KR102295942B1 - Method for manufacturing dishwashing detergent composition using soapberry extract - Google Patents

Abstract

The present invention relates to a method for manufacturing a dishwashing detergent composition, and specifically, to a method for manufacturing a dishwashing detergent composition using a fruit extract of Sapindus mukorossi which is environmentally friendly, has little skin irritation, has little toxicity to a human body even when it remains on dishes, and has excellent foaming amount, cleaning power and rinsing properties.

Description

Method for manufacturing dishwashing detergent composition using soapberry extract

The present invention relates to a method for preparing a dishwashing detergent composition, and more specifically, it is environmentally friendly, has almost no skin irritation, and has almost no toxicity to the human body even if it remains on dishes. It relates to a method for preparing a dishwashing detergent composition used.

Conventional dishwashing detergents are manufactured using anionic surfactants as main components, among which surfactants widely used are sodium linear alkylbenzene sulfonate (LAS), alpha olefin sulfonate (AOS), sodium lauryl sulfate (SLS), sodium lauryl ethoxylated sulfate (SLES), alkyl ether sulfate (AES), and the like. While they have excellent foaming and cleaning power, their rinse properties are quite weak, so there is a problem that the level remaining in the tableware is high, which may be harmful to the human body. In addition, these dishwashing detergents have a low degree of biodegradation in general water systems, adversely affecting the water quality environment, and have a problem of causing considerable irritation to the skin of the human body.

Accordingly, even if the detergent composition remains on the tableware, it is urgent to develop an eco-friendly dishwashing detergent with a fairly low oral toxicity, excellent cleaning power, foaming amount, and rinsing properties, while minimizing skin irritation and having little effect on the water system. .

Korean Patent Publication No. 2015-0018305

The present invention was devised in consideration of the above points, and it is environmentally friendly, has almost no skin irritation, and is almost nontoxic to the human body even if it remains on dishes. An object of the present invention is to provide a method for preparing a detergent composition.

Another object of the present invention is to provide a method for preparing a dishwashing detergent composition using a patient-free fruit extract that can achieve an excellent antiseptic effect even when used by minimizing preservatives that can irritate the skin.

Furthermore, another object of the present invention is to provide a method for preparing a dishwashing detergent composition using a patient-free tree fruit extract that minimizes the problem of shaking and re-mixing the detergent every time it is used because the phases are separated in the liquid state.

In order to solve the above problems, the present invention provides a composition comprising the steps of (1) mixing a surfactant containing a first nonionic surfactant derived from a natural substance and a functional ingredient containing an extract of a patient-free tree fruit with purified water, and (2) It provides a method for preparing a dishwashing detergent composition using a patient-free fruit extract comprising the step of adjusting the pH of the composition to neutral.

According to an embodiment of the present invention, the functional ingredient may further include honey extract and orange oil.

According to another embodiment of the present invention, 25 to 55% by weight of the surfactant and 5 to 10% by weight of the fruit extract of the patient-free tree may be contained based on the total weight of the composition.

According to another embodiment of the present invention, the first nonionic surfactant derived from the natural material may include cocoglucoside and decylglucoside.

According to another embodiment of the present invention, the first nonionic surfactant derived from a natural material is an alkyl polyglucoside including cocoglucoside and decylglucoside, and the surfactant is a hydrophilic-philic component as the second nonionic surfactant. It may further contain polysorbate having an oil-based ratio (HLB) of 16.0 to 17.0.

According to another embodiment of the present invention, the cocoglucoside and decyl glucoside may be contained in a weight ratio of 1: 2-3.

According to another embodiment of the present invention, the first nonionic surfactant component and the second nonionic surfactant component may be contained in a weight ratio of 3 to 5:1.

According to another embodiment of the present invention, the surfactant further contains cocoamidopropyl betaine as an amphoteric surfactant, and the cocoamidopropyl betaine and the second nonionic surfactant are 0.3 to 0.6: 1 by weight. may contain.

According to another embodiment of the present invention, the patient-free tree fruit extract may include a hot-water extract obtained by extracting the patient-free tree fruit or coarsely pulverized product of the patient-free tree fruit with hot water at a temperature of 80 to 100°C.

