KR100419969B1 - Composition for cleaning foods - Google Patents
Composition for cleaning foods Download PDFInfo
- Publication number
- KR100419969B1 KR100419969B1 KR10-2001-0076272A KR20010076272A KR100419969B1 KR 100419969 B1 KR100419969 B1 KR 100419969B1 KR 20010076272 A KR20010076272 A KR 20010076272A KR 100419969 B1 KR100419969 B1 KR 100419969B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- food
- composition
- ethanol
- sodium citrate
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 235000013305 food Nutrition 0.000 title claims abstract description 28
- 238000004140 cleaning Methods 0.000 title abstract description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 54
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 36
- GCSPRLPXTPMSTL-IBDNADADSA-N [(2s,3r,4s,5s,6r)-2-[(2s,3s,4s,5r)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[C@@]1([C@]2(CO)[C@H]([C@H](O)[C@@H](CO)O2)O)O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O GCSPRLPXTPMSTL-IBDNADADSA-N 0.000 claims abstract description 21
- 239000003599 detergent Substances 0.000 claims abstract description 20
- 239000001509 sodium citrate Substances 0.000 claims abstract description 19
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 239000000575 pesticide Substances 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 9
- 239000002994 raw material Substances 0.000 abstract description 5
- 230000009931 harmful effect Effects 0.000 abstract description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 abstract 2
- 229910000160 potassium phosphate Inorganic materials 0.000 abstract 1
- 235000011009 potassium phosphates Nutrition 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 description 10
- 239000008213 purified water Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 241000208822 Lactuca Species 0.000 description 4
- 235000003228 Lactuca sativa Nutrition 0.000 description 4
- 241000207961 Sesamum Species 0.000 description 4
- 235000003434 Sesamum indicum Nutrition 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 238000011109 contamination Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
본 발명은 식용가능한 원료만을 사용하여 적절히 조합함으로써 세정효과가 우수하고 세정제가 식품에 잔류하더라도 인체에 무해할 뿐만 아니라 식품의 잔류농약 또한 제거할 수 있는 식품용 세정제 조성물에 관한 것으로서, 구연산나트륨, 피로인산칼륨 또는 이들의 혼합물 3 내지 20중량%, 자당라우레이트(Sucrose laurate) 0.1 내지 2중량%, 에탄올 1 내지 10중량%, 프로필렌글리콜 1 내지 10중량% 및 잔량으로서 물을 포함하여 이루어짐을 특징으로 한다.The present invention relates to a food detergent composition which is excellent in cleaning effect by using only edible raw materials, and which is not harmful to the human body even if the detergent remains in the food, and also removes the residual pesticides of the food. Sodium citrate, fatigue 3 to 20% by weight of potassium phosphate or a mixture thereof, 0.1 to 2% by weight of sucrose laurate, 1 to 10% by weight of ethanol, 1 to 10% by weight of propylene glycol, and the balance as water do.
Description
본 발명은 야채, 과일 등의 세정을 위하여 사용되는 식품용 세정제 조성물에 관한 것으로, 더욱 상세하게는 식용가능한 원료만을 사용하여 적절히 조합함으로써 세정효과가 우수하고 세정제가 식품에 잔류하더라도 인체에 무해할 뿐만 아니라 식품의 잔류농약 또한 제거할 수 있는 식품용 세정제 조성물에 관한 것이다.The present invention relates to a detergent composition for foods used for washing vegetables, fruits, and the like, and more particularly, by using only an edible raw material and properly combined, the cleaning effect is excellent and harmless to the human body even if the detergent remains in the food. It also relates to a food detergent composition that can also remove residual pesticides in food.
일반적으로, 식기세척 등의 용도로써 다양한 주방세제가 사용되고 있는데, 이들은 오염을 깨끗이 제거하고, 헹굼도 잘 되는 유익한 점이 있지만, 이들을 식품세정 용도로서 대용하기에는, 일부 야채, 과일 등의 식품에 대해서는 세정효과가 양호하지 못하며 과일 등에 잔류할 경우 인체에 유해한 영향을 끼칠 가능성이 있고, 세정을 하더라도 식품의 잔류농약을 제거하지 못하는 문제점이 있었다.In general, various dish detergents are used for the purpose of dishwashing, but they are advantageous in removing dirt and rinsing well.However, in order to substitute them for food washing, some vegetables, fruits and the like have a washing effect. Is not good and there is a possibility that harmful effects on the human body if left in the fruit, there is a problem that can not remove the residual pesticides of food even if washed.
