SI9300482A - Hair treatment agent - Google Patents

Description

HENKEL KOMMANDITGESELLSCHAFT AUE AKTIEN

Postfach 10 11 '

D-4000 Dusseldorf 1, Germany

Inventors

1. Kurt Seidel, Nosthoffenstrasse 59, 4000 Dusseldorf 13, BRD

2. Dr. Reinhard Muller, Gottfried-Hausmann-Weg 13, 5140

Erkelenz 7, BRD ^!

3. Dr. Detlef Hollenberg, Fliederweg 31, 4006 Erkrath, BRD

4. Christian Priebe, Velberter Strasse 38, 5603 Wulfrath, BRD

Hair treatment

FIELD OF THE INVENTION

The subject matter of the invention is a hair treatment preparation with a special combination of polymers.

The state of the art and the technical problem of hair cleaning and care are an important component of human body care.

Both shampooing and decorative hair styling, such as dyeing or permanent curls, are interventions that affect the natural composition and properties of hair. For example, after such treatment, wet and dry combing of the hair, posture and fullness of the hair may be unsatisfactory or may show increased hair .....

cepian ie.

It is therefore common for a long time to undergo special hair treatments. The hair is usually treated in the form of a rinse with special active substances, for example quaternary ammonia salts or special polymers. This treatment improves, depending on the formulation of the combing ability, posture and fullness of the hair, and reduces the degree of cleavage.

Additions of cationic polymers to hair care products generally lead to improved wet and dry combing; the addition of amphoteric polymers to greatly improved wet combing, while the effect on dry combining is generally only minor.

Further positive effects can often be achieved by combining several active substances from different classes. Thus, for example, it is known from the German Opening File DE-A1--3044 738 to equip hair-dressing agents with a mixture of amphoteric and cationic polymers.

While the improvement of wet combinability, i. reduction of wet combustion work is desirable in all cases, the dry combustion conditions are more complicated. Low values of the work of combing indicate improvement of combing, but if the work of combing is reduced too much, they lose their hair posture and fullness, so that in the extreme case, certain hairstyles can no longer be done. Therefore, it may be desirable, especially for more complex hairstyles, to increase the dry combing work within certain limits in order to improve the posture of the hairstyle.

More surprisingly, it has now been found that agents with a combination of amphoteric or two-ion polymers and certain cationic polymers in the desired manner improve wet combing, while dry combing increases to an area that is optimal for posture hairstyles. This achieves both a distinct improvement in wet hair styling options and an increase in dry hair content. In addition, the treated hair shows good curling ability and good suspension force.

Description of the solution to the technical problem and implementation examples

The subject of the invention is thus an aqueous preparation for hair treatment containing, in addition to conventional cosmetic ingredients, a combination of cationic and amphoteric or two-ion polymers, characterized by terns, containing cationic polymers of the imidazoline group.

The cationic polymers of the invention are constructed from compounds containing, in addition to at least one cationic group, at least one group

O D V E T N I K

polymerizable and free of anionic groups.

The polymerizable group is preferably a vinyl group. However, cationic polymerizates are also useful in which the main polymer chain is formed, for example, from glycosides.

Common cationic groups are groups with quaternary nitrogen or phosphorus atoms. Groups with quaternary nitrogen atoms are preferred. Quaternary nitrogen atoms can thus bear both 4 different or partially identical substituents as well as part of the ring system. It is essential for the present invention that it contains at least part of the cationic group of quaternary nitrogen atoms which are part of the imidazoline ring. According to the invention, polymers containing at least 50% of the cationic groups of the imidazoline ring are preferred. Particularly preferred are such polymers in which imidazoline systems are the only cationic groups.

Imidazoline systems are preferably quaternary imidazoles containing only the polymerizable group as a substituent. Alternatively, such imidazoles may be used containing further substituents, in particular alkyl groups of 1 to 4 carbon atoms. Kvaterni .....

wounding may be effected by all known means of quaternary, e.g. dimethyl sulfate, diethyl sulfate and methyl chloride.

According to the invention, cationic copolymers containing at least one non-ionic monomer in addition to the cationic monomers are also preferred. Suitable non-ionic monomers are e.g. vinylpyrrolidone, vinyl acetate.

acrylamide, methacrylate, ethyl acrylate, methyl methacrylate and ethyl methacrylate. Vinylpyrrolidone is a particularly preferred non-ionic monomer.

Vinylimidazolinemethyl chloride / vinylpyrrolidone copolymerizers are e.g. commercially available under the code Luviquat ^R (BASF).

Among the cationic and nonionic monomers, preferred in the invention are those in which the ratio of cationic to nonionic monomers is in the range of 1.5: 1 to 1: 1.5. Copolymers in which the ratio of cationic and non-ionic monomers was approximately 1: 1 have proved particularly suitable according to the invention.

Under the umbrella term ampopolymers are included amphoteric polymers, ie. polymers containing both free amino groups and free -COOH- or SO- ^ H- groups in the molecule and capable of carrying out internal salts, two-ion polymers containing quaternary ammonium groups in the molecule and ~ C00 ~ - or - SO ^ ”- groups.

