WO2010062080A2

WO2010062080A2 - Environmentally-friendly detergent composition

Info

Publication number: WO2010062080A2
Application number: PCT/KR2009/006816
Authority: WO
Inventors: 김영배
Original assignee: Kim Young Bae
Priority date: 2008-11-25
Filing date: 2009-11-19
Publication date: 2010-06-03
Also published as: KR100917337B1; WO2010062080A3

Abstract

The present invention relates to an environmentally-friendly detergent composition containing natural food additives, which has no bubbles and excellent cleaning ability, deodorizing properties, and sterilizing properties for effectively adsorbing and removing microorganism, agricultural chemicals, heavy metal, and the like from the surface of fruits, vegetables, etc. The environmentally-friendly detergent composition of the present invention is safe to the human body in terms of sanitation, and leaves no materials that are harmful to food. The detergent composition of the present invention has significantly high biodegradability and solubility, and therefore, is free from water pollution and the destruction of the ecological system.

Description

Eco-friendly Detergent Composition

The present invention effectively removes various contaminants such as microorganisms, pesticides and heavy metals on the surface of fruits, vegetables, etc. by exerting excellent cleaning power, deodorant and sterilization, safe for food and hygiene, and no environmental pollution problems. The present invention relates to a detergent composition containing a raw material of an additive, wherein the composition is for cleaning non-toxic and pollution-free eco-friendly vegetables, fruits, utensils, kitchen utensils, baby products, detergents for human body (for body cleanser or wet wipes), or It relates to a laundry detergent composition.

Cleaning consists of three elements: liquid (water or solvent), detergents, and mechanical forces.

The medium liquid of the urea dissolves the detergent, carries the detergent component to the interface between the object and the dirt, and separates and transports the desorbed dirt.

In addition, among the above components, the detergent includes a detergent main ingredient and an auxiliary component. The detergency has a complex effect of lowering the surface tension, emulsifying, solubilizing, penetrating, and micelle formation of the detergent.

In addition, the mechanical force of the above-mentioned elements is generally not cleaned simply by soaking the object to be cleaned in a liquid containing detergent. By appropriately applying mechanical (physical) forces, the cleaning process can be completed efficiently and quickly. For example, the use of a washing machine, a washboard, a laundry net, a dishcloth, and a brush is mentioned.

Detergents consist of a main component and an auxiliary agent, and the surfactants used for cleaning purposes are particularly called cleaning agents. The surfactant molecule is composed of two completely different moieties called hydrophilic and lipophilic groups.

The former includes a carboxyl group, a hydroxyl group, a sulfuric acid group, a sulfate ester group and an ammonium group, and the latter includes an alkyl group, an alkylallyl group, a fatty acid group and an alkyl ketone group. By combining these, surfactants having different properties are completed, and among them, those having various properties required as detergents are selected and prepared into detergents.

There are four kinds of surfactants, which are the main components of the detergent, such as petrochemical anionic surfactants, cationic surfactants, amphoteric surfactants, and nonionic surfactants. All four types of detergents are included. As the anionic surfactant, soap, alkylbenzene sulfate, higher alcohol sulfate ester salt and the like are mainly used. Alkylbenzene sulfate is a main agent of detergent, and this refers to synthetic detergent.

Problems of the Prior Art

Alkylbenzene-based synthetic detergents are the main cause of contamination by detergents. Alkyl benzene-based detergents are difficult to decompose by microorganisms living in the wastewater, promote the foaming of the river and at the same time prevent the oxygen absorption in the air.

In addition, since the action of lowering the natural purification action of the river, when the river water is used in the beverage, the synthetic detergent component accumulates in the human body.

In addition, the accumulation of fish and shellfish in rivers and the like is inevitable.

In addition, there are several reports concerning the toxicity of synthetic detergents to humans and livestock. Among the toxic damages identified by eyes, for example.

(1) Skin damage caused by the contact of synthetic detergent components with skin, such as finger skin eczema or cutaneous symptoms of a housewife who washes dishes every day.

(2) The use of detergents made of synthetic detergents destroys the skin barrier due to its strong cleansing and penetrating power. As a result, moisture in the skin escapes, the skin dries quickly, wrinkles are formed, and the aging process is accelerated. In other words, breaking the normal skin barrier causes skin trouble and aging.

Even more surprising is that the ingredients of the synthetic detergents overlap with those used to cause cancer in animal experiments. Because synthetic detergents are very small in molecular weight, it is well known that when they are absorbed into the skin through the pores, they enter the blood vessels, accumulate in organs, and have a high risk of developing cancer.

Synthetic surfactants also dissolve proteins, so they dissolve DNA, which also serves as a design for cells in our bodies. Peeling fat from the skin to melt cell membranes can cause skin disorders, dermatitis, rough skin, eczema, acidification of the constitution, inhibition of enzymatic activity, and destruction of white blood cells. have.

The most frightening thing is that these synthetic surfactants are not immediately damaged, but they become chronic and build up in the body and later become toxic. Such petrochemical surfactants are commonly contained in products used in our lives, such as dish detergents, shampoos, bath products, and laundry, and commercially available vegetable shampoos are no exception.

For example, there may be some differences in the ingredients of a vegetable shampoo and the manufacturing process of each manufacturer, but the composition ratio of the components of a commonly known vegetable shampoo is approximately:

50-60% of water

30-35% surfactant

Functional additives (neutralizing agents, preservatives, antifreezes, pigments or flavorings) 3-5%

Thickener 10-20%

Herb Extract 1-3% (optional ingredient included in high quality products)

As seen above, in the case of conventional vegetable shampoos that are commercially available, the dosage of the surfactant, which is considered to be the main cause of environmental pollution or pollution, does not change compared to conventional shampoos, and only after adding a small amount of herbal extracts There is a problem in advertising and marketing as a natural vegetable product.

On the other hand, the surfactant which is a main component of the conventional synthetic detergent is known to have about 13% biodegradability. Here, biodegradability refers to the degree of nature that is naturally decomposed in the natural world. Fish, meat, or food are naturally degraded, while plastic containers made from petroleum cannot be broken down if they are buried in the soil.

Such low biodegradable surfactants are difficult to be decomposed by microorganisms residing in the waste water, promote the foaming of the river, and prevent the oxygen absorption from the air and reduce the natural purification of the river.

In addition, the detergents of conventional surfactants require a large amount of water to remove the foam because a lot of foam occurs. As a result, due to the large amount of water required for defoaming, there is a problem of increasing the burden of water consumption by the public and increasing the cost of water purification treatment by increasing domestic sewage generation and emissions.

Furthermore, since the raw materials used in synthetic detergents are not soluble in cold and hard water, the residual components of the surfactants on the tableware after washing the dishes are absorbed and accumulated in the human body through the tableware, which adversely affects the human body. It has a negative impact on the water quality ecosystem.

