SI9300480A - Hair treatment agent - Google Patents

Description

D-Dusseldorf 1, Germany

Invent calf and

1. Kurt Seidel, Nosthoffenstrasse 59, 4000 Dusseldorf 13, BRD

2. Dr. Reinhard Muller, Gottfried- ~ Hausmann-Weg 13, 5140 Erkeleriz 7, BRD

3. Dr. Detlef Hollenberg, Fliederweg 31, 4006 Erkrath, BRD

4. Christian Priebe, Velberter Strasse 38, 5603 Wulfrath, BRD

Hair treatment

FIELD OF THE INVENTION

The field of the invention is a hair treatment preparation with a special combination of polymers

Technical problem and state of the art Hair cleaning and care is an important component of human body care. Both shampooing and decorative hair styling, such as coloring or permanent curls, are interventions that affect the natural composition and properties of hair. For example, wet and dry combing of hair, posture and fullness of hair may be unsatisfactory after such treatment, or the hair may show increased hair splitting.

It is therefore common for a long time to undergo special hair treatments. The hair is usually treated in the form of a rinse with special active substances, for example quaternary ammonia salts or special polymers. This treatment improves depending on the formulation of combing ability, posture and fullness of the hair and reduces the degree of cleavage.

Additions of cationic polymers in hair treatments generally lead to improved wet and dry combing; the addition of amphoteric or two-ion polymers to greatly improved wet combing, while dry combining is generally only minor.

Further positive effects can often be achieved by combining several active substances from different classes. Thus, for example, it is known from the German opening file DE-A1-3O44 738 to equip hair treatment agents with a mixture of amphoteric and cationic polymers.

While the improvement of wet combinability, i. Reduction of wet combustion is desirable in all cases, the conditions of dry combing are more complicated. Low values of the work of combing indicate improvement of combing, but if the work of combing is reduced too much, they lose their hair posture and fullness, so that in the extreme case, certain hairstyles can no longer be done. Therefore, it may be desirable, especially in the case of more complex hairstyles, in certain mea- sures, to increase the work of dry comb to improve the posture of the hairstyle.

It is surprising to find that agents with a combination of dopant ion polymers and certain cationic polymers improve the properties of hair in a presentably good way.

Solution to a technical problem with description of implementation examples

I

The subject of the invention are, therefore, guided hair treatments containing, in addition to conventional cosmetic ingredients, a combination of cationic and bipolar polymers, characterized in that the cationic polymers are cellulose derivatives and do not contain imidase .....

line groups.

The useful cationic polymers of the invention are cellulose derivatives.

The class of these cellulose derivatives are substances obtained by the modification of the cellulose base body by cationic groups.

Examples of cellulose base bodies are cellulose, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxylpropylcellulose and methylhydroxypropylcellulose.

Common cationic groups are groups with quaternary nitrogen or phosphorus atoms. Groups with quaternary nitrogen atoms are preferred. Quaternary nitrogen atoms can thus bear both 4 different or partially identical substituents as well as part of the ring system.

Preferred substituents are alkyl groups of 1 to 4 C atoms, aryl groups, alkylaryl groups, cycloalkyl groups, alkoxyalkyl groups and alkoxyaryl groups. Trialkylammonium groups, especially trimethylammonium groups, are preferred. The cationic groups can be either directly bonded or via intermediate groups with a cellulose framework. Preferred are polymers in which cationic groups are bonded via alkyl chains or alkoxyalkyl groups with a basic cellulosic backbone. Preferred counterions to the cationic groups are halide groups, in particular chloride and methosulfate.

Examples of such compounds are those described in U.S. Patent 3, 472.840, which are periods of the mark Polymer JR ^R in the store.

A further class of cationic cellulose derivatives is formed by such compounds which are constructed of cationic and non-ionic units.

Cationic units may be constructed in accordance with the above-named cationic cellulose derivatives,

Cationic units may further be compounds containing at least one polymerizable group in addition to at least one cationic group. The polymerizable group is preferably a vinyl group, the cationic groups are preferably the aforementioned ammonium groups. Such cationic units are, for example, dialyldimethylammonium chloride, methyl acrylamidopropyltrimethylammonium chloride, quaternized dimethylaminomethacrylate with diethyl sulfate and quaternized dimethylaminoethyl methyl methacrylate with diethyl sulfate.

Nonionic units are, for example, cellulose, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, methylhydroxy ···· propylcellulose, vinylpyrrolidone, vinyl acetate, acrylamide, methacrylamide, methyl acrylate, ethylacrylate, ethylacrylate, ethyl acrylate. Hydroxyethylcellulose is the preferred non-ionic unit.

Examples of such copolymers are compounds purchased under the name Celquat ^R.

Cationic polymers, which are copolymers from at least one cationic unit and at least one non-ionic unit, are preferred in the science of the invention. Particularly preferred are such copolymers in which the non-ionic unit is hydroxyethylcellulose. A particularly preferred cationic polymer is Celuquat ^R L200, a copolymer of hydroxyethylcellulose and diallyldimethylammonium chloride.

