KR100270499B1 - 0가니켈,2자리인화합물및루이스산존재하의시안화수소화방법 - Google Patents

0가니켈,2자리인화합물및루이스산존재하의시안화수소화방법 Download PDF

Info

Publication number
KR100270499B1
KR100270499B1 KR1019970706561A KR19970706561A KR100270499B1 KR 100270499 B1 KR100270499 B1 KR 100270499B1 KR 1019970706561 A KR1019970706561 A KR 1019970706561A KR 19970706561 A KR19970706561 A KR 19970706561A KR 100270499 B1 KR100270499 B1 KR 100270499B1
Authority
KR
South Korea
Prior art keywords
formula
compound
pentenenitrile
lewis acid
hydrogen cyanide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
KR1019970706561A
Other languages
English (en)
Korean (ko)
Other versions
KR19980703158A (ko
Inventor
앤 아이리사 브레익스
Original Assignee
미리암 디. 메코나헤이
이.아이,듀우판드네모아앤드캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 미리암 디. 메코나헤이, 이.아이,듀우판드네모아앤드캄파니 filed Critical 미리암 디. 메코나헤이
Publication of KR19980703158A publication Critical patent/KR19980703158A/ko
Application granted granted Critical
Publication of KR100270499B1 publication Critical patent/KR100270499B1/ko
Assigned to 인비스타 테크놀러지스 에스.에이 알.엘. reassignment 인비스타 테크놀러지스 에스.에이 알.엘. 권리의 전부이전등록 Assignors: 이 아이 듀폰 디 네모아 앤드 캄파니
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1019970706561A 1995-03-22 1996-03-07 0가니켈,2자리인화합물및루이스산존재하의시안화수소화방법 Expired - Lifetime KR100270499B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/408,250 US5523453A (en) 1995-03-22 1995-03-22 Process for hydrocyanation
US8/408,250 1995-03-22
US08/408,250 1995-03-22

Publications (2)

Publication Number Publication Date
KR19980703158A KR19980703158A (ko) 1998-10-15
KR100270499B1 true KR100270499B1 (ko) 2000-11-01

Family

ID=23615497

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019970706561A Expired - Lifetime KR100270499B1 (ko) 1995-03-22 1996-03-07 0가니켈,2자리인화합물및루이스산존재하의시안화수소화방법

Country Status (13)

