JP5464844B2 - Oxidative hair dye - Google Patents
Oxidative hair dye Download PDFInfo
- Publication number
- JP5464844B2 JP5464844B2 JP2008304058A JP2008304058A JP5464844B2 JP 5464844 B2 JP5464844 B2 JP 5464844B2 JP 2008304058 A JP2008304058 A JP 2008304058A JP 2008304058 A JP2008304058 A JP 2008304058A JP 5464844 B2 JP5464844 B2 JP 5464844B2
- Authority
- JP
- Japan
- Prior art keywords
- agent
- dye
- hair
- oxidative
- oxidative hair
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 230000001590 oxidative effect Effects 0.000 title claims description 50
- 239000000118 hair dye Substances 0.000 title claims description 31
- 239000003795 chemical substances by application Substances 0.000 claims description 63
- 239000000975 dye Substances 0.000 claims description 38
- 238000004043 dyeing Methods 0.000 claims description 17
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 16
- 229960001755 resorcinol Drugs 0.000 claims description 16
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 14
- 230000003647 oxidation Effects 0.000 claims description 12
- 238000007254 oxidation reaction Methods 0.000 claims description 12
- 239000007800 oxidant agent Substances 0.000 claims description 9
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000002243 precursor Substances 0.000 claims description 8
- 239000003002 pH adjusting agent Substances 0.000 claims description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 5
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 239000000982 direct dye Substances 0.000 claims description 4
- 229940102253 isopropanolamine Drugs 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 238000013329 compounding Methods 0.000 claims description 3
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- 235000005985 organic acids Nutrition 0.000 claims description 3
- -1 ascorbyl citrate Chemical compound 0.000 description 32
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 19
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000008213 purified water Substances 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 229960000541 cetyl alcohol Drugs 0.000 description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 239000002280 amphoteric surfactant Substances 0.000 description 5
- 229960004585 etidronic acid Drugs 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 4
- 229940058015 1,3-butylene glycol Drugs 0.000 description 3
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 239000001099 ammonium carbonate Substances 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229940124274 edetate disodium Drugs 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 3
- 239000011755 sodium-L-ascorbate Substances 0.000 description 3
- 235000019187 sodium-L-ascorbate Nutrition 0.000 description 3
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 2
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- RNPXCFINMKSQPQ-UHFFFAOYSA-N dicetyl hydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCOP(O)(=O)OCCCCCCCCCCCCCCCC RNPXCFINMKSQPQ-UHFFFAOYSA-N 0.000 description 2
- 229940093541 dicetylphosphate Drugs 0.000 description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 229940093915 gynecological organic acid Drugs 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- ZZYXNRREDYWPLN-UHFFFAOYSA-N pyridine-2,3-diamine Chemical class NC1=CC=CN=C1N ZZYXNRREDYWPLN-UHFFFAOYSA-N 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 229940031723 1,2-octanediol Drugs 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- OQWWMUWGSBRNMA-UHFFFAOYSA-N 1-(2,4-diaminophenoxy)ethanol Chemical compound CC(O)OC1=CC=C(N)C=C1N OQWWMUWGSBRNMA-UHFFFAOYSA-N 0.000 description 1
- XYAQUYKPDDPZHG-UHFFFAOYSA-N 1-(4-aminoanilino)propan-2-ol Chemical compound CC(O)CNC1=CC=C(N)C=C1 XYAQUYKPDDPZHG-UHFFFAOYSA-N 0.000 description 1
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical class CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- NXVHEHXRZVQDCR-UHFFFAOYSA-N 1-n,1-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1C NXVHEHXRZVQDCR-UHFFFAOYSA-N 0.000 description 1
- VRBHTEGUHVNKEA-UHFFFAOYSA-N 16-methylheptadecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC(C)C VRBHTEGUHVNKEA-UHFFFAOYSA-N 0.000 description 1
- 229940113489 2,4-diaminophenoxyethanol Drugs 0.000 description 1
- 229940113490 2,4-diaminophenoxyethanol hydrochloride Drugs 0.000 description 1
- HQCHAOKWWKLXQH-UHFFFAOYSA-N 2,6-Dichloro-para-phenylenediamine Chemical compound NC1=CC(Cl)=C(N)C(Cl)=C1 HQCHAOKWWKLXQH-UHFFFAOYSA-N 0.000 description 1
- PBVFDMZFBPZIMC-UHFFFAOYSA-N 2-(2,4-diaminophenoxy)ethanol;hydrochloride Chemical compound Cl.NC1=CC=C(OCCO)C(N)=C1 PBVFDMZFBPZIMC-UHFFFAOYSA-N 0.000 description 1
- ISCYHXYLVTWDJT-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)anilino]ethanol Chemical compound NC1=CC=C(N(CCO)CCO)C=C1 ISCYHXYLVTWDJT-UHFFFAOYSA-N 0.000 description 1
- MGLZGLAFFOMWPB-UHFFFAOYSA-N 2-chloro-1,4-phenylenediamine Chemical compound NC1=CC=C(N)C(Cl)=C1 MGLZGLAFFOMWPB-UHFFFAOYSA-N 0.000 description 1
- MPUYRZSQOVOWER-UHFFFAOYSA-N 2-chloro-6-methylbenzene-1,4-diamine Chemical compound CC1=CC(N)=CC(Cl)=C1N MPUYRZSQOVOWER-UHFFFAOYSA-N 0.000 description 1
- KNRVAYVZVIKHHL-UHFFFAOYSA-N 2-methoxy-5-methylbenzene-1,4-diamine Chemical compound COC1=CC(N)=C(C)C=C1N KNRVAYVZVIKHHL-UHFFFAOYSA-N 0.000 description 1
- HGUYBLVGLMAUFF-UHFFFAOYSA-N 2-methoxybenzene-1,4-diamine Chemical compound COC1=CC(N)=CC=C1N HGUYBLVGLMAUFF-UHFFFAOYSA-N 0.000 description 1
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 1
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- 229940018563 3-aminophenol Drugs 0.000 description 1
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- URLLLTTZXHBPEK-UHFFFAOYSA-N CCCCC(C1N)=CC=CC1(N)Cl Chemical class CCCCC(C1N)=CC=CC1(N)Cl URLLLTTZXHBPEK-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
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- MLSJBGYKDYSOAE-DCWMUDTNSA-N L-Ascorbic acid-2-glucoside Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)=C1O MLSJBGYKDYSOAE-DCWMUDTNSA-N 0.000 description 1
- 150000000996 L-ascorbic acids Chemical class 0.000 description 1
- QAQJMLQRFWZOBN-LAUBAEHRSA-N L-ascorbyl-6-palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](O)[C@H]1OC(=O)C(O)=C1O QAQJMLQRFWZOBN-LAUBAEHRSA-N 0.000 description 1
- 239000011786 L-ascorbyl-6-palmitate Substances 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- BFQXHKUVKHEARI-UHFFFAOYSA-N N',N'-dimethylethane-1,2-diamine tetradecanoic acid Chemical compound CN(C)CCN.CCCCCCCCCCCCCC(O)=O BFQXHKUVKHEARI-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