By two-pole-ionic polymers are meant such polymers containing in the molecule quaternary ammonium groups and groups C00 ~ or SO ^.

Examples of usable two-ionic polymers of the invention are compounds named in English Opening File 2 104 091, European Opening File 47 714, European Opening File 283 817 and German Opening File 28 17 369.

Particularly preferred are two-ion polymers consisting essentially of (ot) monomers with quaternary ammonium groups according to general equation (I)

R ¹ -CH = CR ² -C0-X (C _n H _2n ) -N ( ⁺ ) r ³ R ⁴ R ⁵ A ^ ^_) (I) in which R ¹ and R ^{2 are} each independently hydrogen or methyl and R ³ , R ⁴ and R ⁵ are independently alkyl group having 1 to 4 C atoms, X group NH or oxygen atom, n an integer from 2 to 5 and an anion of organic or inorganic acid and (ft>) monomeric carboxylic acids in general equations (II),

R ⁶ -CH = CR ⁷ -C00H (II) in which R ⁶ and R ^{7 represent} independently of one another hydrogen or methyl group.

These compounds can be used according to the invention both directly and in the form of salts obtained by the neutralization of polymerizates, for example with alcaline and hydroxide. In detail, the manufacture of these polymerizates is expressly referred to in the contents of the German opening file 39 29 973.

Particularly preferred are such polymers based on monomers of type (x), in which R ³ , R ⁴ and R ^{3 are} methyl groups, X is an NH group, and p '') is a halide, methoxy sulfate or ethoxysulfate ion; Acrylics · Dopropytrimethylammonium chloride is a particularly preferred monomer (oQ.) The acrylic acid or alkali salt of acrylic acid, in particular the sodium salt, is used as the monomer (/ ¼) for the named polymers.

In addition, such two-ionic polymers are preferred in which the number of monomers of type (oL) is greater than the number of monomers of type (fb). Particularly preferred are monomers with a ratio (</): Q $) greater than 1.5.

Both cationic and bi-polar ionic polymers are preferably contained in the compositions of the invention in amounts of from 0.01 to 10% by weight relative to the total preparation. Quantities from 0.01 to 5% by weight are particularly preferred.

Compositions containing cationic polymers and bipolar ionic polymers in amounts of between 5: 1 and 1: 1 have proven to be particularly effective.

It has further been found that particularly good results in the science of the invention are achieved if the preparations according to the invention contain additional surfactant. This may be anionic, cationic, ampholytic, bipolar-ionic or non-ionic surfactant.

Examples of cationic surfactants useful for hair treatment agents of the invention are cationic surfactants in particular quaternary ammonium compounds. Preferred are ammonium halides such as alkyltrimethylammonium chloride, dialkyldimethylammonium chloride and trialkylmethylammonium chloride, e.g. cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, laurildimethylammonium chloride, laurildimethylbenzylammonium chloride and tricethylmethylammonium chloride. Further useful cationic surfactants according to the invention are protein hydrolysates.

According to the invention, cationic silicone oils are also commercially available as commercially available 02-7224 products (manufacturer: Dow Corning; stabilized trimethylsilylamodimethicone), Dow Corning 929 emulsion (containing hydroxyl-amino-modified silicone, also referred to as Amodimethicone), SM - 2509 (General Electric manufacturer), SLM-55067 (manufacturer: Wacker) as well as Abil ^R Quat 3270 and 3272 (manufacturer: Th. Goldschmidt; diquaternary polydimethylsiloxane, Ouaternium - 80).

Al kilamidoamines, especially fatty acid amidoamines such as Tego Amid ^R S18, commercially available stearylamidopropyldimethylamine, are distinguished in addition to their good corrosion effect, especially by their good biodegradability.

Also very good biodegradable quaternary ester compounds, so-called Esterquats, such as under the trade mark Stepantex ^R distributed dialkilamoniummetosulfat and methyl-hidroksilalkildialkoiloksialkil-Amonium metosulfat.

An example of the quaternary sugar derivative used as a cationic surfactant is the commercial product Glucquat ^R 100, according to the CTFA-Nomenclature Lauril-Methyl-Gluceth-10-Hydroxypropyl Dimonium Chlorid.

Particularly preferred cationic surfactants are alkylamidoamides, quaternary ester compounds and quaternary sugar derivatives.

As anionic surfactants, suitable anionic surfactants are suitable in the compositions of the invention for use in the human body. They are characterized by a water solubility-releasing anionic group such as e.g. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group of about 10 to 22 C atoms. They may additionally be contained in the molecule of the glycol or polyglycol ester group, the amine ester group as well as the hydroxyl group. Examples of suitable anionic surfactants are, in each case, in the form of sodium, potassium and ammonium as well as mono-, di- and trialkanol 10 mono salts with 2 or 3 C atoms in the alkanol group,

- linear fatty acids with 10 to 22 C atoms (soaps)

- ethercarboxylic acid of the formula R-O- (CH2 ~ CH20) _x ~ CH2 "C00H, in which R represents a linear alkyl group having 10 to 22 c atoms and x = 0 or 1 to 16,

- acyl sarcosides with 10 to 18 C atoms in the acyl group,

- acyltaurids having 10 to 18 C atoms in acyl groups,

- acyl isethionates with 10 to 18 C atoms in the acyl group.