According to another embodiment of the present invention, the patient-free tree fruit extract further comprises an alcohol extract of a patient-free tree fruit or a crudely crushed fruit of a patient-free tree, and a hot water extract and an alcohol extract of a patient-free fruit or a crudely crushed fruit of a patient-free tree 1: It may be included in a weight ratio of 1-2.

According to another embodiment of the present invention, the alcohol extract comprises a first heat treatment step of heat-treating at 60 to 70° C. for the dried product of the fruit extraction residue remaining after hot water extraction of the fruit of the patient-free tree or the crude crushed product of the fruit of the patient-free tree; , may be an alcohol extract extracted with a lower alcohol having 1 to 4 carbon atoms after performing a second heat treatment process of heat treatment at least once at 90 to 110° C. by applying steam.

The dishwashing detergent composition prepared by the manufacturing method according to the present invention can prevent water pollution caused by the use of petrochemical surfactants by using surfactants derived from natural substances. In addition, it does not cause skin troubles, is excellent in moisturizing the skin, and has good rinsing properties, so it hardly remains on the tableware, and oral toxicity is minimized or prevented, so it is safe for the human body. Furthermore, as the fruit extract of the patient-free tree is mixed with a surfactant derived from a natural substance, it has excellent foaming and cleaning power, rinsing properties can be further improved, and the amount of washing water can be saved, which is more eco-friendly.

Hereinafter, embodiments of the present invention will be described in detail so that those of ordinary skill in the art to which the present invention pertains can easily implement them. The present invention may be embodied in many different forms and is not limited to the embodiments described herein.

A dishwashing detergent composition using the fruit extract of the patient-free tree according to an embodiment of the present invention is obtained by mixing (1) a surfactant containing a first non-ionic surfactant derived from a natural substance and a functional ingredient containing an extract of a patient-free tree fruit with purified water. to prepare a composition, and (2) may be prepared including the step of adjusting the pH of the composition to neutral.

First, as step (1) of the present invention, a surfactant containing a first nonionic surfactant derived from a natural substance and a functional ingredient containing an extract of a patient-free tree fruit are mixed with purified water to prepare a composition.

The surfactant is a component responsible for the cleaning function of removing contaminants, such as various foods, adhered to the tableware, and the present invention includes a first nonionic surfactant derived from a natural product as a main component of the surfactant. The first nonionic surfactant derived from a natural material may be used without limitation in the case of a surfactant derived from a known natural material, but may preferably include cocoglucoside and/or decylglucoside, and more preferably both It can contain both components, and through this, it has a synergistic effect with the non-patient tree fruit extract contained as a functional component, which will be described later, significantly improving cleaning power, rinsing properties and foaming even with little or no use of conventional petrochemical surfactants. can increase In addition, coco glucoside and decyl glucoside exhibit excellent effects in resolving the layer separation phenomenon that occurs when the extract of the fruit of the patient-free tree is contained in the composition. In this case, more preferably, the cocoglucoside and the decyl glucoside may be contained in a weight ratio of 1: 2 to 3, which has the advantage that the desired effect of the present invention can be more easily achieved.

According to an embodiment of the present invention, the surfactant further contains a second nonionic surfactant, which is a polysorbate having a hydrophilicity-lipophilic ratio (HLB) of 16.0 to 17.0, together with a first nonionic surfactant derived from a natural material. Through this, the layer separation problem of the cleaning composition, especially the layer separation problem at low temperature, is minimized, so storage stability is improved regardless of the storage temperature for a long period of time, and the concern that consumers may perceive the layer separation phenomenon as a quality decrease. There are advantages that can be In addition, there is an advantage that the rinsing property is further improved, and the amount of water required for rinsing can be saved. More preferably, the first nonionic surfactant component and the second nonionic surfactant component may be contained in a weight ratio of 3 to 5: 1, which is advantageous to achieve a more synergistic effect in the desired effect. .

