KR100265359B1 - A method for forming storage node in semiconductor memory device - Google Patents
A method for forming storage node in semiconductor memory device Download PDFInfo
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- 239000010703 silicon Substances 0.000 abstract description 5
- 125000006850 spacer group Chemical group 0.000 abstract description 5
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 230000000873 masking effect Effects 0.000 abstract 1
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- 239000011229 interlayer Substances 0.000 description 5
- 229920002120 photoresistant polymer Polymers 0.000 description 4
- 239000003990 capacitor Substances 0.000 description 3
- 238000001312 dry etching Methods 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 2
- 239000005380 borophosphosilicate glass Substances 0.000 description 2
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- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/30—DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
- H10B12/31—DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells having a storage electrode stacked over the transistor
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- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
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- H01L21/3105—After-treatment
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- H01L21/76802—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/01—Manufacture or treatment
- H10B12/02—Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
- H10B12/03—Making the capacitor or connections thereto
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Abstract
Description
본 발명은 반도체 제조 기술에 관한 것으로, 특히 반도체 메모리 소자의 캐패시터 하부전극인 전하저장 전극 형성 공정에 관한 것이다.BACKGROUND OF THE
반도체 메모리 소자의 집적도가 증가함에 따라 소자의 리프레시(refresh) 특성이 큰 문제로 부각되었으며, 이를 해결하는 하나의 방안으로서 캐패시터의 하부 전극인 전하저장 전극의 높이 증가를 통한 표면적 확보를 통해 정전용량을 증가시키는 기술에 대한 많은 연구·개발이 진행되어 왔다.As the degree of integration of semiconductor memory devices has increased, the refresh characteristics of the devices have emerged as a big problem. As a solution to this problem, the capacitance is increased by securing the surface area by increasing the height of the charge storage electrode, which is the lower electrode of the capacitor. Much research and development has been conducted on increasing technology.
그러나, 이러한 전하저장 전극 높이의 증가는 전하저장 전극이 있는 지역(셀 지역)과 없는 지역(주변회로 지역)간의 단차를 만들어, 후속 금속배선 형성 공정에서 브리지(bridge)를 유발하는 원인으로 작용하며, 이러한 브리지는 소자의 신뢰도 및 수율을 저하시키는 요인이 된다. 때문에, 전하저장 전극의 높이를 증가시켜 정전용량을 확보하는데는 한계가 있다.However, this increase in charge storage electrode height creates a step between the region where the charge storage electrode is located (cell region) and the region where there is no (circuit circuit region), which causes a bridge in subsequent metallization process. This bridge becomes a factor of lowering the reliability and yield of the device. Therefore, there is a limit in securing the capacitance by increasing the height of the charge storage electrode.
본 발명은 단차 유발을 억제하면서 그 표면적을 증가시킬 수 있는 반도체 메모리 소자의 전하저장 전극 형성방법을 제공하는데 그 목적이 있다.SUMMARY OF THE INVENTION An object of the present invention is to provide a method for forming a charge storage electrode of a semiconductor memory device which can increase the surface area while suppressing step generation.
도 1a 내지 도 1e는 본 발명의 일 실시예에 따른 전하저장 전극 형성 공정도.1A to 1E are diagrams illustrating a process of forming a charge storage electrode according to an exemplary embodiment of the present invention.
도 2a는 도 1c의 주사전자현미경(SEM) 사진.Figure 2a is a scanning electron microscope (SEM) picture of Figure 1c.
도 2b는 도 1d의 주사전자현미경(SEM) 사진.Figure 2b is a scanning electron microscope (SEM) picture of Figure 1d.
* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings
10 : 실리콘 기판 11 : 게이트 산화막10
12 : 게이트 전극 13 : 마스크 산화막12
14 : 스페이서 산화막 15 : 층간절연막14
16 : 산화막 17 : 포토레지스트 패턴16
18 : 전하저장 전극18: charge storage electrode
상기의 기술적 과제를 달성하기 위한 본 발명의 반도체 메모리 소자의 전하저장 전극 형성방법은, 반도체 기판 상에 게이트 절연막과, 그 상부 및 측벽이 절연된 게이트 전극을 형성하는 제1 단계; 상기 제1 단계를 마친 전체 구조 상부에 불순물을 포함하는 제1 산화막 및 불순물을 포함하지 않은 제2 산화막을 차례로 형성하는 제2 단계; 상기 제2 산화막 및 상기 제1 산화막을 선택 식각하여 전하저장 전극 콘택홀을 형성하되, 적어도 상기 제2 산화막의 식각 프로파일이 포지티브 경사를 이루도록 하는 제3 단계: 상기 제1 및 제2 산화막의 식각 선택비를 이용하여 상기 제2 산화막의 등방성 식각을 실시하되, 상기 제2 산화막 하부에 언더컷 영역이 형성되도록 하는 제4 단계; 및 상기 제4 단계를 마친 전체 구조 표면을 따라 전하저장 전극용 전도막을 형성하는 제5 단계를 포함하여 이루어진다.According to an aspect of the present invention, there is provided a method of forming a charge storage electrode of a semiconductor memory device, the method including: forming a gate insulating film and a gate electrode having an upper sidewall and an insulating side thereof formed on a semiconductor substrate; A second step of sequentially forming a first oxide film including an impurity and a second oxide film not including an impurity on the entire structure after the first step; Selecting and etching the second oxide layer and the first oxide layer to form a charge storage electrode contact hole, wherein at least an etching profile of the second oxide layer forms a positive slope: etching selection of the first and second oxide layers Performing an isotropic etching of the second oxide film using a ratio, wherein an undercut region is formed under the second oxide film; And a fifth step of forming a conductive film for a charge storage electrode along the entire structure surface of the fourth step.
이하, 본 발명이 속한 기술분야에서 통상의 지식을 가진 자가 본 발명을 보다 용이하게 실시할 수 있도록 하기 위하여 본 발명의 바람직한 실시예를 소개하기로 한다.Hereinafter, preferred embodiments of the present invention will be introduced in order to enable those skilled in the art to more easily carry out the present invention.
첨부된 도면 도 1a 내지 도 1e는 본 발명의 일 실시예에 따른 전하저장 전극 형성 공정을 도시한 것으로, 이하 이를 참조하여 설명한다.1A to 1E illustrate a process of forming a charge storage electrode according to an exemplary embodiment of the present invention, which will be described below with reference to the drawings.
본 실시예에 따른 전하저장 전극 형성 공정은, 우선 도 1a에 도시된 바와 같이 실리콘 기판(10) 상에 게이트 산화막(11)과, 스페이서 절연막(14) 및 마스크 산화막(13)으로 절연된 게이트 전극(12)을 형성한다. 이때, 스페이서 절연막(14) 및 마스크 산화막(13)으로는 TEOS(TetraEthylOthoSilicate)계 산화막, LTO(Low Temperature Oxide), MTO(Medium Temperature Oxide), HTO(High Temperature Oxide) 등의 비도핑 산화막(undoped oxide)을 사용하며, 그 형성 공정은 통상적인 방식에 따른다.In the process of forming a charge storage electrode according to the present embodiment, first, as shown in FIG. 1A, a gate electrode insulated from the
