JP7164875B2 - Aerosol type hair dye or decolorant composition - Google Patents

Description

The present invention relates to an aerosol hair dye or bleach composition.

A general cream-like hair dye contains an alkaline agent and a dye in the first part, and an oxidizing agent in the second part. Before dyeing the hair, the first part and the second part of this creamy hair dye are transferred to a tray container and mixed at the time of use, and then the hair is dyed with a brush. Therefore, the mixed solution of the first agent and the second agent prepared before hair dyeing may be insufficient or excessive. If the amount is insufficient, the first agent and the second agent are mixed again before use, and the hair is dyed with a brush. On the other hand, if there are too many, they cannot be kept and must be discarded, resulting in wasted work and cost. In recent years, there has been a demand for a “quick dyeing type” that dyes gray hair in a short period of time. often do.

On the other hand, a cream-like two-part aerosol type hair dye or bleaching composition is produced by ejecting the first part and the second part directly onto the brush, and then holding the first part and the second part on the brush. Apply directly to hair for dyeing or bleaching. Therefore, the hair can be dyed or bleached without soiling the hands, and the first and second agents can be discharged from the aerosol container as much as the user wants to use. ” and other problems are less likely to occur. Also, by using a brush, the first and second agents do not stick to your hands, so when you pick up the aerosol container or press the button of the aerosol container to discharge the first and second agents. There is no need to worry about the aerosol container slipping out of the hand.

As such a two-part aerosol type hair dye or bleach composition, the first inner pouch filled with the first part and the second inner pouch filled with the second part are placed in one pressure container, and the inner A creamy two-component aerosol type hair dye or decolorant composition is disclosed in which a compressed gas is filled between a pouch and a pressure-resistant container, and the same pressure is applied to simultaneously discharge the first and second components. (Patent document 1).

JP 2014-237621 A

However, in Patent Document 1, although the balance between the amounts of the first agent and the second agent ejected from the aerosol container and the suppression of dripping are taken into consideration, the first agent and the second agent ejected to the brush are considered. No consideration is given to the spreadability of each of the first agent and the second agent when the two agents are applied to the hair. If the spreadability of either the first agent or the second agent is poor, there is a possibility that the first agent and the second agent cannot be uniformly applied on the hair surface. Therefore, the first agent and the second agent cannot be mixed at the predetermined ratio on the surface of the hair, and as a result, unevenness may occur.

In the case of hair dyes, the first agent often contains a high-concentration alkaline agent or dye. Therefore, the stability of the first agent is lowered, and it tends to be difficult to ensure sufficient stability especially under high temperature conditions. For example, when commodities are transported by land, the temperature inside the vehicle rises to about 60° C. in the summer, and the commodities are stored in a high temperature state for a long period of time. If this state continues for a long time, if the product is an emulsion, the emulsion structure may be destroyed and separation may occur. Therefore, a technique for improving stability under high temperature conditions is also desired.

Accordingly, the present invention provides an aerosol-type hair dye or bleach composition in which both the first agent and the second agent have good spreadability when applied to the hair, and the first agent and the second agent are applied under high temperature conditions. To provide an aerosol type hair dye or decolorant composition which is both stable and has good hair dyeing properties.

In addition, the hair dyeing property in the present invention means dyeing property, bleaching property or both.

As a result of intensive studies to solve the above problems, the present inventors have found an aerosol-type hair dye or bleaching composition comprising (A) glycerin, polyethylene glycol, and dipropylene glycol for both the first agent and the second agent. , at least one selected from diglycerin and 1,3-butylene glycol, (B) polyoxyethylene alkyl ether, (C) higher alcohol having 16 to 22 carbon atoms, (D) oil component (described in (C) ), and the mass ratio (C)/(D) between the component (C) and the component (D) is 0.25 to 4. It is another object of the present invention to provide an agent or a decolorizing agent composition.

According to the present invention, it is possible to obtain an aerosol type hair dye or decolorant composition that has good spreadability when applied, good stability under high temperature conditions, and good hair dyeing properties.

It is an explanatory view showing the composition of a brush. It is an explanatory view showing the composition of a brush. FIG. 2 is an explanatory diagram showing the states of the first agent and the second agent discharged from the aerosol-type hair dye or decolorant composition.

The present invention will be described in detail below. In addition, all the units which show content are the mass % unless otherwise specified.

The present invention is an aerosol-type hair dye or bleach composition, wherein both the first agent and the second agent contain (A) at least one selected from glycerin, polyethylene glycol, dipropylene glycol, diglycerin and 1,3-butylene glycol. (B) a polyoxyethylene alkyl ether, (C) a higher alcohol having 16 to 22 carbon atoms, (D) an oily component (excluding the higher alcohol described in (C)), and the above (C ) to the component (D) in a mass ratio (C)/(D) of 0.25 to 4.

The first agent of the aerosol type hair dye or decolorant composition of the present invention will be described.

The first agent of the aerosol-type hair dye or bleach composition of the present invention is composed of (A) glycerin, polyethylene glycol, dipropylene glycol, diglycerin and 1,3-butylene glycol from the viewpoint of stability under high temperature conditions. Contains at least one selected. Among them, polyethylene glycol and glycerin are preferable from the viewpoint of stability under high temperature conditions.

The (A) polyethylene glycol contained in the first agent of the aerosol-type hair dye or bleach composition of the present invention is not particularly limited, but preferably has an average molecular weight of 1000 or less, more preferably 400 or less. (A) When the average molecular weight of polyethylene glycol exceeds 1,000, elongation may decrease.

Here, the average molecular weight can be obtained, for example, according to the average molecular weight test described in the Standards for Quasi-Drug Ingredients 2006 Polyethylene Glycol section.

The content of the component (A) contained in the first part of the aerosol-type hair dye or decolorant composition of the present invention is not particularly limited, but is preferably 1 to 10 from the viewpoint of stability under high temperature conditions. %, more preferably 3 to 8%. If the content of component (A) is less than 1% or more than 10%, the stability under high temperature conditions may decrease.

