CN107603787B - Tableware detergent composition and preparation method thereof - Google Patents
Tableware detergent composition and preparation method thereof Download PDFInfo
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- CN107603787B CN107603787B CN201710858533.7A CN201710858533A CN107603787B CN 107603787 B CN107603787 B CN 107603787B CN 201710858533 A CN201710858533 A CN 201710858533A CN 107603787 B CN107603787 B CN 107603787B
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Abstract
The invention provides a tableware detergent composition, which is prepared from the following components in parts by weight: 0.1-0.2 part of argy wormwood leaf essential oil, 0.2-0.4 part of citronella essential oil, 0.1-0.4 part of preservative, 55-65 parts of water, 6-9 parts of nonionic surfactant, 0.2-0.3 part of pH value regulator, 0.1-0.2 part of chelating agent, 12-15 parts of anionic surfactant, 0.1-0.2 part of sodium caseinate and 1 part of tween-800.5, wherein the weight ratio of the argy wormwood leaf essential oil to the citronella essential oil is 1: 2. The invention also provides a preparation method of the tableware detergent composition. The tableware detergent composition provided by the invention has strong decontamination performance, degerming and mildew removing performance and thermal stability.
Description
Technical Field
The invention relates to a tableware detergent composition and a preparation method thereof.
Background
Detergents are products formulated to enhance detergency performance. There are various kinds of detergents, and one kind of detergent used for tableware is detergent. The tableware detergent belongs to a preparation type product, is developed very rapidly in China in recent years, and is full of precious in appearance, super-strong in detergency, super-concentrated and the like. The dish washing detergent generally takes out food residue, grease on the dishes by chemical action such as penetration, saponification, emulsification or suspension thereof, and generally consists of a main component, surfactant and various auxiliaries.
Chinese patent application CN201611030447.9 discloses a dish washing detergent, which comprises the following components in percentage by mass: 1-2 parts of pigment, 1-2 parts of spice, 6-8 parts of banana stalk, 5-7 parts of linear alkyl benzene sulfonic acid, 4-5 parts of sodium cumene sulfonate, 1-3 parts of alkyl polyglycoside, 7-8 parts of tetracycline, 10-12 parts of coconut oil fatty acid monoethanolamide and 80-120 parts of water.
Disclosure of Invention
The invention aims to provide a tableware detergent composition which has strong decontamination performance, degerming and mildew removing performance and thermal stability.
In order to solve the technical problems, the technical scheme of the invention is as follows:
a tableware detergent composition is prepared from the following components in parts by weight: 0.1-0.2 part of argy wormwood leaf essential oil, 0.2-0.4 part of citronella essential oil, 0.1-0.4 part of preservative, 55-65 parts of water, 6-9 parts of nonionic surfactant, 0.2-0.3 part of pH value regulator, 0.1-0.2 part of chelating agent, 12-15 parts of anionic surfactant, 0.1-0.2 part of sodium caseinate and 1 part of tween-800.5, wherein the weight ratio of the argy wormwood leaf essential oil to the citronella essential oil is 1: 2.
Further, the preparation steps of the argy wormwood leaf essential oil are as follows:
drying folium artemisiae argyi in the shade, crushing, sieving with a 60-mesh sieve to obtain folium artemisiae argyi powder, adding the folium artemisiae argyi powder into a distillation flask, then adding distilled water and sodium chloride, uniformly oscillating, soaking for 10 hours, transferring to a distillation device, and then carrying out steam distillation extraction for 4 hours to obtain folium artemisiae argyi essential oil, wherein the weight ratio of the folium artemisiae argyi powder to the distilled water to the sodium chloride is 6:100: 1.
Further, the preparation steps of the citronella essential oil are as follows:
cutting the lemongrass with the growth height of 90cm to obtain 50 cm-long lemongrass strips, drying in the shade, grinding to obtain lemongrass powder, adding the lemongrass powder into n-hexane according to the solid-to-liquid ratio of 1:8g/mL, uniformly oscillating, soaking for 1 hour, heating to 50 ℃, extracting for 5 hours in a water bath, filtering out an extracting solution, and recovering the n-hexane to obtain the lemongrass essential oil.
Further, the preservative is ethylparaben.
Further, the water is deionized water.
