JPS642587B2 - - Google Patents
Info
- Publication number
- JPS642587B2 JPS642587B2 JP53000050A JP5078A JPS642587B2 JP S642587 B2 JPS642587 B2 JP S642587B2 JP 53000050 A JP53000050 A JP 53000050A JP 5078 A JP5078 A JP 5078A JP S642587 B2 JPS642587 B2 JP S642587B2
- Authority
- JP
- Japan
- Prior art keywords
- cyclohexene
- alkylperoxycarbonyl
- hexyl
- pentyl
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 85
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims description 76
- -1 1,1,3,3-tetramethylbutyl Chemical group 0.000 claims description 42
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 31
- 238000006116 polymerization reaction Methods 0.000 claims description 26
- 150000002148 esters Chemical class 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 19
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 17
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 14
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 13
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 8
- 239000012933 diacyl peroxide Substances 0.000 claims description 8
- 229920001971 elastomer Polymers 0.000 claims description 8
- 239000000806 elastomer Substances 0.000 claims description 6
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 6
- 229920006305 unsaturated polyester Polymers 0.000 claims description 6
- 125000002252 acyl group Chemical group 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 125000005725 cyclohexenylene group Chemical group 0.000 claims description 4
- 125000004956 cyclohexylene group Chemical group 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 239000005062 Polybutadiene Substances 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 2
- UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 claims 4
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000002253 acid Substances 0.000 description 37
- 239000000047 product Substances 0.000 description 28
- 239000000243 solution Substances 0.000 description 28
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 24
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 24
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
- 229920000642 polymer Polymers 0.000 description 19
- 239000004793 Polystyrene Substances 0.000 description 17
- 238000001723 curing Methods 0.000 description 17
- 229920002223 polystyrene Polymers 0.000 description 17
- 239000003999 initiator Substances 0.000 description 14
- 238000000465 moulding Methods 0.000 description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 13
- 150000007513 acids Chemical class 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 13
- 229920005989 resin Polymers 0.000 description 12
- 239000011347 resin Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000009826 distribution Methods 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000010410 layer Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- ZBBVVLVKOKFDFJ-UHFFFAOYSA-N 8-(7-hexyl-1,3-dioxo-3a,4,7,7a-tetrahydro-2-benzofuran-4-yl)octanoyl chloride Chemical compound CCCCCCC1C=CC(CCCCCCCC(Cl)=O)C2C(=O)OC(=O)C12 ZBBVVLVKOKFDFJ-UHFFFAOYSA-N 0.000 description 8
