person, even if indirect contact with the person who consumed the lacquer appears so severe that the lacquer rises, the pharmacological action of the lacquer is known, but due to its toxicity, it is reluctant to approach or consume the lacquer. .
본 발명은 옻나무의 성분 중에서 알러지를 일으키는 성분인 우루시올(Urushiol)을 제거하는 방법 및 장치로서 옻나무와 껍질, 뿌리 등을 대패밥이나 톱밥의 형태로 잘게 부순 다음 환류장치와 폭기장치가 부착된 장치에 넣고 2시간동안 폭기하면서 가열하여 짧은 시간내에 우루시올을 제거하는 동시에 옻나무의 약리성분을 우려내는 방법이다. The present invention is a method and device for removing allergic components of urushiol (Urushiol) among the components of the lacquer, and finely crushed the lacquer, bark, root, etc. in the form of planer or sawdust, and then put in a device with a reflux device and aeration device It is a method that removes urushiol in a short time by heating with aeration for 2 hours, and at the same time, concerns the pharmacological components of lacquer trees.
본 발명에 속하는 장치는 환류장치와 폭기장치를 부착하여 옻나무 성분을 짧은 시간 내에 우루시올을 완전히 제거하는 새로운 방법이다.A device belonging to the present invention is a new method of attaching a reflux device and an aeration device to completely remove urushiol in a short time.
도 1은 본발명의 일 실시예에 따른 옻물 제조장치를 도시한다. 환류장치(1)는 기존의 공지된 장치로, 가열장치(3)의 상부와 연통되어 가열장치(3) 내에서 발생된 증기가 환류장치(1) 내를 통하여 흐르는 냉각수와 열교환으로 액화되어서 가열장치(3) 내로 환류되어 외부로 배출되지 못하도록 하는 장치로서, 증기에 포함된 우르시올이 외부로 유출되는 것을 방지하여 주변의 오염을 막고, 옻을 타는 사람도 장치를 안전하게 가동할 수 있게 한 것이고, 폭기장치 역시 공지된 장치로서, 가열장치(3) 내에 공기를 주입하여 가열장치 내의 내용물을 버블링시켜줌으로써 우루시올을 짧은 시간에 산화시키는 역할을 하는 것이다.Figure 1 shows a lacquer production apparatus according to an embodiment of the present invention. The reflux apparatus 1 is a conventionally known apparatus, in which the steam generated in the heating apparatus 3 is communicated with the upper portion of the heating apparatus 3 to liquefy by heat exchange with the cooling water flowing through the reflux apparatus 1 to be heated. A device that refluxs into the device 3 and prevents it from being discharged to the outside, thereby preventing the uricol contained in the vapor from leaking outside to prevent contamination of the surroundings and allowing the lacquer to operate the device safely. , Aeration device is also known as a device, it is to inject air into the heating device (3) to bubble the contents in the heating device serves to oxidize urushiol in a short time.
또한 발명의 다른 목적은 독성을 죽인 우루시올을 회수하여 옻칠이나 다른 목적으로 사용함으로써 상업적인 면에서도 유리한 기능성음료인 옻물 제조방법 및 그 장치를 제공함에 있다. In addition, another object of the present invention is to provide a method and apparatus for manufacturing lacquer, which is a functional beverage, which is advantageous in terms of commerciality, by recovering urushiol, which is toxic and used for lacquer or other purposes.
<실시예 1> 옻물추출과정Example 1 Lacquer Extraction Process
톱밥형태로 만든 8년 이상된 참옻나무와 껍질 1kg을 도 1의 장치에 넣은 후 물 20L를 추가한다. 그리고 <실시예 2-2>에 나타난 조건과 같이 가열장치 내의 물이 끓도록 가열함과 동시에 환류장치에 냉각수를 통과시키고 폭기장치로 공기를 불어넣으면서 교반시킨다. 2시간동안 상기의 상태를 유지시킨 후 1시간동안 방치하여 냉각시킨 다음 밸브를 틀어 여과장치로 옮긴 다음 여과하여 찌꺼기를 제거하고 독성이 제거된 옻물을 용기에 담아 포장한다.1 kg of oak and bark 8 years old made in the form of sawdust into the device of Figure 1, and then add 20L of water. Then, as shown in <Example 2-2>, the water in the heating device is heated to boil and at the same time passing the cooling water through the reflux device and stirred while blowing air into the aeration device. After maintaining the above state for 2 hours, it is left to cool for 1 hour, and then the valve is turned to the filtration apparatus, filtered to remove the debris, and the detoxified lacquer is packed in a container.
