JPWO2013108725A1 - Manufacturing method of glass plate, manufacturing method of glass substrate for display, and glass plate - Google Patents

Abstract

The method for producing a glass plate includes a step of grinding an end surface of the glass plate and a step of polishing the end surface of the glass plate after grinding. The step of grinding the end surface of the glass plate includes a first grinding step of grinding the end surface of the glass plate using a first grinding wheel in which abrasive grains are hardened with a first binder, and a first grinding step. Then, a second grinding step of grinding the end face of the glass plate using a second grinding wheel in which the abrasive grains are hardened with a second binder whose hardness and rigidity are lower than those of the first binder. Have.

Description

  The present invention relates to a method for manufacturing a glass plate, a method for manufacturing a glass substrate for a display, and a glass plate including a step of grinding an end face of a molded glass plate.

  When manufacturing a glass plate such as a flat panel display, the formed glass plate is cut into a predetermined size. In cutting a glass plate, mechanical cutting using a cutter and cutting using a laser are generally used. In the cutting of a glass plate using a cutter, since the glass plate is mechanically cut and cut, a crack having a depth of about several μm to 100 μm, for example, a thickness of the glass plate is formed on the cut end surface. Cracks extending from the surface to the inside from 7% to 10% are generated. This crack causes deterioration of the mechanical strength of the glass plate. Moreover, in the cutting | disconnection using a laser, since it cut | disconnects and cut | disconnects in a glass plate using a thermal stress, the end surface of the cut | disconnected glass plate will be in the state which is sharp and easy to chip. Therefore, the cracks and sharp portions on the end face of the cut glass plate are removed by grinding and polishing. That is, the end face of the glass plate is ground and polished in order to increase the mechanical strength of the glass plate, prevent chipping and cracking of the glass plate, and facilitate handling in the subsequent process.

  As processing of the end face of the glass plate, there is known a chamfering method in which the end face of the glass plate is ground by a metal bond diamond wheel and then polished by a polishing wheel having flexibility and elasticity disclosed in JP-A-2001-259978. It has been. However, in the conventional end surface processing, even if polishing is performed with the above-described polishing wheel, removal of minute irregularities on the end surface of the glass plate may be insufficient. In such a case, if particles such as glass powder are clogged in the minute irregularities on the end face of the glass plate, the particles clogged in the irregularities in the subsequent process are the main surfaces that are the front and back surfaces of the glass plate during the processing in the subsequent process. It adheres to and causes the quality of the glass plate to deteriorate. Furthermore, when the unevenness | corrugation of the end surface of a glass plate is not fully reduced, the mechanical strength of a glass plate may fall. Moreover, in the manufacturing method of a glass plate, in order to improve the productivity of a glass plate, it is also necessary to raise a grinding speed.

  The present invention provides a method for producing a glass plate, a method for producing a glass substrate for a display, and a glass plate that reduce the unevenness of the end face of the glass plate as compared with the conventional method while securing the production amount of the glass plate.

One embodiment of the present invention is a method for manufacturing a glass plate. The manufacturing method is
Grinding the end face of the glass plate;
Polishing the end face of the glass plate after grinding.
The step of grinding the end face of the glass plate,
A first grinding step of grinding an end face of the glass plate using a first grinding wheel in which abrasive grains are hardened with a first binder;
After the first grinding step, the end face of the glass plate is ground using a second grinding wheel in which abrasive grains are hardened with a second binder having lower hardness and rigidity than the first binder. 2 grinding processes.

  Preferably, the first binder is a metal binder and the second binder is a resin binder.

  In the first grinding step, the end surface of the glass plate is ground so that the maximum height Rmax defined in JIS B 0601-1982 is 10 μm or more and 18 μm or less. In the second grinding step, The end surface of the glass plate is preferably ground so that the maximum height Rmax is 4 μm or more and 8 μm or less.

  In the step of polishing the glass plate, the end surface of the glass plate is preferably polished so that the maximum height Rmax is less than 4 μm.

  Preferably, the grinding amount of the end face of the glass plate in the first grinding step is 40 μm or more and 60 μm or less, and the grinding amount of the end face of the glass plate in the second grinding step is 10 μm or more and 30 μm or less. It is.

In that case, it is preferable to grind | polish without the said grinding | polishing process changing substantially the shape of the end surface of the said glass substrate ground by the said grinding process.
Moreover, it is preferable that the said grinding | polishing process mirror-processes the end surface ground by the said grinding process.

Preferably, performing the first grinding step, the second grinding step, and the step of polishing the glass plate while conveying the glass plate,
The conveyance direction of the glass plate in the second grinding step is opposite to the conveyance direction of the glass plate in the first grinding step.

  In that case, the rotation direction of the first grinding wheel at the point where the first grinding wheel contacts the glass plate is opposite to the conveying direction of the glass plate, and the second grinding wheel is The rotation direction of the second grinding wheel at the point of contact with the glass plate is preferably the same direction as the conveying direction of the glass plate.

The conveyance speed of the said glass plate is 10 m / min or more, for example.
The conveyance speed of the glass plate in the second grinding step is, for example, 15 m / min or more.