- sulfo-succinic acid sulpho-succinic acid mono and dialkyl esters of 8 to 18 alkyl groups and sulpho-succinic acid mono-alkyl polyoxyethyl esters of 8 to 18 C-atoms of alkyl and 1 to 6 oxy-yl groups,

- linear alkanesulfonates having 12 to 18 C atoms,

- linear alpha-olefinsulfonates having 12 of the 18 C atoms,

- alpha-sulfo-fatty acid methyl ester of fatty acids with 12 to 18 C atoms,

- alkylsulfates and alkylpolyglycoletersulfates pp. of the formula R-OCCl ^ CH2O) _x ~ OSO ^ H, in which R is preferably a linear alkyl group having 10 to 18 C atoms and x = 0 or 1 to 12,

- mixtures of surfactant hydroxysulfonates according to DE-A-37 25 030,

- sulfated ethers of hydroxyalkyl polyethylene and / or hydroxyalkylene propylene glycol according to DE-A-37 23 354,

- Sulfonates of unsaturated fatty acids with 12 to 24 C atoms and 1 to 6 double bonds according to DE-A-3926344,

- tartaric acid and citric acid ester with alcohols representing the accumulated products of about 2-15 ethylene oxide and / or propylene oxide molecules on fatty alcohols of 8 to 22 C atoms.

Preferred anionic surfactants are alkylsulfates, alkylpolyglycoletersulfates, and ether carboxylic acids with 10 to 18 C atoms in the alkyl group and up to 12 glycol ether groups in the molecule, as well as mono and dialkyl ester sulfo-succinic acids with 8 to 18 C atoms in alkyl. group and mono-alkylpolyoxyethyl ester of sulfo-succinic acid with 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups.

Such surfactants are those which carry at least one quaternary ammonium in the molecule .....

into the group and at least one group with COO4 · ^- ) or SO ^ ^- ) especially suitable two-ionic surfactants are so-called betaines as N-alkyl ~ N, N-dimethylammonium glycyl nat, for example cocosalkyldimethyl-1-ammonium glycinate, N-acyl- aminopropyl-N, N-dimethylammonium glycinate, e.g. cocosacylaminopropyl-dimethylammoniumglycinate and 2-alkyl-3-carboxymethyl-3-hydroxyethyl-imidazoline with 8 to 18 C atoms in each alkyl or acyl group as well as cocosacylamino-ethylhydroxyethylcarboxymethylglycinate. A preferred two-ion surfactant is known fatty acid amide derivatives under the CTFA code Cocamidopropyl Betaine.

Ampholytic surfactants are understood to mean such surfactants containing at least one free amino group and at least one COOH or SO ^ H group in the molecule other than a Cg-C1-8 alkyl or acyl group and capable of forming internal salts. Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkyl12 propionic acid, N-alkylamino-butyric acid, Nalki1iminodipropionic acid, Nh id rox ietes 1 - weavers 1 amidopropyl Igl nici n, N-alkyl-sarkin, N-alkyl-sarkin, N-alkyl-sarkin alkylaminopropionic acid and alkyl-amino-acid acid with each of about 8 to 18 C atoms in each alkyl group. Particularly preferred ampholytic surfactants are N-kokosalkilaminopropionat, kokosacilaminoetilaminopropionat and C ^ ₂ -i8 Isarkosin.

Non-ionic surfactants contain as hydrophilic group e.g. a polyol group, a polyalkylene glycol etei group or a combination of polyol and polyglycol ether groups. Such compounds are, for example:

- additive products of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide on linear fatty alcohols of 8 to 22 C atoms, of fatty acids of 12 to 22 C atoms and of alkylphenols of 8 to 15 C atoms in an alkyl group,

- C ₁₂ - C ₂₂ - Mono- and diester fatty acids of additive products with 1 to 30 moles of ethylene oxide per glycerin,

- Cg - C ₂₂ -alkylmono- and oligoglycosides and their ethoxylated analogs as well as

- Additive products of 5 to 60 moles of ethylene oxide on castor oil and hardened castor oil.

Compounds used as surfactants with alkyl groups may each be single substances. As a rule, however, it is preferable to proceed from the manufacture of these substances from native plant or animal raw materials, so that mixtures of the substance with different alkyl chain lengths independent of the raw material are obtained.

In the case of surfactants representing the additive products of et i. of flax and / or propylene oxide on fatty alcohols or derivatives of these additive products, both products with a normal homologous distribution and those with a narrowed homologous distribution may be used. Normal homogeneous distribution refers to mixtures of homologens obtained from the conversion of fatty alcohol and alkylene oxide when using alkali metals, alkali metal hydroxides or alkali metal alcohols as catalysts. Narrowed homologeneous distributions, however, are obtained when, for example, hydrotalicytes, terrestrial sikals of the ethereal carboxylic acid salts, oxides, hydroxides, or alkaline earth metal alcoholates are used as catalysts. The use of products with a narrow homologous distribution may be preferred.