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- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
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- 239000006096 absorbing agent Substances 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
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- QKWNIOMGXBERHJ-RXSVEWSESA-N azane;(2r)-2-[(1s)-1,2-dihydroxyethyl]-3,4-dihydroxy-2h-furan-5-one Chemical compound N.OC[C@H](O)[C@H]1OC(=O)C(O)=C1O QKWNIOMGXBERHJ-RXSVEWSESA-N 0.000 description 1
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- 235000010376 calcium ascorbate Nutrition 0.000 description 1
- 239000011692 calcium ascorbate Substances 0.000 description 1
- 229940047036 calcium ascorbate Drugs 0.000 description 1
- BLORRZQTHNGFTI-ZZMNMWMASA-L calcium-L-ascorbate Chemical compound [Ca+2].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] BLORRZQTHNGFTI-ZZMNMWMASA-L 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
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- 235000015165 citric acid Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
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- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- QZIVCPPRKFXYKE-UHFFFAOYSA-N diethylamino octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)ON(CC)CC QZIVCPPRKFXYKE-UHFFFAOYSA-N 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- BHDAXLOEFWJKTL-UHFFFAOYSA-L dipotassium;carboxylatooxy carbonate Chemical compound [K+].[K+].[O-]C(=O)OOC([O-])=O BHDAXLOEFWJKTL-UHFFFAOYSA-L 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000010350 erythorbic acid Nutrition 0.000 description 1
- 239000004318 erythorbic acid Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- LRBQNJMCXXYXIU-QWKBTXIPSA-N gallotannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@H]2[C@@H]([C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-QWKBTXIPSA-N 0.000 description 1
- 229960002449 glycine Drugs 0.000 description 1
- 235000013905 glycine and its sodium salt Nutrition 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical class OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229940026239 isoascorbic acid Drugs 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229940018564 m-phenylenediamine Drugs 0.000 description 1
- 229940074358 magnesium ascorbate Drugs 0.000 description 1
- AIOKQVJVNPDJKA-ZZMNMWMASA-L magnesium;(2r)-2-[(1s)-1,2-dihydroxyethyl]-4-hydroxy-5-oxo-2h-furan-3-olate Chemical compound [Mg+2].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] AIOKQVJVNPDJKA-ZZMNMWMASA-L 0.000 description 1
- KBOPZPXVLCULAV-UHFFFAOYSA-N mesalamine Chemical compound NC1=CC=C(O)C(C(O)=O)=C1 KBOPZPXVLCULAV-UHFFFAOYSA-N 0.000 description 1
- 229960004963 mesalazine Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
- 238000001139 pH measurement Methods 0.000 description 1
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- 229960003893 phenacetin Drugs 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000019275 potassium ascorbate Nutrition 0.000 description 1
- 229940017794 potassium ascorbate Drugs 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- CONVKSGEGAVTMB-RXSVEWSESA-M potassium-L-ascorbate Chemical compound [K+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] CONVKSGEGAVTMB-RXSVEWSESA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- MIROPXUFDXCYLG-UHFFFAOYSA-N pyridine-2,5-diamine Chemical compound NC1=CC=C(N)N=C1 MIROPXUFDXCYLG-UHFFFAOYSA-N 0.000 description 1
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 231100000279 safety data Toxicity 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000010352 sodium erythorbate Nutrition 0.000 description 1
- 239000004320 sodium erythorbate Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、酸化染毛剤に関する。更に詳しくは、毛髪を黄色の色相に染色することのできる酸化染毛剤に関する。尚、本発明でいう黄色とは、マンセル表色系の色相5Yから10YR、明度8以上、彩度8以上の色相を表す。 The present invention relates to an oxidative hair dye. More specifically, the present invention relates to an oxidative hair dye capable of dyeing hair into a yellow hue. Note that yellow in the present invention represents a Munsell color system hue of 5Y to 10YR, a brightness of 8 or more, and a saturation of 8 or more.
酸化染毛剤は、アルカリ剤と酸化染料を含有する第1剤と、酸化剤を含有する第2剤とからなる二剤式のものが一般的である。このニ剤式の酸化染毛剤は、使用時に第1剤と第2剤とを混合することにより毛髪中のメラニン色素を酸化分解すると共に、無色低分子の酸化染料を毛髪内で酸化重合して種々の色相の色素を生成させ、毛髪を所望の色に染色する。 The oxidative hair dye is generally of a two-component type comprising a first agent containing an alkali agent and an oxidative dye and a second agent containing an oxidant. This two-part oxidative hair dye oxidizes and decomposes the melanin pigment in hair by mixing the first and second agents at the time of use, and oxidatively polymerizes colorless low-molecular oxidative dyes in the hair. To produce pigments of various hues and dye the hair to the desired color.
しかし、近年、酸化染毛剤に配合される酸化染料の安全性に対する懸念が高まってきており、一部の酸化染料では安全性の観点から、使用が控えられるようになってきている。特に欧州諸国では、安全性に懸念のある酸化染料や、安全性データが十分ではない酸化染料については、製品に配合することが禁止されるようになってきている。そのため、安全性に懸念のある酸化染料については、世界的に使用が避けられるようになってきた。 However, in recent years, there has been a growing concern about the safety of oxidative dyes blended with oxidative hair dyes, and some oxidative dyes have been refrained from the viewpoint of safety. Especially in European countries, it is becoming prohibited to mix oxidative dyes with safety concerns and oxidative dyes with insufficient safety data into products. For this reason, the use of oxidation dyes with safety concerns has been avoided worldwide.
そして、従来、毛髪を黄色系の色相に染色する際に用いられていたオルトアミノフェノールも、安全性の観点から欧州諸国で使用が規制されるようになってきたため、該酸化染料の使用も避けられるようになってきた。このため、毛髪を黄色系の色相に染色する酸化染料の組合せができないという問題がある。 Also, ortho-aminophenol, which has been conventionally used for dyeing hair into a yellowish hue, has been regulated in European countries from the viewpoint of safety, so avoid the use of such oxidation dyes. Has come to be. For this reason, there exists a problem that the combination of the oxidation dye which dye | stains hair to a yellowish hue cannot be performed.
この問題点を解決するために、従来から、p−ニトロ−o−フェニレンジアミンなどのニトロ系の直接染料を用いることにより、毛髪を黄色の色相に染色する方法が行われている(例えば、特許文献1参照)。しかしながら、直接染料による染色は、毛髪の表面に染料を付着させて染色することから、日常の洗髪などにより退色が起こり易く、堅牢性に劣るという問題がある。 In order to solve this problem, conventionally, a method of dyeing hair into a yellow hue by using a nitro-based direct dye such as p-nitro-o-phenylenediamine has been performed (for example, patents). Reference 1). However, dyeing with a direct dye involves dyeing on the surface of the hair and dyeing it, so that there is a problem that fading is likely to occur due to daily hair washing or the like and the fastness is inferior.