On the other hand, in order to achieve more improved cleaning power, cocoamidopropyl betaine is further contained as an amphoteric surfactant, and the cocoamidopropyl betaine and the second non-ionic surfactant may be contained in a weight ratio of 0.3 to 0.6: 1. At this time, when cocoamidopropyl betaine is contained in an excess of 0.6 times compared to the second nonionic surfactant, there is a concern that storage stability at low temperature may be rather deteriorated.

Next, the functional ingredient includes an extract from the fruit of the patient-free tree. The fruit extract of the patient-free tree contains saponins, and various components including the saponin component included in the fruit extract of the patient-free tree are beneficial to the skin, and in addition, it can help improve cleaning power by generating abundant foam. That is, the first nonionic surfactant used as the main component of the surfactant of the present invention may be somewhat weak in cleaning power due to its natural origin. There is an advantage in that it can express the same or more cleaning power compared to the detergent in the case of the case. In this case, the fruit extract of the patient-free tree may be extracted using a known extraction solvent and extraction method. Preferably, the fruit extract of the patient-free tree may be a hot water extract, and more preferably, it may be a mixture of a hot water extract and an alcohol extract of the fruit of the patient-free tree. At this time, the nature of the fruit extract of the patient-free tree may be a liquid or a powder. The powder phase may be freeze-dried after concentration of the extract under reduced pressure after extraction.

Specifically, when explaining the fruit extract of the patient-free tree, after washing the obtained fruit of the patient-free tree, the fruit and the seeds of the patient-free fruit may be separated and extracted using the fruit part. In this case, the dried fruit portion may be used or a non-dried fruit portion may be used. In addition, the fruit part may be pulverized to a predetermined size in order to increase extraction efficiency, but is not limited thereto.

The prepared fruit of the patient-free tree or its coarsely pulverized product may then be subjected to an extraction process with hot water at a temperature of 80 to 100°C. In this case, the extraction time may be, for example, 5 to 15 hours, and through this, it may be advantageous to maximize the content of the active ingredient effective for cleaning. If the extraction temperature is less than 80 ℃, there is little extraction of effective ingredients for cleaning, and thus the cleaning effect may be insignificant. In addition, when the extraction temperature exceeds 100° C., it may be undesirable to use as a dishwashing agent as ingredients that may cause skin irritation are additionally extracted. In addition, if the extraction time is less than 5 hours, there may be little extraction of the effective ingredient for cleaning, and if the extraction temperature exceeds 15 hours, the increase in the extraction amount of the effective ingredient for cleaning is insignificant, and ingredients that may cause skin irritation is likely to increase the extraction of

After performing extraction for a predetermined time through hot water, a conventional filtration or separation process of separating the extraction residue and the extract may be performed.

On the other hand, the fruit extract of the patient-free tree may further include an alcohol extract together with the hot water extract described above. The alcohol extract has the advantage of a higher cleaning effect and foaming. At this time, the hot water extract and the alcohol extract may be included in a weight ratio of 1: 1 to 2, more preferably 1: 1.4 to 2.0 by weight. If the alcohol extract is included in an amount less than 1.4 times the weight of the hot water extract, the increased cleaning effect and the foaming effect may be insignificant. In addition, if the alcohol extract is contained in excess of 2.0 times the weight of the hot water extract, the amount of water required for rinsing may significantly increase due to excessive foaming. This may be insignificant or the cleaning effect may be lowered. In addition, there is a risk of layer separation or solid/liquid phase separation of the dishwashing detergent composition.

According to a preferred embodiment of the present invention, the alcohol extract of the patient-free tree fruit or the coarsely pulverized fruit of the patient-free tree is an alcohol extract of the patient-free fruit or the crudely crushed fruit of the patient-free tree, which is prepared before being extracted with hot water when the hot water extract is prepared. It may be extracted using . However, more preferably, the extraction target of the alcohol extract may be the extract from the fruit of the patient-free tree obtained when the hot water extract is prepared in order to have a higher cleaning effect, a foaming effect, and prevention of layer separation/phase separation, preferably dried It may be a dried product from which water, which is an extract liquid, has been removed through the process. In addition, the alcohol may be preferably a lower alcohol having 1 to 4 carbon atoms, more preferably ethanol. At this time, extraction using alcohol may be performed at room temperature, for example, 20 to 30° C. for 3 to 6 hours, and extraction by heating or extraction for a long period of time is undesirable because components that may cause skin irritation are excessively extracted.