An example of a usable amphopolymer of the invention is an acrylic resin, obtainable under the designation Amphomer ^R , which represents a copolymer of tertiary butylarninoethylmethacrylate, N- (1,1,3,3-trambutyl 1) acrylamide, as well as two or more monomers of the group acrylic or methacrylic acids and their simple esters.

Further usable inventions of the f f-1 come from me are in English Opening File 2 104 091, European Opening File 47714,

the European Opening File 217 274, the European Opening File 283 817 and the German Opening File 28 17369 named compounds.

Particularly preferred are cbopol-ionic polymers consisting essentially of:

(c /) Quaternary ammonium monomers according to the general equation (T)

R ¹ -CH = CR ² -C0-X (C _n H _2n ) -N ^ ⁺⁾ R ³ R ⁴ R ⁵ A ^ ^- ) (I) in which R-'- and R ^{2 are} each independently hydrogen or methyl a group and R ³ , R ⁴ and R ³ an independently alkyl group having 1 to 4 C atoms, an X group of NH or an oxygen atom, n an integer of 2 to 5 and a (~) anion of organic or inorganic acid and ((b ) of the monomeric carboxylic acids according to general equation (II),

I

R ⁶ ~ CH ~ CR ⁷ -C00H (II) in which R ⁶ and R ^{7 are} each independently hydrogen or methyl.

These compounds can be used according to the invention both directly and in the form of salts obtained by the neutralization of polymerizates, for example by alkali hydroxide. Given the detail of the manufacture of these polymerizates, it is explicitly referred to the content of the German opening file 39 29 973.

Particularly preferred are such monomers based on (</) monomers in which R ³ , R ⁴ and R ^{3 are} methyl groups, X is an NH group and a halide, methoxy sulfate or ethoxysulfate ion; acrylarydopropyltrimethylammonium chloride is a particularly preferred monomer (Z). The acrylic acid or alkali salt of acrylic acid, in particular the sodium salt, is preferably used as the monomer C / 2?) For the named polymers.

In addition, two ionic polymers are preferred in which the number of monomers of type (</ -) is greater than the number of monomers of type (/ 2>). Particularly preferred are monomers with only a ratio of: (Z) greater than 1.5.

Both cationic and two-ion polymers are preferably contained in the compositions of the invention in amounts of 0.01 to 10% by weight relative to the total preparation. Quantities from 0.01 to 5% by weight are particularly preferred.

Preparations containing cationic and amphoteric or two-ionic polymers in the ratio of 10: 1 and 2: 1 monomers have proven to be particularly effective.

It was further found that a particularly good resolution of D V E r N i K was achieved

MILCSAV rmfeiifiOilS

61000 Liubi'aa. 17?

thieves according to the invention according to the invention, if the preparations according to the invention contain an additional surfactant. This may be an anionic, cationic, ampholytic, two-ionic or non-ionic surfactant.

Examples of cationic surfactants useful for hair treatment agents of the invention are, in particular, quaternary ammonium compounds. Preferred are ammonium halides such as alkyltrimethylammonium chloride, dialkyldimethylammonium chloride and trialkylmethylammonium chloride, e.g. cetyltrimethylammonium chloride, stearylthiethylmethylammonium chloride, distearyldimethylammonium chloride, laurildimethylammonium chloride, laurildimethylbenzylammonium chloride and tricethylmethylammonium chloride. Further cationic surfactants useful in the invention are protein hydrolysates.

According to the invention, cationic silicone oils are also useful commercially available products 02-7224 (manufacturer: Dow Corning; stabilized trimethylsilylamodimethicone), Dow Corning 929 emulsion (containing hydroxyl-amino-modified silicone, also referred to as Amodimethicone), SM - 2509 (General Electric manufacturer), SUM ..... 55067 (manufacturer: Wacker) as well as Abil ^R Quat 3270 and 3272 (manufacturer: Th. Goldschmidt; diquaternary polydimethylsiloxane, Ouaternium - 80).

Alk 1 amidoary, especially fatty acid amidoamines such as under the Tego Amid ^R S18 labeled stear i larnidoprop ldime ti lami n, are distinguished in addition to their good conditioning effect, especially by their good biodegradability.

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Also very good biodegradable quaternary ester compounds, so-called Esterguats, such as under the trade mark Stepantex ^R distributed dialkilamoniummetosulfat and methyl-hidroksilalkildialkoiloksialkil-Amonium metosulfat.

The quaternary sugar derivative used as a cationic surfactant is the commercial product Glucquat ^R 100, according to the CTFA -nomenclature Lauril-Methyl-Gluceth-10-Hydroxypropyl Dimonium Chlorid.

Particularly preferred cationic surfactants are alkylamidoamines, quaternary ester compounds and quaternary sugar derivatives.

As anionic surfactants, suitable for the use on the human body are suitable anionic surfactants. They are characterized by a water-soluble anion-releasing group such as e.g. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group of about 10 to 22 C atoms. They may additionally be contained in the molecule of the glycol or polyglycol ester group, the amine ester group as well as the hydroxyl group. Examples of suitable anionic surfactants are, in each case, in the form of sodium, potassium and ammonium, as well as mono-, di- and trialkanol mono salts with 2 or 3 C atoms in the alkanol group.