The abrasive grains of the first grinding wheel and the second grinding wheel are diamond abrasive grains,
The grain size of the abrasive grains of the first grinding wheel is preferably equal to or coarser than the grain size of the abrasive grains of the second grinding wheel.

Further, in the step of polishing the glass plate, the binder of the polishing wheel for polishing the end surface of the glass plate is a foamed elastic material, and the abrasive is one or more selected from SiC, Al ₂ O ₃ , or CeO ₂ It is preferable to be formed of the material.

  The glass plate is used for a substrate of a display device of a flat panel display or a cover glass of a display screen of an electronic device, and the glass plate is preferably formed by a down draw method or a float method.

Moreover, the other one aspect | mode of this invention is the glass plate manufactured by the manufacturing method of the said glass plate. The glass plate
The cross-sectional shape of the end surface of the glass plate is formed into a convex shape with a curvature, and the maximum height Rmax defined by JIS B 0601-1982 of the end surface of the glass plate is less than 4 μm, and JIS B 0601-1982 The arithmetic average roughness Ra specified by is 0.06 μm or less.

Furthermore, another one aspect | mode of this invention is a manufacturing method of the glass substrate for displays. The manufacturing method is
Grinding the end face of the glass substrate and grinding the end face into a convex shape with a curvature;
Polishing without substantially changing the shape of the end face of the glass substrate after grinding;
including.
The step of grinding the end surface of the glass substrate,
A first polishing wheel in which abrasive grains are hardened with a first binder is used to grind the end surface of the glass substrate so that the maximum height Rmax defined in JIS B0601-1982 is 10 μm or more and 18 μm or less. Grinding process of
After the first grinding step, using a second grinding wheel in which abrasive grains are hardened with a second binder having lower hardness and rigidity than the first binder, the amount of grinding by the second grinding wheel And a second grinding step that sets the value to be equal to or greater than the value measured as Rmax.

  In that case, it is preferable that the grinding amount of the end surface of the said glass plate in a said 2nd grinding process is 10 micrometers or more and 30 micrometers or less.

  Moreover, it is preferable that the thickness of the said glass substrate is 0.25 mm-0.7 mm.

  According to the manufacturing method and glass plate of the said aspect, the unevenness | corrugation of the end surface of a glass plate can be reduced conventionally compared with ensuring the manufacture amount of a glass plate.

It is a figure which shows the flow of the processing of the end surface of the glass plate in 1 line in the manufacturing process of a glass plate. It is a perspective view which shows the 1st grinding wheel and 2nd grinding wheel in this embodiment.

Hereinafter, the manufacturing method of the glass plate of this invention, the manufacturing method of the glass substrate for a display, and a glass plate are demonstrated in detail based on this embodiment.
Although the glass plate manufactured in this embodiment is not particularly limited, for example, it is suitable for a cover glass used for a display screen of an electronic device such as a portable electronic device, a display glass substrate for a display device such as a flat panel display, and the like. Used.

Although the composition of a glass plate is not specifically limited, For example, it can apply to the glass plate of the following composition ratios.
(A) SiO ₂ : 50 to 70% by mass,
(B) B ₂ O ₃ : 5 to 18% by mass,
(C) Al ₂ O ₃ : 10 to 25% by mass,
(D) MgO: 0 to 10% by mass,
(E) CaO: 0 to 20% by mass,
(F) SrO: 0 to 20% by mass,
(O) BaO: 0 to 10% by mass,
(P) RO: 5 to 20% by mass (wherein R is at least one selected from Mg, Ca, Sr and Ba, and is the total content of RO),
(Q) R ′ ₂ O: more than 0.20% by mass and 2.0% by mass or less (where R ′ is at least one selected from Li, Na and K, and is the total content of R ′ ₂ O) is there),
(R) 0.05 to 1.5 mass% in total of at least one metal oxide selected from tin oxide, iron oxide, and cerium oxide.

  In this embodiment, after the melted glass is formed by the downdraw method, the glass plate cut to a predetermined length is conveyed at a conveyance speed of 10 m / min or more, and the end surface of the glass plate is ground and polished. Do. The glass forming method is not limited to the downdraw method, and may be formed by other methods such as a float method.

  FIG. 1 is a diagram showing a flow of processing of an end face of a glass plate in one line during the manufacturing process of the glass plate manufacturing method or the display glass substrate manufacturing method of the present embodiment. Hereinafter, unless specifically distinguished from each other, the glass plate and the glass substrate are referred to as a glass plate. The glass plate end face processing line 10 is provided with a first chamfering machine 12, a second chamfering machine 14, a corner cutting machine 16, and a reversing machine 18. The 1st chamfering machine 12, the reversing machine 18, the 2nd chamfering machine 14, and the corner cutting machine 16 are arrange | positioned in order from the upstream of a conveyance path | route. FIG. 2 is a perspective view showing the first grinding wheel and the second grinding wheel in the first chamfering machine 12 and the second chamfering machine 14.

