KR100491387B1 - 랜덤프로필렌공중합체의제조방법및그로부터수득된제품 - Google Patents

랜덤프로필렌공중합체의제조방법및그로부터수득된제품 Download PDF

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Publication number
KR100491387B1
KR100491387B1 KR1019970707632A KR19970707632A KR100491387B1 KR 100491387 B1 KR100491387 B1 KR 100491387B1 KR 1019970707632 A KR1019970707632 A KR 1019970707632A KR 19970707632 A KR19970707632 A KR 19970707632A KR 100491387 B1 KR100491387 B1 KR 100491387B1
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South Korea
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compound
electron donating
alkyl
dimethoxypropane
radical
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Korean (ko)
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KR19990008107A (ko
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기안니 콜리나
기암삐에로 모리니
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바셀 노쓰 아메리카 인코포레이티드
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
KR1019970707632A 1996-02-27 1997-02-25 랜덤프로필렌공중합체의제조방법및그로부터수득된제품 Expired - Fee Related KR100491387B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI96A000357 1996-02-27
IT96MI000357A IT1282691B1 (it) 1996-02-27 1996-02-27 Processo per la preparazione di copolimeri random del propilene e prodotti cosi' ottenuti

Related Child Applications (1)

Application Number Title Priority Date Filing Date
KR10-2004-7016749A Division KR100475760B1 (ko) 1996-02-27 1997-02-25 랜덤 프로필렌 공중합체의 제조방법 및 그로부터 수득된제품

Publications (2)

Publication Number Publication Date
KR19990008107A KR19990008107A (ko) 1999-01-25
KR100491387B1 true KR100491387B1 (ko) 2005-08-31

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KR1019970707632A Expired - Fee Related KR100491387B1 (ko) 1996-02-27 1997-02-25 랜덤프로필렌공중합체의제조방법및그로부터수득된제품
KR10-2004-7016749A Expired - Fee Related KR100475760B1 (ko) 1996-02-27 1997-02-25 랜덤 프로필렌 공중합체의 제조방법 및 그로부터 수득된제품

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Country Status (13)

Country Link
US (2) US6365685B1 (enExample)
EP (1) EP0822945B1 (enExample)
JP (1) JPH11504679A (enExample)
KR (2) KR100491387B1 (enExample)
AR (1) AR006009A1 (enExample)
AT (1) ATE236199T1 (enExample)
AU (1) AU730331B2 (enExample)
BR (1) BR9702095A (enExample)
CA (1) CA2218997A1 (enExample)
DE (1) DE69720338T2 (enExample)
ES (1) ES2193356T3 (enExample)
IT (1) IT1282691B1 (enExample)
WO (1) WO1997031954A1 (enExample)

Cited By (6)

* Cited by examiner, † Cited by third party
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WO2011087231A2 (ko) 2010-01-13 2011-07-21 삼성토탈 주식회사 프로필렌 중합용 고체촉매의 제조 방법 및 그에 의해 제조된 촉매
WO2012070753A2 (ko) 2010-11-24 2012-05-31 삼성토탈 주식회사 프로필렌 중합용 고체촉매 및 그 제조 방법
EP3330299A1 (en) 2016-12-05 2018-06-06 Hanwha Total Petrochemical Co., Ltd. Process of manufacture of catalyst and propylene polymer that use this or copolymer for propylene polymerization
EP3670546A1 (en) 2018-12-20 2020-06-24 Hanwha Total Petrochemical Co., Ltd. Solid catalyst for propylene polymerization and method of producing block copolymer using the same
EP3812403A1 (en) 2019-10-21 2021-04-28 Hanwha Total Petrochemical Co., Ltd. Preparation method of solid catalyst for propylene polymerization
EP4361186A1 (en) 2022-10-24 2024-05-01 Hanwha TotalEnergies Petrochemical Co., Ltd. Solid catalyst for producing polypropylene and method for preparation of propylene-derived polymer

