KR0163503B1 - Composition for cleaning fruits and vegetable - Google Patents
Composition for cleaning fruits and vegetableInfo
- Publication number
- KR0163503B1 KR0163503B1 KR1019950046041A KR19950046041A KR0163503B1 KR 0163503 B1 KR0163503 B1 KR 0163503B1 KR 1019950046041 A KR1019950046041 A KR 1019950046041A KR 19950046041 A KR19950046041 A KR 19950046041A KR 0163503 B1 KR0163503 B1 KR 0163503B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- fatty acid
- glycerin
- acid esters
- vegetable
- Prior art date
Links
- 235000012055 fruits and vegetables Nutrition 0.000 title claims abstract description 21
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 238000004140 cleaning Methods 0.000 title description 2
- 239000003599 detergent Substances 0.000 claims abstract description 29
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 23
- -1 sucrose fatty acid esters Chemical class 0.000 claims abstract description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 18
- 239000000194 fatty acid Substances 0.000 claims abstract description 18
- 229930195729 fatty acid Natural products 0.000 claims abstract description 18
- 239000000419 plant extract Substances 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 229930006000 Sucrose Natural products 0.000 claims abstract description 5
- 239000005720 sucrose Substances 0.000 claims abstract description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 235000011187 glycerol Nutrition 0.000 claims description 14
- 244000305267 Quercus macrolepis Species 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 235000009051 Ambrosia paniculata var. peruviana Nutrition 0.000 claims description 5
- 235000003097 Artemisia absinthium Nutrition 0.000 claims description 5
- 240000001851 Artemisia dracunculus Species 0.000 claims description 5
- 235000017731 Artemisia dracunculus ssp. dracunculus Nutrition 0.000 claims description 5
- 235000003261 Artemisia vulgaris Nutrition 0.000 claims description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 5
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 claims description 5
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 claims description 5
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 claims description 5
- 244000241838 Lycium barbarum Species 0.000 claims description 5
- 235000015459 Lycium barbarum Nutrition 0.000 claims description 5
- 235000015468 Lycium chinense Nutrition 0.000 claims description 5
- 239000001138 artemisia absinthium Substances 0.000 claims description 5
- 210000004207 dermis Anatomy 0.000 claims description 5
- 229940010454 licorice Drugs 0.000 claims description 5
- 229940087305 limonene Drugs 0.000 claims description 5
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 5
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 4
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 4
- 244000088415 Raphanus sativus Species 0.000 claims description 4
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 claims description 4
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 4
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 4
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 claims description 3
- 240000003259 Brassica oleracea var. botrytis Species 0.000 claims description 3
- 229940068977 polysorbate 20 Drugs 0.000 claims description 3
- 239000008347 soybean phospholipid Substances 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 244000303040 Glycyrrhiza glabra Species 0.000 claims 1
- 240000005979 Hordeum vulgare Species 0.000 claims 1
- 235000007340 Hordeum vulgare Nutrition 0.000 claims 1
- 235000004431 Linum usitatissimum Nutrition 0.000 claims 1
- 240000006240 Linum usitatissimum Species 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 239000000284 extract Substances 0.000 claims 1
- 239000000575 pesticide Substances 0.000 abstract description 27
- 239000007788 liquid Substances 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 14
- 150000004665 fatty acids Chemical class 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- 241000202807 Glycyrrhiza Species 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 231100000263 cytotoxicity test Toxicity 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 240000002045 Guettarda speciosa Species 0.000 description 3
- 235000001287 Guettarda speciosa Nutrition 0.000 description 3
- 229920001214 Polysorbate 60 Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 231100000135 cytotoxicity Toxicity 0.000 description 3
- 230000003013 cytotoxicity Effects 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 3
- 210000003491 skin Anatomy 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 240000008067 Cucumis sativus Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 244000070406 Malus silvestris Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000010533 azeotropic distillation Methods 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 210000002950 fibroblast Anatomy 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 241000411851 herbal medicine Species 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000447 pesticide residue Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 235000009849 Cucumis sativus Nutrition 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 235000008498 Drimys winteri Nutrition 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 241001311547 Patina Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000012773 agricultural material Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 210000004102 animal cell Anatomy 0.000 description 1
- 235000021016 apples Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004113 cell culture Methods 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001284 gas chromatography-nitrogen--phosphorus detection Methods 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 239000003987 organophosphate pesticide Substances 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229940068965 polysorbates Drugs 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
본 발명은 수종의 식물 추출물과 자당 지방산 에스테르 등의 계면활성제, 유기 또는 무기 빌더, 프로필렌 글리콜 등의 용매를 함유하는 액체 세제 및 스프레이식 과일·야채 세정제 조성물에 관한 것이고, 이는 독성이 없어 과일·야채를 안심하고 세정할 수 있으며 잔류농약을 효과적으로 제거시켜 주는 것을 특징으로 한다.The present invention relates to liquid detergents and spray-type fruit and vegetable detergent compositions containing several plant extracts and surfactants such as sucrose fatty acid esters, organic or inorganic builders, and solvents such as propylene glycol. It can be washed with confidence and is characterized in that it effectively removes residual pesticides.