As shown in FIG. 1, while conveying the glass plate G, the first chamfering machine 12 uses the diamond wheel 12a for grinding provided on both sides of the conveyance path on the short side end surface of the rectangular glass plate G. Is used for grinding. As shown in FIG. 2, diamond wheel 12a in the direction of the rotation axis Z, and is configured in the first grinding wheel 12a ₁ and second 2-stage grinding wheel 12a _2.

The first grinding wheel 12a ₁ is a grinding wheel in which diamond abrasive grains are hardened with a metallic binder containing iron. First binding agent of the grinding wheel 12a ₁ are those hardness and rigidity higher than the second binding agent of the grinding wheel 12a ₂ are used. Here, the hardness is Shore hardness, and the rigidity is Young's modulus. If the binder of the first grinding wheel 12a ₁ is a metal, other metal binders such as cobalt and bronze may be used. Also, the higher the second hardness and rigidity than the binding agent of the grinding wheel 12a ₂ is a binder of the ceramic membrane may be used as the first binding agent of the grinding wheel 12a _1. For the first grinding wheel 12a ₁ , diamond abrasive grains having a particle size of about # 300 to # 400 defined by JIS R6001-1987 can be used, for example. In this embodiment, the first grinding wheel 12a ₁ uses diamond grains of granularity # 400. The abrasive grains are not limited to diamond but may be CBN (borazone). First granularity of the grinding wheel 12a ₁ may be the second grinding wheel 12a whether or rougher than equal the diamond abrasive particle size _2.

The second grinding wheel 12a ₂ is a grinding wheel in which diamond abrasive grains are hardened with a resin-based binder containing epoxy. Binding agent of the second grinding wheel 12a ₂ of the diamond abrasive grains as hardness and rigidity is lower than the first binding agent of the grinding wheel 12a ₁ is used. A low second binding agent of the grinding wheel 12a ₂ has hardness and synthetic than the first binding agent of the grinding wheel 12a _1, it may be used a binder of the ceramic electrolyte. As long as the binder of the second grinding wheel 12a ₂ is resin-based, for example, a polyimide-based material may be used. The second abrasive grinding wheel 12a ₂ is not limited to diamond, may be CBN. In this embodiment, the second grinding wheel 12a ₂ uses a diamond abrasive grain size of ♯400 defined by JIS R6001-1987.
The first abrasive grain size of the grinding wheel 12a ₁ is preferable for the second whether or coarser than equal abrasive grain of the grinding wheel 12a _2, it is performed efficiently grinding.

In the first grinding process, in the first chamfering machine 12, the glass plate G is conveyed in the conveying direction indicated by the arrow in FIG. 1, and the grinding groove W indicated by the dotted line in FIG. 2 of the _first grinding wheel 12a1. Thus, the end face of the glass plate G is ground. The first grinding wheel 12a ₁ grinds the end surface of the glass plate G by a predetermined grinding amount. Thereby, the end surface of the glass plate G retreats to the center side of the glass plate from the original end surface, and the cross-sectional shape of the end surface has a curvature corresponding to the cross-sectional shape of the grinding groove W of the _first grinding wheel 12a1. It is ground into a convex shape. Here, the grinding amount is the distance from the position of the original end face before grinding to the position of the apex of the convex end face after grinding which has been ground and retreated. That is, the amount of the end face of the glass plate G ground in a direction parallel to the main surface of the glass plate G. Grinding amount of the first glass sheet G by the grinding wheels 12a ₁ is, for example, in the range from 40μm to 60 [mu] m. It is preferable that the conveyance speed of the glass plate G in a 1st grinding process is 10 m / min or more from a viewpoint of ensuring productivity. In this embodiment, the conveyance speed of the glass plate G is 10 m / min.

  In the first grinding step, the glass plate G has a maximum height Rmax defined by JIS B 0601-1982 of at least 10 μm and 18 μm, more preferably 13 μm and 14 μm. The end face of G is ground. Moreover, the arithmetic average roughness Ra prescribed | regulated by JIS B 0601-1982 of the end surface of the glass plate G will be about 0.5 micrometer, for example.

After that, as shown in FIG. 2, the diamond wheel 12 a moves in the direction of the rotation axis Z so that the grinding groove W of the second grinding wheel 12 a ₂ corresponds to the position of the end face of the glass plate G. In the second grinding step, the glass plate G is conveyed in the direction opposite to the arrow in FIG. 1, and the end surface is ground by the grinding groove W of the _second grinding wheel 12a ₂ during this conveyance. Thereby, the cross-sectional shape of the end surface of the glass plate G is ground into a convex shape with a curvature corresponding to the cross-sectional shape of the grinding groove W of the _second grinding wheel 12a2.

The grinding amount of the glass plate G by the second grinding wheel 12a ₂ is in the range of 10 μm to 30 μm, for example. The conveyance speed of the glass plate G in the second grinding step is preferably 10 m / min or more, and more preferably 15 m / min or more from the viewpoint of ensuring productivity. In this embodiment, the conveyance speed of the glass plate G is 15 m / min. It is preferable that the conveyance speed of the glass plate G in a 2nd grinding process is larger than the conveyance speed of the glass plate G in a 1st grinding process.