- linear fatty acids with 10 to 22 C atoms (soaps)

- ethercarboxylic acid of the formula R-O- (CHo-CH _o O) -CH-COOH, in which R represents a linear alkyl group having 10 to 22 C atoms, and

O D V E Ύ N f K χ = 0 or 1 to 13,

- acyl sarcosides with 10 to 18 C atoms in the acyl group,

- acyltaurids having 10 to 18 C atoms in the acyl group,

- acylisethionates having 10 to 18 C atoms in the acyl group,

- a sulfo-succinic acid sulpho-succinic acid mono and dialkyl ester of 8 to 18 alkyl groups and a sulfo-succinic mono-alkyl polyoxyethyl ester of 8 to 18 C atoms of alkyl and 1 to 6 oxyethyl groups

- linear alkanesulfonates having 12 to 18 C atoms,

- linear alpha-olefinsulfonates having 12 to 18 C atoms,

- alpha-sulfo-fatty acid methyl ester of fatty acids with 12 to 18 C atoms,

- alkylsulphates and alkylpolyglycoletersulphates according to the formula R-OCCl · CH ₂ O) _x -OS0 ₃ H, in which R is preferably a linear alkyl group having 10 to 18 C atoms and x = 0 or 1 to 12,

- mixtures of surfactant hydroxysulfonates according to DE-A-37 25 030,

- sulfated ethers of hydroxyalkyl polyethylene and / or hydroxyalkylene propylene glycol according to DE-A-37 23 354,

- Sulfonates of unsaturated fatty acids having 12 to 24 C atoms and 1 to 6 double bonds according to DE-A ~ 3926344,

- tartaric acid and citric acid ester with alcohols representing the accumulated products of about 2 - 15 ethylene oxide and / or propylene oxide molecules on fatty alcohols of S to 22 C atoms.

Preferred anionic surfactants are alkylsulfates, alkylpolyglycoletersulfates, and ether carboxylic acids with 10 to 18 C atoms in the alkyl group and up to 12 glycol ether groups in the molecule, as well as rnono and

dialkyl ester sulfo-succinic acid with 8 to 18 C atoms in the alkyl group and mono-alkyl polyoxyethyl ester sulfo succinic acid with 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups.

Such surfactants are those surfactants which carry in the molecule at least one quaternary ammonium group and at least one group with COO ^ ^- ) or SO · ^ ^- ) especially suitable two-ion surfactants are so-called betaines as N-alkyl-N, N-dimethylammonium- glycinate, for example cocosalkyl dimethyl ammonium glycinate, N-aci 1-aminopropyl 1-N, N-dimers, and 1-arnones are dimethylated, e.g. cocosacylaminopropyl-dimethylammoniumglycinate and 2-alkyl-3-carboxymethyl-3-hydroxyethyl-imidazoline with 8 to 18 C atoms in each alkyl or acyl group as well as cocosacylamino-ethylhydroxyethylcarboxymethylglycinate. The preferred two-ion surfactant is a known fatty acid amide derivative under the CTFA code Cocamidopropyl Betaine.

Ampholytic surfactants are understood to mean such surfactants containing at least one free amino group and at least one COOH or SO3H group in the molecule, other than a C 1 -C 6 alkyl or acyl group, capable of forming internal salts. Examples of suitable ampholytic surfactants are N-alkylglycines. N-alkylpropionic acid, N-alkali laminated butyric acid. Nalkyliminodipropionic acid, N-hydroxyethyl-Lalk lamidopropylglycine, N-alky 1 -turine, N-alkyl-sarcosin, 2alkylaminopropionic acid and alkyl-amino-acid acid with about 8 to 18 C atoms each in the alkyl group. Especially lite?

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* · «; 1- f., <! // preferred ampholytic surfactants are N-cocosalkylaminopropionate, cocosacylaminoethylaminopropionate and C12-I8 "acylsarcosine.

Non-ionic surfactants contain as hydrophilic group e.g. a polyol group, a polyalkylene glycol etei group or a combination of polyol and polyglycol ether groups. Such compounds are, for example:

- additive products of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide on linear fatty alcohols of 8 to 22 C atoms, of fatty acids of 12 to 22 C atoms and of alkylphenols of 8 to 15 C atoms in an alkyl group,

- C | 2 ~ ^ 22 ~ mono- and diester fatty acids of additive products with 1 to 30 moles of ethylene oxide per glycerin,

- Cg - C ₂ 2 -alkylmono- and oligoglycosides and their ethoxylated analogs as well as

- Additive products of 5 to 60 moles of ethylene oxide on castor oil and hardened castor oil.

Compounds used as surfactants with alkyl groups may each be single substances. As a rule, however, it is preferable to proceed from the manufacture of these substances from native plant or animal raw materials, so that mixtures of the substance with different alkyl chain lengths independent of the raw material are obtained.

