JPS63313717A - Chemically treating agent for hair - Google Patents
Chemically treating agent for hairInfo
- Publication number
- JPS63313717A JPS63313717A JP15078687A JP15078687A JPS63313717A JP S63313717 A JPS63313717 A JP S63313717A JP 15078687 A JP15078687 A JP 15078687A JP 15078687 A JP15078687 A JP 15078687A JP S63313717 A JPS63313717 A JP S63313717A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- methylsiloxane
- carbon chain
- agent
- scalp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 210000004209 hair Anatomy 0.000 title claims abstract description 55
- -1 methylsiloxane Chemical class 0.000 claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 229920000642 polymer Polymers 0.000 claims abstract description 14
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 10
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 8
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 8
- 239000001913 cellulose Substances 0.000 claims abstract description 6
- 229920002678 cellulose Polymers 0.000 claims abstract description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 4
- 239000000194 fatty acid Substances 0.000 claims abstract description 4
- 229930195729 fatty acid Natural products 0.000 claims abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 21
- 239000000126 substance Substances 0.000 claims description 20
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 210000004761 scalp Anatomy 0.000 abstract description 24
- 206010061218 Inflammation Diseases 0.000 abstract description 17
- 230000004054 inflammatory process Effects 0.000 abstract description 15
- 230000037308 hair color Effects 0.000 abstract description 8
- 238000002156 mixing Methods 0.000 abstract description 8
- 239000003086 colorant Substances 0.000 abstract description 3
- 239000007844 bleaching agent Substances 0.000 abstract description 2
- 230000006378 damage Effects 0.000 abstract description 2
- 230000001976 improved effect Effects 0.000 abstract description 2
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 description 21
- 239000007788 liquid Substances 0.000 description 15
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 9
- 239000000654 additive Substances 0.000 description 9
- 201000004384 Alopecia Diseases 0.000 description 8
- 230000003676 hair loss Effects 0.000 description 8
- 208000024963 hair loss Diseases 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000007800 oxidant agent Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 238000010998 test method Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000003158 alcohol group Chemical group 0.000 description 3
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 230000003700 hair damage Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 3
- 239000001923 methylcellulose Substances 0.000 description 3
- 235000010981 methylcellulose Nutrition 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- QIJRTFXNRTXDIP-UHFFFAOYSA-N (1-carboxy-2-sulfanylethyl)azanium;chloride;hydrate Chemical compound O.Cl.SCC(N)C(O)=O QIJRTFXNRTXDIP-UHFFFAOYSA-N 0.000 description 2
- PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical compound CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000003766 combability Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229960002433 cysteine Drugs 0.000 description 2
- 229960001305 cysteine hydrochloride Drugs 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 230000006749 inflammatory damage Effects 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical group OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- PORPENFLTBBHSG-MGBGTMOVSA-N 1,2-dihexadecanoyl-sn-glycerol-3-phosphate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP(O)(O)=O)OC(=O)CCCCCCCCCCCCCCC PORPENFLTBBHSG-MGBGTMOVSA-N 0.000 description 1
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 1
- XWNSFEAWWGGSKJ-UHFFFAOYSA-N 4-acetyl-4-methylheptanedinitrile Chemical compound N#CCCC(C)(C(=O)C)CCC#N XWNSFEAWWGGSKJ-UHFFFAOYSA-N 0.000 description 1
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 1
- RKDBLFVPSORYNW-UHFFFAOYSA-J Br(=O)(=O)[O-].[Th+4].Br(=O)(=O)[O-].Br(=O)(=O)[O-].Br(=O)(=O)[O-] Chemical compound Br(=O)(=O)[O-].[Th+4].Br(=O)(=O)[O-].Br(=O)(=O)[O-].Br(=O)(=O)[O-] RKDBLFVPSORYNW-UHFFFAOYSA-J 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004201 L-cysteine Substances 0.000 description 1
- 235000013878 L-cysteine Nutrition 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004153 Potassium bromate Substances 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 229930006000 Sucrose Chemical group 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical group O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Chemical class [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical group C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- 210000001520 comb Anatomy 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000005313 fatty acid group Chemical group 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003051 hair bleaching agent Substances 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N inositol Chemical group OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 235000019396 potassium bromate Nutrition 0.000 description 1
- 229940094037 potassium bromate Drugs 0.000 description 1
- 150000003140 primary amides Chemical class 0.000 description 1
- KOODSCBKXPPKHE-UHFFFAOYSA-N propanethioic s-acid Chemical compound CCC(S)=O KOODSCBKXPPKHE-UHFFFAOYSA-N 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- KOUKXHPPRFNWPP-UHFFFAOYSA-N pyrazine-2,5-dicarboxylic acid;hydrate Chemical compound O.OC(=O)C1=CN=C(C(O)=O)C=N1 KOUKXHPPRFNWPP-UHFFFAOYSA-N 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003334 secondary amides Chemical class 0.000 description 1
- 125000003607 serino group Chemical group [H]N([H])[C@]([H])(C(=O)[*])C(O[H])([H])[H] 0.000 description 1
- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 150000003408 sphingolipids Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 239000005720 sucrose Chemical group 0.000 description 1
- 150000003511 tertiary amides Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q7/00—Preparations for affecting hair growth
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、パーマネントウェーブ剤、ヘアカラー、ブリ
ーチ剤等の毛髪用化学処理剤に関し、更に詳述すると頭
皮の炎症や毛髪の損傷を防止し、毛髪に良好な感触を付
与し得る毛髪用化学処理剤に関する。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to chemical hair treatment agents such as permanent waving agents, hair coloring agents, and bleaching agents. The present invention relates to a chemical treatment agent for hair that can impart a good feel to hair.