The amount of surfactant contained in the compositions according to the invention depends on the type of surfactant and the purpose of use of the preparation.

The hair post-treatment agents preferably contain cationic and / or non-ionic surfactants, in particular in amounts of 0.1 to 10% by weight relative to the total preparation. Quantities between 0.1 and 3% by weight are particularly preferred.

Hair treatment preparations also preferably contain cationic and / or non-ionic surfactants, in particular in amounts of 0.1 to 10% by weight, based on the total preparation. Quantities between 0.1 and 5% by weight are particularly advantageous.

The compositions of the invention preferably exhibit pH values of 2.5 to 7, in particular 3 to 6.

Shampoos, hair conditioners and hair treatments are preferred preparations of the invention. The preparations may also be preparations for permanent curling, dyes, hairdryers and other common hair treatments.

The formulations may be formulated as aqueous or, aqueous-alcoholic solutions, creams, lotions, jellies, emulsions as well as other conventional cosmetics in cosmetics.

Suitable uses and formulations may contain the compositions according to the invention for any particular purpose of using conventional cosmetic accessories.

Such common ingredients are:

- non-ionic surfactants such as e.g. vinylpyrrolidone / vinyl acrylate copolymers, polyvinylpyrrolidone and vinylpyrrolidone / vinyl copolymers .....

cetate and polysiloxanes,

- anionic polymers such as e.g. polyacrylic acid, cross-linked polyacrylic acid, vinyl acetate / crotonic acid copolymer, vinylpyrrolidone / vinyl acrylate copolymer, vinyl acetate / butyl maleate / isobornyl acrylate copolymer, maleic acid / maleic acid anhydride, and terpolymer acrylate acrylate acrylate.

- thickeners such as agar-agar, guar-gum, alginate and xanthan gum,

- Structures such as glucose and maleic acid,

- hair-conditioning compounds such as phospholipids, for example soya-gelatin, egg lecithin and kefalin, as well as silicone oils,

- protein hydrolysates, in particular the hydrolysates of collagen, keratin, milk, egg whites, soyprotein, mande.1 protein, pea protein, potato protein, maize protein and cereal protein, their condensation products with fatty acids as well as quaternized protein hydrolysates,

- perfume oils, 'dimethylisosorbide and cyclodextrin,

- solution mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerin and diethylene glycol,

-Dyes

- dandruff active substances such as pyroctone, olamine and zinc omadine,

- further pH adjusting substances,

- active substances such as panthenol, alantion, plant extracts and vitamins, ¹

- light protection products,

- consistency providers such as sugar ester, polyolester or poly oal only, and,

- fats and waxes such as whale fat, beeswax, montane wax, paraffin and fatty alcohols,

- fatty acid alcoholamides,

- complex agents such as EDTA, NTA and phosphonic acid,

- swelling and penetration agents such as glycerin, propylene glycol monoethyl ether, carbonate, hydrogen carbonate, guanidine, urea as well as primary, secondary and tertiary phosphates,

- latex tempering agents,

- pearl luster agents such as monostearate and ethylene oleagin ·· lycol distearate, ~ propellants as mixtures of propane-butane, N ₂ 0, dimethyl ether, C0 ₂ and air as well as

- antioxidants

- direct drawing dyes,

- so-called joining and development components as oxidation dye products, ~ reducing agents such as e.g. thioglycolic acid and its derivatives, thio-lactic acid, cysteamine, thio-malic acid and cL-mercaptoethanesulfonic acid,

- Oxidizing agents such as hydrogen peroxide, potassium bronate and sodium bronate.

The subject of the invention is also a method of treating hair with the composition of the invention.

Preferred is a method whereby the compositions of the active compound of the invention are applied to the hair and, after a certain period of action, typically lying between a few seconds and about 20 minutes, are rinsed again with water or with an agent .....

vom containing essentially water.

The following examples should explain the subject of the invention in more detail.

Examples

I. Determination of wet combustion

Search method

Wet combing was investigated using two different methods. Method 1 is based on the objective determination of wet combing work, method 2 on the subjective assessment of test subjects.

Method 1:

The basis of the research on combing is the method according to J.Soc. Cosm. Chem. 1973 (24) 782.

Each time, the work of combing on brown hair was investigated (Alkinco 6634, length 12 cm, weight lg). it was lightly damaged (cold curled or blonded) hair, as expected for the average user. After zero measurement, the strands were filled with 100 ml of the test recipe. After 5 minutes of action, the hair was rinsed for 1 minute under running water (1 1 / min, 38 ° C). The strands were then re-measured to determine wet combing work.

