CN106102701B - Oxide hair dye, the manufacturing method of oxidation hair-dye intermixture and oxidation hair-dye method - Google Patents
Oxide hair dye, the manufacturing method of oxidation hair-dye intermixture and oxidation hair-dye method Download PDFInfo
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K8/00—Cosmetics or similar toiletry preparations
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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Abstract
The present invention provides a kind of oxide hair dye, can reduce penetrating odor when use, can reduce the damage for hair and scalp, and then can fully dye to hair, the excitement of scalp is few.Oxide hair dye of the invention includes the 1st dose and the 2nd dose, and the 1st dose includes ingredient A: monoethanolamine etc.；Ingredient B: carbonate etc.；Ingredient C: ammonia；With ingredient D: oxidation dye, 2nd dose includes ingredient X: hydrogen peroxide, above-mentioned 1st dose in above-mentioned 2nd dose of intermixture, the content of mentioned component A is 4.0 mass % or more, 7.0 mass % or less, the content of mentioned component B is 0.20mmol/g or more 0.70mmol/g or less, the total content of ammonia and ammonium ion is calculated as 0.20mmol/g or more 0.45mmol/g hereinafter, the content of mentioned component X is 1.5 mass % more than and less than 2.7 mass % with ammonia conversion.
Description
Technical field
The present invention relates to a kind of oxide hair dyes, at least have the 1st dose comprising alkaline reagent and oxidation dye and
The 2nd dose comprising hydrogen peroxide, above-mentioned 1st dose is used in mixed way with above-mentioned 2nd dose.Moreover, it relates to use oxidation hair-dye
The manufacturing method and oxidation hair-dye method of the oxidation hair-dye intermixture of agent.
Background technique
In order to dye to hair, be widely used for the oxide hair dye of multi-agent formula, have comprising alkaline reagent and
The 1st dose and the 2nd dose comprising hydrogen peroxide of oxidation dye.Utilize mix above-mentioned 1st dose with above-mentioned 2nd dose
Intermixture dyes hair.
When by coloring hairs at distinct tone, decolorizing ability is required mostly.In addition, mix in white hair and dark hair
In the case where hair, preferably by the way that dark hair to be decolourized to and made its distinctness, to reduce the white hair dyed after hair dyeing and be dyed
Dark hair difference.
It, can be and keeping hair distinct due to can be improved decolorizing ability usually as the alkaline reagent of oxide hair dye
Dyeing capacity is improved, thus ammonia has most been widely used.In addition, it is known that hydroxide other than ammonia as above-mentioned alkaline reagent
Sodium, monoethanolamine, diethanol amine, triethanolamine, isopropanolamine, single Propanolamine, dipropanolamine, tripropanol amine, 2- amino -2- first
Base -1,3- propylene glycol, 2-amino-2-methyl-1-propanol and 2- amino -2- hydroxymethyl -1,3- propylene glycol；And contain
Many alkalinity examinations such as carbonate, bicarbonate, lactate, citrate and the glycollate of sodium, potassium, lithium, calcium, magnesium and barium etc.
Agent.
In addition, in oxide hair dye, when the content of the hydrogen peroxide in intermixture is few, hair and scalp can reduce
Damage；On the other hand, when the content of the hydrogen peroxide in intermixture is more, it can be improved decolorizing ability, it can be by keeping hair distinct
And improve dyeing capacity.It changes from the point of view of a viewpoint, when the content of the hydrogen peroxide in intermixture is more, the damage of hair and scalp becomes larger；
On the other hand, when the content of the hydrogen peroxide in intermixture is few, decolorizing ability can not be improved, hair cannot become distinct, Wu Fati
High dyeing capacity.
In the past, in order to show the dyeing capacity as basic performance, the content of the hydrogen peroxide in intermixture is normally set up
For 2.7 mass % or more.
The following patent document 1 discloses decolorising agent, rather than oxide hair dye.The decoloration recorded in patent document 1
Agent includes ammonia or ammonium ion, carbanion and hydrogen peroxide in intermixture.In the case where the decolorising agent, intermixture
In, the content of ammonia and ammonium ion is calculated as 0.5 mass % or more with ammonia conversion, and the content of carbanion is 1 matter of mass %~10
% is measured, the content of hydrogen peroxide is more than 3 mass %.
Oxide hair dye is disclosed in following patent documents 2.The oxide hair dye (composition) recorded in patent document 2
Hydrogen peroxide and oxidisability comprising at least the non-ammonia basifier of 1.5 weight %, 0.5 weight of weight %~4 % in intermixture
Dyestuff, the non-ammonia basifier are selected from by monoethanolamine, diethanol amine, triethanolamine, single Propanolamine, dipropanolamine, 3 third
Hydramine, 2- amino-2-methyl -1,3- propylene glycol, 2-amino-2-methyl-1-propanol, 2- amino -2- hydroxymethyl -1,3- the third two
The group of alcohol and their mixture composition.Above-mentioned non-ammonia basifier is 1.10 or more relative to the weight ratio of hydrogen peroxide.Separately
Outside, the oxide hair dye recorded in patent document 2 may include the ammonia less than 0.5 weight % in intermixture, but preferably be free of
Ammonia.
Existing technical literature
Patent document
Patent document 1: Japanese Unexamined Patent Publication 11-343219 bulletin
Patent document 2:WO2012/099935A1
Summary of the invention
Subject to be solved by the invention
The decolorising agent recorded in patent document 1 does not include oxidation dye, is not oxide hair dye.In addition, in patent document 1
In, the content of the hydrogen peroxide in intermixture is more than 3 mass %, therefore the damage of hair and scalp becomes larger.
It in patent document 2, about the non-ammonia basifier other than ammonia, but is to describe monoethanolamine, diethyl blanketly
Hydramine, triethanolamine, single Propanolamine, dipropanolamine, tripropanol amine, 2- amino-2-methyl -1,3- propylene glycol, 2- amino -2- first
Base -1- propyl alcohol and 2- amino -2- hydroxymethyl -1,3- propylene glycol.In patent document 2, in these non-ammonia basifiers, and
It is also not right in embodiment and comparative example not about the specific record for sharing monoethanolamine and other non-ammonia basifiers
Monoethanolamine and other non-ammonia basifiers are shared.
In addition, describing the content for making the hydrogen peroxide in intermixture in the embodiment and comparative example of patent document 2
The 2 weight % of weight %~4.7, but the content of the hydrogen peroxide in intermixture be the 2 mass % of mass %~3 in the case where, ammonia
It is not used, and monoethanolamine is only only used only.Such oxide hair dye is unable to fully obtain as basic performance
Dyeing capacity.
In addition, previous, about the penetrating odor 1) reduced when using, 2) reduce damage for hair, 3) reduce pair
In scalp excitement and 4) fully hair is dyed, this four performances, exist be extremely hard to make all four performances
(rather than only one, two, three performances) good problem.
