JPS649256B2 - - Google Patents
Info
- Publication number
- JPS649256B2 JPS649256B2 JP61219095A JP21909586A JPS649256B2 JP S649256 B2 JPS649256 B2 JP S649256B2 JP 61219095 A JP61219095 A JP 61219095A JP 21909586 A JP21909586 A JP 21909586A JP S649256 B2 JPS649256 B2 JP S649256B2
- Authority
- JP
- Japan
- Prior art keywords
- glass
- gold
- photochromic
- palladium
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011521 glass Substances 0.000 claims description 95
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 50
- 239000010931 gold Substances 0.000 claims description 27
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 26
- 229910052737 gold Inorganic materials 0.000 claims description 26
- 229910052763 palladium Inorganic materials 0.000 claims description 25
- 229910052709 silver Inorganic materials 0.000 claims description 17
- 239000004332 silver Substances 0.000 claims description 17
- 239000013078 crystal Substances 0.000 claims description 12
- -1 silver halide Chemical class 0.000 claims description 12
- 239000003086 colorant Substances 0.000 claims description 9
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 claims description 3
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 3
- 229910021612 Silver iodide Inorganic materials 0.000 claims description 3
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims description 3
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 claims description 3
- 229940045105 silver iodide Drugs 0.000 claims description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 3
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 3
- 229910052689 Holmium Inorganic materials 0.000 claims 1
- 229910017493 Nd 2 O 3 Inorganic materials 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 29
- 238000002834 transmittance Methods 0.000 description 20
- 238000010438 heat treatment Methods 0.000 description 17
- 238000007792 addition Methods 0.000 description 10
- 239000000460 chlorine Substances 0.000 description 9
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 7
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 7
- 229910018068 Li 2 O Inorganic materials 0.000 description 7
- 229910004298 SiO 2 Inorganic materials 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005562 fading Methods 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 239000011630 iodine Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 3
- 238000010583 slow cooling Methods 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 239000006121 base glass Substances 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 239000005368 silicate glass Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- NDDLLTAIKYHPOD-ISLYRVAYSA-N (2e)-6-chloro-2-(6-chloro-4-methyl-3-oxo-1-benzothiophen-2-ylidene)-4-methyl-1-benzothiophen-3-one Chemical compound S/1C2=CC(Cl)=CC(C)=C2C(=O)C\1=C1/SC(C=C(Cl)C=C2C)=C2C1=O NDDLLTAIKYHPOD-ISLYRVAYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 101150003085 Pdcl gene Proteins 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/04—Compositions for glass with special properties for photosensitive glass
- C03C4/06—Compositions for glass with special properties for photosensitive glass for phototropic or photochromic glass
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/113,797 US4251278A (en) | 1980-01-21 | 1980-01-21 | Photochromic glasses which darken to a brown hue |
