JPS6356835B2 - - Google Patents
Info
- Publication number
- JPS6356835B2 JPS6356835B2 JP2730085A JP2730085A JPS6356835B2 JP S6356835 B2 JPS6356835 B2 JP S6356835B2 JP 2730085 A JP2730085 A JP 2730085A JP 2730085 A JP2730085 A JP 2730085A JP S6356835 B2 JPS6356835 B2 JP S6356835B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- sintered body
- firing
- present
- hardening agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000010304 firing Methods 0.000 claims description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 8
- 239000011707 mineral Substances 0.000 claims description 8
- 239000004575 stone Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 241001465754 Metazoa Species 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 230000036571 hydration Effects 0.000 claims description 3
- 238000006703 hydration reaction Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 235000020188 drinking water Nutrition 0.000 description 8
- 239000003651 drinking water Substances 0.000 description 8
- 230000002378 acidificating effect Effects 0.000 description 6
- 230000003472 neutralizing effect Effects 0.000 description 5
- 235000014653 Carica parviflora Nutrition 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 241000243321 Cnidaria Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 3
- 239000008235 industrial water Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000003113 alkalizing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- ZPLCXHWYPWVJDL-UHFFFAOYSA-N 4-[(4-hydroxyphenyl)methyl]-1,3-oxazolidin-2-one Chemical compound C1=CC(O)=CC=C1CC1NC(=O)OC1 ZPLCXHWYPWVJDL-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000242757 Anthozoa Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003621 irrigation water Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Description
[産業上の利用分野]
本発明は、酸性となつた、飲料水、工業用水等
の水を中和若しくはアルカリ性にするための装置
に関するものである。
[従来の技術]
従来、酸性に汚染された水を中和するには、石
灰系水酸化カルシウムによる酸化水の中和、もし
くは水酸化ナトリウム等のアルカリ成分を添加す
る方法が考えられているが、安全性を考慮すると
飲料水の中和、もしくは弱アルカリ化に対して
は、適当な方法がなかつた。そこでさんご虫の群
体の石灰質骨格が堆積して生じたさんごや貝殻等
の破砕物を飲料水と接触させて中和させる方法も
考えられているが、これも持続性に乏しく、中和
する効力が長続きしないという欠点があつた。こ
れらの成分は通常1ケ月位しか効果が持続せず、
これが実用上大きな欠点となつていた。
[本発明が解決しようとする問題点]
本発明は、飲料水を中和もしくは弱アルカリ化
するのに安全で、しかも効果が長続きする中和装
置を提供することを目的としている。
[問題点を解決するための手段]
係る目的を達成するために、本発明では動物性
殻類の細粒物、鉱物性石土及び焼成硬化剤とを混
合成形し、焼成して多孔質な焼結体とした物から
成ることを特徴とする酸性水中和器に構成した。
本発明は、焼結体から成るものであり、係る焼
結体は動物性殻類の細粒物を原料の1つとしてい
る。係る動物性殻類の細粒物としては、さんごの
粒状物もしくは粒状物、貝殻の粉状物等を挙げる
ことができる。
更に原料としては鉱物性石土を用いる。鉱物性
石土としては通常陶磁器、フアインセラミツクの
製造に用いられる粘土をいずれも使用することが
でき、例えば白珪石、カオリン、木節粘土、陶
石、ベントナイト、長石、ドロマイト、滑石等を
用いることができる。
更に焼成硬化剤も用いる。係る焼成硬化剤とし
ては、アルカリ金属ケイ酸塩系接着剤、シリカゾ
ル系接着剤、リン酸塩系接着剤、でん粒等の有機
物系接着剤等を用いることができるが、飲料水に
万一しみ出しても安全なものを用いるのが好まし
い。
これらの動物性殻類、鉱物性石土及び焼成硬化
剤は適量混合して使用するが、混合例を挙げると
動物性殻類:30%〜90%(重量%、以下同じ)、
好ましくは50%〜70%、鉱物性石土:残部、焼成
硬化剤:適宜若干混合する。係る混合物を円盤
形、円柱形、立方体形等所望の形状に成形し焼成
する。この際成形物を第1図に示すようにドーナ
ツ状の円盤形に成形し、上端から下端へ貫通する
小孔1を多数空けたものであつても良い。焼成は
所望の温度で行なわれるが一般により高温で焼成
すると、処理する水がよりアルカリになり易い。
通常焼成温度は600℃〜1000℃、好ましくは700℃
〜800℃で行なわれる。こうして焼成すると水が
焼結体の内部まで浸透する多孔質な焼結体とな
る。係る焼結体を本発明では主要物としている。
[作 用]
本発明の酸性水中和器を飲料水に浸漬すると、
飲料水の水素イオン濃度(PH)は中性ないしはア
ルカリ側に移行する。飲料水のみならず工業用
水、産業用水、潅漑用水等の水も同様に酸性から
中性ないしはアルカリ側へ移行する。
[実施例]
実施例 1
造礁さんご破砕物(約1ミリの砂状)150gと、
粘質陶土150g、焼成硬化剤として無鉛フリツト
60gを混合して直径9.5cm、厚さ2.5cmの円盤状に
成形し、750℃で焼成・セラミツク化して多孔質
な焼結体を得た。このものをPH6.8の水道水1
中に投入浸漬して10秒後に取り出したところ、そ
の水道水のPHは7.4となつた。
実施例 2
実施例1で製造した焼結体から成る酸性水中和