従来の技11及び 明が解決しようとする4題点従来、
パーマネントウェーブ剤としては、チオグリコール酸、
L−システィン又はこれらの塩類等のメルカプト化合物
を主成分とする第1液と臭素酸カリウム、臭素酸すトリ
ウム又は過酸化水素などの酸化剤を主成分とする第2液
とからなるものが用いられ、またヘアカラーとしては、
パラフェニレンジアミン等の芳香族アミンやその誘導体
からなる酸化染料と過酸化水素などの酸化剤とからなる
ものなどが使用されている。Conventional techniques 11 and 4 problems that Ming tries to solve Conventionally,
Permanent waving agents include thioglycolic acid,
A liquid consisting of a first liquid containing a mercapto compound such as L-cysteine or a salt thereof as a main component and a second liquid containing an oxidizing agent such as potassium bromate, thorium bromate, or hydrogen peroxide as a main component is used. Also, as a hair color,
A dye made of an oxidizing dye made of an aromatic amine such as paraphenylene diamine or a derivative thereof and an oxidizing agent such as hydrogen peroxide is used.
しかし、上記パーマネントウェーブ剤及びヘアカラーは
、頭皮及び毛髪への刺激性が強く、そのため頭皮の炎症
、抜毛などの原因になっている。However, the above-mentioned permanent waving agents and hair colors are highly irritating to the scalp and hair, causing scalp inflammation and hair loss.
この刺激性は、パーマネントウェーブ剤の場合は特に第
1液中に含有されている還元剤と助剤として配合されて
いる界面活性剤やアルカリなど、ヘアカラーの場合は助
剤として配合されている界面活性剤やアルカリ及び酸化
剤などによるものとされている。This irritation can be caused by the reducing agent contained in the first liquid and the surfactants and alkalis contained as auxiliary agents in the case of permanent waving agents, and the auxiliary agents in the case of hair coloring. This is thought to be caused by surfactants, alkalis, oxidizing agents, etc.
このため、これら毛髪用化学処理剤における一ヒ述した
ような欠点を改善すべく、種々の提案がなされているが
、未だ十分なものは見い出されておらず、この分野での
一層の研究技術開発が望まれている。For this reason, various proposals have been made to improve the above-mentioned drawbacks of these chemical treatment agents for hair, but none have yet been found to be satisfactory, and further research and technology in this field is required. Development is desired.
本発明は上記事情に鑑みなされたもので、毛髪の化学処
理に伴う頭皮の炎症や毛髪の損傷を防ぎ、かつ頭皮から
の毛髪抜けを抑えることができると共に、毛髪の感触を
改良することができる毛髪用化学処理剤を提供すること
を目的とする。The present invention was developed in view of the above circumstances, and is capable of preventing scalp inflammation and hair damage caused by chemical treatment of hair, suppressing hair loss from the scalp, and improving the feel of the hair. The purpose of the present invention is to provide a chemical treatment agent for hair.
問題点を解決するための手段及び作用
本発明者らは、上記目的を達成するため、即ち従来の毛
髪用化学処理剤の欠点である頭皮の炎症、抜毛などの発
生を防止するため鋭意検討を行なった結果、重合度が1
000以上のメチルシロキサン重合体を配合することに
より、頭皮の炎症、抜毛及び毛髪の損傷を有効に防止し
得ることを見い出した。Means and Action for Solving the Problems In order to achieve the above object, the present inventors have made extensive studies to prevent the occurrence of scalp inflammation, hair loss, etc., which are the shortcomings of conventional chemical hair treatment agents. As a result, the degree of polymerization was 1
It has been found that scalp inflammation, hair loss, and hair damage can be effectively prevented by incorporating a methylsiloxane polymer of 000 or more.
また、この重合度1000以上のメチルシロキサン重合
体に低重合度の鎖状又は環状メチルシロキサンを併用し
た場合、或いはカチオン化セルロースやポリビニルピロ
リドンを併用した場合、上述した目的がより効果的に達
成され、毛髪の感触も更に向上することを知見し、本発
明をなすに至った・
従って、本発明は重合度1000以上のメチルシロキサ
ン重合体を含有することを特徴とする毛壁用化学処理剤
を提供するものである。In addition, when a linear or cyclic methylsiloxane with a low degree of polymerization is used in combination with this methylsiloxane polymer having a degree of polymerization of 1000 or more, or when cationized cellulose or polyvinylpyrrolidone is used in combination, the above-mentioned purpose can be achieved more effectively. The present invention was based on the discovery that the feel of the hair was further improved. Therefore, the present invention provides a chemical treatment agent for hair walls characterized by containing a methylsiloxane polymer with a degree of polymerization of 1000 or more. This is what we provide.
以下、本発明を更に詳しく説明する。The present invention will be explained in more detail below.
本発明の毛髪用化学処理剤に配合するメチルシロキサン
重合体は、下記一般式(3)
%式%(3)
で示すことができる。ここで、式中nは1000以上の
数であり、好ましくは3000〜10000である。重
合度が1000未満のメチルシロキサン重合体では、本
発明の目的を達成し得ない。The methylsiloxane polymer blended into the hair chemical treatment agent of the present invention can be represented by the following general formula (3). Here, n in the formula is a number of 1000 or more, preferably 3000 to 10000. Methylsiloxane polymers having a degree of polymerization of less than 1000 cannot achieve the object of the present invention.