また、本発明に関連する技術として、パラメチルアミノフェノールとレゾルシンを使用して毛髪を染色する酸化染毛剤の報告がなされている(例えば、特許文献2〜6参照)。しかし、これらいずれの酸化染毛剤も、毛髪を黄色系の色相へ染色しようとするものではなく、単に混合される種々の染料の一部として用いられているに過ぎない。 In addition, as a technique related to the present invention, there has been reported an oxidative hair dye that dyes hair using paramethylaminophenol and resorcin (see, for example, Patent Documents 2 to 6). However, any of these oxidative hair dyes are not intended to dye hair into a yellowish hue, but are merely used as part of various dyes to be mixed.
本発明は、前記の従来の技術に鑑みてなされたものであって、安全性の懸念の低い酸化染料を組合わせることにより、従来から使用されているオルトアミノフェノールを使用しなくとも、毛髪を黄色の色相へ染色することができ、しかも染色した黄色の毛髪の色相の退色がなく、堅牢性にも優れる酸化染毛剤を提供することを課題とする。 The present invention has been made in view of the above-described conventional technology. By combining an oxidative dye with low safety concerns, hair can be obtained without using conventionally used orthoaminophenol. It is an object of the present invention to provide an oxidative hair dye that can be dyed into a yellow hue and that does not fade in the hue of the dyed yellow hair and is excellent in fastness.
すなわち、本発明は、
(1)炭酸塩及び重炭酸塩を除くアルカリ剤並びに酸化染料を含有する第1剤と、酸化剤を含有する第2剤とからなる酸化染毛剤であって、
染料前駆体としてパラメチルアミノフェノール及び/又はその塩を用い、カップラーとしてレゾルシンを用い、
パラメチルアミノフェノール及び/又はその塩とレゾルシンの合計量が酸化染料全量中70〜100モルパーセントであり、
パラメチルアミノフェノール(A)とレゾルシン(B)の配合比がモル比で、A:B=2:1〜1:5であり、
毛髪を黄色の色相に染色して用いられることを特徴とする酸化染毛剤、
(2)アルカリ剤が、アンモニア、モノエタノールアミン、イソプロパノールアミンからなる群から選ばれる1種以上であることを特徴とする前記(1)に記載の酸化染毛剤、
(3)更に、第1剤にpH調整剤を含有することを特徴とする前記(1)又は(2)に記載の酸化染毛剤、
(4)pH調整剤が、炭酸塩、重炭酸塩、無機酸、有機酸からなる群から選ばれる1種以上であることを特徴とする前記(3)に記載の酸化染毛剤、
(5)第1剤と第2剤の混合時の系のpHが、pH9〜11であることを特徴とする前記(1)〜(4)のいずれかに記載の酸化染毛剤、
(6)染料前駆体としてオルトアミノフェノールを含有しないことを特徴とする前記(1)〜(5)のいずれかに記載の酸化染毛剤、並びに
(7)直接染料を含有しないことを特徴とする前記(1)〜(6)のいずれかに記載の酸化染毛剤
に関する。
That is, the present invention
(1) An oxidative hair dye comprising a first agent containing an alkaline agent excluding carbonate and bicarbonate and an oxidative dye, and a second agent containing an oxidant,
Using paramethylaminophenol and / or a salt thereof as a dye precursor, using resorcin as a coupler,
The total amount of paramethylaminophenol and / or its salt and resorcin is 70 to 100 mole percent of the total amount of the oxidation dye,
The compounding ratio of paramethylaminophenol (A) and resorcin (B) is a molar ratio, A: B = 2: 1 to 1: 5,
An oxidative hair dye characterized by being used by dyeing hair into a yellow hue;
( 2 ) The oxidative hair dye according to (1 ), wherein the alkali agent is at least one selected from the group consisting of ammonia, monoethanolamine, and isopropanolamine,
( 3 ) The oxidative hair dye according to (1) or (2) , further comprising a pH adjuster in the first agent,
( 4 ) The oxidative hair dye according to ( 3 ), wherein the pH adjuster is at least one selected from the group consisting of carbonates, bicarbonates, inorganic acids, and organic acids.
( 5 ) The oxidative hair dye according to any one of (1) to ( 4 ) above, wherein the pH of the system at the time of mixing the first agent and the second agent is pH 9-11.
( 6 ) The oxidative hair dye according to any one of the above (1) to ( 5 ), which does not contain orthoaminophenol as a dye precursor, and ( 7 ) which does not contain a direct dye. The oxidative hair dye according to any one of (1) to ( 6 ).
本発明の酸化染毛剤は、毛髪を黄色の色相へ染色することができ、しかも染色した黄色の毛髪の色相の退色がなく、堅牢性にも優れるという効果を奏する。 The oxidative hair dye of the present invention is capable of dyeing hair into a yellow hue, and has the effect that the hue of the dyed yellow hair does not fade and is excellent in fastness.
本発明の酸化染毛剤には、アルカリ剤及び酸化染料を含有する第1剤と酸化剤を含有する第2剤とから構成される。まず、本発明の第1剤について説明する。 The oxidative hair dye of the present invention comprises a first agent containing an alkali agent and an oxidative dye and a second agent containing an oxidant. First, the 1st agent of this invention is demonstrated.
本発明に用いるアルカリ剤は、炭酸塩及び重炭酸塩を除くアルカリ剤が用いられる。用い得るアルカリ剤は、本発明の効果を発揮すれば特に限定されないが、例えば、アンモニア、水酸化ナトリウム等の無機アルカリ剤;モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、イソプロパノールアミン、2−アミノ−2−メチル−1−プロパノール等の有機アルカリ剤を例示することができる。なかでも、黒色の毛髪を十分に脱色すると共に、毛髪を鮮明な黄色に染色する観点から、アンモニア、モノエタノールアミン、イソプロパノールアミン等を用いることが好ましい。 As the alkaline agent used in the present invention, an alkaline agent excluding carbonate and bicarbonate is used. The alkali agent that can be used is not particularly limited as long as the effects of the present invention are exhibited. For example, inorganic alkali agents such as ammonia and sodium hydroxide; monoethanolamine, diethanolamine, triethanolamine, isopropanolamine, 2-amino-2 -Organic alkali agents, such as methyl-1-propanol, can be illustrated. Of these, ammonia, monoethanolamine, isopropanolamine and the like are preferably used from the viewpoints of sufficiently decolorizing black hair and dyeing the hair vividly yellow.
第1剤中のアルカリ剤の含有量は、本発明の効果を発揮すれば特に限定されないが、毛髪への染色性の観点から1質量%以上が好ましく、3質量%以上がより好ましい。また、頭皮への刺激性の観点から、15質量%以下が好ましく、12質量%以下がより好ましい。これらのことから、第1剤中のアルカリ剤の含有量は、好ましくは1〜15質量%であり、より好ましくは3〜12質量%である。 The content of the alkali agent in the first agent is not particularly limited as long as the effect of the present invention is exhibited, but is preferably 1% by mass or more, more preferably 3% by mass or more from the viewpoint of dyeability to hair. Moreover, from a viewpoint of irritation to the scalp, 15 mass% or less is preferable and 12 mass% or less is more preferable. From these things, content of the alkaline agent in the 1st agent becomes like this. Preferably it is 1-15 mass%, More preferably, it is 3-12 mass%.
