CN1086707A - Agent for treatment of hair - Google Patents

Abstract

The water system agent for treatment of hair that is combined by the cationic polymer that contains imidazole radicals and both sexes or amphoteric ion polymer is used for hair, very good wet comb is arranged, and delayed dried comb within the specific limits, and this is very ideal for fixing hair.

Description

Agent for treatment of hair

The present invention relates to contain the agent for treatment of hair of the polymer of particular combinations.

The cleaning of hair and maintenance are the important component parts of human body maintenance, and U.S.'s decorations of shampoo washing hair and hair style are for example had hair dyed or permed to the natural structure and the abrasive influence of character of hair.Hair is handled for example wet afterwards comb property like this and is done comb property, and the tenacity of hair and fullness people in addition can not be satisfied with, and perhaps broken hair increases.

Thereby conventional method is to carry out special post processing for a long time, conventional method is with specific medicament for example quaternary ammonium salt or specific polymer treatment hair with the form of flushing, improved hair comb property by this prescription processing, tenacity and fullness have reduced the broken hair rate.

Add cation type polymer in the agent for treatment of hair and generally can improve wet comb property and do comb property, add that amphoteric polymer has improved wet comb greatly and very little doing the influence of comb property.

Combination with the medicament of number of different types usually can obtain further good result.For example German patent DE-Al-3044738 is exactly a known example, can improve agent for treatment of hair after adding the mixture of amphoteric cation type polymer.

Because the wet comb that promptly reduced of wet comb property improvement is operated, this all is desirable in all cases, but the situation of dried comb property is just complicated.Though low carding operation value has characterized the improvement of carding operation, when carding operation was very low, the tenacity and the fullness of hair had lost, so that no longer can make fixed hair style under extreme case.Therefore, when complicated hair style, improving in certain qualification and do the comb operation, is desirable fully with the toughness of improving hair style.

Unexpectedly the other places is found now, the medicament that is combined by both sexes or amphoteric ion polymer and certain cation type polymer has improved the wet comb of hair satisfactorily, also improved dried comb within the specific limits, this tenacity to hair style is good, therefore both improve the hair style under the moisture state clearly and manufactured, and also can improve the tenacity of hair style under the drying regime.In addition, the hair of handling like this has the ability of good fixedly curly hair and good fluffy power is arranged.

Thereby content of the present invention comprises the water solublity prescription of treatment of hair, removes to contain conventional beauty treatment composition, also has the compositions of the polymer of cation and amphoteric or amphoteric ion type, it is characterized in that, contains the cation type polymer of imidazolinyl.

The used cation type polymer of the present invention is to be made of such chemical compound, except containing a cation group at least, at least also contains a polymerisable group, and does not have cation group.

The polymerizability group is preferably vinyl, however also available cationic polymerization product, and the main polymer chain of this moment for example is to be made of (sugar) glycosides chain.

The cation radical of conventional usefulness is to have quaternary nitrogen Huo Phosphonium atomic radical.The group of quaternary nitrogen atoms is preferred, has been somebody's turn to do four groups substituent group both inequality or that part is identical that nitrogen-atoms connected, also but ring system, cation group of the present invention importantly to the small part group be the quaternary nitrogen atoms that constitutes by imidazoline.The preferred polymer of the present invention is to have at least 50% cation radical to contain the imidazoline ring.Especially preferred those cation radicals are polymer of imidazoline ring.

The imidazoline ring system is the imidazoles of preferred quaternary nitrogenization, and it only is contained in polymerisable group as substituent group.Yet also can introduce such imidazole radicals, the alkyl of long-chain substituent group, a particularly 1-4 carbon atom is arranged on it, can carry out quaternizedly, for example use dimethyl sulfate, sulfonyl diethylester chloromethanes with all known quaternizing agents.

According to cationic copolymer of the present invention also is preferred, and it also contains at least a nonionic monomers except cation mono is external.Suitable nonionic monomers for example has vinyl pyrrolidone, vinyl acetate, acrylamide, Methacrylamide, acrylic acid methyl ester., ethyl acrylate, methyl methacrylate and ethyl methacrylate, nonionic monomers are preferably vinyl pyrrolidone especially.

Vinyl imidazole quinoline methoxy chloride/ethyl pyrrolidone copolymerization product is for example with Luviquat ^R(BASF) title can have been bought.

By the copolymer of cationic and this generation of nonionic within the scope of the present invention preferably the proportion of cationic monomer and nonionic monomers be the copolymer that generated in 1.5: 1 to 1: 1.5.The suitable especially copolymer of the present invention is a cationic monomer and the ratio of nonionic monomers is approximately 1: 1.

" amphiphilic polymers " of the present invention be meant the free-COOH that promptly has free amino to have again in the molecule or-SO ₃The H group, thereby can generate inner salt." amphoteric ion type polymer " be meant contain in the molecule quaternary ammonium ion and-COO ^-Or-SO - ₃Group.

An example of the amphiphilic polymers that the present invention proposes is to claim Amphomer ^RCommercially available acrylic resin, it is by methacrylic acid tert-butylamine base ethyl ester, N-(1,1,3,3-tetramethyl butyl) copolymer that two or more monomers generated of acrylamide and acrylic acid, methacrylic acid and simple ester thereof.

