JPS637367B2 - - Google Patents
Info
- Publication number
- JPS637367B2 JPS637367B2 JP58148895A JP14889583A JPS637367B2 JP S637367 B2 JPS637367 B2 JP S637367B2 JP 58148895 A JP58148895 A JP 58148895A JP 14889583 A JP14889583 A JP 14889583A JP S637367 B2 JPS637367 B2 JP S637367B2
- Authority
- JP
- Japan
- Prior art keywords
- mol
- contact lens
- fraction
- water
- washed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 claims description 50
- 239000000203 mixture Substances 0.000 claims description 41
- 239000011347 resin Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000010526 radical polymerization reaction Methods 0.000 claims description 5
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 4
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims 1
- 210000002196 fr. b Anatomy 0.000 claims 1
- 210000000540 fraction c Anatomy 0.000 claims 1
- 150000002989 phenols Chemical class 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 42
- 229920001296 polysiloxane Polymers 0.000 description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
- 239000012074 organic phase Substances 0.000 description 31
- 239000000243 solution Substances 0.000 description 30
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 28
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 28
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 28
- 239000000178 monomer Substances 0.000 description 28
- 229910052938 sodium sulfate Inorganic materials 0.000 description 28
- 235000011152 sodium sulphate Nutrition 0.000 description 28
- 238000003756 stirring Methods 0.000 description 26
- -1 dimethylsiloxane groups Chemical group 0.000 description 24
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- 239000000047 product Substances 0.000 description 18
- 238000006460 hydrolysis reaction Methods 0.000 description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 16
- 239000012043 crude product Substances 0.000 description 16
- 239000001301 oxygen Substances 0.000 description 16
- 229910052760 oxygen Inorganic materials 0.000 description 16
- 230000007062 hydrolysis Effects 0.000 description 15
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 14
- 238000005481 NMR spectroscopy Methods 0.000 description 14
- 238000004458 analytical method Methods 0.000 description 14
- 239000008346 aqueous phase Substances 0.000 description 14
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 14
- 235000019341 magnesium sulphate Nutrition 0.000 description 14
- XUIMIQQOPSSXEZ-OUBTZVSYSA-N silicon-29 atom Chemical compound [29Si] XUIMIQQOPSSXEZ-OUBTZVSYSA-N 0.000 description 14
- 239000005051 trimethylchlorosilane Substances 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 13
- 238000002156 mixing Methods 0.000 description 12
- 239000003039 volatile agent Substances 0.000 description 12
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 11
- 125000005375 organosiloxane group Chemical group 0.000 description 11
- 230000035699 permeability Effects 0.000 description 10
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000003999 initiator Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000010348 incorporation Methods 0.000 description 4
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- FHLPGTXWCFQMIU-UHFFFAOYSA-N [4-[2-(4-prop-2-enoyloxyphenyl)propan-2-yl]phenyl] prop-2-enoate Chemical compound C=1C=C(OC(=O)C=C)C=CC=1C(C)(C)C1=CC=C(OC(=O)C=C)C=C1 FHLPGTXWCFQMIU-UHFFFAOYSA-N 0.000 description 2
- QUZSUMLPWDHKCJ-UHFFFAOYSA-N bisphenol A dimethacrylate Chemical compound C1=CC(OC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OC(=O)C(C)=C)C=C1 QUZSUMLPWDHKCJ-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 210000004087 cornea Anatomy 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- ROAYSRAUMPWBQX-UHFFFAOYSA-N ethanol;sulfuric acid Chemical compound CCO.OS(O)(=O)=O ROAYSRAUMPWBQX-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- JOEWGPALVTUVKQ-UHFFFAOYSA-N (2-hydroxy-3-methoxypropyl) prop-2-enoate Chemical compound COCC(O)COC(=O)C=C JOEWGPALVTUVKQ-UHFFFAOYSA-N 0.000 description 1
- HFQYAVPDOBKWAX-UHFFFAOYSA-N (2-hydroxynaphthalen-1-yl) 2-methylprop-2-enoate Chemical compound C1=CC=C2C(OC(=O)C(=C)C)=C(O)C=CC2=C1 HFQYAVPDOBKWAX-UHFFFAOYSA-N 0.000 description 1
- CZNMYMLUZPIJKF-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;2-methylprop-2-enamide Chemical compound CC(=C)C(N)=O.C=CC1=CC=CC=C1C=C CZNMYMLUZPIJKF-UHFFFAOYSA-N 0.000 description 1
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- OWPUOLBODXJOKH-UHFFFAOYSA-N 2,3-dihydroxypropyl prop-2-enoate Chemical compound OCC(O)COC(=O)C=C OWPUOLBODXJOKH-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical compound CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- YYPLPZPLLWYWKD-UHFFFAOYSA-N 2-ethenylpyridin-1-ium;chloride Chemical compound Cl.C=CC1=CC=CC=N1 YYPLPZPLLWYWKD-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- SQVSEQUIWOQWAH-UHFFFAOYSA-N 2-hydroxy-3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCC(O)CS(O)(=O)=O SQVSEQUIWOQWAH-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 1
- CTHJQRHPNQEPAB-UHFFFAOYSA-N 2-methoxyethenylbenzene Chemical compound COC=CC1=CC=CC=C1 CTHJQRHPNQEPAB-UHFFFAOYSA-N 0.000 description 1
- FMFHUEMLVAIBFI-UHFFFAOYSA-N 2-phenylethenyl acetate Chemical compound CC(=O)OC=CC1=CC=CC=C1 FMFHUEMLVAIBFI-UHFFFAOYSA-N 0.000 description 1
- NFPBWZOKGZKYRE-UHFFFAOYSA-N 2-propan-2-ylperoxypropane Chemical compound CC(C)OOC(C)C NFPBWZOKGZKYRE-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- MAGFQRLKWCCTQJ-UHFFFAOYSA-N 4-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=C(C=C)C=C1 MAGFQRLKWCCTQJ-UHFFFAOYSA-N 0.000 description 1
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
- DYPSPXFRXXXUNB-UHFFFAOYSA-N 4-ethenylpyridine;hydrochloride Chemical compound Cl.C=CC1=CC=NC=C1 DYPSPXFRXXXUNB-UHFFFAOYSA-N 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- YOQXWFAPUCIKIH-UHFFFAOYSA-N 5-ethenyl-2-ethylpyridine Chemical compound CCC1=CC=C(C=C)C=N1 YOQXWFAPUCIKIH-UHFFFAOYSA-N 0.000 description 1
- GUZNQCFYZWZJGJ-UHFFFAOYSA-N 5-ethenyl-2-methylpyridin-1-ium;chloride Chemical compound [Cl-].CC1=CC=C(C=C)C=[NH+]1 GUZNQCFYZWZJGJ-UHFFFAOYSA-N 0.000 description 1
- VJOWMORERYNYON-UHFFFAOYSA-N 5-ethenyl-2-methylpyridine Chemical compound CC1=CC=C(C=C)C=N1 VJOWMORERYNYON-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- BEKKKWRHMRJZNV-UHFFFAOYSA-N C(C=C)(=O)O[Si](OOC(C=C)=O)(C)C Chemical compound C(C=C)(=O)O[Si](OOC(C=C)=O)(C)C BEKKKWRHMRJZNV-UHFFFAOYSA-N 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- JZUFKLXOESDKRF-UHFFFAOYSA-N Chlorothiazide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC2=C1NCNS2(=O)=O JZUFKLXOESDKRF-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- GDFCSMCGLZFNFY-UHFFFAOYSA-N Dimethylaminopropyl Methacrylamide Chemical compound CN(C)CCCNC(=O)C(C)=C GDFCSMCGLZFNFY-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 description 1
- LOPVAWVHGAWUPS-UHFFFAOYSA-M [2-hydroxy-3-(2-methylprop-2-enoyloxy)propyl]-trimethylazanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC(O)C[N+](C)(C)C LOPVAWVHGAWUPS-UHFFFAOYSA-M 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- BTHCBXJLLCHNMS-UHFFFAOYSA-N acetyloxysilicon Chemical compound CC(=O)O[Si] BTHCBXJLLCHNMS-UHFFFAOYSA-N 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- SYWDWCWQXBUCOP-UHFFFAOYSA-N benzene;ethene Chemical class C=C.C1=CC=CC=C1 SYWDWCWQXBUCOP-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- BRXCDHOLJPJLLT-UHFFFAOYSA-N butane-2-sulfonic acid Chemical compound CCC(C)S(O)(=O)=O BRXCDHOLJPJLLT-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- QABCGOSYZHCPGN-UHFFFAOYSA-N chloro(dimethyl)silicon Chemical compound C[Si](C)Cl QABCGOSYZHCPGN-UHFFFAOYSA-N 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- NVLHKSGUMYMKRR-UHFFFAOYSA-N dodeca-2,10-dienediamide Chemical compound NC(=O)C=CCCCCCCC=CC(N)=O NVLHKSGUMYMKRR-UHFFFAOYSA-N 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- KUDUQBURMYMBIJ-UHFFFAOYSA-N ethylene glycol diacrylate Substances C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 description 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