本発明における酸化染料とは、自身の酸化重合により発色する染料前駆体、および染料前駆体との反応により種々の色相とするカップラーの双方を意味する。本発明に用いることのできる酸化染料前駆体としては、例えば、フェニレンジアミン類、アミノフェノール類、ジアミノピリジン類、及びそれらの塩酸塩、硫酸塩等の塩類等が挙げられる。具体的には、p−フェニレンジアミン、トルエン−2,5−ジアミン、トルエン−3,4−ジアミン、2,5−ジアミノアニソール、N−フェニル−p−フェニレンジアミン、N−メチル−p−フェニレンジアミン、N,N−ジメチル−p−フェニレンジアミン、6−メトキシ−3−メチル−p−フェニレンジアミン、N,N−ジエチル−2−メチル−p−フェニレンジアミン、N−エチル−N−(ヒドロキシエチル)−p−フェニレンジアミン、N−(2−ヒドロキシプロピル)−p−フェニレンジアミン、2−クロル−6−メチル−p−フェニレンジアミン、2−クロロ−p−フェニレンジアミン、N,N−ビス−(2−ヒドロキシエチル)−p−フェニレンジアミン、2,6−ジクロル−p−フェニレンジアミン、2−クロル−6−ブロム−p−フェニレンジアミン等のフェニレンジアミン類;パラアミノフェノール、オルトアミノフェノール、パラメチルアミノフェノール、2,4−ジアミノフェノール、5−アミノサリチル酸、2−メチル−4−アミノフェノール、3−メチル−4−アミノフェノール、2,6−ジメチル−4−アミノフェノール、3,5−ジメチル−4−アミノフェノール、2,3−ジメチル−4−アミノフェノール、2,5−ジメチル−4−アミノフェノール、2−クロロ−4−アミノフェノール、3−クロロ−4−アミノフェノール等のアミノフェノール類;2,5−ジアミノピリジン等のジアミノピリジン類等及びそれらの塩類等を例示することができる。 The oxidative dye in the present invention means both a dye precursor that develops color by its own oxidative polymerization and a coupler that has various hues by reaction with the dye precursor. Examples of the oxidative dye precursor that can be used in the present invention include phenylenediamines, aminophenols, diaminopyridines, and salts thereof such as hydrochlorides and sulfates. Specifically, p-phenylenediamine, toluene-2,5-diamine, toluene-3,4-diamine, 2,5-diaminoanisole, N-phenyl-p-phenylenediamine, N-methyl-p-phenylenediamine N, N-dimethyl-p-phenylenediamine, 6-methoxy-3-methyl-p-phenylenediamine, N, N-diethyl-2-methyl-p-phenylenediamine, N-ethyl-N- (hydroxyethyl) -P-phenylenediamine, N- (2-hydroxypropyl) -p-phenylenediamine, 2-chloro-6-methyl-p-phenylenediamine, 2-chloro-p-phenylenediamine, N, N-bis- (2 -Hydroxyethyl) -p-phenylenediamine, 2,6-dichloro-p-phenylenediamine, 2-chloro-6-butyl Phenylenediamines such as mu-p-phenylenediamine; paraaminophenol, orthoaminophenol, paramethylaminophenol, 2,4-diaminophenol, 5-aminosalicylic acid, 2-methyl-4-aminophenol, 3-methyl-4 -Aminophenol, 2,6-dimethyl-4-aminophenol, 3,5-dimethyl-4-aminophenol, 2,3-dimethyl-4-aminophenol, 2,5-dimethyl-4-aminophenol, 2- Examples thereof include aminophenols such as chloro-4-aminophenol and 3-chloro-4-aminophenol; diaminopyridines such as 2,5-diaminopyridine, and salts thereof.
カップラーとしては、例えば、レゾルシン、m−アミノフェノール、m−フェニレンジアミン、2,4−ジアミノフェノキシエタノール、5−アミノ−o−クレゾール、2−メチル−5−ヒドロキシエチルアミノフェノール、2,6−ジアミノピリジン、カテコール、ピロガロール、没食子酸、タンニン酸等及びそれらの塩類等を例示することができる。 Examples of the coupler include resorcin, m-aminophenol, m-phenylenediamine, 2,4-diaminophenoxyethanol, 5-amino-o-cresol, 2-methyl-5-hydroxyethylaminophenol, and 2,6-diaminopyridine. And catechol, pyrogallol, gallic acid, tannic acid and the like and salts thereof.
本発明では、これら酸化染料のうち、少なくとも染料前駆体としてパラメチルアミノフェノール及び/又はその塩を用い、カップラーとしてレゾルシンを用いる。従来、パラメチルアミノフェノールは、酸化染毛剤に多用されない酸化染料ではあるが、この両者の組合せにより、毛髪を黄色系の色相へ染色できることを見出した。 In the present invention, among these oxidation dyes, at least paramethylaminophenol and / or a salt thereof is used as a dye precursor, and resorcin is used as a coupler. Conventionally, although paramethylaminophenol is an oxidative dye that is not frequently used as an oxidative hair dye, it has been found that hair can be dyed into a yellowish hue by combining both.
第1剤中の酸化染料の含有量は、本発明の効果を発揮すれば特に限定されないが、毛髪への染色性の観点から0.1質量%以上が好ましく、1質量%以上がより好ましい。また、毛髪を黄色系の色相に染色する観点および頭皮への刺激性の観点から、10質量%以下が好ましく、5質量%以下がより好ましい。これらのことから、第1剤中の酸化染料の含有量は、好ましくは0.1〜10質量%であり、より好ましくは1〜5質量%である。 The content of the oxidative dye in the first agent is not particularly limited as long as the effect of the present invention is exhibited. However, the content is preferably 0.1% by mass or more, more preferably 1% by mass or more from the viewpoint of dyeability to hair. Moreover, 10 mass% or less is preferable and 5 mass% or less is more preferable from the viewpoint of dyeing hair in a yellowish hue and the viewpoint of irritation to the scalp. From these things, content of the oxidation dye in the 1st agent becomes like this. Preferably it is 0.1-10 mass%, More preferably, it is 1-5 mass%.