다음으로, 도 1b에 도시된 바와 같이 소정의 층간절연막(15) 및 산화막(16)을 차례로 증착하고, 그 상부에 전하저장 전극 콘택홀 형성을 위한 포토레지스트 패턴(17)을 형성한다. 이때 층간절연막(15)으로 BSG(Boro Silicate Glass)막, PSG(Phospho Silicate Glass)막, BPSG(BoroPhospho Silicate Glass)막 등의 도핑 산화막(doped oxide)을 사용하며, 산화막(16)으로서 비도핑 산화막을 사용한다.Next, as shown in FIG. 1B, a predetermined
계속하여, 도 1c에 도시된 바와 같이 포토레지스트 패턴(17)을 식각 장벽으로 하여 산화막(16) 및 층간절연막(15)을 건식 식각함으로써 일차적인 전하저장 전극 콘택홀을 형성하고, 포토레지스트 패턴(17)을 제거한다.Subsequently, as shown in FIG. 1C, dry etching of the
이때, 건식 식각은 하부의 게이트 전극(12)과 콘택간의 단락(short)을 방지할 수 있도록 콘택홀과 게이트 전극(12)과의 중첩 정확도(overlay accuracy)까지 고려하여 최종적인 CD(Critical Dimension)가 작아지도록 즉, DICD(Develop Inspection Critical Dimension)와 FICD(Final Inspection Critical Dimension)의 비가 2 : 1 이상이 되도록 경사 정도를 크게 한다.In this case, dry etching may be performed in consideration of an overlay accuracy between the contact hole and the
이러한 경사 식각 방식의 세부 공정 조건을 살펴보면, 가열 실리콘 루프(heated silicon roof)가 장착된 ICP(Induced coupled plasma) 방식의 고밀도 플라즈마 방식의 건식 식각 챔버를 사용하며, C3F8가스 및 CO 가스를 사용하되, 총 가스유량을 30∼150 sccm으로 하고, C3F8가스와 CO 가스의 유량비를 1 : 0.5∼5로 한다. 여기서 C3F8가스는 CF4, CHF3, CH3F, C2F6, C3F8, C4F8, CH2F2가스 등의 CF 계열 가스로 대체하여 사용할 수 있다. 또한 220℃∼290℃ 범위의 실리콘 루프 온도와, 1600 W∼2800 W 범위의 ICP RF 전력 및 600 W∼1800 W 범위의 바이어스(bias) RF 전력을 사용한다. 또한, 경사 식각은 NF3가스와 같이 F기를 포함하는 가스를 주 반응 가스로 하는 플라즈마 식각 방식을 사용할 수도 있으며, NH3가스를 주 반응 가스로 하는 플라즈마 식각 방식을 사용할 수도 있다. 도 2a에 경사 식각 후의 전자 현미경 사진을 도시하였다.The detailed process conditions of the inclined etching method include a dry etch chamber of a high density plasma method of an induced coupled plasma (ICP) method equipped with a heated silicon roof, and a C 3 F 8 gas and a CO gas. The total gas flow rate is 30 to 150 sccm, and the flow rate ratio of C 3 F 8 gas and CO gas is 1: 0.5 to 5. The C 3 F 8 gas may be replaced with CF-based gas such as CF 4 , CHF 3 , CH 3 F, C 2 F 6 , C 3 F 8 , C 4 F 8 , CH 2 F 2 gas. Silicon loop temperatures in the range 220 ° C. to 290 ° C., ICP RF power in the 1600 W to 2800 W range and bias RF power in the 600 W to 1800 W range are also used. In addition, the gradient etching may use a plasma etching method using a gas containing F group as a main reaction gas, such as NF 3 gas, or may use a plasma etching method using NH 3 gas as a main reaction gas. 2A shows an electron micrograph after oblique etching.