The purpose of the present invention is to provide the manufacturing methods and oxidation of a kind of oxide hair dye, oxidation hair-dye intermixture
Hair colouring methods, since the amount of ammonia and ammonium ion is few, it is thus possible to penetrating odor when using is reduced, due to the amount of hydrogen peroxide
It is quite few, it is thus possible to reduce damage for hair, although and then hydrogen peroxide amount it is quite few, can be fully to hair
Hair is dyed, and the excitement of scalp is few
Solution for solving the problem
Oxide hair dye of the invention at least has the 1st dose and the 2nd dose, and above-mentioned 1st dose is used in mixed way with above-mentioned 2nd dose,
Above-mentioned 1st dose includes following compositions A, following compositions B, following compositions C and following compositions D, and above-mentioned 2nd dose includes following compositions X,
Above-mentioned 1st dose in above-mentioned 2nd dose of intermixture, the content of mentioned component A be 4.0 mass % or more, 7.0 mass % hereinafter, on
The content for stating ingredient B is 0.20mmol/g or more 0.70mmol/g hereinafter, the total content of ammonia and ammonium ion is calculated as with ammonia conversion
0.20mmol/g or more 0.45mmol/g hereinafter, the content of mentioned component X is 1.5 mass % more than and less than 2.7 mass %,
Ingredient A: the compound in the group being made of monoethanolamine, diethanol amine, triethanolamine and isopropanolamine；
Ingredient B: the compound in the group being made of carbonate and bicarbonate；
Ingredient C: ammonia；
Ingredient D: oxidation dye；
Ingredient X: hydrogen peroxide.
In oxide hair dye of the invention, above-mentioned 1st dose is preferably 9.4 in 25 DEG C of pH with above-mentioned 2nd dose of intermixture
Above 10.0 or less.
In oxide hair dye of the invention, above-mentioned 1st dose preferably further includes following compositions E.
Ingredient E: phosphate dialkyl ester.
In oxide hair dye of the invention, above-mentioned 1st dose is preferably 1:1.5~1.5 with above-mentioned 2nd dose by quality ratio:
1。
The manufacturing method of oxidation hair-dye intermixture of the invention has mixed processes, wherein includes using at least having
The 1st dose and the 2nd dose of the oxidation comprising mentioned component X of mentioned component A, mentioned component B, mentioned component C and mentioned component D
Above-mentioned 1st dose is mixed with above-mentioned 2nd dose, obtains intermixture by hair dye；In obtained intermixture, make mentioned component A's
Content is 4.0 mass % or more, 7.0 mass % hereinafter, making the above 0.70mmol/g of content 0.20mmol/g of mentioned component B
Hereinafter, the total content of ammonia and ammonium ion is made to be calculated as 0.20mmol/g or more 0.45mmol/g hereinafter, making mentioned component X with ammonia conversion
Content be 1.5 mass % more than and less than 2.7 mass %.
Oxidation hair-dye method of the invention have following processes: mixed processes, using at least have comprising mentioned component A,
The 1st dose and the 2nd dose of the oxide hair dye comprising mentioned component X of mentioned component B, mentioned component C and mentioned component D, will
Above-mentioned 1st dose mixes with above-mentioned 2nd dose, obtains intermixture；With hair dyeing process, hair is dyed using above-mentioned intermixture；
In obtained intermixture, make 4.0 mass % of content or more, the 7.0 mass % of mentioned component A hereinafter, making mentioned component B
Content be 0.20mmol/g or more 0.70mmol/g hereinafter, make the total content of ammonia and ammonium ion with ammonia conversion be calculated as
0.20mmol/g or more 0.45mmol/g is hereinafter, make the 1.5 mass % of content of mentioned component X more than and less than 2.7 mass %.
In the manufacturing method of oxidation hair-dye intermixture of the invention and oxidation hair-dye method of the invention, obtained
In intermixture, making 25 DEG C of pH is preferably 9.4 or more 10.0 or less.
In the manufacturing method of oxidation hair-dye intermixture of the invention and oxidation hair-dye method of the invention, obtained
In intermixture, preferably by above-mentioned 1st dose with above-mentioned 2nd dose by quality ratio in the way of 1:1.5~1.5:1 by the above-mentioned 1st
Agent is mixed with above-mentioned 2nd dose.
The effect of invention
The manufacturing method of oxide hair dye, oxidation hair-dye intermixture of the invention of the invention and oxidation of the invention dye
In forwarding method, the 1st dose includes ingredient A: in the group being made of monoethanolamine, diethanol amine, triethanolamine and isopropanolamine
Compound；Ingredient B: the compound in the group being made of carbonate and bicarbonate；Ingredient C: ammonia；With ingredient D: oxidation
Dyestuff, the 2nd dose include ingredient X: hydrogen peroxide, in turn, above-mentioned 1st dose in above-mentioned 2nd dose of intermixture, mentioned component A
Content be 4.0 mass % or more, 7.0 mass % hereinafter, the content of mentioned component B is 0.20mmol/g or more 0.70mmol/g
Hereinafter, the total content of above-mentioned ammonia and ammonium ion is calculated as 0.20mmol/g or more 0.45mmol/g hereinafter, mentioned component X with ammonia conversion
Content be 1.5 mass % more than and less than 2.7 mass %, thus, it is possible to which penetrating odor when reducing use, can reduce
Damage for hair can reduce the excitement of scalp, and then can fully dye to hair.
Specific embodiment
Hereinafter, the present invention will be described in detail.
Oxide hair dye of the invention at least has the 1st dose and the 2nd dose.The manufacture of oxidation hair-dye intermixture of the invention
Oxide hair dye used in method and oxidation hair-dye method of the invention at least has the 1st dose and the 2nd dose.Above-mentioned 1st dose with
Above-mentioned 2nd dose is used in mixed way.Above-mentioned 1st dose is mixed when in use with above-mentioned 2nd dose.
In above-mentioned oxide hair dye, above-mentioned 1st dose includes: selected from by monoethanolamine, diethanol amine, triethanolamine and different
Compound in the group of Propanolamine composition；Compound in the group being made of carbonate and bicarbonate；Ammonia；It is contaminated with oxidation
Material.In oxide hair dye of the invention, above-mentioned 2nd dose includes hydrogen peroxide.
In this specification, sometimes by above-mentioned " selected from being made of monoethanolamine, diethanol amine, triethanolamine and isopropanolamine
Group in compound " be known as " ingredient (A) ".In addition, sometimes by above-mentioned " in the group being made of carbonate and bicarbonate
Compound " be known as " ingredient (B) ".In turn, above-mentioned " ammonia " is known as to " ingredient (C) " sometimes.In addition, sometimes by above-mentioned " oxidation
Dyestuff " is known as " ingredient (D) ".In addition, above-mentioned " hydrogen peroxide " to be known as to " ingredient (X) " sometimes.
In oxide hair dye of the invention, above-mentioned 1st dose with above-mentioned 2nd dose of intermixture, the content of ingredient (A) is
4.0 mass % or more, 7.0 mass % is hereinafter, the content of ingredient (B) is 0.20mmol/g or more 0.70mmol/g hereinafter, ammonia and ammonium
The total content of ion is calculated as 0.20mmol/g or more 0.45mmol/g hereinafter, the content of ingredient (X) is 1.5 mass % with ammonia conversion
More than and less than 2.7 mass %.Above-mentioned 1st dose is to mix above-mentioned 1st dose with above-mentioned 2nd dose with above-mentioned 2nd dose of intermixture
Made of intermixture.
The manufacturing method of oxidation hair-dye intermixture of the invention has mixed processes, wherein uses above-mentioned oxidation hair-dye
Above-mentioned 1st dose is mixed with above-mentioned 2nd dose, obtains intermixture by agent.Oxidation hair-dye method of the invention has following processes: mixed
Close process, wherein use above-mentioned oxide hair dye, above-mentioned 1st dose is mixed with above-mentioned 2nd dose, obtains intermixture；With hair dyeing work
Sequence, wherein hair is dyed using above-mentioned intermixture.