Description
본 발명은 과일·야채에 잔류하는 농약 제거효과가 우수한 세정제 조성물에 관한 것이다. 더욱 상세하게, 본 발명은 공비증류한 식물 추출물과 계면활성제에 유기염과 무기염의 빌더를 혼합시키거나 디-리모넨을 혼합시켜 과일·야채 표면에 잔류하는 농약을 효과적으로 제거시키는 과일·야채 전용 세정제에 관한 것이다.The present invention relates to a cleaning composition excellent in the effect of removing pesticides remaining in fruits and vegetables. More specifically, the present invention is a fruit and vegetable cleaning agent that effectively removes pesticides remaining on the surface of fruits and vegetables by mixing organic and inorganic salt builders with azeotropically distilled plant extracts and surfactants or by mixing di-limonene. It is about.
농약은 병충해 및 잡초로부터 농작물을 보호하며, 농업 생산물의 양적 증대와 함께 품질을 향상시키기 위한 농업 자재로서 현대 농업에 있어서 없어서는 안될 수단으로 농약없이는 농업 경영이 불가능한 실정이다. 통계에 의하면 농약을 사용하지 않을 경우 20％이상의 수확량이 감소되고 해마다 수확량이 감소율이 증가된다고 한다. 그래서 과일·야채에는 농약이 잔류되어 있는데 우리나라에서도 1988년 28 종의 농산물에 대한 17가지 농약의 잔류 허용기준이 제정된 바 있다.Pesticides are agricultural materials to protect crops from pests and weeds, and to improve the quality of agricultural products and to improve their quality, which is an indispensable means in modern agriculture. Statistics show that without pesticides, yields are reduced by more than 20% and yields increase annually. Therefore, pesticide residues remain in fruits and vegetables. In 1988, 17 pesticide residue limits for 28 agricultural products were established in Korea.
과일·야채 표면에 잔류하는 농약은 세제에 의해 세정될 수 있는데, 기존의 주방용 세제를 사용하면 과일·야채 표면의 잔류농약에 계면활성제 성분이 흡착하며 물 속으로 유화·분산시키는 롤링업 작용으로 어느 정도 제거가 될 수 있으며, 일본 후생성에서 발간한 세제의 독성과 그 평가라는 보고 책자에도 세제의 잔류농약 제거를 설명하고 있다. 그러나, 주방세제의 계면활성제가 과일·야채 내부에 침투되어 세정후 과일·야채 섭취시 주방세제를 먹게 될 수 있다는 우려 때문에 주방세제 사용방법에 의한 과일·야채 세정법은 그다지 보편적으로 사용되고 있지 못한 실정이다. 또한 농가에서 농약에 중독되면 예로부터 농약 해독제 한약을 복용하는 경우가 있는데, 국내 특허출원 제2465호(1980년)에 명시된 것처럼 여러 가지 한약제를 증류한 제재가 약물 해독제로 소개되어 있다. 그러나 이런 전통 한방제재도 실제 과일·야채 표면으로부터 농약을 제거시키는 현상은 미약하여 세정제로서의 상품성은 떨어진다고 판단된다.Pesticides remaining on the surface of fruits and vegetables can be cleaned by detergents. Using conventional kitchen detergents, surfactants are adsorbed on residual pesticides on the surface of fruits and vegetables. The elimination of residual pesticides is also described in the report book on the toxicity and evaluation of detergents published by the Ministry of Health, Labor and Welfare. However, due to the concern that the detergent of the dish detergent may penetrate inside the fruit and vegetables, and the kitchen detergent may be eaten when the fruit and vegetables are ingested after washing, the fruit and vegetable washing method using the dish detergent is not widely used. . In addition, if a farmer is addicted to pesticides, he or she may take a traditional pesticide detoxifier. As described in Korean Patent Application No. 2465 (1980), a distillate of various herbal medicines is introduced as a drug detoxifier. However, these traditional herbal medicines are also less effective in removing pesticides from the surface of fruits and vegetables.