In general, a foamy detergent may be regarded as having good cleaning power and excellent quality, but the foamability and cleaning power of the detergent have no relation.

As such, cleaning detergents prepared with the surfactants of the prior art have a problem of harming public health and destroying the water ecosystem, wasting water or raising the cost of water purification.

On the other hand, as a subsidiary material (adjuvant) of a conventional detergent, antiseptics, antifreezes, neutralizers, thickeners, pigments, flavoring moisturizers and the like are widely used in cosmetics, shampoos and detergents. However, these chemicals are harmful to the human body because they may cause fine wrinkles, alopecia, chronic fatigue, memory loss.

Technical task and purpose of the present invention for solving the prior art

The present invention has the following technical problem and object to solve the problems of the prior art as described above.

First, alkylbenzenes and alkyl sulfates, which are used as main components of cleaning detergents, are known as latent carcinogens, and preservatives, antifreezes, neutralizers, thickeners, pigments, and fragrances, which are used as auxiliaries, are harmful chemicals. It is known as a harmful substance that harms the human body. The present invention excludes the raw materials of the hazardous chemicals as described above, safe and hygienic for food, no problem at all, and environmentally friendly detergent composition containing food additives that do not adversely affect the environment and ecosystem at all There are technical challenges and objectives to promote health.

Second, domestic sewage from organic kitchens and detergent sewage from baths and laundry account for 70% of Korea's total water pollution. The cause of this phenomenon is that petrochemical-based surfactants, preservatives, antifreezes, pigments, and fragrances, which are used as main ingredients and auxiliaries in the manufacture of cleaning detergents in the prior art, are mostly toxic, environmental pollution occurs, and bubbles are more than necessary. Because it does not melt well in cold and hard water. More washing water is needed to remove this much generated foam and the sewage emissions increase. In addition, if the detergent is discharged in an insoluble state, the pollution concentration and the emission of malignant sewage are increased by that amount.

In order to significantly improve this problem, all raw materials consisting of petrochemical-based surfactants and hazardous chemicals are not used at all, and should be replaced with pollution-free and non-toxic eco-friendly raw materials that are harmless to the human body. In addition, with excellent cleaning and disinfecting power, it removes various contaminants such as microorganisms, pesticides and heavy metals on the surface of vegetables and fruits hygienically and safely, and has no problems with food, almost no bubbles, and dissolves well in cold and hard water. There is a need for a breakthrough technology to create an eco-friendly, pollution-free and non-toxic cleaning detergent with high biodegradability.

The present invention achieves the above technical problem and reduces the degree of contamination by a drastic improvement, as well as washing rinsing water and washing rinsing water is reduced by about 30-40% compared to the conventional detergent composition, the public's use of water It is aimed at reducing the cost of water, and contributing to reducing the cost of water purification.

Third, petrochemical-based surfactants and hazardous chemical ingredients, which are used as main components and auxiliary agents of detergents in the prior art, are mostly discharged under low biodegradability and insoluble in water, which adversely affects the water quality environment. It is known.

The present invention excludes the use of biodegradable and low-solubility petrochemical-based surfactants and hazardous chemicals, and replaces with non-toxic, pollution-free, eco-friendly food additives that are highly biodegradable and soluble and purified to water pollution. It is aimed at contributing to the preservation of ecosystems and the water quality of the environment, including fishes in rivers and rivers.

Fourth, most of the materials used in the prior art as main ingredients and auxiliary agents in cleaning detergents are mostly imported goods. It aims to reduce foreign currency expenditure due to imports and to create jobs and increase employment by activating domestic domestic industry by replacing conventional detergents manufactured and manufactured with imported raw materials with domestic raw materials produced in Korea.

The present invention (A) at least one of sodium bicarbonate or sodium carbonate; (B) at least one of palm oil, palm oil or olive oil; (C) glycerin or glycerin fatty acid ester; (D) at least one of sodium citrate or citric acid; (E) at least one of sodium alginate or sodium fibrin glycoate; (F) sodium chloride; And (G) relates to a detergent composition for washing vegetables, fruits, tableware, kitchen utensils, baby products or human body, characterized in that it contains purified water.

Preferably, based on the total weight of the detergent composition, (A) 7-25% by weight of at least one of sodium bicarbonate or sodium carbonate; (B) 2-15% by weight of at least one of palm oil, palm oil or olive oil; (C) 3-20% by weight of at least one of glycerin or glycerin fatty acid ester; (D) 2-15% by weight of at least one of sodium citrate or citric acid; (E) 1-10% by weight of at least one of sodium alginate or sodium cellulose glycoate; (F) 0.5-10% by weight sodium chloride; And (G) after mixing the remaining amount of purified water, and relates to a detergent composition for washing vegetables, fruits, tableware, kitchen utensils, baby supplies or human body prepared by stirring for 3 to 24 hours.

More preferably, (A) 10-20% by weight of at least one of sodium bicarbonate or sodium carbonate; (B) 2-10% by weight of at least one of palm oil, palm oil or olive oil; (C) 3-15% by weight of at least one of glycerin or glycerin fatty acid ester; (D) 3-10% by weight of at least one of sodium citrate or citric acid; (E) 1-5% by weight of at least one of sodium alginate or sodium cellulose glycoate; (F) 1-5% by weight sodium chloride; And (G) after mixing the remaining amount of purified water, and relates to a detergent composition for washing vegetables, fruits, tableware, kitchen utensils, baby supplies or human body prepared by stirring for 3 to 24 hours.

Even more preferably, the mixing ratio of at least one of (B) palm oil, palm oil or olive oil, and at least one of (C) glycerin or glycerin fatty acid ester in the composition of the present invention is 1: 5, Especially preferably, the mixing ratio is 1: 3.

In still another aspect of the present invention, there is provided an article of manufacture comprising (A) at least one of sodium bicarbonate or sodium carbonate; (B) at least one of palm oil, palm oil or olive oil; (C) at least one of glycerin or glycerin fatty acid ester; (D) at least one of sodium citrate or citric acid; (E) at least one of sodium alginate or sodium fibrin glycoate; (F) sodium chloride; (G) caustic soda; And (H) purified water.

Preferably, (A) 7-20% by weight of at least one of sodium bicarbonate or sodium carbonate; (B) 2-10% by weight of at least one of palm oil, palm oil or olive oil; (C) 3-20% by weight of at least one of glycerin or glycerin fatty acid ester; (D) 2-15% by weight of at least one of sodium citrate or citric acid; (E) 1-5% by weight of at least one of sodium alginate or sodium cellulose glycoate; (F) 0.5-10% by weight sodium chloride; (G) 5-15% by weight caustic soda; And (H) after mixing the remaining amount of purified water, and relates to a laundry detergent composition prepared by stirring for 3 hours to 24 hours.