器を水道蛇口に当て、1分間約3の割合いで放
水し、その水の水素イオン濃度を測定したところ
7.4であつた。尚、実施例1及び2において水素
イオン濃度はPH測定用試薬BTB(ブロムチモー
ル・ブルー溶液)を使用した。
実施例 3
実施例1で製造した焼結体から成る酸性水中和
器を岐阜県美濃加茂市太田町境松1158の31の総合
保健センター臨床検査部において主任計量者坂野
一雄氏により分析してもらつた。
その結果は次の通りであつた。
(試験方法)
酸性水中和器をPH6.1の水道水1に浸漬し、
最初のみ軽く撹拌し時間の経過とともにPHと温度
を測定した。
(結 果)
第1表の通りとなつた。
[Industrial Application Field] The present invention relates to an apparatus for neutralizing or making alkaline water, such as drinking water or industrial water, which has become acidic. [Prior Art] Conventionally, methods of neutralizing oxidized water with lime-based calcium hydroxide or adding alkaline components such as sodium hydroxide have been considered to neutralize acidic contaminated water. Considering safety, there was no suitable method for neutralizing or slightly alkalizing drinking water. Therefore, a method has been considered in which the crushed corals and shells produced by the accumulation of calcareous skeletons of coral worm colonies are brought into contact with drinking water to neutralize it, but this method also lacks sustainability and neutralizes it. The drawback was that the efficacy of the drug did not last long. These ingredients usually only last about a month,
This was a major practical drawback. [Problems to be Solved by the Present Invention] An object of the present invention is to provide a neutralization device that is safe for neutralizing or slightly alkalizing drinking water and has a long-lasting effect. [Means for Solving the Problems] In order to achieve the above object, the present invention mixes and molds fine grains of animal shells, mineral stone soil, and a firing hardening agent, and bakes the mixture to form a porous material. The acid hydration device is constructed of a sintered material. The present invention consists of a sintered body, and the sintered body uses fine grains of animal shellfish as one of its raw materials. Examples of such fine grains of animal shells include coral grains or granules, shell powders, and the like. Furthermore, mineral stone soil is used as a raw material. As the mineral stone soil, any of the clays normally used in the production of ceramics and fine ceramics can be used, such as white silica stone, kaolin, kibushi clay, pottery stone, bentonite, feldspar, dolomite, talc, etc. be able to. Furthermore, a baking hardening agent is also used. As such baking hardening agents, alkali metal silicate adhesives, silica sol adhesives, phosphate adhesives, organic adhesives such as starch, etc. can be used, but if drinking water It is preferable to use a material that is safe even if it oozes out. These animal shells, mineral stone soil, and calcined hardening agent are mixed in appropriate amounts. Examples of mixing include animal shells: 30% to 90% (wt%, the same applies hereinafter);
Preferably 50% to 70%, mineral stone soil: balance, firing hardening agent: mixed slightly as appropriate. The mixture is formed into a desired shape such as a disk, cylinder, or cube and fired. At this time, the molded product may be formed into a donut-like disk shape, as shown in FIG. 1, and a large number of small holes 1 may be formed therethrough from the upper end to the lower end. Firing is carried out at a desired temperature, but generally speaking, firing at a higher temperature tends to make the water to be treated more alkaline.
