JPWO2016021425A1 - Oxidative hair dye, method for producing oxidative hair dye mixture, and oxidative hair dyeing method - Google Patents

Abstract

Disclosed is an oxidative hair dye that can reduce damage to hair, exhibit excellent dyeing power, and is excellent in storage stability. In the oxidative hair dye according to the present invention, the first agent is a compound selected from the group consisting of component A: ammonia, monoethanolamine, diethanolamine, triethanolamine and isopropanolamine, and component B: carbonate and hydrogen carbonate. A compound selected from the group consisting of a salt, component C: dialkyl phosphate, component D: higher alcohol, component E: an oxidation dye, the second agent includes component X: hydrogen peroxide, In one agent, the content of the component D is 5.5% by mass or less, and in the mixture of the first agent and the second agent, the content of the component X is 1.5% by mass or more, 2 Less than 7% by mass.

Description

  The present invention comprises at least a first agent containing an alkali agent and an oxidative dye and a second agent containing hydrogen peroxide, and the oxidative hair dye used by mixing the first agent and the second agent. It relates to the agent. Moreover, this invention relates to the manufacturing method of the mixing agent for oxidation hair dyes using an oxidation hair dye, and the oxidation hair dyeing method.

  In order to decolorize and dye hair, multi-component decoloring agents and oxidative hair dyes comprising a first agent containing an alkaline agent and a second agent containing hydrogen peroxide are widely used (for example, patents). Reference 1). Hair is dyed by a mixture of the first agent and the second agent.

JP-A-11-343219

  The decolorizing agent described in Patent Document 1 has a problem in that hair damage increases because the content of hydrogen peroxide in the mixture exceeds 3% by mass.

  In order to reduce the damage to the hair, it is conceivable to reduce the content of hydrogen peroxide in the mixed agent. However, in the oxidative hair dye, there is a problem that the dyeing power is lowered.

  An object of the present invention is to provide a method for producing an oxidative hair dye and a oxidative hair dye mixture which can reduce damage to hair, exhibit excellent dyeing power, and also have excellent storage stability. And providing an oxidative hair dyeing method.

  As a result of intensive studies, the present inventors have determined that the content of hydrogen peroxide by using a compound selected from the group consisting of carbonates and bicarbonates, dialkyl phosphates, and higher alcohols as the first agent. It has been found that an oxidative hair dye exhibiting excellent dyeing power can be obtained even when the amount is reduced.

  However, it has been found that the above-mentioned oxidative hair dye has a new disadvantage that the viscosity of the first agent increases with time, resulting in poor storage stability.

  Conventionally, the present situation is that an oxidative hair dye that has little hair damage, has excellent dyeing power, and also has good storage stability has not been obtained. I found a configuration that can solve the problem.

  The oxidative hair dye according to the present invention comprises at least a first agent and a second agent, and the first agent and the second agent are mixed and used, and the first agent comprises the following component A, The following component B, the following component C, the following component D, and the following component E are included, the said 2nd agent contains the following component X, In said 1st agent, content of the said component D is 5.5. In the mixed agent of the first agent and the second agent, the content of the component X is 1.5% by mass or more and less than 2.7% by mass.

Component A: Compound selected from the group consisting of ammonia, monoethanolamine, diethanolamine, triethanolamine and isopropanolamine Component B: Compound selected from the group consisting of carbonate and bicarbonate Component C: Dialkyl phosphate Component D : Higher alcohol Component E: Oxidative dye Component X: Hydrogen peroxide

  In the oxidative hair dye which concerns on this invention, it is preferable that pH at 25 degrees C of the mixing agent of the said 1st agent and the said 2nd agent is 8.8 or more and 10.0 or less.

  In the oxidative hair dye according to the present invention, it is preferable that the first agent contains the following component A ′ as the component A.

  Component A ': Monoethanolamine

  In the oxidative hair dye according to the present invention, the total content of ammonia and ammonium ions in the mixture of the first agent and the second agent is preferably 0.45 mmol / g or less in terms of ammonia.

  In the oxidation hair dye which concerns on this invention, it is preferable that a said 2nd agent further contains the following component Y.

  Component Y: Nonionic surfactant

  In the oxidative hair dye which concerns on this invention, it is preferable that a said 1st agent is creamy and a said 2nd agent is creamy.

  In the oxidative hair dye which concerns on this invention, it is preferable that said 1st agent and said 2nd agent are 1: 1.5-1.5: 1 by mass ratio.

  The method for producing a mixture for oxidative hair dyeing according to the present invention comprises the component A, the component B, the component C, the component D, and the component E, and the component D is 5.5. A mixing step of mixing the first agent and the second agent by using an oxidative hair dye comprising at least a second agent containing the first agent and the component X, and obtaining a mixture. In the obtained mixture, the content of the component X is 1.5 mass% or more and less than 2.7 mass%.

  The oxidative hair dyeing method according to the present invention includes the component A, the component B, the component C, the component D, and the component E, and includes the component D at 5.5% by mass or less. A mixing step of mixing the first agent and the second agent using an oxidative hair dye comprising at least a second agent containing the first agent and the component X to obtain a mixture, and the mixture And a hair dyeing process for dyeing hair, and in the resulting mixture, the content of the component X is 1.5 mass% or more and less than 2.7 mass%.

  In the method for producing an oxidative hair dye mixture according to the present invention and the oxidative hair dye method according to the present invention, in the obtained admixture, the pH at 25 ° C. is preferably 8.8 or more and 10.0 or less. .