On the other hand, in order to achieve a more synergistic effect with respect to the desired effect of the present invention, the dried product obtained by drying the extract of the fruit of the patient-free tree remaining after hot water extraction may be subjected to a pretreatment process before being extracted with alcohol. The pretreatment process may include a first heat treatment step of heat-treating the dried material at 60 to 70° C., and a second heat treatment step of heat-treating the dried material at least once at 90 to 110° C. by applying steam. There is an advantage that can significantly increase the content of active ingredients effective for cleaning the back. If the temperature conditions are not satisfied in the first heat treatment step or if the second heat treatment process in which steam is heat treated is performed without the first heat treatment step, the content of the active ingredient may not be significantly increased. In addition, in the second heat treatment process, there is a fear that the active ingredients necessary for washing may deteriorate during heat treatment under conditions exceeding 110° C., while there is a risk that the ingredients that irritate the skin may be excessively extracted through alcohol. In addition, when the second heat treatment is performed at a temperature of less than 90° C., the active ingredient required for cleaning to a desired level may not be extracted through alcohol.

In addition, the first heat treatment process may be performed for 30 minutes to 60 minutes, and the second heat treatment process may be performed for 2 hours to 4 hours during one heat treatment. If the duration of the first heat treatment process does not satisfy the above range, it may be difficult to achieve the desired effect even if the second heat treatment process is performed.

According to an embodiment of the present invention, the functional ingredient may further include honey extract and orange oil. The honey extract may be prepared by a known method, or may be commercially available, and may help moisturize the skin. The honey extract may be contained, for example, in an amount of 0.3 to 1% by weight based on the total weight of the detergent composition. The orange oil is an oil extracted from natural orange, and may be prepared by a known method or commercially available. The orange oil adds aroma to the dishwashing detergent composition, and through this, the user of the detergent composition can help relieve stress and change mood. The content of the orange oil may be contained in an amount of 0.1 to 1% by weight based on the total weight of the detergent composition, but is not limited thereto.

The surfactant described above may be included in an amount of 25 to 55% by weight based on the total weight of the dishwashing detergent composition, and the extract of the patient-free tree fruit may be included in an amount of 5 to 10% by weight. The properties and foaming properties can be further improved. If the surfactant content is less than 25% by weight, the cleaning effect may be insignificant, and if it exceeds 55% by weight, the cleaning effect is insignificant, whereas there is a concern that the water consumption during rinsing is significantly increased. On the other hand, when the fruit extract of the patient-free tree exceeds 10% by weight, the product cost is increased, which is not preferable, and even if the content of the surfactant is increased, there is a concern that the layer separation of the detergent composition occurs and the storage stability is not good. In addition, there is a possibility that skin irritation may occur at a rather high content.

The detergent composition may further include other additives commonly used in detergent compositions in addition to the above-described surfactants and functional ingredients. As the other additives may be known, the present invention is not particularly limited thereto, but may further contain, for example, 1% by weight or less of a preservative, 1% by weight or less of a chelating agent, a fragrance, and a pigment.

Preservatives play a role in preventing the growth of mold or various bacteria due to contamination during manufacturing or use of products and preventing deterioration of products. The preservative may be used without limitation in the case of a preservative used in dishwashing detergent. However, those known as preservatives may be harmful to the human body, such as skin, so it is preferable to include them in a small amount.