이에 본 발명자들은 전통적인 한방요법과 계면활성제 사용에 의한 계면공학을 이용하여 과일·야채 표면의 잔류농약 제거효과도 우수하고 과일·야채 표면에 세정제가 침투되더라도 제정제의 독성이 없이 안심하고 먹을 수 있는 세정제를 개발하기에 이르렀다.Therefore, the present inventors have excellent effect of removing residual pesticides on the surface of fruits and vegetables by using conventional herbal remedies and interfacial engineering using surfactants, and can be eaten safely without the toxicity of the detergent even if the cleaning agent penetrates the fruits and vegetables. The cleaner has been developed.
본 발명은 당귀, 진피, 애옆, 율무, 도인, 갈근, 동피, 무송잎, 상수리나무잎, 참나무 껍질, 약쑥, 구기자, 감초, 이들의 혼합물을 물과 글리세린을 사용하여 공비증류한 식물추출물 0.1 내지 80 중량％; 자당 지방산에스테르, 글리세린 지방산에스테르, 프로필렌글리콜 지방산에스테르, 대두인지질 및 폴리옥시에틸렌 솔비탄 모노라우릴레이트(폴리소르베이트20)중에서 선택된 1종 이상의 계면활성제 0.1 내지 20중량％; 구연산, 구연산염, 인산칼륨염 또는 이들의 혼합물 0.5 내지 10 중량％; 및 글리세린, 디-리모넨, 프로필렌글리콜, 부틸렌글리콜, 에탄올 또는 이들의 혼합물 0.1 내지 10중량％ 함유함을 특징으로 하는 과일·야채 세정제 조성물에 관한 것이다.The present invention is a plant extract 0.1 to azeotropically, dermis, lateral side, yulmu, cauliflower, roots, winter skin, radish leaves, oak leaves, oak bark, wormwood, wolfberry, licorice, a mixture of these using a water and glycerin 80 wt%; 0.1 to 20% by weight of one or more surfactants selected from sucrose fatty acid esters, glycerin fatty acid esters, propylene glycol fatty acid esters, soy phospholipids and polyoxyethylene sorbitan monolaurylates (polysorbates 20); 0.5 to 10% by weight citric acid, citrate, potassium phosphate salt or mixtures thereof; And 0.1 to 10% by weight of glycerin, di-limonene, propylene glycol, butylene glycol, ethanol or a mixture thereof.
본 발명에 따른 과일·야채 세정제 조성물 중에 사용되는 식물 추출물로는 당귀, 진피, 애옆. 율무, 도인, 갈근, 동피, 무송잎, 상수리나무 잎, 참나무 껍질, 약쑥, 구기자, 감초, 이들의 혼합물을 물과 글리세린을 사용하여 공비증류한 것이 좋다. 공비증류한 식물 추출물은 0.1 내지 80 중량％, 바람직하게는 20 내지 70중량％ 사용한다.Plant extracts used in the fruit and vegetable detergent composition according to the present invention as Angelica, dermis, patina. Yulmu, cabbage, brown root, winter bark, radish leaves, oak leaves, oak bark, wormwood, wolfberry, licorice, and mixtures thereof are preferably azeotropically distilled with water and glycerin. The azeotropic plant extract is used in an amount of 0.1 to 80% by weight, preferably 20 to 70% by weight.