In the manufacturing method and oxidation hair-dye method of the invention of oxidation hair-dye intermixture of the invention, acquired
Intermixture in, make 4.0 mass % of content or more, the 7.0 mass % of ingredient (A) hereinafter, making the content of ingredient (B)
0.20mmol/g or more 0.70mmol/g is hereinafter, make the total content of ammonia and ammonium ion be calculated as 0.20mmol/g or more with ammonia conversion
0.45mmol/g is hereinafter, make the 1.5 mass % of content of ingredient (X) more than and less than 2.7 mass %.
In the present invention, due to above-mentioned composition, 1) and the amount of ammonia and ammonium ion is few, it is thus possible to it reduces when using
Penetrating odor；2) content of hydrogen peroxide is quite few, it is thus possible to reduce the damage for hair；3) it can reduce scalp
Excitement；Although 4) amount of hydrogen peroxide is quite few in turn, fully hair can be dyed.In addition, of the invention
In, although the amount of ammonia and ammonium ion is few, 4) fully hair can be dyed.
In the past, about 1) reduce use when penetrating odor, 2) reduce for hair damage, 3) reduce scalp thorn
Excitation and 4) fully hair is dyed, this four performances, exists and be extremely hard to make all that four performances are (rather than only
Only one, two, three performances) good problem.For the problem, the inventors discovered that can make 1) to can reduce use
When penetrating odor；2) it can reduce the damage for hair；3) it can reduce the excitement of scalp；And then it 4) can be abundant
Ground carries out hair to dye the good above-mentioned composition of this four performances.
In above-mentioned oxide hair dye, above-mentioned 1st dose preferably comprises phosphate dialkyl ester.
In this specification, above-mentioned " phosphate dialkyl ester " is known as sometimes " ingredient (E) ".
Above-mentioned 1st dose includes at least ingredient (A), ingredient (B), ingredient (C) and ingredient (D).Above-mentioned 1st dose preferably comprises into
Divide (E).Above-mentioned 1st dose may include other ingredients.Above-mentioned 2nd dose includes at least ingredient (X).Above-mentioned 2nd dose may include it
Its ingredient.Ingredient (A), ingredient (B), ingredient (D), ingredient (E) and other ingredients can be used only a kind respectively, can also share 2
Kind or more.
Ingredient (C) as ammonia is the state of ammonia or ammonium ion in intermixture.Ingredient (B) is selected from by ammonium carbonate and carbon
In the case where compound (at least one compound) in the group of sour hydrogen ammonium composition, ammonium carbonate and ammonium hydrogen carbonate are raw in intermixture
Ammonification or ammonium ion.In addition, also can be used in intermixture other than ingredient (B) and ingredient (C) and generate ammonia or ammonium ion
Other ingredients.
In above-mentioned oxide hair dye, above-mentioned 1st dose in the above-mentioned 2nd dose of intermixture mixed, ammonia and ammonium from
The total content of son is calculated as 0.20mmol/g or more 0.45mmol/g or less with ammonia conversion.In intermixture, ammonia and ammonium ion it is total
Content more preferably 0.25mmol/g or more in terms of ammonia conversion.When the total content of ammonia and ammonium ion is above-mentioned lower limit or more, decoloration
Power and dyeing capacity further increase.
In addition, ingredient (B) is not compound (at least one chemical combination in the group being made of ammonium carbonate and ammonium hydrogen carbonate
Object) in the case where, in intermixture, the total content of ammonia and ammonium ion from ingredient (C) is preferably in terms of ammonia conversion
0.20mmol/g or more, more preferably 0.25mmol/g or more；Preferably 0.45mmol/g or less.
In addition, ingredient (B) is compound (at least one chemical combination in the group being made of ammonium carbonate and ammonium hydrogen carbonate
Object) in the case where, in intermixture, the content of the total content of the ammonia and ammonium ion from ingredient (C), ammonium carbonate and ammonium hydrogen carbonate
Preferably 0.20mmol/g or more, more preferably 0.25mmol/g or more in terms of ammonia conversion；Preferably 0.45mmol/g or less.
Hereinafter, being illustrated to the details of each ingredient used in above-mentioned oxide hair dye.
(ingredient (A))
Ingredient (A) is alkaline reagent.Ingredient (A) is selected from by monoethanolamine, diethanol amine, triethanolamine and isopropanolamine
Compound (at least one amine compounds) in the group of composition.Ingredient (A) is played to decoloration caused by the amount for reducing ingredient (C)
The effect that power deficiency is made up keeps hair distinct, to improve dyeing capacity.Even if the amount of ingredient (C) and ingredient (X) is few, lead to
It crosses with specified amount using ingredient (A) and ingredient (B), can also be improved decolorizing ability, and improve dyeing capacity.In addition, passing through increase
The amount of ingredient (A), it is possible to reduce the amount of ingredient (C) can effectively inhibit penetrating odor when use.
From the aspect of further increasing decolorizing ability and dyeing capacity, ingredient (A) is preferably selected from by monoethanolamine and different
Compound (at least one amine compounds) in the group of Propanolamine composition, more preferably monoethanolamine is (hereinafter, sometimes will be above-mentioned
" monoethanolamine " is known as ingredient (A ')).Above-mentioned 1st dose preferably comprises ingredient (A ') as ingredient (A).
In intermixture, the content of ingredient (A) is 4.0 mass % or more, 7.0 mass % or less.In intermixture, ingredient
The content of (A ') is preferably 4.0 mass % or more, preferably 7.0 mass % or less.
In 100 mass % of intermixture, the content of ingredient (A) and the content of ingredient (A ') are respectively preferably 4.0 mass %
It above, is preferably 7.0 mass % or less；More preferably 4.0 mass % or more, more preferably 6.0 mass % or less.Ingredient (A)
When each content with ingredient (A ') is above-mentioned lower limit or more, decolorizing ability and dyeing capacity are further increased.Ingredient (A) and ingredient (A ')
Each content be the above-mentioned upper limit below when, the excitement of damage and scalp for hair is further lowered.
(ingredient (B))
Ingredient (B) is alkaline reagent.Ingredient (B) is the compound in the group being made of carbonate and bicarbonate
(at least one compound).By using ingredient (B), the pH of intermixture can be set as lower, head can be further suppressed
The excitement of skin.Ingredient (B) plays the role of making up decolorizing ability deficiency caused by the amount for reducing ingredient (C), makes hair
Hair is distinct, to improve dyeing capacity.Even if the amount of ingredient (C) and ingredient (X) is few, by with specified amount using ingredient (A) and at
Divide (B), can also be improved decolorizing ability, and improve dyeing capacity.
As ingredient (B), can enumerate ammonium carbonate, ammonium hydrogen carbonate, sodium carbonate, sodium bicarbonate, potassium carbonate, saleratus,
Guanidine carbonate, bicarbonate guanidine, lithium carbonate, calcium carbonate, magnesium carbonate and barium carbonate etc..Mentioned component (B) can be used only a kind, can also
To share two or more.
From the aspect of further increasing decolorizing ability and dyeing capacity, ingredient (B) is preferably selected from by ammonium carbonate, bicarbonate
Compound (at least one compound) in the group of ammonium, sodium carbonate and sodium bicarbonate composition.From further increasing decolorizing ability and dye
Color power, from the aspect of further suppressing the excitement of scalp simultaneously, ingredient (B) is more preferably selected from by ammonium hydrogen carbonate and carbonic acid
Compound (at least one compound) in the group of hydrogen sodium composition, further preferably ammonium hydrogen carbonate.Above-mentioned 1st dose preferably comprises
Ammonium hydrogen carbonate is as ingredient (B).