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 8
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 7
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 7
- 239000012263 liquid product Substances 0.000 description 7
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 7
- 239000004926 polymethyl methacrylate Substances 0.000 description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 235000020778 linoleic acid Nutrition 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 150000002978 peroxides Chemical class 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tertâbutyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 150000001805 chlorine compounds Chemical class 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- MKQBLYMEKNJFOX-UHFFFAOYSA-N 3-(8-chloro-8-oxooctyl)-6-hexylcyclohex-4-ene-1,2-dicarbonyl chloride Chemical compound CCCCCCC1C=CC(CCCCCCCC(Cl)=O)C(C(Cl)=O)C1C(Cl)=O MKQBLYMEKNJFOX-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 238000005698 Diels-Alder reaction Methods 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 239000012024 dehydrating agentsâ Substances 0.000 description 4
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 4
- 239000001530 fumaric acid Substances 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 4
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 3
- XRXANEMIFVRKLN-UHFFFAOYSA-N 2-hydroperoxy-2-methylbutane Chemical compound CCC(C)(C)OO XRXANEMIFVRKLN-UHFFFAOYSA-N 0.000 description 3
- MVNKYWIYFHYPRE-UHFFFAOYSA-N 5-(8-chloro-8-oxooctyl)-2-hexylcyclohexane-1-carbonyl chloride Chemical compound CCCCCCC1CCC(CCCCCCCC(Cl)=O)CC1C(Cl)=O MVNKYWIYFHYPRE-UHFFFAOYSA-N 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 3
- YVHZHYMKFSGFAA-UHFFFAOYSA-N ditert-butyl 3-(8-tert-butylperoxy-8-oxooctyl)-6-hexylcyclohex-4-ene-1,2-dicarboperoxoate Chemical compound CCCCCCC1C=CC(CCCCCCCC(=O)OOC(C)(C)C)C(C(=O)OOC(C)(C)C)C1C(=O)OOC(C)(C)C YVHZHYMKFSGFAA-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 150000002976 peresters Chemical class 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 229920006250 telechelic polymer Polymers 0.000 description 3
- CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 description 2
- JMUKALCRCFJQTI-UHFFFAOYSA-N 2-(7-carboxyheptyl)-5-hexylcyclohex-3-ene-1-carboxylic acid Chemical compound CCCCCCC1CC(C(O)=O)C(CCCCCCCC(O)=O)C=C1 JMUKALCRCFJQTI-UHFFFAOYSA-N 0.000 description 2
- RMHNLLYQAWIDQE-UHFFFAOYSA-N 2-(8-chloro-8-oxooctyl)-5-hexylcyclohex-3-ene-1-carbonyl chloride Chemical compound CCCCCCC1CC(C(Cl)=O)C(CCCCCCCC(Cl)=O)C=C1 RMHNLLYQAWIDQE-UHFFFAOYSA-N 0.000 description 2
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 2