본 발명에서 사용되는 계면활성제로는 자당 지방산 에스테르, 글리세린 지방산 에스테르, 프로필렌 글리콜 지방산 에스테르, 대두 인지질 및 폴리옥시에틸렌 솔비탄 모노라우릴레이트(폴리 소르베이트 20) 중에서 선택된 1종 이상의 성분을 사용하며, 그의 사용량은 0.1 내지 20중량％가 바람직하다.As the surfactant used in the present invention, at least one component selected from sucrose fatty acid ester, glycerin fatty acid ester, propylene glycol fatty acid ester, soybean phospholipid and polyoxyethylene sorbitan monolaurylate (poly sorbate 20) is used. The amount of use thereof is preferably 0.1 to 20% by weight.
본 발명에 따른 과일·야채 세정제 조성물은 구연산, 구연산염 및 인산칼륨염 중에서 선택된 1종 이상의 성분을 함유하며, 그의 사용량은 0.5 내지 10 중량％가 바람직하다.The fruit and vegetable detergent composition according to the present invention contains at least one component selected from citric acid, citrate and potassium phosphate salt, the amount of which is preferably 0.5 to 10% by weight.
본 발명에 따른 과일·야채 세정제 조성물은 또한 글리세린, 디-리모넨, 프로필렌 글리콜, 부틸렌 글리콜 및 에탄올 중에서 선택된 1종 이상의 성분을 하며, 그의 사용량은 0.1 내지 10중량％가 바람직하다.The fruit and vegetable detergent composition according to the present invention also contains at least one component selected from glycerin, di-limonene, propylene glycol, butylene glycol, and ethanol, and its amount is preferably 0.1 to 10% by weight.
본 발명에서 사용한 잔류농약 제거효과에 대한 분석법은 다음의 순서에 따라 가스 크로마토그래피(GC)로 실시하였다. 실험에 사용한 농작물은 오이, 포도, 사과를 사용하였으며 분석을 실시한 농약은 유기인계 농약으로 널리 사용되고 있는 다이아지논을 사용했다. 먼저 농작물을 깨끗이 세척한 후 자연건조시킨 후 농약 사용의 희석배율에 맞추어 30초 동안 침적시킨 다음 하루밤 지연건조시켜 동일량의 농약을 농작물에 부착시킨 다음 본 발명의 과일·야채 세정제를 분무시킨후 흐르는 물로 5초 동안 헹구고 시판중인 주방세제는 표준사용 농도의 수용액을 사용하여 10분간 진탕하여 세정하고 역시 5초 동안 흐르는 물로 헹구는 방법을 사용하였다. 헹굼이 끝난 과일·야채는 150g 씩 분취하여 쥬스기로 갈은 후 클로포름과 노르말 헥산으로 농약을 추출해 냈다. GC/NPD 검출기를 사용하여 분석을 실시하였다.Analysis of the residual pesticide removal effect used in the present invention was carried out by gas chromatography (GC) in the following order. The crops used for the experiment were cucumber, grape, and apple, and the analyzed pesticides were diazinon, which is widely used as organophosphorus pesticide. First, the crops are washed thoroughly, then dried naturally, and then immersed for 30 seconds in accordance with the dilution ratio of the pesticide use, and then dried overnight to attach the same amount of pesticide to the crops, followed by spraying the fruit and vegetable detergent of the present invention. Rinsing with water for 5 seconds and commercially available dishwashers were washed by shaking for 10 minutes using an aqueous solution of a standard use concentration and rinsing with running water for 5 seconds. After rinsing, fruits and vegetables were collected in 150g each, ground in juicer, and then extracted with pesticide with chloroform and normal hexane. Analysis was performed using a GC / NPD detector.