Method 1:

About 2 g of Kerling's heavy strands of hair were damaged by one treatment for permanent curling and medium curling each time (30 minutes long hair treatment with 6% H ₂ 0 ₂ solution adjusted with ammonia to pH 9.4 ). The strands were then washed twice with an aqueous solution of Texapon N25 (sodium laulylretersulfate), which was adjusted to 12? 'Of the active substance. Then, the strand was treated with 0.5 g of the test solution for 2 minutes. It was finally rinsed with warm water (30 ° C).

Results

The composition of the tested mixtures as well as the results of the combustion studies are summarized in Table 1. The values of the combing part according to method I refer to the value of the zero measurement each time. The key to method 2 subjective assessment ranges from 1 = very good to 2 ~ good, 3 = satisfactory, and 4 = sufficient to 5 = defective.

♦

10> o r »o

LO

O * CM

O O- fO

Table I _ / Quantities in mass parts / tO> I

IO 4

CO tO

LO 10 rd Oh 0 w «· Oh rO OJ 0 Oh Oh 4- 1

ro

Ol rd What > 1 * · 1 4 1 Oh OJ

rd 4 »H that 1 rd r » 1 1 OJ i> 0 1 1 • rl rd N • rd \ • rd PM ro rd cn Oh ro Ol you • rd you a Ex you P 0 Ch Oh Oh F » hO that Ό rd Φ you • rd 34 you rd W a Oh С. ro ro · » a P ¥ !. ω rd hO Φ • rd Oh W S, Φ rd • rd Φ you 34 Ex Oh a Oh you F » • rd 0] F » rd OJ n Oh 34 Φ t — 1 you <* - = 4 • rd OJ ro • ro cn Oh rd rd • ro • rd • rd ro • rl • rd you Pd rd »You Ό P PČ you you 34 P P4 n Oh Oh m 0) Oh ro you you Φ P P 0) P a a Φ you Φ Φ > 0 Φ Φ d ro • rd ro you a a a a 0 you rd rd r — 1 0 • rd \ 0 ro p o ¹ 0 • rd • rl rd that λ ro you 0 0 a rd Ex P you you Oh ts Ex τ 34 Ex Ex 0 Φ Oh Φ 34 ro Pt cn € c Oh Oh Ul a ro you \ • 3 > S 1 1

¹ Hydroxyethylcellulose / Diallyldimethylammonium chloride (95% active substance; CTFA name: Polyquaternium - 4) (Delft National) ^la methylmethacrylate-tert. butylaminoethylmethacrylate-2-hydroxypropylmethacrylate-N (1,1,3,3-tetramethylbutyl) acrylamide .....

copolymer.

II. Determination of Curl-Retention Capacity

Research Method cm long hair strand (Fa.Kerling; strand weight: 2 g) was treated with 0.5 g of the test mixture for 2 minutes. Then the strand was flushed and wound onto a glass tube with an outer diameter of 2.0 cm, fixed and dried. The measure of curl stability obtained after pulling out the glass bar is the so-called Curlretention value (CR value), which is defined as / (1-1 _χ / (1-1 _ο ) / χ100%, where 1 is the length of the hair strand and 1 _χ length of hair curl after x-hour hanging deposition in a dry cabinet under constant conditions (25 ° C, 60% relative air humidity).

Results

The results of the tests for curling ability are summarized in Table 2.

Table 2

Measurement value / mixture VI V2 El V3 CR values after - 6 hours (%) 81,4 82.6 86.5 88,4 - 8 hours (%) 79.8 80.7 83,7 86,2

The values for treatment with pure water were 83.2 (after 79.9 (after 8 hours)).

III. Examples of use

V 4

82,9

81,3 hours)

The quantities given in the following examples are by weight%.

1. Flushing with water

Stanol ^R 1618 ^ 3.0 Cutin ^P 'GMS ³ 0.5 Eumulgin ^p B l ⁴ 0.4 Eumulgin ^p B 2 ⁵ 0.8 Eutanol ^P G ^ 1.0

1-dimer of acrylamidopropyltrimethyl ammonium chloride / acrylic acid neutralized with sodium hydroxide solution (Polymer Pl, according to DE 39 29 973) 0.2

Celquat ^p L200 1.0

Gafquat ^R 755 ~ N ⁷ 2.5

Water ad 100 ^{2 c} 16 / ^c 18 ”fatty alcohol (Henkel) ³ glycerin monostearate (CTFA code: Glyceril Stearate) (Henkel) ⁴ quaternary alcohol of about 12 moles E0 (CTFA code: Ceteareth-12) (Henkel) ⁵ quinteryl alcohol of about 20 moles EO (CTFA code: Ceteareth - 20) (Henkel) ⁶ saturated liquid fatty alcohol condensation product, predominantly decyl alcohol, prepared by the Guebert reaction (CTFA code: Octyldodecanol) (Henkel) ⁷ copolymer of vinylpyrrolidone / dimethylaminoethylmethacrylate, quaternium zranylranylranecranyl active substances in water) (GAF).