  In the second grinding step, the end surface of the glass plate G is adjusted so that the maximum height Rmax defined by JIS B 0601-1982 of the end surface of the glass plate G is at least 4 μm and 8 μm, more preferably about 6 μm. Grind. Further, the arithmetic average roughness Ra of the end surface of the glass plate G is, for example, about 0.1 μm to 0.2 μm.

  In addition, about the rotation direction of the grinding wheel 12a, the rotation direction of the outer peripheral surface of the grinding wheel 12a in the point which contacts the glass plate G may be set so that it may become the same as the conveyance direction of the glass plate G, and vice versa. May be set in the direction. In the present embodiment, the rotation direction of the outer peripheral surface of the grinding wheel 12a at the point of contact with the glass plate G in the first grinding step is opposite to the conveying direction of the glass plate G, and the glass in the second grinding step. The grinding wheel 12a is rotated in one direction so as to be in the same direction as the conveying direction of the plate G.

In the polishing process, the end face of the glass G ground in the second grinding process is polished by the polishing wheels 12b provided on both sides of the conveyance path. As the polishing wheel 12b, for example, a resin-bonded polishing wheel having flexibility and elasticity as disclosed in Japanese Patent Laid-Open No. 2001-259978 can be used. In this case, the elastic modulus of the resin bonded polishing wheel is, for example, 50 to 10000 kg / cm ² or preferably 500 to 7000 kg / cm ² in terms of ensuring flexibility and elasticity. Further, the Shore D hardness of the resin bonded polishing wheel is preferably 10 to 95 or 40 to 80, for example, and the density of the resin bonded polishing wheel is, for example, 0.4 to 2.5 g / cm ^3. preferable. This application refers to JP 2001-259978 A.

The polishing wheel 12b, which is a resin-bonded polishing wheel, is obtained by hardening abrasive grains normally used for polishing materials such as SiC, Al ₂ O ₃ and CeO ₂ with a resin binder having flexibility and elasticity. As the grain size of the abrasive grains of the polishing wheel 12b, for example, about # 300 to # 500 defined by JIS R6001-1987 can be used. In the present embodiment, the particle size of the polishing wheel 12b is # 400. As the resin binder, for example, a polyurethane or polyimide binder can be used.

  It is preferable that the conveyance speed of the glass plate G in a grinding | polishing process is 15 m / min or more from a viewpoint of ensuring productivity. In this embodiment, the conveyance speed of the glass plate G is 20 m / min, for example. The rotation direction of the polishing wheel 12b may be set so that the rotation direction of the outer peripheral surface of the grinding wheel 12b at the point of contact with the glass plate G is the same as the conveyance direction of the glass plate G. The reverse direction may be set. In the present embodiment, the rotation direction of the polishing wheel 12b is set so that the rotation direction of the outer peripheral surface of the polishing wheel 12b at the point of contact with the glass plate G is opposite to the conveyance direction of the glass plate G. .

In the polishing step, the end surface of the glass plate G is polished so that the maximum height Rmax of the end surface of the glass plate G is less than 4 μm, preferably 3.5 μm or less. The average roughness Ra of the end surface of the glass plate G is, for example, about 0.03 μm to 0.06 μm.
In the present embodiment, grinding and polishing of the end face of the glass plate G are clearly distinguished. That is, the grinding is a process of forming the cross-sectional shape of the end face of the glass plate G into a desired shape by scraping the glass, and involves a grinding amount of at least several μm. Therefore, depending on grinding, it is not possible to obtain the above-mentioned surface quality of the end face of the sheet glass G that will be the final product.
On the other hand, the polishing is a process for improving the surface quality of the end face of the glass plate G by reducing or removing the fine unevenness by leveling the fine unevenness of the end face of the glass plate G. Therefore, there is almost no change in the cross-sectional shape of the end face of the glass plate G depending on the polishing, which is a process including a surface treatment called so-called mirror finish. That is, the polishing step polishes the end surface of the glass plate G while maintaining the shape of the end surface of the glass plate G without substantially changing the shape of the end surface of the glass plate G ground by the grinding step. .
In this embodiment, polishing is performed using the polishing wheel 12b. However, polishing may be performed using a known tape polishing technique, pad polishing technique, brush polishing technique, or magnetic fluid finishing technique instead of the polishing wheel 12b. it can.

  In this embodiment, the end face is ground and polished without moving the diamond wheel 12a and the polishing wheel 12b in the conveying direction of the glass plate G. However, while the glass plate G is stationary or the glass plate G is conveyed, The end face of the glass plate G may be ground and polished by moving the diamond wheel 12a and / or the polishing wheel 12b.

After polishing, the reversing machine 18 rotates the direction of the glass plate G by 90 degrees, and conveys the glass plate G to the second chamfering machine 14 along the conveyance path. The second chamfering machine 14 includes a diamond wheel 14 a similar to the diamond wheel 12 a of the first chamfering machine 12. As shown in FIG. 2, the diamond wheel 14 a is similar to the first grinding wheel 12 a ₁ and the second grinding wheel 12 a _{2 of} the first chamfering machine 12, and the first grinding wheel 14 a ₁ and the second grinding wheel 14 a _2. And.