On the other hand, the preservative may include allantoin in a predetermined content, and there is an advantage in that the content of allantoin can be greatly reduced due to the use of allantoin, and an increased effect of the preservative performance can be exhibited. Preferably, the preservative may include 80 to 90% by weight of a preservative component and 10 to 20% by weight of allantoin based on the total weight of the preservative. If allantoin is included in an amount of less than 10% by weight based on the total weight of the preservative, it may be difficult to express a synergistic effect of the preservative. In addition, when allantoin is included in an amount exceeding 20% by weight, the synergism of the preservative performance is insignificant, and when it is included in a larger amount, the preservative performance may be rather deteriorated. In addition, there is a risk that storage stability may be deteriorated, such as layer separation or separation of solid/liquid phases during storage. In this case, the known preservatives may be used without limitation, for example, sodium benzoate, ethanol, phenoxyethanol, benzisothiazolinone, methylchloroisothiazolinone, methylisothiazolinone, pentynediol, or Parabens, etc. can be used. However, it is preferable to use sodium benzoate in consideration of the synergistic effect of the antiseptic effect with allantoin.

Meanwhile, allantoin is known in medicine to promote cell growth, promote wound healing, soften keratin proteins, and have other physiological functions. It is also known for use in relieving and treating dry skin, scaly skin disorders, skin ulcers, peptic ulcers and inflammation. Furthermore, it is known to be effective in osteomyelitis, diabetes, liver cirrhosis and acne. In addition, it is also used as a special additive for cosmetics or hair, but allantoin is not known to have antiseptic properties or to help antiseptic performance, and in fact, allantoin alone does not exhibit antiseptic properties. Nevertheless, allantoin exhibits a synergistic effect on the antiseptic effect when used in combination with other preservatives, particularly sodium benzoate, and this technical feature has been discovered by the present inventors and is not a known effect in the prior art.

In addition, in the composition, in addition to the above-mentioned components, purified water is included in the remaining amount.

In step (1), the above-mentioned ingredients are mixed and stirred for 1 hour or more to dissolve the powdery oyster tree fruit extract, and there is no layer separation between the solid phase, the liquid phase, and the liquid phase.

Thereafter, a step of adjusting the pH of the composition prepared as step (2) according to the present invention to neutral is performed. Adjustment of pH may be adjusted using a known pH adjusting agent, and the present invention is not particularly limited thereto. For example, as the pH adjusting agent, sodium citrate, sodium bicarbonate, etc. may be used, and in addition, ethanolamines such as monoethanolamine, diethanolamine, and triethanolamine; bases such as sodium hydroxide (NaOH) and potassium hydroxide (KOH); Alternatively, an acid such as citric acid, salicylic acid, or acetic acid may be used. In addition, the content of the pH adjusting agent may be appropriately adjusted in consideration of the pH of the composition prepared in step (1) and the type of the pH adjusting agent used, so the present invention is not limited thereto.

The present invention will be described in more detail through the following examples, but the following examples are not intended to limit the scope of the present invention, which should be construed to aid understanding of the present invention.

<Preparation example 1>

After separating the fruit and seeds from the fruit of the patient-free tree, the fruit part was crushed to a predetermined size to prepare a coarsely pulverized product. After that, the coarsely pulverized product was immersed in water at 85° C. for 10 hours, and the extract was separated from the extract using filter paper. Thereafter, the extract was concentrated under reduced pressure and then freeze-dried to prepare a hot water extract powder from the fruit of the patient-free tree.

<Preparation example 2>

After separating the fruit and seeds from the fruit of the patient-free tree, the fruit part was crushed to a predetermined size to prepare a coarsely pulverized product. After that, the coarsely pulverized product was immersed in a 90% aqueous solution of ethanol at a temperature of 25° C. for 4 hours, and the extract was separated from the extract using filter paper. Thereafter, the extract was concentrated under reduced pressure and then freeze-dried to prepare an alcohol extract powder from the fruit of a patient without a patient.

<Preparation example 3>

The extract residues from the fruit of the patient-free tree separated in Preparation Example 1 were dried with hot air at 40°C. After the first heat treatment process in which the dried material was heat treated at 65 ° C. for 50 minutes in the absence of steam, a second heat treatment process was performed in which steam was introduced at 100 ° C. for 3 hours, but the second heat treatment process was performed twice. . After the heat treatment process was performed, the extract residues from the fruit of the patient-free tree were immersed in a 90% aqueous solution of ethanol at 25° C. for 4 hours to obtain an extract using a filter paper. Thereafter, the extract was concentrated under reduced pressure and then freeze-dried to prepare an alcohol extract powder from the fruit of a patient without a patient.