- OXZMJPQKHGOTGJ-UHFFFAOYSA-N n-[10-(prop-2-enoylamino)decyl]prop-2-enamide Chemical compound C=CC(=O)NCCCCCCCCCCNC(=O)C=C OXZMJPQKHGOTGJ-UHFFFAOYSA-N 0.000 description 1
- AYGYHGXUJBFUJU-UHFFFAOYSA-N n-[2-(prop-2-enoylamino)ethyl]prop-2-enamide Chemical compound C=CC(=O)NCCNC(=O)C=C AYGYHGXUJBFUJU-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- UQMGAWUIVYDWBP-UHFFFAOYSA-N silyl acetate Chemical class CC(=O)O[SiH3] UQMGAWUIVYDWBP-UHFFFAOYSA-N 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- XFTALRAZSCGSKN-UHFFFAOYSA-M sodium;4-ethenylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=C(C=C)C=C1 XFTALRAZSCGSKN-UHFFFAOYSA-M 0.000 description 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical compound OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 1
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
- C08F283/124—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes on to polysiloxanes having carbon-to-carbon double bonds
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
- G02B1/043—Contact lenses
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Eyeglasses (AREA)
- Silicon Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
ææ©ã·ãããµã³åããé
žçŽ ééæ§ãèªå°ããã³
ã³ã¿ã¯ãã¬ã³ãºã¯è§èãžã®å åãªé žçŽ 移éãäžã
ãããã«å®è³ªçãªå«éã®ãªã«ã¬ãã·ãããµã³ãå¿
èŠãšããŠããã äžè¬ã«ææ©ã·ãããµã³ååã¯ãã®ä»ã®åéäœã
å«ãå€ãã®çµæç©äžã§äž¡ç«ã§ããªãåŸåãããã
äŸãã°ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãã«ææ©ã·ãããµã³ã
溶解ããããŠåèšæº¶æ¶²ãéåããããšã¯ãã°ãã°
ã³ã³ã¿ã¯ãã¬ã³ãºçšãšããŠäžé©åœãªäžéæã®ææ
ãããããã å è¡æè¡ã¯äžé£œåã®éåãåŸãåºã«ååŠçã«çµ
åããçãææ©ã·ãããµã³åäœãããããªææ©ã·
ãããµã³åéäœããã®ä»ã®åéäœãšå ±éåããŠäž¡
ç«å¯èœã§äžã€ããæ ã«éæãªææã«éããæ段ã
æäŸããããšã瀺ããŠããã äžæ¹ããã äžçš®ã®äžé£œåã®éåãåŸãåºã®ã¿ã
å«æããææ©ã·ãããµã³åäœã¯ãã®ä»ã®åéäœã
ãšãã«èŠªæ°Žåéäœãšå ±éåããå Žåã«ãã°ãã°ã©
ã³ãã ãªå ±éåäœãäžããªãããã®ç¶æ ã¯çžåé¢
ããã³äžéæææã«å°ããäžå®ã®å Žåã«ãçžåé¢
ã¯èŠèŠçã«æ¢ç¥ã§ããªããããããææã®ç©çç
æ§è³ªã¯èšŒæãããŠããããã®ç¶æ ã¯ãããç¿æ§ãš
ç Žç ã«å¯Ÿããæ§è³ªã瀺ãææãäžããããšãã§ã
ãã ãžã¡ãã«ã·ãããµã³ãžã¢ã¯ãªã¬ãŒããªãªãŽããŒ
ãã調補ãããé«åºŠã«äº€åçµåããéåäœã®ç©ç
çæ§è³ªã¯åœæ¥äžå ¬ç¥ã§ãããäžè¬ã«ã埮çžåé¢ã¯
ãã¬éåäœã«ããããžã¡ãã«ã·ãããµã³åºã®éã
å¢å ããå Žåã«æããããããã®çŸè±¡ã¯é·ãææ©
é åã®æ¬ é€ã«èµ·å ããŠãããå šäœã«ã«ãã
ïŒKatzïŒã®æ¥ç©ãJ.Polym.Sci.Chem.Ed.16(3)597
ïŒ1978ïŒãã¯ãææ©çé åãçžåé¢ã«å¯Ÿããå å°ã
è¡ãªããæ ã«ããããªåå¿æ§ææ©ã·ãããµã³åé
äœã«å ±éåã«å察ã§ãããšæ瀺ããŠãããããã
ãªããã³ã³ã¿ã¯ãã¬ã³ãºææã«ãããŠãç©ççæ§
質ã®é©åœãªãã©ã³ã¹ãã¯ããããã«ïŒçš®ä»¥äžã®å ±
éåäœãå å«ããããšãæãŸããããšãç¥ãããŠ
ããã ããæ ãã³ã³ã¿ã¯ãã¬ã³ãºé©çšã®ããã«äž¡ç«ã§
ããææ©ã·ãããµã³åäœã®å®è³ªçãªéãå«æãã
ã©ã³ãã ãªå ±éåäœãæäŸããããšãæãŸããã
æ¬çºæã¯å€éäžé£œåã®éåãåŸãåºãå«æããå
å²ç¶ææ©ã·ãããµã³æ§é ãå©çšããããããã®æ
æã¯ãã®ä»ã®åéäœãšå ±éåããå Žåãéæã§ã
é«åºŠã«é žçŽ ééæ§ã§èä¹ æ§ã®ããçµæç©ãæäŸã
ããéåããã»ã¹ã®ã©ã³ãã ãªæ§è³ªã¯å€éã®äžé£œ
åéåãåŸãåºã®ååšã«ãã€ãŠé«ãããããé瀺
ãããææ©ããªã·ãããµã³åéäœã®äž¡ç«åã¯é«åºŠ
ã«åæããææ©ããªã·ãããµã³åã®å©çšã«ãã€ãŠ
æ¹åãããã æ¬çºæã®ç®çã¯ããåç¬ã§ãŸãã¯ãã®ä»ã®ææ©
ææãšçµåãããŠã³ã³ã¿ã¯ãã¬ã³ãºã圢æããã®
ã«æçšãªæ°èŠãªäžé£œåå€å®èœæ§ææ©ããªã·ãããµ
ã³ãæäŸããããšã§ããã æ¬çºæã®ããäžã€ã®ç®çã¯ã·ãããµã³ãåç¬ã§
ãŸãã¯ãã®ä»ã®ææ©ææãšçµåããŠäœ¿çšããããš
ãã§ããã³ã³ã¿ã¯ãã¬ã³ãºã®åœ¢ã§äžé£œåå€å®èœæ§
ææ©ããªã·ãããµã³ã®éååç©ãæäŸããããšã§
ããã ããã«æ¬çºæã®ç®çã¯é žçŽ ééæ§ã寞æ³å®å®
çã芪氎æ§äžã€è¯å¥œãªå åŠçéææ§ããã³æãã
ããããæ¬çºæã«åºã¥ãã³ã³ã¿ã¯ãã¬ã³ãºææã
ãã³ã³ã³ã¿ã¯ãã¬ã³ãºãæäŸããããšã§ããã æ¬çºæã®ããã«ããäžã€ã®ç®çã¯é¡èãªç¡¬ããŸ
ãã¯å硬æ§ã®é žçŽ ééæ§ã¬ã³ãºãæ £çšã®ææ©ã·ã
ããµã³å«æã³ã³ã¿ã¯ãã¬ã³ãºã«æ¯èŒããå Žåã«ã
ãããæžå°ããŠè¯å¥œãªåŒ·åºŠãæããŠåœ¢æãããå
èšç®çã«åºã¥ãã³ã³ã¿ã¯ãã¬ã³ãºãæäŸããããš
ã§ããã æ¬çºæã¯ãããã®ç®çãéæããããã®ãã®ã§
ãã€ãŠãæ¬¡åŒ ïŒåŒäžãâïœâã¯0.10ã0.40ã®ã¢ã«ãã©ã¯ã·ãš
ã³å€ãæããâïœâã¯0.25ã0.80ã®ã¢ã«ãã©ã¯ã·
ãšã³å€ãæããããŠâïœâã¯0.10ã0.40ã®ã¢ã«ã
ã©ã¯ã·ãšã³å€ãæããïŒ ã§è¡šããããæš¹èç³»ã®éåäœãå«ãã§æãã³ã³ã¿
ã¯ãã¬ã³ãºææãæäŸãããã®ã§ããã äžå®ã®å¥œãŸããæ æ§ã«ãããŠã³ã³ã¿ã¯ãã¬ã³ãº
ææã¯ïœïŒ0.20ã0.35ã¢ã«ãã©ã¯ã·ãšã³ãïœïŒ
0.40ã0.60ã¢ã«ãã©ã¯ã·ãšã³ãïœïŒ0.20ã0.40ã¢
ã«ãã©ã¯ã·ãšã³ã«ãã30ã60ééïŒ ãã¡ãã«ã¡ã¿
ã¯ãªã¬ãŒã69ã40ééïŒ ããã³ããã«ãããªã
ã³ãã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãŸãã¯ãããã®æ··
åç©ïŒã10ééïŒ ã®éã«ãããŠåèšåŒã®ç¬¬ïŒæå
ããéé¢åºéååã«ãã95ïŒ ãŸãã¯ãã以äžãŸã§
éåããŠããæåã®æ··åç©ãšå ±ã«æããŠããã æ¬çºæã®ææããäœãããã³ã³ã¿ã¯ãã¬ã³ãºã¯
奜ãŸããã¯ç¡¬æ§ãŸãã¯å硬æ§ã§ãããæ £çšã®æ段
ã§å®¹æã«çµç«ãŠããäžã€ä»äžããããåè¶ãã寞
æ³å®å®æ§ãæããé©åœãªå±æçã§æ¬æ¥æ¹¿æœ€æ§ã§ã
ããããŠè¯å¥œãªå äŒéæ§è³ªãæããããšãæ¬çºæ
ã®ç¹åŸŽã§ããããããã¬ã³ãºã¯èä¹ æ§ããããè¯
奜ãªé žçŽ ééæ§ãæããŠãããç®ãšã®ãã€ãªé©å
æ§ããããå®è³ªçã«éæ°Žåæ§ã§ãããååŠçã«å®
å®ã§ãåççãªåŒæ»ãæµææ§ãšå ±ã«èçœèç©ã«å¯Ÿ
ããæµææ§ãæããŠããããããã®ãã®ã䜿çšè
ã¯å»¶é·ãããæéã®éãå®å šäžã€å¿«é©ã«ãããã
ãšãã§ããäžæ¹ã䜿çšè ã«è¯å¥œãªèŠèŠãæäŸã
ãããã®ããšã¯ã¬ã³ãºåæ±ãã®æéãå°ãããäž
ã€ä»åŸã®ç掻ã倧ããæ¹åããã æ¬çºæã®æ°èŠãªææ©ããªã·ãããµã³ã®ãããã
ãå€çš®é¡ã®ååããæ§æãããäžçš®ã®ç¹æ®ãªçµæ
ç©ã§ã¯ãªããããŠããæ ã«æããã¯äžçš®ä»¥äžã®é
åãåŸãåºãæããå¹³åçãŸãã¯å žåççµæç©ãš
ããŠè¿°ã¹ãããããšãç解ãã¹ãã§ãããããã
æ§é ã¯å ¬ç¥ã§ãããããŠæ··åãããæ§é ãšããŠè¿°
ã¹ãããããŸãã¯ãããªãã°æš¹èãšããŠç¥ããäž
ã€è¿°ã¹ãããŠããã æš¹èãŸãã¯æš¹èç³»ãšããŠèšèŒããããšãã§ãã
æ¬çºæã®ïŒçš®ã®åäœäžé£œåå€å®èœæ§ææ©ããªã·ã
ããµã³ã¯åœæ¥äžåšç¥ã®å€æ§ãªåå¿æè¡ãå©çšããŠ
調補ããããšãã§ãããæã奜ãŸããã¯ã¯ããã·
ã©ã³ãŸãã¯ã¢ã«ã³ãã·ã·ã©ã³äžéäœã䜿çšããã
å ±å æ°Žå解ã«ãŒãã§ãããå ±å æ°Žå解åå¿ã¯ã¡ã¿
ããŒã«ãŸãã¯ãšã¿ããŒã«ã®ãããªæ°Žæ··åæ§æº¶åªã®
ååšäžäžŠã³ã«ãžãšãã«ãšãŒãã«ããžããã«ãšãŒã
ã«ããã«ãšã³ããããµãŸãã¯ã¯ããããªã«ã ã®ã
ããªæ°Žæµžæ§æº¶åªã®ååšäžå®æœããããšãã§ããã ãšã¿ããŒã«ïŒç¡«é žè§Šåªç³»ãšå ±ã«ã¢ã»ããã·ã·ã©
ã³äžéäœã®äœ¿çšããŸãæ¬çºæã®äžé£œåå€å®èœåºæ
æ©ããªã·ãããµã³ã補é ããããã«è¡ãªãããã å ±å æ°Žå解ã«ãããŠãåå¿äœã®æ··åç©ã¯æçµè£œ
åã«ææãããã¢ã«ãã©ã¯ã·ãšã³ãæäŸãããã
ã«éžæãããåã ã®éã§éžæããããããããŠ
âïœâïŒâïœâããã³âïœâã«ã€ããŠäžè¿°ãããã
ã«ã¢ã«ãã©ã¯ã·ãšã³ã¯åç²åçµæã«ãããæ§é ç
å¶éãæããã«ãããææ©æº¶åªã®å¯èœãªå å«ã«ã
ãæ°Žäžåå¿äœã®ã¹ã©ãªãŒãåœæ¥äžç¥ãããéãã«
ã€ãã€ããå æ°Žå解ããã³çž®åãçããããã«å
åãªæéããšããããïŒæéããïŒæ¥ã®å žåçãª
æéãâ20ã98âã®æž©åºŠãããŠäžå±€å¥œãŸããã¯å®€
æž©ã«ãããŠéæãããããã«çšãããããææ©çž
ã¯åœ¢æããã補åãéã³ãããŠææ©çžãæ°Žãšæ··å
ã§ããªãæ ã«æ°Žããåé¢ãããäœååéã®å¯çç©
ã奜ãŸããã¯åœæ¥äžå ¬ç¥ã®ç±ããã³ç空ãå©çšã
ãããšã«ããææ©çžããåãé€ãããçŽ200以äž
ã®ååéãé€ããããå¯çç©é€å»åŸæ®ã€ãŠããç²
çæç©ãå¡©åºæ§æº¶æ¶²ã§æœåºããæ°ŽæŽããããŠæ¬¡ã
ã§ä¹Ÿç¥ããããããŠãã®ãã®ã¯ããã«åå¿ããŠã³
ã³ã¿ã¯ãã¬ã³ãºã«åœ¢æã§ãäžã€ã³ã³ã¿ã¯ãã¬ã³ãº
ææãšããŠäœçšããæçµã®é«ååééåäœã圢æ
ããããšãã§ããæš¹è補åãšããŠèšåããã粟補
æçµçæç©ã§ããã ããããªå ±å æ°Žå解æäœã¯åœæ¥äžåšç¥ã§ããã
ã¢ã«ã³ãã·ã·ã©ã³ããã³ã¢ã»ããã·ã·ã©ã³ãåå¿
äœãšããŠäœ¿çšãããå Žåã«å¥œãŸããã¯ãšã¿ããŒã«
âç¡«é žè§Šåªãçšããããã奜ãŸããã¯ã·ã©ã³ã¯å°
éã®æ°Žãå«æãããšã¿ããŒã«ç¡«é žè§Šåªãçšãåèš
æäœã«ãããããã«ããŠæ··åããããåå¿æéã
ãã³æž©åºŠã¯å¥œãŸããã¯å述䞊ã³ã«ç²çæç©ã®è£œé
ã®éãã§ãããããããªåå¿ã¯ç±³åœç¹èš±ç¬¬
3808178å·ã«è©³çŽ°ã«ãããŠããã å žåçã«ã¯æ¬çºæã®åºçºææã¯æ¬¡åŒã®çš®é¡ã®å
å¿æ§ã·ã©ã³ Râ³2SiX2 Râ³3SiX ïŒåŒäžãã¯æ°ŽçŽ ãŸãã¯ã¡ãã«ã§ãããRâ²ã¯
ïŒãçŽïŒåã®ççŽ ååãæããïŒäŸ¡ã®ã¢ã«ãã¬ã³
åºã§ãããRâ³ã¯ïŒãçŽïŒåã®ççŽ ååãæãã
ïŒäŸ¡ã®çåæ°ŽçŽ ãïŒãçŽïŒåã®ççŽ ååãæãã
眮æãããïŒäŸ¡ã®çåæ°ŽçŽ åºãããšãã«åºã眮æ
ãããããšãã«åºãŸãã¯ã·ã¯ãããã·ã«åºã§ã
ããââã¯ã¯ãããã¡ããã·ããšããã·ãã¡ã
ãã·ãšããã·ãŸãã¯ã¢ã»ããã·ã®ãããªå®¹æã«å
æ°Žå解ã§ããåºã§ããïŒããéžæãããã çš®ã ã®åå¿äœã®ã¢ã«æ¯ã¯åå¿äœææ©ããªã·ãã
ãµã³ã®ååéããã³æ§é ã倧ãã«å¶åŸ¡ãããåå¿
ã®æž©åºŠããã³æº¶åªã®ååšã®ãããªãã®ä»ã®èŠçŽ ã
ãŸã補åææ©ããªã·ãããµã³ã®çµæã«åœ±é¿ããã æ¬çºæã®æ°èŠãªææ©ããªã·ãããµã³ã®ãããã
ãããç¹å®ã®çµæç©ã§ãªãå€æ§ãªååãããªãã
ããŠããæ ã«ïŒçš®ä»¥äžã®éåãåŸãåºãæããå¹³
åçãŸãã¯å žåçãªçµæç©ã«ã€ããŠèšè¿°ãããã°
ãªããªãããšãç解ãã¹ãã§ããããããæ§é ã¯
å ¬ç¥ã§ãããããŠæ··åãããæ§é ãšããŠè¿°ã¹ãã
ãããŸãã¯æã æš¹èãšããŠç¥ãããŠããã 奜ãŸããã¯ã³ã³ã¿ã¯ãã¬ã³ãºçµæç©ã¯åç¬ã§é
åããããŸãã¯ãã®ä»ã®åéäœãšå ±éåããäžé£œ
åå€å®èœæ§ææ©ããªã·ãããµã³ããæ§æããããš
ãã§ãããå ±éåäœã¯èŠªæ°Žæ§åéäœã®ãããªæ¹¿æœ€
å€ããã³ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãã®ãããªç¡¬åå€ãŸ
ãã¯äžå®ã®ãã®ä»ã®ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãª
ã¬ãŒãã®ãããªè»åå€ã§ãã硬床å€æ§å€ãæ··å ¥ã
ãããšãã§ããã æ¬çºæã§é瀺ãããçµæç©ã®ç©ççæ§è³ªã¯å€å®
èœæ§ææ©ããªã·ãããµã³æåã«ãããæ§é çå€å
ããã³ïŒãŸãã¯ã³ã¢ãããŒïŒå ±åéäœïŒã®çš®é¡ã
ãã³ããŒã»ã³ããå€åãããããšã«ããå€ããã
ãšãã§ããã æ¬çºæã®äžã€ã®æ æ§ã«ãããŠãé žçŽ ç§»éããã
éæãªãæ¬æ¥çã«æ¹¿æœ€æ§ã®ã³ã³ã¿ã¯ãã¬ã³ãºãæ¬
çºæã®ã¿ã®éåããææ©ããªã·ãããµã³æš¹èãã
äœãããã æ¬çºæã®ããäžã€ã®æ æ§ã«ãããŠãéåçµæç©
ã¯ïŒä»¥äžã®ãã®ä»ã®åéäœã«ããå ±éåããæ¬çº
æã®ææ©ããªã·ãããµã³æš¹èãããªãã ããããªãã®ä»ã®å ±éåäœã¯å¥œãŸããã¯ç¡¬åãŸ
ãã¯è»åå€ãŸãã¯èŠªæ°Žå€ã§ãããäŸãã°ç¡¬åºŠå€æ§
å€ã¯C1ãC20ã®ïŒäŸ¡ãŸãã¯å€äŸ¡ã¢ã«ã«ããŒã«ãŸã
ã¯ããšããŒã«ãšæ¬è³ªçã«ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«