The first agent of the aerosol type hair dye or bleach composition of the present invention contains (B) polyoxyethylene alkyl ether from the viewpoint of emulsification.

The component (B) contained in the first part of the aerosol-type hair dye or bleach composition of the present invention is not particularly limited, but examples include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxy Ethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene behenyl ether and the like can be used. More specifically, polyoxyethylene cetyl ether (2E.O.) "HLB = 5.3", polyoxyethylene cetyl ether (5E.O.) "HLB = 9.5", polyoxyethylene stearyl ether ( 2E.O.) "HLB = 4.9", polyoxyethylene stearyl ether (5E.O.) "HLB = 9.0", polyoxyethylene behenyl ether (5E.O.) "HLB = 8.1" , polyoxyethylene behenyl ether (10E.O.) "HLB = 11.5", polyoxyethylene lauryl ether (9E.O.) "HLB = 13.6", polyoxyethylene lauryl ether (21E.O.) "HLB = 16.6", polyoxyethylene cetyl ether (10E.O.) "HLB = 12.9", polyoxyethylene cetyl ether (15E.O.) "HLB = 14.6", polyoxyethylene cetyl Ether (20 E.O.) "HLB=15.7", Polyoxyethylene cetyl ether (30 E.O.) "HLB=16.9", Polyoxyethylene cetyl ether (40 E.O.) "HLB=17. 6", polyoxyethylene stearyl ether (15 E.O.) "HLB = 13.5", polyoxyethylene stearyl ether (20 E.O.) "HLB = 15.3", polyoxyethylene stearyl ether (40 E.O. .) "HLB = 17.3", polyoxyethylene behenyl ether (20 E.O.) "HLB = 15.4", polyoxyethylene behenyl ether (30 E.O.) "HLB = 16.6", etc. It can contain one or more of these. Among them, from the viewpoint of emulsion stability, polyoxyethylene cetyl ether (10E.O.) "HLB = 12.9", polyoxyethylene cetyl ether (15E.O.) "HLB = 14.6", polyoxy Ethylene cetyl ether (20 E.O.) "HLB = 15.7", polyoxyethylene cetyl ether (30 E.O.) "HLB = 16.9", polyoxyethylene cetyl ether (40 E.O.) "HLB = 17.6", polyoxyethylene stearyl ether (15E.O.) "HLB = 13.5", polyoxyethylene stearyl ether (20E.O.) "HLB = 15.3", polyoxyethylene stearyl ether (40E .O.) "HLB = 17.3", polyoxyethylene behenyl ether (20E.O.) "HLB = 15.4", polyoxyethylene behenyl ether (30E.O.) "HLB = 16.6" good. The value in parentheses means the average added mole number of ethylene oxide (E.O.).

"HLB" in the present invention is an abbreviation of HYDROPHILE-LIPOPHILE BALANCE, a parameter representing the relative strength of hydrophilicity and lipophilicity possessed by surfactant molecules. . The larger the HLB value, the stronger the hydrophilicity, and the smaller the HLB value, the stronger the lipophilicity. The HLB described herein is calculated from the known GRIFFIN formula.

The component (B) contained in the first part of the aerosol-type hair dye or bleach composition of the present invention is preferably a polyoxyethylene alkyl having an HLB of less than 16 from the viewpoint of improving stability under high-temperature conditions. It is preferable to combine an ether and a polyoxyethylene alkyl ether having an HLB of 16 or more.

The content of the component (B) contained in the first part of the aerosol-type hair dye or decolorant composition of the present invention is not particularly limited, but from the viewpoint of stability or elongation under high temperature conditions, it is preferably It is preferably contained in an amount of 0.5 to 8%. If the content of component (B) is less than 0.5%, the stability under high temperature conditions may decrease. If the component (B) content exceeds 8%, the stability or elongation under high temperature conditions may decrease.

The first part of the aerosol type hair dye or bleach composition of the present invention contains (C) a higher alcohol having 16 to 22 carbon atoms from the viewpoint of viscosity adjustment.

The component (C) contained in the first part of the aerosol-type hair dye or bleach composition of the present invention is not particularly limited, but examples thereof include cetyl alcohol, stearyl alcohol, behenyl alcohol, octyldodecanol, and the like. It can contain one or more. Among them, cetyl alcohol, stearyl alcohol and octyldodecanol are preferred from the viewpoint of elongation.

The content of the component (C) contained in the first part of the aerosol-type hair dye or decolorant composition of the present invention is not particularly limited, but from the viewpoint of viscosity adjustment, it is preferably 2 to 15%, more preferably. is preferably contained in an amount of 4 to 12%, more preferably 4 to 8%. If the content of the component (C) is less than 2%, the stability under high temperature conditions may deteriorate. If the content of component (C) exceeds 15%, elongation may decrease.

The first part of the aerosol type hair dye or bleach composition of the present invention contains (D) an oily component from the viewpoint of spreadability.

The component (D) contained in the first part of the aerosol-type hair dye or decolorant composition of the present invention is not particularly limited, but examples thereof include hydrocarbons, fats and oils, waxes, and higher hydrocarbons having 12 to 22 carbon atoms. fatty acids, esters, silicones and the like. Higher alcohols having 6 or more carbon atoms other than the higher alcohols having 16 to 22 carbon atoms which are the component (C) are included in the component (D). These (D) components can contain one or more. Among them, an oily component that is liquid at 25°C is preferable from the viewpoint of ease of application.

Examples of hydrocarbons include α-olefin oligomers, light isoparaffins, light liquid isoparaffins, liquid isoparaffins, liquid paraffins, squalane, polybutene, paraffins, microcrystalline waxes, petroleum jelly and the like.

Oils and fats include olive oil, rosehip oil, camellia oil, shea butter, macadamia nut oil, almond oil, sunflower oil, sesame oil, cacao butter, corn oil, peanut oil, rapeseed oil, rice bran oil, rice germ oil, grape seed oil. , avocado oil, castor oil, linseed oil, coconut oil and the like.