이러한 문제점을 해결하기 위한 방안으로, 미국 특허 제5,498,295호에 식품 세정 방법 및 그 조성물에 관하여 출원된 바 있다. 이 식품용 세정제 조성물의 경우 식용가능한 원료만을 사용한 것은 아니므로 인체 유해성 우려가 여전히 존재하며, 조성물의 pH가 9.5 내지 12.5의 범위에 속하여 강알카리성이므로 피부자극 발생의 문제점이 있다.In order to solve this problem, US Patent No. 5,498, 295 has been filed with respect to food cleaning methods and compositions thereof. In the case of the food detergent composition, only edible raw materials are used, so there is still a concern about human hazards, and since the pH of the composition is strongly alkaline in the range of 9.5 to 12.5, there is a problem of skin irritation.
그외, 미국 특허 제5,503,764호에 식품 세정제 조성물에 관하여 출원된 바 있으나, 이 또한 식용가능한 원료만을 사용한 것이 아니므로 인체 유해성 우려가 존재하는 문제점이 있다.In addition, although US Patent No. 5,503,764 has been filed with respect to the food detergent composition, this also has a problem that there is a risk of human health because it is not used only edible raw materials.
또한, 한국 특허공개 제1999-0055305호에 구연산나트륨과 폴리옥시에틸렌 솔비탄 모노 미리스테이트를 주성분으로 함유하는 식품용 세정제 조성물에 관하여 출원된 바 있다.In addition, Korean Patent Publication No. 1999-0055305 has been filed for a food detergent composition containing sodium citrate and polyoxyethylene sorbitan mono myristate as a main component.
본 발명은 앞서 설명한 바와 같은 종래 기술의 문제점을 더욱 효율적으로 해결하기 위하여 제공된 것으로서, 그 목적은 구연산나트륨, 피로인산칼륨 또는 이들의 혼합물, 자당라우레이트, 에탄올, 프로필렌글리콜과 같은 식용가능한 원료만을 사용하여 적절히 조합함으로써 세정효과가 우수하고 세정제가 식품에 잔류하더라도 인체에 무해할 뿐만 아니라 기름기 등의 세정력이 우수하여 식품의 잔류농약 또한 제거할 수 있는 식품용 세정제 조성물을 제공하고자 하는 것이다.The present invention has been provided to more efficiently solve the problems of the prior art as described above, the object of which is to use only edible raw materials such as sodium citrate, potassium pyrophosphate or mixtures thereof, sucrose laurate, ethanol, propylene glycol By properly combining, the cleaning effect is excellent, and even if the detergent remains in the food, it is not only harmless to the human body, but also has excellent cleaning power, such as oily, to provide a food detergent composition for removing the residual pesticides of the food.
상기한 목적을 달성하기 위하여 본 발명에 따른 식품용 세정제 조성물은 구연산나트륨, 피로인산칼륨 또는 이들의 혼합물 3 내지 20중량%, 자당라우레이트(Sucrose laurate) 0.1 내지 2중량%, 에탄올 1 내지 10중량%, 프로필렌글리콜 1 내지 10중량% 및 잔량으로서 물을 포함하여 이루어짐을 특징으로 한다.Food detergent composition according to the present invention for achieving the above object is 3 to 20% by weight of sodium citrate, potassium pyrophosphate or mixtures thereof, 0.1 to 2% by weight of sucrose laurate, 1 to 10% by weight of ethanol %, 1 to 10% by weight of propylene glycol and the balance comprises water.
또한, 상기 자당라우레이트는 하기 화학식 1로 표시된다 ;In addition, the sucrose laurate is represented by the following formula (1);
상기 식에서, R은 C12의 알킬기이다.In the above formula, R is an alkyl group of C 12 .