Other both sexes mentioned of the present invention or amphoteric ion type polymer are in British patent 2104091, European patent 47714,217274,283817 and Deutsche Bundespatent 2817364 in the chemical compound mentioned.

Particularly preferred amphoteric ion type polymer mainly be by

(α) has the monomer of the quaternary ammonium group of logical formula I

R in the formula ¹And R ²Represent hydrogen or methyl independently of one another, R ³, R ⁴And R ⁵Represent the alkyl of 1-4 carbon atom independently of one another, X is NH-base or oxygen atom, and n is integer 2-5, and A is the anion of organic or inorganic acid, or

(β) has the carboxylic acid monomer of logical formula II

R in the formula ⁶And R ⁷Represent hydrogen or methyl independently of one another.

These chemical compounds are used for when of the present invention, promptly can be directly with form that also can salt for example with obtaining with polymerizate in the alkali metal hydroxide, can be about the detailed method for making of these polymerizates referring to the content of Deutsche Bundespatent 3929973.

Particularly preferred polymer is the monomer of (α) type, wherein R ³, R ⁴And R ⁵Be methyl, X is the NH-base, A ^-Be halogenide, methoxy sulfate or ethoxy sulfate ion; Particularly preferred (α) monomer is an acrylamido propyl group trimethylamine chloride, and the monomer of polymer (β) is preferably acrylic acid or acrylic acid alkali metal salt, especially goes up sodium salt.

In addition, the amphoteric ion type polymer is preferably (α) type number of monomers greater than (β) type number of monomers, and (α): (β) monomer ratio is particularly preferred greater than 1.5 o'clock.

In total formulation weight, content cationic and both sexes and amphoteric ion type polymer is preferably 0.01-10%(weight).0.01-50%(weight) especially preferred.

The weight ratio of cation type polymer and both sexes and amphoteric ion type polymer is that the prescription between 10: 1 to 2: 1 is effective especially.

And then find, good especially result is arranged with regard to reaching requirement of the present invention if in the present invention's prescription, add surfactant.Thereby can consider anionic, cationic, amphoteric, amphoteric ion type or nonionic surfactant.

The example of used cationic surface active agent quaternary ammonium compounds particularly in the agent for treatment of hair of the present invention, be preferably ammonium halide, as the chlorination alkyltrimethylammonium, chlorination dialkyl group dimethylammonium and chlorination trialkyl first ammonium, chlorination cetyl trimethylammonium for example, chlorination stearyl dimethylammonium, chlorination distearyl dimethylammonium, chlorination lauryl trimethylammonium, chlorination lauryl dimethyl benzyl ammonium and chlorination three whales base first ammonium, another available cationic surfactant of the present invention is quaternised protein hydrolysate.

Cationic silicone oil also is applicable to the present invention, for example commercially available prod Q2-7224(maker: Dow Cornig; TMS hydroxyl amino modification silicon), Dow Cornig929 Emulsion (contain hydroxyl amino modification silicon, be also referred to as amodimethicone), the SM-2059(maker: General Electric), SLM-55067(maker: Wacker) and Abil ^R-Quat 3270 and 3272(maker: Th.Coldschmidt; The polydimethylsiloxane of two seasonizations, Quaternium-80).

Alkyl amido amine, particularly fatty acid amidoamines are as with Tego Amid by name ^RThe amino propyl group dimethylamine of the stearoyl that s18 sells, it also has favorable biological degradability except that good maintenance effect is arranged.

So-called " Esterquats " quaternized ester compounds also has very favorable biological degradability, for example is Stepantex with the trade mark ^RAnd ethoxy sulphuric acid dioxane ammonium and the ethoxy sulphuric acid methyl hydroxy alkyl dialkyl acyloxy alkylammonium sold.

Commodity as the quaternized sugar derivatives of cationic surface active agent are Glucq-nat ^R100, according to the CTFA nomenclature, it is " chlorination lauryl methyl Portugal second-10 a hydroxypropyl diammonium ".

Special preferred cationic type surfactant is an alkylamidoalkyl amine, the bonded and quaternized sugar derivatives of quaternized ester.

Being suitable for the fill a prescription anionic surfactant of usefulness of the present invention is all suitable anionic surfactanies that can be used for human body, it is characterized in that water miscible, anionic group for example is carboxylate radical, sulfate radical, sulfonate radical or phosphate groups, the lipotropy alkyl is the alkyl of about 10-22 carbon atom, also can contain glycol ether or polyglycols ether, ester group, ether and amide groups and hydroxyl in the molecule.The example of suitable anionic ionic surfactant always with receive, potassium and ammonium salts or, two or three alkanol ammonium salts, chain triacontanol base contains 2 or 3 carbon atoms, they are,

-have a straight chain fatty acid (soap) of 10-22 carbon atom,

-general formula is R-O-(CH ₂-CH ₂) _x-CH ₂-CO ₂The ether carboxylic acid of H, R are the straight chained alkyl that contains 10-22 carbon atom, X=0 or 1-16,