Normal firing temperature is 600℃~1000℃, preferably 700℃
Performed at ~800°C. When fired in this manner, the sintered body becomes porous, allowing water to penetrate into the inside of the sintered body. Such a sintered body is the main material in the present invention. [Function] When the acidic water hydrating device of the present invention is immersed in drinking water,
The hydrogen ion concentration (PH) of drinking water shifts to the neutral or alkaline side. Not only drinking water but also industrial water, industrial water, irrigation water, etc., similarly shifts from acidic to neutral or alkaline. [Example] Example 1 150 g of crushed reef-building coral (approximately 1 mm sand-like),
150g of clay clay, lead-free frit as firing hardening agent
60g of the mixture was mixed and formed into a disk shape with a diameter of 9.5cm and a thickness of 2.5cm, and fired at 750°C to form a ceramic to obtain a porous sintered body. Add this to 1 part tap water with a pH of 6.8.
When I poured it into the water and took it out after 10 seconds, the pH of the tap water was 7.4. Example 2 The acid hydrator made of the sintered body produced in Example 1 was placed on a tap, water was sprayed at a rate of about 3:00 for 1 minute, and the hydrogen ion concentration of the water was measured.
It was 7.4. In Examples 1 and 2, a pH measuring reagent BTB (bromothymol blue solution) was used to measure the hydrogen ion concentration. Example 3 The acid hydration device made of the sintered body produced in Example 1 was analyzed by Mr. Kazuo Sakano, the chief measurer, at the Clinical Laboratory Department of the 31 General Health Center, 1158 Sakaimatsu, Ota-cho, Minokamo City, Gifu Prefecture. . The results were as follows. (Test method) Immerse the acidic water hydrator in tap water 1 of PH6.1,
The mixture was stirred lightly at first, and the pH and temperature were measured over time. (Results) The results are as shown in Table 1.
【表】
[発明の効果]
本発明の酸性水中和器を水中に浸漬すれば水は
迅速にアルカリないし中和される。又、この効果
は最低3ケ月は持続する。3ケ月以上経過し、中
和能力が衰えた焼結体は、乾燥してから都市ガス
の炎に当てると効力が元に戻る。また水中にミネ
ラル分が流出し簡単にミネラルウオーターを製造
することができる。[Table] [Effects of the Invention] When the acidic water hydrator of the present invention is immersed in water, the water is quickly made alkaline or neutralized. Moreover, this effect lasts for at least 3 months. If a sintered body whose neutralizing ability has diminished after more than three months has passed, its potency will be restored by drying it and exposing it to a city gas flame. In addition, minerals flow out into the water, making it possible to easily produce mineral water.
第1図は本発明の一実施例を示す平面図、第2
図は同実施例の断面図である。
1……小孔。
FIG. 1 is a plan view showing one embodiment of the present invention, and FIG.
The figure is a sectional view of the same embodiment. 1...Small hole.
Claims (1)
化剤とを混合成形し、焼成して多孔質な焼結体と
した物から成ることを特徴とする酸性水中和器。1. An acid hydration device characterized by being made of a porous sintered body formed by mixing and molding fine grains of animal shells, mineral stone soil, and a firing hardening agent, and firing the mixture.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2730085A JPS61185377A (en) | 1985-02-12 | 1985-02-12 | Acidic water neutralizing vessel |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2730085A JPS61185377A (en) | 1985-02-12 | 1985-02-12 | Acidic water neutralizing vessel |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61185377A JPS61185377A (en) | 1986-08-19 |
JPS6356835B2 true JPS6356835B2 (en) | 1988-11-09 |
Family
ID=12217238
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2730085A Granted JPS61185377A (en) | 1985-02-12 | 1985-02-12 | Acidic water neutralizing vessel |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61185377A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3706313B2 (en) * | 2001-04-13 | 2005-10-12 | 実 深谷 | Ceramic industry block |
JP6311139B2 (en) * | 2015-11-12 | 2018-04-18 | 大阪瓦斯株式会社 | Neutralizing agent module and neutralizer for acidic liquid using the same |
-
1985
- 1985-02-12 JP JP2730085A patent/JPS61185377A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS61185377A (en) | 1986-08-19 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
LAPS | Cancellation because of no payment of annual fees |