  In the method for producing an oxidative hair dye mixture according to the present invention and the oxidative hair dye method according to the present invention, in the obtained admixture, the total content of ammonia and ammonium ions is 0.45 mmol / g or less in terms of ammonia. It is preferable to do.

  In the method for producing an oxidative hair dye mixture according to the present invention and the oxidative hair dye method according to the present invention, in the obtained admixture, the first agent and the second agent are in a mass ratio of 1: 1. It is preferable to mix the first agent and the second agent so as to be 5 to 1.5: 1.

  In the oxidation hair dye which concerns on this invention, the manufacturing method of the mixture for oxidative hair which concerns on this invention, and the oxidative hair dyeing method which concerns on this invention, the damage to hair is reduced by being provided with the structure of this invention. And developing sufficient dyeing power for hair. Moreover, the storage stability of the first agent is also excellent.

  Hereinafter, the present invention will be described in detail.

  The oxidative hair dye according to the present invention includes at least a first agent and a second agent. The oxidative hair dye used in the method for producing the oxidative hair dye mixture according to the present invention and the oxidative hair dyeing method according to the present invention comprises at least a first agent and a second agent. The first agent and the second agent are mixed and used. The first agent and the second agent are mixed at the time of use (that is, at the time of dyeing hair).

  In the oxidative hair dye, the first agent was selected from the group consisting of ammonia, monoethanolamine, diethanolamine, triethanolamine and isopropanolamine, and the group consisting of carbonate and bicarbonate. A compound, a dialkyl phosphate, a higher alcohol, and an oxidation dye are included. In the oxidative hair dye according to the present invention, the second agent contains hydrogen peroxide.

  In the present specification, the “compound selected from the group consisting of ammonia, monoethanolamine, diethanolamine, triethanolamine and isopropanolamine” may be referred to as “component (A)”. The “compound selected from the group consisting of carbonates and bicarbonates” may be referred to as “component (B)”. Furthermore, the “dialkyl phosphate” may be referred to as “component (C)”. The above “higher alcohol” may be referred to as “component (D)”. Further, the “oxidative dye” may be referred to as “component (E)”. Further, the “hydrogen peroxide” may be referred to as “component (X)”.

  In the oxidative hair dye according to the present invention, in the first agent, the content of the component (D) is 5.5% by mass or less, and in the mixture of the first agent and the second agent, Content of component (X) is 1.5 mass% or more and less than 2.7 mass%. The mixed agent of the first agent and the second agent is a mixed agent obtained by mixing the first agent and the second agent.

  The manufacturing method of the mixed agent for oxidative hair coloring which concerns on this invention comprises the mixing process of mixing the said 1st agent and the said 2nd agent using the said oxidative hair dye, and obtaining a mixed agent. The oxidative hair dyeing method according to the present invention uses the oxidative hair dye to mix the first agent and the second agent to obtain a mixture, and uses the mixture to produce hair. A hair dyeing step for dyeing.

  In the method for producing an oxidative hair dye mixture according to the present invention and the oxidative hair dye method according to the present invention, the content of component (X) in the obtained admixture is 1.5 mass% or more and 2.7 mass%. Less than.

  In this invention, since the structure mentioned above is provided, since the content of hydrogen peroxide is considerably small, damage to hair can be reduced. Despite the considerably low content of hydrogen peroxide, the hair can be sufficiently dyed by using the component (B), the component (C), and the component (D) in combination. This is not particularly limited to the following estimation, but the effect of improving the dyeing power while keeping the pH low to some extent by component (B) and the combination of component (C) and component (D) allow the admixture to penetrate into the hair. The effect of improving the dyeing power by facilitating the dyeing, and the effect of improving the dyeing power by improving the adhesion of the mixture to the hair by increasing the viscosity of the mixture to some extent by component (D). Presumed to be due to multiple effects.

  Furthermore, in this invention, since content of a component (D) is made into the specific range, the viscosity raise with time of a 1st agent can be suppressed and storage stability can also be improved.

  The inventors of the present invention 1) reduce damage to hair, 2) sufficiently dye hair, and 3) increase the viscosity stability of the first agent over time and increase storage stability. We have found the above configuration that can solve the extremely difficult problem of improving all three performances.

  In addition, in the present invention, since the component (B) exhibits decoloring power, when used for hair mixed with white hair and black hair, the color of white hair dyed after dyeing and dyed black hair Difference can be reduced, and so-called familiarity with white hair is improved. In addition, the oxidative hair dye which concerns on this invention can be used also for the hair which is not mixed with the white hair. Furthermore, the irritating odor at the time of use is also reduced by the effect of a component (B), a component (C), and a component (D).

  In the oxidative hair dye, the second agent preferably contains a nonionic surfactant.

  In the present specification, the “nonionic surfactant” may be referred to as “component (Y)”.

  The first agent includes at least a component (A), a component (B), a component (C), a component (D), and a component (E). The first agent may contain other components. The second agent contains at least component (X). The second agent preferably contains a component (Y). The second agent may contain other components. Only 1 type may be used for a component (A), a component (B), a component (D), a component (E), a component (Y), and another component, respectively, and 2 or more types may be used together. .