é žãã€ã¿ã³ã³é žããã³ãããã®æ··åç©ãããªãé¡
ããéžæãããé žãšã®ãšã¹ãã«ã§ããåŸãã芪氎
æ§åéäœã¯åŸè¿°ããããã«å€ãã®ç°ãªãææãã
ãªãããšãã§ããã å ±åéäœãçšããããå Žåãæ¬çºæã®éåçµæ
ç©ã¯å¥œãŸããã¯æ £çšã®éé¢åºéåæè¡ã«ãã調補
ããããéé¢åºéå§å€ã¯25âã125âã®åå¿æž©åºŠ
ã«ãããŠå šçµæç©ã®0.01ã2.0ééïŒ ã®éã§æ··å ¥
ãããŠéåãéå§ãäžã€å®äºãããæ £çšã®ãã«ã¯
éåæäœã¯ã³ã³ã¿ã¯ãã¬ã³ãºã補é ããããã«æ £
çšã®æäœã§æ©æ¢°ã«ããäžã€ç£šãããšãã§ããé³ç©
ã補é ããããã«äœ¿çšããããšãã§ãããå¥æ³ãš
ããŠéåãã³ã³ã¿ã¯ãã¬ã³ãºé³åäžã§çŽæ¥å®æœã
ãããšãã§ãããåºçºæš¹èç³»ã¯å¥œãŸããã¯éé¢åº
觊åªã«ãã95ïŒ ä»¥äžã®éæãŸã§éåããã å€å®èœæ§ææ©ããªã·ãããµã³æš¹èã¯é«åºŠã®é žçŽ
ééæ§ãäžããããšãã§ããäžæ¹ã匷床ããã³ã
ã€ãªé©åæ§ã¯å ±åéäœãçšããå Žåã«å ±éåäœã®
ãã®ä»ã®éšåã«ããäžããããšãã§ãããã¡ã¿ã¯
ãªã¬ãŒããŸãã¯ã¢ã¯ãªã¬ãŒããšã¹ãã«ã®äœ¿çšã¯è¥
å¹²ã®å Žåã«ããã匷床ããã³ç¡¬åºŠãŸãã¯åŒŸæ§ãäž
ããã芪氎æ§åéäœã®æ··å ¥ã¯ææã®æ¹¿æœ€æ§ã倧ã
ãå¢å€§ããŠãã€ãªé©åæ§ãéæããããšãã§ã
ãã æ¬çºæã®æ°èŠãªæš¹èçµæç©ã¯è€æ°ã®äžé£œåéå
ãåŸãåºãå«æããææ©ããªã·ãããµã³ãã調補
ããããå åŠçã³ã³ã¿ã¯ãã¬ã³ãºã¯ã³ã³ã¿ã¯ãã¬
ã³ãºã«ææãããç©ççããã³ååŠçæ§è³ªã®é©åœ
ãªãã©ã³ã¹ãäžããããã«å¥œãŸããã¯ãã®ä»ã®å ±
åéäœãæ··å ¥ãããããã®æš¹èç³»åéäœã®éåäœ
ããçµç«ãŠããããå žåçã«ã¯æ¬çºæã«æçšãªå€
å®èœæ§ææ©ããªã·ãããµã³æš¹èç³»ã¯åç¬ã§éåã
äžã€ã³ã³ã¿ã¯ãã¬ã³ãºã圢æããããšãã§ããã
ãŸãã¯ãã®ä»ã®ææ©æåãšå ±éåããããšãã§ã
ãããŠæ¬¡åŒ ïŒåŒäžãâïœâã¯0.10ã0.40ã®ã¢ã«ãã©ã¯ã·ãš
ã³å€ãæããâïœâã¯0.25ã0.80ã®ã¢ã«ãã©ã¯ã·
ãšã³å€ãæããããŠâïœâã¯0.10ã0.40ã®ã¢ã«ã
ã©ã¯ã·ãšã³å€ãæããïŒ ãæããŠããã æ¬çºæã®ã¬ã³ãºçµæç©äžã«å€å®èœæ§ææ©ããªã·
ãããµã³ãšå ±ã«çšããå ±åéäœã¯éé¢åºéåãè¡
ãªãããšãã§ãäžã€æ©æ¢°é©æ§ãèä¹ æ§ããã³ãã€
ãªé©åæ§ã®ãããªæãŸããæ§è³ªãé«ãããããã
ã®éåãåŸãåéäœã§ããåŸãã æ¬çºæã«ããæçšã«çšããããšãã§ããå ±åé
äœã®èª¬æã以äžã«è¡ãªãã 奜ãŸããã¯å ±åéäœã¯C1ãC20ã®ïŒäŸ¡ãŸãã¯å€
䟡ã®ã¢ã«ã«ããŒã«ãŸãã¯ããšããŒã«ãšæ¬è³ªçã«ã¢
ã¯ãªã«é žããã³ã¡ã¿ã¯ãªã«é žãããªãé¡ããéžæ
ãããé žãšã®ãšã¹ãã«ã®ãããªç¡¬åå€ãŸãã¯è»å
å€ã§ããåŸããã€ã¿ã³ããŒãã¢ãâãŸãã¯ãžâãš
ã¹ãã«ã®ãããªèŠªæ°Žæ§ç¡¬åå€ããã®ä»ã«çšããã
ãšãã§ããã ã¡ãã«ããšãã«ããããã«ãïœâããã«ãã€ãœ
ãããã«ãããã·ã«ããããã«ãã·ã¯ãããã·
ã«ãïŒâãšãã«ããã·ã«ããšããã·ãšãã«ããã
ãã·ãšãã«ãïŒâããããã·ãšãã«ãïŒâãŸãã¯
ïŒâããããã·ãããã«ãïŒâã¡ããã·âïŒâã
ãããã·ãããã«ãããã©ããããã«ããªã«ãã¢
ãªãŒã«ãã¢ãªã«ãã°ãªã·ããã·ã®ãããªã¢ã¯ãªã«
é žãã¡ã¿ã¯ãªã«é žããã³ã€ã¿ã³ã³é žã®èªå°äœãæ
çšã§ããã ãã®ä»ã®å ±åéäœã¯ïŒ®âããã«ã«ã«ããŸãŒã«ã
âããã«ãããªãã³ãããããã·ãããã«ã¡ã¿
ã¯ãªã¬ãŒããã¹ããªã«ãäŸãã°ã¹ãã¬ã³ãã¡ãã«
ã¹ãã¬ã³ãã¡ããã·ã¹ãã¬ã³ããã³ã¢ã»ããã·ã¹
ãã¬ã³ãå å«ããã ã¢ã«ãªã«æ§åéäœãäŸãã°ãžã¢ãªã«ãžã°ãªã³ãŒ
ã«ãžã«ãŒãããŒãããžã¢ãªã«ãã¿ã¬ãŒãããžã¢ãª
ã«ã«ãŒãããŒãããã³ããªã¢ãªã«ã·ã¢ãã¬ãŒãã
ãŸãæçšãªå ±åéäœã§ããã æ¬çºæã§é瀺ãããçµæç©ã®æ¹¿æœ€æ§ã¯èŠªæ°Žæ§äž
æ§åéäœã芪氎æ§ã«ããªã³æ§åéäœããã³èŠªæ°Žæ§
ã¢ããªã³æ§åéäœããã³ãããã®æ··åç©ãå å«ã
ãããšã§é«ããããšãã§ããããããã®ãã®ã¯å š
ãŠæ¹¿æœ€å€ãšããŠäœçšããããããååç©ã®é¡ã¯èŠª
æ°Žæ§ã¢ã¯ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒããã¢ã¯ãª
ã«ã¢ãããã¡ã¿ã¯ãªã«ã¢ããããã³ããã«âã©ã¯
ã¿ã ã§ããã 芪氎æ§è³ªãæ¬çºæã®ã³ã³ã¿ã¯ãã¬ã³ãºææã®è¡š
é¢ã«åäžãã代衚çãªèŠªæ°Žæ§äžæ§åéäœã¯ïŒ®âã
ãã«ãããªãã³ãã¢ã¯ãªã«ã¢ãããã¡ã¿ã¯ãªã«ã¢
ãããïŒïŒ®âãžã¡ãã«ã¢ã¯ãªã«ã¢ãããŸãã¯ã¡
ã¿ã¯ãªã«ã¢ãããïŒâããããã·ãšãã«ã¢ã¯ãªã¬
ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒããïŒâãŸãã¯ïŒâãã
ããã·ãããã«ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒ
ããã°ãªã»ãªã«ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒ
ããã°ãªã·ãžã«ã¢ã¯ãªã¬ãŒããŸãã¡ã¿ã¯ãªã¬ãŒ
ããäžè¬åŒHOïŒCoH2oïŒxïŒåŒäžãâïœâã¯ïŒã
çŽïŒã®æ°ã§ãããããŠâïœâã¯ïŒãçŽ10ã®æ°ã§ã
ããïŒã®ããªãšãŒãã«ãšã¢ã¯ãªã«é žããã³ã¡ã¿ã¯
ãªã«é žãšã®ïŒâã¡ããâïŒâããããã·ãããã«
ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒãã¢ããšã¹ãã«
ãå å«ããã ã«ããªã³æ§èŠªæ°Žæ§åéäœã¯åœå垯é»ç¶æ ã«ãã
åŸãããŸãã¯ã³ã³ã¿ã¯ãã¬ã³ãºã®åœ¢æåŸãåŒç¶ã
ãŠåž¯é»ç¶æ ã«å€æãããããããååç©ã®é¡ã¯å¡©
åºæ§ãŸãã¯ã«ããªã³æ§ã¢ã¯ãªã¬ãŒããã¡ã¿ã¯ãªã¬
ãŒããã¢ã¯ãªã«ã¢ãããã¡ã¿ã¯ãªã«ã¢ããããã
ã«ããªãžã³ãããã«ã€ãããŸãŒã«ããã³ãžã¢ã«ãª
ã«ãžã¢ã«ãã«ã¢ã³ã¢ããŠã éåæ§åºã«ç±æ¥ããã
ããããªåéäœã¯ïŒ®ïŒïŒ®âãžã¡ãã«ã¢ãããšãã«
ã¢ã¯ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒããïŒâã¡ã¿ã¯
ãªã«ãªãã·ãšãã«ããªã¡ãã«ã¢ã³ã¢ããŠã ã¯ããª
ãããã³ã¡ãã«ã¹ã«ããšãŒããïŒâïŒïŒâããã³
ïŒâã¡ãã«ââïŒâããã«ããªãžã³ãïŒâïŒïŒâ
ããã³ïŒâã¡ãã«ââïŒâããã«ããªãžããŠã ã¯
ããªãããã³ã¡ãã«ã¹ã«ããšãŒããâïŒïŒâã¡
ã¿ã¯ãªã«ã¢ãããããã«ïŒâïŒïŒ®âãžã¡ãã«ã¢
ãã³ãâïŒïŒâã¡ã¿ã¯ãªã«ã¢ãããããã«ïŒâ
ïŒïŒ®ïŒïŒ®âããªã¡ãã«ã¢ã³ã¢ããŠã ã¯ããªãã
âïŒïŒâã¡ã¿ã¯ãªã«ãªãã·âïŒâããããã·ã«
ãããã«ïŒâïŒïŒ®ïŒïŒ®âããªã¡ãã«ã¢ã³ã¢ããŠ
ã ã¯ããªãããžã¢ã«ãªã«ãžã¡ãã«ã¢ã³ã¢ããŠã ã¯
ããªãããã³ã¡ãã«ã¹ã«ããšãŒãã«ããè¡šããã
ãã ã¢ããªã³æ§èŠªæ°Žæ§åéäœã¯åœåäžæ§ã®ç¶æ ã§ã
ããåŸã§ã¢ããªã³æ§ç¶æ ã«å€æãããããããã®
é¡ã®ååç©ã¯ã«ã«ããã·ãã¹ã«ããªããŒãããã³
ãã¹ããšãŒããŸãã¯ãã¹ããšãŒãåºãå«æããé
åæ§åéäœãå å«ãããããããªåéäœã¯ã¢ã¯ãª
ã«é žãã¡ã¿ã¯ãªã«é žããããªãŠã ã¢ã¯ãªã¬ãŒãã
ãã³ã¡ã¿ã¯ãªã¬ãŒããããã«ã¹ã«ããªã³é žããã
ãªãŠã ããã«ã¹ã«ãããŒããïœâã¹ãã¬ã³ã¹ã«ã
ãªã³é žããããªãŠã ïœâã¹ãã¬ã³ã¹ã«ããªããŒ
ããïŒâã¡ã¿ã¯ãªãã€ã«ãªãã·ãšãã«ã¹ã«ããªã³
é žãïŒâã¡ã¿ã¯ãªãã€ã«ãªãã·âïŒâããããã·
ãããã«ã¹ã«ããªã³é žãïŒâã¢ã¯ãªã«ã¢ããâïŒ
âã¡ãã«ãããã³ã¹ã«ãã³é žãã¢ã«ãªã«ã¹ã«ããª
ã³é žãïŒâãã¹ãã¢ããšãã«ã¡ã¿ã¯ãªã¬ãŒãã«ã
ãè¡šããããã å ±åéäœãæ¬çºæã®æš¹èç³»ãšå ±ã«çšããããå Ž
åããããã¯éãå€ããŠäœ¿çšãããã次ã®è¡šã¯å¯
èœãªçŸåçããã³åŠæ¹ã説æãããã®ã§ããã
ã³ã¿ã¯ãã¬ã³ãºã¯è§èãžã®å åãªé žçŽ 移éãäžã
ãããã«å®è³ªçãªå«éã®ãªã«ã¬ãã·ãããµã³ãå¿
èŠãšããŠããã äžè¬ã«ææ©ã·ãããµã³ååã¯ãã®ä»ã®åéäœã
å«ãå€ãã®çµæç©äžã§äž¡ç«ã§ããªãåŸåãããã
äŸãã°ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãã«ææ©ã·ãããµã³ã
溶解ããããŠåèšæº¶æ¶²ãéåããããšã¯ãã°ãã°
ã³ã³ã¿ã¯ãã¬ã³ãºçšãšããŠäžé©åœãªäžéæã®ææ
ãããããã å è¡æè¡ã¯äžé£œåã®éåãåŸãåºã«ååŠçã«çµ
åããçãææ©ã·ãããµã³åäœãããããªææ©ã·
ãããµã³åéäœããã®ä»ã®åéäœãšå ±éåããŠäž¡
ç«å¯èœã§äžã€ããæ ã«éæãªææã«éããæ段ã
æäŸããããšã瀺ããŠããã äžæ¹ããã äžçš®ã®äžé£œåã®éåãåŸãåºã®ã¿ã
å«æããææ©ã·ãããµã³åäœã¯ãã®ä»ã®åéäœã
ãšãã«èŠªæ°Žåéäœãšå ±éåããå Žåã«ãã°ãã°ã©
ã³ãã ãªå ±éåäœãäžããªãããã®ç¶æ ã¯çžåé¢
ããã³äžéæææã«å°ããäžå®ã®å Žåã«ãçžåé¢
ã¯èŠèŠçã«æ¢ç¥ã§ããªããããããææã®ç©çç
æ§è³ªã¯èšŒæãããŠããããã®ç¶æ ã¯ãããç¿æ§ãš
ç Žç ã«å¯Ÿããæ§è³ªã瀺ãææãäžããããšãã§ã
ãã ãžã¡ãã«ã·ãããµã³ãžã¢ã¯ãªã¬ãŒããªãªãŽããŒ
ãã調補ãããé«åºŠã«äº€åçµåããéåäœã®ç©ç
çæ§è³ªã¯åœæ¥äžå ¬ç¥ã§ãããäžè¬ã«ã埮çžåé¢ã¯
ãã¬éåäœã«ããããžã¡ãã«ã·ãããµã³åºã®éã
å¢å ããå Žåã«æããããããã®çŸè±¡ã¯é·ãææ©
é åã®æ¬ é€ã«èµ·å ããŠãããå šäœã«ã«ãã
ïŒKatzïŒã®æ¥ç©ãJ.Polym.Sci.Chem.Ed.16(3)597
ïŒ1978ïŒãã¯ãææ©çé åãçžåé¢ã«å¯Ÿããå å°ã
è¡ãªããæ ã«ããããªåå¿æ§ææ©ã·ãããµã³åé
äœã«å ±éåã«å察ã§ãããšæ瀺ããŠãããããã
ãªããã³ã³ã¿ã¯ãã¬ã³ãºææã«ãããŠãç©ççæ§
質ã®é©åœãªãã©ã³ã¹ãã¯ããããã«ïŒçš®ä»¥äžã®å ±
éåäœãå å«ããããšãæãŸããããšãç¥ãããŠ
ããã ããæ ãã³ã³ã¿ã¯ãã¬ã³ãºé©çšã®ããã«äž¡ç«ã§
ããææ©ã·ãããµã³åäœã®å®è³ªçãªéãå«æãã
ã©ã³ãã ãªå ±éåäœãæäŸããããšãæãŸããã
æ¬çºæã¯å€éäžé£œåã®éåãåŸãåºãå«æããå
å²ç¶ææ©ã·ãããµã³æ§é ãå©çšããããããã®æ
æã¯ãã®ä»ã®åéäœãšå ±éåããå Žåãéæã§ã
é«åºŠã«é žçŽ ééæ§ã§èä¹ æ§ã®ããçµæç©ãæäŸã
ããéåããã»ã¹ã®ã©ã³ãã ãªæ§è³ªã¯å€éã®äžé£œ
åéåãåŸãåºã®ååšã«ãã€ãŠé«ãããããé瀺
ãããææ©ããªã·ãããµã³åéäœã®äž¡ç«åã¯é«åºŠ
ã«åæããææ©ããªã·ãããµã³åã®å©çšã«ãã€ãŠ
æ¹åãããã æ¬çºæã®ç®çã¯ããåç¬ã§ãŸãã¯ãã®ä»ã®ææ©
ææãšçµåãããŠã³ã³ã¿ã¯ãã¬ã³ãºã圢æããã®
ã«æçšãªæ°èŠãªäžé£œåå€å®èœæ§ææ©ããªã·ãããµ
ã³ãæäŸããããšã§ããã æ¬çºæã®ããäžã€ã®ç®çã¯ã·ãããµã³ãåç¬ã§
ãŸãã¯ãã®ä»ã®ææ©ææãšçµåããŠäœ¿çšããããš
ãã§ããã³ã³ã¿ã¯ãã¬ã³ãºã®åœ¢ã§äžé£œåå€å®èœæ§
ææ©ããªã·ãããµã³ã®éååç©ãæäŸããããšã§
ããã ããã«æ¬çºæã®ç®çã¯é žçŽ ééæ§ã寞æ³å®å®
çã芪氎æ§äžã€è¯å¥œãªå åŠçéææ§ããã³æãã
ããããæ¬çºæã«åºã¥ãã³ã³ã¿ã¯ãã¬ã³ãºææã
ãã³ã³ã³ã¿ã¯ãã¬ã³ãºãæäŸããããšã§ããã æ¬çºæã®ããã«ããäžã€ã®ç®çã¯é¡èãªç¡¬ããŸ
ãã¯å硬æ§ã®é žçŽ ééæ§ã¬ã³ãºãæ £çšã®ææ©ã·ã
ããµã³å«æã³ã³ã¿ã¯ãã¬ã³ãºã«æ¯èŒããå Žåã«ã
ãããæžå°ããŠè¯å¥œãªåŒ·åºŠãæããŠåœ¢æãããå
èšç®çã«åºã¥ãã³ã³ã¿ã¯ãã¬ã³ãºãæäŸããããš
ã§ããã æ¬çºæã¯ãããã®ç®çãéæããããã®ãã®ã§
ãã€ãŠãæ¬¡åŒ ïŒåŒäžãâïœâã¯0.10ã0.40ã®ã¢ã«ãã©ã¯ã·ãš
ã³å€ãæããâïœâã¯0.25ã0.80ã®ã¢ã«ãã©ã¯ã·
ãšã³å€ãæããããŠâïœâã¯0.10ã0.40ã®ã¢ã«ã
ã©ã¯ã·ãšã³å€ãæããïŒ ã§è¡šããããæš¹èç³»ã®éåäœãå«ãã§æãã³ã³ã¿
ã¯ãã¬ã³ãºææãæäŸãããã®ã§ããã äžå®ã®å¥œãŸããæ æ§ã«ãããŠã³ã³ã¿ã¯ãã¬ã³ãº
ææã¯ïœïŒ0.20ã0.35ã¢ã«ãã©ã¯ã·ãšã³ãïœïŒ
0.40ã0.60ã¢ã«ãã©ã¯ã·ãšã³ãïœïŒ0.20ã0.40ã¢
ã«ãã©ã¯ã·ãšã³ã«ãã30ã60ééïŒ ãã¡ãã«ã¡ã¿
ã¯ãªã¬ãŒã69ã40ééïŒ ããã³ããã«ãããªã
ã³ãã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãŸãã¯ãããã®æ··
åç©ïŒã10ééïŒ ã®éã«ãããŠåèšåŒã®ç¬¬ïŒæå
ããéé¢åºéååã«ãã95ïŒ ãŸãã¯ãã以äžãŸã§
éåããŠããæåã®æ··åç©ãšå ±ã«æããŠããã æ¬çºæã®ææããäœãããã³ã³ã¿ã¯ãã¬ã³ãºã¯
奜ãŸããã¯ç¡¬æ§ãŸãã¯å硬æ§ã§ãããæ £çšã®æ段
ã§å®¹æã«çµç«ãŠããäžã€ä»äžããããåè¶ãã寞
æ³å®å®æ§ãæããé©åœãªå±æçã§æ¬æ¥æ¹¿æœ€æ§ã§ã
ããããŠè¯å¥œãªå äŒéæ§è³ªãæããããšãæ¬çºæ
ã®ç¹åŸŽã§ããããããã¬ã³ãºã¯èä¹ æ§ããããè¯
奜ãªé žçŽ ééæ§ãæããŠãããç®ãšã®ãã€ãªé©å
æ§ããããå®è³ªçã«éæ°Žåæ§ã§ãããååŠçã«å®
å®ã§ãåççãªåŒæ»ãæµææ§ãšå ±ã«èçœèç©ã«å¯Ÿ
ããæµææ§ãæããŠããããããã®ãã®ã䜿çšè
ã¯å»¶é·ãããæéã®éãå®å šäžã€å¿«é©ã«ãããã
ãšãã§ããäžæ¹ã䜿çšè ã«è¯å¥œãªèŠèŠãæäŸã
ãããã®ããšã¯ã¬ã³ãºåæ±ãã®æéãå°ãããäž
ã€ä»åŸã®ç掻ã倧ããæ¹åããã æ¬çºæã®æ°èŠãªææ©ããªã·ãããµã³ã®ãããã