In intermixture, the content of ingredient (B) is 0.20mmol/g or more 0.70mmol/g or less.In intermixture, choosing
Free ammonium carbonate, ammonium hydrogen carbonate, sodium carbonate and sodium bicarbonate composition group in compound content, selected from by ammonium hydrogen carbonate and
The content of compound and the content of ammonium hydrogen carbonate in the group of sodium bicarbonate composition are respectively preferably 0.20mmol/g or more, excellent
It is selected as 0.70mmol/g or less.
In intermixture, the content of ingredient (B), selected from what is be made of ammonium carbonate, ammonium hydrogen carbonate, sodium carbonate and sodium bicarbonate
The content of compound in group, the content and bicarbonate of compound in the group being made of ammonium hydrogen carbonate and sodium bicarbonate
The content of ammonium is more preferably 0.25mmol/g or more, more preferably 0.65mmol/g or less respectively.Each content of ingredient (B) etc. is
When more than above-mentioned lower limit, decolorizing ability and dyeing capacity are further increased.When each content of ingredient (B) etc. is the above-mentioned upper limit or less, hair
The damage of hair and scalp further decreases.
(ingredient (C))
Ingredient (C) is alkaline reagent.By using the ammonia as ingredient (C), decolorizing ability and dyeing capacity can be greatly improved.
In the present invention, in order to reduce penetrating odor when use, ingredient (C) is used with fewer amount.That is, of the invention
In, as described above, being calculated as 0.20mmol/g or more by weight of the total content of ammonia and ammonium ion is with ammonia in intermixture
0.45mmol/g mode below is come using ingredient (C).Even if the total content of ammonia and ammonium ion is calculated as 0.20mmol/ with ammonia conversion
G or more also can reduce penetrating odor when use by using mentioned component (B).
(ingredient (D))
It, can be by coloring hairs at defined color by using the ingredient (D) as oxidation dye.
" oxidation dye " refer to the oxidation dye precursors to be developed the color by the oxidation polymerization of itself and by with oxidation dye
The reaction of precursor and both the colour coupler (coupler) for developing the color into various colors.Above-mentioned oxidation dye precursors and above-mentioned quality
Agent can be used only a kind respectively, can also share two or more.
As above-mentioned oxidation dye precursors, can enumerate phenylenediamine, amino phenols and diamino-pyridine class and it
Salt etc..As the salt, hydrochloride and sulfate etc. can be enumerated.
As above-mentioned phenylenediamine, p-phenylenediamine, Toluene-2,4-diisocyanate, 5- diamines, Toluene-3,4-dithiol, 4- diamines, 2,5- bis- can be enumerated
Aminoanisole, N- phenyl-pphenylenediamine, N- methyl-p-phenylenediamine, N, N- dimethyl-p-phenylenediamine, 6- methoxyl group -3- first
Base-p-phenylenediamine, N, N- diethyl -2- methyl-p-phenylenediamine, N- ethyl-N- (ethoxy)-p-phenylenediamine, N- (2- hydroxypropyl
Base)-p-phenylenediamine, the chloro- 6- methyl-p-phenylenediamine of 2-, the chloro- p-phenylenediamine of 2-, N, N- bis- (2- ethoxy)-p-phenylenediamine, 2,
The chloro- p-phenylenediamine of 6- bis- and the bromo- p-phenylenediamine of the chloro- 6- of 2- etc..As above-mentioned amino phenols, can enumerate para-aminophenol,
O-aminophenol, p-methylaminophenol, 2,4- diaminophenol, 5-aminosalicylic acid, 2- methyl -4-aminophenol, 3- first
Base -4-aminophenol, 2,6- dimethyl -4-aminophenol, 3,5- dimethyl -4-aminophenol, 2,3- dimethyl -4- aminobenzene
Phenol, 2,5- dimethyl -4-aminophenol, the chloro- 4-aminophenol of 2- and the chloro- 4-aminophenol of 3- etc..As above-mentioned diamino pyrrole
Pyridine class can enumerate 2,5- diamino-pyridine etc..
As above-mentioned colour coupler, for example, resorcinol, m-aminophenol, m-phenylene diamine (MPD), 2,4- diaminobenzene
Ethoxy-ethanol, 5- amino-o-cresol, 2- methyl -5- hydroxyethylaminophenol, 2,6- diamino-pyridine, catechol, even benzene three
Phenol, alpha-Naphthol, gallic acid and tannic acid and their salt etc..
The content of ingredient (D) is contemplated that dyed tone and dyeing capacity carry out appropriate adjustment.In 100 mass % of intermixture
In, the content of oxidation dye is preferably 0.01 mass % or more, more preferably 0.05 mass % or more, is more preferably
0.1 mass % or more, preferably 8.0 mass % or less, more preferably 6.0 mass % or less, further preferably 4.0 mass %
Below.When the content of ingredient (D) is above-mentioned lower limit or more, dyeing capacity is further increased.The content of ingredient (D) be the above-mentioned upper limit with
When lower, skin irritatin is reduced.
(ingredient (E))
The above-mentioned 1st dose ingredient (E) for being preferably contain as phosphate dialkyl ester.Phosphate dialkyl ester as ingredient (E)
Penetrating odor when use can be further decreased, keeps intermixture readily permeable to hair, further increases dyeing capacity.
From when further decreasing use penetrating odor, further increase dyeing capacity from the aspect of, the alkane of ingredient (E)
The carbon atom number of base is preferably 12 or more, and preferably 24 or less, more preferably 20 or less.
From when further decreasing use penetrating odor, further increase dyeing capacity from the aspect of, ingredient (E) is preferred
For dicetyl phosphate (hereinafter, sometimes referred to as ingredient (E ')).Above-mentioned 1st dose preferably comprises ingredient (E ') as ingredient (E).
In 100 mass % of intermixture, the content of ingredient (E) and the content of ingredient (E ') be preferably 0.1 mass % or more,
More preferably 0.2 mass % or more, preferably 4.0 mass % or less, more preferably 2.0 mass % or less.Ingredient (E) and ingredient
When each content of (E ') is above-mentioned lower limit or more, penetrating odor when use is further decreased, and dyeing capacity further increases.At
When dividing each content of (E) and ingredient (E ') for below the above-mentioned upper limit, the damage of hair is further decreased.
(ingredient (X))
Ingredient (X) as hydrogen peroxide makes hair decolourize and dye when mixing with alkaline reagent.
In the present invention, in order to reduce the damage for hair and the excitement of scalp, ingredient is used with fewer amount
(X).In the past, in order to show the dyeing capacity as basic performance, the content of the hydrogen peroxide in intermixture is typically set at 2.7
Quality % or more can worry the damage to hair and the stimulation to scalp when for the 2.7 mass % or more.In contrast, this hair
In bright, the content of ingredient (X) is set at a fairly low.That is, in 100 mass % of intermixture, ingredient (X's) contains in the present invention
Amount is 1.5 mass % more than and less than 2.7 mass %.The content of ingredient (X) is preferably 1.7 mass % or more, preferably 2.5 matter
Measure % or less.When the content of ingredient (X) is above-mentioned lower limit or more, decolorizing ability and dyeing capacity are further increased.The content of ingredient (X)
When for below the above-mentioned upper limit, the damage of hair and the excitement of scalp are further decreased.