- PNBNQMAKOFABBM-UHFFFAOYSA-N 2-methylbutan-2-yl 5-hexyl-2-[8-(2-methylbutan-2-ylperoxy)-8-oxooctyl]cyclohexane-1-carboperoxoate Chemical compound CCCCCCC1CCC(CCCCCCCC(=O)OOC(C)(C)CC)C(C(=O)OOC(C)(C)CC)C1 PNBNQMAKOFABBM-UHFFFAOYSA-N 0.000 description 2
- WPAJONGYCAHYII-UHFFFAOYSA-N 2-octylbutanedioyl dichloride Chemical compound CCCCCCCCC(C(Cl)=O)CC(Cl)=O WPAJONGYCAHYII-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- RYKIXDBAIYMFDV-UHFFFAOYSA-N 5-(7-carboxyheptyl)-2-hexylcyclohex-3-ene-1-carboxylic acid Chemical compound CCCCCCC1C=CC(CCCCCCCC(O)=O)CC1C(O)=O RYKIXDBAIYMFDV-UHFFFAOYSA-N 0.000 description 2
- OOOUMHNGIRRJRR-UHFFFAOYSA-N 6-tert-butylperoxycarbonyl-2-(8-tert-butylperoxy-8-oxooctyl)-5-hexylcyclohex-3-ene-1-carboxylic acid Chemical compound CCCCCCC1C=CC(CCCCCCCC(=O)OOC(C)(C)C)C(C(O)=O)C1C(=O)OOC(C)(C)C OOOUMHNGIRRJRR-UHFFFAOYSA-N 0.000 description 2
- UHAZWRKCUCUKKG-UHFFFAOYSA-N 6-tert-butylperoxycarbonyl-2-(9-tert-butylperoxy-9-oxononyl)-5-pentylcyclohex-3-ene-1-carboxylic acid Chemical compound CCCCCC1C=CC(CCCCCCCCC(=O)OOC(C)(C)C)C(C(O)=O)C1C(=O)OOC(C)(C)C UHAZWRKCUCUKKG-UHFFFAOYSA-N 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000004641 Diallyl-phthalate Substances 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical compound CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 230000002902 bimodal effect Effects 0.000 description 2
- PTDAVEVZLNOKTA-UHFFFAOYSA-N bis(2-methylbutan-2-yl) 3-hexyl-6-[8-(2-methylbutan-2-ylperoxy)-8-oxooctyl]cyclohex-4-ene-1,2-dicarboperoxoate Chemical compound CCCCCCC1C=CC(CCCCCCCC(=O)OOC(C)(C)CC)C(C(=O)OOC(C)(C)CC)C1C(=O)OOC(C)(C)CC PTDAVEVZLNOKTA-UHFFFAOYSA-N 0.000 description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
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- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
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- 238000005502 peroxidation Methods 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
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- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
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- 229920003023 plastic Polymers 0.000 description 1
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- 229920001225 polyester resin Polymers 0.000 description 1
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- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
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- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- AZIQALWHRUQPHV-UHFFFAOYSA-N prop-2-eneperoxoic acid Chemical compound OOC(=O)C=C AZIQALWHRUQPHV-UHFFFAOYSA-N 0.000 description 1
- OVLOGGZZKMDRPQ-UHFFFAOYSA-N prop-2-enoyl 2-hexyl-5-(8-oxo-8-prop-2-enoylperoxyoctyl)cyclohex-3-ene-1-carboperoxoate Chemical compound CCCCCCC1C=CC(CCCCCCCC(=O)OOC(=O)C=C)CC1C(=O)OOC(=O)C=C OVLOGGZZKMDRPQ-UHFFFAOYSA-N 0.000 description 1