尚、毛髪を黄色の色相へ染色する観点から、パラメチルアミノフェノール及び/又はその塩と、レゾルシンの合計量は、第1剤の酸化染料全量中、70モルパーセント以上が好ましく、80モルパーセント以上がより好ましく、90モルパーセント以上が特に好ましい。なかでも毛髪をより鮮明な黄色に染色する場合、100モルパーセントとして用いると良い。これらのことから、パラメチルアミノフェノール及び/又はその塩とレゾルシンの合計量は、第1剤の酸化染料全量中、70〜100モルパーセントである。 In addition, from the viewpoint of dyeing hair into a yellow hue, the total amount of paramethylaminophenol and / or a salt thereof and resorcin is preferably 70 mol percent or more, and 80 mol percent or more in the total amount of oxidation dye of the first agent. Is more preferable, and 90 mole percent or more is particularly preferable. In particular, when the hair is dyed in a brighter yellow, it may be used as 100 mole percent. From these facts, the total amount of paramethylaminophenol and / or its salt and resorcin is 70 to 100 mole percent in the total amount of the first component oxidation dye.
また、パラメチルアミノフェノール及び/又はその塩と、レゾルシンとの配合比は、本発明の効果を発揮すれば特に限定されないが、毛髪をより鮮明な黄色に染色する観点から、パラメチルアミノフェノール(A)とレゾルシン(B)とのモル比で、A:B=2:1〜1:5とすることが好ましく、A:B=1:1〜1:4とすることがより好ましい。 Further, the blending ratio of paramethylaminophenol and / or a salt thereof and resorcin is not particularly limited as long as the effect of the present invention is exhibited. However, paramethylaminophenol (from the viewpoint of dyeing hair more vividly yellow) The molar ratio of A) to resorcin (B) is preferably A: B = 2: 1 to 1: 5, and more preferably A: B = 1: 1 to 1: 4.
本発明においては、毛髪をより鮮明な黄色に染色する観点から、使用時の系のpHを調整するために、第1剤にpH調整剤を含有させることができる。用いるpH調整剤としては、本発明の効果を発揮すれば特に限定されないが、例えば、炭酸アンモニウム、炭酸ナトリウム、炭酸カリウム等の炭酸塩;炭酸水素アンモニウム、炭酸水素ナトリウム、炭酸水素カリウム等の重炭酸塩;リン酸、塩酸等の無機酸;クエン酸、乳酸、シュウ酸、グリコール酸等の有機酸を例示することができる。 In the present invention, from the viewpoint of dyeing hair in a brighter yellow, the first agent can contain a pH adjuster in order to adjust the pH of the system during use. The pH adjuster to be used is not particularly limited as long as the effect of the present invention is exhibited. For example, carbonates such as ammonium carbonate, sodium carbonate, and potassium carbonate; bicarbonates such as ammonium bicarbonate, sodium bicarbonate, and potassium bicarbonate. Salts; inorganic acids such as phosphoric acid and hydrochloric acid; and organic acids such as citric acid, lactic acid, oxalic acid, and glycolic acid.
pH調整剤の含有量は、第1剤と第2剤の混合時(使用時)の系を目的のpHに調整できる量を含有すれば良い。 The content of the pH adjusting agent may be an amount that can adjust the system at the time of mixing (using) the first agent and the second agent to the target pH.
本発明にかかる第1剤には、酸化染料の製剤保存中での酸化を防止する観点から、酸化防止剤を含有させることができる。酸化防止剤としては、アスコルビン酸ナトリウム、アスコルビン酸カリウム、アスコルビン酸カルシウム、アスコルビン酸アンモニウム、エリソルビン酸、エリソルビン酸ナトリウム、アスコルビン酸リン酸エステルマグネシウム、クエン酸アスコルビル、酢酸アスコルビル、酒石酸アスコルビル、パルミチン酸アスコルビル、ステアリン酸アスコルビル、アスコルビルグルコシド等のアスコルビン酸やアスコルビン酸誘導体の他、亜硫酸塩、亜硫酸水素塩、ピロ亜硫酸水素塩等を挙げることができる。 The 1st agent concerning this invention can contain antioxidant from a viewpoint which prevents the oxidation in the formulation preservation | save of an oxidation dye. Antioxidants include sodium ascorbate, potassium ascorbate, calcium ascorbate, ammonium ascorbate, erythorbic acid, sodium erythorbate, magnesium ascorbate phosphate, ascorbyl citrate, ascorbyl acetate, ascorbyl tartrate, ascorbyl palmitate, In addition to ascorbic acid and ascorbic acid derivatives such as ascorbyl stearate and ascorbyl glucoside, sulfites, bisulfites, pyrobisulfites and the like can be mentioned.
次に、本発明の第2剤について説明する。本発明に係る第2剤には、第1剤中の酸化染料を毛髪内で酸化重合させるために、必須成分として酸化剤を含有する。用いる酸化剤としては、過酸化水素、過炭酸ナトリウム、過炭酸カリウム、過ホウ酸ナトリウム、過ホウ酸カリウム等を挙げることができ、過酸化水素を用いるのが好ましい。 Next, the second agent of the present invention will be described. The second agent according to the present invention contains an oxidizing agent as an essential component in order to oxidatively polymerize the oxidative dye in the first agent in the hair. Examples of the oxidizing agent to be used include hydrogen peroxide, sodium percarbonate, potassium percarbonate, sodium perborate, potassium perborate and the like, and it is preferable to use hydrogen peroxide.
第2剤中の酸化剤の含有量は、本発明の効果を発揮すれば特に限定されないが、染色性の観点から、0.01質量%以上が好ましく、0.1質量%以上がより好ましい。また、皮膚刺激や毛髪の損傷を防止する観点から、10質量%以下が好ましく、6質量%以下がより好ましい。これらのことから、第2剤中の酸化剤の含有量は、0.01〜10質量%とすることが好ましく、より好ましくは0.1〜6質量%とするとよい。 The content of the oxidizing agent in the second agent is not particularly limited as long as the effects of the present invention are exhibited, but from the viewpoint of dyeability, 0.01% by mass or more is preferable, and 0.1% by mass or more is more preferable. Moreover, from a viewpoint of preventing skin irritation and hair damage, 10 mass% or less is preferable and 6 mass% or less is more preferable. From these things, it is preferable that content of the oxidizing agent in a 2nd agent shall be 0.01-10 mass%, More preferably, it is good to set it as 0.1-6 mass%.
本発明の第2剤には、酸化剤の安定剤を含有させることができる。例えば、フェナセチン、ヒドロキシエタンジホスホン酸等を例示することができる。 The second agent of the present invention may contain an oxidizing agent stabilizer. For example, phenacetin, hydroxyethane diphosphonic acid and the like can be exemplified.