ãå€çš®é¡ã®ååããæ§æãããäžçš®ã®ç¹æ®ãªçµæ
ç©ã§ã¯ãªããããŠããæ ã«æããã¯äžçš®ä»¥äžã®é
åãåŸãåºãæããå¹³åçãŸãã¯å žåççµæç©ãš
ããŠè¿°ã¹ãããããšãç解ãã¹ãã§ãããããã
æ§é ã¯å ¬ç¥ã§ãããããŠæ··åãããæ§é ãšããŠè¿°
ã¹ãããããŸãã¯ãããªãã°æš¹èãšããŠç¥ããäž
ã€è¿°ã¹ãããŠããã æš¹èãŸãã¯æš¹èç³»ãšããŠèšèŒããããšãã§ãã
æ¬çºæã®ïŒçš®ã®åäœäžé£œåå€å®èœæ§ææ©ããªã·ã
ããµã³ã¯åœæ¥äžåšç¥ã®å€æ§ãªåå¿æè¡ãå©çšããŠ
調補ããããšãã§ãããæã奜ãŸããã¯ã¯ããã·
ã©ã³ãŸãã¯ã¢ã«ã³ãã·ã·ã©ã³äžéäœã䜿çšããã
å ±å æ°Žå解ã«ãŒãã§ãããå ±å æ°Žå解åå¿ã¯ã¡ã¿
ããŒã«ãŸãã¯ãšã¿ããŒã«ã®ãããªæ°Žæ··åæ§æº¶åªã®
ååšäžäžŠã³ã«ãžãšãã«ãšãŒãã«ããžããã«ãšãŒã
ã«ããã«ãšã³ããããµãŸãã¯ã¯ããããªã«ã ã®ã
ããªæ°Žæµžæ§æº¶åªã®ååšäžå®æœããããšãã§ããã ãšã¿ããŒã«ïŒç¡«é žè§Šåªç³»ãšå ±ã«ã¢ã»ããã·ã·ã©
ã³äžéäœã®äœ¿çšããŸãæ¬çºæã®äžé£œåå€å®èœåºæ
æ©ããªã·ãããµã³ã補é ããããã«è¡ãªãããã å ±å æ°Žå解ã«ãããŠãåå¿äœã®æ··åç©ã¯æçµè£œ
åã«ææãããã¢ã«ãã©ã¯ã·ãšã³ãæäŸãããã
ã«éžæãããåã ã®éã§éžæããããããããŠ
âïœâïŒâïœâããã³âïœâã«ã€ããŠäžè¿°ãããã
ã«ã¢ã«ãã©ã¯ã·ãšã³ã¯åç²åçµæã«ãããæ§é ç
å¶éãæããã«ãããææ©æº¶åªã®å¯èœãªå å«ã«ã
ãæ°Žäžåå¿äœã®ã¹ã©ãªãŒãåœæ¥äžç¥ãããéãã«
ã€ãã€ããå æ°Žå解ããã³çž®åãçããããã«å
åãªæéããšããããïŒæéããïŒæ¥ã®å žåçãª
æéãâ20ã98âã®æž©åºŠãããŠäžå±€å¥œãŸããã¯å®€
æž©ã«ãããŠéæãããããã«çšãããããææ©çž
ã¯åœ¢æããã補åãéã³ãããŠææ©çžãæ°Žãšæ··å
ã§ããªãæ ã«æ°Žããåé¢ãããäœååéã®å¯çç©
ã奜ãŸããã¯åœæ¥äžå ¬ç¥ã®ç±ããã³ç空ãå©çšã
ãããšã«ããææ©çžããåãé€ãããçŽ200以äž
ã®ååéãé€ããããå¯çç©é€å»åŸæ®ã€ãŠããç²
çæç©ãå¡©åºæ§æº¶æ¶²ã§æœåºããæ°ŽæŽããããŠæ¬¡ã
ã§ä¹Ÿç¥ããããããŠãã®ãã®ã¯ããã«åå¿ããŠã³
ã³ã¿ã¯ãã¬ã³ãºã«åœ¢æã§ãäžã€ã³ã³ã¿ã¯ãã¬ã³ãº
ææãšããŠäœçšããæçµã®é«ååééåäœã圢æ
ããããšãã§ããæš¹è補åãšããŠèšåããã粟補
æçµçæç©ã§ããã ããããªå ±å æ°Žå解æäœã¯åœæ¥äžåšç¥ã§ããã
ã¢ã«ã³ãã·ã·ã©ã³ããã³ã¢ã»ããã·ã·ã©ã³ãåå¿
äœãšããŠäœ¿çšãããå Žåã«å¥œãŸããã¯ãšã¿ããŒã«
âç¡«é žè§Šåªãçšããããã奜ãŸããã¯ã·ã©ã³ã¯å°
éã®æ°Žãå«æãããšã¿ããŒã«ç¡«é žè§Šåªãçšãåèš
æäœã«ãããããã«ããŠæ··åããããåå¿æéã
ãã³æž©åºŠã¯å¥œãŸããã¯å述䞊ã³ã«ç²çæç©ã®è£œé
ã®éãã§ãããããããªåå¿ã¯ç±³åœç¹èš±ç¬¬
3808178å·ã«è©³çŽ°ã«ãããŠããã å žåçã«ã¯æ¬çºæã®åºçºææã¯æ¬¡åŒã®çš®é¡ã®å
å¿æ§ã·ã©ã³ Râ³2SiX2 Râ³3SiX ïŒåŒäžãã¯æ°ŽçŽ ãŸãã¯ã¡ãã«ã§ãããRâ²ã¯
ïŒãçŽïŒåã®ççŽ ååãæããïŒäŸ¡ã®ã¢ã«ãã¬ã³
åºã§ãããRâ³ã¯ïŒãçŽïŒåã®ççŽ ååãæãã
ïŒäŸ¡ã®çåæ°ŽçŽ ãïŒãçŽïŒåã®ççŽ ååãæãã
眮æãããïŒäŸ¡ã®çåæ°ŽçŽ åºãããšãã«åºã眮æ
ãããããšãã«åºãŸãã¯ã·ã¯ãããã·ã«åºã§ã
ããââã¯ã¯ãããã¡ããã·ããšããã·ãã¡ã
ãã·ãšããã·ãŸãã¯ã¢ã»ããã·ã®ãããªå®¹æã«å
æ°Žå解ã§ããåºã§ããïŒããéžæãããã çš®ã ã®åå¿äœã®ã¢ã«æ¯ã¯åå¿äœææ©ããªã·ãã
ãµã³ã®ååéããã³æ§é ã倧ãã«å¶åŸ¡ãããåå¿
ã®æž©åºŠããã³æº¶åªã®ååšã®ãããªãã®ä»ã®èŠçŽ ã
ãŸã補åææ©ããªã·ãããµã³ã®çµæã«åœ±é¿ããã æ¬çºæã®æ°èŠãªææ©ããªã·ãããµã³ã®ãããã
ãããç¹å®ã®çµæç©ã§ãªãå€æ§ãªååãããªãã
ããŠããæ ã«ïŒçš®ä»¥äžã®éåãåŸãåºãæããå¹³
åçãŸãã¯å žåçãªçµæç©ã«ã€ããŠèšè¿°ãããã°
ãªããªãããšãç解ãã¹ãã§ããããããæ§é ã¯
å ¬ç¥ã§ãããããŠæ··åãããæ§é ãšããŠè¿°ã¹ãã
ãããŸãã¯æã æš¹èãšããŠç¥ãããŠããã 奜ãŸããã¯ã³ã³ã¿ã¯ãã¬ã³ãºçµæç©ã¯åç¬ã§é
åããããŸãã¯ãã®ä»ã®åéäœãšå ±éåããäžé£œ
åå€å®èœæ§ææ©ããªã·ãããµã³ããæ§æããããš
ãã§ãããå ±éåäœã¯èŠªæ°Žæ§åéäœã®ãããªæ¹¿æœ€
å€ããã³ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãã®ãããªç¡¬åå€ãŸ
ãã¯äžå®ã®ãã®ä»ã®ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãª
ã¬ãŒãã®ãããªè»åå€ã§ãã硬床å€æ§å€ãæ··å ¥ã
ãããšãã§ããã æ¬çºæã§é瀺ãããçµæç©ã®ç©ççæ§è³ªã¯å€å®
èœæ§ææ©ããªã·ãããµã³æåã«ãããæ§é çå€å
ããã³ïŒãŸãã¯ã³ã¢ãããŒïŒå ±åéäœïŒã®çš®é¡ã
ãã³ããŒã»ã³ããå€åãããããšã«ããå€ããã
ãšãã§ããã æ¬çºæã®äžã€ã®æ æ§ã«ãããŠãé žçŽ ç§»éããã
éæãªãæ¬æ¥çã«æ¹¿æœ€æ§ã®ã³ã³ã¿ã¯ãã¬ã³ãºãæ¬
çºæã®ã¿ã®éåããææ©ããªã·ãããµã³æš¹èãã
äœãããã æ¬çºæã®ããäžã€ã®æ æ§ã«ãããŠãéåçµæç©
ã¯ïŒä»¥äžã®ãã®ä»ã®åéäœã«ããå ±éåããæ¬çº
æã®ææ©ããªã·ãããµã³æš¹èãããªãã ããããªãã®ä»ã®å ±éåäœã¯å¥œãŸããã¯ç¡¬åãŸ
ãã¯è»åå€ãŸãã¯èŠªæ°Žå€ã§ãããäŸãã°ç¡¬åºŠå€æ§
å€ã¯C1ãC20ã®ïŒäŸ¡ãŸãã¯å€äŸ¡ã¢ã«ã«ããŒã«ãŸã
ã¯ããšããŒã«ãšæ¬è³ªçã«ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«
é žãã€ã¿ã³ã³é žããã³ãããã®æ··åç©ãããªãé¡
ããéžæãããé žãšã®ãšã¹ãã«ã§ããåŸãã芪氎
æ§åéäœã¯åŸè¿°ããããã«å€ãã®ç°ãªãææãã
ãªãããšãã§ããã å ±åéäœãçšããããå Žåãæ¬çºæã®éåçµæ
ç©ã¯å¥œãŸããã¯æ £çšã®éé¢åºéåæè¡ã«ãã調補
ããããéé¢åºéå§å€ã¯25âã125âã®åå¿æž©åºŠ
ã«ãããŠå šçµæç©ã®0.01ã2.0ééïŒ ã®éã§æ··å ¥
ãããŠéåãéå§ãäžã€å®äºãããæ £çšã®ãã«ã¯
éåæäœã¯ã³ã³ã¿ã¯ãã¬ã³ãºã補é ããããã«æ £
çšã®æäœã§æ©æ¢°ã«ããäžã€ç£šãããšãã§ããé³ç©
ã補é ããããã«äœ¿çšããããšãã§ãããå¥æ³ãš
ããŠéåãã³ã³ã¿ã¯ãã¬ã³ãºé³åäžã§çŽæ¥å®æœã
ãããšãã§ãããåºçºæš¹èç³»ã¯å¥œãŸããã¯éé¢åº
觊åªã«ãã95ïŒ ä»¥äžã®éæãŸã§éåããã å€å®èœæ§ææ©ããªã·ãããµã³æš¹èã¯é«åºŠã®é žçŽ
ééæ§ãäžããããšãã§ããäžæ¹ã匷床ããã³ã
ã€ãªé©åæ§ã¯å ±åéäœãçšããå Žåã«å ±éåäœã®
ãã®ä»ã®éšåã«ããäžããããšãã§ãããã¡ã¿ã¯
ãªã¬ãŒããŸãã¯ã¢ã¯ãªã¬ãŒããšã¹ãã«ã®äœ¿çšã¯è¥
å¹²ã®å Žåã«ããã匷床ããã³ç¡¬åºŠãŸãã¯åŒŸæ§ãäž
ããã芪氎æ§åéäœã®æ··å ¥ã¯ææã®æ¹¿æœ€æ§ã倧ã
ãå¢å€§ããŠãã€ãªé©åæ§ãéæããããšãã§ã
ãã æ¬çºæã®æ°èŠãªæš¹èçµæç©ã¯è€æ°ã®äžé£œåéå
ãåŸãåºãå«æããææ©ããªã·ãããµã³ãã調補
ããããå åŠçã³ã³ã¿ã¯ãã¬ã³ãºã¯ã³ã³ã¿ã¯ãã¬
ã³ãºã«ææãããç©ççããã³ååŠçæ§è³ªã®é©åœ
ãªãã©ã³ã¹ãäžããããã«å¥œãŸããã¯ãã®ä»ã®å ±
åéäœãæ··å ¥ãããããã®æš¹èç³»åéäœã®éåäœ
ããçµç«ãŠããããå žåçã«ã¯æ¬çºæã«æçšãªå€
å®èœæ§ææ©ããªã·ãããµã³æš¹èç³»ã¯åç¬ã§éåã
äžã€ã³ã³ã¿ã¯ãã¬ã³ãºã圢æããããšãã§ããã
ãŸãã¯ãã®ä»ã®ææ©æåãšå ±éåããããšãã§ã
ãããŠæ¬¡åŒ ïŒåŒäžãâïœâã¯0.10ã0.40ã®ã¢ã«ãã©ã¯ã·ãš
ã³å€ãæããâïœâã¯0.25ã0.80ã®ã¢ã«ãã©ã¯ã·
ãšã³å€ãæããããŠâïœâã¯0.10ã0.40ã®ã¢ã«ã
ã©ã¯ã·ãšã³å€ãæããïŒ ãæããŠããã æ¬çºæã®ã¬ã³ãºçµæç©äžã«å€å®èœæ§ææ©ããªã·
ãããµã³ãšå ±ã«çšããå ±åéäœã¯éé¢åºéåãè¡
ãªãããšãã§ãäžã€æ©æ¢°é©æ§ãèä¹ æ§ããã³ãã€
ãªé©åæ§ã®ãããªæãŸããæ§è³ªãé«ãããããã
ã®éåãåŸãåéäœã§ããåŸãã æ¬çºæã«ããæçšã«çšããããšãã§ããå ±åé
äœã®èª¬æã以äžã«è¡ãªãã 奜ãŸããã¯å ±åéäœã¯C1ãC20ã®ïŒäŸ¡ãŸãã¯å€
䟡ã®ã¢ã«ã«ããŒã«ãŸãã¯ããšããŒã«ãšæ¬è³ªçã«ã¢
ã¯ãªã«é žããã³ã¡ã¿ã¯ãªã«é žãããªãé¡ããéžæ
ãããé žãšã®ãšã¹ãã«ã®ãããªç¡¬åå€ãŸãã¯è»å
å€ã§ããåŸããã€ã¿ã³ããŒãã¢ãâãŸãã¯ãžâãš
ã¹ãã«ã®ãããªèŠªæ°Žæ§ç¡¬åå€ããã®ä»ã«çšããã
ãšãã§ããã ã¡ãã«ããšãã«ããããã«ãïœâããã«ãã€ãœ
ãããã«ãããã·ã«ããããã«ãã·ã¯ãããã·
ã«ãïŒâãšãã«ããã·ã«ããšããã·ãšãã«ããã
ãã·ãšãã«ãïŒâããããã·ãšãã«ãïŒâãŸãã¯
ïŒâããããã·ãããã«ãïŒâã¡ããã·âïŒâã
ãããã·ãããã«ãããã©ããããã«ããªã«ãã¢
ãªãŒã«ãã¢ãªã«ãã°ãªã·ããã·ã®ãããªã¢ã¯ãªã«
é žãã¡ã¿ã¯ãªã«é žããã³ã€ã¿ã³ã³é žã®èªå°äœãæ
çšã§ããã ãã®ä»ã®å ±åéäœã¯ïŒ®âããã«ã«ã«ããŸãŒã«ã
âããã«ãããªãã³ãããããã·ãããã«ã¡ã¿
ã¯ãªã¬ãŒããã¹ããªã«ãäŸãã°ã¹ãã¬ã³ãã¡ãã«
ã¹ãã¬ã³ãã¡ããã·ã¹ãã¬ã³ããã³ã¢ã»ããã·ã¹
ãã¬ã³ãå å«ããã ã¢ã«ãªã«æ§åéäœãäŸãã°ãžã¢ãªã«ãžã°ãªã³ãŒ
ã«ãžã«ãŒãããŒãããžã¢ãªã«ãã¿ã¬ãŒãããžã¢ãª
ã«ã«ãŒãããŒãããã³ããªã¢ãªã«ã·ã¢ãã¬ãŒãã
ãŸãæçšãªå ±åéäœã§ããã æ¬çºæã§é瀺ãããçµæç©ã®æ¹¿æœ€æ§ã¯èŠªæ°Žæ§äž
æ§åéäœã芪氎æ§ã«ããªã³æ§åéäœããã³èŠªæ°Žæ§
ã¢ããªã³æ§åéäœããã³ãããã®æ··åç©ãå å«ã
ãããšã§é«ããããšãã§ããããããã®ãã®ã¯å š
ãŠæ¹¿æœ€å€ãšããŠäœçšããããããååç©ã®é¡ã¯èŠª
æ°Žæ§ã¢ã¯ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒããã¢ã¯ãª
ã«ã¢ãããã¡ã¿ã¯ãªã«ã¢ããããã³ããã«âã©ã¯
ã¿ã ã§ããã 芪氎æ§è³ªãæ¬çºæã®ã³ã³ã¿ã¯ãã¬ã³ãºææã®è¡š
é¢ã«åäžãã代衚çãªèŠªæ°Žæ§äžæ§åéäœã¯ïŒ®âã
ãã«ãããªãã³ãã¢ã¯ãªã«ã¢ãããã¡ã¿ã¯ãªã«ã¢
ãããïŒïŒ®âãžã¡ãã«ã¢ã¯ãªã«ã¢ãããŸãã¯ã¡
ã¿ã¯ãªã«ã¢ãããïŒâããããã·ãšãã«ã¢ã¯ãªã¬
ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒããïŒâãŸãã¯ïŒâãã
ããã·ãããã«ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒ
ããã°ãªã»ãªã«ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒ
ããã°ãªã·ãžã«ã¢ã¯ãªã¬ãŒããŸãã¡ã¿ã¯ãªã¬ãŒ
ããäžè¬åŒHOïŒCoH2oïŒxïŒåŒäžãâïœâã¯ïŒã
çŽïŒã®æ°ã§ãããããŠâïœâã¯ïŒãçŽ10ã®æ°ã§ã
ããïŒã®ããªãšãŒãã«ãšã¢ã¯ãªã«é žããã³ã¡ã¿ã¯
ãªã«é žãšã®ïŒâã¡ããâïŒâããããã·ãããã«
ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒãã¢ããšã¹ãã«
ãå å«ããã ã«ããªã³æ§èŠªæ°Žæ§åéäœã¯åœå垯é»ç¶æ ã«ãã
åŸãããŸãã¯ã³ã³ã¿ã¯ãã¬ã³ãºã®åœ¢æåŸãåŒç¶ã
ãŠåž¯é»ç¶æ ã«å€æãããããããååç©ã®é¡ã¯å¡©
åºæ§ãŸãã¯ã«ããªã³æ§ã¢ã¯ãªã¬ãŒããã¡ã¿ã¯ãªã¬
ãŒããã¢ã¯ãªã«ã¢ãããã¡ã¿ã¯ãªã«ã¢ããããã
ã«ããªãžã³ãããã«ã€ãããŸãŒã«ããã³ãžã¢ã«ãª
ã«ãžã¢ã«ãã«ã¢ã³ã¢ããŠã éåæ§åºã«ç±æ¥ããã
ããããªåéäœã¯ïŒ®ïŒïŒ®âãžã¡ãã«ã¢ãããšãã«
ã¢ã¯ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒããïŒâã¡ã¿ã¯
ãªã«ãªãã·ãšãã«ããªã¡ãã«ã¢ã³ã¢ããŠã ã¯ããª
ãããã³ã¡ãã«ã¹ã«ããšãŒããïŒâïŒïŒâããã³
ïŒâã¡ãã«ââïŒâããã«ããªãžã³ãïŒâïŒïŒâ
ããã³ïŒâã¡ãã«ââïŒâããã«ããªãžããŠã ã¯
ããªãããã³ã¡ãã«ã¹ã«ããšãŒããâïŒïŒâã¡
ã¿ã¯ãªã«ã¢ãããããã«ïŒâïŒïŒ®âãžã¡ãã«ã¢
ãã³ãâïŒïŒâã¡ã¿ã¯ãªã«ã¢ãããããã«ïŒâ
ïŒïŒ®ïŒïŒ®âããªã¡ãã«ã¢ã³ã¢ããŠã ã¯ããªãã
âïŒïŒâã¡ã¿ã¯ãªã«ãªãã·âïŒâããããã·ã«
ãããã«ïŒâïŒïŒ®ïŒïŒ®âããªã¡ãã«ã¢ã³ã¢ããŠ
ã ã¯ããªãããžã¢ã«ãªã«ãžã¡ãã«ã¢ã³ã¢ããŠã ã¯
ããªãããã³ã¡ãã«ã¹ã«ããšãŒãã«ããè¡šããã
ãã ã¢ããªã³æ§èŠªæ°Žæ§åéäœã¯åœåäžæ§ã®ç¶æ ã§ã
ããåŸã§ã¢ããªã³æ§ç¶æ ã«å€æãããããããã®
é¡ã®ååç©ã¯ã«ã«ããã·ãã¹ã«ããªããŒãããã³
ãã¹ããšãŒããŸãã¯ãã¹ããšãŒãåºãå«æããé
åæ§åéäœãå å«ãããããããªåéäœã¯ã¢ã¯ãª
ã«é žãã¡ã¿ã¯ãªã«é žããããªãŠã ã¢ã¯ãªã¬ãŒãã
ãã³ã¡ã¿ã¯ãªã¬ãŒããããã«ã¹ã«ããªã³é žããã
ãªãŠã ããã«ã¹ã«ãããŒããïœâã¹ãã¬ã³ã¹ã«ã
ãªã³é žããããªãŠã ïœâã¹ãã¬ã³ã¹ã«ããªããŒ
ããïŒâã¡ã¿ã¯ãªãã€ã«ãªãã·ãšãã«ã¹ã«ããªã³
é žãïŒâã¡ã¿ã¯ãªãã€ã«ãªãã·âïŒâããããã·
ãããã«ã¹ã«ããªã³é žãïŒâã¢ã¯ãªã«ã¢ããâïŒ
âã¡ãã«ãããã³ã¹ã«ãã³é žãã¢ã«ãªã«ã¹ã«ããª
ã³é žãïŒâãã¹ãã¢ããšãã«ã¡ã¿ã¯ãªã¬ãŒãã«ã
ãè¡šããããã å ±åéäœãæ¬çºæã®æš¹èç³»ãšå ±ã«çšããããå Ž