With surfactants. which represent the additive products of ethylene and / or propylene oxide on fatty alcohols or derivatives of these additive products, both products with a normal homologous distribution and those with a reduced

homologous distribution. Normal homogeneous distribution refers to mixtures of homologens obtained from the conversion of fatty alcohol and alkylene oxide when using alkali metals, alkali metal hydroxides or alkali metal alcohols as catalysts. Narrowed homologeneous distributions, however, are obtained when, for example, hydrotalicytes, the alkali metal salts of ether carboxylic acids, oxides, hydroxides or alcoholates of the alkaline earth metals are used as catalysts. The use of products with a narrow homologous distribution may be preferred.

The amount of surfactant contained in the compositions according to the invention depends on the type of surfactant and the purpose of use of the preparation.

The hair post-treatment agents preferably contain cationic and / or non-ionic surfactants, in particular in amounts of 0.1 to 10% by weight relative to the total preparation. Quantities between 0.1 and 3% by weight are particularly preferred.

Hair treatment preparations also preferably contain cationic and / or non-ionic surfactants, in particular in amounts of 0.1 to 10% by weight, based on the total preparation. Quantities between 0.1 and 5% by weight are particularly preferred.

shampoos preferably contain anionic surfactants, optionally in combination with ampholytic and / or nonionic surfactants, in particular in amounts of from 1 to 50% by weight, based on the total preparation.

4 '

Quantities between 3 and 20% by weight are particularly preferred.

The compositions of the invention preferably exhibit pH values of 2.5 to 7, in particular 3 to 6.

shampoos, hair conditioners and hair treatments are preferred preparations of the invention. The preparations may also be preparations for permanent curling, dyes, hairdryers and other common hair treatments.

The formulations may be formulated as aqueous or aqueous-alcoholic solutions, creams, lotions, jellies, emulsions as well as other conventional cosmetics in cosmetics.

All the known further ingredients may contain the appropriate type of hair conditioner and form of dressing.

- non-ionic surfactants such as e.g. vinylpyrrolidone / vinyl acrylate copolymers, polyvinyl pyrrolidone and vinylpyrrolidone / vinyl acetate copolymers and polysiloxanes, anionic polymers such as e.g. polyacrylic acid, cross-linked polyacrylic acid, copolymer of vinyl acetate / crotonic acid, vinylpyrrolidone / vinyl acrylate copolymer, vinyl acetate / butyl maleate / isobornyl acrylate copolymer, maleic acid anhydride / terrylacrylate anhydride copolymer

- further cationic polymers such as quaternized cellulose ether, polysiloxane with quaternary groups, acrylamide / dimethyldialylammonium chloride copolymers as well as diethyl .....

sulfate quaternary dimethylaminomethacrylate / vinylpyridone copolymers,

- thickeners such as agar-agar, guar-gum, alginate and xanthan gum,

- Structures such as glucose and maleic acid,

- hair conditioners such as phospholipids, for example soyalacitin, egg lecithin and cephalin. as well as silicone oils,

- protein hydrolysates, in particular the hydrolysates of collagen, keratin, milk, egg whites, soyaprotein, almond protein, pea protein, potato protein, maize protein and cereal protein, their condensation products with fatty acids as well as quaternized protein hydrolysates, ·orb parfumidyls, and cyclodextrin,

- solution brokers as. are ethanol, isopropanol, ethylene glycol, propylene glycol, glycerin and diethylene glycol,

- colorants

- dandruff active substances such as pyroctone, olamine and zinc omadine,

...... further substances for pH adjustment, • active substances such as panthenol, allanthion, plant extracts, and therein,

- light protectants, consistency providers such as sugar ester, polyolester or po 61000 L o Kitty in Hi \ 7 lioalkyl ether,

- fats and waxes such as whale fat, beeswax, montane wax, paraffin and fatty alcohols,

- fatty acid alcoholamides,

- complex agents such as EDTA, NTA and phosphonic acid,

- swelling and penetration agents such as glycerin, propylene glycol monoethyl ether, carbonate, hydrogen carbonate, guanidine, urea as well as primary, secondary and tertiary phosphates,

- latex tempering agents,

- pearl gloss agents such as ethylene glycol monostearate and distearate,

- Propellants as mixtures of propane-butane, N ₂ 0, dimethyl ether, C0 ₂ and air as well

- antioxidants

- direct drawing dyes,

- so-called coupling and development components as pre-products of oxidising dyes,

- reducing agents such as e.g. thioglycolic acid and its derivatives, thiolactic acid, cysteamine, thio-malic acid and

- mercaptoethanesulfonic acid,

- Oxidizing agents such as hydrogen peroxide, potassium bromate and sodium bromate.

The subject of the invention is also a method of treating hair with the composition of the invention. ΐ _;

Preferred is a method whereby the compositions of the active compound of the invention are applied to the hair and, after a certain period of action, typically lying between a few seconds and about 20 minutes, are rinsed again with water or an agent containing essentially water.

The following examples should explain the subject of the invention in more detail.

Examples

I. Determination of wet and dry combustion

I

Investigation method

The basis of the research on combing is the method according to J.Soc. Cosm. Chem. 1973 (24) 782.