| US113797 | 1980-01-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6278127A JPS6278127A (ja) | 1987-04-10 |
| JPS649256B2 true JPS649256B2 (enExample) | 1989-02-16 |
Family
ID=22351588
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55125886A Expired JPS6031781B2 (ja) | 1980-01-21 | 1980-09-10 | フオトクロミツクガラス |
| JP61219095A Granted JPS6278127A (ja) | 1980-01-21 | 1986-09-17 | フオトクロミツクガラス |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55125886A Expired JPS6031781B2 (ja) | 1980-01-21 | 1980-09-10 | フオトクロミツクガラス |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4251278A (enExample) |
| JP (2) | JPS6031781B2 (enExample) |
| BR (1) | BR8006459A (enExample) |
| DE (1) | DE3036103C2 (enExample) |
| ES (1) | ES494735A0 (enExample) |
| FR (1) | FR2474019A1 (enExample) |
| GB (1) | GB2067548B (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3020357A1 (de) * | 1980-05-29 | 1981-12-03 | Jenaer Glaswerk Schott & Gen., 6500 Mainz | Verfahren zur verstaerkung des phototropen effekts in phototropen glaesern |
| DE3117000C2 (de) * | 1981-04-29 | 1986-05-28 | Schott Glaswerke, 6500 Mainz | Phototropes Glas mit einem Brechungsindex ≥ 1,59, einer Abbezahl ≥ 40 und einer Dichte ≦ 3,2 g/cm↑3↑ |
| DE3206958C2 (de) * | 1982-02-26 | 1986-09-18 | Schott Glaswerke, 6500 Mainz | Phototropes Glas mit einem Brechungsindex ≥ 1,59, einer Abbezahl ≥ 44 und einer Dichte ≦ 3,0 g/cm↑3↑ |
| DE3220367A1 (de) * | 1982-05-29 | 1983-12-01 | Schott Glaswerke, 6500 Mainz | Phototropes glas mit brauntoenung im belichteten zustand |
| JPS61132537A (ja) * | 1984-11-30 | 1986-06-20 | Hoya Corp | 眼鏡用レンズ及びその製造方法 |
| FR2584706B1 (fr) * | 1985-07-11 | 1991-08-16 | Corning Glass Works | Verre photochromique a eclaircissement rapide |
| FR2601354B1 (fr) * | 1986-07-11 | 1992-05-07 | Corning Glass Works | Verres legerement teintes a transmission variable. |
| DE3772876D1 (de) * | 1986-07-11 | 1991-10-17 | Corning Glass Works | Leicht gefaerbte glaeser mit einer veraenderlichen durchlaessigkeit. |
| US5244845A (en) * | 1992-10-02 | 1993-09-14 | Corning Incorporated | Multipurpose photochromic brown glasses |
| FR2701020B1 (fr) * | 1993-02-01 | 1995-04-21 | Corning Inc | Verres photochromiques qui s'assombrissent en prenant une teinte rose. |
| DE4408190C1 (de) * | 1994-03-11 | 1995-08-03 | Deutsche Spezialglas Ag | Hochbrechendes phototropes Glas |
| US5482901A (en) * | 1994-07-15 | 1996-01-09 | Corning Incorporated | Amber photochromic glasses |
| US5534041A (en) * | 1994-11-07 | 1996-07-09 | Corning Incorporated | Method of making laser eyewear protection |
| US5482902A (en) * | 1994-12-21 | 1996-01-09 | Corning Incorporated | Brown-photochromic glasses |
| DE19520016C2 (de) * | 1995-05-26 | 1997-04-30 | Ivoclar Ag | Photochrome Dentalmaterialien |
| JP3363818B2 (ja) | 1998-03-31 | 2003-01-08 | セイコーインスツルメンツ株式会社 | 可逆的変色性組成物及びこれを用いた時計用外装部品 |
| US6197711B1 (en) * | 1998-09-09 | 2001-03-06 | Corning S.A. | Protective filter lens |
| US7468148B2 (en) * | 2005-10-24 | 2008-12-23 | Corning Incorporated | Visible polarizing glass and process |
| CN100383070C (zh) * | 2006-02-24 | 2008-04-23 | 浙江大学 | 一种应用于内部激光着色并形成三维黑色图案的玻璃 |
| JP2008280393A (ja) * | 2007-05-09 | 2008-11-20 | Akiyoshi Sugimoto | フォトクロミック材料の製造方法 |
| US9663393B2 (en) | 2015-09-01 | 2017-05-30 | Owens-Brockway Glass Container Inc. | Process and apparatus for coloring glass containers |