åããããã¯éãå€ããŠäœ¿çšãããã次ã®è¡šã¯å¯
èœãªçŸåçããã³åŠæ¹ã説æãããã®ã§ããã
ãè¡šã
ãããµã³ææ
硬床å€æ§å€ 0 75ã2ïŒ 75ã1ïŒ
芪氎æ§å€ 0 ïŒ 1ã10ïŒ
ããå Žåã«ãããŠäº€åçµåå€ãæ¬æ现æžäžã«é
瀺ãããæ°èŠãªææ©ããªã·ãããµã³ã«åºã¥ãçµæ
ç©ã«æ··å ¥ããããšãæãŸããã 亀åçµåå€ã®äŸãšããŠã¯ã¢ã¯ãªã«é žãã¡ã¿ã¯ãª
ã«é žãã¢ã¯ãªã«ã¢ãããã¡ã¿ã¯ãªã«ã¢ããããã³
å€ããã«çœ®æããããã³ãŒã³ã®ããªå®èœåºèªå°äœ
ãå å«ãã次ã®ãã®ãå å«ããããããã«éå®ã
ããªãã ãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããŸãã¯ãžã¡
ã¿ã¯ãªã¬ãŒãããžãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬
ãŒããŸãã¯ãžã¡ã¿ã¯ãªã¬ãŒããããã©ãšãã¬ã³ã°
ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒãã
ããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããŸãã¯ã¡
ã¿ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ããªã¢ã¯
ãªã¬ãŒããŸãã¯ããªã¡ã¿ã¯ãªã¬ãŒãããã¹ããšã
ãŒã«ïŒ¡ãžã¢ã¯ãªã¬ãŒããŸãã¯ãžã¡ã¿ã¯ãªã¬ãŒãã
ãšããã·ã«åãããã¹ããšããŒã«ïŒ¡ãžã¢ã¯ãªã¬ãŒ
ããŸãã¯ãžã¡ã¿ã¯ãªã¬ãŒãããã³ã¿ãšãªããªããŒ
ã«ããªâããã³ããã©ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯
ãªã¬ãŒããããã©ã¡ãã¬ã³ãžã¢ã¯ãªã¬ãŒããŸãã¯
ãžã¡ã¿ã¯ãªã¬ãŒããã¡ãã¬ã³ãã¹ã¢ã¯ãªã«ã¢ãã
ãŸãã¯ã¡ã¿ã¯ãªã«ã¢ããããžã¡ãã¬ã³ãã¹ã¢ã¯ãª
ã«ã¢ãããŸãã¯ã¡ã¿ã¯ãªã«ã¢ãããïŒNâ²âãž
ããããã·ãšãã¬ã³ãã¹ã¢ã¯ãªã«ã¢ãããŸãã¯ã¡
ã¿ã¯ãªã«ã¢ããããããµã¡ãã¬ã³ãã¹ã¢ã¯ãªã«ã¢
ãããŸãã¯ã¡ã¿ã¯ãªã«ã¢ããããã«ã¡ãã¬ã³ãã¹
ã¢ã¯ãªã«ã¢ãããŸãã¯ã¡ã¿ã¯ãªã«ã¢ãããžããã«
ãã³ãŒã³ã æ¬çºæã«ãããŠèšèŒãããå ±éåäœã¯éé¢åºé
å§å€ã®æ··å ¥ã«ããåºã®éåã«ãã調補ããããé
å§å€ã¯ããã«ã¿ã€ãåéäœãéåããããã«éåžž
å©çšããããã®ããéžæããããããŠæ¬¡ã®ä»£è¡šç
ãªéå§å€ãå å«ããã ïŒïŒ2â²âã¢ãŸâãã¹âã€ãœããããããªã«ã
ïŒïŒ4â²âã¢ãŸâãã¹âïŒïŒâã·ã¢ããã³ã¿ãã³
é žïŒãïœâããã«ãâãªã¯ããšãŒãããã³ãŸã€ã«
ãâãªãã·ããã©ãŠãã€ã«ããŒãªãã·ããã¡ãã«
ãšãã«ã±ãã³ãâãªãã·ãããžã€ãœãããã«ãâ
ãªãã·ã«ãŒãããŒãã éé¢åºéå§å€ã¯éåžžå šååç©ã®0.01ãïŒééïŒ
ã®éã§äœ¿çšããããéåã¯å¥œãŸããã¯åºæ¥ãã ã
100ïŒ è¿ããŸã§æšé²ãããåå¿ã«ããåºçºææã®
95ïŒ ãŸãã¯ãã以äžã«ãŸã§è¡ãªãããã æ¬çºæã®ææã¯é©åœãªé³åäžã§çŽæ¥éåããŠã³
ã³ã¿ã¯ãã¬ã³ãºã圢æããããšãã§ããããã®æ
æã¯å šãŠç±ç¡¬åæ§ã§ãããèããŠçš®ã ã®çµç«ãŠæ¹
æ³ã䜿çšããããšãã§ãããã³ã³ã¿ã¯ãã¬ã³ãºã
æ©æ¢°ã«ãããããããã«ã·ãŒããŸãã¯æ£ç¶åæãž
ãšéåããããšã奜ãŸããã ããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒPMMAïŒã®ãã
ã«äœ¿çšãããããªã³ã³ã¿ã¯ãã¬ã³ãºã圢æããå Ž
åã«æ £çšã®æ¹æ³ã䜿çšããããšã奜ãŸããããã®
æ¹æ³ã«ãããŠãåŠæ¹ã¯çŽæ¥ã·ãŒããŸãã¯æ£ã«éå
ãããããŠã³ã³ã¿ã¯ãã¬ã³ãºã¯ãã¿ã³ããã€ã¹ã¯
ãŸãã¯ãã®ä»ã®æ圢åã®åœ¢æ ã«ã«ããããããã
ãŠæ¬¡ãã§ã¬ã³ãºè¡šé¢ãåŸãããã«æ©æ¢°ã«ãããã
ããåŸããããã¿ã³ã®éåæ§åæã¯æ¬çºæã«åºã¥
ãåå·®ããªãŒã§é žçŽ ééæ§ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãº
ã補é ããã«å¿ èŠãªå åŠçå質ãæããŠããã æ¬çºæã®å€å®èœæ§ææ©ããªã·ãããµã³åéäœã¯
ã³ã³ã¿ã¯ãã¬ã³ãºææã®åºç€ãšããŠå©çšããå Žå
ã«ãå€ãã®å©çãäžãããé瀺ãããåéäœã¯å®
質çã«ææ©ããªã·ãããµã³ã§ããããéé¢åºéå
ã«ããå ±éåäœç³»äžã«æ¥æ¿ãªæ··å ¥ã蚱容ããå€å®
èœåºãå«æãããããã«å€å®èœã®éåæ§åºã®ååš
ã®æ ã«ææ©ããªã·ãããµã³éšåã¯å ±éåäœæ§é äž
ã§äž¡ç«ããããã«ãªãã ããè§èã®é žçŽ èŠæ±ã¯ãã確ç«ãããŠãããã
ãŠæ¬çºæã®éåäœããã³å ±éåäœããäœãããã³
ã³ã¿ã¯ãã¬ã³ãºã¯ãã®èŠæ±ã«åèŽãäžã€å®¹æã«è¶
è¶ããããšãã§ããã çµæç©ã®ç¬ç¹ã®æ§è³ªã®æ ã«ããããã圢æãã
ãã³ã³ã¿ã¯ãã¬ã³ãºã¯é«åºŠã®é žçŽ ééæ§ãæãã
äžæ¹ãéæ床ã湿最æ§ããã³èä¹ æ§ã®ãããªãã®
ä»ã®æ¬è³ªçæ§è³ªãç¶æããŠãããé žçŽ ééæ§ã¯ïŒ
Ã10-11mlO2cm2ïŒsecmlmmHgããã倧ãªãé žçŽ é
éæ§ãæããéåæ§ææãå å«ããããšãæå³ã
ãã 次ã®å®æœäŸã¯æ¬çºæã説æããããã«äžããã
ãããæ¬çºæã¯ããã«éå®ããããã®ã§ã¯ãªãã å®æœäŸ ïŒ Î³âã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³155mlïŒ1.264ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³155mlïŒ1.264ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯
æ··åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«
é žãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠ
ã 溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ã
ç¡«é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©230mlãåŸãã 25âã«ãããŠ13.2ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
硬床å€æ§å€ 0 75ã2ïŒ 75ã1ïŒ
芪氎æ§å€ 0 ïŒ 1ã10ïŒ
ããå Žåã«ãããŠäº€åçµåå€ãæ¬æ现æžäžã«é
瀺ãããæ°èŠãªææ©ããªã·ãããµã³ã«åºã¥ãçµæ
ç©ã«æ··å ¥ããããšãæãŸããã 亀åçµåå€ã®äŸãšããŠã¯ã¢ã¯ãªã«é žãã¡ã¿ã¯ãª
ã«é žãã¢ã¯ãªã«ã¢ãããã¡ã¿ã¯ãªã«ã¢ããããã³
å€ããã«çœ®æããããã³ãŒã³ã®ããªå®èœåºèªå°äœ
ãå å«ãã次ã®ãã®ãå å«ããããããã«éå®ã
ããªãã ãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããŸãã¯ãžã¡
ã¿ã¯ãªã¬ãŒãããžãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬
ãŒããŸãã¯ãžã¡ã¿ã¯ãªã¬ãŒããããã©ãšãã¬ã³ã°
ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒãã
ããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããŸãã¯ã¡
ã¿ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ããªã¢ã¯
ãªã¬ãŒããŸãã¯ããªã¡ã¿ã¯ãªã¬ãŒãããã¹ããšã
ãŒã«ïŒ¡ãžã¢ã¯ãªã¬ãŒããŸãã¯ãžã¡ã¿ã¯ãªã¬ãŒãã
ãšããã·ã«åãããã¹ããšããŒã«ïŒ¡ãžã¢ã¯ãªã¬ãŒ
ããŸãã¯ãžã¡ã¿ã¯ãªã¬ãŒãããã³ã¿ãšãªããªããŒ
ã«ããªâããã³ããã©ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯
ãªã¬ãŒããããã©ã¡ãã¬ã³ãžã¢ã¯ãªã¬ãŒããŸãã¯
ãžã¡ã¿ã¯ãªã¬ãŒããã¡ãã¬ã³ãã¹ã¢ã¯ãªã«ã¢ãã
ãŸãã¯ã¡ã¿ã¯ãªã«ã¢ããããžã¡ãã¬ã³ãã¹ã¢ã¯ãª
ã«ã¢ãããŸãã¯ã¡ã¿ã¯ãªã«ã¢ãããïŒNâ²âãž
ããããã·ãšãã¬ã³ãã¹ã¢ã¯ãªã«ã¢ãããŸãã¯ã¡
ã¿ã¯ãªã«ã¢ããããããµã¡ãã¬ã³ãã¹ã¢ã¯ãªã«ã¢
ãããŸãã¯ã¡ã¿ã¯ãªã«ã¢ããããã«ã¡ãã¬ã³ãã¹
ã¢ã¯ãªã«ã¢ãããŸãã¯ã¡ã¿ã¯ãªã«ã¢ãããžããã«
ãã³ãŒã³ã æ¬çºæã«ãããŠèšèŒãããå ±éåäœã¯éé¢åºé
å§å€ã®æ··å ¥ã«ããåºã®éåã«ãã調補ããããé
å§å€ã¯ããã«ã¿ã€ãåéäœãéåããããã«éåžž
å©çšããããã®ããéžæããããããŠæ¬¡ã®ä»£è¡šç
ãªéå§å€ãå å«ããã ïŒïŒ2â²âã¢ãŸâãã¹âã€ãœããããããªã«ã
ïŒïŒ4â²âã¢ãŸâãã¹âïŒïŒâã·ã¢ããã³ã¿ãã³
é žïŒãïœâããã«ãâãªã¯ããšãŒãããã³ãŸã€ã«
ãâãªãã·ããã©ãŠãã€ã«ããŒãªãã·ããã¡ãã«
ãšãã«ã±ãã³ãâãªãã·ãããžã€ãœãããã«ãâ
ãªãã·ã«ãŒãããŒãã éé¢åºéå§å€ã¯éåžžå šååç©ã®0.01ãïŒééïŒ
ã®éã§äœ¿çšããããéåã¯å¥œãŸããã¯åºæ¥ãã ã
100ïŒ è¿ããŸã§æšé²ãããåå¿ã«ããåºçºææã®
95ïŒ ãŸãã¯ãã以äžã«ãŸã§è¡ãªãããã æ¬çºæã®ææã¯é©åœãªé³åäžã§çŽæ¥éåããŠã³
ã³ã¿ã¯ãã¬ã³ãºã圢æããããšãã§ããããã®æ
æã¯å šãŠç±ç¡¬åæ§ã§ãããèããŠçš®ã ã®çµç«ãŠæ¹
æ³ã䜿çšããããšãã§ãããã³ã³ã¿ã¯ãã¬ã³ãºã
æ©æ¢°ã«ãããããããã«ã·ãŒããŸãã¯æ£ç¶åæãž
ãšéåããããšã奜ãŸããã ããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒPMMAïŒã®ãã
ã«äœ¿çšãããããªã³ã³ã¿ã¯ãã¬ã³ãºã圢æããå Ž
åã«æ £çšã®æ¹æ³ã䜿çšããããšã奜ãŸããããã®
æ¹æ³ã«ãããŠãåŠæ¹ã¯çŽæ¥ã·ãŒããŸãã¯æ£ã«éå
ãããããŠã³ã³ã¿ã¯ãã¬ã³ãºã¯ãã¿ã³ããã€ã¹ã¯
ãŸãã¯ãã®ä»ã®æ圢åã®åœ¢æ ã«ã«ããããããã
ãŠæ¬¡ãã§ã¬ã³ãºè¡šé¢ãåŸãããã«æ©æ¢°ã«ãããã
ããåŸããããã¿ã³ã®éåæ§åæã¯æ¬çºæã«åºã¥
ãåå·®ããªãŒã§é žçŽ ééæ§ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãº
ã補é ããã«å¿ èŠãªå åŠçå質ãæããŠããã æ¬çºæã®å€å®èœæ§ææ©ããªã·ãããµã³åéäœã¯
ã³ã³ã¿ã¯ãã¬ã³ãºææã®åºç€ãšããŠå©çšããå Žå
ã«ãå€ãã®å©çãäžãããé瀺ãããåéäœã¯å®
質çã«ææ©ããªã·ãããµã³ã§ããããéé¢åºéå
ã«ããå ±éåäœç³»äžã«æ¥æ¿ãªæ··å ¥ã蚱容ããå€å®
èœåºãå«æãããããã«å€å®èœã®éåæ§åºã®ååš
ã®æ ã«ææ©ããªã·ãããµã³éšåã¯å ±éåäœæ§é äž
ã§äž¡ç«ããããã«ãªãã ããè§èã®é žçŽ èŠæ±ã¯ãã確ç«ãããŠãããã
ãŠæ¬çºæã®éåäœããã³å ±éåäœããäœãããã³
ã³ã¿ã¯ãã¬ã³ãºã¯ãã®èŠæ±ã«åèŽãäžã€å®¹æã«è¶
è¶ããããšãã§ããã çµæç©ã®ç¬ç¹ã®æ§è³ªã®æ ã«ããããã圢æãã
ãã³ã³ã¿ã¯ãã¬ã³ãºã¯é«åºŠã®é žçŽ ééæ§ãæãã
äžæ¹ãéæ床ã湿最æ§ããã³èä¹ æ§ã®ãããªãã®
ä»ã®æ¬è³ªçæ§è³ªãç¶æããŠãããé žçŽ ééæ§ã¯ïŒ
Ã10-11mlO2cm2ïŒsecmlmmHgããã倧ãªãé žçŽ é
éæ§ãæããéåæ§ææãå å«ããããšãæå³ã
ãã 次ã®å®æœäŸã¯æ¬çºæã説æããããã«äžããã
ãããæ¬çºæã¯ããã«éå®ããããã®ã§ã¯ãªãã å®æœäŸ ïŒ Î³âã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³155mlïŒ1.264ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³155mlïŒ1.264ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯
æ··åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«
é žãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠ
ã 溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ã
ç¡«é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©230mlãåŸãã 25âã«ãããŠ13.2ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ ïŒ
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³155mlïŒ1.264ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³155mlïŒ1.264ã¢ã«ïŒã®æ··åç©ããã€ãããšãž
ãšãã«ãšãŒãã«300mlããã³æ°Ž300mlã®ã¹ã©ãªãŒã«
æ·»å ãããå æ°Žå解ã®æž©åºŠã¯ãšãŒãã«ãéæµãã
ããããšã«ããçŽ40âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããææ©çžããæ®çºåãåã
é€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«
é žãããªãŠã ã§æœåºããç¡«é žãããªãŠã 溶液ã§æŽ
æ»ããã次ãã§ææ©ããªã·ãããµã³ãç¡«é žãã°ã
ã·ãŠã ã§ä¹Ÿç¥ãçæç©230mlãåŸãã 25âã«ãããŠ14.8ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³155mlïŒ1.264ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³155mlïŒ1.264ã¢ã«ïŒã®æ··åç©ããã€ãããšãž
ãšãã«ãšãŒãã«300mlããã³æ°Ž300mlã®ã¹ã©ãªãŒã«
æ·»å ãããå æ°Žå解ã®æž©åºŠã¯ãšãŒãã«ãéæµãã
ããããšã«ããçŽ40âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããææ©çžããæ®çºåãåã
é€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«
é žãããªãŠã ã§æœåºããç¡«é žãããªãŠã 溶液ã§æŽ
æ»ããã次ãã§ææ©ããªã·ãããµã³ãç¡«é žãã°ã
ã·ãŠã ã§ä¹Ÿç¥ãçæç©230mlãåŸãã 25âã«ãããŠ14.8ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ ïŒ