- XJNSVKFVZKFUTC-UHFFFAOYSA-N propan-2-yloxycarbonyl 2-hexyl-1-methyl-5-(8-oxo-8-propan-2-yloxycarbonylperoxyoctyl)cyclohex-3-ene-1-carboperoxoate Chemical compound CCCCCCC1C=CC(CCCCCCCC(=O)OOC(=O)OC(C)C)CC1(C)C(=O)OOC(=O)OC(C)C XJNSVKFVZKFUTC-UHFFFAOYSA-N 0.000 description 1
- ABLCIUARRXJFEA-UHFFFAOYSA-N propan-2-yloxycarbonyl 2-hexyl-5-(8-oxo-8-propan-2-yloxycarbonylperoxyoctyl)cyclohex-3-ene-1-carboperoxoate Chemical compound CCCCCCC1C=CC(CCCCCCCC(=O)OOC(=O)OC(C)C)CC1C(=O)OOC(=O)OC(C)C ABLCIUARRXJFEA-UHFFFAOYSA-N 0.000 description 1
- PFHODOZHPBIVAI-UHFFFAOYSA-N propan-2-yloxycarbonyl 2-hexyl-5-(8-oxo-8-propan-2-yloxycarbonylperoxyoctyl)cyclohexane-1-carboperoxoate Chemical compound CCCCCCC1CCC(CCCCCCCC(=O)OOC(=O)OC(C)C)CC1C(=O)OOC(=O)OC(C)C PFHODOZHPBIVAI-UHFFFAOYSA-N 0.000 description 1
- FCLARAJPODGLIH-UHFFFAOYSA-N propan-2-yloxycarbonyl 5-(8-acetylperoxy-8-oxooctyl)-2-hexylcyclohex-3-ene-1-carboperoxoate Chemical compound CCCCCCC1C=CC(CCCCCCCC(=O)OOC(C)=O)CC1C(=O)OOC(=O)OC(C)C FCLARAJPODGLIH-UHFFFAOYSA-N 0.000 description 1
- LJLVUSFANHLCMN-UHFFFAOYSA-N propan-2-yloxycarbonyl 5-(9-oxo-9-propan-2-yloxycarbonylperoxynonyl)-2-pentylcyclohex-3-ene-1-carboperoxoate Chemical compound CCCCCC1C=CC(CCCCCCCCC(=O)OOC(=O)OC(C)C)CC1C(=O)OOC(=O)OC(C)C LJLVUSFANHLCMN-UHFFFAOYSA-N 0.000 description 1
- ALJRRSLLGRKHLR-UHFFFAOYSA-N propan-2-yloxycarbonyl 5-hexyl-2-(8-oxo-8-propan-2-yloxycarbonylperoxyoctyl)cyclohex-3-ene-1-carboperoxoate Chemical compound CCCCCCC1CC(C(=O)OOC(=O)OC(C)C)C(CCCCCCCC(=O)OOC(=O)OC(C)C)C=C1 ALJRRSLLGRKHLR-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- JBYXPOFIGCOSSB-UQGDGPGGSA-N rumenic acid Chemical compound CCCCCC\C=C/C=C/CCCCCCCC(O)=O JBYXPOFIGCOSSB-UQGDGPGGSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- CENFGFRVEHLMRC-UHFFFAOYSA-N tert-butyl 2-(8-tert-butylperoxy-8-oxooctyl)-5-hexyl-1-methylcyclohexane-1-carboperoxoate Chemical compound CCCCCCC1CCC(CCCCCCCC(=O)OOC(C)(C)C)C(C)(C(=O)OOC(C)(C)C)C1 CENFGFRVEHLMRC-UHFFFAOYSA-N 0.000 description 1
- DOLRJIABTVKKGE-UHFFFAOYSA-N tert-butyl 2-(8-tert-butylperoxy-8-oxooctyl)-5-hexylcyclohexane-1-carboperoxoate Chemical compound CCCCCCC1CCC(CCCCCCCC(=O)OOC(C)(C)C)C(C(=O)OOC(C)(C)C)C1 DOLRJIABTVKKGE-UHFFFAOYSA-N 0.000 description 1
- JONDLWAXOJNANP-UHFFFAOYSA-N tert-butyl 2-(9-tert-butylperoxy-9-oxononyl)-1-methyl-5-pentylcyclohex-3-ene-1-carboperoxoate Chemical compound CCCCCC1CC(C)(C(=O)OOC(C)(C)C)C(CCCCCCCCC(=O)OOC(C)(C)C)C=C1 JONDLWAXOJNANP-UHFFFAOYSA-N 0.000 description 1
- SJUPTGQYWYBLMO-UHFFFAOYSA-N tert-butyl 2-(9-tert-butylperoxy-9-oxononyl)-1-methyl-5-pentylcyclohexane-1-carboperoxoate Chemical compound CCCCCC1CCC(CCCCCCCCC(=O)OOC(C)(C)C)C(C)(C(=O)OOC(C)(C)C)C1 SJUPTGQYWYBLMO-UHFFFAOYSA-N 0.000 description 1
- FQIAVTKBJAWIQS-UHFFFAOYSA-N tert-butyl 2-(9-tert-butylperoxy-9-oxononyl)-5-pentylcyclohex-3-ene-1-carboperoxoate Chemical compound CCCCCC1CC(C(=O)OOC(C)(C)C)C(CCCCCCCCC(=O)OOC(C)(C)C)C=C1 FQIAVTKBJAWIQS-UHFFFAOYSA-N 0.000 description 1