In the second chamfering machine 14, the rectangular glass plate G with respect to the end face of the long side, the first grinding wheel 14a ₁ of the diamond wheel 14a provided on both sides of the conveyance path similar to the first chamfering machine 12 A first grinding step is performed. Then, the end face of the long sides of the rectangular glass plate G, a second grinding step similar to the first chamfering machine 12 is performed by the second grinding wheel 14a _2.

  Thereafter, in the polishing step, polishing of the end face of the glass plate G that has been ground using the polishing wheels 14b provided on both sides of the conveyance path is performed. The grinding wheel 14 b is configured in the same manner as the grinding wheel 12 b of the first chamfering machine 12. Thereafter, the glass plate G is conveyed to the corner cutting machine 16, and the corners of the glass plate G are ground and polished using the corner cutting diamond wheel 16a. Thereafter, the glass plate G is shipped as a product through a cleaning process and an inspection process.

In the present embodiment, the end face of the glass plate G is ground by grinding with the first grinding wheels 12a ₁ and 14a ₁ which are metal bond diamond wheels in which diamond abrasive grains are hardened with a metal binder, and the diamond abrasive grains are heated. This is performed in two stages: grinding with the second grinding wheels 12a ₂ and 14a ₂ which are resin bond diamond wheels hardened with a curable resin binder.

  Metal-bonded diamond wheels, that is, grinding wheels that use metal binders, can grind with an emphasis on the grinding quality depending on the particle size and binder specifications, and can perform high-speed grinding with an emphasis on the grinding processing capacity. Any grinding specification can be set. With wheel specifications that focus on grinding processing capacity, damage to the glass plate increases as the processing capacity to grind the glass plate increases, and the quality of the end surface of the glass plate, such as surface roughness and chipping, may be sacrificed. is there. Therefore, when it is going to maintain the quality of the end surface of a glass plate, the metal bond diamond wheel of the specification which attached importance to the grinding quality will be used. However, increasing the grinding speed using a wheel with an emphasis on grinding quality increases the frequency of abrasive clogging and clogging, resulting in insufficient grinding processing capacity and frequent occurrence of defects such as grinding burns and scratches. Risk that For this reason, it is difficult to maintain and improve productivity when using a metal bond diamond wheel with specifications that emphasize grinding quality. In addition, in order to improve the quality of the product by sufficiently reducing the unevenness of the end face of the glass plate G by polishing the unevenness of the end face of the glass plate G in a state ground with a grinding wheel using a metal binder, Since the polishing time becomes excessively long, productivity must be sacrificed.

  A resin-bonded diamond wheel, that is, a grinding wheel using a thermosetting resin binder, has a higher cushioning property and higher flexibility than a grinding wheel using a metal binder. Therefore, the damage given to the end surface of the glass plate G is suppressed as much as possible, and delicate grinding is possible. Therefore, the surface roughness of the end surface of the glass plate G becomes smaller than that of a grinding wheel using a metal binder.

  In this embodiment, emphasis is placed on the grinding force as grinding by a metal bond diamond wheel, and a necessary shape is formed in a short time on the end face of the glass plate by high speed grinding. After that, by grinding with a resin bond diamond wheel, the end face of the glass plate G is ground as fast as possible so as to achieve a predetermined surface roughness that can achieve the target surface roughness in the next process polishing. . Then, by subjecting the end surface of the glass plate, which is obtained by grinding according to the present embodiment, to a higher quality than conventional grinding, final polishing is performed so that the target surface roughness of the glass plate G is high quality. Can be obtained and can be processed in a short time. Furthermore, in this embodiment, the above-mentioned grinding can suppress the glass particles which generate | occur | produce with time from the end surface of the glass plate G, and can reduce the adhesion amount to the surface of a glass particle. This makes it possible to use wiring / electrode materials with low adhesion in TFT (Thin Film Transistor) panel displays for organic EL (Elector-Luminescence) and TFT panel displays for high-definition liquid crystals. For example, a low-resistance Cu-based electrode material can be used although the adhesion is lower than that of an Al-based electrode, Cr, or Mo electrode. In other words, by expanding the selection range of the electrode material, it is possible to solve the problem of RC delay (wiring delay) that tends to be a problem in a large panel display. Further, it is possible to provide a glass substrate that can solve the problem of RC delay that may occur in a small-sized panel display that will be further refined in the future.

  In the present embodiment, the maximum height Rmax is used as an index of surface roughness. In the grinding and polishing of the end face of the glass plate G, minute unevenness is formed on the end face of the glass plate G, but the recess is considered to be dominant over the protrusion. Therefore, by using the maximum height Rmax as an index of surface roughness, it is possible to prevent an extremely deep recess from being formed. Thereby, the amount of particles clogged in the recesses on the end face of the glass plate G can be reduced, the amount of particles adhering to the surface of the glass plate G can be reduced, and the quality of the glass plate G can be improved. Moreover, the strength of the glass plate can be improved by preventing an extremely deep recess from being formed on the end face of the glass plate G.