また、本発明に係る第1剤及び/又は第2剤には、本発明の目的の効果を損なわない範囲であれば、上記した成分のほか、エタノール、イソプロパノール等の低級アルコール;ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール等の高級アルコール;ラウリン酸、ミリスチン酸、ステアリン酸、オレイン酸等の高級脂肪酸;流動パラフィン、流動イソパラフィン、スクワラン等の炭化水素;ミリスチン酸ミリスチル、ミリスチン酸イソステアリル、ステアリン酸ステアリル等のエステル;アボガド油、オリーブ油、サフラワー油、硬化油等の動植物油;ポリエチレングリコール、グリセリン、ポリグリセリン、1,3−ブチレングリコール、1,2−ペンタンジオール、1,2−オクタンジオール等の多価アルコール;ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、及びこれらのアルキレンオキシド付加物、ポリグリセリン脂肪酸エステル、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンラノリン等のノニオン性界面活性剤;高級脂肪酸石鹸、アルキル硫酸エステル塩、アルキルリン酸塩、ポリオキシエチレンアルキルエーテル硫酸塩、アルキルエーテルリン酸エステル、アルキルエーテルカルボン酸塩、アシルメチルタウリン塩、アルキルスルホコハク酸及びその塩等のアニオン性界面活性剤;アルキルグリシン塩、カルボキシメチルグリシン塩、N−アシルアミノエチル−N−2−ヒドロキシエチルグリシン塩等のグリシン型両性界面活性剤、アルキルアミノプロピオン酸塩、アルキルイミノジプロピオン酸塩等のアミノプロピオン酸型両性界面活性剤、アルキルジメチルアミノ酢酸ベタイン、脂肪酸アミドプロピルジメチルアミノ酢酸ベタイン等のアミノ酢酸ベタイン型両性界面活性剤、アルキルヒドロキシスルホベタイン等のスルホベタイン型両性界面活性剤等の両性界面活性剤;塩化ラウリルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化ジステアリルジメチルアンモニウムなどのアルキルアミン塩;ミリスチン酸ジメチルアミノエチルアミド、ステアリン酸ジエチルアミノプロピルアミドなどの脂肪酸アミドアミン等のカチオン性界面活性剤;増粘剤、抗炎症剤、紫外線吸収剤、着色剤、香料、水等を目的に応じて適宜含有させることができる。 In addition, the first agent and / or the second agent according to the present invention include, in addition to the above components, lower alcohols such as ethanol and isopropanol; lauryl alcohol, myristyl, as long as the effects of the object of the present invention are not impaired. Higher alcohols such as alcohol, cetyl alcohol, stearyl alcohol; higher fatty acids such as lauric acid, myristic acid, stearic acid, oleic acid; hydrocarbons such as liquid paraffin, liquid isoparaffin, squalane; myristyl myristate, isostearyl myristate, stearin Esters such as stearyl acid; animal and vegetable oils such as avocado oil, olive oil, safflower oil, hydrogenated oil; polyethylene glycol, glycerin, polyglycerin, 1,3-butylene glycol, 1,2-pentanediol, 1,2-octanediol Etc. Nonionic properties such as alcohol; sorbitan fatty acid ester, glycerin fatty acid ester, and adducts thereof, polyglycerin fatty acid ester, polyoxyalkylene alkyl ether, polyoxyalkylene fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene lanolin Surfactant: Higher fatty acid soap, alkyl sulfate ester salt, alkyl phosphate salt, polyoxyethylene alkyl ether sulfate salt, alkyl ether phosphate ester, alkyl ether carboxylate salt, acylmethyl taurate salt, alkyl sulfosuccinic acid and its salt, etc. Anionic surfactants; glycine-type amphoteric surfactants such as alkylglycine salts, carboxymethylglycine salts, N-acylaminoethyl-N-2-hydroxyethylglycine salts Agents, aminopropionic acid type amphoteric surfactants such as alkylaminopropionate and alkyliminodipropionate, aminoacetic acid betaine type amphoteric surfactants such as alkyldimethylaminoacetic acid betaine and fatty acid amidopropyldimethylaminoacetic acid betaine, alkyl Amphoteric surfactants such as sulfobetaine-type amphoteric surfactants such as hydroxysulfobetaine; alkylamine salts such as lauryltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride; dimethylaminoethylamide myristate, diethylamino stearate Cationic surfactants such as fatty acid amide amines such as propylamide; thickeners, anti-inflammatory agents, ultraviolet absorbers, colorants, fragrances, water, etc. can be appropriately contained depending on the purpose. .
尚、本発明に係る第1剤及び第2剤の剤型としては、液状、ジェル状、クリーム状等の種々の剤型で用いることができ、第1剤と第2剤を混合して使用する。使用時の第1剤と第2剤の混合比は、通常、質量比で1:2〜2:1程度で混合すればよい。 In addition, as a dosage form of the 1st agent and 2nd agent which concern on this invention, it can be used with various dosage forms, such as a liquid form, a gel form, and a cream form, and mixes and uses a 1st agent and a 2nd agent To do. What is necessary is just to mix the mixing ratio of the 1st agent and the 2nd agent at the time of use by about 1: 2 to 2: 1 by mass ratio normally.
また、混合時の系(薬剤)のpHは、本発明の効果を発揮すれば特に限定されないが、黒色の毛髪であっても、より鮮明な黄色に染色する観点から、pH8〜11が好ましく、pH9〜10.5がより好ましい。 Further, the pH of the system (drug) at the time of mixing is not particularly limited as long as the effect of the present invention is exhibited, but pH 8 to 11 is preferable from the viewpoint of dyeing black hair even more vividly, A pH of 9 to 10.5 is more preferred.
以下、本発明を実施例に基づいて更に詳細に説明するが、本発明はかかる実施例のみに限定されるものではない。尚、配合量は特記しない限り、質量%である。また、「POE」は、ポリオキシエチレンの略であり、括弧内の数字は付加モル数を表す。 EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to this Example. The blending amount is mass% unless otherwise specified. “POE” is an abbreviation for polyoxyethylene, and the number in parentheses represents the number of added moles.
(試料の調製)
表1〜2に示す組成に従い、各第1剤を定法により調製し、第1剤20gに対し、下記の第2剤40gとを混合して各実施例および比較例の試験試料を調製した。各試験試料を、下記評価試験に供した。
(Sample preparation)
According to the composition shown in Tables 1-2, each 1st agent was prepared by the usual method, the following 2nd agent 40g was mixed with 20 g of 1st agents, and the test sample of each Example and a comparative example was prepared. Each test sample was subjected to the following evaluation test.
(酸化染毛剤第2剤)
過酸化水素水(35%) 16.7
ヒドロキシエタンジホスホン酸 0.1
精製水 残 部
合 計 100.0
(Oxidative hair dye second agent)
Hydrogen peroxide solution (35%) 16.7
Hydroxyethane diphosphonic acid 0.1
Purified water balance part Total 100.0
(試験例1:pHの測定)
実施例および比較例の各試験試料を、pH測定器(F−23II型,堀場製作所社製)にてpHを測定した。結果を表3〜4に記す。
(Test Example 1: Measurement of pH)
The pH of each test sample of Examples and Comparative Examples was measured with a pH meter (F-23II type, manufactured by Horiba, Ltd.). The results are shown in Tables 3-4.