More preferably, (A) 10-20% by weight of at least one of sodium bicarbonate or sodium carbonate; (B) 2-7% by weight of one or more of palm oil, palm oil or olive oil; (C) 3-15% by weight of at least one of glycerin or glycerin fatty acid ester; (D) 3-10% by weight of at least one of sodium citrate or citric acid; (E) 1-3% by weight of at least one of sodium alginate or sodium cellulose glycoate; (F) 1-5% by weight sodium chloride; (G) 5-10% by weight of caustic soda; And (H) after mixing the remaining amount of purified water, and relates to a laundry detergent composition prepared by stirring for 3 hours to 24 hours.

Sodium bicarbonate, sodium citrate, glycerin, palm oil, sodium alginate, sodium chloride, caustic soda is a highly biodegradable, soluble, deodorant and antimicrobial, has excellent cleaning power and is an environmentally friendly, non-toxic, non-toxic food additive without edible problems.

Based on these points, the present inventors have conducted intensive research experiments. As a result, the present inventors have used environmental hormones used as a main component in the prior art, as well as preservatives, antifreezes, thickeners, neutralizers, pigments, and harmful chemicals. Natural preservatives (glycerine, sodium chloride), natural neutralizers (glycerine), natural thickeners (sodium alginate), natural antifreezes (glycerine, sodium chloride), natural pigments (palm oil, sodium alginate), natural fragrances When using a detergent composition containing environmentally friendly natural materials such as palm oil, it has been found that the fundamental problems (environmental hormone, skin eczema, environmental pollution) of the prior art can be improved.

In the following, look at each component contained in the composition of the present invention.

Sodium bicarbonate, sodium carbonate

Sodium bicarbonate is also referred to as sodium bicarbonate, sodium bicarbonate, sodium bicarbonate of carbonic acid, sodium bicarbonate, baking soda. Sodium carbonate is also known as soda ash. When sodium bicarbonate or sodium carbonate becomes aqueous solution, it generates carbon dioxide and begins to hydrolyze, and about 90% turns to caustic soda, showing alkalinity.

Sodium bicarbonate is one of the important elements to maintain a highly biodegradable life, well dissolved in water, naturally exists in a certain amount in the human body. Therefore, it is used as a raw material for pharmaceuticals such as antacids. In addition, the sodium bicarbonate solution has the remarkable property of removing harmful gases such as heavy metals such as lead and sulfurous acid gas, and has the function of neutralizing acidic substances in liquid or gaseous state, and also improves various pollution by acid rain. Known. In addition, aqueous sodium bicarbonate solution is an environmentally friendly food additive that has adsorption, deodorization, neutralization, softening, and action and is completely decomposed after use.

Aqueous solution of sodium bicarbonate, when mixed in a proper ratio with the self-cleaning palm oil occurs a unique alkali balancing action. This action exerts excellent efficacy and cleaning power for cleaning and deodorization, changes insoluble pollutants to water solubility, and expresses an amazing effect of neutralizing odor molecules. Therefore, the more the detergent detergent of the present invention is used, the more the environment is purified and the better the water quality is.

However, when sodium bicarbonate is used for metal, it cannot corrode the metal and discolor the metal surface. However, if sodium citrate is mixed with sodium bicarbonate, it can cause corrosion of metal and discoloration of metal surface. You can stop it.

The present invention may be used alone by selecting any one of the above sodium bicarbonate or sodium carbonate, or may be used by mixing.

2, palm oil, palm oil, olive oil

Palm oil is oil made by squeezing the fruits of palm trees called dates. Palm oil is transformed into oil for many uses depending on how it is refined from its crude CPO (the first oil). It is used in many places for food and edibles, such as ramen frying, shortening and margarine, and the demand is gradually increasing.

Palm oil generally begins to solidify when it is below 7-8 ° C, and must be 22-24 ° C to return to liquid form. Palm oil is a typical oil that is widely used for making handmade soaps because of its self-cleaning ability. Palm oil is a natural substance that contains high amounts of oleic acid, which prevents arteriosclerosis, and vitamin F, which lowers blood cholesterol. Vitamin F is mixed with the drying agent and humectant contained in glycerin and adsorbed on the surface of vegetables and fruits to keep moisture of vegetables and fruits.

Palm oil is called copra, which is a dried part of the fatty nucleus that is collected from the fruit of coco palm. The quality of the copra depends on the degree of drying, and the amount of moisture remaining should be less than 8% because the mold will grow due to mold. The dryness of copra affects the quality and yield of palm oil.

Olive oil is also called pale yellow undried oil and olive oil. Olive oil becomes cloudy at 10 ° C and becomes ointment at 0 ° C. About 25% of olive oil is solid glycerides (stearic acid, palmitic acid, arabic acid) and about 75% is liquid glycerides (linoleic acid, oleic acid).

The present invention may use solid glyceride olive oil (stearic acid, palmitic acid, arabic acid) or liquid (linoleic acid, oleic acid) glycerides, or palm oil, including the palm oil, and the present invention is also palm oil, palm oil or olive oil Any one of them may be selected and used, or two or more may be mixed and used.

3, glycerine. Glycerin fatty acid esters or derivatives thereof

Glycerin is a colorless, clear and sweet viscous liquid with a strong hygroscopicity. Glycerin is a by-product of soap making that softens and protects the skin. In addition, the ability to make or maintain two or more substances that cannot be mixed like oil and water in a uniform mixture promotes the synthesis and mixing of added substances to promote maximum synthesis efficiency and increase product spreadability.

In addition, it acts as a drying inhibitor, a humectant, a viscous agent, and has the ability to adjust (coagulation) of fats and oils, ability to modify fats and oils, and natural preservatives.

Glycerin fatty acid esters are esters and derivatives of fatty acids and glycerin or polyglycerine. These include glycerin fatty acid esters, glycerin acetic acid fatty acid esters, glycerin lactic acid fatty acid esters, glycerin citric acid fatty acid esters, glycerin pumpkin fatty acid esters, glycerin diacetyl tartrate fatty acid esters, glycerin acetate esters, polyglycerol fatty acid esters or polyglycerol condensed lysinolenic acid esters. Etc. are included.

4.Sodium citrate, citric acid

Sodium citrate is a natural metabolite of plants and animals in nature and is the most abundant organic acid from citrus fruits. It is widely used in the food and pharmaceutical industry as a sour acid, pH regulator, antioxidant, detergent, astringent, etc.

Sodium citrate is divided into citric acid and citric anhydride according to the water molecule content, and is also used in the form of salts such as sodium citrate, calcium citrate and potassium citrate, and citric acid triether, acetyl citrate and citric acid ester.