また、このメチルシロキサン重合体の配合量は特に制限
されるものではなく、処理剤の種類等に応じて適宜選択
されるが、組成物全体の0.1〜20重量%の範囲が好
ましく、より好ましくは0.3〜15重量%の範囲であ
る。配合量が0.1重量%未満の場合は櫛通りが悪くな
ることがあり、一方20重量%を超えると毛髪にべとつ
きを感じる場合がある。Further, the amount of the methylsiloxane polymer blended is not particularly limited, and is appropriately selected depending on the type of treatment agent, etc., but is preferably in the range of 0.1 to 20% by weight of the entire composition, and more Preferably it is in the range of 0.3 to 15% by weight. If the amount is less than 0.1% by weight, combability may become difficult, while if it exceeds 20% by weight, the hair may feel sticky.
本発明の毛髪用化学処理剤には、上記のメチルシロキサ
ン重合体と共に、下記一般式(1)で示されるメチルシ
ロキサン及び/又は下記一般式(2)
で示される環状メチルシロキサンを配合することが好ま
しい。この低分子メチルシロキサン及び/又は環状メチ
ルシロキサンを上記の重合度1000以上のメチルシロ
キサン重合体と併用することにより、頭皮の炎症や毛髪
の損傷の防止、毛髪抜けの防止、毛髪の感触の改善など
の作用、効果がより確実なものとなる。The chemical treatment agent for hair of the present invention may contain a methylsiloxane represented by the following general formula (1) and/or a cyclic methylsiloxane represented by the following general formula (2) together with the above-mentioned methylsiloxane polymer. preferable. By using this low-molecular-weight methylsiloxane and/or cyclic methylsiloxane in combination with the above-mentioned methylsiloxane polymer with a degree of polymerization of 1000 or more, it can prevent scalp inflammation and hair damage, prevent hair loss, and improve the feel of hair. The action and effect of this will become more reliable.
また、本発明の目的を更に効果的に達成させる上で、カ
チオン化セルロース及び/又はポリビニルピロリドンを
配合することが好ましい。このカチオン化セルロースと
しては分子量30,000〜2,000,000のもの
が好ましく、例えばヒドロキシエチルセルロースとグリ
シジルトリメチルアンモニウムクロリドとのエーテル(
商品名;レオガードG、ライオン(株)社製、ポリマー
JR−30M−125及び同一400.ユニオンカーバ
イド社製)などが挙げられ、またポリビニルピロリドン
としては、分子量10,000〜1,000,000の
ものが好ましく、商品名PVP K−30,PVP
K−90(uNずれもGAF社製)などが挙げられる
。Further, in order to achieve the object of the present invention more effectively, it is preferable to blend cationized cellulose and/or polyvinylpyrrolidone. The cationized cellulose preferably has a molecular weight of 30,000 to 2,000,000, for example, an ether of hydroxyethylcellulose and glycidyltrimethylammonium chloride (
Product name: Leogard G, manufactured by Lion Corporation, Polymer JR-30M-125 and Same 400. (manufactured by Union Carbide Co., Ltd.), and the polyvinylpyrrolidone preferably has a molecular weight of 10,000 to 1,000,000, and its trade name is PVP K-30, PVP
Examples include K-90 (uN also manufactured by GAF).
なお、カチオン化セルロース及び/又はポリビニルピロ
リドンを配合する場合、その配合量は、0.1〜20重
量%とすることが好ましく、より好ましくは0.5〜5
重量%である。この配合量が0.1重量%未満であると
これらを配合したに見合う効果が発揮されず、また20
重量%を超えると毛髪に過剰に付着して毛髪の感触が悪
くなる場合がある。In addition, when blending cationized cellulose and/or polyvinylpyrrolidone, the blending amount is preferably 0.1 to 20% by weight, more preferably 0.5 to 5% by weight.
Weight%. If the blending amount is less than 0.1% by weight, the effect commensurate with the blending of these components will not be achieved, and
If it exceeds % by weight, excessive adhesion to the hair may result in poor feel of the hair.
また、本発明の処理剤には奇数炭素鎖長脂肪酸誘導体及
び/又は奇数炭素鎖長アルコール誘導体を配合すること
もでき、これらの配合は頭皮の炎症を抑える点で好まし
い。Furthermore, odd carbon chain length fatty acid derivatives and/or odd carbon chain length alcohol derivatives can also be blended into the treatment agent of the present invention, and these blends are preferred in terms of suppressing scalp inflammation.
この奇数炭素鎖長脂肪酸誘導体及び奇数炭素鎖長アルコ
ール誘導体としては、下記のものが例示される。Examples of the odd carbon chain length fatty acid derivatives and odd carbon chain length alcohol derivatives include the following.