Waxes include beeswax, candelilla wax, carnauba wax, jojoba oil, rice bran wax, sugarcane wax, palm wax and the like.

Higher fatty acids having 12 to 22 carbon atoms include myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, hydroxystearic acid, oleic acid and linoleic acid.

Examples of esters include diisobutyl adipate, cetyl ethylhexanoate, isononyl isononanoate, diisopropyl sebacate, isopropyl myristate, octyldodecyl myristate, isopropyl palmitate, stearyl stearate, hexyl laurate, and hexyldecyl dimethyloctanoate. mentioned.

Examples of silicones include methylpolysiloxane, highly polymerized methylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, amino-modified silicone, and alkyl-modified silicone.

The content of the component (D) contained in the first part of the aerosol-type hair dye or bleach composition of the present invention is not particularly limited, but from the viewpoint of stability or elongation under high temperature conditions, it is preferably The content is preferably 2 to 20%, more preferably 4 to 15%. If the content of component (D) is less than 2%, elongation may be reduced. If the content of component (D) exceeds 20%, the stability or elongation under high temperature conditions may deteriorate.

The mass ratio (C)/(D) of the component (C) and the component (D) contained in the first agent of the aerosol-type hair dye or bleach composition of the present invention is the stability under high temperature conditions. Alternatively, from the viewpoint of elongation, it is preferably 0.25 to 4. If the mass ratio (C)/(D) of the component (C) to the component (D) is less than 0.25, the stability under high temperature conditions may deteriorate. When the mass ratio (C)/(D) of the component (C) to the component (D) exceeds 4, there is a possibility that the extensibility may be lowered.

The first agent of the aerosol type hair dye or bleach composition of the present invention can contain (E) a cationic surfactant from the viewpoint of emulsification.

The component (E) that can be contained in the first part of the aerosol-type hair dye or bleaching composition of the present invention is not particularly limited, but examples include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, and behenyltrimethylammonium chloride. is mentioned. Among them, behenyltrimethylammonium chloride is preferable from the viewpoint of stability under high temperature conditions.

The content of the component (E) that can be contained in the first part of the aerosol-type hair dye or decolorant composition of the present invention is not particularly limited, but is preferably 4% or less from the viewpoint of stretchability. . If the content of component (E) exceeds 4%, elongation may be reduced.

The first agent of the aerosol-type hair dye or bleach composition of the present invention can be improved in stability under high-temperature conditions by using the component (B) and the component (E) in combination.

The mass ratio of at least one or more selected from the (B) component and the (E) component to the (A) component contained in the first agent of the aerosol type hair dye or bleaching composition of the present invention ( (B)+(E))/(A) is preferably 0.25 to 4 from the viewpoint of stability under high temperature conditions. The mass ratio of at least one selected from the component (B) and the component (E) to the component (A) ((B) + (E))/(A) is less than 0.25 or greater than 4 In such cases, the stability under high temperature conditions may decrease.

The first agent of the aerosol type hair dye or bleach composition of the present invention contains an alkaline agent.

The alkaline agent contained in the first part of the aerosol-type hair dye or bleach composition of the present invention is not particularly limited. amines, inorganic alkalis such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogencarbonate and ammonium hydrogencarbonate; basic amino acids such as arginine and lysine; salts thereof; can contain.

The content of the alkaline agent in the first part of the aerosol type hair dye or bleach composition of the present invention is 1.0 to 10.0%, preferably 1.5 to 8%, from the viewpoint of hair dyeing properties. .0%.

The first part of the aerosol type hair dye or bleach composition of the present invention may contain an oxidation dye as a dye.

The oxidation dye contained in the first part of the aerosol-type hair dye or bleach composition of the present invention is not particularly limited, but examples include paraphenylenediamine, toluene-2,5-diamine, 5-aminoorthocresol, para-aminophenol, meta-aminophenol, 2,4-diaminophenoxyethanol, 2-nitro-p-phenylenediamine, picramic acid, 2-amino-5-nitrophenol, and salts thereof, and other "quasi-drugs Ingredients Standards 2006 Integrated Edition” (published on November 25, 2013, Yakuji Nippo Co., Ltd.) can be used as appropriate. These oxidation dyes may be contained singly or in combination of two or more.

The first part of the aerosol-type hair dye or bleach composition of the present invention may contain acid dyes, basic dyes, etc., in addition to oxidation dyes.

Acid dyes and basic dyes contained in the first part of the aerosol-type hair dye or bleach composition of the present invention are not particularly limited. No. (1), orange No. 205, green No. 401, purple No. 401, black No. 401, 8-amino-2-bromo-5-hydroxy-4-imino-6-[(3-(trimethylammonio)phenyl ) amino]-1(4H)-naphthalinone-chloride, tris(4-amino-3-methylphenyl)-carbenium-chloride, 1-[(4-aminophenyl)azo]-7-(trimethylammonio)-2 -naphthol-chloride, 1-[(4-amino-3-nitrophenyl)azo]-7-(trimethylammonio)-2-naphthol-chloride, 2-hydroxy-1-[(2-methoxyphenyl)azo] -7-(trimethylammonio)-naphthalene-chloride, 2-[2((2,4-dimethoxyphenyl)amino)ethenyl]-1,3,3-trimethyl-3H-indol-1-ium-chloride and the like can contain one or more. In addition, those listed in the "Ministerial Ordinance Determining Tar Pigments Usable in Pharmaceuticals" (Ministry of Health and Welfare Notification of 1966) can also be used as appropriate. These acid dyes and basic dyes may be contained singly or in combination of two or more.

Antioxidants such as sulfite, ascorbic acid and ascorbate, edetate and the like are contained in the first agent of the aerosol type hair dye or bleach composition of the present invention to improve the stability of the oxidation dye. of stabilizers can be used. Other ingredients that can be used include, for example, water, anionic surfactants, amphoteric surfactants, alcohols, sugars, amino acids, plant extracts, pigments, pH adjusters, fragrances, preservatives, and the like. . These components are not particularly limited as long as they do not impair the effects of the present invention, and one or more of them can be contained.