Further, the nonionic surfactant is a mixture of alkyl glucoside and AEO-9.
Further, the pH value regulator is citric acid.
Further, the chelating agent is EDTA-4 Na.
Further, the anionic surfactant is α -sodium alkenyl sulfonate.
Another technical problem to be solved by the present invention is to provide a process for preparing the above dishwashing detergent composition.
In order to solve the technical problems, the technical scheme is as follows:
a process for preparing a dishwashing detergent composition comprising the steps of:
(1) weighing the components in parts by weight, adding folium artemisiae argyi essential oil and citronella essential oil into tween-80, and uniformly stirring to obtain a mixed solution A;
(2) adding a nonionic surfactant and an anionic surfactant into water, and uniformly stirring at 70-80 ℃ to obtain a mixed solution B;
(3) after the mixed solution B is cooled to 38 ℃, adding a pH value regulator into the mixed solution B, and regulating the pH value to 7.7-7.9 to obtain a mixed solution C;
(4) and adding the mixed solution A and other components into the mixed solution B, stirring uniformly, transferring into a storage tank, and aging for 11 hours to obtain the tableware detergent composition.
Compared with the prior art, the invention has the following beneficial effects:
1) the mugwort is artemisia of Compositae, namely mugwort, wormwood and the like, and the leaf part of the mugwort, namely the mugwort, contains various active ingredients; in addition, the argy wormwood leaf essential oil also has very strong antibacterial and mildew-removing activity, so that the degerming and mildew-removing performance of the tableware detergent composition can be improved.
2) The lemongrass is called lemon grass and is a perennial herb of citronella, the lemongrass is mown when the growth height reaches 90cm, and is dried in the shade, and then n-hexane is used as an extraction solvent to extract citronella essential oil, the citronella essential oil also has good antibacterial and mildew-removing activities, and the citronella essential oil can reach the strongest effect when being mixed with the argy wormwood leaf essential oil in a weight ratio of 1:2, so that the degerming and mildew-removing performance of the tableware detergent composition is further improved; in addition, the extraction rate of the citronella essential oil extracted when the citronella grass is mown at the growth height of 90cm is higher than that of other growth heights.
3) The sodium caseinate and the tween-80 can effectively improve the solubility of the argy wormwood leaf essential oil and the citronella essential oil, thereby further improving the decontamination performance and the degerming and mildew-removing performance of the tableware detergent composition; in addition, sodium caseinate and tween-80 have strong thermal stability, so that the thermal stability of the tableware detergent composition can be effectively improved.
Detailed Description
The present invention will be described in detail with reference to specific embodiments, and the exemplary embodiments and descriptions thereof herein are provided to explain the present invention but not to limit the present invention.
Examples 1 to 4
Dishwashing detergent compositions were prepared according to the proportions (in parts by weight) of table 1:
TABLE 1
The preparation process of examples 1-4 comprises the following steps:
(1) drying folium artemisiae argyi in the shade, crushing, sieving with a 60-mesh sieve to obtain folium artemisiae argyi powder, adding the folium artemisiae argyi powder into a distillation flask, then adding distilled water and sodium chloride, uniformly oscillating, soaking for 10 hours, transferring to a distillation device, and then carrying out steam distillation extraction for 4 hours to obtain folium artemisiae argyi essential oil, wherein the weight ratio of the folium artemisiae argyi powder to the distilled water to the sodium chloride is 6:100: 1;
(2) cutting the lemongrass with the growth height of 90cm to obtain 50 cm-long lemongrass strips, drying in the shade, grinding to obtain lemongrass powder, adding the lemongrass powder into n-hexane according to the solid-to-liquid ratio of 1:8g/mL, uniformly oscillating, soaking for 1 hour, heating to 50 ℃, extracting for 5 hours in a water bath, filtering out an extracting solution, and recovering the n-hexane to obtain the lemongrass essential oil;
(3) weighing the components in parts by weight, adding folium artemisiae argyi essential oil and citronella essential oil into tween-80, and uniformly stirring to obtain a mixed solution A;
(4) adding a mixture of alkyl glucoside and AEO-9 and α -sodium alkenyl sulfonate into water, and uniformly stirring at 70-80 ℃ to obtain a mixed solution B;
(5) after the mixed solution B is cooled to 38 ℃, adding citric acid into the mixed solution B, and adjusting the pH value to 7.7-7.9 to obtain a mixed solution C;
(6) and adding the mixed solution A and other components into the mixed solution B, stirring uniformly, transferring into a storage tank, and aging for 11 hours to obtain the tableware detergent composition.