下記一般式CI)又は(II)で示されるモノグリセラ
イド、
(1) (II)
(但し、Rは偶数の炭素鎖長を有する直鎖式有機基を表
す)
下記一般式〔■〕又は[IV)で示されるジグリセライ
ド、
(m) (IV)
(但し、R工及びR2は鎖式有機基であって、これらの
うち少なくとも一方は偶数の炭素鎖長を有する直鎖式有
機基を表す)
下記一般式〔■〕で示されるトリグリセライド、(V)
(但し、R11R2及びR3は鎖式有機基であって、こ
れらのうち少なくとも一つは偶数の炭素鎖長を有する直
鎖式有機基を表す)
下記一般式(VI)で示される脂肪酸塩、(Vl)
(RCOO)nM
(但し、Rは偶数の炭素鎖長を有する直鎖式有機基、M
は金属原子、nはMの価数に対応した整数を表す)
下記一般式〔■〕で示されるエステル、〔■〕
RCOOR’
(但し、Rは偶数の炭素鎖長を有する直鎖式有機基、R
′は1価若しくは2価アルコール残基、アミン残基、ポ
リオキシエチレン残基、ソルビタン残基、又はショ糖残
基を表す)
下記一般式〔■〕で示される第1アミド、〔■〕
RCONR’R”
(但し、Rは偶数の炭素鎖長を有する直鎖式有機基、R
’、R”は水素又は有機基を表す)下記一般式(IK)
で示される第2アミド、(IK)
(但し、R1及びR2は有機基であって、これらのうち
少なくともいずれか一方は偶数の炭素鎖長を有する直鎖
式有機基、R′は水素又は有機基を表す)
下記一般式(X)で示される第3アミド、(X)
(但し、R1,R2及びR3は有機基であって、これら
のうち少なくとも一つは偶数の炭素鎖長を有する直鎖式
有機基を表す)
下記一般式〔又〕で示される二塩基酸及びその塩、(X
I)
HOOCRC○○H
(但し、Rは奇数の炭素鎖長を有する直鎖式有機基を表
す)
下記一般式〔別〕で示されるステロールエステル、
(但し、Rは偶数の炭素鎖長を有する直鎖式有機基を表
す)
下記一般式〔双〕で示されるリン脂質、〔廻〕
(ただし、R1及びR2は鎖式有機基であって、これら
のうち少なくともいずれか一方は偶数の炭素鎖長を有す
る直鎖式有機基、Xはコリン残基、エタノールアミン残
基、セリン残基、又はイノシトール残基を表す)
下記一般式〔藷〕で示されるフォスファチジン酸、
[)
(但し、R工及びR2は鎖式有機基であって、これらの
うち少なくともどちらか一方は偶数の炭素鎖長を有する
直鎖式有機基を表す)、並びに下記一般式〔X■〕で示
されるスフィンゴ脂質、(XV)
(ただし、Rは偶数の炭素鎖長を有する直鎖式有機基、
Xは糖残基、リン酸残基、又はアミン塩基残基を表す)
下記一般式(XVI)で示されるアルコールエステル。Monoglycerides represented by the following general formula CI) or (II), (1) (II) (wherein, R represents a linear organic group having an even number of carbon chain lengths) the following general formula [■] or [IV] Diglycerides represented by (m) (IV) (wherein R and R2 are chain organic groups, and at least one of them represents a straight chain organic group having an even carbon chain length) the following general Triglyceride (V) represented by the formula [■] (wherein, R11R2 and R3 are chain organic groups, and at least one of them represents a straight chain organic group having an even carbon chain length): Fatty acid salt represented by general formula (VI), (Vl) (RCOO) nM (where R is a linear organic group having an even carbon chain length, M
is a metal atom, n is an integer corresponding to the valence of M) Ester represented by the following general formula [■], [■] RCOOR' (However, R is a linear organic group having an even number of carbon chain lengths) ,R
' represents a monovalent or divalent alcohol residue, an amine residue, a polyoxyethylene residue, a sorbitan residue, or a sucrose residue) The primary amide represented by the following general formula [■], [■] RCONR 'R' (where R is a linear organic group with an even carbon chain length, R
', R'' represents hydrogen or an organic group) following general formula (IK)
A secondary amide represented by (IK) (wherein R1 and R2 are organic groups, at least one of them is a linear organic group having an even carbon chain length, and R' is hydrogen or an organic group). A tertiary amide represented by the following general formula (X), (X) (wherein R1, R2 and R3 are organic groups, and at least one of them is a linear group having an even carbon chain length) (represents a chain organic group) dibasic acids and their salts represented by the following general formula [also], (X
I) HOOCRC○○H (However, R represents a linear organic group having an odd carbon chain length) A sterol ester represented by the following general formula [separate], (However, R has an even carbon chain length) A phospholipid represented by the following general formula [bi] (represents a straight-chain organic group), [mawari] (where R1 and R2 are chain organic groups, and at least one of them is an even-numbered carbon chain) (X represents a choline residue, an ethanolamine residue, a serine residue, or an inositol residue) A phosphatidic acid represented by the following general formula: R and R2 are chain organic groups, at least one of which represents a straight chain organic group having an even number of carbon chain lengths), and sphingolipids represented by the following general formula [X■] , (XV) (wherein R is a linear organic group having an even carbon chain length,
(X represents a sugar residue, a phosphoric acid residue, or an amine base residue) An alcohol ester represented by the following general formula (XVI).
〔XVI)
R1−0−COR
(但し、R1−0は奇数鎖アルコール残基、−CORは
脂肪酸残基を表す)
下記一般式〔X■〕で示されるアルコールエーテル、
〔X■〕
Rニー0−R
(但し、Rニー〇−は奇数鎖アルコール残基、Rは有機
基を表す)
本発明の毛髪用化学処理剤にこれら奇数炭素鎖長脂肪酸
誘導体及び/又は奇数炭素鎖長アルコール誘導体を配合
する場合、その配合量は0.1〜20重量%が好ましく
、より好ましくは0.5〜10重景%重量る。[XVI) R1-0-COR (However, R1-0 represents an odd-numbered chain alcohol residue, -COR represents a fatty acid residue) Alcohol ether represented by the following general formula [X■], [X■] Rnee 0 -R (However, R - represents an odd-numbered chain alcohol residue, and R represents an organic group) These odd-numbered carbon chain length fatty acid derivatives and/or odd-numbered carbon chain length alcohol derivatives are blended into the chemical treatment agent for hair of the present invention. If so, the blending amount is preferably 0.1 to 20% by weight, more preferably 0.5 to 10% by weight.