  In the oxidative hair dye, in the mixed agent in which the first agent and the second agent are mixed, the total content of ammonia and ammonium ions is preferably 0.20 mmol / g or more, more preferably in terms of ammonia. Is 0.25 mmol / g or more, preferably 0.45 mmol / g or less. When the total content of ammonia and ammonium ions is within the above range, the dyeing power is further increased. In addition, the decolorization power is improved and the familiarity with gray hair is further improved. Furthermore, when the total content of ammonia and ammonium ions is not more than the above upper limit, the irritating odor and the irritating feeling during use are further reduced. Although it does not specifically limit as a component which produces ammonia or ammonium ion, For example, ammonia used as a component (A); Ammonium carbonate, ammonium hydrogencarbonate etc. which are used as a component (B) are mentioned.

  Hereinafter, the detail of each component used for the said oxidation hair dye is demonstrated.

(Ingredient (A))
Component (A) is an alkaline agent. Component (A) is a compound (at least one compound) selected from the group consisting of ammonia, monoethanolamine, diethanolamine, triethanolamine, and isopropanolamine.

  From the viewpoint of further enhancing the dyeing power, the component (A) is preferably a compound (at least one amine compound) selected from the group consisting of monoethanolamine and isopropanolamine, and monoethanolamine (hereinafter referred to as the above). More preferably, “monoethanolamine” may be referred to as component (A ′). The first agent preferably contains a component (A ′) as the component (A).

  In 100% by mass of the mixture, the content of the component (A) and the content of the component (A ′) are each preferably 0.5% by mass or more, more preferably 2.0% by mass or more, preferably 7 It is 0.0 mass% or less, More preferably, it is 6.0 mass% or less. When the content of each of the component (A) and the component (A ′) is not less than the above lower limit, the dyeing power is further increased. When each content of the component (A) and the component (A ′) is not more than the above upper limit, the hair damage is further reduced.

(Ingredient (B))
Component (B) is an alkaline agent. Component (B) is a compound (at least one compound) selected from the group consisting of carbonates and bicarbonates. The component (B) plays a role of improving the dyeing power and compensating for the shortage of hair dyeing power accompanying the reduction of the component (X). Moreover, since a component (B) improves depigmenting power, it improves the familiarity of gray hair when it is used for hair in which gray hair and black hair are mixed. Furthermore, by using component (B), the pH of the admixture can be kept low, so that the irritating odor and the feeling of irritation are further suppressed.

  Examples of the component (B) include ammonium carbonate, ammonium bicarbonate, sodium carbonate, sodium bicarbonate, potassium carbonate, potassium bicarbonate, guanidine carbonate, guanidine bicarbonate, lithium carbonate, calcium carbonate, magnesium carbonate, and barium carbonate. .

  From the viewpoint of further improving the familiarity with gray hair, the component (B) is preferably a compound (at least one compound) selected from the group consisting of ammonium carbonate, ammonium bicarbonate, sodium carbonate and sodium bicarbonate. . Among these, the component (B) is more preferably a compound (at least one compound) selected from the group consisting of ammonium hydrogen carbonate and sodium hydrogen carbonate. From the viewpoint of improving dyeability, the component (B) is more preferably ammonium hydrogen carbonate. The first agent preferably contains ammonium hydrogen carbonate as the component (B).

  In the admixture, the content of the component (B), the content of a compound selected from ammonium carbonate, ammonium hydrogen carbonate, sodium carbonate and sodium hydrogen carbonate, the content of a compound selected from ammonium hydrogen carbonate and sodium hydrogen carbonate, And ammonium hydrogen carbonate content is preferably 0.03 mmol / g or more, more preferably 0.20 mmol / g or more, still more preferably 0.25 mmol / g or more, preferably 0.70 mmol / g or less, more preferably Is 0.65 mmol / g or less. When each content of the component (B) is equal to or higher than the above lower limit, the staining power is further increased. In addition, familiarity with gray hair is improved, and the irritating odor and feeling during use are further reduced. When each content of the component (B) is not more than the above upper limit, hair damage is further reduced.

(Ingredient (C))
Component (C), dialkyl phosphate, facilitates penetration of the admixture into the hair and further enhances the dyeing power. Moreover, the irritating odor at the time of use can be reduced further. The said effect is still more excellent by using together with a component (C) and a component (D).

  From the viewpoint of further enhancing the dyeing power, the carbon number of the alkyl group of component (C) is preferably 12 or more, preferably 24 or less, more preferably 20 or less.

  Among them, the component (C) is preferably dicetyl phosphate (hereinafter sometimes referred to as “component (C ′)”). The first agent preferably contains a component (C ′) as the component (C).

  In 100% by mass of the first agent, the content of the component (C) and the content of the component (C ′) are preferably 0.2% by mass or more, more preferably 0.3% by mass or more, and still more preferably 0. 0.5% by mass or more, preferably 10.0% by mass or less, more preferably 5.0% by mass or less, still more preferably 2.0% by mass or less, and particularly preferably 1.5% by mass or less. When the content of each of the component (C) and the component (C ′) is not less than the above lower limit, the dyeing power is further increased. Moreover, the irritating odor at the time of use is further reduced. When each content of the component (C) and the component (C ′) is not more than the above upper limit, the preparation stability is further enhanced.

(Component (D))
By using a component (D) by a predetermined quantity, the viscosity of a 1st agent and a mixing agent can be raised moderately, the adhesiveness to the hair of a mixing agent can be improved, and dyeing power can be improved. In addition, the storage stability of the first agent can be improved by suppressing the increase in viscosity of the first agent over time.