The second agent of the aerosol type hair dye or bleach composition of the present invention will be described.

The second agent of the aerosol type hair dye or bleach composition of the present invention is composed of (A) glycerin, polyethylene glycol, dipropylene glycol, diglycerin and 1,3-butylene glycol from the viewpoint of stability under high temperature conditions. Contains at least one selected. Among them, polyethylene glycol and glycerin are preferable from the viewpoint of stability under high temperature conditions.

The content of component (A) contained in the second part of the aerosol-type hair dye or decolorant composition of the present invention is not particularly limited, but is preferably 1 to 10 from the viewpoint of stability under high temperature conditions. %, more preferably 1 to 8%, and still more preferably 1.5 to 6%. If the content of component (A) is less than 1% or more than 10%, the stability under high temperature conditions may decrease.

The second agent of the aerosol type hair dye or bleach composition of the present invention contains (B) polyoxyethylene alkyl ether from the viewpoint of emulsification.

The component (B) contained in the second part of the aerosol-type hair dye or bleach composition of the present invention is not particularly limited, but examples include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxy Ethylene stearyl ether, polyoxyethylene oleyl ether and polyoxyethylene behenyl ether can be used. More specifically, polyoxyethylene cetyl ether (2E.O.) "HLB = 5.3", polyoxyethylene cetyl ether (5E.O.) "HLB = 9.5", polyoxyethylene stearyl ether ( 2E.O.) "HLB = 4.9", polyoxyethylene stearyl ether (5E.O.) "HLB = 9.0", polyoxyethylene behenyl ether (5E.O.) "HLB = 8.1" , polyoxyethylene behenyl ether (10E.O.) "HLB = 11.5", polyoxyethylene lauryl ether (9E.O.) "HLB = 13.6", polyoxyethylene lauryl ether (21E.O.) "HLB = 16.6", polyoxyethylene cetyl ether (10E.O.) "HLB = 12.9", polyoxyethylene cetyl ether (15E.O.) "HLB = 14.6", polyoxyethylene cetyl Ether (20 E.O.) "HLB=15.7", Polyoxyethylene cetyl ether (30 E.O.) "HLB=16.9", Polyoxyethylene cetyl ether (40 E.O.) "HLB=17. 6", polyoxyethylene stearyl ether (20E.O.) "HLB = 15.3", polyoxyethylene stearyl ether (40E.O.) "HLB = 17.3", polyoxyethylene behenyl ether (20E.O. .) "HLB = 15.4", polyoxyethylene behenyl ether (30E.O.) "HLB = 16.6", etc., and one or more of them can be contained. Among them, from the viewpoint of emulsion stability, polyoxyethylene cetyl ether (10E.O.) "HLB = 12.9", polyoxyethylene cetyl ether (15E.O.) "HLB = 14.6", polyoxy Ethylene cetyl ether (20 E.O.) "HLB = 15.7", polyoxyethylene cetyl ether (30 E.O.) "HLB = 16.9", polyoxyethylene cetyl ether (40 E.O.) "HLB = 17.6", polyoxyethylene stearyl ether (20E.O.) "HLB = 15.3", polyoxyethylene stearyl ether (40E.O.) "HLB = 17.3", polyoxyethylene behenyl ether (20E .O.) "HLB=15.4" and polyoxyethylene behenyl ether (30E.O.) "HLB=16.6" are preferred.

The component (B) contained in the second part of the aerosol-type hair dye or bleach composition of the present invention is preferably a polyoxyethylene alkyl having an HLB of less than 15 from the viewpoint of improving stability under high-temperature conditions. It is preferable to combine an ether and a polyoxyethylene alkyl ether having an HLB of 15 or more.

The content of the component (B) contained in the second part of the aerosol-type hair dye or decolorant composition of the present invention is not particularly limited, but from the viewpoint of stability or elongation under high temperature conditions, it is preferably The content is preferably 1.4 to 20%. If the content of component (B) is less than 1.4%, the stability under high temperature conditions may decrease. If the content of component (B) exceeds 20%, the stability or elongation under high temperature conditions may decrease.

The second component of the aerosol type hair dye or bleach composition of the present invention contains (C) a higher alcohol having 16 to 22 carbon atoms from the viewpoint of viscosity adjustment.

The component (C) contained in the second part of the aerosol-type hair dye or bleach composition of the present invention is not particularly limited, but examples thereof include cetyl alcohol, stearyl alcohol, behenyl alcohol, octyldodecanol, and the like. It can contain one or more. Among them, cetyl alcohol, stearyl alcohol and octyldodecanol are preferred from the viewpoint of elongation.

The content of the component (C) contained in the second part of the aerosol-type hair dye or decolorant composition of the present invention is not particularly limited, but from the viewpoint of viscosity adjustment, it is preferably 2 to 16%, more preferably. is preferably contained in an amount of 5 to 12%. If the content of the component (C) is less than 2%, the stability under high temperature conditions may deteriorate. If the content of component (C) exceeds 16%, elongation may decrease.

The second part of the aerosol type hair dye or bleach composition of the present invention contains (D) an oily component from the viewpoint of spreadability.

The component (D) contained in the second part of the aerosol-type hair dye or decolorant composition of the present invention is not particularly limited, but examples thereof include hydrocarbons, fats and oils, waxes, and higher hydrocarbons having 12 to 22 carbon atoms. fatty acids, esters, silicones and the like. Higher alcohols having 6 or more carbon atoms other than the higher alcohols having 16 to 22 carbon atoms which are the component (C) are included in the component (D). These (D) components can contain one or more. Among them, an oily component that is liquid at 25°C is preferable from the viewpoint of ease of application.