이하에는 이러한 구성에 따른 본 발명의 식품용 세정제 조성물의 작용 효과를 상세히 설명한다.Hereinafter, the effect of the food detergent composition of the present invention according to such a configuration will be described in detail.
본 발명의 식품용 세정제 조성물은 그 구성성분으로서 구연산나트륨, 피로인산칼륨 또는 이들의 혼합물, 자당라우레이트(Sucrose laurate), 에탄올, 프로필렌글리콜 및 물을 포함하는데, 이들은 모두「식품첨가물공전」 및 「식품공전」에 식용가능한 것으로 수록되어 있는 것이다.The food detergent composition of the present invention includes sodium citrate, potassium pyrophosphate or a mixture thereof, sucrose laurate, ethanol, propylene glycol, and water, all of which are described in "Food Additives" and " Food Code ”is listed as edible.
이들 중, 유기산염인 구연산나트륨, 무기산염인 피로인산칼륨 또는 이들의 혼합물은 살포된 농약의 지용성성분이 흡착되어 있는 농산물 껍질층의 왁스성분을 제거함으로써 발생되는 용액의 알칼리도 변화를 방지하며, 금속이온에 대한 킬레이트효과를 나타내는 작용을 한다.Of these, sodium citrate as an organic acid, potassium pyrophosphate as an inorganic acid, or a mixture thereof prevents the alkalinity change of the solution generated by removing the wax component of the agricultural product layer on which the fat-soluble component of the applied pesticide is adsorbed, and the metal It acts as a chelating effect on ions.
이러한 본 발명의 구연산나트륨, 피로인산칼륨 또는 이들의 혼합물은 조성물 총 중량에 대하여 3중량% 미만의 양으로 사용할 경우 식품 중의 잔류농약을 제거할 수 없는 문제점이 있으며, 20중량% 초과의 양으로 사용할 경우 조성물의 외관이 불투명하게 되어 종국에는 분리현상이 발생하는 문제점이 있다. 따라서, 본 발명의구연산나트륨, 피로인산칼륨 또는 이들의 혼합물은 조성물 총 중량에 대하여 3 내지 20중량%의 양으로 사용하는 것이 바람직하다.Sodium citrate, potassium pyrophosphate or a mixture thereof of the present invention can not remove the residual pesticides in food when used in an amount of less than 3% by weight based on the total weight of the composition, it is used in an amount of more than 20% by weight When the appearance of the composition becomes opaque, there is a problem that the separation phenomenon occurs in the end. Accordingly, the sodium citrate, potassium pyrophosphate or mixtures thereof of the present invention is preferably used in an amount of 3 to 20% by weight based on the total weight of the composition.
자당라우레이트는 상기한 효과를 상승시키기 위한 계면활성제로서 포함된다. 이러한 역할을 수행하기 위하여 자당라우레이트는 하기 화학식 1로 표시되는 것을 사용하는 것이 더욱 바람직하다 ;Sucrose laurate is included as a surfactant for enhancing the above effects. In order to perform this role, it is more preferable to use sucrose laurate represented by the following formula (1);
화학식 1Formula 1
상기 식에서, R은 C12의 알킬기이다.In the above formula, R is an alkyl group of C 12 .
이러한 본 발명의 자당라우레이트(Sucrose laurate)는 조성물 총 중량에 대하여 0.1중량% 미만의 양으로 사용할 경우 잔류농약을 제거할 수 없는 문제점이 있으며, 2중량% 초과의 양으로 사용할 경우 사용시 거품이 지나치게 발생하여 헹굼과정을 여러번 해야 하는 불편함이 있다. 따라서, 본 발명의 자당라우레이트는 조성물 총 중량에 대하여 0.1 내지 2중량%의 양으로 사용하는 것이 바람직하다.Sucrose laurate of the present invention is a problem that can not remove the residual pesticide when used in an amount of less than 0.1% by weight relative to the total weight of the composition, when used in an amount of more than 2% by weight excessive foam There is an inconvenience of having to rinse several times. Therefore, the sucrose laurate of the present invention is preferably used in an amount of 0.1 to 2% by weight based on the total weight of the composition.