  The number of carbon atoms of component (D) is preferably 12 or more, more preferably 14 or more, preferably 22 or less, more preferably 18 or less. From the viewpoint of further improving the storage stability of the first agent and controlling the viscosity of the mixture within a better range, the component (D) is preferably an aliphatic monovalent higher alcohol.

  Examples of the component (D) include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetostearyl alcohol, isostearyl alcohol, 2-octyldodecanol, oleyl alcohol, behenyl alcohol, and batyl alcohol.

  From the viewpoint of suppressing the increase in viscosity of the first agent over time and enhancing the storage stability, the content of the component (D) is 5.5% by mass or less in 100% by mass of the first agent. From the viewpoint of further improving the storage stability of the first agent, the content of the component (D) in 100% by mass of the first agent is preferably 5.0% by mass or less, more preferably 4.5% by mass. It is as follows. In addition, the content of component (D) is preferably 0.5 mass from the viewpoint of making the first agent creamy and further improving the adhesion of the mixture to the hair and further improving the dyeing power. % Or more, more preferably 2.0 mass% or more, still more preferably 3.0 mass% or more.

(Ingredient (E))
By using the component (E) which is an oxidation dye, hair can be dyed into a predetermined color.

  “Oxidative dye” means both an oxidative dye precursor that develops color by its own oxidative polymerization and a coupler that develops various colors by reacting with the oxidative dye precursor. As for the said oxidation dye precursor and the said coupler, only 1 type may respectively be used and 2 or more types may be used together.

  Examples of the oxidative dye precursor include phenylenediamines, aminophenols and diaminopyridines, and salts thereof. Examples of the salts include hydrochloride and sulfate.

  Examples of the phenylenediamines include p-phenylenediamine, toluene-2,5-diamine, toluene-3,4-diamine, 2,5-diaminoanisole, N-phenyl-p-phenylenediamine, and N-methyl-p-. Phenylenediamine, N, N-dimethyl-p-phenylenediamine, 6-methoxy-3-methyl-p-phenylenediamine, N, N-diethyl-2-methyl-p-phenylenediamine, N-ethyl-N- (hydroxy Ethyl) -p-phenylenediamine, N- (2-hydroxypropyl) -p-phenylenediamine, 2-chloro-6-methyl-p-phenylenediamine, 2-chloro-p-phenylenediamine, N, N-bis- (2-hydroxyethyl) -p-phenylenediamine, 2,6-dichloro-p-phenylenediamine And 2-chloro-6-bromo -p- phenylenediamine are listed. Examples of the aminophenols include paraaminophenol, orthoaminophenol, paramethylaminophenol, 2,4-diaminophenol, 5-aminosalicylic acid, 2-methyl-4-aminophenol, 3-methyl-4-aminophenol, 2 , 6-Dimethyl-4-aminophenol, 3,5-dimethyl-4-aminophenol, 2,3-dimethyl-4-aminophenol, 2,5-dimethyl-4-aminophenol, 2-chloro-4-amino Examples include phenol and 3-chloro-4-aminophenol. Examples of the diaminopyridines include 2,5-diaminopyridine.

  Examples of the coupler include resorcin, m-aminophenol, m-phenylenediamine, 2,4-diaminophenoxyethanol, 5-amino-o-cresol, 2-methyl-5-hydroxyethylaminophenol, and 2,6-diamino. Examples thereof include pyridine, catechol, pyrogallol, α-naphthol, gallic acid and tannic acid, and salts thereof.

  The content of the component (E) is appropriately adjusted in consideration of the color tone to be dyed and the dyeing power. In 100% by mass of the mixture, the content of the oxidation dye is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, preferably 2.0% by mass. Hereinafter, it is more preferably 1.5% by mass or less, and still more preferably 1.0% by mass or less. When the content of the component (E) is not less than the above lower limit, the staining power is further increased. When the content of component (E) is not more than the above upper limit, skin irritation is reduced.

(Ingredient (X))
Component (X), which is hydrogen peroxide, decolorizes and dyes hair when mixed with an alkaline agent.

  In the present invention, component (X) is used in a relatively small amount in order to reduce hair damage. Conventionally, the content of hydrogen peroxide in the mixture is generally set to 2.7% by mass or more in order to develop the dyeing power that is the basic performance. On the other hand, in the present invention, the content of component (X) is set to be quite low. That is, in the present invention, in the mixture, the content of component (X) is 1.5% by mass or more and less than 2.7% by mass. Content of component (X) becomes like this. Preferably it is 1.7 mass% or more, Preferably it is 2.5 mass% or less. When the content of component (X) is not less than the above lower limit, the dyeing power is further increased. When the content of component (X) is not more than the above upper limit, hair damage is further reduced.

  In the present invention, even if the content of the component (X) is less than 2.7% by mass in the admixture, the dyeing power is sufficiently high because the components (A) to (D) are used.

(Ingredient (Y))
The second agent preferably contains a component (Y) that is a nonionic surfactant. By using the component (Y), the adhesiveness of the mixture to the hair can be further improved, and the dyeing power can be further improved.

  As the component (Y), it is preferable to use polyoxyalkylene alkyl ether, glycerin fatty acid ester, polyoxyalkylene fatty acid ester, polyoxyalkylene castor oil, polyoxyalkylene hydrogenated castor oil, alkyl polyglucoside, and polyoxyalkylene alkyl ether. It is more preferable to use Specific examples of the polyoxyalkylene alkyl ether include polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene behenyl ether and polyoxyethylene octyldodecyl ether. In addition, the addition mole number of the alkylene oxide of the said polyoxyalkylene alkyl ether is not specifically limited.