Examples of hydrocarbons include α-olefin oligomers, light isoparaffins, light liquid isoparaffins, liquid isoparaffins, liquid paraffins, squalane, polybutene, paraffins, microcrystalline waxes, petroleum jelly and the like.

Oils and fats include olive oil, rosehip oil, camellia oil, shea butter, macadamia nut oil, almond oil, sunflower oil, sesame oil, cacao butter, corn oil, peanut oil, rapeseed oil, rice bran oil, rice germ oil, grape seed oil. , avocado oil, castor oil, linseed oil, coconut oil and the like.

Waxes include beeswax, candelilla wax, carnauba wax, jojoba oil, rice bran wax, sugarcane wax, palm wax and the like.

Higher fatty acids having 12 to 22 carbon atoms include myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, hydroxystearic acid, oleic acid and linoleic acid.

Esters include diisobutyl adipate, cetyl ethylhexanoate, isononyl isononanoate, diisopropyl sebacate, isopropyl myristate, octyldodecyl myristate, isopropyl palmitate, stearyl stearate, hexyl laurate, hexyldecyl dimethyloctanoate, myristine triisodecyl acid, ethylene glycol di-2-ethylhexanoate, and the like.

Examples of silicones include methylpolysiloxane, highly polymerized methylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, amino-modified silicone, and alkyl-modified silicone.

The content of the component (D) contained in the second part of the aerosol-type hair dye or decolorant composition of the present invention is not particularly limited, but from the viewpoint of stability or elongation under high temperature conditions, it is preferably The content is preferably 2 to 20%, more preferably 4 to 15%. If the content of the component (D) is less than 2%, the elongation may deteriorate. If the content of component (D) exceeds 20%, the stability under high temperature conditions may decrease.

The mass ratio (C)/(D) of the component (C) and the component (D) contained in the second part of the aerosol-type hair dye or bleach composition of the present invention is stable under high temperature conditions. It is preferably 0.25 to 4 from the viewpoint of flexibility or elongation. If the mass ratio (C)/(D) of the component (C) to the component (D) is less than 0.25, the stability under high temperature conditions may deteriorate. When the mass ratio (C)/(D) of the component (C) to the component (D) exceeds 4, there is a possibility that the extensibility may be lowered.

The second agent of the aerosol type hair dye or bleach composition of the present invention can contain (E) a cationic surfactant from the viewpoint of emulsification.

The component (E) that can be contained in the second part of the aerosol-type hair dye or bleach composition of the present invention is not particularly limited, but examples include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, and the like. and can contain one or more. Among them, behenyltrimethylammonium chloride is preferable from the viewpoint of stability under high temperature conditions.

The content of the component (E) that can be contained in the second part of the aerosol-type hair dye or decolorant composition of the present invention is not particularly limited, but is preferably 4% or less from the viewpoint of stretchability. . If the content of component (E) exceeds 4%, elongation may be reduced.

The mass ratio of at least one or more selected from the component (B) and the component (E) to the component (A) contained in the second agent of the aerosol hair dye or bleach composition of the present invention ( (B)+(E))/(A) is preferably 0.25 to 4 from the viewpoint of stability under high temperature conditions. When the mass ratio of at least one selected from the component (B) and the component (E) to the component (A) ((B)+(E))/(A) is less than 0.25 or greater than 4 , the stability under high temperature conditions may decrease.

The second agent of the aerosol type hair dye or bleach composition of the present invention contains an oxidizing agent.

The oxidizing agent contained in the second part of the aerosol-type hair dye or bleaching composition of the present invention is not particularly limited, and examples thereof include hydrogen peroxide, sodium percarbonate, sodium bromate, and the like. can contain

The content of the oxidizing agent in the second part of the aerosol type hair dye or bleach composition of the present invention is preferably 1.0 to 10.0%, more preferably 2.0 to 8.0%, from the viewpoint of bleaching power. 0%.

For the second part of the aerosol type hair dye or bleach composition of the present invention, an acid such as phosphoric acid or a phosphate, or a sequestering agent such as edetate is used to improve the stability of the oxidizing agent. can do. In addition to the components described above, water, anionic surfactants, amphoteric surfactants, alcohols, saccharides, amino acids, plant extracts, pH adjusters, fragrances, preservatives and the like can be used. These components are not particularly limited as long as they do not impair the effects of the present invention, and one or more of them can be contained.

The viscosities of the first part and the second part of the aerosol type hair dye or bleaching composition of the present invention at 20° C. are preferably 5,000 to 50,000 mPa· from the viewpoint of spreadability on hair. s, more preferably 10,000 to 50,000 mPa·s, still more preferably 15,000 to 40,000 mPa·s. If the viscosity is less than 5,000 mPa·s, dripping may occur. If the viscosity exceeds 50,000 mPa·s, the extensibility may deteriorate.

The viscosities of the first agent and the second agent of the aerosol type hair dye or bleaching composition of the present invention under the condition of 20 ° C. Fill 120 g of a 140 g sample bottle (Food 140: manufactured by Daiichi Glass Co., Ltd.) and leave it at 20 ° C. for 2 days, then use a B-type viscometer with a helical stand (model: digital viscometer TVB-10M, Toki Sangyo Co., Ltd. (manufactured by the company), and measured after rotating at 20° C. and 12 rpm for 1 minute using an M4 rotor.

In the aerosol type hair dye or bleach composition of the present invention, both the first agent and the second agent are preferably cream-like from the viewpoint of suppressing dripping.

The first and second parts of the aerosol-type hair dye or bleach composition of the present invention are required to have good spreadability on the hair surface from the viewpoint of hair dyeing properties. If the spreadability of either the first agent or the second agent is poor, the first agent and the second agent cannot be mixed on the surface of the hair at a predetermined ratio, which may result in unevenness. .

The aerosol type hair dye or decolorant composition of the present invention may be of a two-part type, or a three-part type or more, but preferably a two-part type.