Moreover, the conveyance direction of the glass plate G in a 2nd grinding process is a reverse direction with the conveyance direction of the glass plate G in a 1st grinding process. Therefore, compared with the case where the glass plate G is conveyed in one direction, a conveyance line can be shortened and grinding apparatuses, such as the 1st chamfering machine 12 and the 2nd chamfering machine 14, can be made compact.
The first rotational direction of the grinding wheel 12a ₁ at the point where the first grinding wheel 12a ₁ comes in contact with the glass sheet G is the direction of the conveying direction opposite the glass sheet G. Thereby, the speed difference between the glass plate G and the first grinding wheel 12a ₁ is increased, and the end face shape can be processed more quickly.
The second rotational direction of the grinding wheel 12a ₂ at the point where the second grinding wheel 12a ₂ is in contact with the glass sheet G is in the same direction as the conveying direction of the glass sheet G. Thereby, while ensuring productivity, reduce the speed difference between the glass plate G and the second grinding wheel 12a _2, it is possible to process a higher quality end faces.
The thickness of the glass plate used for this embodiment is 0.25 mm-0.7 mm, Preferably it is 0.3-0.5 mm.

As described above, according to the glass plate manufacturing method of the present embodiment, the unevenness of the end face of the glass plate G can be sufficiently reduced and the quality of the product can be improved while ensuring the productivity.
In addition, the end surface processing line 10 of the glass plate G is not limited to said structure. For example, the first chamfering machine 12 may have the functions of the corner cutting machine 16 and the reversing machine 18, and the corner cutting machine 16 and the reversing machine 18 may be omitted. In this case, the following (1) to (5) can be performed in one chamfering machine.
(1) After conveying the glass plate G in the conveyance direction and performing a corner cut, the first grinding process of the long side of the glass plate G is performed, and further the corner cut is performed.
(2) The glass plate G is conveyed in the direction opposite to the conveying direction, and the second grinding step for the long side of the glass plate G is performed.
(3) The glass plate G is rotated by 90 °.
(4) After transporting the glass plate G in the transport direction and performing a corner cut, the first grinding step of the short side of the glass plate is performed, and further the corner cut is performed.
(5) The glass plate G is conveyed in the direction opposite to the conveying direction, and the second grinding step of the short side of the glass plate G is performed.
In addition, the corner cut of the process of (4) is performed only when the dimension to cut is large. For the corner cut, the first grinding wheel 12a ₁ used in the first grinding process can be used. The chamfering machine that performs grinding and the polishing machine that performs polishing may be separate devices.

(Examples and comparative examples)
Hereinafter, the Example based on said embodiment and the comparative example different from this embodiment are demonstrated.

In the examples, as described above, the first grinding step, the second grinding step, and the polishing step were performed on the end face of the glass plate G having a thickness of 0.5 mm. In the comparative example compared with the examples, the above polishing process was performed after grinding using only the diamond wheel using the same metal binder as the _first grinding wheel 12a1 in the above embodiment. .

  The outer diameter of the diamond wheel 12a used in the examples and comparative examples was 250 mm, and the outer diameter of the polishing wheel 14b was 150 mm. Further, the rotational speed of the grinding wheel 12a in the first grinding process is 2298 rpm, the rotational speed of the grinding wheel 12a in the second grinding process is 3000 rpm, and the rotational speed of the polishing wheel 14b in the polishing process is 2500 rpm. did. The diamond abrasive grain size of the diamond wheel used in the first grinding step was # 400 in the example and # 500 in the comparative example, and an iron-based binder was used as the metal binder. The diamond wheel used in the second grinding step had a diamond abrasive grain size of # 400, and an epoxy binder was used as the resin binder. The abrasive used in the polishing step was SiC, the particle size was # 400, and a polyurethane binder was used as the resin binder having flexibility and elasticity. Under this condition, the end face of the glass plate was ground and polished. In the examples, the conveyance speed of the glass plate was 10 m / min in the first grinding process, 15 m / min in the second grinding process, and 20 m / min in the polishing process. In the comparative example, the conveying speed of the glass plate was 7 m / min in the grinding process, and 20 m / min in the polishing process in the polishing process.

At this time, the grinding amount of the end surface of the glass plate was 40 μm to 60 μm in the first grinding process of the example, and 90 μm to 110 μm in the grinding process of the comparative example. Then, in the 2nd grinding process performed in the Example, the grinding amount of the end surface of a glass plate was 10 micrometers-30 micrometers.
In the examples and comparative examples, thereafter, polishing was performed using a polishing wheel similar to the polishing wheel 14b in the above embodiment.

  That is, in the said Example, after grinding the end surface of a glass plate in two steps, grinding with a metal bond diamond wheel and grinding with a resin bond diamond wheel, the end surface of the glass plate after grinding was grind | polished. On the other hand, in the comparative example, after grinding the end face of the plate glass only by grinding with a metal bond diamond wheel, the end face of the glass plate after grinding is polished. .