Reference example 1
The components do not contain argy wormwood leaf essential oil, and other components and preparation methods are the same as those in example 4.
Reference example 2
The ingredients do not include citronella essential oil, and other ingredients and preparation methods are the same as example 4.
Reference example 3
The weight ratio of the argy wormwood leaf essential oil to the citronella essential oil in the components is 3:2, wherein the weight part of the argy wormwood leaf essential oil is 15, the weight part of the citronella essential oil is 10, and other components and preparation methods are the same as those in example 4.
Reference example 4
Sodium caseinate and tween-80 were not included in the components, and the other components and preparation methods were the same as in example 4.
Comparative example
The comparative example is example 1 of chinese patent application No. CN 201611030447.9.
The first experimental example: stain removal Performance test
The test method comprises the following steps: cleaning the oil-soaked white cloth by using various detergents, and then detecting the color of the white cloth by using a precise color difference meter to obtain a measured value, wherein the larger the measured value is, the stronger the decontamination performance is, and the test result is shown in table 2:
TABLE 2
As can be seen from Table 2, the measured values for inventive examples 1-4 are all greater than the comparative examples, indicating that the invention has greater stain removal performance, with example 4 having the strongest stain removal performance. The compositions of reference examples 1-4 are different from example 4, in which the measured values of reference examples 1 and 4 are slightly reduced, which shows that the essential oil of argy wormwood leaf, sodium caseinate and tween-80 are effective in improving the decontamination performance; the measured values of reference examples 2 and 3 are equivalent to those of examples 1 to 4, and show that the weight ratio of the citronella essential oil and the argy wormwood leaf essential oil to the citronella essential oil has no substantial influence on the stain removal performance.
Experiment example two: degerming and mildew removal performance test
The respective detergent is tested to respectively inhibit the bacteria of common bacteria, namely escherichia coli, staphylococcus aureus, and common mould, namely rhizopus nigricans and mucor racemosus, the higher the inhibition rate is, the stronger the bacteria removal and mildew removal performance is, and the test results are shown in table 3:
TABLE 3
As can be seen from Table 3, the bacteria and mold inhibiting rates of the examples 1-4 of the present invention are much higher than those of the comparative examples, which shows that the present invention has strong bacteria and mold removing performance, wherein the bacteria and mold removing performance of the example 4 is the best. The components of reference examples 1-4 are different from those of example 4, wherein the bacteriostatic rates of reference examples 1 and 2 on bacteria and mould are both slightly reduced, which indicates that the argy wormwood leaf essential oil and citronella essential oil can effectively improve the degerming and mould-removing performance; the reference example 3 shows that the bacteriostasis rate of bacteria and mould is reduced to the greatest extent, and the sterilization and mould removal effects are best when the weight ratio of the argy wormwood leaf essential oil to the citronella essential oil is 1: 2; the reference example 4 shows that the degree of reduction of the bacteriostatic rate of bacteria and mold is moderate, and sodium caseinate and tween-80 can effectively improve the solubility of the essential oil of artemisia argyi and the essential oil of citronella.
Experiment example three: thermal stability test
Placing each detergent in an oven at 60 ℃ for standing for 12 hours, taking out, observing whether the detergent is layered or turbid, if the detergent is layered or turbid, indicating that the detergent is poor in thermal stability, and if the detergent is not layered or turbid, indicating that the detergent is strong in thermal stability, wherein the test results are shown in table 4:
| example 1 | No delamination and turbidity |
| Example 2 | No delamination and turbidity |
| Example 3 | No delamination and turbidity |
| Example 4 | No delamination and turbidity |
| Reference example 1 | No delamination and turbidity |
| Reference example 2 | No delamination and turbidity |
| Reference example 3 | No delamination and turbidity |
| Reference example 4 | The phenomenon of delamination and turbidity appears |
| Comparative example | The phenomenon of delamination and turbidity appears |
TABLE 4
As can be seen from Table 4, no delamination or turbidity occurred in any of examples 1 to 4 of the present invention, indicating that the present invention has a high thermal stability. The compositions of reference examples 1-4 are different from example 4, wherein reference examples 1-3 also have no delamination or turbidity, indicating that the argy wormwood leaf essential oil, citronella essential oil and their weight ratios have no influence on the thermal stability; the reference example 4 shows the phenomena of delamination and turbidity as the comparative example, which shows that sodium caseinate and Tween-80 are the key points for improving the thermal stability.