(試験例2:染色性の評価)
試験毛束として、スタッフス社製毛束「人毛 黒髪(レベル4)1g10cm毛束」及び「ヤク毛 1g10cm毛束」を用いた。尚、毛束は、予め0.5gラウリル硫酸ナトリウム液に50℃,1時間つけ置き洗浄したものを使用した。
各実施例及び各比較例の試料2gを、ハケを用いて毛束全体に約1分かけて充分なじませた後、毛束を30℃,70%RHの恒温恒湿槽中に30分間放置した。その後、試験毛束を恒温恒湿槽から取り出し、35℃の水道水で約30秒間洗浄後、市販のシャンプーの適量を30秒程度なじませ洗い流した。続いて、洗浄後の毛束に市販のコンディショナーの適量を10秒程度なじませたのち、再度水道水で洗い流し風乾した。乾燥後の黒髪毛束(黒毛)並びにヤク毛毛束(白毛)への黄色の染色の程度について、下記評価基準に基づいて評価した。結果を表3〜4に記す。
(Test Example 2: Evaluation of dyeability)
As the test hair bundle, a hair bundle “man hair black hair (level 4) 1 g 10 cm hair bundle” and “yak hair 1 g 10 cm hair bundle” manufactured by Staffus Co., Ltd. were used. In addition, the hair | bristle bundle used what was previously put on 0.5g sodium lauryl sulfate liquid at 50 degreeC and wash | cleaned for 1 hour.
After 2 g of the samples of each Example and each Comparative Example were thoroughly blended with the brush over the entire hair bundle over about 1 minute, the hair bundle was left in a constant temperature and humidity chamber at 30 ° C. and 70% RH for 30 minutes. did. Thereafter, the test hair bundle was taken out from the constant temperature and humidity chamber, washed with tap water at 35 ° C. for about 30 seconds, and then washed with an appropriate amount of a commercially available shampoo for about 30 seconds. Subsequently, an appropriate amount of a commercial conditioner was applied to the washed hair bundle for about 10 seconds, and then rinsed with tap water and air-dried again. The degree of yellow dyeing of the black hair bundle (black hair) and the yak hair bundle (white hair) after drying was evaluated based on the following evaluation criteria. The results are shown in Tables 3-4.
<評価基準>
◎:鮮やかな黄味がある
○:淡い黄味がある
△:黄味はあるが緑味が強い
×:強い緑味があり黄味がない
<Evaluation criteria>
◎: Bright yellowish ○: Light yellowish △: Yellowish but strong green ×: Strong greenish and no yellowish
(試験例3:堅牢性の評価)
上記試験例2の評価後のヤク毛毛束を、2.5%POE(3)ラウリルエーテル硫酸ナトリウム水溶液中に浸漬し、40℃,10分間超音波処理を行ない風乾した。得られた毛束を分光測色計(CM−3610d型,コニカミノルタセンシング社製)を用いて測定し、浸漬前の毛束と浸漬処理後の毛束との色差(△E)を算出し、堅牢性を下記評価基準により評価した。結果を表3〜4に記す。尚、△E値が小さいほど、堅牢性がよいことを表わす。
(Test Example 3: Evaluation of fastness)
The yak hair bundle after the evaluation in Test Example 2 was immersed in a 2.5% POE (3) aqueous sodium lauryl ether sulfate solution, subjected to ultrasonic treatment at 40 ° C. for 10 minutes, and air-dried. The obtained hair bundle was measured using a spectrocolorimeter (CM-3610d type, manufactured by Konica Minolta Sensing), and the color difference (ΔE) between the hair bundle before immersion and the hair bundle after immersion treatment was calculated. The fastness was evaluated according to the following evaluation criteria. The results are shown in Tables 3-4. In addition, it shows that robustness is so good that (DELTA) E value is small.
<評価基準>
◎:△Eが5未満
○:△Eが5以上6未満
△:△Eが6以上7未満
×:△Eが7以上
<Evaluation criteria>
◎: ΔE is less than 5 ○: ΔE is 5 or more and less than 6 Δ: ΔE is 6 or more and less than 7 ×: ΔE is 7 or more
(試験例4:色移りの評価)
上記試験例3の評価後の毛束をろ紙に挟み、1kgの加重を30秒間かけ、ろ紙への色移りを評価した。
(Test Example 4: Evaluation of color transfer)
The hair bundle after the evaluation in Test Example 3 was sandwiched between filter papers, 1 kg was applied for 30 seconds, and the color transfer to the filter papers was evaluated.
<評価基準>
○:ろ紙に殆ど色移りが確認されない
△:ろ紙に色移りが確認された
×:ろ紙に濃い色移りが確認された。
<Evaluation criteria>
○: Almost no color transfer was confirmed on the filter paper. Δ: Color transfer was confirmed on the filter paper. X: Dark color transfer was confirmed on the filter paper.
表3〜4の結果から、本発明の酸化染毛剤は、従来から毛髪の黄色系への染色に用いられるオルトアミノフェノールを用いなくとも、毛髪を鮮やかな黄色の色相へ染色することができ、しかも染色した黄色の毛髪の色相の退色がなく、堅牢性にも優れることが分かる。 From the results of Tables 3 to 4, the oxidative hair dye of the present invention can dye hair into a bright yellow hue without using orthoaminophenol conventionally used for dyeing hair into yellow color. In addition, it can be seen that there is no fading of the hue of the dyed yellow hair and it is excellent in fastness.
以下に、本発明の酸化染毛剤の処方例を示す。尚、配合量は質量%である。 Below, the formulation example of the oxidation hair dye of this invention is shown. In addition, a compounding quantity is the mass%.