  In 100% by mass of the second agent, the content of the component (Y) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, preferably 10.0% by mass or less, more preferably 7%. 0.0 mass% or less. When the content of the component (Y) is not less than the above lower limit and not more than the above upper limit, the storage stability of the second agent is further enhanced, and the adhesiveness of the mixture to the hair is further enhanced.

(Other ingredients)
The first agent and the second agent each contain water. The water is not particularly limited, but purified water is preferable. The content of water in 100% by mass of the first agent and the content of water in 100% by mass of the second agent are not particularly limited, but each is preferably 50% by mass or more.

  In order to adjust the color tone, the first agent may contain a direct dye. Examples of the direct dye include paranitroorthophenylenediamine, nitroparaphenylenediamine, paranitrometaphenylenediamine sulfate, 2-amino-5-nitrophenol, and picramic acid.

  The first agent preferably further contains a reducing agent. The reducing agent suppresses the color development of the oxidation dye when the first agent is exposed to the atmosphere.

  Examples of the reducing agent include N-acetyl-L-cysteine, L-ascorbic acid, sodium L-ascorbate, sodium sulfite, sodium pyrosulfite and thioglycolic acid. These salts may be used. As for the said reducing agent, only 1 type may be used and 2 or more types may be used together.

  From the viewpoint of effectively suppressing the color development of the oxidative dye before use, the content of the reducing agent is preferably 0.01% by mass or more, more preferably 0.05% by mass in 100% by mass of the first agent. As mentioned above, Preferably it is 2.0 mass% or less, More preferably, it is 1.0 mass% or less.

  The second agent preferably contains a higher alcohol. In the second agent, only one kind of the higher alcohol may be used, or two or more kinds may be used in combination.

  The carbon number of the higher alcohol is preferably 12 or more, more preferably 14 or more, preferably 22 or less, more preferably 18 or less. From the viewpoint of further improving the stability of the first agent and the second agent, the higher alcohol is preferably an aliphatic monovalent higher alcohol.

  Examples of the higher alcohol that can be used in the second agent include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetostearyl alcohol, isostearyl alcohol, 2-octyldodecanol, oleyl alcohol, behenyl alcohol, and batyl alcohol. Can be mentioned.

  From the viewpoint of further enhancing the storage stability of the second agent, the content of the higher alcohol is preferably 0.5% by mass or more, more preferably 2.0% by mass or more, in 100% by mass of the second agent. More preferably, it is 3.0% by mass or more, preferably 10.0% by mass or less, more preferably 7.0% by mass or less.

  The first agent preferably contains a surfactant other than the component (C). The second agent may contain a surfactant other than the nonionic surfactant. Examples of the surfactant include an anionic surfactant, a cationic surfactant, an amphoteric surfactant, and a nonionic surfactant. As for the said surfactant, only 1 type may be used and 2 or more types may be used together.

  Examples of the anionic surfactant include sulfate ester type anionic surfactant, phosphate ester type anionic surfactant, phosphate ether type anionic surfactant, sulfonic acid type anionic surfactant and carboxylic acid type An anionic surfactant etc. are mentioned.

  As the amphoteric surfactant, glycine type amphoteric surfactant, aminopropionic acid type amphoteric surfactant, aminoacetic acid betaine type amphoteric surfactant and sulfobetaine type amphoteric surfactant, imidazolinium type amphoteric surfactant, Examples thereof include amine oxide type amphoteric surfactants and phosphobetaine type amphoteric surfactants.

  Examples of the cationic surfactant include quaternary ammonium salt type cationic surfactants.

  Examples of the nonionic surfactant that can be used in the first agent include polyoxyalkylene alkyl ether, glycerin fatty acid ester, polyoxyalkylene fatty acid ester, polyoxyalkylene castor oil, polyoxyalkylene hydrogenated castor oil, and alkylpolyglucoside. It is preferable to use polyoxyalkylene alkyl ether. Specific examples of the polyoxyalkylene alkyl ether include polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene behenyl ether and polyoxyethylene octyldodecyl ether. In addition, the addition mole number of the alkylene oxide of the said polyoxyalkylene alkyl ether is not specifically limited.

  In 100% by mass of the first agent, the content of the surfactant (the content of the surfactant other than the component (C)) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more. Preferably, it is 10.0 mass% or less, More preferably, it is 7.0 mass% or less.

  At least one of the first agent and the second agent may contain a thickening polymer. Examples of the thickening polymer include cationized cellulose, a cationic polymer, and an anionic polymer. As for the said thickening polymer, only 1 type may be used and 2 or more types may be used together.

  Examples of the cationized cellulose include -O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose and diallyldimethylammonium chloride / hydroxyethylcellulose.

  Examples of the cationic polymer include cationic starch, cationized guar gum derivative, diallyl quaternary ammonium salt polymer, diallyl quaternary ammonium salt / acrylic acid copolymer, diallyl quaternary ammonium salt / acrylamide copolymer, and quaternary polyvinyl. Examples include pyrrolidone derivatives. Specific examples of the cationic polymer include chloride-O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum, dimethyldiallylammonium chloride / acrylic acid copolymer liquid, dimethyldiallylammonium chloride / acrylamide copolymer. And quaternized derivatives of vinyl pyrrolidone and dimethylamino methacrylate with dimethyl sulfate.