Country Link
US (1) US5523453A (https=)
EP (1) EP0815073B1 (https=)
JP (1) JP2911608B2 (https=)
KR (1) KR100270499B1 (https=)
CN (1) CN1069310C (https=)
AT (1) ATE203233T1 (https=)
BR (1) BR9607982A (https=)
CA (1) CA2214009C (https=)
DE (1) DE69613968T2 (https=)
IN (1) IN186815B (https=)
MY (1) MY117595A (https=)
TW (1) TW343962B (https=)
WO (1) WO1996029303A1 (https=)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2177135C (en) * 1993-11-23 2005-04-26 Wilson Tam Processes and catalyst compositions for hydrocyanation of monoolefins
US5693843A (en) * 1995-12-22 1997-12-02 E. I. Du Pont De Nemours And Company Process for hydrocyanation of diolefins and isomerization of nonconjugated 2 alkyl-3-monoalkenenitriles
JP3441605B2 (ja) * 1996-10-30 2003-09-02 高砂香料工業株式会社 新規光学活性ジホスフィン及び該化合物より得られる遷移金属錯体及び該錯体の存在下にて光学活性体を得る方法
US5710344A (en) * 1996-11-08 1998-01-20 E. I. Du Pont De Nemours And Company Process to prepare a linear aldehyde
DE19652273A1 (de) 1996-12-16 1998-06-18 Basf Ag Monoolefinische C¶5¶-Mononitrile, Verfahren zu ihrer Herstellung und ihre Verwendung
US5847191A (en) * 1997-07-29 1998-12-08 E. I. Du Pont De Nemours And Company Process for the hydrocyanation of monoolefins using bidentate phosphite ligands and zero-valent nickel
DE19740180A1 (de) 1997-09-12 1999-03-18 Basf Ag Katalysator, umfassend wenigstens einen Nickel(0)Komplex auf Basis eines Phosphonitliganden und Verfahren zur Herstellung von Nitrilen
DE19825212A1 (de) 1998-06-05 1999-12-09 Basf Ag Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines zweizähnigen Phosphonitliganden und Verfahren zur Herstellung von Nitrilen
DE19827232A1 (de) 1998-06-18 1999-12-23 Basf Ag Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines Phosphinitliganden und Verfahren zur Hydroformylierung und Hydrocyanierung
US6048996A (en) * 1999-08-26 2000-04-11 E. I. Du Pont De Nemours And Company Insoluble promoters for nickel-catalyzed hydrocyanation of monoolefins
US6365322B1 (en) 1999-12-07 2002-04-02 Clariant Finance (Bvi) Limited Photoresist composition for deep UV radiation
FR2803294B1 (fr) * 1999-12-30 2002-02-15 Rhodia Polyamide Intermediates Procede d'hydrocyanation de composes organiques insatures
US6362354B1 (en) 2000-11-17 2002-03-26 E. I. Du Pont De Nemours And Company Phosphonite ligands, catalyst compositions and hydroformylation process utilizing same
US6437192B1 (en) 2000-11-17 2002-08-20 E. I. Du Pont De Nmeours And Company Hydroformylation of conjugated dienes to alkenals using phosphonite ligands
DE10136488A1 (de) * 2001-07-27 2003-02-06 Basf Ag Ni(O) enthaltendes Katalysatorsystem
FR2830530B1 (fr) * 2001-10-08 2004-07-02 Rhodia Polyamide Intermediates Procede de transformation, d'une part, de composes a insaturation ethylenique en nitriles et, d'autre part, de nitriles branches en nitriles lineaires
DE10150286A1 (de) * 2001-10-12 2003-04-17 Basf Ag Phosphinite
AR036636A1 (es) * 2001-10-12 2004-09-22 Basf Ag Fosfonita i, su uso como ligando en complejos de metal de transicion, dichos complejos, procedimiento para la obtencion de estos ultimos, uso de complejos de metal transitorio como catalizador y procedimientos para la adicion de acido cianhidrico a un doble enlace olefinico y para la isomerizacion d
DE10150285A1 (de) * 2001-10-12 2003-04-17 Basf Ag Phosphonite
US6893996B2 (en) 2001-11-26 2005-05-17 Invista North America S.A.R.L. Process for the preparation of a nickel/phosphorous ligand catalyst for olefin hydrocyanation
US6660876B2 (en) 2001-11-26 2003-12-09 E. I. Du Pont De Nemours And Company Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions
AR038161A1 (es) * 2002-01-24 2004-12-29 Basf Ag Procedimiento para separar acidos de mezclas de reaccion quimicas con la ayuda de liquidos ionicos
US6906218B2 (en) 2002-12-18 2005-06-14 Invista North America S.A.R.L. Cyclohexane derivatives and methods for their preparation
FR2849027B1 (fr) * 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
US6936171B2 (en) * 2003-01-08 2005-08-30 Invista North America S.A.R.L. Process for catalyst recovery from hydrocyanation product mixtures
US6897329B2 (en) * 2003-01-14 2005-05-24 Invista North America S.A.R.L. Process for the preparation of nickel/phosphorous ligand catalyst for olefin hydrocyanation
FR2850966B1 (fr) * 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
US6844289B2 (en) * 2003-04-08 2005-01-18 Invista North America S.A.R.L. Process for the preparation of a nickel/phosphorous ligand catalyst
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
FR2854892B1 (fr) * 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates Procede de fabrication de dinitriles
EP2154127A3 (en) 2003-09-11 2010-10-13 Invista Technologies S.à.r.l. Conversion of hydrocyanated unsaturated carboxylic acid derivatives into amines