그 외, 에탄올과 프로필렌글리콜은 농산물 왁스성분에 대한 용매효과를 제공하며 안정성을 부여하는 작용을 한다.In addition, ethanol and propylene glycol provide a solvent effect on the agricultural wax component and acts to impart stability.
본 발명의 에탄올과 프로필렌글리콜 각 성분은 조성물 총 중량에 대하여 1중량% 미만의 양으로 사용할 경우, 과일 등의 표면의 왁스층의 제거가 충분치 못하여잔류농약의 제거가 충분치 못하게 되는 문제점이 있을 수 있으며, 10중량% 초과의 양으로 사용할 경우 배합되는 물의 양이 상대적으로 줄어듦으로써 구연산나트륨, 피로인산칼륨의 용해도가 낮아져 조성물을 불안정하게 하는 문제점이 있을 수 있다. 따라서, 본 발명의 에탄올과 프로필렌글리콜 각 성분은 조성물 총 중량에 대하여 1 내지 10중량%의 양으로 사용하는 것이 바람직하다.When the ethanol and propylene glycol components of the present invention are used in an amount of less than 1% by weight based on the total weight of the composition, there may be a problem that the removal of the residual pesticides may not be enough due to insufficient removal of the wax layer on the surface of the fruit, When used in an amount of more than 10% by weight, the amount of water to be blended is relatively reduced, so that the solubility of sodium citrate and potassium pyrophosphate is lowered, which may cause a problem of destabilizing the composition. Therefore, the ethanol and propylene glycol components of the present invention is preferably used in an amount of 1 to 10% by weight based on the total weight of the composition.
본 발명의 조성물은 그 외 잔량으로서 물을 포함하여 이루어진다.The composition of the present invention comprises water as the remaining amount.
이하 식품용 세정제 조성물을 실시예 및 비교예를 들어 보다 구체적으로 설명하지만 본 발명이 이들예로만 한정되는 것은 아니다.Hereinafter, the detergent composition for food will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited only to these examples.
[실시예 1]Example 1
구연산나트륨 4.0중량%, 피로인산칼륨 0중량%, 자당라우레이트 1.5중량%, 에탄올 8중량%, 프로필렌글리콜 2중량% 및 잔량으로서 정제수를 함유하도록 배합한 후, 통상의 세정제 조성물 제조방법과 동일한 방법에 따라 제조하였다.4.0% by weight of sodium citrate, 0% by weight of potassium pyrophosphate, 1.5% by weight of sucrose laurate, 8% by weight of ethanol, 2% by weight of propylene glycol, and the balance to contain purified water, followed by the same method as in the conventional method for preparing a cleaning composition. It was prepared according to.
[실시예 2]Example 2
구연산나트륨 10중량%, 피로인산칼륨 5중량%, 자당라우레이트 1.0중량%, 에탄올 5중량%, 프로필렌글리콜 5중량% 및 잔량으로서 정제수를 함유하도록 배합한 후, 통상의 세정제 조성물 제조방법과 동일한 방법에 따라 제조하였다.10% by weight of sodium citrate, 5% by weight of potassium pyrophosphate, 1.0% by weight of sucrose laurate, 5% by weight of ethanol, 5% by weight of propylene glycol, and the balance to contain purified water, followed by the same method as in the conventional method for preparing a cleaning composition. It was prepared according to.
[실시예 3]Example 3
구연산나트륨 15중량%, 피로인산칼륨 5중량%, 자당라우레이트 0.5중량%, 에탄올 3중량%, 프로필렌글리콜 8중량% 및 잔량으로서 정제수를 함유하도록 배합한 후, 통상의 세정제 조성물 제조방법과 동일한 방법에 따라 제조하였다.15% by weight of sodium citrate, 5% by weight of potassium pyrophosphate, 0.5% by weight of sucrose laurate, 3% by weight of ethanol, 8% by weight of propylene glycol, and the balance to contain purified water, followed by the same method as in the conventional method for preparing a cleaning composition. It was prepared according to.