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³155mlïŒ1.264ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³1155mlïŒ1.264ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€
ãã€ãããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã®æº¶æ¶²
ã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã
50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«
é žãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠ
ã 溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ã
ç¡«é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©200mlãåŸãã 25âã«ãããŠ24.4ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³155mlïŒ1.264ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³1155mlïŒ1.264ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€
ãã€ãããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã®æº¶æ¶²
ã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã
50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«
é žãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠ
ã 溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ã
ç¡«é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©200mlãåŸãã 25âã«ãããŠ24.4ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ ïŒ
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³78mlïŒ0.632ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³233mlïŒ1.896ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯
æ··åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«
é žãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠ
ã 溶液ã§æŽæ»ããã次ã«ææ©ããªã·ãããµã³ãç¡«
é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©220mlãåŸãã 25âã«ãããŠ30.2ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³78mlïŒ0.632ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³233mlïŒ1.896ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯
æ··åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«
é žãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠ
ã 溶液ã§æŽæ»ããã次ã«ææ©ããªã·ãããµã³ãç¡«
é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©220mlãåŸãã 25âã«ãããŠ30.2ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ ïŒ
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³78mlïŒ0.632ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³233mlïŒ1.896ã¢ã«ïŒã®æ··åç©ããã€ãããšãž
ãšãã«ãšãŒãã«300mlããã³æ°Ž300mlã®ã¹ã©ãªãŒã«
æ·»å ãããå æ°Žå解ã®æž©åºŠã¯ãšãŒãã«ãéæµãã
ããããšã«ããçŽ40âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§70ã75âã®æž©åºŠã«ãããŠ
é«ç空ãå©çšããªããææ©çžããæ®çºåãåãé€
ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é žã
ããªãŠã ã§æœåºããç¡«é žãããªãŠã 溶液ã§æŽæ»ã
ãã次ãã§ææ©ããªã·ãããµã³ãç¡«é žãã°ãã·ãŠ
ã ã§ä¹Ÿç¥ãçæç©225mlãåŸãã 25âã«ãããŠ28.0ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³78mlïŒ0.632ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³233mlïŒ1.896ã¢ã«ïŒã®æ··åç©ããã€ãããšãž
ãšãã«ãšãŒãã«300mlããã³æ°Ž300mlã®ã¹ã©ãªãŒã«
æ·»å ãããå æ°Žå解ã®æž©åºŠã¯ãšãŒãã«ãéæµãã
ããããšã«ããçŽ40âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§70ã75âã®æž©åºŠã«ãããŠ
é«ç空ãå©çšããªããææ©çžããæ®çºåãåãé€
ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é žã
ããªãŠã ã§æœåºããç¡«é žãããªãŠã 溶液ã§æŽæ»ã
ãã次ãã§ææ©ããªã·ãããµã³ãç¡«é žãã°ãã·ãŠ
ã ã§ä¹Ÿç¥ãçæç©225mlãåŸãã 25âã«ãããŠ28.0ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ ïŒ
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³78mlïŒ0.632ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³233mlïŒ1.896ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã®æº¶æ¶²ã«
æ·»å ãããå æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã50
âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ã«ããªã·ãããµã³ãç¡«é žãã°
ãã·ãŠã ã§ä¹Ÿç¥ãçæç©105mlãåŸãã 25âã«ãããŠã63.7ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæ
ãããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³78mlïŒ0.632ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³233mlïŒ1.896ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã®æº¶æ¶²ã«
æ·»å ãããå æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã50
âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ã«ããªã·ãããµã³ãç¡«é žãã°
ãã·ãŠã ã§ä¹Ÿç¥ãçæç©105mlãåŸãã 25âã«ãããŠã63.7ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæ
ãããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ ïŒ
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³116mlïŒ0.948ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³194mlïŒ1.580ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯
æ··åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ã«ææ©ããªã·ãããµã³ãç¡«é ž
ãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©205mlãåŸãã 25âã«ãããŠ21.6ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³116mlïŒ0.948ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³194mlïŒ1.580ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯
æ··åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ã«ææ©ããªã·ãããµã³ãç¡«é ž
ãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©205mlãåŸãã 25âã«ãããŠ21.6ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ ïŒ
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³116mlïŒ0.948ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³194mlïŒ1.580ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã«æ·»å ã
ããå æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã50âã«ç¶
æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ãç¡«
é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©225mlãåŸãã 25âã«ãããŠ13.3ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³116mlïŒ0.948ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³194mlïŒ1.580ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã«æ·»å ã
ããå æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã50âã«ç¶
æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ãç¡«
é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©225mlãåŸãã 25âã«ãããŠ13.3ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ ïŒ
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³232mlïŒ1.896ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³232mlïŒ1.896ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯
æ··åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ã«ææ©ããªã·ãããµã³ãç¡«é ž
ãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©245mlãåŸãã 25âã«ãããŠ10.7ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³232mlïŒ1.896ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³232mlïŒ1.896ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯
æ··åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ã«ææ©ããªã·ãããµã³ãç¡«é ž
ãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©245mlãåŸãã 25âã«ãããŠ10.7ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâïŒãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ 10
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³232mlïŒ1.896ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³232mlïŒ1.896ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã®æº¶æ¶²ã«
æ·»å ãããå æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã50
âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ãç¡«
é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©273mlãåŸãã 25âã«ãããŠ8.1ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâ10ãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³150mlïŒ0.632ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©
ã³232mlïŒ1.896ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·
ã©ã³232mlïŒ1.896ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ã
ã€ãããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã®æº¶æ¶²ã«
æ·»å ãããå æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã50
âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ãç¡«
é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©273mlãåŸãã 25âã«ãããŠ8.1ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâ10ãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ 11
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³75mlïŒ0.316ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©ã³
78mlïŒ0.632ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·ã©
ã³267mlïŒ2.212ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ãã€
ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯æ··
åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåé€
ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ã«ç¡«é žãããªãŠã 溶