Each time the work of combing on brown hair (Alkinco 6634, length of strand 12 cm, weight of strand 1 g) was investigated, it was lightly damaged (cold curled or blonded) hair, as expected for the average user. After zero measurement, the strands were filled with 100 ml of the test recipe. After 5 minutes of sc activity, the hair was rinsed for 1 minute under running water (1 L / min, 38 ° C). The strands were then re-measured to determine wet combing work.

To determine dry combing work, the strands were first dried for 12 hours at 30 ° C at a relative humidity of 20% and then measured again.

The result

The composition of the mixtures tested as well as the results of measurements of combing work are shown in Table 1. The values for combing work refer to the value of the zero measurement each time; their statistical reliability was 99.99%.

- 19 O tA 4 CO O IO «. ·> ·.«. »> TO O O O H

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O o B »» oo o tO

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O tO 4- CO O O

4 · ·> ·> *> »·> II * i> tO O O O H 00

4 · O) o- m rH

Table 1 / Data on quantities in mass parts /

Oh LO 4 00 o OJ o co that. rH ·> »· r * r » r » ♦ »· * 1 Φ that w that o o o rH About 4- / ~ 1 OJ ^ • 1 c J ) r- 1 o that 4 · co Oh Oh that o ro ·> ·> r » · » τ and t> H !> that o o o rH 1 4 · 1 a > OJ o that 4 · 00 Oh OJ Oh LO OJ ·> »> »· e · * 1 1 4 · 00 that o o o rH Oh

OJ tO lo 4 ·

Oh LO 4- 00 o oo rH 00 rH »» ·> ·> r <* 1 1 1 ί> that o Oh o rH s 1 / r » o o ra this) d d \ • rl rH that 1 r — 1 Oh rH ra a CO., LTD • H • rl • rl Pn 44 co Oh m OJ iR. \ (4 ra d \ ra \ ra \ P. d o co • ro TO \ Oh rH P that ra ra ra ra d • rl • P TO ra ra ro to ra • rl H ra M d rH • ro rH d ra TO a d o ra d ro • ro d ra ra that n • H n • H ra ra ra ra r-l \ N o o ra d ra d ra ra n ra • rl ra A LOO > o Oh ra ro> υ rH ra B H that 4 d «D d LO S » P > o P > o N OO rH OJ 44 • rl ra r 1 ra d • d ro • H X. r-l OJ ra P P rH O LO this) Oh ra about that) d ra ro that ω ff) «LO Oh • rl Ph Ph LO ra 44 ho 44 ra ra this) • P rH Sl « « o d H N «O- P ra ! P P ra d 0 d d « ra 44 • rH P -P « 44 Oh -d 2 • r, d ra « « • rl • rl rH a a rH ra ra 4 ^ Oh d d d o d d d rH that ho S) Oh • rl d ra a d ro a • d ra d, B d ra o Oh d rH H d rH • rl P • rH σ 'd ra ra o A d • H P d ra 0 d -P rH • rl o ¹ ro o H o H O rH o S ra -P a P » A o Oh p »<p d rH d rH Λ rH d rH Oh • P d § d d Oh a ra ht d ro o ra ra ra ra M ω o w w W M ra d A O> o 1 A 1 Q 1 A

blond hair 95 256 ^C 16 / ^(: J8 fatty alcohol (HENKEL) ² glycerin monostearate (CTFA code: Glyceryl Stearate) (HENKEL)

° Cetylstyrylalcohol z around 12 prays EO (CTFA tag: Ceteareth-12) (HENKEL) ⁴ Cetylstyrylalcohol z around 20 prays EO (CTFA tag: Ceteareth-20) (HENKEL) ⁵ condensation, product from saturated liquids ma stingy alcoholic

hunting, predominantly dioyl alcohol, made by the reaction of Guerbet (CTFA code: Octyldodecanol) (HENKEL) and ' ⁶ vinylimidazolinemethyl chloride / vinylpyrrolidone copolymer (50:50) (mean molecular weight: about 8,000 Daltons; 40% active substance; CTFA code: Polyquaternium 16) (BASF) ⁷ vinylpyrrolidone / dimethylaminoethylmethacrylate copolymer, quaternized diethyl sulfate (19% active substance in water) (GAF)

The results show that the use of the composition according to the invention leads to the desired improvement in wet combing work (the area to be achieved lies at values around and below 70) while increasing the dry combing work to an area of about 230 - 270, which is optimum to hold a hairstyle.

II. Examples of use

The quantities given in the following examples are by weight%.

1. Rinse your hair

Stanol ^R 1610 1.8 Tegoamide ^R S 18 ⁸ 1.6 1,2-Propylene glycol 1.0 Citric acid 0.6 Luviquat ^R FC 550 1.0 Polymer Pl, according to DE 39 29 973 0.2 Perfume oil, water ad 100

⁸ N, N -dimethyl-N'-stearoyl-1,3-diamino-propane (CTFA code: Stear amidopropyl Dimethylamine) (GOLDSCHMIDT)