(other ingredients)
Above-mentioned 1st dose and above-mentioned 2nd dose separately includes water.Above-mentioned water is not particularly limited, preferably pure water.Above-mentioned
The content of water in 1 dose of 100 mass % and the content of the water in above-mentioned 2nd dose of 100 mass % are not particularly limited, excellent respectively
It is selected as 50 mass % or more.
In order to adjust tone, above-mentioned 1st dose may include direct dyes.As direct dyes, can enumerate to nitro neighbour
Phenylenediamine, nitro p-phenylenediamine, sulfuric acid are to nitro m-phenylene diamine (MPD), 2- Amino-5-nitrophenol and picramic acid etc..Above-mentioned direct dye
Material can be used only a kind, can also share two or more.
Above-mentioned 1st dose preferably further includes reducing agent.Above-mentioned reducing agent inhibits oxidation when being exposed to atmosphere for the 1st dose
The colour developing of dyestuff.
As above-mentioned reducing agent, n-acetyl-L-cysteine, L-AA, L-AA sodium, Asia can be enumerated
Sodium sulphate, sodium pyrosulfite and thioacetic acid etc..Also their salt can be used.Above-mentioned reducing agent can be used only a kind, can also
To share two or more.
From the aspect of the colour developing for effectively inhibiting oxidation dye before using, in above-mentioned 1st dose of 100 mass %, on
State reducing agent content be preferably 0.01 mass % or more, more preferably 0.05 mass % or more, preferably 2.0 mass % with
Under, more preferably 1.0 mass % or less.
Above-mentioned 1st dose preferably comprises higher alcohol.Above-mentioned 2nd dose preferably comprises higher alcohol.At above-mentioned 1st dose and the above-mentioned 2nd
In agent, above-mentioned higher alcohol can be used only a kind, can also share two or more.
The carbon atom number of above-mentioned higher alcohol is preferably 12 or more, is more preferably 14 or more, preferably 22 or less, is more preferably
18 or less.It controls from by the viscosity of intermixture as from the aspect of better range, above-mentioned higher alcohol is preferably aliphatic unitary
Higher alcohol.
As above-mentioned higher alcohol, laruyl alcohol, myristyl alcohol, hexadecanol, stearyl alcohol, cetostearyl alcohol, different can be enumerated
Stearyl alcohol, 2- octyldodecanol, oily enol, docosyl alcohol and batyl alcohol etc..
From the viscosity of the 1st dose and intermixture is controlled for good range and improve the 1st dose storage stability in terms of
Consider, above-mentioned 1st dose preferably comprises higher alcohol.As the viscosity of the 1st dose and intermixture capable of being controlled as good range and
Improve the 1st dose of storage stability as a result, it is above-mentioned 1)~4) effect improve.
From the viscosity of the 1st dose and intermixture is controlled as better range and further increases the 1st dose of storage stability
From the aspect of, in above-mentioned 1st dose of 100 mass %, the content of above-mentioned higher alcohol be preferably 0.5 mass % or more, more preferably
For 2.0 mass % or more, preferably 5.0 mass % or less, more preferably 4.5 mass % or less.From further increasing the 2nd dose
From the aspect of storage stability, in above-mentioned 2nd dose of 100 mass %, the content of above-mentioned higher alcohol be preferably 0.5 mass % with
Upper, more preferably 2.0 mass % or more, preferably 10.0 mass % or less, more preferably 7.0 mass % or less.
The above-mentioned 1st dose of surfactant preferably comprised other than ingredient (E).Above-mentioned 2nd dose preferably comprises surfactant.
As above-mentioned surfactant, anionic surfactant, cationic surface active agent, amophoteric surface active can be enumerated
Agent and nonionic surface active agent etc..Above-mentioned surfactant can be used only a kind, can also share two or more.
As above-mentioned anionic surfactant, sulfuric acid ester type anionic surfactant, phosphoric acid ether can be enumerated
Type anionic surfactant, phosphate type anionic surfactant, sulfonic acid type anionic surfactant and carboxylic
Acid type anionic surfactant etc..
As above-mentioned amphoteric surfactant, glycine type amphoterics, aminopropan acid type both sexes can be enumerated
Surfactant, oxyneurine type amphoteric surfactant and sulfobetaine type amphoteric surfactant, imidazoline
Type amphoteric surfactant, amine oxide type amphoteric surfactant and phosphate glycine betaine type amphoteric surfactant etc..
As above-mentioned cationic surface active agent, quaternary ammonium salt cationic surfactant etc. can be enumerated.
As above-mentioned nonionic surface active agent, it is preferable to use polyoxyalkylene alkyl, fatty acid glyceride, polyoxygenated
Alkene aliphatic ester, polyoxyalkylene castor oil, polyoxyalkylene hydrogenated castor oil, alkyl polyglucoside more preferably use polyoxyalkylene
Alkyl ether.As the concrete example of polyoxyalkylene alkyl, polyoxyethylene cetyl ether, polyoxyethylene stearyl base can be enumerated
Ether, polyoxyethylene docosyl ether and polyoxethylene octylphenyl lauryl ether etc..It should be noted that above-mentioned polyoxyalkylene alkane
The addition molal quantity of the epoxyalkane of base ether is not particularly limited.
From the aspect of the adaptation for further increasing intermixture and hair, above-mentioned 2nd dose preferably comprise it is non-ionic
Surfactant.If the adaptation of intermixture and hair is high, it is above-mentioned 1)~3) effect improve.
In above-mentioned 1st dose of 100 mass %, the content of the surfactant other than ingredient (E) be preferably 0.1 mass % with
Upper, more preferably 0.5 mass % or more, preferably 10.0 mass % or less, more preferably 7.0 mass % or less.The above-mentioned 2nd
In 100 mass % of agent, the content of the surfactant other than mentioned component (E) is preferably 0.1 mass % or more, is more preferably
0.5 mass % or more, preferably 10.0 mass % or less, more preferably 7.0 mass % or less.Above-mentioned surfactant and above-mentioned
When each content of nonionic surface active agent is above-mentioned lower limit or more and the above-mentioned upper limit or less, the 2nd dose of storage stability into
One step improves and the adaptation of intermixture and hair further increases.In particular, the content of nonionic surface active agent is upper
When stating lower limit or more and the above-mentioned upper limit or less, the adaptation of intermixture and hair becomes quite high.
Above-mentioned 1st dose and at least one of above-mentioned 2nd dose may include viscosity-sensitive polymer.As tackifying high score
Son can enumerate cationized cellulose, cation property copolymer, anionic polymer etc..Above-mentioned viscosity-sensitive polymer can
To be used only a kind, two or more can also be shared.
As above-mentioned cationized cellulose, chlorination-O- [2- hydroxyl -3- (trimethyl ammonium) propyl] hydroxyl second can be enumerated
Base cellulose (Polyquaternium-10) and diallyldimethylammonium chloride hydroxyethyl cellulose (polyquaternium -4) etc..
As above-mentioned cation property copolymer, cationic starch, cationized guar gum derivative, diene can be enumerated
Quaternary ammonium salts polymer, diallyl quaternary ammonium/acrylic copolymer, diallyl quaternary ammonium/acrylamide copolymer and
Quaternised polyvinyl pyrrolidinone derivatives etc..As the concrete example of above-mentioned cation property copolymer, chlorination-O- can be enumerated
[2- hydroxyl -3- (trimethyl ammonium) propyl] guar gum, dimethyl diallyl ammonium chloride acrylic acid copolymer thing liquid, dimethyl
Diallyl ammonium chloride acrylamide copolymer and vinyl pyrrolidone dimethylamino methyl acrylate based on sulphur
The quaternary ammonium derivative etc. that dimethyl phthalate obtains.
