KR100346932B1 - 고활성폴리에틸렌촉매 - Google Patents

고활성폴리에틸렌촉매 Download PDF

Info

Publication number
KR100346932B1
KR100346932B1 KR1019960705581A KR19960705581A KR100346932B1 KR 100346932 B1 KR100346932 B1 KR 100346932B1 KR 1019960705581 A KR1019960705581 A KR 1019960705581A KR 19960705581 A KR19960705581 A KR 19960705581A KR 100346932 B1 KR100346932 B1 KR 100346932B1
Authority
KR
South Korea
Prior art keywords
silica
catalyst
amount
molar ratio
ethylene
Prior art date
Application number
KR1019960705581A
Other languages
English (en)
Korean (ko)
Other versions
KR970702100A (ko
Inventor
올즈 해거티 로버트
크리스챤 허스비 퍼
빅토로비치 키신 유리
이반 밍크 로버트
에드워드 노울린 토마스
Original Assignee
엑손모빌 오일 코포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 엑손모빌 오일 코포레이션 filed Critical 엑손모빌 오일 코포레이션
Publication of KR970702100A publication Critical patent/KR970702100A/ko
Application granted granted Critical
Publication of KR100346932B1 publication Critical patent/KR100346932B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1019960705581A 1994-06-10 1995-06-05 고활성폴리에틸렌촉매 KR100346932B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/257,997 US5514634A (en) 1991-11-06 1994-06-10 High activity polyethylene catalysts
US08/257,997 1994-06-10
PCT/US1995/007090 WO1995034380A1 (en) 1994-06-10 1995-06-05 High activity polyethylene catalysts

Publications (2)

Publication Number Publication Date
KR970702100A KR970702100A (ko) 1997-05-13
KR100346932B1 true KR100346932B1 (ko) 2002-12-26

Family

ID=22978660

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960705581A KR100346932B1 (ko) 1994-06-10 1995-06-05 고활성폴리에틸렌촉매

Country Status (11)

Country Link
US (1) US5514634A (xx)
EP (1) EP0766599B1 (xx)
JP (1) JPH10502101A (xx)
KR (1) KR100346932B1 (xx)
CN (1) CN1071338C (xx)
AU (1) AU691003B2 (xx)
CA (1) CA2182093C (xx)
DE (1) DE69518324T2 (xx)
ES (1) ES2149994T3 (xx)
WO (1) WO1995034380A1 (xx)
ZA (1) ZA954656B (xx)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050095133A (ko) * 2004-03-25 2005-09-29 차이나 페트로리움 앤드 케미컬 코포레이션 에틸렌 중합용 촉매, 및 그의 제조방법과 용도

