JPWO2013172046A1 - Raw material charging method to blast furnace - Google Patents

Abstract

In the blast furnace operation method in which ore raw materials such as sintered ore, pellets and massive ore and blast furnace charging raw materials of coke are charged into the blast furnace using a rotating chute, mixing of the ore raw materials and the coke is mixed. When the mixed layer is formed in a predetermined region in the blast furnace by charging the raw material into the blast furnace as a raw material, the mixed layer is made uniform by setting the discharge rate of the mixed raw material into the blast furnace to 1.5 t / s or more. Improve sexiness.

Description

  The present invention relates to a raw material charging method for a blast furnace in which a raw material is charged into a furnace with a swirl chute, and in particular, aims to achieve uniformization of a mixed layer of ore raw material and coke.

  In a blast furnace, generally, ore raw materials such as sintered ore, pellets and massive ore and coke are charged in layers from the top of the furnace, and combustion gas flows from the tuyere to obtain pig iron. The coke and ore raw material, which are the charged raw materials for the blast furnace, descend from the top of the furnace to the lower part of the furnace, and ore reduction and raw material temperature rise occur. The ore raw material layer is gradually deformed while filling the gaps between the ore raw materials due to the temperature rise and the load from above, and the lower part of the shaft part of the blast furnace has a very high resistance to gas and almost no gas flows. Form a layer.

Conventionally, raw material charging into a blast furnace is performed by alternately charging ore raw materials and coke, and in the furnace, ore raw material layers and coke layers are alternately layered. Further, in the lower part of the blast furnace, there is a region called a cohesive zone where an ore raw material layer having a large ventilation resistance softened and fused with ore and a coke slit having a relatively small ventilation resistance derived from coke are mixed.
The air permeability of this cohesive zone has a great influence on the air permeability of the entire blast furnace, and the productivity in the blast furnace is limited. When a low coke operation is performed, it is considered that the coke slit becomes extremely thin because the amount of coke used is reduced.

In order to improve the cohesive zone ventilation resistance, it is known that mixing coke into the ore raw material layer is effective, and many studies have been reported to obtain an appropriate mixing state. .
For example, in Patent Document 1, in a bell-less blast furnace, coke is charged into the ore hopper on the downstream side of the ore hopper, the coke is stacked on the ore on a conveyor, charged into the furnace top bunker, and the ore And coke are charged into the blast furnace through a turning chute.
However, in Patent Document 1, since ore and coke are mixed in the furnace top bunker, segregation occurs in the furnace top bunker, and the mixing ratio of iron ore and coke cannot be accurately maintained. There was a problem.

Patent Document 2 proposes that ore and coke are separately stored in a bunker at the top of the furnace, and coke and ore are mixed and charged simultaneously.
However, no particular consideration is given to the separation of coke and ore after the raw material is charged into the furnace, and there is concern about the separation of coke and ore due to segregation of coarse and fine particles after raw material charging. .

Furthermore, in Patent Document 3, in order to prevent the instability of the cohesive zone shape in the blast furnace operation and the decrease in the gas utilization rate near the center, and to improve the safe operation and thermal efficiency, the raw material charging method in the blast furnace is In addition, after all ore and all coke are thoroughly mixed, they are charged into the furnace.
However, in the technique described in Patent Document 3, although a blast furnace having no coke slit is described, a specific raw material charging method in the blast furnace is not mentioned, and a method for controlling the charge mixture rate is not described. It is unknown.

By the way, the inventors, in Patent Document 4, as a raw material charging method to improve the ventilation resistance without the presence of coke slits,
`` A method of operating a blast furnace in which ore raw materials such as sintered ore, pellets, massive ore and blast furnace charging raw materials of coke are charged into the blast furnace with a rotating chute,
When charging the blast furnace charging raw material into the blast furnace, a central coke layer was formed in the axial center portion, and the ore raw material and coke were mixed so as not to generate a coke slit outside the central coke layer. A raw material charging method for a blast furnace, wherein a mixed layer is formed. "
Proposed.

JP-A-3-211210 JP 2004-107794 A Japanese Patent Publication No.59-10402 JP 2012-97301 A

  Due to the development of the above-mentioned Patent Document 4, the air permeability in the blast furnace has been greatly improved, and stable blast furnace operation has become possible.

  The present invention relates to the improvement of the technique described in Patent Document 4 described above, and at the time of forming a mixed layer, it is intended to achieve further uniformization and thereby enable more stable blast furnace operation. It is.