液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ãç¡«é ž
ãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©112mlãåŸãã 25âã«ãããŠ13.1ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâ11ãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³75mlïŒ0.316ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©ã³
78mlïŒ0.632ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·ã©
ã³267mlïŒ2.212ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ãã€
ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯æ··
åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåé€
ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ã«ç¡«é žãããªãŠã 溶
液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ãç¡«é ž
ãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©112mlãåŸãã 25âã«ãããŠ13.1ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâ11ãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ 12
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³75mlïŒ0.316ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©ã³
78mlïŒ0.632ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·ã©
ã³267mlïŒ2.212ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ãã€
ãããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã«æ·»å ã
ããå æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã50âã«ç¶
æãããã äžå€æ¹æåŸãæ°Žæ§çžãåé¢ããããŠææ©çžãç
éã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ã
ããŠé«ç空ãå©çšããªããæ®çºåãææ©çžããå
ãé€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒ
ç¡«é žãããªãŠã 溶液ã§æœåºãã次ã«ç¡«é žãããªãŠ
ã 溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ã
ç¡«é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©147mlãåŸãã 25âã«ãããŠ9.4ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâ12ãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³75mlïŒ0.316ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©ã³
78mlïŒ0.632ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·ã©
ã³267mlïŒ2.212ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ãã€
ãããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã«æ·»å ã
ããå æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã50âã«ç¶
æãããã äžå€æ¹æåŸãæ°Žæ§çžãåé¢ããããŠææ©çžãç
éã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ã
ããŠé«ç空ãå©çšããªããæ®çºåãææ©çžããå
ãé€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒ
ç¡«é žãããªãŠã 溶液ã§æœåºãã次ã«ç¡«é žãããªãŠ
ã 溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ã
ç¡«é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©147mlãåŸãã 25âã«ãããŠ9.4ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâ12ãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ 13
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³75mlïŒ0.316ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©ã³
39mlïŒ0.316ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·ã©
ã³300mlïŒ2.528ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ãã€
ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯æ··
åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ã«ææ©ããªã·ãããµã³ãç¡«é ž
ãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©125mlãåéããã 25âã«ãããŠ16.8ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâ13ãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³75mlïŒ0.316ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©ã³
39mlïŒ0.316ã¢ã«ïŒããã³ãžã¡ãã«ãžã¯ããã·ã©
ã³300mlïŒ2.528ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ãã€
ãããšæ°Ž600mlã«æ·»å ãããå æ°Žå解ã®æž©åºŠã¯æ··
åäžå€§ãã40ã50âã«ç¶æãããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ã«ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«é ž
ãããªãŠã 溶液ã§æœåºãã次ãã§ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ã«ææ©ããªã·ãããµã³ãç¡«é ž
ãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©125mlãåéããã 25âã«ãããŠ16.8ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâ13ãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ 14
γâã¡ã¿ã¯ãªã«ãªãã·ãããã«ããªã¡ããã·ã·
ã©ã³75mlïŒ0.316ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©ã³
39mlïŒ0.316ã¢ã«ïŒããã³ãžã¡ãã«ã¯ããã·ã©ã³
300mlïŒ2.528ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ãã€ã
ããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã«æ·»å ããã
å æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã50âã«ç¶æã
ããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«
é žãããªãŠã 溶液ã§æœåºãã次ã«ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ãç¡«
é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©144mlãåŸãã 25âã«ãããŠ13.6ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâ14ãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ã©ã³75mlïŒ0.316ã¢ã«ïŒãããªã¡ãã«ã¯ããã·ã©ã³
39mlïŒ0.316ã¢ã«ïŒããã³ãžã¡ãã«ã¯ããã·ã©ã³
300mlïŒ2.528ã¢ã«ïŒã®æ··åç©ãæ¹æãã€ã€ãã€ã
ããšã¡ã¿ããŒã«300mlããã³æ°Ž300mlã«æ·»å ããã
å æ°Žå解ã®æž©åºŠã¯æ··åäžå€§ãã40ã50âã«ç¶æã
ããã äžå€æ¹æåŸãæ°Žçžãåé¢ããããŠææ©çžãçé
ã®æ°Žã§æŽæ»ããã次ãã§çŽ70ã75âã®æž©åºŠã«ãã
ãŠé«ç空ãå©çšããªããæ®çºåãææ©çžããåã
é€ããã次ãã§ç²çæç©ãæ°Žé žåãããªãŠã ïŒç¡«
é žãããªãŠã 溶液ã§æœåºãã次ã«ç¡«é žãããªãŠã
溶液ã§æŽæ»ããã次ãã§ææ©ããªã·ãããµã³ãç¡«
é žãã°ãã·ãŠã ã§ä¹Ÿç¥ãçæç©144mlãåŸãã 25âã«ãããŠ13.6ã»ã³ãã¹ããŒã¯ã®ç²åºŠãæã
ããã®ææãPSâ14ãšæ称ãããæ žç£æ°å ±å
ïŒã·ãªã³ã³29ïŒåæã¯æ瀺ããã¢ã«æ¯çã«ãããŠ
次ã®åºãååšããããšã瀺ããã
ãè¡šã
å®æœäŸ 15
硬質é
žçŽ ééæ§ã¬ã³ãºææãã¡ãã«ã¡ã¿ã¯ãªã¬
ãŒãïŒMMAïŒãPSâïŒãPSâïŒãPSâïŒãã
ã³ã¡ã¿ã¯ãªã«é žïŒMAïŒã®éžæãããå ±åéäœæ··
åç©ããéé¢åºéå§å€ïŒïŒ2â²âã¢ãŸãã¹ã€ãœãã
ããããªã«ïŒAIBNïŒã䜿çšããŠäœããåŠæ¹æå
ïŒè¡šïŒã«éééšã§ç€ºãïŒãå åã«æ··åããçªçŽ ã§
æŽæµã次ãã§è¡æž ãã€ããã§å¯å°ããè©Šéšç®¡ã«ç§»
ããããã®è©Šéšç®¡ã¯æ¬¡ãã§40âã«ãããŠæ°ŽæµŽäžã«
眮ãããããŠïŒæ¥ééåããããã次ãã§è©Šéšç®¡
ãè¿œå ã®ïŒæ¥é65âã®ãªãŒãã³äžã«çœ®ãããã®åŸ
éåããæ£ãè©Šéšç®¡ããé€å»ããã次ã«ç¡¬è³ªéæ
ãªæ£ãç空äž100âã«ãããŠå€§ãã24æé調æŽã«
ä»ããŠéåããã»ã¹ãçµäºãäžã€ãããªãæ©æ¢°ç
ã²ã¥ã¿ã®ååšããåãé€ãã調æŽãããæ£ã¯æ¬¡ã
ã§æ©æ¢°ã«ãããŠã³ã³ã¿ã¯ãã¬ã³ãºãã©ã³ã¯ã«ãã
ïŒçŽåŸ1/2ã€ã³ããåã¿3/16ã€ã³ãã®ãã€ã¹ã¯ïŒã ããã§è¿°ã¹ãææãã補é ããã³ã³ã¿ã¯ãã¬ã³
ãºã®é žçŽ ééæ§å€ã¯å€§ããªå¹³åŠãªãã€ã¹ã¯ã®ææ
ã®ä»£ãã«ãã©ãã³ã³ã¿ã¯ãã¬ã³ãºãçšããããšã
é€ãASTM D1434ã«èšèŒã®æäœã«ããäœãã
ããééæ§è£ 眮ã¯å®éã®ã³ã³ã¿ã¯ãã¬ã³ãºãåå ¥
ãããããªæ¹æ³ã§ã€ããããããŠè¡šïŒã§å ±åãã
ãã®ä»ã®éåæ§é žçŽ ééæ§ããŒã¿ã«ããç®çãã
ããããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããããªã«ãŒãããŒ
ãããã³ããªã¹ãã¬ã³ã¯å€«ã ïŒïŒ22ããã³35cm3
mmïŒcm2ç§cmÃ10-10ã®é žçŽ ééæ§ãæããã
ãŒãïŒMMAïŒãPSâïŒãPSâïŒãPSâïŒãã
ã³ã¡ã¿ã¯ãªã«é žïŒMAïŒã®éžæãããå ±åéäœæ··
åç©ããéé¢åºéå§å€ïŒïŒ2â²âã¢ãŸãã¹ã€ãœãã
ããããªã«ïŒAIBNïŒã䜿çšããŠäœããåŠæ¹æå
ïŒè¡šïŒã«éééšã§ç€ºãïŒãå åã«æ··åããçªçŽ ã§
æŽæµã次ãã§è¡æž ãã€ããã§å¯å°ããè©Šéšç®¡ã«ç§»
ããããã®è©Šéšç®¡ã¯æ¬¡ãã§40âã«ãããŠæ°ŽæµŽäžã«
眮ãããããŠïŒæ¥ééåããããã次ãã§è©Šéšç®¡
ãè¿œå ã®ïŒæ¥é65âã®ãªãŒãã³äžã«çœ®ãããã®åŸ
éåããæ£ãè©Šéšç®¡ããé€å»ããã次ã«ç¡¬è³ªéæ
ãªæ£ãç空äž100âã«ãããŠå€§ãã24æé調æŽã«
ä»ããŠéåããã»ã¹ãçµäºãäžã€ãããªãæ©æ¢°ç
ã²ã¥ã¿ã®ååšããåãé€ãã調æŽãããæ£ã¯æ¬¡ã
ã§æ©æ¢°ã«ãããŠã³ã³ã¿ã¯ãã¬ã³ãºãã©ã³ã¯ã«ãã
ïŒçŽåŸ1/2ã€ã³ããåã¿3/16ã€ã³ãã®ãã€ã¹ã¯ïŒã ããã§è¿°ã¹ãææãã補é ããã³ã³ã¿ã¯ãã¬ã³
ãºã®é žçŽ ééæ§å€ã¯å€§ããªå¹³åŠãªãã€ã¹ã¯ã®ææ
ã®ä»£ãã«ãã©ãã³ã³ã¿ã¯ãã¬ã³ãºãçšããããšã
é€ãASTM D1434ã«èšèŒã®æäœã«ããäœãã
ããééæ§è£ 眮ã¯å®éã®ã³ã³ã¿ã¯ãã¬ã³ãºãåå ¥
ãããããªæ¹æ³ã§ã€ããããããŠè¡šïŒã§å ±åãã
ãã®ä»ã®éåæ§é žçŽ ééæ§ããŒã¿ã«ããç®çãã
ããããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããããªã«ãŒãããŒ
ãããã³ããªã¹ãã¬ã³ã¯å€«ã ïŒïŒ22ããã³35cm3
mmïŒcm2ç§cmÃ10-10ã®é žçŽ ééæ§ãæããã
ãè¡šã
å®æœäŸ 16
å®æœäŸ15ã®å®éšæäœãå©çšããªããããã®å®æœ
äŸã§ã¯ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºã補é ããã®ã«å¥œé©
ãªææã®èª¿è£œããã³æ§è³ªã説æããã
äŸã§ã¯ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºã補é ããã®ã«å¥œé©
ãªææã®èª¿è£œããã³æ§è³ªã説æããã
ãè¡šã
å®æœäŸ 17
å®æœäŸ15ã®å®éšæäœãå©çšããªããããã®å®æœ
äŸã¯ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºã補é ããã®ã«å¥œé©ãª
ææã®èª¿è£œããã³æ§è³ªã説æããã
äŸã¯ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºã補é ããã®ã«å¥œé©ãª
ææã®èª¿è£œããã³æ§è³ªã説æããã
ãè¡šã
å®æœäŸ 18
å®æœäŸ15ã®å®éšæäœãå©çšããªããããã®å®æœ
äŸã¯ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºã補é ããã®ã«å¥œé©ãª
ææã®èª¿è£œããã³æ§è³ªã説æããã
äŸã¯ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºã補é ããã®ã«å¥œé©ãª
ææã®èª¿è£œããã³æ§è³ªã説æããã
ãè¡šã
å®æœäŸ 19
å®æœäŸ15ã®å®éšæäœãå©çšããªããããã®å®æœ
äŸã¯ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºã補é ããã®ã«å¥œé©ãª
ææã®èª¿è£œããã³æ§è³ªã説æããã
äŸã¯ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºã補é ããã®ã«å¥œé©ãª
ææã®èª¿è£œããã³æ§è³ªã説æããã