<실시예 2> 우루시올 제거 확인실험Example 2 Urushiol Removal Confirmation Experiment
<실시예 2-1> GC-MSD에 의한 우루시올(Urushiol)의 확인Example 2-1 Identification of Urushiol by GC-MSD
우루시올의 존재를 확인하기 위하여 에탄올에 녹인 생칠을 TLC plate 상에서 헥산:에틸아세테이트 (8:2 v/v)로 전개하여 우르시올로 추측되는 성분이(Rf=4.0) 다른 성분과 분리됨을 확인하였으며, 그 성분을 확인하기 위하여 컬럼크로마토 그래피로 분리하여 HP-Inowax 25m capillary column과 5973 MSD가 장착된 HP-6890 GC를 이용하여 분석한 결과 용출시간이 20~29분 사이에서 분자량 314~320을 갖는 여러 종류의 우르시올을 확인할 수 있었다.(그림 2 참조)In order to confirm the presence of urushiol, raw ethanol dissolved in ethanol was developed on a TLC plate with hexane: ethyl acetate (8: 2 v / v) to confirm that the component that is supposed to be urushiol (Rf = 4.0) was separated from other components. In order to identify the components, separated by column chromatography and analyzed using HP-Inowax 25m capillary column and HP-6890 GC equipped with 5973 MSD, the dissolution time was 20-29 minutes. The type of ursiol could be identified (see Figure 2).
<실시예 2-2> 생칠 중의 우루시올 제거 확인실험Example 2-2 Confirmation Test of Urushiol Removal in Raw Paste
50ml 3구 둥근바닥 프라스크에 환류냉각기와 온도계, 폭기장치를 부착하고 생옻칠 5g과 증류수 30ml를 넣는다. 자석교반기로 교반해 주면서 깨끗한공기를 주입하면서 120~130℃의 오일중탕냄비로 가열하여 환류시킨다. 옻물의 성분을 분석하기 위하여 10분 간격으로 소량의 옻칠과 옻물을 채취하여 에테르로 추출한다. 에테르층은 황산소오다로 건조한 다음 농축하여 TLC plate 상에서 헥산:에틸아세테이트 (8:2 v/v)로 전개하여 우르시올(Rf=4.0)의 존재를 확인한다. 그 결과 1.5시간 이내에 우루시올은 완전히 제거되었음을 확인할 수 있었다.A reflux cooler, thermometer, and aerator are attached to a 50 ml three-neck round bottom flask, and 5 g of fresh lacquer and 30 ml of distilled water are added. While stirring with a magnetic stirrer, clean air is injected and heated to reflux in an oil bath of 120 ~ 130 ℃. To analyze the components of the lacquer, a small amount of lacquer and lacquer are extracted every 10 minutes and extracted with ether. The ether layer was dried over sodium sulfate and concentrated to develop hexane: ethyl acetate (8: 2 v / v) on a TLC plate to confirm the presence of ursiol (Rf = 4.0). As a result, it was confirmed that urushiol was completely removed within 1.5 hours.
<실시예 2-3> 옻나무 중의 우루시올 제거 확인실험Example 2-3 Confirmation Test of Urushiol Removal in Sumac
상기 <실시예 2-2>와 동일하게 장치하고 톱밥형태의 생옻나무 10g을 상기 장치에서 제조한 옻물의 성분을 분석하기 위하여 10분 간격으로 옻물 50 ml 를 톱밥형태의 옻나무와 함께 시료를 채취하여 에테르로 3회 반복하여 추출한다. 추출한 에테르층은 황산소오다로 건조한 다음 농축하여 TLC plate 상에서 헥산:에틸아세테이트 (8:2 v/v)로 전개하여 우르시올의 존재를 확인한다. 1.5시간 이내에 우루시올은 완전히 제거됨을 확인할 수 있었다.In the same manner as in <Example 2-2> and 10g of sawdust-shaped raw lacquer tree in order to analyze the components of the lacquer prepared in the device 50ml of lacquer with a sawdust-like lacquer at 10 minutes intervals Extract three times with ether. The extracted ether layer was dried over sodium sulfate and concentrated to develop hexane: ethyl acetate (8: 2 v / v) on a TLC plate to confirm the presence of ursiol. It was confirmed that urushiol was completely removed within 1.5 hours.