- LAXMMAYMKLLBQC-UHFFFAOYSA-N tert-butyl 2-(9-tert-butylperoxy-9-oxononyl)-5-pentylcyclohexane-1-carboperoxoate Chemical compound CCCCCC1CCC(CCCCCCCCC(=O)OOC(C)(C)C)C(C(=O)OOC(C)(C)C)C1 LAXMMAYMKLLBQC-UHFFFAOYSA-N 0.000 description 1
- KFGLCGQJVWNFSV-UHFFFAOYSA-N tert-butyl 2-hexyl-5-[8-(2-methylbutan-2-ylperoxy)-8-oxooctyl]cyclohex-3-ene-1-carboperoxoate Chemical compound CCCCCCC1C=CC(CCCCCCCC(=O)OOC(C)(C)CC)CC1C(=O)OOC(C)(C)C KFGLCGQJVWNFSV-UHFFFAOYSA-N 0.000 description 1
- KYEGQWPCLRCIDF-UHFFFAOYSA-N tert-butyl 5-(11-tert-butylperoxy-11-oxoundec-2-enyl)-2-propylcyclohex-3-ene-1-carboperoxoate Chemical compound CCCC1C=CC(CC=CCCCCCCCC(=O)OOC(C)(C)C)CC1C(=O)OOC(C)(C)C KYEGQWPCLRCIDF-UHFFFAOYSA-N 0.000 description 1
- OLOYYTHNHGATJO-UHFFFAOYSA-N tert-butyl 5-(11-tert-butylperoxy-11-oxoundecyl)-2-propylcyclohexane-1-carboperoxoate Chemical compound CCCC1CCC(CCCCCCCCCCC(=O)OOC(C)(C)C)CC1C(=O)OOC(C)(C)C OLOYYTHNHGATJO-UHFFFAOYSA-N 0.000 description 1
- ONFOXHJEOHEHEC-UHFFFAOYSA-N tert-butyl 5-(12-tert-butylperoxy-12-oxododec-3-enyl)-2-ethylcyclohex-3-ene-1-carboperoxoate Chemical compound CCC1C=CC(CCC=CCCCCCCCC(=O)OOC(C)(C)C)CC1C(=O)OOC(C)(C)C ONFOXHJEOHEHEC-UHFFFAOYSA-N 0.000 description 1
- BOUHRKSYXHENLR-UHFFFAOYSA-N tert-butyl 5-(12-tert-butylperoxy-12-oxododeca-1,3-dienyl)-2-ethylcyclohex-3-ene-1-carboperoxoate Chemical compound CCC1C=CC(C=CC=CCCCCCCCC(=O)OOC(C)(C)C)CC1C(=O)OOC(C)(C)C BOUHRKSYXHENLR-UHFFFAOYSA-N 0.000 description 1
- NCEBXZGMLFKRCQ-UHFFFAOYSA-N tert-butyl 5-(12-tert-butylperoxy-12-oxododecyl)-2-ethylcyclohexane-1-carboperoxoate Chemical compound CCC1CCC(CCCCCCCCCCCC(=O)OOC(C)(C)C)CC1C(=O)OOC(C)(C)C NCEBXZGMLFKRCQ-UHFFFAOYSA-N 0.000 description 1
- LZIRTCIAHFWMKE-UHFFFAOYSA-N tert-butyl 5-(8-tert-butylperoxy-8-oxooctyl)-2-hex-1-enylcyclohex-3-ene-1-carboperoxoate Chemical compound CCCCC=CC1C=CC(CCCCCCCC(=O)OOC(C)(C)C)CC1C(=O)OOC(C)(C)C LZIRTCIAHFWMKE-UHFFFAOYSA-N 0.000 description 1
- OWZWOLCCGIUCKW-UHFFFAOYSA-N tert-butyl 5-(8-tert-butylperoxy-8-oxooctyl)-2-hex-3-enylcyclohex-3-ene-1-carboperoxoate Chemical compound CCC=CCCC1C=CC(CCCCCCCC(=O)OOC(C)(C)C)CC1C(=O)OOC(C)(C)C OWZWOLCCGIUCKW-UHFFFAOYSA-N 0.000 description 1
- AGOZQJZNBYPZIC-UHFFFAOYSA-N tert-butyl 5-(8-tert-butylperoxy-8-oxooctyl)-2-hexyl-1-methylcyclohex-3-ene-1-carboperoxoate Chemical compound CCCCCCC1C=CC(CCCCCCCC(=O)OOC(C)(C)C)CC1(C)C(=O)OOC(C)(C)C AGOZQJZNBYPZIC-UHFFFAOYSA-N 0.000 description 1
- NSWRODQWQOTICC-UHFFFAOYSA-N tert-butyl 5-(9-tert-butylperoxy-9-oxononyl)-1-methyl-2-pentylcyclohex-3-ene-1-carboperoxoate Chemical compound CCCCCC1C=CC(CCCCCCCCC(=O)OOC(C)(C)C)CC1(C)C(=O)OOC(C)(C)C NSWRODQWQOTICC-UHFFFAOYSA-N 0.000 description 1
- OTPQWFGAGJXDPG-UHFFFAOYSA-N tert-butyl 5-(9-tert-butylperoxy-9-oxononyl)-1-methyl-2-pentylcyclohexane-1-carboperoxoate Chemical compound CCCCCC1CCC(CCCCCCCCC(=O)OOC(C)(C)C)CC1(C)C(=O)OOC(C)(C)C OTPQWFGAGJXDPG-UHFFFAOYSA-N 0.000 description 1
