KR100222119B1 - 감마,델타-에폭시부텐으로부터 2,5-디하이드로푸란을 제조하는 연속공정 - Google Patents

감마,델타-에폭시부텐으로부터 2,5-디하이드로푸란을 제조하는 연속공정 Download PDF

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Publication number
KR100222119B1
KR100222119B1 KR1019940701687A KR19940701687A KR100222119B1 KR 100222119 B1 KR100222119 B1 KR 100222119B1 KR 1019940701687 A KR1019940701687 A KR 1019940701687A KR 19940701687 A KR19940701687 A KR 19940701687A KR 100222119 B1 KR100222119 B1 KR 100222119B1
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South Korea
Prior art keywords
iodide
reaction zone
alkyl
dihydrofuran
compounds
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KR1019940701687A
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English (en)
Korean (ko)
Inventor
제럴드 웨인 필립스
스테펀 닐 폴링
스테펀 알렌 굿러스키
존 로버트 모니어
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그윈넬 해리 제이
이스트만 케미칼 컴퍼니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/28—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B01J31/0268—Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Catalysts (AREA)
  • Saccharide Compounds (AREA)
  • Epoxy Compounds (AREA)
  • Epoxy Resins (AREA)
KR1019940701687A 1991-11-19 1992-11-09 감마,델타-에폭시부텐으로부터 2,5-디하이드로푸란을 제조하는 연속공정 Expired - Fee Related KR100222119B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US74840891A 1991-11-19 1991-11-19
US748408 1991-11-19
US07/962,545 US5315019A (en) 1991-11-19 1992-10-19 Continuous process for the manufacture of 2,5-dihydrofurans from γ, δ-epoxybutenes
PCT/US1992/009676 WO1993010111A1 (en) 1991-11-19 1992-11-09 CONTINUOUS PROCESS FOR THE MANUFACTURE OF 2,5-DIHYDROFURANS FROM η,δ-EPOXYBUTENES
US962545 1997-10-31

Publications (1)

Publication Number Publication Date
KR100222119B1 true KR100222119B1 (ko) 1999-10-01

Family

ID=27114936

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940701687A Expired - Fee Related KR100222119B1 (ko) 1991-11-19 1992-11-09 감마,델타-에폭시부텐으로부터 2,5-디하이드로푸란을 제조하는 연속공정

Country Status (16)

Country Link
US (1) US5315019A (https=)
EP (1) EP0624157B1 (https=)
JP (1) JP3184527B2 (https=)
KR (1) KR100222119B1 (https=)
CN (1) CN1050837C (https=)
AT (1) ATE149492T1 (https=)
AU (1) AU665502B2 (https=)
BR (1) BR9206778A (https=)
CA (1) CA2122455C (https=)
DE (1) DE69217999T2 (https=)
DK (1) DK0624157T3 (https=)
ES (1) ES2098562T3 (https=)
GR (1) GR3022904T3 (https=)
MY (1) MY108257A (https=)
TW (1) TW275627B (https=)
WO (1) WO1993010111A1 (https=)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2119392T3 (es) * 1994-01-18 1998-10-01 Eastman Chem Co Polimeros polieter derivados de 3,4-epoxi-1-buteno.
DE4422671A1 (de) 1994-06-30 1996-01-04 Basf Ag Verfahren zur Herstellung von 2,5-Dihydrofuran
DE4424219A1 (de) 1994-07-09 1996-01-11 Basf Ag Verfahren zur Herstellung von 2,5-Dihydrofuran
US5466832A (en) * 1995-02-13 1995-11-14 Eastman Chemical Company Process for the manufacture of 2,5-dihydrofurans from γ, δ-epoxybutenes
US5591874A (en) * 1995-09-29 1997-01-07 Eastman Chemical Company Process for the preparation of 2,5-dihydrofuran compounds
DE19539331A1 (de) * 1995-10-23 1997-04-24 Basf Ag Verfahren zur Abtrennung von oligomeren Nebenprodukten von einem Isomerisierungskatalysator
US5681969A (en) * 1996-05-03 1997-10-28 Eastman Chemical Company Continuous process for the conversion of 2,5-dihydrofuran to 2,3-dihydrofuran
US5693833A (en) * 1996-08-26 1997-12-02 Eastman Chemical Company Process for the reactivation of iodine-containing catalysts
WO1998037110A1 (en) * 1997-02-25 1998-08-27 Eastman Chemical Company Polymers containing functionalized olefin monomers
US6335455B1 (en) * 1998-01-12 2002-01-01 Eastman Chemical Company Process for the production of 2,5-dihydrofuran
US5986141A (en) * 1998-09-29 1999-11-16 Eastman Chemical Company Process for the production of cyclopropanemethylamine
US6472491B1 (en) 2000-10-05 2002-10-29 Eastman Chemical Company Process for preparing ethylene interpolymers and ethylene interpolymers
US6608156B1 (en) 2000-10-05 2003-08-19 Eastman Chemical Company Process for preparing interpolymers of ethylene and 2,3-dihydrofuran, or a heteroatom substituted olefin monomer and ethylene interpolymers
US6353140B1 (en) 2000-10-19 2002-03-05 Eastman Chemical Company Process for the purification of cyclopropanecarboxaldehyde
US7001369B2 (en) * 2003-03-27 2006-02-21 Scimed Life Systems, Inc. Medical device
US8404872B2 (en) * 2006-03-17 2013-03-26 Cornell University Production of 2,5-dihydrofurans and analogous compounds

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3812158A (en) * 1970-12-17 1974-05-21 Petro Tex Chem Corp Preparation of dihydrofuran from 3,4-epoxy-1-butene,3,4-dihydroxy-1-butene,or 1,4-dihydroxy-2-butene
US3932468A (en) * 1974-02-08 1976-01-13 Chevron Research Company Dihydrofuran preparation
US3996248A (en) * 1975-11-17 1976-12-07 Chevron Research Company Preparation of 2,5-dihydrofurans from butadiene monoxides
DE3926147A1 (de) * 1989-08-08 1991-02-14 Basf Ag Verfahren zur herstellung von 2,5-dihydrofuranen
US5082956A (en) * 1990-03-08 1992-01-21 Eastman Kodak Company Isomerization of epoxyalkenes to 2,5-dihydrofurans

Also Published As

Publication number Publication date
EP0624157B1 (en) 1997-03-05
CN1073435A (zh) 1993-06-23
TW275627B (https=) 1996-05-11
DE69217999D1 (de) 1997-04-10
GR3022904T3 (en) 1997-06-30
CN1050837C (zh) 2000-03-29
JP3184527B2 (ja) 2001-07-09
DK0624157T3 (da) 1997-09-15
MY108257A (en) 1996-08-30
CA2122455A1 (en) 1993-05-27
ATE149492T1 (de) 1997-03-15
ES2098562T3 (es) 1997-05-01
CA2122455C (en) 1997-12-09
DE69217999T2 (de) 1997-06-12
AU665502B2 (en) 1996-01-04
US5315019A (en) 1994-05-24
AU3131693A (en) 1993-06-15
EP0624157A1 (en) 1994-11-17
WO1993010111A1 (en) 1993-05-27
JPH07507043A (ja) 1995-08-03
BR9206778A (pt) 1995-11-07

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