The aerosol-type hair dye or bleaching composition of the present invention contains a first internal pouch filled with the first agent and a second internal pouch filled with the second agent in a single pressure container, and the internal pouch and the pressure container. A double structure aerosol container filled with compressed gas and having a mechanism for simultaneously discharging the first agent and the second agent, or an inner bag of a pressure container having an inner bag for each of the first agent and the second agent A double aerosol container having a mechanism for simultaneously discharging the first agent and the second agent by connecting two containers filled with compressed gas between the inner bag and the pressure-resistant container can be used.

Examples of the double structure aerosol container and the double aerosol container include the double structure aerosol container described in Japanese Patent Application Laid-Open No. 2005-231644 and the double structure aerosol container described in Japanese Patent Application Laid-Open No. 2004-91356. can be used.

Examples of the compressed gas used in the aerosol type hair dye or bleach composition of the present invention include those generally used in aerosol products such as dimethyl ether, liquefied petroleum gas, nitrogen gas, CFC alternatives, and compressed air. can be used. Among these, nitrogen gas is preferably used from the viewpoint of safety.

In the aerosol type hair dye or bleaching composition of the present invention, the initial internal pressure applied to the first part and the second part is preferably 0.3 to 0.8 MPa, more preferably 0, at 25 ° C. from the viewpoint of dischargeability. .4 to 0.7 MPa.

The aerosol type hair dye or bleach composition of the present invention can be used with a brush from the viewpoint of usability and not staining the hands.

The brush used for the aerosol-type hair dye or bleaching composition of the present invention needs to retain the first and second parts discharged from the discharge port of the aerosol-type hair dyeing or bleaching composition. Therefore, for example, it is preferable that the brush has a shape in which teeth are installed on something like a table (hereinafter referred to as a table-shaped brush). Teeth may be provided on only one side of the trapezoidal brush, or may be provided on both sides. Further, it is preferable that the teeth provided on the table-shaped brush are provided on one side of the table-shaped brush at regular intervals.

As the brush, for example, the brush described in JP-A-2005-97310 can be used.

EXAMPLES The present invention will be described in more detail below with reference to Examples, but the present invention is not limited only to these Examples.

In the evaluation tests shown in this specification, the components contained in the first agent and the second agent and their contents were variously changed. All the units indicating the content of each component are % by mass, and were prepared by a conventional method. In the table, "polyoxyethylene" is written as "POE".

In the evaluation tests shown in this specification, "stretchability", "stability under high temperature conditions" and "hair dyeability" were evaluated by the following methods.

[Elongation]
In the evaluation test related to "stretchability" shown in this specification, the first internal pouch filled with the first agent and the second internal pouch filled with the second agent were placed in one pressure container, and the internal pouch and the pressure resistant Using a double structure aerosol container having a mechanism for simultaneously discharging the first agent and the second agent, filled with compressed gas between the containers, the first agent and the second agent of the examples shown in this specification are doubled. Fill 50 g each into the inner bag in the structural aerosol container, and fill compressed nitrogen gas between the inner bag and the pressure-resistant container so that the internal pressure applied to the first agent and the second agent is 0.7 MPa (25 ° C.). A two-part aerosol type hair dye or bleaching agent composition is prepared, and the first part and the second part are discharged on a table brush at a ratio of 1: 1 so that the total amount is 4 g, and the length of the hair was cut to 25 cm for hair test (“Cut Mannequin No. 775N” manufactured by Beaulux Co., Ltd.), combed once from the root to the tip of the hair, and then the first and second agents after application. The "spreadability" of each cream was evaluated based on the following evaluation criteria. In order to make it easier to evaluate "elongation", in this test, Yellow No. 201 (1) was added to the first agent to the extent that it does not affect "elongation" to make the appearance color yellow, and the second agent (appearance color: white).
<Evaluation Criteria>
◎: The cream spreads well to the ends of the hair (very good)
〇: The cream extends to the ends of the hair (better)
△: Cream extends to near the tip of the hair (good)
×: Does not extend near the tip of the hair (defective)

[Stability under high temperature conditions]
In the evaluation test related to "formulation stability at high temperature" shown in this specification, the first internal pouch filled with the first agent and the second internal pouch filled with the second agent were placed in one pressure container, Using a double structure aerosol container having a mechanism for simultaneously discharging the first and second agents, filled with compressed gas between the inner pouch and the pressure container, the first and second agents of the examples shown in this specification were used. 50 g of each agent is filled in the inner bag of the double structure aerosol container, and compressed between the inner bag and the pressure container so that the internal pressure applied to the first agent and the second agent is 0.7 MPa (25 ° C.). A two-agent aerosol type hair dye or bleach composition filled with nitrogen gas is prepared, stored at 60° C. for 24 hours, and then returned to room temperature. was dismantled, the inner bag filled with the first agent and the second agent was opened, and the states of the first agent and the second agent were visually confirmed.
<Evaluation Criteria>
◎: No separation after storage for 24 hours at 60°C ○: No separation after storage for 24 hours at 60°C although there is slight water removal △: Some water is removed after storage for 24 hours at 60°C No separation ×: Separation after storage for 24 hours at 60°C

[Hair dyeing property]
In the evaluation test related to the "hair dyeability" shown in this specification, the first agent and the second agent were discharged onto a table-shaped brush at a ratio of 1:1, and the hair was cut to a length of 25 cm. Using a doll (“Cut Mannequin No. 775N” manufactured by Beaulux Co., Ltd.), apply a total of 120 g to the entire head, leave it at 25 ° C for 15 minutes, wash thoroughly with shampoo, and dry with a towel. was wiped off and dried with a dryer. This wig was evaluated based on the following evaluation criteria.
<Evaluation Criteria>
◎: Evenly uniform to the tip of the hair ○: Almost evenly uniform to the tip of the hair △: Slightly uneven to the tip of the hair but almost uniform ×: Uneven and uneven

1 and 2 are explanatory diagrams showing the configuration of brushes used in Examples and Comparative Examples of the present invention. The brush used in the present invention has a length L1 of 170 mm and a width W1 of 65 mm. (112) is 7 mm, the short tooth (113) is 4 mm, the long tooth (112) installed on the brush base of the trapezoidal brush is 80, and the short tooth (113) is 24.