- XNYALIHQUNZXPH-UHFFFAOYSA-N tert-butyl 5-(9-tert-butylperoxy-9-oxononyl)-2-pent-2-enylcyclohex-3-ene-1-carboperoxoate Chemical compound CCC=CCC1C=CC(CCCCCCCCC(=O)OOC(C)(C)C)CC1C(=O)OOC(C)(C)C XNYALIHQUNZXPH-UHFFFAOYSA-N 0.000 description 1
- DRRPGCLOKQERML-UHFFFAOYSA-N tert-butyl 5-(9-tert-butylperoxy-9-oxononyl)-2-pentylcyclohexane-1-carboperoxoate Chemical compound CCCCCC1CCC(CCCCCCCCC(=O)OOC(C)(C)C)CC1C(=O)OOC(C)(C)C DRRPGCLOKQERML-UHFFFAOYSA-N 0.000 description 1
- PXTWBSQPHHJCAJ-UHFFFAOYSA-N tert-butyl 8-(cyclohexen-1-yl)octaneperoxoate Chemical compound CC(C)(C)OOC(=O)CCCCCCCC1=CCCCC1 PXTWBSQPHHJCAJ-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- RVNGZZVEPVCUTE-UHFFFAOYSA-N undec-2-enoyl 2-hexyl-5-(8-oxo-8-undec-2-enoylperoxyoctyl)cyclohex-3-ene-1-carboperoxoate Chemical compound C(C=CCCCCCCCC)(=O)OOC(=O)C1C(C=CC(C1)CCCCCCCC(=O)OOC(C=CCCCCCCCC)=O)CCCCCC RVNGZZVEPVCUTE-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- DTOSIQBPPRVQHS-UHFFFAOYSA-N α-Linolenic acid Chemical compound CCC=CCC=CCC=CCCCCCCCC(O)=O DTOSIQBPPRVQHS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/38—Peroxy compounds the âOâOâ group being bound between a >C=O group and a carbon atom, not further substituted by oxygen atoms, i.e. esters of peroxy acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
- C08F299/0442—Catalysts
- C08F299/045—Peroxy-compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/36—Per-compounds with more than one peroxy radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
- Polyesters Or Polycarbonates (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Description
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Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP507879A JPS5596816A (en) | 1978-01-05 | 1979-01-19 | Gas burner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/757,185 US4079074A (en) | 1977-01-06 | 1977-01-06 | Unsymmetrical diperoxides and processes of use in polymerizing unsaturated monomers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5387338A JPS5387338A (en) | 1978-08-01 |
| JPS642587B2 true JPS642587B2 (ja) | 1989-01-18 |
Family
ID=25046752
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5078A Granted JPS5387338A (en) | 1977-01-06 | 1978-01-05 | Asymmetrical diperoxide and its use as hardening catalyst |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4079074A (ja) |
| JP (1) | JPS5387338A (ja) |
| AU (1) | AU509887B2 (ja) |
| CA (1) | CA1085416A (ja) |
| DE (1) | DE2757514A1 (ja) |
| FR (1) | FR2376843A1 (ja) |
| GB (1) | GB1580820A (ja) |
| IT (1) | IT1091786B (ja) |
| NL (1) | NL7800023A (ja) |
| SE (1) | SE436567B (ja) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4219676A (en) * | 1978-01-16 | 1980-08-26 | Pennwalt Corporation | Unsymmetrical diperoxides and processes of use in polymerizing unsaturated monomers |
| US4634753A (en) * | 1983-05-20 | 1987-01-06 | Pennwalt Corporation | Hydroxy-t-alkyl peroxyester |