As above-mentioned anionic polymer, xanthan gum, alkyl acrylate methacrylate can be enumerated
Ester polyoxyethylene stearyl base ether copolymer, alkyl acrylate methacrylic acid Ju ethylene oxide behenyl alcohol copolyether,
Alkyl acrylate itaconic acid polyoxyethylene stearyl base ether copolymer and alkyl acrylate methacrylic acid polyoxyethylene
Stearyl ether cross-linked polymer etc..
Above-mentioned 1st dose and at least one of above-mentioned 2nd dose preferably comprises hydro carbons.Above-mentioned 1st dose and above-mentioned 2nd dose preferably
Separately include hydro carbons.Above-mentioned hydro carbons can be used only a kind, can also share two or more.
As above-mentioned hydro carbons, paraffin, atoleine, liquid isoparaffin, squalene and saualane etc. can be enumerated.It is above-mentioned
Hydro carbons can be used only a kind, can also share two or more.
In above-mentioned 1st dose of 100 mass % and in above-mentioned 2nd dose of 100 mass %, each content difference of above-mentioned hydro carbons is preferred
For 0.01 mass % or more, more preferably 0.1 mass % or more, preferably 5.0 mass % or less, more preferably 4.0 mass %
Below.In 100 mass % of intermixture, the content of above-mentioned hydro carbons is preferably 0.01 mass % or more, more preferably 0.1 mass %
More than, preferably 5.0 mass % or less, more preferably 4.0 mass % or less.The content of above-mentioned hydro carbons is the above-mentioned upper limit or less
When, the slickness of the hair after hair dyeing becomes more preferably, and then is difficult to dyeing caused by generating excessive hydro carbons and hinders.
Above-mentioned 1st dose and at least one of above-mentioned 2nd dose preferably comprises silicone oil.Above-mentioned 1st dose and above-mentioned 2nd dose preferably
Separately include silicone oil.By using silicone oil, hand sense of touch during rinsing becomes more preferably after hair dyeing, and then the hair after having hair dyed is smooth
Property becomes more preferable.
As above-mentioned silicone oil, methyl polysiloxane, methyl phenyl silicone, octamethylpolysiloxane, eight can be enumerated
Methyl cyclotetrasiloxane, prestox cyclopentasiloxane, decamethylcyclopentaandoxane, methylhydrogenpolysi,oxane, amino modified silicone
With polyether modified silicone etc..Above-mentioned silicone oil can be used only a kind, can also share two or more.
Above-mentioned 1st dose and at least one of above-mentioned 2nd dose preferably comprises polyalcohol.Above-mentioned 1st dose and above-mentioned 2nd dose excellent
Choosing separately includes polyalcohol.Above-mentioned polyalcohol can be used only a kind, can also share two or more.
As above-mentioned polyalcohol, polyethylene glycol, glycerol, polyglycereol, propylene glycol, dipropylene glycol, 1,3- fourth two can be enumerated
Alcohol, 1,2- pentanediol and 1,2- ethohexadiol etc..
The above-mentioned 2nd dose stabilizer that may include hydrogen peroxide.The stabilizer of above-mentioned hydrogen peroxide can be used only a kind,
Two or more can also be shared.
As the stabilizer of above-mentioned hydrogen peroxide, phenoxetol, phenaetin and hydroxyethane diphosphonic acid can be enumerated
Deng.
In above-mentioned oxide hair dye, in a range that does not hinder the effect of the present invention, can be used for example D-sorbite,
The sugar alcohols such as maltitol and trehalose；Chelating agent；Antioxidant；Plant extracts；Pigment；PH adjusting agent；Fragrance；Preservative；
Solvent etc..
(details of the oxide hair dye of multi-agent formula)
Above-mentioned oxide hair dye at least has above-mentioned 1st dose and above-mentioned 2nd dose.That is, above-mentioned oxide hair dye is that at least have
For above-mentioned 1st dose and above-mentioned 2nd dose of oxide hair dye complete set of supplies.Above-mentioned oxide hair dye can be except above-mentioned 1st dose and upper
It states and is further equipped with the 3rd dose outside the 2nd dose.As the 3rd dose, conditioners (ヘ ア リ Application ス drug), hair-care agent (ヘ can be enumerated
ア ト リ ー ト メ Application ト drug) and hair conditioner (ヘ ア U Application デ ィ シ ョ ニ Application グ drug) etc..Above-mentioned oxide hair dye includes above-mentioned 3rd dose
And above-mentioned 3rd dose with above-mentioned 1st dose and it is above-mentioned 2nd dose be used in mixed way in the case where, above-mentioned intermixture comprising above-mentioned 3rd dose,
Above-mentioned intermixture is by the way that above-mentioned 1st dose, above-mentioned 2nd dose and above-mentioned 3rd dose to be obtained by mixing.
In above-mentioned oxide hair dye, above-mentioned 1st dose with above-mentioned 2nd dose be mixed and in the form of intermixture use.Make
For above-mentioned 1st dose, the character of above-mentioned 2nd dose and intermixture, liquid, lotion state, gelatin and emulsifiable paste shape etc. can be enumerated.
Above-mentioned intermixture is preferably 4000mPas or more, is more preferably 6000mPas or more in 25 DEG C of viscosity, excellent
It is selected as 25000mPas or less, more preferably 20000mPas or less.The viscosity of above-mentioned intermixture be above-mentioned lower limit more than and
When below the above-mentioned upper limit, 1) penetrating odor when using further decreases, and 2) damage of hair is further decreased, 3) head
The excitement of skin further decreases, and then 4) hair is more effectively colored.
About the viscosity of intermixture, using Brookfield viscometer (manufacture of TOKIMEC society), according to the character of intermixture, at 25 DEG C
Under rotor No.3,12rpm and 1 minute or rotor No.4,12rpm and 1 minute it is each under the conditions of be measured.
Above-mentioned intermixture is preferably 9.0 or more, is more preferably 9.4 or more, preferably 10.5 or less, more excellent in 25 DEG C of pH
It is selected as 10.0 or less.When pH when mixing is above-mentioned lower limit or more and the above-mentioned upper limit or less, following four kinds can be balancedly improved
Performance: 1) use when penetrating odor reduction, 2) for the reduction of the damage of hair, 3) reduction of the excitement of scalp,
4) dyeing of hair.
Above-mentioned oxide hair dye can be mixed in the mixing container, can also be mixed on comb, can be with
It is mixed on hair.1st dose and the 2nd dose can be discharged by the different containers that accommodates with mixed state, can also be by not
Same receiving container is discharged with unmixing state.
As mixing vessel, the mixing vessel for having container body and the lid with jetting nozzle can be enumerated.As upper
Receiving container is stated, aerosol container etc. can be enumerated.