Now, the inventors have made various studies in order to achieve further uniformity in forming the mixed layer in the blast furnace.
As a result, the present inventors have obtained a novel finding that the uniformization of the mixed layer is greatly improved by increasing the discharge rate of the mixed raw material into the blast furnace.
The present invention is based on the above findings.

That is, the gist configuration of the present invention is as follows.
1. In the blast furnace operation method of charging ore raw materials such as sintered ore, pellets, massive ore and blast furnace charging raw materials of coke into the blast furnace using a rotating chute,
When a mixed layer is formed in a predetermined region in the blast furnace by charging the mixed raw material and the coke into the blast furnace, the discharge rate of the mixed raw material into the blast furnace is 1.5 t. / S or more, The raw material charging method to the blast furnace characterized by the above-mentioned.

2. At least two furnace top bunkers disposed at the top of the blast furnace, and a collecting hopper disposed at a discharge port of each furnace top bunker and mixing raw materials discharged from the furnace top bunker to supply the swirl chute With
One or two of the furnace top bunker stores either or both of the ore raw material or the mixed raw material obtained by mixing the ore raw material and the coke, and stores them in one of the remaining furnace top bunkers. When the coke is stored and the mixed layer is formed, the coke and the ore raw material and / or mixed raw material are discharged simultaneously from the furnace top bunker, mixed with the collecting hopper, and mixed into the swivel chute. 2. The raw material charging method to the blast furnace as described in 1 above, wherein the raw material is supplied.

3. 3. The raw material charging method to the blast furnace according to 1 or 2 above, wherein a central coke layer is formed in the axial center portion of the blast furnace when charging the blast furnace raw material into the blast furnace.

  According to the present invention, when the mixed raw material in which the ore raw material and coke are mixed into the blast furnace is charged and the mixed layer is formed in the blast furnace, it is possible to achieve further uniformization of the mixed layer, which is more stable It becomes possible to carry out the blast furnace operation.

It is a schematic diagram which shows the raw material charging state containing a furnace top bunker. It is a schematic block diagram which shows the experimental apparatus which measures the high temperature property of an ore raw material. It is a graph which shows the relationship between the mixing ratio of the coke to the ore raw material and the maximum pressure loss ratio which used the coke particle diameter as a parameter. It is the graph which showed the time-dependent change of the mixing rate of the coke in a charging raw material in the case of mixing in a bunker and simultaneous discharge mixing. It is the graph which showed the change of the coke mixing ratio over the furnace radial direction when changing discharge speed on simultaneous discharge conditions. It is the graph which showed the change of the mixing rate at the time of changing various discharge speeds at the time of simultaneous discharge.

Hereinafter, an embodiment of the present invention will be described with reference to the drawings.
A specific charging procedure for charging the ore material and coke into the blast furnace will be described with reference to FIG.
In this example, the ore raw material and coke mixed raw material are stored in the furnace top bunker 12b, only the coke is stored in the furnace top bunker 12a, and only the ore raw material is stored in the furnace top bunker 12c. Yes.
Here, in the mixed raw material stored in the furnace top bunker 12b, the coke amount is preferably adjusted to 30% by mass or less of the total coke amount. This is because, if the amount of coke to be mixed is 30% by mass or less of the total amount of coke, when the coke is stored in the furnace top bunker 12b, there is no large segregation between the coke and the ore raw material, and the turning chute It is because the mixing rate of the mixed layer of the ore raw material and coke formed by 16 can be made substantially uniform.
On the other hand, when the amount of coke exceeds 30% by mass of the total amount of coke, segregation due to difference in specific gravity and particle size is likely to occur, and segregation between coke and ore raw material when stored in the furnace top bunker 12b. As a result, a region in which only the ore raw material or only coke exists locally is generated.

Now, in order to charge the raw material from the furnace bunker, the coke, mixed raw material and ore raw material discharged from the furnace top bunkers 12a to 12c after being adjusted to a predetermined flow rate by the flow rate adjusting gate 13 are collected into the collecting hopper 14. Then, the mixture is fed to the bellless type charging device 15 immediately below, and charged into the blast furnace 10 by the turning chute 16 of the bellless type charging device 15.
Here, the swirl chute 16 is revolved around the axis of the blast furnace 10 and at the same time is reversely tilted so as to tilt from the axial center of the blast furnace 10 toward the furnace wall. The case of making an input will be described.
The case where the central coke layer is formed in the axial center portion of the blast furnace will be described.