ãè¡šã
å®æœäŸ 20
å®æœäŸ15ã®å®éšæäœãå©çšããªããããã®å®æœ
äŸã¯ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºã補é ããã®ã«å¥œé©ãª
ææã®èª¿è£œããã³æ§è³ªã説æããã
äŸã¯ç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºã補é ããã®ã«å¥œé©ãª
ææã®èª¿è£œããã³æ§è³ªã説æããã
ãè¡šã
åè¿°ããå®æœäŸã¯æ¬çºæã®æš¹èç³»ã®èª¿è£œããã³
ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã«é žãšã®æ··
åããã³å ±éåã説æãããåè¿°ããããã«ãã®
ä»ã®å ±åéäœã¯æš¹èç³»ãšå ±ã«çšããŠéåãã補å
ã圢æããããšãã§ãããè¥å¹²ã®å Žåã«ãæš¹èç³»
ã¯ããèªäœã§éåããŠç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºææ
ã圢æããããšãã§ãããæ¬çºæã®æš¹èãåç¬é
åãäžã€ã³ã³ã¿ã¯ãã¬ã³ãºçšã«äœ¿çšãããå Žåã
è¡šé¢ã湿最æ§ã«ããããã«æ £çšã®é žåãŸãã¯ã°ã©
ããã³ã°ã«ãããããã¬ã³ãºãè¡šé¢åŠçããããš
ã奜ãŸããã
ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã«é žãšã®æ··
åããã³å ±éåã説æãããåè¿°ããããã«ãã®
ä»ã®å ±åéäœã¯æš¹èç³»ãšå ±ã«çšããŠéåãã補å
ã圢æããããšãã§ãããè¥å¹²ã®å Žåã«ãæš¹èç³»
ã¯ããèªäœã§éåããŠç¡¬è³ªã³ã³ã¿ã¯ãã¬ã³ãºææ
ã圢æããããšãã§ãããæ¬çºæã®æš¹èãåç¬é
åãäžã€ã³ã³ã¿ã¯ãã¬ã³ãºçšã«äœ¿çšãããå Žåã
è¡šé¢ã湿最æ§ã«ããããã«æ £çšã®é žåãŸãã¯ã°ã©
ããã³ã°ã«ãããããã¬ã³ãºãè¡šé¢åŠçããããš
ã奜ãŸããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¬¡åŒ ïŒåŒäžãâïœâã¯0.10ã0.40ã®ã¢ã«ãã©ã¯ã·ãš
ã³å€ãæããâïœâã¯0.25ã0.80ã®ã¢ã«ãã©ã¯ã·
ãšã³å€ãæããããŠâïœâã¯0.10ã0.40ã®ã¢ã«ã
ã©ã¯ã·ãšã³å€ãæããïŒ ã§è¡šããããæš¹èç³»ã®éåäœãå å«ããããšãç¹
城ãšããã³ã³ã¿ã¯ãã¬ã³ãºææã ïŒ ïŒ¡ æ¬¡åŒ ïŒåŒäžãïœïŒ0.10ã0.40ã¢ã«ãã©ã¯ã·ãšã³ã
ïœïŒ0.25ã0.80ã¢ã«ãã©ã¯ã·ãšã³ãïŒ0.10ã
0.40ã¢ã«ãã©ã¯ã·ãšã³ïŒãæããæš¹èç³»25ã98
ééïŒ ã  C1ãC20ã®ïŒäŸ¡ãŸãã¯å€äŸ¡ã¢ã«ã«ããŒã«ãŸã
ã¯ããšããŒã«ãšæ¬è³ªçã«ã¢ã¯ãªã«é žãã¡ã¿ã¯ãª
ã«é žãã€ã¿ã³ã³é žããã³ãããã®æ··åç©ãããª
ãé¡ããéžæãããé žãšã®ãšã¹ãã«75ãïŒïŒ ã
ã㳠 芪氎å€ïŒã10ïŒ ãã圢æãããéé¢åºéåã«ãã95ïŒ ä»¥äžã®éæ
床ã«éåãããŠããææãéåããããšãç¹åŸŽãš
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®ã³ã³ã¿ã¯ãã¬
ã³ãºææã ïŒ ïŒ¡ã30ã60ééïŒ ã®ç¯å²ã«ããã ïœïŒ0.20ã0.35ã¢ã«ãã©ã¯ã·ãšã³ ïœïŒ0.40ã0.60ã¢ã«ãã©ã¯ã·ãšã³ ïœïŒ0.20ã0.40ã¢ã«ãã©ã¯ã·ãšã³ ã69ã40ééïŒ ã§ããäžã€ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒ
ãã§ããã ãïŒã10ééïŒ ã§ããããšãç¹åŸŽãšããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ã³ã³ã¿ã¯ãã¬ã³ãºææã ïŒ ïŒ£ãããã«ãããªãã³ã§ããããšãç¹åŸŽãšã
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ã³ã³ã¿ã¯ãã¬ã³ãº
ææã ïŒ ïŒ£ãã¢ã¯ãªã«é žã§ããããšãç¹åŸŽãšããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ã³ã³ã¿ã¯ãã¬ã³ãºææã ïŒ ïŒ£ãã¡ã¿ã¯ãªã«é žã§ããããšãç¹åŸŽãšããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ã³ã³ã¿ã¯ãã¬ã³ãºæ
æã
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US43048982A | 1982-09-30 | 1982-09-30 | |
US430489 | 1982-09-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5961816A JPS5961816A (ja) | 1984-04-09 |
JPS637367B2 true JPS637367B2 (ja) | 1988-02-16 |
Family
ID=23707771
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14889583A Granted JPS5961816A (ja) | 1982-09-30 | 1983-08-16 | ã·ãªã³ã³å«æã³ã³ã¿ã¯ãã¬ã³ãºææ |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPS5961816A (ja) |
AU (1) | AU564035B2 (ja) |
CA (1) | CA1226696A (ja) |
DE (1) | DE3329722A1 (ja) |
FR (1) | FR2533933B1 (ja) |
GB (1) | GB2129005B (ja) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0627911B2 (ja) * | 1987-06-06 | 1994-04-13 | æ ªåŒäŒç€Ÿã¡ãã³ã³ | ã³ã³ã¿ã¯ãã¬ã³ãºææ |
EP0336633B1 (en) * | 1988-04-04 | 1996-08-14 | Loctite Corporation | MTQ/polysiloxane hybrid resins, method of making the same, and coating/potting compositions containing the same |
IE892033L (en) * | 1988-07-07 | 1990-01-07 | Smc Patents Ltd | Aqueous emulsion copolymers with siloxane functionality |
DE19630100A1 (de) * | 1996-07-25 | 1998-01-29 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung eines fÌr optische Zwecke geeigneten Formkörpers |
JP4883683B2 (ja) * | 2006-03-31 | 2012-02-22 | æåæã±ãã«ã«ãºæ ªåŒäŒç€Ÿ | æ°äœåé¢èçšãªã«ã¬ãããªã·ãããµã³ |
EP3556795B1 (en) * | 2016-12-13 | 2021-10-27 | Mitsubishi Chemical Corporation | Polyorganosiloxane, polyorganosiloxane composition, cured product, polyorganosiloxane-containing electrolytic solution for electrolytic capacitor, and electrolytic capacitor using same |
JP7091683B2 (ja) * | 2017-02-06 | 2022-06-28 | äžè±ã±ãã«ã«æ ªåŒäŒç€Ÿ | ãªã«ã¬ãããªã·ãããµã³ |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58207023A (ja) * | 1982-05-10 | 1983-12-02 | ããŠã»ã³âãã³ã°ã»ã³âãã¬âã·ãšã³ | åºæ湿最æ§ã®ã·ãªã³âã³æš¹èã«ããèŠèŠè£ 眮 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1018625B (de) * | 1954-05-20 | 1957-10-31 | Dow Corning | Verfahren zur Herstellung von neuen Organopolysiloxanen |
US4035355A (en) * | 1975-12-10 | 1977-07-12 | Dow Corning Corporation | Anaerobically curing silicone compositions |
US4120570A (en) * | 1976-06-22 | 1978-10-17 | Syntex (U.S.A.) Inc. | Method for correcting visual defects, compositions and articles of manufacture useful therein |
US4216303A (en) * | 1979-01-26 | 1980-08-05 | George F. Tsuetaki | Oxygen-permeable contact lens compositions, methods and articles of manufacture |
US4259467A (en) * | 1979-12-10 | 1981-03-31 | Bausch & Lomb Incorporated | Hydrophilic contact lens made from polysiloxanes containing hydrophilic sidechains |
US4424328A (en) * | 1981-12-04 | 1984-01-03 | Polymer Technology Corporation | Silicone-containing contact lens material and contact lenses made thereof |
-
1983
- 1983-07-29 AU AU17435/83A patent/AU564035B2/en not_active Ceased
- 1983-08-16 JP JP14889583A patent/JPS5961816A/ja active Granted
- 1983-08-17 DE DE19833329722 patent/DE3329722A1/de not_active Withdrawn
- 1983-08-23 FR FR8313627A patent/FR2533933B1/fr not_active Expired
- 1983-09-07 CA CA000436190A patent/CA1226696A/en not_active Expired
- 1983-09-07 GB GB08323955A patent/GB2129005B/en not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58207023A (ja) * | 1982-05-10 | 1983-12-02 | ããŠã»ã³âãã³ã°ã»ã³âãã¬âã·ãšã³ | åºæ湿最æ§ã®ã·ãªã³âã³æš¹èã«ããèŠèŠè£ 眮 |
Also Published As
Publication number | Publication date |
---|---|
CA1226696A (en) | 1987-09-08 |
GB2129005A (en) | 1984-05-10 |
GB8323955D0 (en) | 1983-10-12 |
AU564035B2 (en) | 1987-07-30 |
FR2533933A1 (fr) | 1984-04-06 |
AU1743583A (en) | 1984-04-05 |
FR2533933B1 (fr) | 1987-02-06 |
JPS5961816A (ja) | 1984-04-09 |
DE3329722A1 (de) | 1984-04-05 |
GB2129005B (en) | 1986-06-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4625007A (en) | Silicone-containing contact lens material and contact lenses made thereof | |
US5331067A (en) | Silicone-containing contact lens polymers, oxygen permeable contact lenses and methods for making these lenses and treating patients with visual impairment | |
EP0154270B1 (en) | Hydrophilic polymers and contact lenses made therefrom | |
US5314961A (en) | Silicone-containing polymers, compositions and improved oxygen permeable hydrophilic contact lenses | |
DE69022809T2 (de) | Verfahren zu Herstellung von Polymerzusammensetzungen fÌr SauerstoffdurchlÀssige Kontaktlinsen. | |
JPS6261929B2 (ja) | ||
US5314960A (en) | Silicone-containing polymers, oxygen permeable hydrophilic contact lenses and methods for making these lenses and treating patients with visual impairment | |
US4826936A (en) | Silicone-containing contact lens material and contact lenses made thereof | |
US4604479A (en) | Silicone-containing contact lens material and contact lenses made thereof | |
US5923397A (en) | Bimodulus contact lens article | |
JPH02147613A (ja) | æ¹è¯ãããã·ãªã³ãŒã³å«æããŒãã³ã³ã¿ã¯ãã¬ã³ãºæãšããŠã®ã·ãŒãåã¯ããã | |
EP1355963A2 (en) | Polymeric biomaterials containing silsesquixane monomers | |
CA2039900A1 (en) | Silicone-containing block copolymers and macromonomers | |
JPS63258917A (ja) | ç©çç¹æ§ãæ¹è¯ãããé£ç¶è£ çã³ã³ã¿ã¯ãã¬ã³ãº | |
CN1123056A (zh) | çšäºæ¥è§Šééçæ¹è¿çè¡£åº·é žé ¯å ±èç©ç»åç© | |
JP3167229B2 (ja) | çŒçšã¬ã³ãºææ | |
JP3753328B2 (ja) | æ°èŠãªã·ãªã³ãŒã³å«æããªããŒåã³åèšããªããŒããã®é žçŽ ééæ§èŠªæ°Žæ§ã³ã³ã¿ã¯ãã¬ã³ãº | |
US5019628A (en) | Silicone containing acrylic star polymers | |
JPS637367B2 (ja) | ||
WO1992007014A1 (en) | Novel silicone-containing acrylic star polymers, block copolymers and macromonomers | |
JP2551603B2 (ja) | ã³ã³ã¿ã¯ãã¬ã³ãº | |
JPS61151212A (ja) | ã¡ã¿ã¯ãªã«ç³»å ±éåäœã®è£œé æ³ | |
JPH0251162B2 (ja) | ||
JP3804238B2 (ja) | ãã©ã¹ããã¯æ圢å | |
JP2003147148A (ja) | ããªã¡ã¿ã¯ãªã«é žã¡ãã«ïŒãžã«ã³ãã¢ãã€ããªãããã£ã«ã |