본 발명에서 실시한 세포독성 시험은 물질 및 제품의 동물세포에 대한 독성을 평가하는 동물시험 대체시험법으로 이미 FDA, CTFA, SDA 등에서 적극적으로 활용되고 있는 실정이다. 본 실험에서 사용한 세포독성 시험은 마우스 섬유아세포를 사용했다. 96웰 플레이트에 일정 농도의 마우스 섬유아세포를 배양한 후 세정제로 처리하면 시험물질의 독성에 의해 세포가 성장을 하지 못하거나 죽게되어 플레이트 바닥으로부터 떨어져 나가게 된다. 일정시간 경과후 배지를 제거하면 각 웰에는 생존한 세포들만이 웰 플레이트 바닥에 남게 되는데, 이 세포들을 NaOH로 용해시켜 단백질을 방출시키고 그 양을 흡광도에 의해 측정함으로써 세정제의 독성을 평가했다. 세포 독성의 평가는 반수 치사농도(H50)로 실시하였으며 세정 조제 10％용액을 배지로 희석한 후 세포 배양시켰다.Cytotoxicity test carried out in the present invention is an alternative to the animal test for assessing the toxicity of the material and the animal cells to the animal, the situation is actively used in FDA, CTFA, SDA and the like. The cytotoxicity test used in this experiment used mouse fibroblasts. After culturing a certain concentration of mouse fibroblasts in a 96-well plate and treating with a detergent, the cells may not grow or die due to the toxicity of the test material, which causes them to fall off the bottom of the plate. After a certain period of time, the medium was removed, leaving only the viable cells in each well at the bottom of the well plate. The cells were lysed with NaOH to release proteins and the amount was measured by absorbance to assess the toxicity of the detergent. Evaluation of cytotoxicity was carried out at half lethal concentration (H 50 ) and the cell culture after diluting the washing aid 10% solution to the medium.
본 발명에서는 첫째, 식물 추출물의 농약 분해 효과를 측정한 결과 당귀, 진피, 애옆, 율무, 도인, 갈근, 동피, 무송잎, 상수리나무 잎, 참나무 껍질, 약쑥, 구기자, 감초, 이들의 혼합물(1kg)을 물(1kg)과 글리세린(1kg)을 사용하여 공비증류한 것이 미약하지만 30％정도의 잔류 농약의 제거효과가 있음을 확인할 수 있었다. 본 발명에서 사용한 공비증류는 식물 1kg을 사용하여 물과 글리세린 1kg을 혼합한 액으로 속실릿 장치를 통해 식물을 추출하는 것을 말한다.In the present invention, first, as a result of measuring the pesticide decomposition effect of the plant extracts Angelica, dermis, flank, Yulmu, Doin, roots, winter skin, radish leaves, oak leaves, oak bark, wormwood, wolfberry, licorice, mixtures thereof (1kg ), But azeotropic distillation using water (1kg) and glycerin (1kg) was found to be effective in removing about 30% of residual pesticides. The azeotropic distillation used in the present invention refers to extracting a plant through a soxhlet apparatus using a mixture of 1 kg of water and 1 kg of glycerin.
둘째, 직쇄 알킬벤젠 술폰산염을 사용하는 시판 범용 주방세제와 알콜 에톡시 설페이트염을 사용하는 시판 마일드 주방세제의 잔류농약 제거효과는 약70％전후로 판정되었으며, 또 외국산 주방세제도 유사한 수준의 잔류농약 제거효과가 관찰되었다. 지방산 에톡실레이트와 구연산염으로 구성된 시판 야채·과일 전용세제의 경우 사과와 오이에서의 농약 제거효과는 70％정도의 잔류농약 제거효과로 다른 세제와 유사했지만 표도와 같이 세척이 힘든 과일의 잔류농약 제거효과는 다소 떨어지는 것으로 나타났다.Second, the removal effect of residual pesticides was about 70% between commercial general dish detergents using straight chain alkylbenzene sulfonates and mild mild dish detergents using alcohol ethoxy sulfate salts. Elimination effect was observed. In the case of commercial vegetable and fruit detergents consisting of fatty acid ethoxylates and citrates, the removal effect of pesticides from apples and cucumbers is 70% of residual pesticides, similar to other detergents. The effect appeared to be somewhat diminished.