Sodium citrate has the ability to remove oxides from the metal surface to prevent corrosion of the metal and to prevent discoloration of the metal surface. Citric acid is widely used as a fabric softener, cleaning agent, tooth cleaner, foaming agent, and phosphoric acid substitute because it is easy to decompose in complexing and ecosystem.

In addition, sodium citrate is widely used for hydrogen ion concentration control, odor prevention, gel formation enhancement, buffering agent, maintaining the safety of active ingredients, increasing the shelf life, antioxidants, and the like. As such, sodium citrate is an edible, environmentally friendly natural material used in food and medicine.

5.Sodium Alginate, Sodium Glycerate

Sodium alginate is also called seaweed. Sodium alginate is a polymer of two kinds of uronic acid. It is a white, yellowish white powder with a degree of polymerization of 80 and a molecular weight of 1500. It is almost odorless, tasteless, and highly viscous substance contained in seaweed such as kelp and seaweed. to be. It dissolves well in water, becomes a store liquid, and becomes a colloidal phase. However, the viscosity of the hard sticky fiber called U-fucoidan contained in sodium alginate has the disadvantage that the dissolution is slightly slow in cold water and hard water.

Sodium alginate has excellent adsorption ability to heavy metals, which is excellent for removing pesticides and heavy metals on the surface of fruits and vegetables. In addition, sodium alginate is used as a thickener and adhesive for emulsifiers (emulsifiers), soaps, ketchup, sauces, fish jelly, etc., and is used as a stabilizer in cold fruits such as ice cream. This should be noted as it is not suitable for strong acidic products and in salts above 8% salts will cause salt to lose viscosity. Sodium alginate is an environmentally friendly natural material that is safe for food.

Sodium cellulose glycol is also referred to as carboxy methyl cellulose or water soluble cellulose. White powder or fibrous material, odorless and easily soluble in water. The solution becomes a neutral or slightly alkaline high viscosity liquid. It doesn't rot like gum arabic, casein or plaster. As a thickener, 0.15-0.18% is commonly used for ice cream, 0.5-1% for ketchup, 1.0-2.0% for ramen broth, eel broth, and 0.5-1.0% for instant red bean porridge.

The present invention includes sodium alginate or sodium cellulose glycolate as a thickener, and may be used alone by selecting any one of sodium alginate or sodium cellulose glycolate, or may be used by mixing two or more thereof.

6.Sodium chloride (sun salt)

Salt is used as an important food and preservative as well as maintaining life. Sodium removes microorganisms on the surface of fruits and vegetables. In addition, salt sterilizes, detoxifies, decays, deodorizes, freezes (antifreezes), and protects the skin to make it strong. The fact that human blood is made up of 0.9% salt indicates the importance of salt.

Salt contains not only its value as a food but also its medicinal properties, and its use is very diverse. Salt is a natural food, thus acts as anti-corruption (preservative) detoxification, sterilization, odor removal, freezing prevention, fiber modifiers, microorganisms in fruits and vegetables, skin protection agents.

In particular, in connection with the disadvantage that the hard fiber Ufucoidan contained in sodium alginate is slightly dissolved in water, sodium chloride penetrates the Ufucoidan tissue contained in sodium alginate to modify the hard viscosity of the fiber to soft viscosity. Sodium is well soluble in water.

7.caustic soda (sodium hydroxide)

Caustic soda is a white translucent solid and is highly deliquescent in air. When dissolved in water, hydrogen is generated while showing strong heat. In addition, the aqueous solution of caustic soda has a strong penetration and is strongly alkaline. It is soluble in water, methyl alcohol, ethyl alcohol and glycerin, and its solubility is 42 g at 0 ° C. and 109 g at 20 ° C. based on 100 ml of water.

Caustic soda is used as an alkaline and neutralizing agent for water softeners, honeycombs, synthetic fibers, bleaching, general cleaning, and food preparation.It is used as a strong alkali in food additives to make sodium salts of food additives, and to make amino acid liquids (chemical soybean oil). . In addition, it has high biodegradability, good dissolution, excellent dispersibility, and strong adsorptivity, so it has a strong penetrating power to remove citrus inner skin and peach blood when manufacturing canned citrus and canned peaches. Is processed.

1. Background and effect of mixing sodium bicarbonate with palm oil, palm oil or olive oil

In the present invention, when sodium bicarbonate is added to the purified water of 7-25% by weight, preferably 10-20% by weight based on the total weight of the composition to prepare an aqueous solution, carbon dioxide is generated and begins to hydrolyze into caustic soda Is converted. When at least one of palm oil, palm oil or olive oil is mixed with 2-15% by weight, preferably 2-10% by weight, more preferably 3-7% by weight, and stirred with a stirrer for at least 1 hour, A weak alkaline saponification reaction with a pH of 7-8 can occur and excellent washing power can be obtained.

However, when sodium bicarbonate is mixed in excess of 25% by weight of the total weight of the composition, although it may be advantageous to increase the washing power, there is a fear that due to the excessive content, saturation occurs in the dissolution process and precipitate. In addition, when sodium bicarbonate is mixed in less than 7% by weight of the total weight of the composition, there is no fear of precipitation after mixing, but there is a fear that the cleaning power is lowered due to insufficient content in the process of mixing with palm oil.

2. Background and effects of palm oil, palm oil or olive oil

Palm, palm or olive oils contain high amounts of oleic acid to prevent arteriosclerosis and vitamin F to lower blood cholesterol. Vitamin F is synthesized with the ingredients of the drying agent and the humectant contained in glycerin, and it adsorbs on the surface of vegetables and fruits when washing vegetables and fruits to prevent drying of the surface moisture of vegetables and fruits. It is effective to keep it stable.

To the composition of the present invention, palm oil, palm oil or olive oil is mixed with 2-15% by weight, preferably 2-10% by weight, more preferably 3-7% by weight, based on the total weight of the composition.

However, when the blending amount of palm oil and the like is less than 2% by weight based on the total weight of the composition, the amount of the desired cleaning power cannot be obtained due to the lack of content, and wetting and moisturizing retention effect is reduced by weakening the moisturizing power on the surfaces of vegetables and fruits. It lowers the freshness maintenance of vegetables and fruits, and may lower the synergistic effects, such as moisturizing of a skin, spreading of a washing | cleaning liquid, and stopping coagulation of palm oil. In addition, when the mixing amount of palm oil and the like exceeds 15% by weight based on the total weight of the composition, the moisture and moisture are increased by enhancing the adsorption power on the surfaces of the vegetables and fruits, which may be advantageous for maintaining the freshness of the vegetables and fruits and moisturizing the skin. However, in mixing with sodium bicarbonate, the content of saponification reaction is lost due to excessive content, and the synergistic effect of the cleaning power is lowered.