2. Rinse your hair

S tonol ^R 1618 1.8 Stepantex ^R VS 90 ⁹ 1.8 1,2-Propylene glycol 0.7 Citric acid 0.2 Luviquat ^R HM 552 ^6a 2.5 Polymer Pl, according to DE 39 29 973 0.4 Perfume oil, colorant,

water ad 100 ⁹ N-methyl - N (2-hydroxyethyl) -N, N-di (tallow acyloxyethyl) ammonium methosulphate (90% of the active substance in isopropanol) (STRPAN) copolymerisate of vinylimidazolineinchloride / vinylpyrrolidone (50:50) (medium molecular weight mass: about 800,000 daltons: 20% of the active substance; CTFA code: Polyquaternium 16) (BASF)

3. Rinse your hair

Stanol ^K 1618 2.5 EumulginRB 1 1.0 Eumulgin ^R B 2 1.0 Cutina ^R CP ¹⁰ 1.0 Eutanol ^R G 0.5 Polawax ^R GP 200 ¹¹ 0.75 Abil ^R Quat 3270 ¹² 0.5 Dow Co rni ng ^R 929 -em ulzia- * · ³ 2.6 L.uviquat ^R FC 370 ¹⁴ 0.8 Amphomer ^R 0.8 Citric acid' 0.02

Water ad 100 ¹⁰ Saturated, long-chain fatty alcohol and fatty acid esters, in particular palmitic acid cetyl ester (CTFA code: Cetyl Palmitate) (HENKEL)

- * · ¹ mixture of stearyl alcohol ~ polyethylene glycol stearate (CTFA code:

Stearyl Alcohol (and) PEG-Stearate (CRODA) zp, diquaternal polymethylsiloxane (CTFA code: Ouaternium - 80) (GOLDSCHMIDT) arn.ino ~ functional polydimethylsiloxane (35% active ingredient) (DOW CORNING) copolymerisate vinylimidazolinomethyl pyrrolidinolinomethyl pyrrolidine meth \

(30:70) (40% active substance; CTFA code: Polyquatern.ium -16) (BASF) methyl methacrylate / tert copolymer. butylaminoethylmethacrylate / 2-hydroxypropylmethacrylate / N - (1,1,3,3-tetramethylbutyl) acrylamide (DELFT NATIONAL)

I

4. Hairwashing

Rewoquat ^R W 7500 ¹⁶ 1.1

Lanette ^R 0 ¹⁷ 3.0

Eumulgin ^R B 1 0.8

Eumulgin ^R B 2 1.6

Cutin ^R GMS 0.5

Eutariol ^R G 1.0

Luviquat ^R HM 552 1.2

Polymer Pl, according to DE 39 29 973 0.4

Water ad 100 ¹⁶ i ~ methyl ~ 2 ~ nortalgalkyl-3 ~ tallow ~ fatty acid- arydoethyl ethyldazoline methosulfate (about 75% active substance) (REWO) a mixture of higher, saturated fatty alcohols, predominantly cetyl alcohol and stearyl alcohol (CTFA code: Cetearyl Alcohol) HEiNKEL)

5. shampoo

Texapori ^R N 25 ¹ ® 43,0 Dehy tori ^ KJ '' ⁷ 10,0 Plantar ^R -1200 ²⁰ 4.0 Euperlan ^R PK 3000 ²¹ 1.6 Arquad ^R 316 ²² 0.5 Luviquat ^R FC 550 1,2 Polymer Pl, according to DE 39 29 973 0.2 Glucamate ^R DOE 120 ²³ 0.5 At three. hydrochloride 0.2 Water ad 100

18 on the trio lauriletersulfate (about 28% active substances; CTFA label: Sodium Laureth Sulfate) (HENKEL) 19 amidderivat fatty acids with betaine composition equations:

R-C0NH (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ C00 "(about 30% of active substance; CTFA code: Cocoamidopropyl Betaine) (HENKEL) ^C J2 ' ^C .16" alkyl alkyl glucoside with an oligomerization rate of 1.4 ( around

50% of the active substance; CTFA code: Lauryl Polyglycosid (HENKEL) ²¹ Liquid dispersion of pearly luster and amphotenside (about 62% of active substance; CTFA code: Glycol Distearate (and) Laureth-4 (and) Cocoarnidopropyl Betaine) ( HENKEL)

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t.ri-C ₁₆ ~ alkylmethylammonium chloride (AKZO) ²³ ethoxylated rnetylglucoside diolate (CTFA code: PEG-120 Methyl Glucose Dileate) (AMERICHOL)

6. Chess no n

Texapon ^R N 70 ²⁴ 21.0 Plantar ^R ~ 1200 8.0 Genetic. n ^R DSAC ²⁵ 1,2 Cutina ^R EGMS ²⁶ 0.6 Luviquat ^R FC 370 2.0 Polymer Pl, according to DE 39 29 973 0.3 Antil ^r 141 1iquid ²⁷ 1.3 Sodium chloride 0.2 Water ad 100

²⁴ sodium laurylethersulfate (about 72% of active substance) (HENKEL) dimethyldistearylarnonium chloride (HOECHST) ²⁶ ethylene glycol monostearate (about 25-35% monoester, 60-70%; CTFA code: Glycol Stearate) (HENKEL) o * 7 polyoxyethylene-propylene ethylene-propylene ethylene glycol % of active substance; CTFA code: Propylene Glycol (and) PED-55 Propylene Glycol Oleate (GOLDSCHMIDT)