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5693583A (en) * 1991-06-10 1997-12-02 Mobil Oil Corporation High activity polyethylene catalysts which produce bimodal or trimodal product molecular weight distributions
US6291384B1 (en) * 1991-11-06 2001-09-18 Mobil Oil Corporation High activity catalyst prepared with alkoxysilanes
US5939348A (en) * 1991-11-06 1999-08-17 Mobil Oil Corporation Catalyst for the manufacture of polythylene with a narrow molecular weight distribution
DE69525679T2 (de) * 1994-05-18 2002-11-07 Mitsubishi Chem Corp Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins
JP3355572B2 (ja) * 1994-08-23 2002-12-09 新日本石油株式会社 オレフィン類重合触媒およびそれを用いたポリオレフィンの製造方法
CN1264393A (zh) * 1997-07-25 2000-08-23 英国石油化学品有限公司 高活性聚乙烯催化剂
EP0924298A1 (en) 1997-12-18 1999-06-23 Stichting Instituut voor Dierhouderij en Diergezondheid (ID-DLO) Protein expression in baculovirus vector expression systems
US6171993B1 (en) * 1998-12-04 2001-01-09 Equistar Chemicals, Lp Enhanced-impact LLDPE with a shear modifiable network structure
EP1035205A1 (en) 1999-03-08 2000-09-13 Stichting Dienst Landbouwkundig Onderzoek Non-spreading pestivirus
AU7431300A (en) * 1999-09-17 2001-04-24 Bp Chemicals Limited Catalyst for polyethylene giving an improved short chain branching distribution
EP1108728A1 (en) * 1999-12-17 2001-06-20 BP Chemicals S.N.C. High activity polyethylene catalysts prepared with alkoxycarbon reagents
EP1336625A1 (en) * 2002-02-14 2003-08-20 Novolen Technology Holdings C.V. Solid catalytic component and catalytic system of the Ziegler-Natta type, process for their preparation and their use in the polymerisation of alk-1-enes
US20040043214A1 (en) * 2002-08-30 2004-03-04 Kimberly-Clark Worldwide, Inc. Method of forming a 3-dimensional fiber and a web formed from such fibers
US20040110442A1 (en) * 2002-08-30 2004-06-10 Hannong Rhim Stretchable nonwoven materials with controlled retraction force and methods of making same
US7226880B2 (en) * 2002-12-31 2007-06-05 Kimberly-Clark Worldwide, Inc. Breathable, extensible films made with two-component single resins
US7932196B2 (en) 2003-08-22 2011-04-26 Kimberly-Clark Worldwide, Inc. Microporous stretch thinned film/nonwoven laminates and limited use or disposable product applications
US6962889B2 (en) * 2004-01-28 2005-11-08 Engelhard Corporation Spherical catalyst for olefin polymerization
ES2605277T3 (es) 2008-08-06 2017-03-13 Union Carbide Chemicals & Plastics Technology Llc Métodos de obtención de composiciones de catalizador de ziegler-natta para producir polietilenos con una cola de alto peso molecular
EP2172490A1 (en) 2008-10-03 2010-04-07 Ineos Europe Limited Controlled polymerisation process
EP2357035A1 (en) 2010-01-13 2011-08-17 Ineos Europe Limited Polymer powder storage and/or transport and/or degassing vessels
EP2383298A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
EP2383301A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
US9394381B2 (en) 2010-11-29 2016-07-19 Ineos Sales (Uk) Limited Polymerisation control process
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
US8796409B2 (en) 2011-10-04 2014-08-05 Exxonmobil Chemical Patents Inc. Use of temperature and ethylene partial pressure to introduce long chain branching in high density polyethylene
SG11201400866RA (en) 2011-10-17 2014-10-30 Ineos Europe Ag Polymer degassing process control
CN105440174B (zh) * 2014-08-15 2017-12-19 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂与应用
US9718907B2 (en) 2015-07-08 2017-08-01 Chevron Phillips Chemical Company Lp Ziegler-Natta—metallocene dual catalyst systems with activator-supports
US9845367B2 (en) 2015-09-24 2017-12-19 Chevron Phillips Chemical Company Lp Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina
US9758599B2 (en) 2015-09-24 2017-09-12 Chevron Phillips Chemical Company Lp Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina
US9540457B1 (en) 2015-09-24 2017-01-10 Chevron Phillips Chemical Company Lp Ziegler-natta—metallocene dual catalyst systems with activator-supports
WO2019162760A1 (en) 2018-02-05 2019-08-29 Exxonmobil Chemical Patents Inc. A Corporation Of State Of Delaware Enhanced processability of lldpe by addition of ultra-high molecular weight high density polyethylene