[실시예 4]Example 4
구연산나트륨 5중량%, 피로인산칼륨 10중량%, 자당라우레이트 0.5중량%, 에탄올 5중량%, 프로필렌글리콜 5중량% 및 잔량으로서 정제수를 함유하도록 배합한 후, 통상의 세정제 조성물 제조방법과 동일한 방법에 따라 제조하였다.5% by weight of sodium citrate, 10% by weight of potassium pyrophosphate, 0.5% by weight of sucrose laurate, 5% by weight of ethanol, 5% by weight of propylene glycol, and the balance to contain purified water, followed by the same method as in the conventional method for preparing a cleaning composition. It was prepared according to.
[실시예 5]Example 5
구연산나트륨 8중량%, 피로인산칼륨 5중량%, 자당라우레이트 0.5중량%, 에탄올 5중량%, 프로필렌글리콜 5중량% 및 잔량으로서 정제수를 함유하도록 배합한 후, 통상의 세정제 조성물 제조방법과 동일한 방법에 따라 제조하였다.8% by weight of sodium citrate, 5% by weight of potassium pyrophosphate, 0.5% by weight of sucrose laurate, 5% by weight of ethanol, 5% by weight of propylene glycol, and the balance to contain purified water, followed by the same method as in the conventional method for preparing a cleaning composition. It was prepared according to.
[실시예 6]Example 6
피로인산칼륨 4중량%, 자당라우레이트 1.5중량%, 에탄올 8중량%, 프로필렌글리콜 2중량% 및 잔량으로서 정제수를 함유하도록 배합한 후, 통상의 세정제 조성물 제조방법과 동일한 방법에 따라 제조하였다.After mixing 4% by weight of potassium pyrophosphate, 1.5% by weight of sucrose laurate, 8% by weight of ethanol, 2% by weight of propylene glycol, and the remaining amount as purified water, it was prepared according to the same method as in the conventional method for preparing a detergent composition.
[실시예 7]Example 7
구연산나트륨 5중량%, 피로인산칼륨 10중량%, 자당라우레이트 1.0중량%, 에탄올 5중량%, 프로필렌글리콜 5중량% 및 잔량으로서 정제수를 함유하도록 배합한 후, 통상의 세정제 조성물 제조방법과 동일한 방법에 따라 제조하였다.5% by weight of sodium citrate, 10% by weight of potassium pyrophosphate, 1.0% by weight of sucrose laurate, 5% by weight of ethanol, 5% by weight of propylene glycol, and the balance to contain purified water, followed by the same method as in the conventional method for preparing a cleaning composition. It was prepared according to.
[실시예 8]Example 8
구연산나트륨 5중량%, 피로인산칼륨 15중량%, 자당라우레이트 0.5중량%, 에탄올 3중량%, 프로필렌글리콜 8중량% 및 잔량으로서 정제수를 함유하도록 배합한 후, 통상의 세정제 조성물 제조방법과 동일한 방법에 따라 제조하였다.5% by weight of sodium citrate, 15% by weight of potassium pyrophosphate, 0.5% by weight of sucrose laurate, 3% by weight of ethanol, 8% by weight of propylene glycol, and the balance to contain purified water, followed by the same method as in the conventional method for preparing a cleaning composition. It was prepared according to.
[실시예 9]Example 9
구연산나트륨 4중량%, 피로인산칼륨 10중량%, 자당라우레이트 0.5중량%, 에탄올 5중량%, 프로필렌글리콜 5중량% 및 잔량으로서 정제수를 함유하도록 배합한 후, 통상의 세정제 조성물 제조방법과 동일한 방법에 따라 제조하였다.4% by weight of sodium citrate, 10% by weight of potassium pyrophosphate, 0.5% by weight of sucrose laurate, 5% by weight of ethanol, 5% by weight of propylene glycol, and the balance to contain purified water, followed by the same method as in the conventional method of preparing a cleaning composition. It was prepared according to.
[실시예 10]Example 10
구연산나트륨 5중량%, 피로인산칼륨 5중량%, 자당라우레이트 0.5중량%, 에탄올 5중량%, 프로필렌글리콜 5중량% 및 잔량으로서 정제수를 함유하도록 배합한 후, 통상의 세정제 조성물 제조방법과 동일한 방법에 따라 제조하였다.5% by weight of sodium citrate, 5% by weight of potassium pyrophosphate, 0.5% by weight of sucrose laurate, 5% by weight of ethanol, 5% by weight of propylene glycol, and the balance to contain purified water, followed by the same method as in the conventional method of preparing a cleaning composition. It was prepared according to.