| US10393934B2 (en) | 2015-09-11 | 2019-08-27 | Corning Incorporated | Multi-pane window with a low emissivity layer and a photochromic glass |
| US10618839B2 (en) | 2016-11-30 | 2020-04-14 | Corning Incorporated | Low emissivity coatings with increased ultraviolet transmissivity |
| EP3556735A1 (en) * | 2018-04-20 | 2019-10-23 | Barberini GmbH | Contrast enhancing glass for sunglass lenses |
| KR20240023516A (ko) | 2021-06-18 | 2024-02-22 | 코닝 인코포레이티드 | 향상된 기계적 내구성을 갖는 착색 유리 물품 |
| US12454479B2 (en) | 2021-06-18 | 2025-10-28 | Corning Incorporated | Gold containing silicate glass |
| US12054422B2 (en) | 2021-06-18 | 2024-08-06 | Corning Incorporated | Colored glass articles having improved mechanical durability |
| US12378152B2 (en) | 2021-06-18 | 2025-08-05 | Corning Incorporated | Colored glass articles having improved mechanical durability |
| CN113567374B (zh) * | 2021-07-26 | 2023-10-03 | 中国建材国际工程集团有限公司 | 计算光致变色玻璃太阳能得热系数的方法 |
| US12240782B2 (en) | 2022-05-31 | 2025-03-04 | Corning Incorporated | Ion exchangeable yellow glass articles |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1771063B1 (de) * | 1968-03-29 | 1971-04-01 | Jenaer Glaswerk Schott & Gen | Phototropes Glas |
| FR2085970A1 (en) * | 1970-04-10 | 1971-12-31 | Jenaer Glaswerk Schott & Gen | Photochromatic colour glass with borosili-ca |
| US3902909A (en) * | 1970-12-10 | 1975-09-02 | Jenaer Glaswerk Schott & Gen | Phototropic material and a method for its production |
| US4043781A (en) * | 1974-11-04 | 1977-08-23 | Corning Glass Works | Method for making a brown photochromic glass |
| US4018965A (en) * | 1975-04-14 | 1977-04-19 | Corning Glass Works | Photochromic sheet glass compositions and articles |
| FR2289458A1 (fr) * | 1975-11-03 | 1976-05-28 | Corning Glass Works | Procede de fabrication de verre photochromique |
| US4072490A (en) * | 1976-11-08 | 1978-02-07 | Corning Glass Works | Apparatus and process for producing a gradient photochromic ophthalmic lens |
| US4134747A (en) * | 1977-03-16 | 1979-01-16 | Corning Glass Works | Method of forming transparent and opaque portions in a reducing atmosphere glass |
| FR2419916B1 (fr) * | 1978-03-17 | 1986-04-18 | Corning Glass Works | Nouveaux verres photochromiques |
-
1980
- 1980-01-21 US US06/113,797 patent/US4251278A/en not_active Expired - Lifetime
- 1980-09-01 GB GB8028180A patent/GB2067548B/en not_active Expired
- 1980-09-03 ES ES494735A patent/ES494735A0/es active Granted
- 1980-09-10 JP JP55125886A patent/JPS6031781B2/ja not_active Expired
- 1980-09-25 DE DE3036103A patent/DE3036103C2/de not_active Expired
- 1980-10-06 FR FR8021321A patent/FR2474019A1/fr active Granted
- 1980-10-08 BR BR8006459A patent/BR8006459A/pt not_active IP Right Cessation
-
1986
- 1986-09-17 JP JP61219095A patent/JPS6278127A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| BR8006459A (pt) | 1981-07-28 |
| US4251278A (en) | 1981-02-17 |
| FR2474019A1 (fr) | 1981-07-24 |
| GB2067548A (en) | 1981-07-30 |
| JPS6278127A (ja) | 1987-04-10 |
| JPS56104750A (en) | 1981-08-20 |
| GB2067548B (en) | 1983-05-25 |
| ES8301183A1 (es) | 1982-12-01 |
| ES494735A0 (es) | 1982-12-01 |
| FR2474019B1 (enExample) | 1984-12-28 |
| DE3036103C2 (de) | 1983-04-28 |
| DE3036103A1 (de) | 1981-07-23 |
| JPS6031781B2 (ja) | 1985-07-24 |
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