配合量が0.1重量%未満の場合、これらを配合したに
見合う効果が十分発揮されず、一方201t −
重量%を超えると毛髪に過剰について、毛髪の感触が悪
くなる場合がある。If the blending amount is less than 0.1% by weight, the effect commensurate with the blending will not be sufficiently exhibited, while if it exceeds 201t - weight%, the hair may be coated in excess and the feel of the hair may be deteriorated.
本発明の毛髪用化学処理剤は、パーマネントウェーブ剤
、ヘアカラー、ブリーチ剤等として調製、使用されるが
、本発明の処理剤には、これらの使用目的などに応じた
適宜な成分を配合することができる5例えば、パーマネ
ントウェーブ剤としては、メルカプト化合物を主成分と
する第1液及び酸化剤を主成分とする第2液より構成さ
れるものに主述したメチルシロキサン重合体などの成分
を各法の一方又は双方にそれぞれ配合することができる
。この場合、このパーマネントウェーブ剤の第1液の主
成分であるメルカプト化合物としては、チオグリコール
酸又はその塩類、システィン又はシスティン塩酸塩、チ
オ乳酸又はその塩、チオプロピオン酸又はその塩、チオ
酢酸又はその塩、メルカプトポリシロキサン、チオグリ
コール酸グリセリンエステル等が挙げられる。また、第
1液には、例えばアンモニア、モノエタノールアミン、
ジェタノールアミン、苛性ソーダ等のpH調整剤、アニ
オン界面活性剤、カチオン界面活性剤、ノニオン界面活
性剤及び両性界面活性剤などの界面活性剤、高級アルコ
ール、流動パラフィン、ラノリン等の油分、プロピレン
グリコール、ブチレングリコール、グリセリン、ピロリ
ドンカルボン酸等の湿潤剤、尿素、チオシアン酸アンモ
ニウム等のウェーブ力増強剤、着色剤、キレート化剤、
香料及びその他の物質を適宜配合しても良い。また、第
2液の酸化剤としては、臭素酸塩、過ホウ酸塩などが挙
げられ、この第2液にはクエン酸、酒石酸、塩酸等のp
H調整剤及び上記第1液で説明したような各種添加剤を
適宜配合してもよい。The chemical treatment agent for hair of the present invention is prepared and used as a permanent waving agent, hair coloring agent, bleaching agent, etc., and appropriate ingredients are added to the treatment agent of the present invention depending on the purpose of use. 5 For example, as a permanent waving agent, a component such as the above-mentioned methylsiloxane polymer may be used as a permanent waving agent, which is composed of a first liquid containing a mercapto compound as a main component and a second liquid containing an oxidizing agent as a main component. They can be incorporated into one or both of the methods. In this case, the mercapto compound which is the main component of the first liquid of this permanent waving agent includes thioglycolic acid or its salts, cysteine or cysteine hydrochloride, thiolactic acid or its salts, thiopropionic acid or its salts, thioacetic acid or Salts thereof, mercaptopolysiloxane, thioglycolic acid glycerin ester, and the like can be mentioned. In addition, the first liquid may include, for example, ammonia, monoethanolamine,
pH adjusters such as jetanolamine and caustic soda, surfactants such as anionic surfactants, cationic surfactants, nonionic surfactants and amphoteric surfactants, higher alcohols, liquid paraffin, oils such as lanolin, propylene glycol, Wetting agents such as butylene glycol, glycerin, pyrrolidone carboxylic acid, waving force enhancers such as urea and ammonium thiocyanate, coloring agents, chelating agents,
Flavors and other substances may be added as appropriate. In addition, examples of the oxidizing agent for the second liquid include bromates, perborates, etc.
An H adjuster and various additives as explained in the above first liquid may be appropriately blended.
また、ヘアカラーはパラフェニレンジアミン等の芳香族
アミンやその誘導体からなる酸化染料と過酸化水素など
の酸化剤から構成されるものを用いることができ、酸化
染料と酸化剤を別々に製剤化した2液型では、メチルシ
ロキサン重合体などの成分を各法の一方又は双方にそれ
ぞれに配合することができる。In addition, hair color can be made of an oxidizing dye made of an aromatic amine such as paraphenylenediamine or its derivative, and an oxidizing agent such as hydrogen peroxide. In the two-part type, components such as methylsiloxane polymers can be incorporated into one or both of the methods.
発明の効果
問題となっている毛髪の化学処理に伴う頭皮の炎症や毛
髪の損但、頭皮からの毛髪抜けの発生を有効に防止し得
ると共に、毛髪の感触の改良を行なうことができる。Effects of the Invention It is possible to effectively prevent inflammation of the scalp, damage to the hair, and hair loss from the scalp due to chemical treatment of hair, and also to improve the feel of the hair.
以下、実施例及び比較例を示し、本発明を具体的に説明
するが、本発明は下記実施例に制限されるものではない
。EXAMPLES Hereinafter, the present invention will be specifically explained by showing examples and comparative examples, but the present invention is not limited to the following examples.
なお、以下に示す配合量の%はいずれも重量%を示す。It should be noted that all percentages in the amounts shown below indicate weight percent.