<Example 1>

As the surfactant, a first nonionic surfactant was prepared in which cocoglucoside and decyl glucoside were mixed in a weight ratio of 1:2. Then, 50% by weight of the surfactant prepared based on the total weight of the detergent composition, 10% by weight of the patient-free tree fruit extract prepared in Preparation Example 1, 1% by weight of the honey extract, 1% by weight of natural orange oil, 0.5% by weight of sodium citrate as a chelating agent, 0.5% by weight of a preservative After mixing for about 1 hour while mixing % purified water, citric acid was added so that the pH became neutral to prepare a dishwashing detergent composition as shown in Table 1 below. At this time, the content of the added citric acid was 0.6% by weight of the final dishwashing detergent composition.

<Examples 2 to 8>

It was prepared in the same manner as in Example 1, but by changing each component as shown in Table 1 below, a dishwashing detergent composition was prepared.

<Comparative Example 1>

A dishwashing detergent composition was prepared in the same manner as in Example 1, but without the patient-free tree fruit extract as shown in Table 1 below.

<Experimental example>

The following physical properties were evaluated for the dishwashing detergent compositions prepared in Examples and Comparative Examples, and the results are shown in Table 1 below.

1. amount of foam

After filling the mixer with 500ml of water, 10ml of dishwashing detergent composition was added, and the mixer was operated at the same intensity for 1 minute, and then the height and area of the bubbles raised on the surface of the water were measured to calculate the volume of the bubbles. At this time, the height of the bubble was measured as the maximum height as the height.

The calculated volume is expressed as a relative percentage with respect to the remaining Examples and Comparative Examples based on the value of Example 1 as 100.

2. Detergency

10 white plates were coated with the same amount and area of contaminants made by grinding cooking oil, red pepper paste, and kimchi, and then left at room temperature for 3 hours. After putting 10 prepared contaminated dishes into the dishwasher, washing was performed after each of the detergent compositions prepared in Examples and Comparative Examples. Afterwards, 10 experts evaluated the cleaning power of the contaminants on the dishes, and the level of cleaning was evaluated as 10 to 0 based on the level of contamination of the dish before treatment with 10 and the level of contamination of the dish with 0 after treatment with contaminants. , the evaluation results of 10 experts were calculated as the average.

3. Amount of washing water required for rinsing

After the same amount of detergent composition was treated on a dish of the same size, the amount of water until the detergent composition was all removed was measured. The measured amount of water was calculated as a percentage based on Example 1.

4. Storage stability

After placing the washing composition in the same container, it was left in a room at 4 ° C. for 180 days, and then visually inspected the appearance to observe whether there is a layer separation, solid phase subsidence, or solid/liquid phase separation such as floating. If there is complete delamination and/or sediment or floats exceeding 1 mm in height, ○, partial delamination or sediments less than 1 mm in height, or if there are floats, △, if there is no abnormality, ×.

Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Comparative Example 1 First nonionic surfactant (A) cocoglucoside ○ ○ not included ○ ○ ○ ○ ○ ○ Decylglucoside ○ not included ○ ○ ○ ○ ○ ○ ○ Mixing ratio (weight ratio) 1:2 - - 1:2 1:2 1:2 1:2 1:2 1:2 Second non-ionic surfactant (B) HLB not included not included not included 16.7
(Polysorbate 20) 15.0
(Polysorbate 80) 19.1
(PEG-80 Sorbitan Laurate) 16.7
(Polysorbate 20) 16.7
(Polysorbate 20) not included Cocoamidopropyl Betaine (C) not included not included not included not included not included not included including including not included Mixing ratio (A:B:C) - - - 3:1 3:1 3:1 3:1:0.6 3:1:0.8 - Nutmeg fruit extract Preparation Example 1/10 wt% Preparation Example 1/10 wt% Preparation Example 1/10 wt% Preparation Example 1/10 wt% Preparation Example 1/10 wt% Preparation Example 1/10 wt% Preparation Example 1/10 wt% Preparation Example 1/10 wt% not included Bubble generation (%) 100 83 76 107 95 102 110 110 71 detergency 8.5 7.9 7.6 8.9 8.2 8.8 9.8 9.8 7.6 Required number of washes (%) 100 100 100 82 111 103 84 83 125 storage stability △ ○ ○ × △ ○ × ○ ×

As can be seen from Table 1,

It can be confirmed that the Example including the patient-free tree fruit extract has excellent effects in the amount of foam generated, the cleaning power, the required washing water, etc. compared to the comparative example.