Now, the turning chute 16 is controlled to reversely tilt so as to turn about the central axis of the blast furnace 10 and simultaneously tilt toward the furnace wall side from the axial center side of the furnace center of the blast furnace 10, and is discharged from the top bunker 12. Raw material charging is performed by a reverse tilt control method in which the charged blast furnace charging material is charged in the reverse direction from the furnace center side to the furnace wall side.
At this time, in the initial charging state where the turning chute 16 is tilted in a substantially vertical state, the flow rate adjusting gates 13 of the furnace top bunkers 12b and 12c are closed, and the flow rate adjusting gate 13 of only the furnace top bunker 12a is opened. Only the coke stored in the furnace top bunker 12a is supplied to the turning chute 16, and a central coke layer 12d is formed at the axial center as shown in FIG.

  Thereafter, the swiveling chute 16 is gradually tilted in the horizontal direction, and when the formation of the central coke layer 12d is completed, the flow rate adjusting gates 13 of the remaining two furnace top bunkers 12b and 12c are opened at a predetermined ratio, The coke discharged from the bunker 12a and the mixed raw material discharged from the top bunker 12b and / or the ore raw material discharged from the top bunker 12c are simultaneously supplied to the collecting hopper 14. Therefore, the coke and the ore raw material are completely mixed by the collecting hopper 14 and then supplied to the turning chute 16, and as shown in FIG. 1, the coke and the ore are outside the central coke layer 12 d in the blast furnace 10. The mixed layer 12e which does not produce a coke slit with a substantially uniform mixing ratio with the raw material is formed.

Here, the coke amount of the central coke layer 12d and the mixed layer 12e is such that the coke amount of the central coke layer 12d is about 5 to 30% by mass of the total charge amount of coke per charge, while the coke amount of the mixed layer 12e is It is set to about 70 to 95% by mass of the total coke amount.
The region where the central coke layer is formed is preferably 0 or more and 0.3 or less in the dimensionless radius of the blast furnace where the blast furnace axial center part is 0 and the furnace wall part is 1. The reason for this is that by collecting a part of the coke in the core part of the furnace, the air permeability in the shaft part and thus the air permeability of the entire blast furnace can be effectively improved.
The amount of coke charged to form the central coke layer is preferably about 5 to 30% by mass of the amount of coke charged per charge. This is because if the amount of coke charged to the shaft center portion is less than 5% by mass, the air permeability around the shaft center portion is not sufficiently improved, while more than 30% by mass of coke is concentrated on the shaft center portion. In this case, not only the amount of coke for use in the mixed layer is reduced, but also the amount of heat removed from the furnace body is increased due to excessive gas flow in the axial center. Preferably it is 10-20 mass%.

Then, layers composed of the central coke layer 12d and the mixed layer 12e are sequentially formed in the blast furnace 10 from the lower part to the upper part.
By sequentially laminating the layers composed of the central coke layer 12d and the mixed layer 12e in this way, the central coke layer 12d having a low ventilation resistance is formed from the lower portion of the blast furnace toward the upper portion of the blast furnace. The mixed layer 12e in which the coke and the ore raw material are mixed is formed around it.

Therefore, in order to demonstrate the above-mentioned effect, the inventors investigated the change in the ventilation resistance by simulating the raw material reduction and the temperature raising process in the blast furnace using the experimental apparatus shown in FIG.
In this experimental apparatus, a furnace core tube 32 is disposed on the inner peripheral surface of a cylindrical furnace body 31, and a cylindrical heating heater 33 is disposed outside the furnace core tube 32. A graphite crucible 35 is disposed at the upper end of a cylindrical body 34 made of a refractory inside the furnace core tube 32, and a charging raw material 36 is charged into the crucible 35. A load is applied to the charged raw material 36 from above by a load loading device 38 connected via a punch bar 37 so as to be in the same level as the fused layer at the bottom of the blast furnace. A drop sampling device 39 is provided below the cylindrical body 34.

The gas adjusted by the gas mixing device 40 is sent to the crucible 35 through the lower cylindrical body 34, and the gas that has passed through the raw material 36 in the crucible 35 is analyzed by the gas analyzer 41. The heating heater 33 is provided with a thermocouple 42 for controlling the heating temperature, and the crucible 35 is set to 1200 to 1500 by controlling the heater 33 with a control device (not shown) while measuring the temperature with the thermocouple 42. Heat to ° C.
Here, as the ore of the charging raw material 36 charged in the crucible 35, a mixture of 50 to 100% by mass of sintered ore and 0 to 50% by mass of massive iron ore was used.