FIG. 3 is a state diagram showing how to use the aerosol type hair dye or bleach composition in Examples and Comparative Examples of the present invention. As shown in FIG. 3, in the examples and comparative examples, the first and second agents were discharged onto a table-shaped brush portion, and a "spreadability" test and a "hair dyeability" test were carried out.

Each test of Examples 1 to 12 and Comparative Examples 1 and 2 described in Tables 2 and 3 was performed in combination with the second agent described in Table 1. Examples 1 to 12 showed good results even when the type and content of the component (A) were changed.

Each test of Examples 13 to 19 described in Table 4 and Comparative Example 3 was performed in combination with the second agent described in Table 1. Examples 13 to 19 showed good results even when the type and content of the component (B) were changed.

Each test of Examples 20 to 26 and Comparative Examples 4 and 5 described in Table 5 was carried out in combination with the second agent described in Table 1. Examples 20 to 26 showed good results even when the type and content of the component (C) were changed.

Each test of Examples 27 to 38 and Comparative Examples 6 and 7 described in Tables 6 and 7 was carried out in combination with the second agent described in Table 1. Examples 27 to 38 showed good results even when the type and content of the component (D) were changed.

Each test of Examples 39 to 44 described in Table 8 and Comparative Example 8 was performed in combination with the second agent described in Table 1. Examples 39 to 44 showed good results even when the type and content of the component (E) were changed.

Each test of Examples 45 to 54 and Comparative Examples 9 and 10 described in Tables 10 and 11 was performed in combination with the first agent described in Table 9. Examples 45 to 54 showed good results even when the type and content of the component (A) were changed.

Each test of Examples 55 to 61 described in Table 12 and Comparative Example 11 was performed in combination with the first agent described in Table 9. Examples 55 to 61 showed good results even when the content of the component (B) was changed.

Each test of Examples 62 to 67 described in Table 13 and Comparative Example 13 was performed in combination with the first agent described in Table 9. Examples 62 to 67 showed good results even when the content of the component (C) was changed.

Each test of Examples 68 to 79 and Comparative Examples 14 and 15 described in Tables 14 and 15 was performed in combination with the first agent described in Table 9. Examples 68 to 79 showed good results even when the type and content of the component (D) were changed.

Each test of Examples 80 to 83 described in Table 16 and Comparative Example 16 was performed in combination with the first agent described in Table 9. Examples 80 to 83 showed good results even when the type and content of the component (E) were changed.

Formulation examples of the first agent and formulation examples of the second agent are listed below. The following formulation examples of the first agent and the second agent were combined, and good results were obtained in terms of spreadability, stability under high temperature conditions, and hair dyeing properties.

(Example 84)
First agent
Component content (mass%)
(A) Glycerin 5.00
(B) Polyoxyethylene cetyl ether (15E.O.) 0.40
(B) Polyoxyethylene cetyl ether (40 E.O.) 0.20
(C) stearyl alcohol 4.00
(D) liquid paraffin 5.00
(D) olive oil 0.50
(D) shea butter 0.50
(D) camellia oil 0.50
(D) Jojoba oil 0.50
(D) Rosehip oil 0.50
(D) Methylpolysiloxane 1.00
(D) Highly polymerized methylpolysiloxane (1) 0.20
(E) behenyltrimethylammonium chloride 1.60
Toluene-2,5-diamine 3.00
2,4-diaminophenoxyethanol hydrochloride 0.20
Para-aminophenol 0.20
Meta-aminophenol 0.50
Resorcinol 0.80
5-amino ortho cresol 0.15
Seaweed extract (1) 0.10
Hydrolyzed conchiolin solution 0.10
Glycyrrhiza extract 0.50
hawthorn extract 0.10
Water-soluble collagen solution (3) 0.10
Royal jelly extract 0.10
Sodium sulfite 0.20
L-ascorbic acid 0.50
Pentasodium diethylenetriaminepentaacetic acid 0.90
DL-sodium malate 1.00
Monoethanolamine (80%) 8.00
Polydimethylmethylene pyrrolidinium chloride 0.15
Dimethyldiallylammonium chloride/acrylic acid copolymer 0.65
Purified water 62.83
Total 100.00

(Example 85)
First agent
Component content (mass%)
(A) Glycerin 5.00
(B) Polyoxyethylene cetyl ether (15E.O.) 0.40
(B) Polyoxyethylene cetyl ether (40 E.O.) 0.20
(C) Cetanol 1.00
(C) stearyl alcohol 5.00
(D) liquid paraffin 3.00
(D) olive oil 0.50
(D) Rosehip oil 0.50
(E) behenyltrimethylammonium chloride 1.60
Seaweed extract (1) 0.10
Hydrolyzed conchiolin solution 0.10
Glycyrrhiza extract 0.50
hawthorn extract 0.10
Water-soluble collagen solution (3) 0.10
Camellia oil 0.50
Royal jelly extract 0.10
Sodium sulfite 0.20
L-ascorbic acid 0.50
Pentasodium diethylenetriaminepentaacetic acid 0.90
DL-sodium malate 1.00
Monoethanolamine (80%) 8.00
Polydimethylmethylene pyrrolidinium chloride 0.15
Dimethyldiallylammonium chloride/acrylic acid copolymer 0.40
Purified water 69.85
Total 100.00