| US4705888A (en) * | 1985-09-30 | 1987-11-10 | Akzo Nv | t-Alkenyl peroxy esters |
| HU201101B (en) * | 1986-11-14 | 1990-09-28 | Mta Koezponti Kemiai Kutato In | Process for producing by radical polymerization of polymers of polydispersity of 1,50 to 2,00, having functional groups in alpha, omega positions |
| CA2019626C (en) * | 1989-06-30 | 1994-11-22 | Yuichi Arito | Styrene type resin and production method thereof |
| CA2134967A1 (en) * | 1992-06-10 | 1993-12-23 | Duane B. Priddy | Oligomers of styrene as flegmatizers for organic peroxides |
| US6703460B1 (en) * | 2003-03-04 | 2004-03-09 | Fina Technology, Inc. | Use of sequential polyperoxides to produce polystyrene with high grafting |
| JP5707948B2 (ja) | 2011-01-12 | 2015-04-30 | æ ªåŒäŒç€Ÿè±ç°èªåç¹æ© | ãšã¢ã³ã³ãã¬ããµ |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2813885A (en) * | 1954-09-02 | 1957-11-19 | Swern Daniel | Process for making fatty peracids |
| US3770770A (en) * | 1966-08-01 | 1973-11-06 | Pennwalt Corp | Certain peroxyesters having a defined substituent positioned on a carbon atom at least beta to a peroxy carbon atom |
| US3494898A (en) * | 1969-04-10 | 1970-02-10 | Heinz W Meyer | Polymerization of olefinic compounds and polymerization catalyst |
| DE2125160C3 (de) * | 1971-05-21 | 1980-05-22 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Verfahren zur Herstellung von aliphatischen PercarbonsÀuren mit 2 bis 5 Kohlenstoffatomen |
| NL7209462A (ja) * | 1972-07-07 | 1974-01-09 | ||
| NL7311783A (nl) * | 1973-08-28 | 1975-03-04 | Akzo Nv | Werkwijze voor het bereiden van voor het initieren van radicaalreacties geschikte nieuwe peresters. |
-
1977
- 1977-01-06 US US05/757,185 patent/US4079074A/en not_active Expired - Lifetime
- 1977-10-19 CA CA289,031A patent/CA1085416A/en not_active Expired
- 1977-11-03 SE SE7712454A patent/SE436567B/xx not_active IP Right Cessation
- 1977-11-15 IT IT51820/77A patent/IT1091786B/it active
- 1977-11-24 GB GB49008/77A patent/GB1580820A/en not_active Expired
- 1977-11-24 AU AU30918/77A patent/AU509887B2/en not_active Expired
- 1977-12-16 FR FR7738072A patent/FR2376843A1/fr active Granted
- 1977-12-22 DE DE19772757514 patent/DE2757514A1/de active Granted
-
1978
- 1978-01-02 NL NL7800023A patent/NL7800023A/xx not_active Application Discontinuation
- 1978-01-05 JP JP5078A patent/JPS5387338A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| AU509887B2 (en) | 1980-05-29 |
| IT1091786B (it) | 1985-07-06 |
| FR2376843B1 (ja) | 1981-10-16 |
| GB1580820A (en) | 1980-12-03 |
| FR2376843A1 (fr) | 1978-08-04 |
| JPS5387338A (en) | 1978-08-01 |
| CA1085416A (en) | 1980-09-09 |
| DE2757514C2 (ja) | 1988-02-25 |
| US4079074A (en) | 1978-03-14 |
| NL7800023A (nl) | 1978-07-10 |
| SE436567B (sv) | 1985-01-07 |
| DE2757514A1 (de) | 1978-07-13 |
| SE7712454L (sv) | 1978-07-07 |
| AU3091877A (en) | 1979-05-31 |
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