3. Background and Effect of Glycerin, Glycerin Fatty Acid Ester, or Derivatives thereof

Glycerin (fatty acid ester) has the ability to make or maintain a uniform mixture of two or more substances that cannot be mixed, such as oil and water.

On the other hand, palm oil generally starts to solidify when it is lowered to about 7-8 ° C or lower, and returns to a liquid state when it is about 22-24 ° C. Since the coagulation phenomenon of palm oil becomes worse in winter, there is a problem to use it as it is in the present invention.

Therefore, in order to solve this problem, in the present invention, one or more of palm oil, palm oil or olive oil and glycerin are preferably mixed in a ratio of 1: 5, more preferably in a ratio of 1: 3. Glycerin and palm oil, palm oil or olive oil mixed at the above ratios become synthetic mixed oils and do not solidify even at minus 20 ° C.

The inventors set the freezer temperature of the refrigerator to minus 20 ° C., mixed 80 ml of palm oil, 20 ml of olive oil, and 300 ml of glycerin in a 500 ml plastic container, and stored in the freezer for 30 days, but did not solidify.

Palm oil and glycerin mixed in the above ratios serve as an excellent moisturizer and fungicide to soften and smooth the skin, and are adsorbed on the surface of vegetables and fruits to effectively maintain the moisturizing and wetting of the surfaces of vegetables and fruits. By inhibiting the evaporation of moisture on the fruit surface and the like, it produces the effect of maintaining and maintaining the freshness of vegetables and fruits.

In the composition of the present invention, at least one of glycerin or glycerin fatty acid ester is mixed at 3-20% by weight, preferably 3-15% by weight, based on the total weight of the composition.

However, when the content of one or more of glycerin or glycerin fatty acid ester is less than 3% by weight, the washing power is lowered due to lack of content in mixing with sodium bicarbonate, and the moisture and moisturizing retention effect is reduced by weakening the moisture on the surface of vegetables and fruits. It may lower the freshness of vegetables and fruits, and lower the synergistic effects such as moisturizing the skin, spreading of the liquor and preventing the coagulation of palm oil. In addition, when the content of at least one of glycerin or glycerin fatty acid ester exceeds 20% by weight, it may be advantageous to maintain the freshness of the vegetable and fruit and to moisturize the skin by increasing the moisture and moisture by enhancing the adsorption power on the surface of the vegetable and fruit, In mixing with sodium, the content of saponification reaction may be lost due to excessive content, which may lower the synergistic effect of the cleaning power.

4.Background and effect of adding sodium citrate or citric acid

Sodium citrate has the ability to remove oxides from the metal surface to prevent corrosion of the metal and to prevent discoloration of the metal surface. Sodium citrate is used as a fabric softener, cleaning agent, tooth cleaner, foaming agent, and phosphoric acid substitute because it is easy to decompose in complexing ability and ecosystem, and also controls hydrogen ion concentration, prevents odor, enhances gel formation, maintains buffer, keeps active ingredients, and preserves them. It is widely used as an antioxidant.

In addition, sodium citrate is also characterized by the sterilization action and odor elimination compound of the sodium bicarbonate, the bactericidal power and odor removal of glycerol to enhance the synergistic effect of odor removal and sterilization action.

However, as described above, when sodium bicarbonate is made into an aqueous solution, it is converted into caustic soda due to hydrolysis. When such an alkali (caustic soda) aqueous solution comes into contact with the metal surface, an oxide film is formed on the metal surface as an alkali ferric acid salt of iron, and the corrosion of the metal is promoted, and hydrogen generated at this time is generated in the form of atoms on the metal surface. It gradually penetrates into the grain boundaries of the metal and causes caustic dropping. This corrosion phenomenon makes sodium bicarbonate unsuitable for use on metals.

However, in the present invention, when sodium citrate is mixed with 2-15% by weight, preferably 3-10% by weight, based on the total weight of the composition, it is neutralized with alkali acid salts of iron to promote the corrosion of the metal, Because it prevents discoloration, it can be safely used for metal.

Here, if the addition amount of sodium citrate exceeds 15% by weight based on the total weight of the composition, the effects of corrosion and discoloration prevention, sterilization and odor removal of heavy metals may be enhanced, but in the mixing process with sodium bicarbonate in an excessive amount The saponification reaction generated is unbalanced and causes deterioration of cleaning power. In addition, when the addition amount of sodium citrate is less than 2% by weight based on the total weight of the composition, it is possible to prevent corrosion and discoloration of heavy metals in the process of neutralizing iron alkali salts which promote corrosion of heavy metals due to the lack of sodium citrate content. The synergistic effect of performance and sterilization and odor removal is reduced.

5.Additional Background and Effect of Sodium Alginate or Sodium Fibroglycolate

Sodium alginate dissolves well in water, and becomes a colloidal solution. However, the viscosity of the hard sticky fiber called U-fucoidan contained in sodium alginate has a disadvantage that the dissolution rate is slightly slow in cold water and hard water. Sodium alginate has excellent adsorption ability to heavy metals, which removes pesticides and heavy metals from fruits and vegetables.

In the present invention, sodium alginate is mixed 1-10% by weight, preferably 1-5% by weight, more preferably 1-3% by weight, based on the total weight of the composition.

Here, when sodium alginate is mixed at less than 1% by weight based on the total weight of the composition, it dissolves and decomposes quickly in water, but it has a low content and maintains a good viscosity, and it is efficient to adsorb and remove heavy metals and pesticides on vegetables and fruits. Degrades. In addition, when sodium alginate is mixed in excess of 10% by weight based on the total weight of the composition, sodium alginate has an excellent adsorptive power to heavy metals, so that the effect of removing pesticides and heavy metals on the surface of fruits and vegetables will be enhanced, but the content is excessive. As a result of reforming the hard fibers into soft ones, the melting efficiency of the soft fibers decreases, resulting in a decrease in the rate of dissolution in water and debris after use.

6 Background and Effect of Sodium Chloride

Salt has excellent effects such as anti-corruption, freeze protection, sterilization, detoxification, odor removal, skin protection.

In the present invention, sodium chloride is mixed at 0.5-10% by weight, preferably 1-5% by weight, based on the total weight of the composition.

Here, if sodium chloride is mixed at less than 0.5% by weight based on the total weight of the composition, there is no risk of salt formation and precipitation, but due to insufficient content, it is possible to prevent rot, freeze, sterilize, detoxify, remove odor, and remove microorganisms. The effect is lowered. In addition, when sodium chloride exceeds 10% by weight based on the total weight of the composition, there is a synergistic effect such as anti-corruption, anti-freezing, bactericidal action, detoxification action, microbial removal, odor removal, enhancement of cleaning power, It is produced and precipitates occur, and there is a risk of reducing the freshness and irritating the skin by drawing out moisture on the surface of vegetables and fruits after use.