  In the comparative example, a chip was seen in the Side View photograph in which the end face was taken from the direction perpendicular to the front and back surfaces (main surface) of the glass plate. Further, in the Front View photograph in which the end face was photographed at a magnification of 5 times and 20 times from the direction parallel to the front and back surfaces of the glass plate, a relatively large recess was formed.

  In the examples, no chipping was observed in the side view photograph taken from the direction perpendicular to the front and back surfaces of the glass plate. Further, in Front View in which the end face was photographed at a magnification of 5 times and 20 times from the direction parallel to the front and back surfaces of the glass plate, the concave portion was shallower and smaller than the comparative example, and the smoothness of the end face was improved. .

  The amount of particles on the end face of the glass plate subjected to grinding and polishing based on the above example and the amount of particle on the end face of the glass plate subjected to grinding and polishing based on the above comparative example were measured and compared. The amount of particles was measured by sucking the end surface of the glass plate using a particle counter having a suction device. Specifically, by sliding against the end face of the glass plate while pressing a soft scraping member softer than the glass plate, the end face of the glass plate is rubbed to scrub particles on the end face, and the scraped particles The particles on the end face of the glass plate were measured by sucking and counting the number with a particle counter. Such a measuring method is described in detail in, for example, Japanese Patent Application Laid-Open No. 2010-230646. In the sample of the above example, the amount of particles was reduced by about 30% compared to the sample of the comparative example.

  The arithmetic average roughness Ra specified in JIS B 0601-1982 of the end face of the glass plate subjected to grinding and polishing based on the above examples, and the arithmetic average of the end face of the glass plate subjected to grinding and polishing based on the above comparative examples The roughness Ra was compared. In the sample of the above example, Ra was around 0.05 μm, and Ra was reduced by about 37% compared to the sample of the above comparative example. In addition, arithmetic mean roughness Ra is the result measured using the Tokyo Seimitsu Co., Ltd. product, a roughness measuring device, and Surfcom (brand name). Note that the maximum height Rmax is also measured by the same method.

  The bending strength of the glass plate which performed grinding and grinding | polishing based on the said Example and the glass plate which performed grinding and grinding | polishing based on the said comparative example was compared. In the sample of the glass plate of the Example, it was confirmed that the 0.1% breakage rate was improved by about 5 to 10 Mpa and the mechanical strength of the glass plate was improved as compared with the sample of the glass plate of the comparative example. The bending strength of the glass plate was measured by a 4-point bending test.

  As mentioned above, although the manufacturing method of the glass plate of this invention was demonstrated in detail, this invention is not limited to the said embodiment, You may make a various improvement and change in the range which does not deviate from the main point of this invention.

  As mentioned above, although the manufacturing method and glass plate of the glass plate of this invention were demonstrated in detail, this invention is not limited to the said embodiment, Even if it is variously improved and changed in the range which does not deviate from the main point of this invention. Of course it is good.

10 end surface processing line 12 first chamfering machine 12a second chamfering machine 12a _1, 14a ₁ first grinding wheel 12a _2, 14a ₂ second grinding wheel 12b, 14b grinding wheel 14 a second chamfering machine 14a diamond wheel 16 Corner Cutting machine 16a Diamond wheel 18 for corner cutting 18 reversing machine

One embodiment of the present invention is a method for manufacturing a glass plate. The manufacturing method is
Grinding the end face of the glass plate;
Polishing the end face of the glass plate after grinding.
The step of grinding the end face of the glass plate,
A first grinding step of grinding an end face of the glass plate using a first grinding wheel in which abrasive grains are hardened with a first binder;
After the first grinding step, the grinding the end face of the glass plate using the second grinding wheel hardness and rigidity than the abrasive grains first binding agent is encased in a lower second binding agent 2 grinding processes.
Another embodiment of the present invention is a method for producing a glass plate. The manufacturing method is
Grinding the end face of the glass plate;
Polishing the end face of the glass plate after grinding.
The step of grinding the end face of the glass plate,
A first grinding step of grinding an end face of the glass plate using a first grinding wheel in which abrasive grains are hardened with a first binder;
After the first grinding step, the end face of the glass plate is ground using a second grinding wheel in which abrasive grains are hardened with a second binder having hardness and rigidity lower than those of the first binder. 2 grinding processes,
Performing the first grinding step, the second grinding step, and the step of polishing the glass plate while conveying the glass plate;
The conveyance direction of the glass plate in the second grinding step is opposite to the conveyance direction of the glass plate in the first grinding step.