  Examples of the anionic polymer include xanthan gum, alkyl acrylate / alkyl methacrylate / polyoxyethylene stearyl ether copolymer, alkyl acrylate / methacrylic acid polyoxyethylene behenes ether copolymer, alkyl acrylate / itaconate poly Examples thereof include oxyethylene stearyl ether copolymers and alkyl acrylate / methacrylic acid polyoxyethylene stearyl ether crosspolymers.

  It is preferable that at least one of the first agent and the second agent contains hydrocarbons. Each of the first agent and the second agent preferably contains hydrocarbons. As for the said hydrocarbons, only 1 type may be used and 2 or more types may be used together.

  Examples of the hydrocarbons include paraffin, liquid paraffin, liquid isoparaffin, squalene, and squalane. As for the said hydrocarbons, only 1 type may be used and 2 or more types may be used together.

  In 100% by mass of the first agent and 100% by mass of the second agent, each content of the hydrocarbons is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, preferably It is 5.0 mass% or less, More preferably, it is 3.0 mass% or less. In 100% by mass of the mixture, the content of the hydrocarbons is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, preferably 5.0% by mass or less, more preferably 3.0%. It is below mass%. When the content of the hydrocarbons is less than or equal to the above upper limit, the smoothness of the hair after dyeing becomes even better, and dyeing inhibition due to excessive hydrocarbons is less likely to occur.

  It is preferable that at least one of the first agent and the second agent contains silicone oil. Each of the first agent and the second agent preferably contains silicone oil. By using silicone oil, the touch at the time of rinsing after dyeing is further improved, and the smoothness of the hair after dyeing is further improved.

  Examples of the silicone oil include methylpolysiloxane, methylphenylpolysiloxane, methylcyclopolysiloxane, octamethylcyclotetrasiloxane, octamethylcyclopentasiloxane, decamethylcyclopentasiloxane, methylhydrogenpolysiloxane, amino-modified silicone, and polyether. Examples include modified silicone. As for the said silicone oil, only 1 type may be used and 2 or more types may be used together.

  It is preferable that at least one of the first agent and the second agent contains a polyhydric alcohol. Each of the first agent and the second agent preferably contains a polyhydric alcohol. As for the said polyhydric alcohol, only 1 type may be used and 2 or more types may be used together.

  Examples of the polyhydric alcohol include polyethylene glycol, glycerin, polyglycerin, propylene glycol, dipropylene glycol, 1,3-butylene glycol, 1,2-pentanediol and 1,2-octanediol.

  The second agent may contain a hydrogen peroxide stabilizer. As the hydrogen peroxide stabilizer, only one type may be used, or two or more types may be used in combination.

  Examples of the hydrogen peroxide stabilizer include phenoxyethanol, phenacetin, and hydroxyethanediphosphonic acid.

  In the above oxidation hair dye, for example, sugar alcohols such as sorbitol, maltitol and trehalose; sequestering agents; antioxidants; plant extract extracts; pigments; A preservative; a solvent or the like may be used.

(Details of multi-component oxidative hair dye)
The oxidative hair dye comprises at least the first agent and the second agent. That is, the oxidative hair dye is an oxidative hair dye kit including at least the first agent and the second agent. The oxidative hair dye may further include a third agent in addition to the first agent and the second agent. Examples of the third agent include a hair rinse agent, a hair treatment agent, and a hair conditioning agent. When the oxidative hair dye contains the third agent and the third agent is used by mixing with the first agent and the second agent, the mixture contains the third agent, and the mixture Is obtained by mixing the first agent, the second agent and the third agent.

  In the oxidative hair dye, the first agent and the second agent are mixed and used as a mixture. Examples of the properties of the first agent, the second agent and the mixed agent include liquid, emulsion, gel and cream.

  From the viewpoint of improving the adhesion of the mixed agent to the hair and further improving the dyeability, the first agent is preferably creamy, the second agent is preferably creamy, and the mixing The agent is preferably creamy.

  The viscosity at 25 ° C. of the mixture is preferably 7000 mPa · s or more, more preferably 10,000 mPa · s or more, preferably 30000 mPa · s or less, more preferably 25000 mPa · s or less. When the viscosity of the mixture is not less than the above lower limit and not more than the above upper limit, 1) the irritating odor at the time of use is further reduced, 2) damage to the hair is further reduced, and 3) the hair is further effective. Stained.

  The viscosity of the admixture was measured using a B-type viscometer (manufactured by Tokimec Co., Ltd.) at 25 ° C. with rotor No. It is measured at 4, 12 rpm and 1 minute.

  The pH of the above mixture at 25 ° C. is preferably 8.8 or more, and preferably 10.0 or less. When the pH at the time of mixing is not less than the above lower limit and not more than the above upper limit, the three performances of 1) reduction of irritating odor during use, 2) reduction of damage to hair, and 3) hair dyeing can be improved in a balanced manner. it can.

  The oxidative hair dye may be mixed in a mixing container, mixed on a comb, or mixed on hair. The 1st agent and the 2nd agent may be discharged in the state mixed from a separate container, and may be discharged in the state where it is not mixed from a separate container.

  Examples of the mixing container include a mixing container including a container body and a lid having a discharge nozzle. Examples of the storage container include an aerosol container.