[시험예 1][Test Example 1]
상기 실시예 1 내지 10의 조성물 1.0%용액 및 물(비교예 1) 4ℓ에 상추와 깻잎을 각 200g씩 투여한 다음, 75rpm의 속도로 3분동안 진탕기에서 세척하였다. 이를 건조한 후 상추와 깻잎 각 50g을 100㎖의 아세톤으로 추출한 다음, 추출액을 다시 100㎖의 헥산에 용해하여 여과한 후 감압·농축하였다. 이를 다시 헥산 20㎖에 용해하여 GC/ECD로 분석하여 잔류농약 제거율을 측정한 결과를 하기 표 1에 나타내었다.200 g of lettuce and sesame leaves were administered to the 1.0% solution of the composition of Examples 1 to 10 and 4 L of water (Comparative Example 1), and then washed in a shaker for 3 minutes at a speed of 75 rpm. After drying, 50 g of each lettuce and sesame leaves were extracted with 100 ml of acetone. The extract was further dissolved in 100 ml of hexane, filtered, and concentrated under reduced pressure. This was again dissolved in 20 ml of hexane and analyzed by GC / ECD to determine the residual pesticide removal rate.
상기 표 1에서 알 수 있는 바와 같이, 실시예 1 내지 10의 조성물을 사용하여 측정한 상추 및 깻잎의 잔류농약 제거율은 90% 이상으로 우수함을 알 수 있다.As can be seen in Table 1, it can be seen that the residual pesticide removal rate of lettuce and sesame leaves measured using the compositions of Examples 1 to 10 is excellent as 90% or more.
[시험예 2][Test Example 2]
상기 실시예 1 내지 10의 조성물 1.0%용액 및 물(비교예 1)을 시료로 하여 기름오염의 세정력을 한국표준협회의 합성세제시험방법(KS-M-2709; 주방세제세척력 평가법)에 의하여 평가하였다. 즉, 모델 유리편(Slide glass)에 오염을 묻힌 후 시료용액으로 세정한 다음 세정정도를 오염의 제거율(무게%)로 나타낸 것으로, 그 결과를 하기 표 2에 나타내었다.Using the 1.0% solution of the composition of Examples 1 to 10 and water (Comparative Example 1) as a sample, the cleaning power of oil contamination was evaluated by the synthetic detergent test method (KS-M-2709; dishwashing detergent evaluation method) of the Korean Standards Association. It was. That is, after staining the model glass (Slide glass) was washed with a sample solution and then the degree of cleaning was expressed as the removal rate (% by weight) of the contamination, the results are shown in Table 2 below.
상기 표 2에서 알 수 있는 바와 같이, 실시예 1 내지 10의 조성물을 사용하여 측정한 기름오염의 제거율은 비교예 1에 비하여 우수함을 알 수 있다.As can be seen in Table 2, it can be seen that the removal rate of oil contamination measured using the compositions of Examples 1 to 10 is superior to Comparative Example 1.