However, as can be seen in the Examples, storage stability at low temperatures may be a problem when the extract of the patient-free tree is included, and Examples 4 and 7, which are preferred embodiments of the present invention, are very excellent in storage stability. In particular, it can be seen that Example 7 significantly improved even the cleaning power.

Although one embodiment of the present invention has been described above, the spirit of the present invention is not limited to the embodiments presented herein, and those skilled in the art who understand the spirit of the present invention can add components within the scope of the same spirit. , changes, deletions, additions, etc. will be able to easily suggest other embodiments, but this will also fall within the scope of the present invention.

Claims (11)

preparing a composition by mixing a surfactant containing a first non-ionic surfactant derived from a natural material and a functional ingredient containing an extract of a patient-free tree fruit with purified water; and
Including; adjusting the pH of the composition to neutral;
The first nonionic surfactant derived from the natural material is an alkyl polyglucoside including cocoglucoside and decylglucoside,
The surfactant further contains polysorbate having a hydrophilicity-lipophilic ratio (HLB) of 16.0 to 17.0 as a second nonionic surfactant,
The surfactant further contains cocoamidopropyl betaine as an amphoteric surfactant component, and the cocoamidopropyl betaine and the second non-ionic surfactant are 0.3 to 0.6: Dishwashing detergent using fruit extract of the patient-free tree contained in a weight ratio of 1 A method for preparing a composition. According to claim 1,
The functional ingredient is a method of manufacturing a dishwashing detergent composition using a patient-free fruit extract, characterized in that it further comprises a honey extract and orange oil. According to claim 1,
Based on the total weight of the composition, 25 to 55% by weight of the surfactant and 5 to 10% by weight of the patient-free tree fruit extract are included. According to claim 1,
The first nonionic surfactant derived from the natural material is a method for producing a dishwashing detergent composition using the fruit extract of the patient-free tree, characterized in that it comprises cocoglucoside and decylglucoside. delete 5. The method of claim 4,
The coco glucoside and decyl glucoside are 1: 2 to 3 weight ratio of the dishwashing detergent composition manufacturing method using the fruit extract of the patient-free tree, characterized in that it is contained. According to claim 1,
The first non-ionic surfactant and the second non-ionic surfactant are 3 to 5: A method for producing a dishwashing detergent composition using the fruit extract of the patient-free tree, characterized in that it is contained in a weight ratio of 1. delete According to claim 1,
The method for producing a dishwashing detergent composition using the patient-free tree fruit extract, wherein the patient-free tree fruit extract comprises a hot-water extract obtained by extracting the patient-free tree fruit or coarsely pulverized product of the patient-free tree fruit with hot water at a temperature of 80 to 100 ℃. 10. The method of claim 9,
The patient-free tree fruit extract further comprises an alcohol extract of a patient-free tree fruit or a crude pulverized product of the patient-free tree fruit,
A method for producing a dishwashing detergent composition using a patient-free tree fruit extract, characterized in that it contains a hot water extract and an alcohol extract of a patient-free tree fruit or a coarsely pulverized product of a patient-free tree fruit in a weight ratio of 1: 1-2. 11. The method of claim 10,
The alcohol extract comprises a first heat treatment step of heat-treating the dried product of the fruit extraction residue remaining after hot water extraction of the fruit of the patient-free tree or the crude crushed product of the fruit of the patient-free tree at 60 to 70 ° C., and at least at 90 to 110 ° C. A method for producing a dishwashing detergent composition using a patient-free tree fruit extract, characterized in that it is an alcohol extract extracted with a lower alcohol having 1 to 4 carbon atoms after performing a second heat treatment process of one time heat treatment.