2. Rinse your hair Stanol ^R 1618 1.8 Tegoamide ^R 18® 1.6 1,2-Propylene glycol 1.0 Citric acid 0.6 Celquat ^R L200 1) 2 Polymer Pl, according to DE 39 29 973 0.2 Perfume oil, water ad 100

⁸ N, N-dimethyl-N '~ stearoyl-1,3-diamino-propane (CTFA code Stearamidopropyl Dimethylamine) (Goldschmidt)

3. Rinse your hair

Stanol ^R 161S 1,8 Stepant.ex ^R VS 90 ⁹ 1,8 1,2-Propylene glycol 0.7 citric acid 0.2 Celquat ^R L200 1.2 Polymer Pl, according to DE 39 29 973 0.3

Perfume Oil, Dye, Water ad 100 ⁹ N-Methyl-N (2 ~ hydroxyethyl) -N, N-di (talc.loxyethyl) ammonium metho sulfate (90% of the active substance in isopropanol) (Stepan)

4. Hairwashing

Stanol ^R 1618 2.5 Eumulgin ^R B 1 1.0 Eumulgin ^R B 2 1.0 Cutina ^R CP ¹⁰ 1.0 Eutanol ^R G 0.5 Polawax ^R GP 200 ¹¹ 0.75 ABIL ^R Quat, 3270 ¹² 0.5 Dow Corning ^R 929- ~ Emulsion · ¹ ' ⁵ 2.6

Polymer JR ^R 400 ¹⁴ 0.6 Polymer Pl, according to DE 39 29 973 0.4 Citric acid 0.02 water ad 100

¹⁰ Ester of saturated long-chain fatty alcohols and fatty acids, in particular cetilester palmitic acid (CTFA name: Cetyl Palmitate) (Henkel) ^{11 of} a mixture of stearyl alcohol, and polyethylene glycol-stearate (CTFA name: stearyl Alcohol (and) PEG-Stearate) (CRODA) ¹² diquaternary polymethylsiloxane (CTFA code: Ouiaternium -80) (Goldschmidt) ¹³ amino-functional polydimethylsiloxane (35% active substance) (DOW CORNING) ¹⁴ quaternary hydroxyethyl cellulose (CTFA code: Polyquaternium-10) (UNION CARBIDE)

5. Rinse your hair

Rewoquat ^R W 7500 ¹³ 1.1 Lanette ^R 0 ¹⁶ 3.0 Eumulgin ^R B 1 0.8 Eumulgin ^R B 2 1.6

Cutina ^R GMS - 0.5 Eutanol ^R G 1.0 Polymer JR ^R - -1251 ⁷ 1.0 Polymer Pl, according to DE 39 29 973 0.4 Water ad 100

¹¹⁵ 1-Methyl-2 ~ nortalgalkyl ~ 3-fatty acid-amidoethylimididoline-metosulfate (about 75% of active substance) (REWO)

-) - ⁶ mixtures of higher, saturated fatty alcohols, predominantly cetyl and stearyl alcohol (CTFA code: Cetearyl Alcohol) (HENKEL) ¹⁷ quaternary hydroxyethyl cellulose (CTFA code: Polyquaterni um - 10) (Union Carbide)

6. Shampoo

Texapon ^R 25 ⁱ⁸ 43,0 Dehyton ^R K ¹⁹ 10,0 Plantar ^R “1200 ² 0 4.0 Euperlan ^R PK 3000 ²¹ 1.6 Arquad ^R 316 ²² 0.5 Celquat ^R L200 1,2 Polymer Pl, according to DE 39 29 973 0.2 Glucamate ^R D0E 120 ² ^ 0.5 Sodium chloride 0.2 Water ad 100

sodium lauryl ether sulfate (about 28% of the active substance; CTFA code: Sodium Laureth Sulfate) (Henkel) a fatty acid amide derivative with the betaine set of the equation RCONH (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ C00 ~ (about 30% active substance,

CTFA code: Cocoamidopropyl Betaine) (Henkel) ²⁰ f ^ g ^ ukosid ⁵ JL oligomerization rate, 4 (about 50% of the active substance; CTFA code: Lauryl Polyglycosid) (Henkel.) ² * liquid dispersion of substances that confer pearly luster and amphotenside (about 20% of active substance; CTFA code: Glycol Distear .....

ate (and) Glycerin (and) Laureth -4 (and) Cocoamidopropyl Betaine) (Henkel) ²² tri-C ₁₆ -alkylmethylammonium chloride (AKZO) ²³ ethosylated methylglucoside dioleate (CTFA code: PEG - 120 Methyl Glucose Dioleate) (Americhol)

7. shampoo

Texapon ^R N 70 ²⁴ 21.0 Plantar ^R -1200 8.0 Genamin ^R DSAC ²⁵ 1,2 Cutina ^R EGMS ²⁶ 0.6