셋째, 식물 추출물을 자당 지방산 에스테르, 글리세린 지방산 에스테르, 프로필렌 글리콜 지방산 에스테르, 대두 인지질, 폴리옥시에틸렌 솔비탄 모노라우릴레이트(폴리소르베이트 20)중의 어떤 계면활성제 성분과 혼합하더라도 단독 사용하는 것보다 잔류농약 제거효과는 일반세제에 비해 약 15％에서 30％정도 증가하는 것을 확인할 수 있었다.Third, any combination of plant extracts with sucrose fatty acid esters, glycerin fatty acid esters, propylene glycol fatty acid esters, soybean phospholipids, and any of the surfactant components in polyoxyethylene sorbitan monolaurylate (polysorbate 20) remains more than used alone. The pesticide removal effect was found to increase about 15% to 30% compared to general detergents.
넷째, 본 발명에 사용된 식물 추출물과 계면성제에 구연산과 구연산염, 인산칼륨염, 프로필렌 글리콜, 글리세린, 부틸렌 글리콜, 에탄올을 사용하면 그 효과가 더 증가함을 확인할 수 있었으며, 디-리모넨을 사용하는 경우에도 그 효과가 증가되어 95％이상으로 완벽하게 잔류농약이 제거되었다.Fourth, the use of citric acid and citrate, potassium phosphate, propylene glycol, glycerin, butylene glycol, ethanol in the plant extracts and surfactants used in the present invention was confirmed that the effect is further increased, using di-limonene The effect was also increased, and residual pesticides were completely removed (95% or more).
특히 실시예의 시료들은 비교예 시료에 비해 세포독성이 거의 없는 것으로 나타나 그 안전성이 입증되었다.In particular, the samples of the examples were shown to have little cytotoxicity compared to the comparative samples, and the safety thereof was proved.
이하 본 발명을 실시예에 의거하여 구체적으로 설명한다.Hereinafter, the present invention will be described in detail with reference to Examples.
[실시예]EXAMPLE
하기 표에 나타낸 성분들의 조성비로 통상적인 세정제의 제조방법에 의거하여 과일·야채 세정제 조성물을 제조하였다. 실시예에서 공비증류한 식물 추출물은 당귀, 진피, 애옆, 도인, 갈근, 동피, 무송잎, 상수리나무 잎, 참나무 껍질, 약쑥, 구기자, 감초, 이들의 혼합물(1kg)을 물(1kg)과 글리세린(1kg)의 혼합액으로 속실릿장치를 통해 추출한 것을 말한다.A fruit and vegetable detergent composition was prepared according to a conventional method for preparing a detergent with the composition ratio of the components shown in the following table. Examples of azeotropic distilled plant extracts include Angelica, dermis, flanks, cauliflower, roots, winter skin, pine needles, oak leaves, oak bark, wormwood, wolfberry, licorice, a mixture thereof (1 kg) of water (1 kg) and glycerin (1kg) refers to the liquid extracted through the soxhlet apparatus.
[비교예][Comparative Example]
시료sample
A : 직쇄 알킬벤젠 술폰산염/알콜 에톡시 설페이트염/지방산 알카놀아미드로 구성되어 있는 시판 주방세제A: Commercial dishwashing agent consisting of straight chain alkylbenzene sulfonate / alcohol ethoxy sulfate salt / fatty acid alkanolamide
B : 알콜 애톡시 설페이트염/지방산 알카놀 아미드/아민옥시드로 구성되어 있는 시판 주방세제B: Commercial dishwashing agent consisting of alcohol ethoxy sulfate salt / fatty acid alkanol amide / amine oxide
C : 지방산 에톡실레이트/구연산염으로 구성되어 있는 시판 야채·과일 전용세제C: Commercial detergent for vegetables and fruits composed of fatty acid ethoxylate / citrate
D : 직쇄 알킬벤젠 술폰산염/알콜 애톡시 설페이트염/지방산 알카놀 아미드/알콜 에톡실레이트/구연산/에탄올로 구성되어 있는 외국산 시판 주방세제D: Commercially available dishwashing agent composed of straight chain alkylbenzene sulfonate / alcohol ethoxy sulfate salt / fatty acid alkanol amide / alcohol ethoxylate / citric acid / ethanol
E : 각종 공비증류한 식물 추출물(실시예에서 사용한 원료)100％ 상술한 여러 가지 세정제 조성물의 잔류농약 제거효과 시험과 세포독성시험을 시판 주방세제와 비교하여 실시하여 보았다.E: Various azeotropically distilled plant extracts (raw materials used in Examples) 100% The pesticide removal effect test and cytotoxicity test of the various detergent compositions described above were carried out in comparison with a commercial dish detergent.