7.Additional Background and Effect of Caustic Soda

Caustic soda is a highly alkaline white translucent solid with a pH of 14 and is highly deliquescent in air. When dissolved in water, it shows strong heat and generates hydrogen. In addition, the aqueous solution is strongly penetrating and may ignite when dissolved. Soluble in water, methyl alcohol, ethyl alcohol, glycerin. Caustic soda is used as water softener, honeycomb, synthetic fiber, bleach, general detergent, and as an alkali and neutralizer for food production, and as a strong alkali for food additives, sodium salt of food additives, amino acid solution (chemical soy sauce oil) Used for manufacturing. Since caustic soda has excellent dissolution and dispersibility, good expansion and adsorption, and strong penetrating power, it is combined with the cleaning power formed in the above additive group, so it is decomposed and washed to the depth of the cloth (washing) sila during washing with strong adsorption and penetrating power. This is completed, thereby enhancing the cleanliness of the laundry and the synergistic effect of sterilization and odor removal.

Since caustic soda has adsorption, expansion, and strong penetrating power, if it is mixed in excess of 15% by weight based on the total weight of the composition, the washing power is increased, but there is a fear that the cloth of the laundry increases due to the expansion force of caustic soda when washing. Will irritate the skin. In addition, when caustic soda is mixed at less than 5% by weight based on the total weight of the composition, there is no fear of maintaining safety against skin irritation and increasing the size of the laundry.

Hereinafter, the present invention will be described in more detail with reference to the following examples, but the present invention is not limited by the examples.

Preparation Example 1

As shown in Table 1 below, 250 g of sodium bicarbonate, 100 g of palm oil, 300 g of glycerin, 120 g of sodium citrate, 30 g of sodium alginate, and 50 g of sodium chloride were added to 1000 ml of purified water at room temperature. Then, stirring for 3 hours to prepare a composition of the present invention.

Table 1

Ingredient name of the composition	content	Weight ratio	Where to buy raw materials
Purified water	1000 ml	54.05% by weight
Sodium bicarbonate	250 g	13.51 wt%	Daemyung Chemical
Palm oil	100 g	5.41% by weight	Same as above
glycerin	300 g	16.22 wt%	Same as above
Sodium citrate	120 g	6.49 wt%	Same as above
Sodium alginate	30 g	1.62 wt%	Same as above
Sodium chloride	50 g	2.70 wt%	Same as above

In Table 1, the weight ratio of each component contained in the composition was rounded to three decimal places. In addition, each component used what was manufactured by Daemyung Chemical.

Preparation Examples 2 and 3

As shown in Table 2, except for changing the content of the Preparation Example 1 and each component, the composition of the present invention was prepared in the same manner as in Preparation Example 1.

TABLE 2

	Preparation Example 2	Preparation Example 3
Ingredient name of the composition	content	content	Where to buy raw materials
Purified water	1000 ml	1000 ml
Sodium bicarbonate	200 g	300 g	Daemyung Chemical
Palm oil	80 g	120 g	Same as above
glycerin	280 g	320 g	Same as above
Sodium citrate	100 g	140 g	Same as above
Sodium alginate	24 g	32 g	Same as above
Sodium chloride	40 g	60 g	Same as above

Preparation Example 4

As shown in Table 3 below, except that the kind of each component was different from Preparation Example 1, the composition of the present invention was prepared in the same manner as in Preparation Example 1.

TABLE 3

Ingredient name of the composition	content	Weight ratio	Where to buy raw materials
Purified water	1000 ml	54.05% by weight
Sodium Carbonate (Soda Ash)	250 g	13.51 wt%	Daemyung Chemical
olive oil	100 g	5.41% by weight	Same as above
Glycerin Fatty Acid Ester	300 g	16.22 wt%	Same as above
Sodium citrate	120 g	6.49 wt%	Same as above
Sodium alginate	30 g	1.62 wt%	Same as above
Sodium chloride	50 g	2.70 wt%	Same as above

Preparation Example 5

As shown in Table 4, the composition of the present invention was prepared in the same manner as in Preparation Example 1, except for changing the weight ratio of each component of the composition to 1500 ml of purified water.

Table 4

Ingredient name of the composition	content	Weight ratio	Where to buy raw materials
Purified water	1500 ml	63.83 wt%
Sodium bicarbonate	250 g	10.64 wt%	Daemyung Chemical
Palm oil	100 g	4.26 wt%	Same as above
glycerin	300 g	12.77 wt%	Same as above
Sodium citrate	120 g	5.10 wt%	Same as above
Sodium alginate	30 g	1.27 wt%	Same as above
Sodium chloride	50 g	2.13 wt%	Same as above

Experimental Example 1

Lettuce, spinach, cucumber, pepper, grapes, using the composition prepared in Preparation Examples 1 to 5, the washing power and freshness was compared.

Group [A] used the one obtained by adding 6 g of the detergent composition prepared in Preparation Example 1 to 3000 ml of tap water.

Group [B] used the one obtained by adding 6 g of the detergent composition prepared in Preparation Example 2 to 3000 ml of tap water.

[C] group used to add 6 g of the detergent composition prepared in Preparation Example 3 to 3000 ml of tap water,

The group [D] used 6 g of the detergent composition prepared in Preparation Example 4 to 3000 ml of tap water, and the group [E] used 6 g of the detergent composition prepared in Preparation Example 5 to 3000 ml of tap water. It was. As a comparative example, [F] group used 3000 ml of tap water.

In the washing method, 150 g of lettuce, spinach, cucumber, red pepper, and grapes were deposited in the [A] to [F] groups for 5 minutes, respectively. Subsequently, 3000 ml of tap water was used as the rinsing water and the rinsing was done once. After the rinsing, lettuce, spinach, cucumber, pepper, grapes were taken out, placed in a sieve and dried at room temperature for 24 hours while the water was missing.

After drying, 20 housewives with a visual acuity (including corrected visual acuity) of 1.0 or more and 30 to 40 years old were selected, and the comparative evaluation selection time per person was within 5 minutes. The degree of cleanness was relatively evaluated for the fruits of groups [A] to [F], and each individual was asked to select any one of one, two, three, four or five points. As a result, the total housewives selected by 20 housewives, respectively, are shown in Table 5 below.

Table 5

	A	B	C	D	E	F	Total number of people rating
Lettuce	89 points	86 points	90 points	88 points	87 points	67 points	20 (out of 100)
spinach	87 points	86 points	90 points	86 points	85 points	56 points	20 (out of 100)
cucumber	75 points	73 points	82 points	76 points	75 points	70 points	20 (out of 100)
Red pepper	79 points	73 points	80 points	73 points	80 points	62 points	20 (out of 100)
grape	92 points	89 points	96 points	90 points	89 points	74 points	20 (out of 100)

In addition, the lettuce, spinach, cucumber, pepper, grapes washed as described above were further dried in shade of shade at room temperature for an additional 7 days. After completion of drying, the degree of freshness was compared and evaluated for the [A] to [F] groups.