Polymer JR ^R -400 0.8 Polymer Pl, by DE 39 29 973 0.3 Antil ^R 141 liquid ²⁷ 1.3 Sodium chloride 0.2 Water ad 100

sodium lauryl ether sulfate (about 72% of active substance) (HENKEL) ²⁵ dimethyldistearylammonium chloride (HOECHST) ² ^ ethylene glycol monostearate (about 25-35% monoester, 60-70% diester; CTFA code: Glycol Stearate) (HENKEL) ²⁷ polyoxyethylene ethylene (40) substances; CTFA code: Propylene Glycol (and) PEG 55 Propylene Glycol Oleate (Goldschmidt)

8. Shampoo

Texapon ^R K 14 S ²⁸ ' 50.0 Dehyton ^R K 10,0 Akypo ^R RLM 100 NV ²⁹ 4.5 Cutina ^R AGS ³⁰ 2.0 D-Pantenol 0.5 Glucose 1.0 Salicylic acid 0.4 Sodium chloride 0.5

Polymer Pl, according to DE 39 29 973 0.6

Celquat ^R L200 0.6

Water ad 100 ²⁸ natrijevlaurilmiristiletersulfat (about 28% active substance; CTFA name: Sodium Myreth Sulfate) (Henkel) _c 12 "14_ _ma s £ _o b _n i alcohol + 10 ethylene oxide-acetic acid, sodium salt (22% active substance; CTFA name : Sodium Laureth -11 Carboxylate) (CHEM-Y) ³⁰ ethylene glycol stearate (about 5-15% monoester, '85-95% diester; CTFA code: Glycol Cistearate) (HENKEL)

9. Shampoo

Texapon ^R K 14 S 25,0 Texapon ^R SB 3 ³¹ 7.5 Eucarol ^R TA ³² 12,0 Akypo ^R RLM 100 NV 9.0 Dehyton ^R AB 30 ³³ 8.3 Elfacos ^R GT 282S ³⁴ 0.5 Sodium chloride 0.5 Polymer Pl, according to DE 39 29 973 0.6 Polymer JR ^R -400 2.0

Water ad 100 polyester sulfo succinic acid based on alkylpolyglycol ether, Di-Na - salt (about 40% of the active substance; CTFA code: Disodium Lau ~ rethsulfosuccinate) (HENKEL) ³² lauryl alcohol + 7 ethylene oxide tartrate - sodium salt (about 25% active Substances; CTFA code: Sodium Laureth-7 Tartrate) (AUSICHME) ³³ fatty amine derivative with betaine structure (about 30% of active substance; CTFA code: Coco Betaine) (HENKEL) ³⁴ tallow + 60 ethylene oxide - myristyl ether (CTFA code: Talloweth 60 Myristyl Glycol) (AKZO)

10. Treatment bandage (flush)

Stanol ^R 1618 3.0 Eumulgin ^R B 1 0.5 Eumulgin ^R B 2 0.5 Cutina ^R CP 1.0 Eutanol ^R Q- 1.5 Carbopol 980 ³ ^ 0.004 Dow Corning ^R 929-Emulsion 2.9 Polymer Pl, according to DE 39 29 973 0.3 Celquat ^R L200 2.0 T rietanloamine 0.09

Water ad 100 ³⁵ polyacrylic acid (GOODRICH)

11. Treatment bandage (stay on hair)

Celquat ^R L 200 0.6 Luviskol ^R K30 ³ ^ 0.2 D-Pantenol 0.5 Dehyquart ^R SP ³⁷ 1.0 Nutrilan ^R I ³⁸ 1.0 Natrosol ^R 250 HR ³⁹ 1.1 Polymer Pl, according to DE 39 29 973 0.5 Water ad 100

⁰⁰ polyvinylpyrrolidone (95% active substance; CTFA code: PVP) (BASF) ³⁷ aqueous oxyethylalkylammonium phosphate solution (about 50% active substance; CTFA code: Ouaternium - 52) (HENKEL) ³⁸ collagen hydrolyzate (about 39% active substance; CTFA code: Hydrolyzed Collogen) (HENKEL) ³⁹ hydroxyethylcellulose (AOUALON)

12. Dye cream

C12-18- Fatty alcohol

1,2

Lanette ^R O 4.0

Eumulgin ^R B 2 0.8

Cutina ^R KD 16 ⁴⁰ 2.0

Sodium sulphite 0.5

L (+) - ascorbic acid 0.5

Ammonium sulfate 0.5

1,2-propylene glycol 1,2 p-aminophenol 0.35 p-Toluylenediamine 0.85

2-Methylresorcin 0.14

6 ~ Methyl-m-aminophenol 0.42 polymer Pl, according to DE 39 29 973 0.5

Celquat ^R L200 1.5

Ammonia 1.5

Water ad 100 ⁴⁰ mixture of mono and diglyceride fatty acid emulsifier (CTEA code: Tallow Glycerides (and) Glyceryl Stearate (and) Potassium Stearate) (HENKEL)

13. Developmental Emulsion for Hair Color Cream 12)

Texapon ^R N 25 2,1 Hydrogen peroxide (5%) 12,0 Turpinal ^R SL ⁴¹ 1,7 Latecoll ^R D ⁴² 12,0 Polymer Pl, according to DE 39 29 973 0,1

- 32 Polymer JR ^R -4OO 0,1

Water ad 100 ⁴¹ l-Hydroxyethane-1,1-diphosphonic acid (60% active substance; CTFA code: Etidronic Acid) (HENKEL) ⁴² copolymer of acrylester and methacrylic acid (25% active substance) (BASF)

The coloring cream had a pH value of 10.0. It produced intense red shades of hair.