  In the oxidative hair dye, the first agent and the second agent are preferably used in a mass ratio (first agent: second agent) of 1: 5 to 5: 1. More preferably, it is used in a ratio of 3: 1, and more preferably 1: 2 to 2: 1. From the viewpoint of mixing the first agent and the second agent well, and 1) reducing the irritating odor during use, 2) reducing the damage to the hair, and 3) improving the hair dyeing performance in a well-balanced manner. The first agent and the second agent are preferably used in a mass ratio of 1: 1.5 to 1.5: 1. Therefore, the mass ratio of the first agent and the second agent (first agent: second agent) in the oxidative hair dye kit is preferably 1: 5 to 5: 1, more preferably 1: 3 to 3. : 1, more preferably 1: 2 to 2: 1, particularly preferably 1: 1.5 to 1.5: 1. That is, the above-mentioned mixed agent (mixture of the first agent and the second agent) has a mass ratio of the first agent to the second agent (first agent: second agent) of 1: 5 to 5: 1 (from The mixture is preferably 1: 3 to 3: 1, more preferably 1: 2 to 2: 1, particularly preferably 1: 1.5 to 1.5: 1.

  The oxidative hair dye can be used for black hair, brown hair, yellow hair, and gray hair. Since it has excellent hair dyeing power, the oxidative hair dye according to the present invention can be suitably used for hair containing gray hair.

  Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples. The present invention is not limited only to the following examples.

(Examples 1-14 and Comparative Examples 1-7)
Each component shown in the following Tables 1 to 4 was blended with the contents shown in the following Tables 1 to 4 to obtain a first agent and a second agent. Specific production methods of the first agent, the second agent, and the mixed agent are as follows.

<Method for producing first agent>
The oil phase heated to 80 ° C. was gradually added to the water phase heated to 80 ° C. and sufficiently dissolved. The mixture was stirred with a homomixer at 2500 rpm / min for 5 minutes for emulsification. After emulsification, the mixture was cooled to 40 ° C. and an alkaline agent was added. Thereafter, the mixture was sufficiently stirred to obtain the first agent.

<Method for producing second agent>
The oil phase heated to 80 ° C. was gradually added to the water phase heated to 80 ° C. and sufficiently dissolved. The mixture was stirred by hand for 5 minutes for emulsification. After emulsification, the mixture was cooled to 40 ° C., and an oxidizing agent, a stabilizer, and a pH adjuster were added. Thereafter, the mixture was sufficiently uniformly stirred to obtain a second agent.

<Method for producing the mixture>
The first agent and the second agent were mixed at a ratio (mass ratio) of 1: 1 to obtain a mixture.

(Evaluation)
<Method for preparing hair bundle for evaluation>
The obtained mixture was applied to a white human hair bundle (Burelux, length 10 cm, weight 1 g) and a black human hair bundle (Stuffs, length 10 cm, weight 1 g), 30 Left at 10 ° C. for 10 minutes. Thereafter, the mixture was washed with shampoo, dried using a dryer, and an evaluation hair bundle dyed white human hair bundle and an evaluation hair bundle dyed black human hair bundle were prepared.

(1) pH of the mixture
It measured using the pH meter (Horiba Ltd. make, F-74).

(2) Irritating odor (ammonia detection concentration)
First, 2.5 g of the first agent and 2.5 g of the second agent were placed in a 100 mL beaker, mixed, and the surface was flattened. Then, the 100 mL beaker was placed in a 2 L beaker, sealed, and left for 1 minute. After leaving, 100 mL of gas in the beaker was sucked using an ammonia detector tube (manufactured by Gastec, No. 3M), and the ammonia concentration was measured.

(3) Hair damage Evaluation was performed using an evaluation hair bundle in which a black human hair bundle was dyed with the obtained mixture. Using an automatic contact angle meter (manufactured by Kyowa Interface Chemical Co., Ltd., Model DM500), 0.5 μL of purified water was dropped onto the hair collected from the evaluation hair bundle, and the contact angle of water on the hair was measured.

  In addition, the contact angle of water in the untreated black human hair bundle not subjected to the dyeing treatment was 125.2 °.

  When the value of the contact angle is 110 ° or more, it can be determined that there is little damage to the hair.

(4) Dyeing power Evaluation was performed using a hair bundle for evaluation in which a white human hair bundle was dyed with the obtained mixture and an untreated white human hair bundle not subjected to a dyeing treatment. Using a spectrocolorimeter (manufactured by Minolta, CM3610d type), the L ^* a ^* b ^* color system L ^* value and a ^* value of each of the evaluation hair bundle and the untreated white human hair bundle The b ^* value was measured, and the color difference ΔE ^* ab between the evaluation hair bundle and the untreated white human hair bundle was calculated.

In addition, it shows that it dye | stained favorably and the dyeing power is so high that (DELTA ⁾ E ^* ab is large. The value of ΔE ^* ab is preferably 39 or more, and when it is 40 or more, the staining power was considerably good.

(5) Good familiarity of white hair Evaluation was performed using an evaluation hair bundle in which a white human hair bundle was dyed with a mixture and an evaluation hair bundle in which a black human hair bundle was dyed with a mixture. Using a spectrocolorimeter (manufactured by Minolta Co., Ltd., CM3610d type), L ^* a ^* b ^* for each of the evaluation hair bundles for staining white human hair bundles and evaluation hair bundles for staining black human hair bundles The L ^* value, a ^* value, and b ^* value of the color system are measured, and the color difference ΔE ^* ab between the evaluation hair bundle that dyes the white human hair bundle and the evaluation hair bundle that dyes the black human hair bundle. Calculated.