Furthermore, another one aspect | mode of this invention is a manufacturing method of the glass substrate for displays. The manufacturing method is
Grinding the end face of the glass substrate and grinding the end face into a convex shape with a curvature;
Polishing without substantially changing the shape of the end face of the glass substrate after grinding;
including.
The step of grinding the end surface of the glass substrate,
A first polishing wheel in which abrasive grains are hardened with a first binder is used to grind the end surface of the glass substrate so that the maximum height Rmax defined in JIS B0601-1982 is 10 μm or more and 18 μm or less. Grinding process of
After the first grinding step, using a second grinding wheel in which abrasive grains are hardened with a second binder having lower hardness and rigidity than the first binder, the amount of grinding by the second grinding wheel There a second grinding step of grinding so that 10μm or more and 30μm or less,
Have

Claims (18)

A method of manufacturing a glass plate,
Grinding the end face of the glass plate;
Polishing the end face of the glass plate after grinding, and
The step of grinding the end face of the glass plate,
A first grinding step of grinding an end face of the glass plate using a first grinding wheel in which abrasive grains are hardened with a first binder;
After the first grinding step, the end face of the glass plate is ground using a second grinding wheel in which abrasive grains are hardened with a second binder having lower hardness and rigidity than the first binder. 2 grinding processes;
The manufacturing method of the glass plate which has this. The first binder is a metal binder and the second binder is a resin binder;
The manufacturing method of the glass plate of Claim 1. In the first grinding step, the end face of the glass plate is ground so that the maximum height Rmax defined in JIS B 0601-1982 is 10 μm or more and 18 μm or less,
In the second grinding step, the end face of the glass plate is ground so that the maximum height Rmax is 4 μm or more and 8 μm or less.
The manufacturing method of the glass plate of Claim 1 or 2. In the step of polishing the glass plate, the end surface of the glass plate is polished so that the maximum height Rmax is less than 4 μm.
The manufacturing method of the glass plate of any one of Claims 1-3. The grinding amount of the end face of the glass plate in the first grinding step is 40 μm or more and 60 μm or less,
The grinding amount of the end face of the glass plate in the second grinding step is 10 μm or more and 30 μm or less.
The manufacturing method of the glass plate of any one of Claims 1-4.   The said polishing process is a manufacturing method of the glass plate of Claim 5 which grind | polishes, without changing the shape of the end surface of the said glass substrate ground by the said grinding process substantially.   The glass plate manufacturing method according to claim 5 or 6, wherein the polishing step mirror-processes the end surface ground by the grinding step. Performing the first grinding step, the second grinding step, and the step of polishing the glass plate while conveying the glass plate;
The conveyance direction of the glass plate in the second grinding step is opposite to the conveyance direction of the glass plate in the first grinding step.
The manufacturing method of the glass plate of any one of Claims 1-7. The rotation direction of the first grinding wheel at the point where the first grinding wheel contacts the glass plate is a direction opposite to the conveying direction of the glass plate,
The rotation direction of the second grinding wheel at the point where the second grinding wheel contacts the glass plate is the same direction as the conveying direction of the glass plate.
The manufacturing method of the glass plate of Claim 8. The conveyance speed of the glass plate is 10 m / min or more.
The manufacturing method of the glass plate of Claim 8 or 9. The conveyance speed of the glass plate in the second grinding step is 15 m / min or more.
The manufacturing method of the glass plate of Claim 10. The abrasive grains of the first grinding wheel and the second grinding wheel are diamond abrasive grains,
The grain size of the abrasive grains of the first grinding wheel is equal to or coarser than the grain size of the abrasive grains of the second grinding wheel;
The manufacturing method of the glass plate of any one of Claims 1-11. In the step of polishing the glass plate, binders grinding wheel for polishing the end face of the glass sheet is foamed elastic material, abrasive SiC, Al ₂ O _3, or one or more materials selected from CeO ₂ Formed by,
The manufacturing method of the glass plate of any one of Claims 1-12. The glass plate is used for a substrate of a display device of a flat panel display, or a cover glass of a display screen of an electronic device,
The glass plate is formed by a downdraw method or a float method,
The manufacturing method of the glass plate of any one of Claims 1-13. It is the glass plate manufactured by the manufacturing method of the glass plate of any one of Claims 1-14,
The cross-sectional shape of the end face of the glass plate is formed into a convex shape with a curvature,
The maximum height Rmax specified by JIS B 0601-1982 of the end face of the glass plate is less than 4 μm, and the arithmetic average roughness Ra specified by JIS B 0601-1982 is 0.06 μm or less.
Glass plate. A method for producing a glass substrate for a display, comprising:
Grinding the end face of the glass substrate and grinding the end face into a convex shape with a curvature;
Polishing without substantially changing the shape of the end face of the glass substrate after grinding;
Including
The step of grinding the end surface of the glass substrate,
A first polishing wheel in which abrasive grains are hardened with a first binder is used to grind the end surface of the glass substrate so that the maximum height Rmax defined in JIS B0601-1982 is 10 μm or more and 18 μm or less. Grinding process of
After the first grinding step, using a second grinding wheel in which abrasive grains are hardened with a second binder having lower hardness and rigidity than the first binder, the amount of grinding by the second grinding wheel A second grinding step in which the value is equal to or greater than the value measured as Rmax;
A method for producing a glass substrate for a display. The grinding amount of the end face of the glass plate in the second grinding step is 10 μm or more and 30 μm or less.
The manufacturing method of the glass substrate for displays of Claim 16. The glass substrate has a thickness of 0.25 mm to 0.7 mm.
The manufacturing method of the glass substrate for displays of Claim 16 or 17.

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