<실시예 3> 우루시올의 회수 실험Example 3 Recovery of Urushiol
<실험1>에서 옻물을 제조하고 여과한 찌꺼기에 에탄올을 3L 추가하여 30분간 가열 환류시킨 다음 냉각시키고 다시 여과하고 난 다음에 여과액은 감압증발기에서 에탄올을 회수하고 농축액은 계속 감압증발시켜 물을 제거하여 우루시올 1.2g을 회수하였다. 회수한 중합상태의 우르시올은 소량의 알콜에 녹여 옻칠의 원료로 사용할 수 있었다.Prepared lacquer in <Experiment 1>, add 3L of ethanol to the filtered residue, heat reflux for 30 minutes, cool and filter again, and then the filtrate recovers ethanol from the evaporator under reduced pressure, and the concentrate is evaporated under reduced pressure. Removal removed 1.2 g of urushiol. The recovered urushiol was dissolved in a small amount of alcohol and could be used as a raw material for lacquer.
본 발명은 앞에서 살펴본 바와 같이 옻나무의 독성을 제거한 옻물의 제조방법 및 그 제조장치를 개발함으로써 다음과 같은 효과를 얻을 수 있다.As described above, the present invention can obtain the following effects by developing a method for manufacturing lacquer and a device for manufacturing the lacquer which have been removed from the poison of the lacquer.
폭기장치를 부착하여 2시간 이내의 빠른 시간 내에 우루시올을 쉽게 완전히 제거하는 방법을 발명하였으며, 가동시에 우루시올이 수분과 함께 공기중으로 유출되는 것을 방지하여 환경오염이 없으며, 옻을 타는 사람도 작동할 수 있도록 하였다. 생옻나무를 장시간 방치하여 건조하는 과정은 우르시올이 공기중으로 분산되어 대기오염을 일으키기 때문에 옻을 타는 사람의 접근이 불가하다.Invented a method to easily and completely remove urushiol within 2 hours by attaching an aeration device. Prevents urushiol from leaking into the air with moisture during operation, so there is no environmental pollution. To make it possible. The process of drying the dead lacquer for a long time is impossible to access the lacquer because urushiol is dispersed in the air causing air pollution.
본 발명은 생옻나무를 그대로 이용하여도 옻의 독성성분인 우루시올이 추출기 내부에서 쉽게 산화, 중합되어 불용성물질로 변하기 때문에 이를 회수하여 칠의 원료나 약재로서 사용할 수 있어 산업적 가치를 높일 수 있다. In the present invention, even if the raw lacquer tree is used as it is, urushiol, which is a toxic component of lacquer, is easily oxidized and polymerized inside the extractor to be converted into an insoluble material, so that it can be recovered and used as a raw material or medicinal herb of the lacquer, thereby enhancing industrial value.
독성을 제거한 옻물을 만듬으로써 옻밥, 옻닭, 옻오리, 옻영양탕, 옻빵, 옻국수, 옻물차, 옻김치, 옻고추장, 옻된장, 옻간장, 옻음료 및 한약재를 조합한 기능성음료의 제조 등 식생활에 필요한 음식물의 가공원료로 사용할 수 있으며, 각종 섬유류에 항균, 방충 및 부식을 방지하는 기능성 천연염색의 원료로 사용할 수 있으며, 3 내지 60%의 알콜도수를 갖는 기능성 술의 원료로도 사용할 수 있다. 또한 본 발명은 독성을 죽인 우르시올의 중합체를 얻음으로써 옻칠이나 약재로서 이용할 수 있는 방법도 포함한다. By making lacquer with no toxic substances, it is possible to make lacquered rice, lacquered chicken, lacquered duck, lactose nut soup, lacquered bread, lacquered noodles, lacquered tea, lacquered kimchi, lacquered red pepper paste, lacquered miso, lacquered soy sauce, lacquered beverage, and herbal beverages. It can be used as a raw material for food processing, and can be used as a raw material of functional natural dyeing to prevent antibacterial, insect repellent and corrosion on various fibers, and also as a raw material of functional liquor having an alcohol content of 3 to 60%. have. In addition, the present invention also includes a method which can be used as a lacquer or a medicine by obtaining a polymer of urushiol which has killed the toxicity.
도 1은 독성을 제거한 옻물의 제조장치 및 원심분리 여과장치이다.1 is a manufacturing apparatus and centrifugal filtration of the lacquer is removed toxicity.
도 2는 우루시올의 GC-MSD spectrum 이다.2 is a GC-MSD spectrum of urushiol.
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| KR102056836B1 (en) * | 2018-09-19 | 2020-01-22 | 주식회사 비플럭스파머 | A method of detoxifying lacquer and a device for detoxifying Lacquer tree |
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| KR20010070556A (en) | 2001-07-27 |
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