7. Shampoo

Texapon ^R K 14 S ²⁸ 50.0 Dehyton ^R K 10,0 Akypo ^R RLM 100 NV ²⁹ 4.5 Cutina ^R AGS ³⁰ 2.0 D-Pantenol 0.5 Glucose 1.0 Salicylic acid 0.4 Sodium chloride 0.5 Polymer Pl, according to DE 39 29 973 0.6 Luviquat ^R HM 552 1.0 Water ad 100

sodium laurylmi ristylethersulfate (about 28% of active substance; CTFA code: Sodium Myreth Sulfate) (HENKEL) ^c 12-.l4 “Fatty alcohol +, .10 ethylene oxide-acid acid sodium salt (2% of active substance; CTFA code: Sodium Laureth- 11 Carboxylate) (CHEM-Y)

3 ° ethylene glycol stearate (about 5-15% monoester, 85-95% diester; CTFA code: Glycol Distearate) (HENKEL)

8. Shampoo

Texapon ^h, K 14 s 25,0 Texapon ^R SB 3 ³ 1 7.5 Eucarol ^ FA ³² 12,0 Akypo ^R RLM 100 NV 9.0 Dehyton ^R AB 30 ³³ 8.3 Elfacos ^R CT 282S ³⁴ 0.5 Sodium chloride 0.5 Polymer PJ, according to DE 39 29 973 0.6 Luviquat ^R FC 550 4.0 Water ad 100

Alkyl polyglycolester sulphonic acid polyester, Di-Na-Sol (about 40% of active substance; CTFA code: Disodium Laurethsulfosuccinate) (HENKEL) ³² lauryl alcohol - + 7 ethylene oxide tartrate sodium salt (about 25% of active substance; CTFA code: Sodium Laureth-7 Tartrate (AUSICHEM) fatty amine derivative with betaine composition (about 30% of active substance; CTFA code: Coco-Betaine) (AKZO) ⁰⁴ talc + 60 ethylene oxide myristylether (CTFA code Talloweth -60 Myristyl Glycol) (AKZO )

9. Medicinal package (flush)

Stanol ^R 1618 3.0

Eumulgin ^R B 1 0.5

Eumulgin ^R B 2 0.5

Cutina ^R CP 1.0

Euthanol ^R G 1,5

Carbopol 980 ³³ 0.004

Dow Corning ^R 929-emulsion 2.9

Polymer Pl, according to DE 39 29 973 0.3

Luviquat ^R FC 550 4.0

Water ad .100 polyacrylic acid (GOODRICH)

10. Health Pack (stay on hair)

Celquat ^R L. 200 ³⁶ 0.6

Luviskol ^R K30 ³⁷ 0.2

D-Pantenol '0.5

Dehyquart ^R SP ³⁸ 1.0

Nutrilan ^R I ³⁹ 1.0

Natrosol ^R 250 HR ⁴⁰ 1.1

Luviquat ^R FC 370 0.7

Polymer Pl, according to DE 39 29 973 0.5

Water ad 100 ³⁶ Quaternary cellulose derivative (95% active substance; CTFA code: Polyquaternium-4) (DELFT NATIONAL) ³⁷ polyvinylpyrrolidone (95% active substance: CTFA code: PVP) ³⁸ aqueous r. oxyethylalkylammonium phosphate solution (about 50% active substance; CTFA code: Quaternium ~ 52) (HENKEL) ³⁹ collagen hydrolyzate (about 39% active substance; CTFA code Hydrolyzed Collagen) (HENKEL) ⁴⁰ hydroxyethyl cellulose (AOUALON)

11. Dye cream

C12 ~ 18-fat alcohol 1,2 L.anette ^R 0 4,0 Eumulgin ^R D 2 0,8 Cutina ^R LD 16 ⁴¹ 2,0 Sodium sulfite 0,5 L (+) - ascorbic acid 0,5 Ammonium sulfate 0 , 5 1,2-Propylene glycol 1,2 Polymer JR ^R 400 ⁴² 0.3

ATTORNEY

61000 LituO'cc. Cc: o'.čKa 17?

p-Aminophenol 0.35 p-To lu i1endi am i n 0.85 2-Methi1resorcin 0.14 6 ~ Methi1-m-aminophenol 0.42 Polymer Pl, according to DE 39 29 973 0.7 Luviquat ^R FC 550 1.0 Ammonia 1.5 Water ad 100

⁴¹ fatty acid mixture mono / diglyceride emulsifier (CTFA code Tallow Glycerides (and) Glyceryl Stearate (and) Potassiurn Stear · ate) (HENKEL) ⁴ 2 Quaternary hydroxyethyl cellulose (Union Carbide)

12. Developmental emulsion for coloring cream 11,

Texapon ^R N 25 2.1 Hydrogen peroxide 12,0 Turpinal ^R SL ⁴³ 1.7 Latekoll ^R D ⁴⁴ 12,0 Polymer Pl, according to DE 39 29 973 0.1 Luviquat ^R FC 550 0.9 Water ad 100

⁴³ 1-Hydroxyethane-1,1-diphosphonic acid (60% of active substance

CTFA code: Etidronic Acid (HENKEL) ⁴⁴ Acrylester - methacrylic acid copolymer (25% active substance) (BASF) ¹

The coloring cream had a pH value of 10.0. It caused intense red hair color.