下記処方の毛髪用化学処理剤N001〜N014を調製
した。Hair chemical treatment agents N001 to N014 having the following formulations were prepared.
チオグリコール酸 6%アンモ
ニア水(28%) 2ソルビタンモ
ノステアリン酸エステル 0.2ポリオキシエチレ
ンステアリルエーテル 3第1表に示す添加剤
第1表に示す量水
残
計 100.0%パーマネント
ウェーブ用液 2液(A)臭素酸ナトリウム
5%1.3−ブチレンゲリコール
2アルキルエーテル硫酸エステル塩
1ヒドロキシエチルセルロース 2第1表
に示す添加剤 第1表に示す量水
残
計 100.0%システィン塩
酸塩−水和物 6%アンモニア水(28
%) 3モノエタノールアミン
2第2表に示す添加剤
第2表に示す量水
残
計 100.0%パーマネン
トウェーブ 液筒2液 B)過酸化水素水(30%)
5%1.3−ブチレンゲリコール
3蛋白加水分解物
1第2表に示す添加剤 第2表に示
す量水 残
計 100.O%p−フェニレ
ンジアミン 2%p−アミノフェノ
ール 10−アミノフェノール
0.5レゾルシン
1.5セタノール
5塩化ステアリルジメチルアンモニウム
1プロピレングリコール 5ア
ンモニア(28%) 8亜硫酸ナト
リウム 0.5第3表に示す
添加剤 第3表に示す量水
残
計 100.0%ヘアカラー第
2液
過酸化水素水(30%) 15%ポリ
オキシエチレンステアリルエーテル 3ラウリル硫酸
トリエタノールアミン 3メチルセルロース
1クエン酸
0.1第3表に示す添加剤
第3表に示す量水
残
計 100.0%N−フェニ
ルパラフェニレンジアミン 3%トルエン−2,5
−ジアミン 3パラアミノフエノール
1ポリオキシエチレンステアリルエ
ーテル 3メチルセルロース
1ラノリン 0.
5ポリオキシエチレンノニルフエニル 0.3エ
ーテル
モノエタノールアミン 3第4表
に示す添加剤 第4表に示す量水
残
計 100.0%ヘアカラー
第2液
過酸化水素水(30%) 15%ポリオ
キシエチレンステアリルエーテル 3ラウリル硫酸ト
リエタノールアミン 3メチルセルロース
1クエン酸
0.1第4表に示す添加剤
第4表に示す量水
残
計 100.0%次に、上記各
処理剤について毛髪の感触、頭皮の炎症、保湿性、毛髪
水分及びブラッシング時の頭皮からの毛髪抜けに関して
下記試験方法及び評価方法で官能試験を行なった。結果
を第1表〜第4表に示す。Thioglycolic acid 6% ammonia water (28%) 2 Sorbitan monostearate 0.2 Polyoxyethylene stearyl ether 3 Additives shown in Table 1
Quantity of water shown in Table 1
Remaining total: 100.0% Permanent wave liquid 2 liquid (A) Sodium bromate
5% 1.3-butylene gellicol
2-alkyl ether sulfate salt
1. Hydroxyethylcellulose 2. Additives shown in Table 1 Quantity of water shown in Table 1
Remaining total 100.0% cysteine hydrochloride hydrate 6% ammonia water (28
%) 3 monoethanolamine
2 Additives shown in Table 2
Quantity of water shown in Table 2
Remaining total 100.0% Permanent Wave 2 liquid cylinder B) Hydrogen peroxide solution (30%)
5% 1.3-butylene gellicol
3 protein hydrolyzate
1 Additives shown in Table 2 Volume of water shown in Table 2 Remaining total 100. O% p-phenylenediamine 2% p-aminophenol 10-aminophenol
0.5 resorcinol
1.5 cetanol
Stearyldimethylammonium pentachloride
1 Propylene glycol 5 Ammonia (28%) 8 Sodium sulfite 0.5 Additives shown in Table 3 Amount of water shown in Table 3
Remaining total: 100.0% Hair color 2nd liquid Hydrogen peroxide solution (30%) 15% Polyoxyethylene stearyl ether 3 Triethanolamine lauryl sulfate 3 Methyl cellulose
1 citric acid
0.1 Additives shown in Table 3
Quantity of water shown in Table 3
Remaining total: 100.0% N-phenylparaphenylenediamine 3% Toluene-2,5
-Diamine 3-para-aminophenol
1 Polyoxyethylene stearyl ether 3 Methyl cellulose
1 lanolin 0.
5 Polyoxyethylene nonylphenyl 0.3 Ether monoethanolamine 3 Additives shown in Table 4 Amount of water shown in Table 4
Remaining total: 100.0% Hair color 2nd liquid Hydrogen peroxide solution (30%) 15% Polyoxyethylene stearyl ether 3 Triethanolamine lauryl sulfate 3 Methyl cellulose
1 citric acid
0.1 Additives shown in Table 4
Quantity of water shown in Table 4
Remaining total: 100.0%Next, sensory tests were conducted on the hair feel, scalp inflammation, moisturizing properties, hair moisture, and hair loss from the scalp during brushing using the following test and evaluation methods for each of the above treatment agents. The results are shown in Tables 1 to 4.
試料毛束
長さ20an、直径0 、07−0 、10wn(7)
バージン毛10gを毛流を揃えて束にし、毛根の方を糸
で固定したものを試験試料とした。Sample hair bundle length 20an, diameter 0, 07-0, 10wn (7)
A test sample was prepared by arranging 10 g of virgin hair into a bundle with the hair flow aligned and fixing the hair root with thread.