Twenty housewives who participated in the cleaning power evaluation again participated in the evaluation of freshness. The freshness evaluation method also evaluates the freshness of the fruits of groups [A] to [F] relatively, so that each individual can select one, two, three, four or five points. It was. As a result, the total housewives selected by 20 housewives, respectively, are shown in Table 6 below.

Table 6

	A	B	C	D	E	F	Total number of people rating
Lettuce	64 points	65 points	63 points	65 points	67 points	34 points	20 (out of 100)
spinach	59 points	61 points	54 points	64 points	60 points	31 points	20 (out of 100)
cucumber	82 points	79 points	80 points	91 points	82 points	62 points	20 (out of 100)
Red pepper	89 points	90 points	88 points	87 points	93 points	77 points	20 (out of 100)
grape	68 points	67 points	64 points	59 points	69 points	40 points	20 (out of 100)

Preparation Example 6

As shown in Table 7, 250 g of sodium bicarbonate, 100 g of palm oil, 300 g of glycerin, 120 g of sodium citrate, 30 g of sodium alginate, 50 g of sodium chloride, and 150 g of caustic soda were added to 1000 ml of purified water, followed by mixing. , The composition of the present invention was prepared.

TABLE 7

Ingredient name of the composition	content	content	Where to buy raw materials
Purified water	1000 ml	50.00 wt%
Sodium bicarbonate	250 g	12.50 wt%	Daemyung Chemical
Palm oil	100 g	5.00 wt%	Same as above
glycerin	300 g	15.00 wt%	Same as above
Sodium citrate	120 g	6.00 wt%	Same as above
Sodium alginate	30 g	1.50 wt%	Same as above
Sodium chloride	50 g	2.50 wt%	Same as above
Caustic soda	150 g	7.50 wt%	Same as above

In Table 7, the weight ratio of each component contained in the composition was rounded to three decimal places.

In addition, each component used what was manufactured by Daemyung Chemical.

Preparation Examples 7 and 8

As shown in Table 8, except for changing the content of the preparation example 6 and each component, the composition of the present invention was prepared in the same manner as in Preparation Example 6.

Table 8

	Preparation Example 7	Preparation Example 8
Ingredient name of the composition	content	content	Where to buy raw materials
Purified water	1000 ml	1000 ml
Sodium bicarbonate	200 g	300 g	Daemyung Chemical
Palm oil	80 g	120 g	Same as above
glycerin	280 g	320 g	Same as above
Sodium citrate	100 g	140 g	Same as above
Sodium alginate	24 g	32 g	Same as above
Sodium chloride	40 g	60 g	Same as above
Caustic soda	120 g	180 g	Same as above

Preparation Example 9

As shown in Table 9, except that the type of each component was different from Preparation Example 6, the composition of the present invention was prepared in the same manner as in Preparation Example 6.

Table 9

Ingredient name of the composition	content	content	Where to buy raw materials
Purified water	1000 ml	50.00 wt%
Sodium Carbonate (Soda Ash)	250 g	12.50 wt%	Daemyung Chemical
Palm oil	100 g	5.00 wt%	Same as above
Glycerin Fatty Acid Ester	300 g	15.00 wt%	Same as above
Sodium citrate	120 g	6.00 wt%	Same as above
Sodium alginate	30 g	1.50 wt%	Same as above
Sodium chloride	50 g	2.50 wt%	Same as above
Caustic soda	150 g	7.50 wt%	Same as above

Experimental Example 2

As shown in Table 10 below, for five white cotton T-shirts (163 g per piece) and five red cotton T-shirts (163.5 g per piece), using the composition prepared in Preparation Examples 6 to 9 above, washing was performed. Detergent performance was compared.

Table 10

	A	B	C	D	E	Total number of people rating
White Cotton T-Shirt	79 points	78 points	88 points	82 points	56 points	20 (out of 100)
Red cotton T-shirt	84 points	80 points	92 points	82 points	68 points	20 (out of 100)

In Table 10 above,

Group [A] used 35000 ml of tap water to which 90 ml of the detergent composition prepared in Preparation Example 6 was added.

Group [B] used 35000 ml of tap water to which 90 ml of the detergent composition prepared in Preparation Example 7 was added.

Group [C] used to add 90 ml of the detergent composition prepared in Preparation Example 8 to 35000 ml of tap water,

In the group [D], 35000 ml of tap water was added with 90 ml of the detergent composition prepared in Preparation Example 9.

As a comparative example, the [E] group used a solution obtained by adding 90 ml of the detergent composition prepared in Preparation Example 1 to 35000 ml of tap water.

In addition, in order to uniformly and uniformly contaminate the laundry object (five white cotton T-shirts and five red cotton T-shirts), the laundry object was immersed in a contaminant made by the present inventors for 10 minutes to contaminate the laundry object.

The contaminants were mixed with 20000 ml of tap water, 80 g of clay, 40 ml of cooking oil, 30 g of soybean paste, and 30 ml of kimchi broth, and then boiled at a temperature of 100 ° C. or higher for 5 minutes, and then removed from the residue.

The washing method was a Daewoo air washing machine, and the washing water of group [A] was simultaneously put together with the laundry object contaminated in the washing machine, and the washing was finished by 14 minutes of washing, 7 minutes of rinsing, and 7 minutes of dehydration. The rinsing water used 35000 ml of tap water each, and rinsing was done once. This washing was performed similarly to the [B]-[E] groups.

After washing, it was dried in the shade at room temperature for 24 hours.

Thereafter, the evaluation method of the degree of washing of the laundry object was selected by visual acuity (including correction visual acuity) 1.0 or more housewives of 30-40 years old, and the comparative evaluation selection time per person was within 5 minutes, and evaluated visually.

The degree of washing was relatively evaluated for the laundry objects in groups [A] to [E], and each individual was allowed to select one of two points, two points, three points, four points, or five points.

As a result, the total housewives selected by 20 housewives, respectively, are shown in Table 10 above.

As shown in Table 10, the washing power of the [A] to [D] group is superior to the [E] group, sodium bicarbonate or sodium carbonate, palm oil, palm oil or olive oil, glycerin or glycerin fatty acid ester, sodium citrate or citric acid, Caustic soda added in addition to sodium alginate or sodium fibrin glycoate and sodium chloride further increases the washing power, indicating that washing is excellent.

Experimental Example 3

For the composition of the present invention prepared in Preparation Example 1, in order to receive the certification for pollution-free and cleaning power, the present inventor commissioned the experiment to the Korea Living Environment Testing Institute.