In addition, it is shown that the smaller the ΔE ^* ab is, the less the color difference between the evaluation hair bundle for staining the white human hair bundle and the evaluation hair bundle for staining the black human hair bundle is better. The value of ΔE ^* ab is preferably 18 or less, and when it is 17 or less, familiarity with white hair was quite good.

(6) Storage stability of the first agent 40 g of the obtained first agent was filled into an aluminum tube (size: diameter 25.4 mm × 125 mm) and cycled [held at 5 ° C. for 1 hour, increased to 45 ° C. in 11 hours. The temperature was kept at 45 ° C. for 1 hour, and the temperature was repeatedly lowered to 5 ° C. in 11 hours]. The properties of the first agent after standing were observed, and the storage stability of the first agent was determined according to the following criteria.

[Criteria for Storage Stability of First Agent]
○: No change from immediately after preparation, or slight increase in viscosity is observed ×: Clear increase in viscosity is observed compared to immediately after preparation

  Details of the composition and the evaluation results are shown in Tables 1 to 7 below. The blending unit of the content of each component in the following Tables 1 to 4 is “% by mass”.

Claims (15)

Comprising at least a first agent and a second agent;
The first agent and the second agent are mixed and used,
The first agent includes the following component A, the following component B, the following component C, the following component D, and the following component E,
The second agent contains the following component X,
In the first agent, the content of the component D is 5.5% by mass or less,
In the mixed agent of the said 1st agent and the said 2nd agent, content of the said component X is 1.5 mass% or more and less than 2.7 mass%, Oxidative hair dye.
Component A: Compound selected from the group consisting of ammonia, monoethanolamine, diethanolamine, triethanolamine and isopropanolamine Component B: Compound selected from the group consisting of carbonate and bicarbonate Component C: Dialkyl phosphate Component D : Higher alcohol Component E: Oxidative dye Component X: Hydrogen peroxide   The oxidative hair dye of Claim 1 whose pH in 25 degreeC of the mixed agent of a said 1st agent and a said 2nd agent is 8.8 or more and 10.0 or less. The oxidative hair dye according to claim 1 or 2, wherein the first agent contains the following component A 'as the component A.
Component A ′: monoethanolamine   4. The mixture of the first agent and the second agent, according to claim 1, wherein the total content of ammonia and ammonium ions is 0.45 mmol / g or less in terms of ammonia. Oxidative hair dye. The oxidative hair dye according to any one of claims 1 to 4, wherein the second agent further comprises the following component Y.
Component Y: Nonionic surfactant The first agent is creamy,
The oxidative hair dye according to any one of claims 1 to 5, wherein the second agent is creamy.   The oxidative hair dye according to any one of claims 1 to 6, wherein the first agent and the second agent are in a mass ratio of 1: 1.5 to 1.5: 1. 1st agent containing the following component A, the following component B, the following component C, the following component D, the following component E, and containing the said component D at 5.5 mass% or less, and the following component X are included. Using an oxidative hair dye comprising at least a second agent, and mixing the first agent and the second agent to obtain a mixture;
The manufacturing method of the mixture for oxidative hair dye which makes content of the said component X 1.5 mass% or more and less than 2.7 mass% in the obtained mixture.
Component A: Compound selected from the group consisting of ammonia, monoethanolamine, diethanolamine, triethanolamine and isopropanolamine Component B: Compound selected from the group consisting of carbonate and bicarbonate Component C: Dialkyl phosphate Component D : Higher alcohol Component E: Oxidative dye Component X: Hydrogen peroxide   The method for producing a mixture for oxidative hair dyeing according to claim 8, wherein the obtained mixture has a pH at 25 ° C of 8.8 or more and 10.0 or less.   The method for producing a mixture for oxidative hair dyeing according to claim 8 or 9, wherein, in the obtained mixture, the total content of ammonia and ammonium ions is 0.45 mmol / g or less in terms of ammonia.   In the obtained mixture, the first agent and the second agent are mixed so that the first agent and the second agent are in a mass ratio of 1: 1.5 to 1.5: 1. The manufacturing method of the mixing agent for oxidative hair dye of any one of Claims 8-10. 1st agent containing the following component A, the following component B, the following component C, the following component D, the following component E, and containing the said component D at 5.5 mass% or less, and the following component X are included. Using an oxidative hair dye comprising at least a second agent, mixing the first agent and the second agent to obtain a mixture; and
A hair dyeing process for dyeing hair using the mixture;
The oxidative hair dyeing method which makes content of the said component X 1.5 mass% or more and less than 2.7 mass% in the mixture obtained.
Component A: Compound selected from the group consisting of ammonia, monoethanolamine, diethanolamine, triethanolamine and isopropanolamine Component B: Compound selected from the group consisting of carbonate and bicarbonate Component C: Dialkyl phosphate Component D : Higher alcohol Component E: Oxidative dye Component X: Hydrogen peroxide   13. The oxidative hair dyeing method according to claim 12, wherein in the obtained mixture, the pH at 25 ° C. is adjusted to 8.8 or more and 10.0 or less.   The oxidative hair dyeing method according to claim 12 or 13, wherein, in the obtained mixture, the total content of ammonia and ammonium ions is 0.45 mmol / g or less in terms of ammonia.   In the obtained mixture, the first agent and the second agent are mixed so that the first agent and the second agent are in a mass ratio of 1: 1.5 to 1.5: 1. The oxidative hair dyeing method according to any one of claims 12 to 14.