The foregoing embodiments are merely illustrative of the principles and utilities of the present invention and are not intended to limit the invention. Any person skilled in the art can modify or change the above-mentioned embodiments without departing from the spirit and scope of the present invention. Accordingly, it is intended that all equivalent modifications or changes which can be made by those skilled in the art without departing from the spirit and technical spirit of the present invention be covered by the claims of the present invention.
Claims (2)
1. A tableware detergent composition is characterized by being prepared from the following components, by weight, 0.1-0.2 part of folium artemisiae argyi essential oil, 0.2-0.4 part of citronella essential oil, 0.1-0.4 part of ethylparaben, 55-65 parts of deionized water, 6-9 parts of a mixture of alkyl glucoside and AEO-9, 0.2-0.3 part of citric acid, 0.1-0.2 part of EDTA-4Na, 12-15 parts of α -sodium alkenyl sulfonate, 0.1-0.2 part of sodium caseinate and 1-1 part of tween-800.5, wherein the weight ratio of the folium artemisiae argyi essential oil to the citronella essential oil is 1:2, and the citronella essential oil is prepared by the following steps:
cutting the lemongrass with the growth height of 90cm to obtain 50 cm-long lemongrass strips, drying in the shade, grinding to obtain lemongrass powder, adding the lemongrass powder into n-hexane according to the solid-to-liquid ratio of 1:8g/mL, uniformly oscillating, soaking for 1 hour, heating to 50 ℃, extracting for 5 hours in a water bath, filtering out an extracting solution, and recovering the n-hexane to obtain the lemongrass essential oil;
the preparation steps of the folium artemisiae argyi essential oil are as follows:
drying folium artemisiae argyi in the shade, crushing, sieving with a 60-mesh sieve to obtain folium artemisiae argyi powder, adding the folium artemisiae argyi powder into a distillation flask, then adding distilled water and sodium chloride, uniformly oscillating, soaking for 10 hours, transferring to a distillation device, and then carrying out steam distillation extraction for 4 hours to obtain folium artemisiae argyi essential oil, wherein the weight ratio of the folium artemisiae argyi powder to the distilled water to the sodium chloride is 6:100: 1.
2. A process for preparing a dishwashing detergent composition according to claim 1, wherein: the method comprises the following steps:
(1) weighing the components in parts by weight, adding folium artemisiae argyi essential oil and citronella essential oil into tween-80, and uniformly stirring to obtain a mixed solution A;
(2) adding a nonionic surfactant and an anionic surfactant into water, and uniformly stirring at 70-80 ℃ to obtain a mixed solution B;
(3) after the mixed solution B is cooled to 38 ℃, adding a pH value regulator into the mixed solution B, and regulating the pH value to 7.7-7.9 to obtain a mixed solution C;
(4) and adding the mixed solution A and other components into the mixed solution C, stirring uniformly, transferring into a storage tank, and aging for 11 hours to obtain the tableware detergent composition.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710858533.7A CN107603787B (en) | 2017-09-21 | 2017-09-21 | Tableware detergent composition and preparation method thereof |
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| CN201710858533.7A CN107603787B (en) | 2017-09-21 | 2017-09-21 | Tableware detergent composition and preparation method thereof |
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| CN107603787B true CN107603787B (en) | 2020-05-12 |
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| CN111187677B (en) * | 2020-01-10 | 2021-06-25 | 洛阳市怡佳净洗涤用品有限公司 | Wormwood sterilizing soap solution and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419966A (en) * | 2014-09-17 | 2016-03-23 | 范暄民 | Natural botanic antibacterial detergent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419966A (en) * | 2014-09-17 | 2016-03-23 | 范暄民 | Natural botanic antibacterial detergent |
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