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US5968865A (en) * 1997-12-10 1999-10-19 Union Carbide Chemicals & Plastics Technology Corporation Electron donor containing compositions
US6124507A (en) * 1997-12-10 2000-09-26 Union Carbide Chemicals & Plastics Technology Corporation Electron donors
SG73622A1 (en) * 1998-03-11 2000-06-20 Sumitomo Chemical Co Solid catalyst component and catalyst for olefin polymerization and process for producing olefin polymer
US6657025B2 (en) * 2001-01-12 2003-12-02 Fina Technology, Inc. Production of ultra high melt flow polypropylene resins
DE60129939T2 (de) 2001-06-27 2008-05-15 Borealis Technology Oy Verfahren zur Herstellung einer Polymerfolie die ein statistisches Propylencopolymer enthält
SG99976A1 (en) * 2002-03-26 2003-11-27 Sumitomo Chemical Co Propylene-based polymer and injection molded article made of the same
EP1778472A1 (en) * 2004-07-29 2007-05-02 BFS Diversified Products, LLC Construction laminates
CN101175778B (zh) * 2005-05-12 2011-12-07 巴塞尔聚烯烃意大利有限责任公司 丙烯-乙烯共聚物和它们的制备方法
DE602007001805D1 (de) * 2006-04-24 2009-09-10 Total Petrochemicals Res Feluy Verfahren zur herstellung von propylenpolymeren mit geringem aschegehalt
EP2226337A1 (en) 2009-03-02 2010-09-08 Borealis AG Process for the production of polypropylene random copolymers for injection moulding applications
KR101982897B1 (ko) 2011-09-16 2019-05-27 벤즈리써치앤드디벨롭먼트코오포레이숀 소수성 안내 렌즈
SG189671A1 (en) 2011-10-29 2013-05-31 China Petroleum & Chemical Propylene random copolymer, method for its preparation, and compositions and articles containing the same
EP2610274A1 (en) * 2011-12-30 2013-07-03 Borealis AG Propylene random copolymer
US9522968B2 (en) * 2012-11-26 2016-12-20 Lummus Novolen Technology Gmbh High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof
US9284392B2 (en) * 2013-03-15 2016-03-15 Basf Corporation Mixed internal donor structures for 1-olefin polymerization catalysts
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US9593179B2 (en) 2014-02-07 2017-03-14 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
EP3140329B1 (en) * 2014-05-06 2019-07-24 Basell Poliolefine Italia S.r.l. Random propylene-ethylene copolymers
BR112016024101B1 (pt) * 2014-05-06 2021-11-16 Basell Poliolefine Italia S.R.L. Copolímeros aleatórios de propileno e etileno com múltiplas camadas
CN106232643B (zh) 2014-05-06 2019-02-26 巴塞尔聚烯烃意大利有限公司 无规丙烯-乙烯共聚物及其制备方法
CA3102001A1 (en) 2018-06-11 2019-12-19 W.R. Grace & Co.-Conn Propylene-ethylene random copolymers with low xs/et ratio and high mfr
US11834534B2 (en) 2018-08-22 2023-12-05 Basell Poliolefine Italia S.R.L. Random propylene-ethylene copolymers
EP3983456A1 (en) * 2019-06-14 2022-04-20 3D Systems, Inc. Polypropylene-based particles for additive manufacturing

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IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
IT1221653B (it) * 1987-11-27 1990-07-12 Ausimonti Spa Copolimeri cristallini del propilene
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US5618895A (en) 1990-04-06 1997-04-08 Basf Aktiengesellschaft Process for preparing copolymers of propylene with other 1-alkenes
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011087231A2 (ko) 2010-01-13 2011-07-21 삼성토탈 주식회사 프로필렌 중합용 고체촉매의 제조 방법 및 그에 의해 제조된 촉매
US9045572B2 (en) 2010-01-13 2015-06-02 Samsung Total Petrochemicals Co., Ltd. Preparation method of solid catalyst for propylene polymerization and catalyst prepared thereby
WO2012070753A2 (ko) 2010-11-24 2012-05-31 삼성토탈 주식회사 프로필렌 중합용 고체촉매 및 그 제조 방법
EP3330299A1 (en) 2016-12-05 2018-06-06 Hanwha Total Petrochemical Co., Ltd. Process of manufacture of catalyst and propylene polymer that use this or copolymer for propylene polymerization
EP3683243A1 (en) 2016-12-05 2020-07-22 Hanwha Total Petrochemical Co., Ltd. Process of manufacture of catalyst and propylene polymer that use this or copolymer for propylene polymerization
EP3670546A1 (en) 2018-12-20 2020-06-24 Hanwha Total Petrochemical Co., Ltd. Solid catalyst for propylene polymerization and method of producing block copolymer using the same
EP3812403A1 (en) 2019-10-21 2021-04-28 Hanwha Total Petrochemical Co., Ltd. Preparation method of solid catalyst for propylene polymerization
EP4361186A1 (en) 2022-10-24 2024-05-01 Hanwha TotalEnergies Petrochemical Co., Ltd. Solid catalyst for producing polypropylene and method for preparation of propylene-derived polymer

Also Published As

Publication number Publication date
AU730331B2 (en) 2001-03-01
BR9702095A (pt) 1999-07-20
ATE236199T1 (de) 2003-04-15
KR19990008107A (ko) 1999-01-25
AU2039797A (en) 1997-09-16
IT1282691B1 (it) 1998-03-31
WO1997031954A1 (en) 1997-09-04
ITMI960357A0 (enExample) 1996-02-27
EP0822945A1 (en) 1998-02-11
DE69720338D1 (de) 2003-05-08
US6365685B1 (en) 2002-04-02
AR006009A1 (es) 1999-07-21
ITMI960357A1 (it) 1997-08-27
US20020137860A1 (en) 2002-09-26
ES2193356T3 (es) 2003-11-01
JPH11504679A (ja) 1999-04-27
KR100475760B1 (ko) 2005-03-14
KR20040103975A (ko) 2004-12-09
CA2218997A1 (en) 1997-09-04
US6693161B2 (en) 2004-02-17
DE69720338T2 (de) 2004-02-12
EP0822945B1 (en) 2003-04-02

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