毛髪の感触の試験及び評価方法
試料毛束を上記処理剤で化学処理を施し、毛髪感触を官
能試験した。Hair feel test and evaluation method Sample hair strands were chemically treated with the above-mentioned treatment agent, and the hair feel was subjected to a sensory test.
毛髪の感触評価は次の5段階評価で行なった。Hair feel was evaluated using the following 5-level evaluation.
◎・・・櫛通しが非常に良く、キシミが全くない。◎...The comb combs very well and there is no crease at all.
O・・・櫛通しが良く、キシミも殆どない。O: Easy to comb through, almost no creases.
O′・・・櫛通しがやや良く、キシミがややある。O': Slightly good combability, with some creases.
Δ・・・櫛通しがやや悪く、キシミがある。Δ: The combing is a little difficult and there are creases.
×・・・櫛通しが悪く、キシミが非常にある。×: The comb is difficult to comb and has a lot of creases.
頭皮の炎症の試験及び評価方法
男女各3名計6名を被検者とし、頭皮に異常がないこと
を確認した後、上記処理剤で化学処理を施し、頭皮の変
化を観察した。Scalp Inflammation Test and Evaluation Method A total of 6 subjects (3 males and 3 females) were examined.After confirming that there were no abnormalities in the scalp, they were chemically treated with the above treatment agent and changes in the scalp were observed.
頭皮の炎症の評価基準は次の5段階評価で行なった・ ◎・・・頭皮の炎症が認められない。The evaluation criteria for scalp inflammation was as follows: ◎: No inflammation of the scalp is observed.
O・・・頭皮の炎症がほんのわずかに認められる人がい
る。O: There are some people who have slight inflammation of their scalp.
O″・・・頭皮の炎症が、わずかに認められる人がいる
。O''...Some people have slight inflammation of the scalp.
Δ・・・頭皮の炎症が認められる人がいる。Δ: Some people have scalp inflammation.
×・・・頭皮の炎症がかなり認められる人がいる。×: There are some people who have significant scalp inflammation.
保湿性の試験及び評価 法
試料毛束を上記処理剤で化学処理を施し、毛髪の保湿性
を官能試験した。Test and Evaluation of Moisture Resistance Method Sample hair bundles were chemically treated with the above-mentioned treatment agent, and the moisture retention property of the hair was subjected to a sensory test.
保湿性の評価は次の5段階で行なった。Moisture retention was evaluated on the following five levels.
◎・・・毛髪がしっとりし、パサつきが全くない。◎...Hair is moist and doesn't feel dry at all.
O・・・毛髪がしっとりし、パサつきが殆どない。O: The hair is moist and has almost no dryness.
○′・・・毛髪がややしっとりし、パサつきが少ない。○': Hair is slightly moisturized and less dry.
Δ・・・毛髪がややパサつく。Δ: Hair is a little dry.
X・・毛髪がかなリパサつく。X: Hair becomes dry and dry.
毛 水分の試験方法
試料毛束に対し、上記処理剤で化学処理を施し、毛髪を
25℃、65%で24時間放置後、カールフィッシャー
水分計で毛髪水分を測定した。Hair Moisture Test Method A sample hair bundle was chemically treated with the above treatment agent, and the hair was left at 25° C. and 65% for 24 hours, after which the hair moisture was measured using a Karl Fischer moisture meter.
ブラッシング時のプ から毛髪抜けの試験方法男女各2
名計4名を被検者とし、上記処理剤で化学処理をした後
、ブラッシングブラシによりブラッシングを行ない、頭
皮から抜ける毛髪の本数を数えた。Test method for hair loss during brushing: 2 for men and women
A total of four subjects were treated with the above-mentioned treatment agent, and then brushed with a brushing brush, and the number of hairs that fell out from the scalp was counted.
