JPS6411603B2 - - Google Patents

Info

Publication number

JPS6411603B2

JPS6411603B2 JP12342279A JP12342279A JPS6411603B2 JP S6411603 B2 JPS6411603 B2 JP S6411603B2 JP 12342279 A JP12342279 A JP 12342279A JP 12342279 A JP12342279 A JP 12342279A JP S6411603 B2 JPS6411603 B2 JP S6411603B2

Authority

JP

Japan

Prior art keywords

antifouling agent

underwater

tetrachloroisophthalonitrile

fouling organisms

ethylenebisdithiocarbamate

Prior art date

1979-09-25

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Links

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• 239000002519 antifouling agent Substances 0.000 claims description 18
• CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 claims description 10
• 239000000203 mixture Substances 0.000 claims description 10
• 239000011701 zinc Substances 0.000 claims description 6
• 229910052725 zinc Inorganic materials 0.000 claims description 6
• 150000003839 salts Chemical class 0.000 claims description 5
• HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
• 239000002253 acid Substances 0.000 claims description 3
• 150000007513 acids Chemical class 0.000 claims description 3
• RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
• 125000000217 alkyl group Chemical group 0.000 claims description 2
• 229910052802 copper Chemical group 0.000 claims description 2
• 239000010949 copper Chemical group 0.000 claims description 2
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
• 150000001875 compounds Chemical class 0.000 description 7
• 238000009472 formulation Methods 0.000 description 7
• 239000003973 paint Substances 0.000 description 7
• CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
• 229920001083 polybutene Polymers 0.000 description 6
• 239000008096 xylene Substances 0.000 description 6
• 239000004480 active ingredient Substances 0.000 description 5
• 230000003373 anti-fouling effect Effects 0.000 description 5
• 230000000694 effects Effects 0.000 description 5
• 239000011347 resin Substances 0.000 description 4
• 229920005989 resin Polymers 0.000 description 4
• 238000012360 testing method Methods 0.000 description 4
• QRNATDQRFAUDKF-UHFFFAOYSA-N 2-carbamothioylsulfanylethyl carbamodithioate Chemical compound NC(=S)SCCSC(N)=S QRNATDQRFAUDKF-UHFFFAOYSA-N 0.000 description 3
• 239000004925 Acrylic resin Substances 0.000 description 3
• 229920000178 Acrylic resin Polymers 0.000 description 3
• 229910000831 Steel Inorganic materials 0.000 description 3
• 238000009360 aquaculture Methods 0.000 description 3
• 244000144974 aquaculture Species 0.000 description 3
• 238000002156 mixing Methods 0.000 description 3
• 239000010959 steel Substances 0.000 description 3
• 241000251468 Actinopterygii Species 0.000 description 2
• 238000000576 coating method Methods 0.000 description 2
• 230000000052 comparative effect Effects 0.000 description 2
• 230000007423 decrease Effects 0.000 description 2
• 150000002696 manganese Chemical class 0.000 description 2
• 229910052748 manganese Inorganic materials 0.000 description 2
• 239000011572 manganese Substances 0.000 description 2
• 239000013535 sea water Substances 0.000 description 2
• 150000003606 tin compounds Chemical class 0.000 description 2
• 150000003751 zinc Chemical class 0.000 description 2
• IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 1
• 241000473391 Archosargus rhomboidalis Species 0.000 description 1
• 241001474374 Blennius Species 0.000 description 1
• 241000700670 Bryozoa Species 0.000 description 1
• 229920002160 Celluloid Polymers 0.000 description 1
• 241000238586 Cirripedia Species 0.000 description 1
• 239000005749 Copper compound Substances 0.000 description 1
• MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
• RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
• PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
• 241000237852 Mollusca Species 0.000 description 1
• 241001600434 Plectroglyphidodon lacrymatus Species 0.000 description 1
• 239000004698 Polyethylene Substances 0.000 description 1
• UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
• BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
• 208000027418 Wounds and injury Diseases 0.000 description 1
• 230000005856 abnormality Effects 0.000 description 1
• 229920006397 acrylic thermoplastic Polymers 0.000 description 1
• 239000000654 additive Substances 0.000 description 1
• 230000002411 adverse Effects 0.000 description 1
• 238000007605 air drying Methods 0.000 description 1
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
• BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
• DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
• 239000011248 coating agent Substances 0.000 description 1
• 238000007796 conventional method Methods 0.000 description 1
• 150000001879 copper Chemical class 0.000 description 1
• 150000001880 copper compounds Chemical class 0.000 description 1
• BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
• KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
• 229940112669 cuprous oxide Drugs 0.000 description 1
• 230000006378 damage Effects 0.000 description 1
• 238000007598 dipping method Methods 0.000 description 1
• 238000002845 discoloration Methods 0.000 description 1
• 239000006185 dispersion Substances 0.000 description 1
• 229920001971 elastomer Polymers 0.000 description 1
• 238000003912 environmental pollution Methods 0.000 description 1
• 239000000446 fuel Substances 0.000 description 1
• 229910001385 heavy metal Inorganic materials 0.000 description 1
• 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
• 239000004615 ingredient Substances 0.000 description 1
• 208000014674 injury Diseases 0.000 description 1
• 231100001231 less toxic Toxicity 0.000 description 1
• 230000007774 longterm Effects 0.000 description 1
• 238000012423 maintenance Methods 0.000 description 1
• 239000000463 material Substances 0.000 description 1
• 150000002736 metal compounds Chemical class 0.000 description 1
• 238000000034 method Methods 0.000 description 1
• 239000000025 natural resin Substances 0.000 description 1
• 239000001301 oxygen Substances 0.000 description 1
• 229910052760 oxygen Inorganic materials 0.000 description 1
• 244000045947 parasite Species 0.000 description 1
• 239000000049 pigment Substances 0.000 description 1
• 239000004014 plasticizer Substances 0.000 description 1
• 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
• -1 polyethylene Polymers 0.000 description 1
• 229920000573 polyethylene Polymers 0.000 description 1
• 230000002265 prevention Effects 0.000 description 1
• 238000011160 research Methods 0.000 description 1
• 239000005060 rubber Substances 0.000 description 1
• 235000015170 shellfish Nutrition 0.000 description 1
• 239000002904 solvent Substances 0.000 description 1
• 239000000126 substance Substances 0.000 description 1
• 230000004083 survival effect Effects 0.000 description 1
• 229920003051 synthetic elastomer Polymers 0.000 description 1
• 229920003002 synthetic resin Polymers 0.000 description 1
• 239000000057 synthetic resin Substances 0.000 description 1
• 239000005061 synthetic rubber Substances 0.000 description 1
• ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
• 231100000331 toxic Toxicity 0.000 description 1
• 230000002588 toxic effect Effects 0.000 description 1
• 231100000419 toxicity Toxicity 0.000 description 1
• 230000001988 toxicity Effects 0.000 description 1
• SBXWFLISHPUINY-UHFFFAOYSA-N triphenyltin Chemical class C1=CC=CC=C1[Sn](C=1C=CC=CC=1)C1=CC=CC=C1 SBXWFLISHPUINY-UHFFFAOYSA-N 0.000 description 1