13. Shade Shampoo

Texapon ^R N 70 14,0 Dehyton ^R K Akypo ^R RLM 45 NV ⁴⁵ 10,0 14.7 Plantar ^R -1200 4.0 Cremophor ^R RH 40 ⁴ ^ 0.8 The dye C.I. 12 719 0.02 The dye C.I. 12 251 0.02 The dye C.I. 12 250 0.04 The dye C.I. 56 059 0.03 PHB-Ester Luviquat ^R FC 370 0.25 1.6 Polymer Pl, according to DE 39 29 973 0.3 Perfume oil q.s.

Water ad 100 ⁴⁵ lauryl alcohol + 4,5 ethylene oxide-acid acid-sodium salt (20,4% active substance) (CHEM-Y) castor oil, hydrated + 45 ethylene oxide (CTFA code: PEG-40 tlydr ogenated Castor Oil) (BASF -)

When washing hair with this shampoo for shades, it has a shimmering, loblond shade.

14. Cream for permanent curling

Curling Cream:

Plantar ^R ~ 800 ⁴⁷ 5.0 Thioglycolic acid 8.0 Turpi nal ^R FIG 0.5 Ammonia (25%) 7.3 Ammonium carbonate 3.0 Chets 1 / Stearyl ~ Alcohol 5.0 Geurebet-Alcohol 4.0 Luviquat ^R HM 552 i; s Polymer Pl, according to DE 39 29 973 0.1 Perfume oil q. s. Water ad 100

⁴ C ₈ - C | q - alkylglucoside with an oligomerization rate of 1.6 world (ca.

60% of the active substance) (HENKEL)

Fixing solution:

Plantar ^R -800 5.0

Hardened Castor Oil 2.0

Potassium bromate 3.5

Nitrilotriacetic acid 0.3

Citric acid 0.2

Polymer Pl, according to DE 39 29 973 0.2

L.uviquat ^R FC 550 1.0

Perfume Oil q.s.

Water ad 100

Claims (13)

PATENT APPLICATIONS An aqueous hair treatment preparation, comprising, in addition to conventional cosmetic ingredients, a combination of cationic And amphoteric or two-ion polymers, characterized in that they contain cationic polymers of the imidazoline group. A preparation according to claim 1, characterized in that the cationic polymer contains at least one non-ionic monomer. A preparation according to claim 2, characterized in that the non-ionic monomer is vinylpy rolidone. A preparation according to any one of claims 1 to 3, characterized in that it contains a two-ion polymer. A preparation according to claim 4, characterized in that the two-ion pole are ..... ery essentially From the (cZ) monomer equations (I) the quaternary is not ammonium with k u p i n a m i po s p 1 o w n i R ¹ ..... PH CR ' CO-Z- iC, .TU _n ) -N tl Z. I 1 1 ° in which R and R mutually independently hydrogen or a methyl group; m R'-, R ¹ and R ^ independently of each other an alkyl group with 1 to 4 C atoms, With an NH group or an oxygen atom n even 1 to 2 Av to 5 and the anion of organic or inorganic acid i n (j monomeric to carboxylic acids according to general equation (II), R ⁶ -CH-CR ⁷ 'COOH (II) in which R ⁶ and R ^{7 represent} , independently of one another, a hydrogen or methyl group, or the alkali, alkaline earth, aluminum or ammonium salts of these acids. A preparation according to claim 5, characterized in that the monomer of the type (c / ..) is acrylamidopropyl-trimethyl-ammonium chloride And the monomer of the type (β) is an acrylic acid or an alkali salt, in particular the sodium salt, of acrylic acid. A preparation according to claim 5 or 6, characterized in that in the two-ion polymer the number of monomers of type (λ) is greater than the number of monomers of type 0). A preparation according to any one of claims 1 to 7, characterized in that contains. 0.01. -10 , especially 0.01 to 5 mass h amphoteric or two-ion h half the names and n ..... 0,0 1 - 10, Evil: with you. 0.01 to 5 fat 1. cationic 1 name each, each! ·, i a t with respect to the whole preparation A preparation according to any one of claims 1 to 8, further comprising surfactant. A preparation according to claim 9, characterized in that the surfactant is cationic and / or non-ionic surfactant. A preparation according to any one of claims 1 to 10, characterized in that the preparation exhibits a pH value between 2.5 and 7, in particular between 3.0 and 6.0. 12. A method for treating hair, characterized in that it is applied to the hair preparation according to one of claims 1 to 11. Method according to claim 12, characterized in that the hair is then rinsed with water or with a substance containing substantially water. 61000 Liiiblj.na. Cesovbra 177 SUMMARY Hair treatment Use of aqueous hair treatments containing a combination of imidazoline groups containing cationic polymers with amphoteric ones. or two-ion polymers, leads to very good wet hair combing when moving dry comb to an area that is optimal for posture hairstyles.