이상에서 알 수 있는 바와 같이, 본 발명의 식품용 세정제 조성물은 세정효과가 우수하며 식용성분만을 포함하도록 구성됨으로써 세제가 식품에 잔류하더라도 인체에 무해할 뿐만 아니라 식품의 잔류농약을 제거할 수 있는 장점이 있다.As can be seen from the above, the detergent composition for food of the present invention has an excellent cleaning effect and is configured to include only edible ingredients, even if the detergent remains in the food is not only harmless to the human body as well as the advantage of removing the residual pesticides of food There is this.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2001-0076272A KR100419969B1 (en) | 2001-12-04 | 2001-12-04 | Composition for cleaning foods |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2001-0076272A KR100419969B1 (en) | 2001-12-04 | 2001-12-04 | Composition for cleaning foods |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20030045525A KR20030045525A (en) | 2003-06-11 |
| KR100419969B1 true KR100419969B1 (en) | 2004-02-26 |
Family
ID=29572947
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR10-2001-0076272A KR100419969B1 (en) | 2001-12-04 | 2001-12-04 | Composition for cleaning foods |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR100419969B1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102239622B1 (en) * | 2019-11-25 | 2021-04-12 | 유융준 | Car cement whitening remover |
| CN113974026B (en) * | 2021-09-24 | 2024-03-08 | 河北绿诺食品有限公司 | Processing technology of fructose-containing concentrated apple juice and concentrated apple juice |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR940019848A (en) * | 1993-02-15 | 1994-09-15 | 원본미기재 | Detergent composition |
| US6056983A (en) * | 1997-05-30 | 2000-05-02 | Broshi; Oded | Edible pleasant tasting bubble making composition |
| KR20000067301A (en) * | 1999-04-27 | 2000-11-15 | 성재갑 | Compositions of detergent for washing vegetable and fruit |
| KR20010110135A (en) * | 2000-05-31 | 2001-12-12 | 야스오 사도야마 | Detergent composition and preparation method thereof |
| KR20030012315A (en) * | 2001-07-31 | 2003-02-12 | 보령메디앙스 주식회사 | The detergent composition for baby goods including baby bottles |
-
2001
- 2001-12-04 KR KR10-2001-0076272A patent/KR100419969B1/en not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR940019848A (en) * | 1993-02-15 | 1994-09-15 | 원본미기재 | Detergent composition |
| US6056983A (en) * | 1997-05-30 | 2000-05-02 | Broshi; Oded | Edible pleasant tasting bubble making composition |
| KR20000067301A (en) * | 1999-04-27 | 2000-11-15 | 성재갑 | Compositions of detergent for washing vegetable and fruit |
| KR20010110135A (en) * | 2000-05-31 | 2001-12-12 | 야스오 사도야마 | Detergent composition and preparation method thereof |
| KR20030012315A (en) * | 2001-07-31 | 2003-02-12 | 보령메디앙스 주식회사 | The detergent composition for baby goods including baby bottles |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20030045525A (en) | 2003-06-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4620937A (en) | All purpose cleaner containing D-Limonene | |
| JP3919828B2 (en) | Methods and compositions for reducing microorganisms for food | |
| US4808330A (en) | Non-toxic detergent for cleaning fruit and vegetables | |
| JP3181598B2 (en) | Cleaning / sanitary methods, compositions and / or articles for natural products | |
| US4177294A (en) | Aqueous cleaning concentrate for the cleaning of foodstuff | |
| EP0625185A1 (en) | Aqueous cleaner containing trisodium phosphate, edta or phytic acid, and solvent mixture | |
| JP2002530097A (en) | Microorganism control method and composition for food | |
| JP3037605B2 (en) | Disinfectant cleaning composition | |
| KR100419969B1 (en) | Composition for cleaning foods | |
| CN106190645A (en) | A kind of multifunction detergent and preparation method thereof | |
| JP2002294286A (en) | Bactericidal detergent composition | |
| KR0163503B1 (en) | Composition for cleaning fruits and vegetable | |
| KR100638004B1 (en) | Compositions of detergent for washing vegetable and fruit | |
| GB2292563A (en) | Food, fruit and vegetable wash | |
| CN107603787B (en) | Tableware detergent composition and preparation method thereof | |
| KR100449211B1 (en) | Nonpolluting and nontoxic detergent composition for kitchen | |
| US20080131394A1 (en) | Natural Cleanser Having Antioxidant Composition | |
| CN105838515A (en) | Liquid cleanser | |
| US6225268B1 (en) | Liquid detergent composition | |
| JPH0571639B2 (en) | ||
| JP2016125048A (en) | Liquid detergent | |
| KR102295942B1 (en) | Method for manufacturing dishwashing detergent composition using soapberry extract | |
| KR20120075718A (en) | External skin preparation containing cream derived from milk | |
| KR19990055305A (en) | Liquid detergent composition for vegetables and fruits | |
| KR102095348B1 (en) | Detergent composition comprising Katsura tree bark extract or Artemisia Capillaris extract |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20111227 Year of fee payment: 9 |
|
| FPAY | Annual fee payment |
Payment date: 20121217 Year of fee payment: 10 |
|
| LAPS | Lapse due to unpaid annual fee |