Claims (1)
有することを特徴とする毛髪用化学処理剤。 2、下記一般式(1) ▲数式、化学式、表等があります▼・・・(1) (m=0〜5) で示されるメチルシロキサン及び/又は下記一般式(2
) ▲数式、化学式、表等があります▼・・・(2) (p=3〜8) で示される環状メチルシロキサンを配合した特許請求の
範囲第1項記載の毛髪用化学処理剤。 3、カチオン化セルロース及び/又はポリビニルピロリ
ドンを0.1〜20重量%配合した特許請求の範囲第1
項又は第2項に記載の毛髪用化学処理剤。 4、奇数炭素鎖長脂肪酸誘導体及び/又は奇数炭素鎖長
アルコール誘導体を配合した特許請求の範囲第1項乃至
第3項のいずれか1項に記載の毛髪用化学処理剤。[Scope of Claims] 1. A chemical treatment agent for hair characterized by containing a methylsiloxane polymer having a degree of polymerization of 1000 or more. 2. The following general formula (1) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼... (1) (m = 0 to 5)
) ▲There are mathematical formulas, chemical formulas, tables, etc.▼...(2) (p=3 to 8) The chemical treatment agent for hair according to claim 1, which contains a cyclic methylsiloxane represented by the following. 3. Claim 1 containing 0.1 to 20% by weight of cationized cellulose and/or polyvinylpyrrolidone
The chemical treatment agent for hair according to item 1 or 2. 4. The chemical treatment agent for hair according to any one of claims 1 to 3, which contains an odd carbon chain length fatty acid derivative and/or an odd carbon chain length alcohol derivative.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15078687A JPS63313717A (en) | 1987-06-17 | 1987-06-17 | Chemically treating agent for hair |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15078687A JPS63313717A (en) | 1987-06-17 | 1987-06-17 | Chemically treating agent for hair |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63313717A true JPS63313717A (en) | 1988-12-21 |
Family
ID=15504400
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15078687A Pending JPS63313717A (en) | 1987-06-17 | 1987-06-17 | Chemically treating agent for hair |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63313717A (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02255608A (en) * | 1989-03-28 | 1990-10-16 | Pola Chem Ind Inc | Permanent waving agent |
JPH04295413A (en) * | 1991-03-15 | 1992-10-20 | Helene Curtis Inc | Agent and method for permanent wave |
JPH04308522A (en) * | 1991-04-04 | 1992-10-30 | Kao Corp | Two-pack hair-treating agent composition and hair-treating method |
JPH04334313A (en) * | 1991-05-08 | 1992-11-20 | Kao Corp | Dyeing agent composition for keratinous fiber |
EP0684036A1 (en) * | 1994-05-27 | 1995-11-29 | GOLDWELL GmbH | Composition for bleaching of human hair |
JPH0940534A (en) * | 1995-07-27 | 1997-02-10 | Shiseido Co Ltd | Hair dye composition of type mixed on employment |
JPH11130637A (en) * | 1997-10-30 | 1999-05-18 | Hoyu Co Ltd | Agent composition for permanent wave |
JPH11130638A (en) * | 1997-10-30 | 1999-05-18 | Hoyu Co Ltd | Agent composition for permanent wave |
JP2000319143A (en) * | 1999-05-06 | 2000-11-21 | Hoyu Co Ltd | Permanent wave agent composition |
JP2002226338A (en) * | 2001-02-05 | 2002-08-14 | Hoyu Co Ltd | Oxidative hair dye composition |
WO2004050049A1 (en) * | 2002-11-28 | 2004-06-17 | Kao Corporation | Composition for hair bleaching or hair dyeing |
JP2005314291A (en) * | 2004-04-28 | 2005-11-10 | Shiseido Co Ltd | Hair treating agent for permanent wave |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS616A (en) * | 1984-03-15 | 1986-01-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair conditioning composition |
JPS6248615A (en) * | 1985-06-06 | 1987-03-03 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair treatment mousse |
JPS63183517A (en) * | 1986-09-03 | 1988-07-28 | Shiseido Co Ltd | Hair cosmetic |
JPS63243019A (en) * | 1987-03-30 | 1988-10-07 | Shiseido Co Ltd | Hair cosmetic |
-
1987
- 1987-06-17 JP JP15078687A patent/JPS63313717A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS616A (en) * | 1984-03-15 | 1986-01-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair conditioning composition |
JPS6248615A (en) * | 1985-06-06 | 1987-03-03 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair treatment mousse |
JPS63183517A (en) * | 1986-09-03 | 1988-07-28 | Shiseido Co Ltd | Hair cosmetic |
JPS63243019A (en) * | 1987-03-30 | 1988-10-07 | Shiseido Co Ltd | Hair cosmetic |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02255608A (en) * | 1989-03-28 | 1990-10-16 | Pola Chem Ind Inc | Permanent waving agent |
JPH04295413A (en) * | 1991-03-15 | 1992-10-20 | Helene Curtis Inc | Agent and method for permanent wave |
JPH04308522A (en) * | 1991-04-04 | 1992-10-30 | Kao Corp | Two-pack hair-treating agent composition and hair-treating method |
JP2516284B2 (en) * | 1991-04-04 | 1996-07-24 | 花王株式会社 | Two-component hair treatment composition and hair treatment method |
JPH04334313A (en) * | 1991-05-08 | 1992-11-20 | Kao Corp | Dyeing agent composition for keratinous fiber |
JPH0791176B2 (en) * | 1991-05-08 | 1995-10-04 | 花王株式会社 | Keratin fiber dye composition |
EP0684036A1 (en) * | 1994-05-27 | 1995-11-29 | GOLDWELL GmbH | Composition for bleaching of human hair |
JPH0940534A (en) * | 1995-07-27 | 1997-02-10 | Shiseido Co Ltd | Hair dye composition of type mixed on employment |
JPH11130637A (en) * | 1997-10-30 | 1999-05-18 | Hoyu Co Ltd | Agent composition for permanent wave |
JPH11130638A (en) * | 1997-10-30 | 1999-05-18 | Hoyu Co Ltd | Agent composition for permanent wave |
JP2000319143A (en) * | 1999-05-06 | 2000-11-21 | Hoyu Co Ltd | Permanent wave agent composition |
JP2002226338A (en) * | 2001-02-05 | 2002-08-14 | Hoyu Co Ltd | Oxidative hair dye composition |
WO2004050049A1 (en) * | 2002-11-28 | 2004-06-17 | Kao Corporation | Composition for hair bleaching or hair dyeing |
JP2004175748A (en) * | 2002-11-28 | 2004-06-24 | Kao Corp | Hair-discoloring or hair-dyeing treating agent composition |
US7364595B2 (en) | 2002-11-28 | 2008-04-29 | Kao Corporation | Composition for hair bleaching or hair dyeing |
JP4564711B2 (en) * | 2002-11-28 | 2010-10-20 | 花王株式会社 | Decolorization or dyeing treatment composition for hair |
JP2005314291A (en) * | 2004-04-28 | 2005-11-10 | Shiseido Co Ltd | Hair treating agent for permanent wave |
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