In above-mentioned oxide hair dye, above-mentioned 1st dose with above-mentioned 2nd dose in terms of mass ratio (the 1st dose: the 2nd dose) preferably with
1:5~5:1 is used, and is more preferably used with 1:3~3:1, further preferably with 1:2~2:1 use.From good with the 2nd dose by the 1st dose
Mix well, so balancedly improve 1) use when penetrating odor reduction, 2) for the reduction of the damage of hair, 3) head
From the aspect of these four performances of the dyeing of the reduction of the excitement of skin, 4) hair, above-mentioned 1st dose with above-mentioned 2nd dose with quality
Than counting preferably with 1:1.5~1.5:1 use.Therefore, above-mentioned 1st dose in above-mentioned oxide hair dye complete set of supplies with the 2nd dose
Mass ratio (the 1st dose: the 2nd dose) is preferably 1:5~5:1, more preferably 1:3~3:1, is more preferably 1:2~2:1, special
Preferably 1:1.5~1.5:1.(the 1st dose with the 2nd dose of intermixture) is preferably the matter of the 1st dose with the 2nd dose that is, above-mentioned intermixture
Amount (more preferably 1:3~3:1, further preferably 1:2~2:1, is particularly preferably than (the 1st dose: the 2nd dose) for 1:5~5:1
1:1.5~1.5:1) intermixture.
Above-mentioned oxide hair dye can be used in dark hair, palm fibre hair, yellow hair and hair containing white hair etc..Since hair dyeing power is excellent,
Thus, oxide hair dye of the invention can be suitable for the hair containing white hair.
Embodiment
Hereinafter, enumerating embodiment and the present invention is specifically described in comparative example.The present invention is not limited to below
Embodiment.
<preparation of sample>
Each ingredient shown in following tables 1,2 is subjected to mixture with content shown in following tables 1,2, utilizes well known side
Method is mixed, and the 1st dose and the 2nd dose are thus obtained.
Next, by the 1st dose and the 2nd dose with mixing ratio (mass ratio) shown in following tables 1,2 (the 1st dose: the 2nd dose) into
Row mixing, obtains the intermixture of embodiment 1~12 and comparative example 1~10.
<preparation of standard sample>
In order to carry out the evaluation of aftermentioned excitement, by each ingredient shown in following tables 1,2 shown in following tables 1,2
Content carry out mixture, be mixed using well known method, thus obtain the 1st dose and the 2nd dose.
Next, by the 1st dose and the 2nd dose with mixing ratio (mass ratio) shown in following tables 1,2 (the 1st dose: the 2nd dose) into
Row mixing, obtains the intermixture of model formula.
<preparation method that pieces is used in evaluation>
The obtained intermixture of 2g is applied to black people mao mao beam (manufacture of STAFFS society, length 10cm, weight 1g),
30 DEG C are placed 30 minutes.Thereafter intermixture is washed with shampoo, is dried with drying machine, prepared black people mao mao
The evaluation pieces of beam dyeing.
(evaluation)
(1) pH of intermixture
The pH of obtained intermixture and the intermixture being formulated with model is measured.It should be noted that
Use pH meter in pH measurement (model: F-74, hole field production society, institute manufacture).
(2) excitement (sensory evaluation)
In the region from symmetrical about 1cm × 2cm square that the neck median line of measured deviates, respectively simultaneously
It is coated with the rigid mixed intermixture 1g of just mixed each intermixture (intermixture of evaluation object) 1g and model formula, according to
Excitement when following benchmark are to after coating by 5 minutes determines.
[determinating reference of excitement (sensory evaluation)]
Zero (good): compared with the intermixture of model formula, the excitement of the intermixture of evaluation object is few.
× (bad): compared with the intermixture of model formula, the excitement of the intermixture of evaluation object is more, alternatively, model
The excitement of intermixture of intermixture and evaluation object of formula is identical.
(3) penetrating odor (ammonia detectable concentration)
1st dose of 2.5g, the 2nd dose of 2.5g are put into 100mL beaker and are mixed, after keeping surface flat, which is burnt
Cup is placed in 2L beaker, closed to place 1 minute.After placement, burnt using ammonia detection pipe (manufacture of GASTEC society, No.3M) suction
Gas 100mL in cup, is measured ammonia density.According to ammonia detectable concentration, penetrating odor is carried out according to following benchmark
Determine.
[determinating reference of penetrating odor (ammonia detectable concentration)]
Zero (good): ammonia detectable concentration is 150ppm or less
△ (slightly good): ammonia detectable concentration is more than 150ppm and is 200ppm or less
× (bad): ammonia detectable concentration is more than 200ppm
(4) damage of hair
The black people mao mao Shu Jinhang evaluation dyed is evaluated with pieces using by obtained intermixture.
Using automatic contact angle meter (manufacture of consonance surface chemistry society, DM500 type), the hair acquired by above-mentioned evaluation pieces is added dropwise
0.5 μ L of pure water, measures the water contact angle of hair.
It should be noted that the water contact angle that the untreated black people mao mao beam of dyeing processing is not carried out is 125 °.
[determinating reference of the damage of hair]
Zero (good): contact angle is 116 ° or more
△ (slightly good): contact angle is 110 ° more than and less than 116 °
× (bad): contact angle is less than 110 °
(5) dyeing capacity
It to the black people mao mao Shu Jinhang evaluation pieces dyed and is not carried out using by obtained intermixture
The untreated black people mao mao beam of processing is dyed to evaluate.Using spectral photometric colour measuring meter (Konica Minolta society manufacture,
CM3610d type), it measures and evaluates and uses pieces and the untreated respective L of black people mao mao beam*a*b*The L of colorimeter system*Value, a*Value, b*
Value, calculates the color difference Δ E of evaluation pieces and untreated black people mao mao beam*ab。
It should be noted that Δ E*Ab is higher, then hair is distincter, is colored well.
[determinating reference of dyeing capacity]
Zero (good): Δ E*Ab is 1.7 or more
△ (slightly good): Δ E*Ab is 1.5 more than and less than 1.7
× (bad): Δ E*Ab is less than 1.5
Details and the evaluation result such as composition are shown in following table 1, in 2.Following table 1, the content of each ingredient in 2
Mixed unit is " quality % ".
[table 1]
[table 2]
Claims (11)
1. a kind of oxide hair dye at least has the 1st dose and the 2nd dose,
Described 1st dose is used in mixed way with described 2nd dose,
Described 1st dose includes following compositions A, following compositions B and following compositions D,
Described 1st dose is made comprising following compositions C or comprising the compound in the group being made of ammonium carbonate and ammonium hydrogen carbonate
For the ingredient B,
Described 2nd dose includes following compositions X,
Described 1st dose in the 2nd dose of the intermixture, the content of the ingredient A be 4.0 mass % or more, 7.0 mass % with
Under, the content of the ingredient B is 0.20mmol/g or more 0.70mmol/g hereinafter, the total content of ammonia and ammonium ion is in terms of ammonia conversion
For 0.20mmol/g or more 0.45mmol/g hereinafter, the content of the ingredient X is 1.5 mass % more than and less than 2.7 mass %,
The mass ratio of the content of the ingredient A/ingredient X content is 1.9~3.2,
Ingredient A: the compound in the group being made of monoethanolamine, diethanol amine, triethanolamine and isopropanolamine；
Ingredient B: the compound in the group being made of carbonate and bicarbonate；
Ingredient C: ammonia；
Ingredient D: oxidation dye；
Ingredient X: hydrogen peroxide.
2. oxide hair dye as described in claim 1, wherein the described 1st dose pH with the 2nd dose of the intermixture at 25 DEG C
It is 9.4 or more 10.0 or less.
3. oxide hair dye as claimed in claim 1 or 2, wherein described 1st dose further includes following compositions E,
Ingredient E: phosphate dialkyl ester.
4. oxide hair dye as claimed in claim 1 or 2, wherein described 1st dose is 1 with described 2nd dose by quality ratio:
1.5~1.5:1.