FIG. 3 is a graph in which the relationship between the maximum pressure loss ratio and the mixing amount when the mixing amount of coke with respect to the ore is changed in the case where the size of the coke is different.
As shown in FIG. 3, the pressure loss was highest when coke was not mixed, whereas the addition of coke significantly reduced the airflow resistance, and this effect increased as the amount of coke increased. I understand. The reason for this is that mixing the coke suppresses the deformation of the ore and maintains the voids in the vicinity of the mixed coke, which suppresses the phenomenon in which the voids between the particles decrease due to the deformation of the ore and the ventilation resistance increases. It is thought that.
In addition, as shown in the figure, when using lump coke and small medium coke, the airflow resistance value in the fusion layer is different, and when using small coke, when using lump coke It was found that the pressure loss was small even with the same mixing amount.
Here, the lump coke means a particle having a particle size of about 30 to 60 mm, and the small and medium lump coke means a particle having a particle size of about 10 to 30 mm. On the other hand, the ore raw material usually has a particle size of about 5 to 25 mm.
Here, in order to avoid deterioration of the air permeability in the furnace due to the particle size of the ore raw material and the coke, the particle size of the ore raw material is preferably 10 to 30 mm and the particle size of the coke is preferably 30 to 55 mm. Furthermore, it is preferable that the particle size ratio (coke particle size / ore material particle size) is about 1.0 to 5.5.

  Moreover, when the inventors investigated the ratio of coke in the mixed layer suitable for reduction of pressure loss, that is, improvement of air permeability (amount of coke / amount of ore raw materials), the mass ratio was about 7 to 25%. It turned out to be preferable. More preferably, it is 10 to 15% of range. In addition, when the suitable ratio of the coke in a mixed layer is converted into the ratio with respect to the total amount of coke, it will be about 20 to 95%.

  By the way, even when the simulation test was performed under the preferable conditions as described above, an increase in the airflow resistance considered to be caused by the non-uniformity of the mixed layer was observed.

Therefore, the inventors conducted an evaluation test of the mixing ratio of coke in the ore raw material using a charging model device that becomes 1/18 scale of an actual blast furnace simulating the top of the blast furnace as shown in FIG. It was.
In this model device, in order to make the material's fall trajectory and deposition behavior coincide with the actual furnace, the raw material particle size is 1/18 times that of the actual blast furnace, the raw material charging amount is 1/18 times, and the charging chute is The turning speed was 1/18 times.

FIG. 4 shows the results of examining the change over time in the mixing ratio of coke in the charged raw material when ore and coke are mixed in a bunker or when ore and coke are discharged simultaneously from two bunker. In either case, the amount of ore and coke was constant, and the target mixing ratio was set to 0.05.
As shown in FIG. 4, when ore and coke are mixed in a bunker, the mixing rate increases in the early and late stages of discharge, and the mixing ratio decreases from the target value (0.05) in the middle of discharging. . On the other hand, when ore and coke were discharged from two bunkers at the same time, the mixing ratio of coke in the ore showed a substantially constant value with respect to the target value. Therefore, it can be seen that co-discharge mixing can control the mixing ratio of coke with higher accuracy than mixing in a bunker.

Next, the results of investigating the change in the coke mixing ratio over the radial direction of the furnace when the discharge rate was changed to 0.85 t / s and 1.27 t / s (both converted to actual machine) under the simultaneous discharge conditions, As shown in FIG.
As shown in FIG. 5, the difference between the maximum value and the minimum value of the coke mixing ratio is greater when the discharge rate is 1.27 t / s in terms of actual equipment than when the discharge rate is 0.85 t / s in terms of actual equipment. It can be seen that it is smaller and more uniformly mixed.

Therefore, the inventors next investigated the change in the mixing ratio when the discharging speed at the time of simultaneous discharging was variously changed. The quality of the mixing rate was judged by the difference between the maximum mixing rate and the minimum mixing rate in the furnace radial direction. The obtained result is shown in FIG. In addition, it can be said that it is mixed more uniformly so that this difference is small.
As shown in FIG. 6, the difference between the maximum mixing rate and the minimum mixing rate decreases as the material discharge rate increases. That is, it can be seen that the ore and coke can be mixed more uniformly by increasing the discharge rate of the raw material.
In particular, by setting the discharge speed to 1.5 t / s or more, the difference between the maximum mixing rate and the minimum mixing rate is greatly reduced, and is substantially constant at 1.8 t / s or more.