시험결과 모든 실시예 세정제는 시판 주방세제에 비해 15 내지 30％의 잔류농약 제거효과가 상승함을 확인할 수 있었다. 특히 비교예 시료 E의 경우 계면활성제를 사용하지 않은 순수한 식물 추출물만을 사용했을 때도 30％정도의 잔류농약 분해효과가 있는 것이 확인되었다. 또 세포독성을 시험한 결과 실시예의 조성물은 비교예 시료에 비해 세포독성이 거의 없는 것으로 나타나 그 안전성이 입증되었다.As a result of the test, it was confirmed that all the example detergents had a residual pesticide removal effect of 15 to 30% compared to commercial dish detergents. In particular, in the case of Comparative Example Sample E, only 30% of the residual pesticide decomposition effect was confirmed even when using pure plant extract without a surfactant. As a result of the cytotoxicity test, the composition of the example was shown to have little cytotoxicity compared to the comparative sample, and its safety was proved.
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| KR1019950046041A KR0163503B1 (en) | 1995-12-01 | 1995-12-01 | Composition for cleaning fruits and vegetable |
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| KR1019950046041A KR0163503B1 (en) | 1995-12-01 | 1995-12-01 | Composition for cleaning fruits and vegetable |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19990055305A (en) * | 1997-12-27 | 1999-07-15 | 성재갑 | Liquid detergent composition for vegetables and fruits |
| KR20030012315A (en) * | 2001-07-31 | 2003-02-12 | 보령메디앙스 주식회사 | The detergent composition for baby goods including baby bottles |
| CN104232363A (en) * | 2014-09-29 | 2014-12-24 | 镇江华域环保设备制造有限公司 | Special fruit and vegetable detergent |
| KR20150015822A (en) * | 2013-08-01 | 2015-02-11 | 애경산업(주) | Antibacterial detergent composition |
| WO2018143639A1 (en) * | 2017-02-01 | 2018-08-09 | 주식회사 아모레퍼시픽 | Method for removing pesticide residues from natural plant extract |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030010259A (en) * | 2001-07-26 | 2003-02-05 | 남정춘 | Antidotes of crude drugs and fabrication method thereof |
| KR101006067B1 (en) * | 2009-02-18 | 2011-01-06 | 김동엽 | Moisturizing Detergent Composition For Industrial labor |
-
1995
- 1995-12-01 KR KR1019950046041A patent/KR0163503B1/en not_active IP Right Cessation
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19990055305A (en) * | 1997-12-27 | 1999-07-15 | 성재갑 | Liquid detergent composition for vegetables and fruits |
| KR20030012315A (en) * | 2001-07-31 | 2003-02-12 | 보령메디앙스 주식회사 | The detergent composition for baby goods including baby bottles |
| KR20150015822A (en) * | 2013-08-01 | 2015-02-11 | 애경산업(주) | Antibacterial detergent composition |
| CN104232363A (en) * | 2014-09-29 | 2014-12-24 | 镇江华域环保设备制造有限公司 | Special fruit and vegetable detergent |
| WO2018143639A1 (en) * | 2017-02-01 | 2018-08-09 | 주식회사 아모레퍼시픽 | Method for removing pesticide residues from natural plant extract |
Also Published As
| Publication number | Publication date |
|---|---|
| KR970042987A (en) | 1997-07-26 |
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