14. Texapon ^R N 70 Shampoo 14,0 Dehyt.on ^R K 10,0 Akypo ^R RLM 45 NV ⁴³ 14.7 Plantar ^R -1200 4.0 Cremophor ^R RH 40 ⁴⁴ 0.8 The dye C.I. 12 719 0.02 The dye C.I. 12 251 0.02 The dye C.I. 12 250 0.04 The dye C.I. 56 059 0.03 PHB-Esther 0.25 Celquat ^R L200 0.8 Polymer Pl, according to DE 39 29 973 0.2 Perfume oil q. s. Water ad 100

⁴³ lauryl alcohol + 4,5 ethylene oxide-acid acid-sodium salt (20,4% active substance) (CHEMY-A) ⁴⁴ castor oil, hydrated + 45 ethylene oxide (CTFA code: PEG-40 Hydrogenated Castor Oil) (BASF)

When washing your hair with this shampoo, your hair is a shimmery, light blue shade.

15. Cream for permanent curls

Curl Cream:

Plantar ^R -800 ⁴⁵ 5.0

Thioglycolic acid 8.0

Turpinal ^R SI_ 0.5

Ammonia (25%) 7.3

Ammonium carbonate 3.0

Cetyl / Stearyl-Alcohol 5.0

Guerbet-Alcohol 4.0

Celquat ^R L200 1.2

Polymer Pl, according to DE 39 29 973 1,0

Perfume Oil q.s.

Water ad 100 ⁴⁵ Cg - C | ₀ - alkylglucoside with an oligomerization rate of 1.6 (about 60% of the active substance) (HENKEL)

Fixed solution:

Plantar ^R -800 5.0

Hardened Castor Oil 2.0

Potassium bromate 3.5

Nitrilotriacetic acid 0.3

Citric acid 0.2

Polymer Pl, according to DE 39 29 973 0.4

Polymer JR ^R ~ 400 1.0

Perfume Oil q.s.

Water ad 100

Claims (12)

PATENT APPLICATIONS An aqueous hair treatment preparation, comprising, in addition to conventional cosmetic ingredients, a combination of cationic and bipolar polymers, characterized in that the cationic polymers are cellulose derivatives and do not contain imidazolinium groups. A preparation according to claim 1, characterized in that the cationic polymer is a copolymer of at least one cationic unit and at least one non-ionic unit. A preparation according to claim 2, characterized in that the non-ionic unit is hydroxyethylcellulose. Preparation according to one of Claims 1 to 3, characterized in that the bipolar ionic unit consists essentially of (JL) monomers with quaternary ammonium groups according to general equation (I) R ¹ -CH = CR ² ~ C0-X (C _n H _2n ) -N ( ⁺ ) r ³ R ⁴ R ⁵ A <~) (I) in which R ¹ and R ^{2 are} each independently hydrogen or methyl and R ^3, R ⁴ and R ⁵ independently of each other an alkyl group having 1 to 4 carbon atoms, X is a group NH or an oxygen atom, n is an integer from 2 to 5 and A ^ ^- ^ is an anion of an organic or inorganic acid and (I / b) monomer carboxylic acids according to general equation (II), R ⁶ -CH = CR ⁷ -C00H (II) in which R ⁶ and R ^{7 represent} , independently of one another, hydrogen or a methyl group or the alkali, alkaline earth, aluminum or ammonium salts of these acids. A preparation according to claim 4, characterized in that the monomer of type (ct) is acrylamidopropyl-trimethyl-ammonium chloride and the monomer of type (0) is an acrylic acid or an alkali salt, in particular the sodium salt, of acrylic acid. A preparation according to claim 4 or 5, characterized in that the number of monomers of type (ck) is greater than the number of monomers of type ((b) in the two-ionic polymer. A preparation according to any one of claims 1 to 6, characterized in that they contain: - 0,01 - 10, in particular 0,01 to 5% by weight of two-pole ionic polymers and 0.01 to 10, in particular 0.01 to 5% by weight of cationic polymers, each time relative to the total preparation. A preparation according to any one of claims 1 to 7, further comprising a surfactant. A preparation according to claim 8, characterized in that the surfactant is a cationic and / or non-ionic surfactant. A preparation according to any one of claims 1 to 9, characterized in that the preparation exhibits a pH value between 2.5 and 7, in particular between 3.0 and 6.0. Method for the treatment of hair, characterized in that the preparation according to one of claims 1 to 10 is applied to the hair. A method according to claim 11, characterized in that the hair is subsequently rinsed with water or with a substance containing substantially water.