  The conventional general raw material discharge rate is about 0.8 to 1.3 t / s, and conventionally no particular attention has been paid to this discharge rate.

Here, the reason why the difference between the maximum mixing ratio and the minimum mixing ratio is reduced by increasing the discharge rate of the charged raw material, that is, the uniformity of the mixed layer is not yet clearly clarified. However, the inventors speculate as follows.
The segregation of the charged raw material is considered to occur because ore having a small particle size is easily affected by the unevenness of the raw material deposition surface when the flow of the charged raw material flows on the stationary raw material deposition surface.
In this regard, when the charging speed is increased, the kinetic energy of the charging raw material during the movement of the deposition surface is increased, and the ore having a small particle size is suppressed. Further, when the discharge rate of the raw material is increased, the layer thickness of the charged raw material flow increases. Furthermore, when the layer thickness of the charged raw material flow is increased, the ratio of particles in contact with the lower surface is relatively decreased, and the influence of unevenness on the lower surface is reduced.
From the above, it is presumed that when the charging speed is increased, segregation of the charging raw material is suppressed and the uniformization of the mixed layer is achieved.

  Note that during blast furnace operation, the shaft pressure is closely monitored, and when the blast furnace charging according to the present invention is continuously performed, if an abnormality is detected in the shaft pressure, the raw material charging method is changed to the normal charging method. It is advantageous to switch to a method in which the ore raw material layer and the coke slit are formed separately, and then after switching to the charging method according to the present invention, once the shaft pressure abnormality is resolved, it is advantageous to operate. .

DESCRIPTION OF SYMBOLS 10 Blast furnace 12a-12c Furnace top bunker 12d Center coke layer 12e Mixing layer 13 Flow control gate 14 Collective hopper 15 Bellless type charging device 16 Turning chute 31 Cylindrical furnace body 32 Furnace core tube 33 Cylindrical heater 34 Cylindrical heater Body 35 Graphite crucible 36 Charge raw material 37 Punch rod 38 Load loading device 40 Mixing device 41 Gas analyzer 42 Thermocouple

That is, the gist configuration of the present invention is as follows.
1. In the blast furnace operation method of charging ore raw materials such as sintered ore, pellets, massive ore and blast furnace charging raw materials of coke into the blast furnace using a rotating chute,
Simultaneously discharging the coke and the ore raw material and / or the mixed raw material obtained by mixing the ore raw material and the coke from the furnace top bunker, mixing them in a collecting hopper, and supplying the swirl chute, When a mixed layer is formed in a predetermined region in the blast furnace by charging it into the blast furnace as a mixed raw material in which the ore raw material and the coke are mixed, the discharge rate of the mixed raw material into the blast furnace is 1.5 t / A method of charging a raw material into a blast furnace, characterized in that it is s or more.

Therefore, the inventors conducted an evaluation test of the mixing ratio of coke in the ore raw material using a charging model device that becomes 1/18 scale of an actual blast furnace simulating the top of the blast furnace as shown in FIG. It was.
In this model device, in order to match the material's dropping trajectory and deposition behavior with the actual furnace, the raw material particle size is 1/18 times that of the actual blast furnace, the raw material charge is (1/18) ³ times, The turning speed of the incoming chute was (1/18) ^0.5 times.

Claims (3)

In the blast furnace operation method of charging ore raw materials such as sintered ore, pellets, massive ore and blast furnace charging raw materials of coke into the blast furnace using a rotating chute,
When a mixed layer is formed in a predetermined region in the blast furnace by charging the mixed raw material and the coke into the blast furnace, the discharge rate of the mixed raw material into the blast furnace is 1.5 t. / S or more, The raw material charging method to the blast furnace characterized by the above-mentioned. At least two furnace top bunkers disposed at the top of the blast furnace, and a collecting hopper disposed at a discharge port of each furnace top bunker and mixing raw materials discharged from the furnace top bunker to supply the swirl chute With
One or two of the furnace top bunker stores either or both of the ore raw material or the mixed raw material obtained by mixing the ore raw material and the coke, and stores them in one of the remaining furnace top bunkers. When the coke is stored and the mixed layer is formed, the coke and the ore raw material and / or mixed raw material are discharged simultaneously from the furnace top bunker, mixed with the collecting hopper, and mixed into the swivel chute. The raw material charging method to the blast furnace according to claim 1, wherein the raw material is supplied.   3. The method of charging a blast furnace with a raw material according to claim 1 or 2, wherein a central coke layer is formed at the axial center of the blast furnace when the blast furnace charging material is charged into the blast furnace.

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