5. oxide hair dye as claimed in claim 3, wherein described 1st dose is 1:1.5 with described 2nd dose by quality ratio
~1.5:1.
6. a kind of manufacturing method of oxidation hair-dye intermixture, with mixed processes, wherein using at least having comprising following
The 1st dose and the 2nd dose of the oxide hair dye comprising following compositions X of ingredient A, following compositions B and following compositions D, will be described
1st dose mixes with described 2nd dose, obtains intermixture,
Described 1st dose is made comprising following compositions C or comprising the compound in the group being made of ammonium carbonate and ammonium hydrogen carbonate
For the ingredient B,
In obtained intermixture, make 4.0 mass % of content or more, the 7.0 mass % of the ingredient A hereinafter, make it is described at
The content for dividing B is 0.20mmol/g or more 0.70mmol/g hereinafter, being calculated as the total content of ammonia and ammonium ion with ammonia conversion
0.20mmol/g or more 0.45mmol/g hereinafter, make the 1.5 mass % of content of the ingredient X more than and less than 2.7 mass %,
Make the mass ratio 1.9~3.2 of content/ingredient X content of the ingredient A,
Ingredient A: the compound in the group being made of monoethanolamine, diethanol amine, triethanolamine and isopropanolamine；
Ingredient B: the compound in the group being made of carbonate and bicarbonate；
Ingredient C: ammonia；
Ingredient D: oxidation dye；
Ingredient X: hydrogen peroxide.
7. the manufacturing method of oxidation hair-dye intermixture as claimed in claim 6, wherein in obtained intermixture, make
25 DEG C of pH is 9.4 or more 10.0 or less.
8. the manufacturing method of oxidation hair-dye intermixture as claimed in claims 6 or 7, wherein in obtained intermixture,
By described 1st dose with described 2nd dose by quality ratio in the way of 1:1.5~1.5:1 by described 1st dose and described 2nd dose
Mixing.
9. a kind of oxidation hair-dye method, with following processes:
Mixed processes, wherein use the 1st dose and packet at least having comprising following compositions A, following compositions B and following compositions D
The 2nd dose of the oxide hair dye of the X containing following compositions, described 1st dose is mixed with described 2nd dose, obtains intermixture；With
Hair dyeing process, wherein hair is dyed using the intermixture,
Described 1st dose is made comprising following compositions C or comprising the compound in the group being made of ammonium carbonate and ammonium hydrogen carbonate
For the ingredient B,
In obtained intermixture, make 4.0 mass % of content or more, the 7.0 mass % of the ingredient A hereinafter, make it is described at
The content for dividing B is 0.20mmol/g or more 0.70mmol/g hereinafter, being calculated as the total content of ammonia and ammonium ion with ammonia conversion
0.20mmol/g or more 0.45mmol/g hereinafter, make the 1.5 mass % of content of the ingredient X more than and less than 2.7 mass %,
Make the mass ratio 1.9~3.2 of content/ingredient X content of the ingredient A,
Ingredient A: the compound in the group being made of monoethanolamine, diethanol amine, triethanolamine and isopropanolamine；
Ingredient B: the compound in the group being made of carbonate and bicarbonate；
Ingredient C: ammonia；
Ingredient D: oxidation dye；
Ingredient X: hydrogen peroxide.
10. oxidation hair-dye method as claimed in claim 9, wherein in obtained intermixture, make 25 DEG C of pH 9.4
Above 10.0 or less.
11. the oxidation hair-dye method as described in claim 9 or 10, wherein in obtained intermixture, according to the described 1st
Agent by quality ratio mixes described 1st dose with described 2nd dose for the mode of 1:1.5~1.5:1 with described 2nd dose.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014162907 | 2014-08-08 | ||
| JP2014162908 | 2014-08-08 | ||
| JP2014-162908 | 2014-08-08 | ||
| JP2014-162907 | 2014-08-08 | ||
| PCT/JP2015/071099 WO2016021424A1 (en) | 2014-08-08 | 2015-07-24 | Oxidative hair dye, method for manufacturing mixture for oxidative hair dying, and oxidative hair dying method |
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| Publication Number | Publication Date |
|---|---|
| CN106102701A CN106102701A (en) | 2016-11-09 |
| CN106102701B true CN106102701B (en) | 2019-09-17 |
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| CN201580013149.6A Active CN106102702B (en) | 2014-08-08 | 2015-07-24 | Oxide hair dye, the manufacturing method of oxidation hair-dye intermixture and oxidation hair-dye method |
| CN201580012759.4A Active CN106102701B (en) | 2014-08-08 | 2015-07-24 | Oxide hair dye, the manufacturing method of oxidation hair-dye intermixture and oxidation hair-dye method |
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| JP7033391B2 (en) * | 2016-03-08 | 2022-03-10 | クローダジャパン株式会社 | Hair dye for hair |
| JP7146520B2 (en) * | 2017-09-20 | 2022-10-04 | 花王株式会社 | powdered composition |
| CN111278409B (en) * | 2017-10-27 | 2023-01-06 | 株式会社爱茉莉太平洋 | Hair dye composition |
| JP7164875B2 (en) * | 2019-02-18 | 2022-11-02 | 株式会社ダリヤ | Aerosol type hair dye or decolorant composition |
| JP7164876B2 (en) * | 2019-02-18 | 2022-11-02 | 株式会社ダリヤ | Aerosol type hair dye or decolorant composition |
| JP7396622B2 (en) * | 2019-09-06 | 2023-12-12 | ホーユー株式会社 | Oxidative hair dye composition and hair dyeing method |
| CN111920695A (en) * | 2020-09-12 | 2020-11-13 | 四川大学 | Hair dye, preparation method and use method thereof |
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| JP2002255763A (en) * | 2001-03-02 | 2002-09-11 | Kao Corp | Hair dye composition |
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| JP5759149B2 (en) * | 2010-11-18 | 2015-08-05 | 株式会社マンダム | First agent composition and multi-component bleaching or oxidative hair dye |
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- 2015-07-24 CN CN201580013149.6A patent/CN106102702B/en active Active
- 2015-07-24 JP JP2016540153A patent/JP6359667B2/en active Active
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| JP2001206825A (en) * | 2000-01-25 | 2001-07-31 | Kao Corp | Hair treating agent |
| JP2002255763A (en) * | 2001-03-02 | 2002-09-11 | Kao Corp | Hair dye composition |
| JP2002370949A (en) * | 2001-06-12 | 2002-12-24 | Hoyu Co Ltd | Decolorant composition and hair dye composition |
| JP2005255656A (en) * | 2004-03-15 | 2005-09-22 | Hoyu Co Ltd | Hair dyeing method |
| JP2008290971A (en) * | 2007-05-24 | 2008-12-04 | Croda Japan Kk | Hair-treating composition |
| JP2010126497A (en) * | 2008-11-28 | 2010-06-10 | Mandom Corp | Oxidation hair dye |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6359668B2 (en) | 2018-07-18 |
| JPWO2016021425A1 (en) | 2017-04-27 |
| CN106102702A (en) | 2016-11-09 |
| JPWO2016021424A1 (en) | 2017-04-27 |
| WO2016021425A1 (en) | 2016-02-11 |
| WO2016021424A1 (en) | 2016-02-11 |
| CN106102701A (en) | 2016-11-09 |
| CN106102702B (en) | 2019-09-17 |
| JP6359667B2 (en) | 2018-07-18 |
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