Sample name: pollution-free dish detergent (composition prepared in Preparation Example 1)

Examination Date: September 11, 2008

Applicant: Kim Young-bae

Address: Korea Living Environment Research Institute [International Certified]

As a result of the present inventor requesting test analysis of the composition prepared in Preparation Example 1 of the present invention to the Korea Living Environment Testing Institute, the following results were obtained.

Heavy metal (Pb) content: conforms to the standards of 1.0 mg / L or less

Detergency: Equivalent to surface detergent

Test Method: KS M 2716: 2006

Exam completion date: September 19, 2008

Date of issue of test results: September 19, 2008

As seen above, the vegetable, fruit, tableware, kitchen utensils, baby products or composition for washing the human body of the present invention is only an amount of less than 1.0 mg / L of the content of heavy metal (Pb) harmful to the human body suitable for the standard Thus, it was proved that not only did not adversely affect the environment, but also the cleaning power did not drop at all as compared to detergents commercially available, but rather had an equivalent effect.

First, as described above, the present invention excludes all raw materials of petrochemical surfactants and harmful chemicals, which are used as main ingredients and auxiliaries in the prior art, and replaced with eco-friendly raw materials of natural food additives that are safe for hygiene and edible use. Therefore, it has the effect of contributing to the improvement of public health and health.

Secondly, the group of additives used in the present invention, as described above, has excellent cleaning power, as well as no bubbles, well dissolved in water, high biodegradability, and no residue. In addition, it has the effect of purifying domestic sewage with the characteristic of changing insoluble pollutants to water solubility and neutralizing odor molecules. Therefore, since domestic sewage, which occupies 70% of total household sewage, is purified and discharged from each household, the amount of domestic sewage at the Sewage Sewage Treatment Plant is also reduced, reducing the use of chemicals (purifiers) used for domestic sewage treatment. This has the effect of reducing the cost of water purification treatment in the country.

Third, the components contained in the detergent composition of the present invention is a non-toxic environment-friendly pollution-free material, when washing and washing, there is no foam, soluble in water, there is no dregs. In addition, since the sewage is purified and discharged with the ability to change insoluble pollutants into water-soluble and neutralize odor molecules, there is no effect of the smell of sewage pipes.

In addition, the composition of the present invention has the effect of removing the microorganisms, dust, pesticides, waxes, heavy metals and the like on strawberries, peaches, grapes, plums and fruits and carrots, potatoes, cucumbers, pumpkins, vegetables and the like.

In addition, the present invention can be used for washing the human body because it is hygienically safe even if residual components remain,

For example, it can also be used in wet wipes or body cleansers.

In addition, since the washing is completed with one washing, one washing and one rinsing water, about 30-40% of water is saved compared to the domestic sewage discharged by the water required to rinse two or more times in the prior art. Reduction of household sewage emissions by each household has the effect of reducing the public's water use charges.

Fourth, the present invention is clean, odor-free washing is completed even without boiled with excellent cleaning power and strong sterilizing power for baby products, infant bottles, diapers, white laundry and the like. Therefore, there is an effect of reducing the time and cost required for washing and washing.

Claims

(A) 7-25% by weight of at least one of sodium bicarbonate or sodium carbonate;

(B) 2-15% by weight of at least one of palm oil, palm oil or olive oil;

(C) 3-20% by weight of at least one of glycerin or glycerin fatty acid ester;

(D) 2-15% by weight of at least one of sodium citrate or citric acid;

(E) 1-10% by weight of at least one of sodium alginate or sodium cellulose glycoate;

(F) 0.5-10% by weight sodium chloride; And

(G) contains the residual amount of purified water,

Vegetable, fruit, tableware, kitchen utensils, infants, characterized in that the mixing ratio of at least one of (B) palm oil, palm oil or olive oil, and at least one of (C) glycerin or glycerin fatty acid ester Supplies or detergent compositions for human body cleaning.
The method of claim 1,

The content of at least one of (A) sodium bicarbonate or sodium carbonate is 10-20% by weight, vegetable, fruit, tableware, kitchen utensils, baby products or detergent composition for washing the human body.
The method of claim 1,

(B) at least one content of palm oil, palm oil or olive oil is characterized in that 2-10% by weight, vegetable, fruit, tableware, kitchen utensils, baby products or detergent composition for washing the human body.
The method of claim 1,

(C) the content of at least one of glycerin or glycerin fatty acid ester is 3-15% by weight, vegetable, fruit, tableware, kitchen utensils, baby products or detergent composition for human washing.
The method of claim 1,

(D) the content of at least one of sodium citrate or citric acid is 3-10% by weight, vegetable, fruit, tableware, kitchen utensils, baby products or detergent composition for washing the human body.
The method of claim 1,

The content of at least one of (E) sodium alginate or sodium cellulose glycoate is 1-5% by weight, vegetable, fruit, tableware, kitchen utensils, baby products or detergent composition for washing the human body.
The method of claim 1,

The content of sodium chloride (F) is 1-5% by weight, vegetable, fruit, tableware, kitchen utensils, baby products or detergent composition for washing the human body.
(A) 7-20% by weight of at least one of sodium bicarbonate or sodium carbonate;

(B) 2-10% by weight of at least one of palm oil, palm oil or olive oil;

(C) 3-20% by weight of at least one of glycerin or glycerin fatty acid ester;

(D) 2-15% by weight of at least one of sodium citrate or citric acid;

(E) 1-5% by weight of at least one of sodium alginate or sodium cellulose glycoate;

(F) 0.5-10% by weight sodium chloride;

(G) 5-15% by weight caustic soda; And

(H) contains the residual amount of purified water,

The mixing ratio of one or more of the (B) palm oil, palm oil or olive oil and one or more of the (C) glycerin or glycerin fatty acid ester is 1: 3, laundry detergent composition for laundry.
The method of claim 8,

The detergent composition for laundry, characterized in that the content of at least one of (A) sodium bicarbonate or sodium carbonate is 10-20% by weight.
9. The laundry detergent composition of claim 8, wherein the content of at least one of (B) palm oil, palm oil or olive oil is 2-7% by weight.
The method of claim 8,

(C) the content of at least one of glycerin or glycerin fatty acid ester is 3-15% by weight, laundry detergent composition.
The method of claim 8,

(D) at least one content of sodium citrate or citric acid is 3-10% by weight, laundry detergent composition.
The method of claim 8,

The detergent composition for laundry, characterized in that the content of at least one of (E) sodium alginate or sodium cellulose glycoate is 1-3% by weight.
The method of claim 8,

The detergent composition for laundry, characterized in that (F) the content of sodium chloride is 1-5% by weight.
The method of claim 8,

(G) the content of caustic soda is characterized in that 5-10% by weight, laundry detergent composition.