이어서, 도 1d에 도시된 바와 같이 산화막(16), 마스크 산화막(13) 및 스페이서 절연막(14)에 대한 층간절연막(10)의 높은 식각 선택비를 갖는 등방성 식각 공정을 실시한다. 이때 등방성 식각은 인산(H3PO4)을 주 식각제로 하고, NH4OH와 과수 및 순수의 혼합비를 적절히 조절하여 사용할 수 있다. 그리고 통상적인 건식 식각 및 습식 세정 공정을 진행할 수도 있다. 도 2b에 등방성 식각 후의 전자 현미경 사진을 도시하였다.Next, as shown in FIG. 1D, an isotropic etching process having a high etching selectivity of the
다음으로, 도 1e에 도시된 바와 같이 폴리실리콘막, 금속산화물 등의 전도막을 증착하고, 전하저장 전극 형성을 위한 마스크를 사용하여 전도막을 선택 식각함으로써 전하저장 전극(18)을 디파인한다.Next, as illustrated in FIG. 1E, a conductive film such as a polysilicon film or a metal oxide is deposited, and the
상기한 실시예에 나타난 바와 같이 본 발명은 경사 식각 공정 및 도핑 산화막과 및 비도핑 산화막의 높은 식각 선택비를 갖는 등방성 식각 공정을 실시하여 자기정렬 콘택을 이루며, 전하저장 전극에 의한 단차를 높이지 않으면서 충분한 전하저장 전극의 표면적을 확보할 수 있다.As shown in the above embodiment, the present invention forms a self-aligned contact by performing an inclined etching process and an isotropic etching process having a high etching selectivity of the doped oxide film and the undoped oxide film, thereby increasing the step by the charge storage electrode. It is possible to secure a sufficient surface area of the charge storage electrode without.
이상에서 설명한 본 발명은 전술한 실시예 및 첨부된 도면에 의해 한정되는 것이 아니고, 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 여러 가지 치환, 변형 및 변경이 가능하다는 것이 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자에게 있어 명백할 것이다.The present invention described above is not limited to the above-described embodiments and the accompanying drawings, and various substitutions, modifications, and changes can be made in the art without departing from the technical spirit of the present invention. It will be apparent to those of ordinary knowledge.
상기한 바와 같이 본 발명은 비교적 간단한 공정을 통해 단차를 유발하지 않으면서 큰 정전용량을 가지는 캐패시터를 제조할 수 있으며, 통상적으로 사용되는 질화막 식각장벽을 이용한 자기 정렬 콘택홀 공정보다 용이하게 자기 정렬 효과를 얻을 수 있다.As described above, the present invention can manufacture a capacitor having a large capacitance without causing a step through a relatively simple process, and the self-aligning effect is easier than a self-aligned contact hole process using a nitride film etching barrier that is commonly used. Can be obtained.
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KR100507863B1 (en) * | 1998-06-30 | 2005-11-16 | 주식회사 하이닉스반도체 | Method for forming contact hole in semiconductor device |
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JP4070919B2 (en) * | 1999-01-22 | 2008-04-02 | 富士通株式会社 | Semiconductor device and manufacturing method thereof |
KR100403328B1 (en) * | 1999-11-03 | 2003-10-30 | 주식회사 하이닉스반도체 | Forming method for self aligned contact of semiconductor device |
KR100604555B1 (en) * | 2001-06-21 | 2006-07-28 | 주식회사 하이닉스반도체 | Method of forming a capacitor in a semiconductor device |
KR100603929B1 (en) * | 2002-03-04 | 2006-07-24 | 삼성전자주식회사 | Cylindrical capacitors having a stepped sidewall and methods for fabricating the same |
KR100753122B1 (en) * | 2002-06-29 | 2007-08-29 | 주식회사 하이닉스반도체 | Method for fabricating capacitor in semiconductor device |
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JPH03174767A (en) * | 1989-09-13 | 1991-07-29 | Oki Electric Ind Co Ltd | Manufacture of semiconductor memory device |
JPH05283643A (en) * | 1992-03-31 | 1993-10-29 | Sanyo Electric Co Ltd | Manufacture of semiconductor element |
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JPH03174767A (en) * | 1989-09-13 | 1991-07-29 | Oki Electric Ind Co Ltd | Manufacture of semiconductor memory device |
JPH05283643A (en) * | 1992-03-31 | 1993-10-29 | Sanyo Electric Co Ltd | Manufacture of semiconductor element |
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