(処方例1)
<第1剤>
ポリオキシエチレン(20)硬化ヒマシ油 5.0
ポリオキシエチレン(20)セチルエーテル 3.0
30%塩化ステアリルトリメチルアンモニウム 3.0
メチルフェニルポリシロキサン 1.0
セチルアルコール 4.0
オレイルアルコール 2.0
グリセリン 2.0
28%アンモニア水 8.0
炭酸水素アンモニウム 2.0
硫酸パラメチルアミノフェノール 1.0
レゾルシン 1.0
無水亜硫酸ナトリウム 0.5
L−アスコルビン酸ナトリウム 0.5
エデト酸二ナトリウム 0.2
精製水 残 部
合 計 100.0
(Prescription Example 1)
<First Agent>
Polyoxyethylene (20) hydrogenated castor oil 5.0
Polyoxyethylene (20) cetyl ether 3.0
30% stearyltrimethylammonium chloride 3.0
Methylphenylpolysiloxane 1.0
Cetyl alcohol 4.0
Oleyl alcohol 2.0
Glycerin 2.0
28% ammonia water 8.0
Ammonium bicarbonate 2.0
Paramethylaminophenol sulfate 1.0
Resorcin 1.0
Anhydrous sodium sulfite 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
Purified water balance
Total 100.0
<第2剤>
35%過酸化水素水 16.0
ヒドロキシエタンジホスホン酸 0.1
ポリオキシエチレン(20)硬化ヒマシ油 0.2
ポリオキシエチレン(20)セチルエーテル 0.2
ポリオキシエチレン(5)セチルエーテル 0.2
セチルアルコール 0.5
1,3−ブチレングリコール 5.0
精製水 残 部
合 計 100.0
<Second agent>
35% hydrogen peroxide solution 16.0
Hydroxyethane diphosphonic acid 0.1
Polyoxyethylene (20) hydrogenated castor oil 0.2
Polyoxyethylene (20) cetyl ether 0.2
Polyoxyethylene (5) cetyl ether 0.2
Cetyl alcohol 0.5
1,3-butylene glycol 5.0
Purified water balance
Total 100.0
(処方例1)
<第1剤>
リン酸ジセチル 1.0
ポリオキシエチレン(40)セチルエーテル 1.0
ポリオキシエチレン(20)セチルエーテル 1.0
メチルポリシロキサン 1.5
セチルアルコール 5.0
ポリエチレングリコール20000 1.0
キサンタンガム 0.1
28%アンモニア水 10.0
リン酸 4.0
硫酸パラメチルアミノフェノール 0.2
レゾルシン 0.4
硫酸トルエンー2,5−ジアミン 0.2
塩酸2,4−ジアミノフェノキシエタノール 0.03
無水亜硫酸ナトリウム 0.5
L−アスコルビン酸ナトリウム 0.5
エデト酸二ナトリウム 0.2
精製水 残 部
合 計 100.0
(Prescription Example 1)
<First Agent>
Dicetyl phosphate 1.0
Polyoxyethylene (40) cetyl ether 1.0
Polyoxyethylene (20) cetyl ether 1.0
Methylpolysiloxane 1.5
Cetyl alcohol 5.0
Polyethylene glycol 20000 1.0
Xanthan gum 0.1
28% ammonia water 10.0
Phosphoric acid 4.0
Paramethylaminophenol sulfate 0.2
Resorcin 0.4
Toluene sulfate-2,5-diamine 0.2
2,4-Diaminophenoxyethanol hydrochloride 0.03
Anhydrous sodium sulfite 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
Purified water balance
Total 100.0
<第2剤>
35%過酸化水素水 16.0
ヒドロキシエタンジホスホン酸 0.1
リン酸ジセチル 0.5
セチルアルコール 0.5
精製水 残 部
合 計 100.0
<Second agent>
35% hydrogen peroxide solution 16.0
Hydroxyethane diphosphonic acid 0.1
Dicetyl phosphate 0.5
Cetyl alcohol 0.5
Purified water balance
Total 100.0
(処方例1)
<第1剤>
ポリオキシエチレン(40)セチルエーテル 3.0
ポリオキシエチレン(20)ステアリルエーテル3.0
ポリオキシエチレン(5)ステアリルエーテル 1.0
デカメチルシクロペンタシロキサン 1.5
高重合メチルポリシロキサン 1.0
ステアリルアルコール 3.0
ジプロピレングリコール 5.0
塩化ジメチルジアリルアンモニウム
・アクリルアミド共重合体液 1.0
塩化ジメチルジアリルアンモニウム
・アクリル酸共重合体液 1.0
28%アンモニア水 6.0
80%モノエタノールアミン液 2.0
リン酸 4.0
硫酸パラメチルアミノフェノール 1.5
レゾルシン 1.0
無水亜硫酸ナトリウム 0.5
L−アスコルビン酸ナトリウム 0.5
エデト酸二ナトリウム 0.2
精製水 残 部
合 計 100.0
<第2剤>
35%過酸化水素水 16.0
ヒドロキシエタンジホスホン酸 0.1
ポリオキシエチレン(20)硬化ヒマシ油 0.2
ポリオキシエチレン(20)セチルエーテル 0.2
ポリオキシエチレン(5)セチルエーテル 0.2
セチルアルコール 0.5
1,3−ブチレングリコール 5.0
精製水 残 部
合 計 100.0
(Prescription Example 1)
<First Agent>
Polyoxyethylene (40) cetyl ether 3.0
Polyoxyethylene (20) stearyl ether 3.0
Polyoxyethylene (5) stearyl ether 1.0
Decamethylcyclopentasiloxane 1.5
Highly polymerized methylpolysiloxane 1.0
Stearyl alcohol 3.0
Dipropylene glycol 5.0
Dimethyl diallylammonium chloride
-Acrylamide copolymer liquid 1.0
Dimethyl diallylammonium chloride
-Acrylic acid copolymer liquid 1.0
28% ammonia water 6.0
80% monoethanolamine solution 2.0
Phosphoric acid 4.0
Paramethylaminophenol sulfate 1.5
Resorcin 1.0
Anhydrous sodium sulfite 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
Purified water balance
Total 100.0
<Second agent>
35% hydrogen peroxide solution 16.0
Hydroxyethane diphosphonic acid 0.1
Polyoxyethylene (20) hydrogenated castor oil 0.2
Polyoxyethylene (20) cetyl ether 0.2
Polyoxyethylene (5) cetyl ether 0.2
Cetyl alcohol 0.5
1,3-butylene glycol 5.0
Purified water balance
Total 100.0
Claims (7)
染料前駆体としてパラメチルアミノフェノール及び/又はその塩を用い、カップラーとしてレゾルシンを用い、
パラメチルアミノフェノール及び/又はその塩とレゾルシンの合計量が酸化染料全量中70〜100モルパーセントであり、
パラメチルアミノフェノール(A)とレゾルシン(B)の配合比がモル比で、A:B=2:1〜1:5であり、
毛髪を黄色の色相に染色して用いられることを特徴とする酸化染毛剤。 An oxidative hair dye comprising a first agent containing an alkali agent excluding carbonate and bicarbonate and an oxidative dye, and a second agent containing an oxidant,
Using paramethylaminophenol and / or a salt thereof as a dye precursor, using resorcin as a coupler,
The total amount of paramethylaminophenol and / or its salt and resorcin is 70 to 100 mole percent of the total amount of the oxidation dye,
The compounding ratio of paramethylaminophenol (A) and resorcin (B) is a molar ratio, A: B = 2: 1 to 1: 5,
An oxidative hair dye characterized by being used by dyeing hair into a yellow hue.
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JP3754295B2 (en) * | 2000-12-28 | 2006-03-08 | 花王株式会社 | Hair dye composition |
JP5016181B2 (en) * | 2004-01-09 | 2012-09-05 | 花王株式会社 | Hair dye composition |
JP2006076914A (en) * | 2004-09-09 | 2006-03-23 | Kao Corp | 1st agent composition for hair dyeing or bleaching |
JP2006182727A (en) * | 2004-12-28 | 2006-07-13 | Kao Corp | Oxidation hair dye |
JP4668647B2 (en) * | 2005-03-07 | 2011-04-13 | 花王株式会社 | Hair bleaching composition and hair dyeing composition |
JP4744167B2 (en) * | 2005-03-15 | 2011-08-10 | シュワルツコフヘンケル株式会社 | Hair dye composition |
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2008
- 2008-11-28 JP JP2008304058A patent/JP5464844B2/en active Active
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KR20180116063A (en) * | 2017-04-14 | 2018-10-24 | 주식회사 미소코스메틱 | Hairdiy set |
KR102353379B1 (en) | 2017-04-14 | 2022-01-19 | 주식회사 바이오리플렉스 | Hairdiy set |
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