US7385071B2 (en) * 2003-10-28 2008-06-10 Invista North America S.A.R.L. Hydrocyanation of pentenenitriles and/or 2-methyl-3-butenenitrile using promoters obtained from the chlorination of titanium-rich ores
DE10351003A1 (de) * 2003-10-30 2005-05-25 Basf Ag Verfahren zur Herstellung von Nickel-Phosphorligand-Komplexen
DE10351000A1 (de) * 2003-10-30 2005-06-09 Basf Ag Verfahren zur Herstellung von Nickel(O)-Phosphorligand-Komplexen
DE10350999A1 (de) * 2003-10-30 2005-06-02 Basf Ag Katalysator, umfassend wenigstens einen Nickel(O)Komplex stabilisiert durch einen sterisch anspruchsvollen Chelatphosphinitphosphitliganden, sowie ein Verfahren zur Herstellung von Nitrilen
DE10351002A1 (de) * 2003-10-30 2005-05-25 Basf Ag Einsatz von azeotrop-getrockneten Nickel(II)-halogeniden
US8119829B2 (en) * 2004-09-08 2012-02-21 Invista North America S.A.R.L. Process of hydrocyanation of unsaturated carboxylic acid derivatives
DE102004049339A1 (de) * 2004-10-08 2006-04-13 Basf Ag Verfahren zur Reinigung von phosphorhaltigen Chelat-Liganden
ES2532982T3 (es) * 2005-10-18 2015-04-06 Invista Technologies S.À.R.L. Proceso de preparación de 3-aminopentanonitrilo
WO2007109005A2 (en) * 2006-03-17 2007-09-27 Invista Technologies S.A R.L. Method for the purification of triorganophosphites by treatment with a basic additive
US7880028B2 (en) * 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7709674B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
US7709673B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
EP2146930A2 (en) 2007-05-14 2010-01-27 INVISTA Technologies S.à.r.l. High efficiency reactor and process
WO2008157218A1 (en) * 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Process for improving adiponitrile quality
CN101918356B (zh) * 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
WO2009091771A2 (en) * 2008-01-15 2009-07-23 Invista Technologies S.A R.L Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
US20090240068A1 (en) * 2008-03-19 2009-09-24 Invista North America S.A.R.L. Methods of making cyclododecatriene and methods of making laurolactone
US8247621B2 (en) * 2008-10-14 2012-08-21 Invista North America S.A.R.L. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
CN102471218B (zh) * 2009-08-07 2014-11-05 因温斯特技术公司 用于形成二酯的氢化并酯化
KR20120104252A (ko) 2009-12-18 2012-09-20 인비스타 테크놀러지스 에스.에이.알.엘. 염기성 니켈 카르보네이트로부터 유도된 니켈 착체 및 니켈 금속 조성물
CN103080119B (zh) 2010-09-07 2015-04-08 因温斯特技术公司 用于制备镍金属的镍组合物和镍配合物
FR2980792B1 (fr) * 2011-09-30 2013-09-06 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
US9133223B2 (en) 2011-12-21 2015-09-15 Invista North America S.A.R.L. Extraction solvent control for reducing stable emulsions
KR20150035479A (ko) 2011-12-21 2015-04-06 인비스타 테크놀러지스 에스.에이 알.엘. 안정한 에멀젼을 감소시키기 위한 추출 용매 제어
EP2794047B1 (en) 2011-12-21 2021-04-14 INVISTA Textiles (U.K.) Limited Extraction solvent control for reducing stable emulsions
JP2015512862A (ja) 2011-12-21 2015-04-30 インヴィスタ テクノロジーズ エスアエルエル 安定なエマルジョンを減じるための抽出溶媒制御
US9914700B2 (en) 2014-06-27 2018-03-13 Invista North America S.A R.L. Enhanced extraction of impurities from mixture comprising nitriles
CN107207406B (zh) 2014-06-27 2019-12-03 英威达纺织（英国）有限公司 用增强的液-液萃取制造腈的整合方法
CN117797874B (zh) * 2023-12-27 2026-01-30 上海蓝科石化环保科技股份有限公司 氢氰化催化剂、制备方法及其应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4774353A (en) * 1986-06-05 1988-09-27 E. I. Du Pont De Nemours And Company Triorganotin catalyst promoters for hydrocyanation
WO1993003839A1 (en) * 1991-08-21 1993-03-04 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3496215A (en) * 1965-11-23 1970-02-17 Du Pont Hydrocyanation of olefins using selected nickel phosphite catalysts
GB1112539A (en) * 1965-11-26 1968-05-08 Du Pont Preparation of organic nitriles
US3496217A (en) * 1967-05-23 1970-02-17 Du Pont Hydrocyanation of olefins
US3558688A (en) * 1967-10-26 1971-01-26 Du Pont Preparation of allylic nitriles from allylic esters and hcn in the presence of zero-valent nickel catalysts
NL7002580A (https=) * 1969-03-03 1970-09-07
US3655723A (en) * 1969-10-31 1972-04-11 Du Pont Hydrocyanation of olefins
US3631191A (en) * 1970-04-08 1971-12-28 Du Pont Synthesis of zero valent nickel-tetrakis triaryl phosphite complexes
US3766237A (en) * 1972-01-25 1973-10-16 Du Pont Hydrocyanation of olefins
US3847959A (en) * 1972-10-25 1974-11-12 Du Pont Process of preparing a zerovalent nickel complex with organic phosphorus compounds
US3846461A (en) * 1972-10-25 1974-11-05 Du Pont Process of preparing a zerovalent nickel complex with organic phosphorus compounds
US3903120A (en) * 1973-06-19 1975-09-02 Du Pont Preparation of zerovalent nickel complexes from elemental nickel
US4874884A (en) * 1988-03-31 1989-10-17 E. I. Du Pont De Nemours And Company Promoter synergism in pentenenitrile hydrocyanation
US5175335A (en) * 1991-11-12 1992-12-29 E. I. Du Pont De Nemours And Company Enantioselective hydrocyanation of aromatic vinyl compounds