(Example 86)
First agent
Component content (mass%)
(A) Glycerin 5.00
(B) Polyoxyethylene cetyl ether (15E.O.) 0.40
(B) Polyoxyethylene cetyl ether (40 E.O.) 0.20
(C) cetyl alcohol 1.00
(C) Octyldodecanol 4.00
(D) liquid paraffin 5.00
(D) olive oil 0.50
(D) shea butter 0.50
(D) camellia oil 0.50
(D) Jojoba oil 0.50
(D) Rosehip oil 0.50
(D) Methylpolysiloxane 1.00
(D) Highly polymerized methylpolysiloxane (1) 0.20
(E) behenyltrimethylammonium chloride 1.60
Toluene-2,5-diamine 3.00
2,4-diaminophenoxyethanol hydrochloride 0.20
Para-aminophenol 0.20
Meta-aminophenol 0.50
Resorcinol 0.80
5-amino ortho cresol 0.15
Seaweed extract (1) 0.10
Hydrolyzed conchiolin solution 0.10
Glycyrrhiza extract 0.50
hawthorn extract 0.10
Water-soluble collagen solution (3) 0.10
Royal jelly extract 0.10
Sodium sulfite 0.20
L-ascorbic acid 0.50
Pentasodium diethylenetriaminepentaacetic acid 0.90
DL-sodium malate 1.00
Monoethanolamine (80%) 8.00
Polydimethylmethylene pyrrolidinium chloride 0.15
Dimethyldiallylammonium chloride/acrylic acid copolymer 0.65
Purified water 62.83
Total 100.00

(Example 87)
First agent
Component content (mass%)
(A) Glycerin 5.00
(B) Polyoxyethylene cetyl ether (15E.O.) 0.40
(B) Polyoxyethylene cetyl ether (40 E.O.) 0.20
(C) stearyl alcohol 3.50
(C) Octyldodecanol 0.50
(D) liquid paraffin 5.00
(D) olive oil 0.50
(D) shea butter 0.50
(D) camellia oil 0.50
(D) Jojoba oil 0.50
(D) Rosehip oil 0.50
(D) Methylpolysiloxane 1.00
(D) Highly polymerized methylpolysiloxane (1) 0.20
(E) behenyltrimethylammonium chloride 1.60
Toluene-2,5-diamine 3.00
2,4-diaminophenoxyethanol hydrochloride 0.20
Para-aminophenol 0.20
Meta-aminophenol 0.50
Resorcinol 0.80
5-amino ortho cresol 0.15
Seaweed extract (1) 0.10
Hydrolyzed conchiolin solution 0.10
Glycyrrhiza extract 0.50
hawthorn extract 0.10
Water-soluble collagen solution (3) 0.10
Royal jelly extract 0.10
Sodium sulfite 0.20
L-ascorbic acid 0.50
Pentasodium diethylenetriaminepentaacetic acid 0.90
DL-sodium malate 1.00
Monoethanolamine (80%) 8.00
Polydimethylmethylene pyrrolidinium chloride 0.15
Dimethyldiallylammonium chloride/acrylic acid copolymer 0.65
Purified water 62.85
Total 100.00

(Example 88)
Second agent
Component content (mass%)
(A) polyethylene glycol (average molecular weight: 400) 1.50
(B) Polyoxyethylene cetyl ether (10E.O.) 1.50
(B) Polyoxyethylene cetyl ether (20E.O.) 2.40
(C) Cetanol 5.50
(C) stearyl alcohol 3.00
(D) liquid paraffin 3.00
Hydrogen peroxide 5.85
Hydroxyethanediphosphonic acid 0.20
Potassium hydroxide 0.05
Purified water 77.00
Total 100.00

(Example 89)
Second agent
Component content (mass%)
(A) polyethylene glycol (average molecular weight: 400) 1.50
(B) Polyoxyethylene cetyl ether (10E.O.) 1.50
(B) Polyoxyethylene cetyl ether (20E.O.) 2.40
(C) Cetanol 4.50
(C) Octyldodecanol 4.00
(D) liquid paraffin 3.00
Hydrogen peroxide 5.85
Hydroxyethanediphosphonic acid 0.20
Potassium hydroxide 0.05
Purified water 77.00
Total 100.00

INDUSTRIAL APPLICABILITY According to the present invention, it is possible to obtain an aerosol type hair dye or bleach composition that has good spreadability when applied, good stability under high temperature conditions, and good hair dyeing properties.

DESCRIPTION OF SYMBOLS 100... Grip part 110... Base type brush 111... Brush base 112... Long tooth 113... Short tooth 120... Comb part

Claims (6)

An aerosol-type cream hair dye or bleach composition,
Both the first agent and the second agent are (A) at least one selected from glycerin, polyethylene glycol, dipropylene glycol and diglycerin ;
(B) polyoxyethylene alkyl ether,
(C) a higher alcohol having 16 to 22 carbon atoms,
(D) containing at least one selected from liquid paraffin, olive oil, isopropyl myristate, dimethylpolysiloxane, highly polymerized dimethylpolysiloxane and petroleum jelly, and the weight of the component (C) and the component (D) The ratio (C)/(D) is 0.25 to 4,
The content of the component (A) in the first agent is 1 to 10 mass%, the content of the component (B) is 0.5 to 8 mass%, and the content of the component (C) is 2. ~ 12% by mass, the content of the component (D) is 2 to 20% by mass,
The content of the component (A) in the second agent is 1 to 8% by mass, the content of the component (B) is 1.8 to 15% by mass, and the content of the component (C) is 5% by mass. 16 mass %, and the content of the component (D) is 2 to 20 mass % . Mass ratio ((B) + (E)) / ((B) + (E))/( The aerosol type cream hair dye or bleach composition according to claim 1, wherein A) is 0.25-4. 3. The aerosol type cream hair dye or bleach composition according to claim 1, wherein the component (B) is polyoxyethylene cetyl ether. 4. The aerosol cream dye according to any one of claims 1 to 3, wherein the component (C) contains at least one selected from cetyl alcohol, stearyl alcohol and octyldodecanol. A hair or depigmenting composition. 3. The aerosol type cream hair dye or bleach composition according to claim 2, wherein the component (E) is behenyltrimethylammonium chloride. 2. The aerosol type creamy hair dye or decolorant composition according to claim 1, wherein the aerosol type hair dye or decolorant composition is used by discharging it onto a brush.

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