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4063009A (en) * 1954-01-19 1977-12-13 Studiengesellschaft Kohle M.B.H. Polymerization of ethylenically unsaturated hydrocarbons
US4076698A (en) * 1956-03-01 1978-02-28 E. I. Du Pont De Nemours And Company Hydrocarbon interpolymer compositions
FR2082153A5 (fr) * 1970-03-05 1971-12-10 Solvay Catalyseurs et procede perfectionnes pour la polymerisation et la copolymerisation des olefines
DE2553179A1 (de) * 1975-11-27 1977-06-08 Hoechst Ag Verfahren zur herstellung eines katalysators
NL7702323A (nl) * 1977-03-04 1978-09-06 Stamicarbon Katalysator voor de bereiding van polyalkenen.
US4302566A (en) * 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
US4362648A (en) * 1979-01-15 1982-12-07 Phillips Petroleum Company Polymerization of olefins
US4335016A (en) * 1981-02-23 1982-06-15 Chemplex Company Catalyst and method
US4378304A (en) * 1981-06-03 1983-03-29 Chemplex Company Catalyst and methods
US4458058A (en) * 1981-06-03 1984-07-03 Chemplex Company Polymerization method
US4374753A (en) * 1981-07-29 1983-02-22 Chemplex Company Polymerization catalyst and method
US4481301A (en) * 1981-12-04 1984-11-06 Mobil Oil Corporation Highly active catalyst composition for polymerizing alpha-olefins
BR8704367A (pt) * 1986-08-25 1988-04-19 Toa Nenryo Kogyo Kk Processo para a producao de uma borracha de copolimero de etileno-propileno e borracha de copolimero de etileno-propileno
US4719193A (en) * 1986-09-30 1988-01-12 Union Carbide Corporation Processes for preparing polyethylene catalysts by heating catalyst precursors
JPH0780968B2 (ja) * 1987-09-09 1995-08-30 住友化学工業株式会社 オレフィン重合体の製造法
US5139986A (en) * 1991-08-06 1992-08-18 Mobil Oil Corporation Catalyst composition for production of linear low-density ethylene-hexene copolymers and films thereof
US5470812A (en) * 1991-11-06 1995-11-28 Mobil Oil Corporation High activity polyethylene catalysts prepared with alkoxysilane reagents
US5336652A (en) * 1991-11-06 1994-08-09 Mobil Oil Corporation High activity polyethylene catalysts prepared with alkoxysilane reagents
CA2157491A1 (en) * 1993-03-03 1994-09-15 Bor-Ping Eric Wang Supported catalyst component for ethylene (co)polymerization

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050095133A (ko) * 2004-03-25 2005-09-29 차이나 페트로리움 앤드 케미컬 코포레이션 에틸렌 중합용 촉매, 및 그의 제조방법과 용도

Also Published As

Publication number Publication date
ZA954656B (en) 1996-12-06
US5514634A (en) 1996-05-07
CA2182093A1 (en) 1995-12-21
ES2149994T3 (es) 2000-11-16
EP0766599A4 (en) 1997-09-24
DE69518324T2 (de) 2000-12-14
CN1071338C (zh) 2001-09-19
AU691003B2 (en) 1998-05-07
EP0766599B1 (en) 2000-08-09
EP0766599A1 (en) 1997-04-09
KR970702100A (ko) 1997-05-13
WO1995034380A1 (en) 1995-12-21
JPH10502101A (ja) 1998-02-24
CA2182093C (en) 2005-08-16
DE69518324D1 (de) 2000-09-14
CN1150394A (zh) 1997-05-21
AU2697495A (en) 1996-01-05

Similar Documents

Publication Publication Date Title
KR100346932B1 (ko) 고활성폴리에틸렌촉매
US5550094A (en) Binary cocatalyst compositions for activating heterogeneous polymerization catalysts
KR100296196B1 (ko) 선형저밀도폴리에틸렌(lldpe)수지생성물의제조에사용하기위한촉매조성물
JPH10505622A (ja) 単一の反応器内での広い／２モードのｍｗｄの樹脂の触媒制御
WO1993009147A1 (en) High activity polyethylene catalysts prepared with alkoxysilane reagents
AU723865B2 (en) Ziegler-natta catalyst for ethylene polymerization or copolymerization
EP0998503B1 (en) High activity polyethylene catalysts
WO1998018842A1 (en) Lldpe copolymers
EP0664815B1 (en) Process for preparing a catalyst composition
JP4331262B2 (ja) 狭い分子量分布を持ったポリエチレンの製造用触媒

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20130628

Year of fee payment: 12

FPAY Annual fee payment

Payment date: 20140627

Year of fee payment: 13

EXPY Expiration of term