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4774353A (en) * 1986-06-05 1988-09-27 E. I. Du Pont De Nemours And Company Triorganotin catalyst promoters for hydrocyanation
WO1993003839A1 (en) * 1991-08-21 1993-03-04 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses

Also Published As

Publication number Publication date
CN1179147A (zh) 1998-04-15
US5523453A (en) 1996-06-04
BR9607982A (pt) 1998-06-23
CN1069310C (zh) 2001-08-08
ATE203233T1 (de) 2001-08-15
CA2214009C (en) 2004-02-24
CA2214009A1 (en) 1996-09-26
JPH10505101A (ja) 1998-05-19
WO1996029303A1 (en) 1996-09-26
JP2911608B2 (ja) 1999-06-23
TW343962B (en) 1998-11-01
DE69613968D1 (de) 2001-08-23
EP0815073B1 (en) 2001-07-18
DE69613968T2 (de) 2002-04-04
IN186815B (https=) 2001-11-17
KR19980703158A (ko) 1998-10-15
MY117595A (en) 2004-07-31
EP0815073A1 (en) 1998-01-07

Similar Documents

Publication Publication Date Title
KR100270499B1 (ko) 0가니켈,2자리인화합물및루이스산존재하의시안화수소화방법
EP0757672B1 (en) Monodentate phosphite and nickel catalyst composition for monoolefin hydrocyanation
US5512695A (en) Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins
EP0730574B1 (en) Processes and catalyst compositions for hydrocyanation of monoolefins
EP1000019B1 (en) Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions therefor
EP0755302B1 (en) Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins
EP0784610B1 (en) Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
US5512696A (en) Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
US5847191A (en) Process for the hydrocyanation of monoolefins using bidentate phosphite ligands and zero-valent nickel
EP2044007B1 (en) Process for making 3-pentenenitrile by hydrocyanation of butadiene
EP1214289B1 (en) Multidentate phosphite ligands and their use in catalytic compositions for hydrocyanation processes
KR20060107797A (ko) 입체 장애형 킬레이트 포스피나이트-포스파이트 리간드,상기 리간드에 의해 안정화된 1종 이상의 니켈(０) 착체를포함하는 촉매, 및 니트릴의 제조 방법
HK1025950B (en) Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions therefor

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 19970920

Patent event code: PA01051R01D

Comment text: International Patent Application

A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 19971230

Comment text: Request for Examination of Application

PG1501 Laying open of application
E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20000127

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20000629

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20000802

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20000803

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20030723

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee

Payment date: 20040723

Start annual number: 5

End annual number: 5

PR1001 Payment of annual fee

Payment date: 20050722

Start annual number: 6

End annual number: 6

PR1001 Payment of annual fee

Payment date: 20060725

Start annual number: 7

End annual number: 7

PR1001 Payment of annual fee

Payment date: 20070723

Start annual number: 8

End annual number: 8

PR1001 Payment of annual fee

Payment date: 20080721

Start annual number: 9

End annual number: 9

PR1001 Payment of annual fee

Payment date: 20090724

Start annual number: 10

End annual number: 10

PR1001 Payment of annual fee

Payment date: 20100729

Start annual number: 11

End annual number: 11

PR1001 Payment of annual fee

Payment date: 20110718

Start annual number: 12

End annual number: 12

FPAY Annual fee payment

Payment date: 20120727

Year of fee payment: 13

PR1001 Payment of annual fee

Payment date: 20120727

Start annual number: 13

End annual number: 13

FPAY Annual fee payment

Payment date: 20130723

Year of fee payment: 14

PR1001 Payment of annual fee

Payment date: 20130723

Start annual number: 14

End annual number: 14

FPAY Annual fee payment

Payment date: 20140722

Year of fee payment: 15

PR1001 Payment of annual fee

Payment date: 20140722

Start annual number: 15

End annual number: 15

FPAY Annual fee payment

Payment date: 20150716

Year of fee payment: 16

PR1001 Payment of annual fee

Payment date: 20150716

Start annual number: 16

End annual number: 16

EXPY Expiration of term
PC1801 Expiration of term

Termination date: 20160907

Termination category: Expiration of duration