-acyl group is the acyl group sarcosine of 10-18 carbon atom

-acyl group is the acyl group taurine of 10-18 carbon atom

-acyl group is the acyl isethinate of 10-18 carbon atom

Alkyl is that the sulfo-mono succinate alkane ester of 8-18 carbon atom is a 8-18 carbon atom with two alkane esters and alkyl, and the sulfo-succinic acid monoalkyl polyoxy ethyl ester of 1-6 oxygen ethyl is arranged,

-contain the LAS of 12-18 carbon atom,

-contain the straight chain α-Xi Jihuangsuanyan of 12-18 carbon atom,

-contain the α-thia fatty acid methyl ester of the straight chain fatty acid of 12-18 carbon atom

-general formula is R-O(H ₂CH ₂O) _x-OSO ₃The alkyl sodium sulfate ester of H and alkyl sodium sulfate Polyethylene Glycol ether-ether, R is preferably the straight chained alkyl that contains 10-18 carbon atom in the formula, X=0 or 1-2,

-by the mixture of the hydroxy-acid salt of the surfactant of German patent DE-A37 25030.

-by the hydroxyalkyl polyglycol ether of the sulfation of German patent DE-A-37 23354 and (or) the hydroxy alkenyl propylene glycol of sulfation

-by German patent DE-A-39 26344 sulfonate of the unsaturated fatty acid of 12-24 carbon atom and 1-6 two keys is arranged,

The ester that-Tartaric acid and citric acid and alcohol form, alcohol be the aliphatic alcohol of 8-22 carbon atom with the oxirane of about 2-15 molecule with (or) addition compound product of expoxy propane.

Preferred anionic surfactants type surfactant is that alkyl is that 10-18 carbon atom, ethylene glycol ether are at most 12 sulphuric acid alkane ester, alkyl sodium sulfate Polyethylene Glycol ether-ether and carboxylic acid ether-ether in the molecule, and perhaps alkyl is that the sulfo-mono succinate alkane ester of 8-18 carbon atom or two alkane ester and alkyl are the sulfo-succinic acid monoalkyl polyoxy ethyl ester of 8-18 carbon atom, a 1-6 oxygen ethyl.

As amphoteric ionic surfactant is such surface active cpd: have a quaternary ammonium group and at least one COO in the molecule at least ^-Or-SO - ₃Group.Shi Yi amphoteric ionic surfactant is so-called betaine class especially; as N-alkyl-N; N dimethylammonium-glycinate; coconut palm alkyl-dimethylammonium-glycinate for example; N-acyl group-aminopropyl N, N-dimethylammonium-glycinate, for example coconut palm acyl group aminopropyl-dimethylammonium-glycinate and 2-alkyl-3-carboxymethyl-3-hydroxyethyl imidazole quinoline; in alkyl or acyl group, respectively contain 8-18 carbon atom, and coconut palm acyl group aminoethyl hydroxyethyl-carboxymethyl glycinate.Preferred amphoteric ionic surfactant is to be coconut palm acyl aminopropyl betaine by the CTFA representation, is the derivant of known fatty acid amide.

Amphoteric surfactant is so surface-active chemical compound that has, and promptly removes in the molecule and contains C ₈-C ₁₈Outside alkyl or the acyl group, have at least a free amine group and at least one-COOH or-SO ₃The H base; thereby can form inner salt, suitable examples of amphoteric surfactants is a N-alkyl glycine, N-alkyl alanine; N-alkylamino butanoic acid; N-alkyl imino dipropionic acid, N-ethoxy-N-alkyl amido propyl group glycine, N-alkyl taurine; N-alkyl sarcosine 2-alkylamino propanoic acid and alkylamino acetic acid; these alkyl respectively are 8 to 18 carbon atoms, and particularly preferred amphoteric surfactant is a N-coconut palm alkyl aminopropionic acid salt, coconut palm acyl group aminoethyl aminopropionate and C _12-18The acyl group sarcosine.

The for example polynary alcohol radical of the hydrophilic group that nonionic surfactant contains, the conjugate of polyalkylene glycols ether or polyol ethers and Polyethylene Glycol ether, these chemical compounds for example are:

The alkane and the straight-chain fatty alcohol of 8-22 carbon atom, the straight chain fatty acid or the alkyl of a 12-22 carbon atom are the addition compound product of the alkyl phenol of 8-15 carbon atom in the epoxy of the oxirane of-2-30 molecule and/or 0-5 molecule,

The C of the addition compound product that the oxirane of-1-30 molecule and glycerol generate ₁₂-C ₂₂Fatty-acid monoester or dibasic acid esters,

-C ₈-C ₂₂The analog of-alkyl monoglycosides and few glucoside and ethoxylation thereof

The oxirane of-5-60 molecule and the addition compound product of Oleum Ricini.

The chemical compound with alkyl used as surfactant can respectively be identical material often, have differently yet usually preferably make these materials thereby should be mentioned that, depend on the alkyl chain length mixture of each raw material by natural plants or animal material.

By oxirane and (or) surfactant made of the addition compound product of expoxy propane and aliphatic alcohol or the derivant of these products, can adopt and have " product that normal homologue distributes, the also product of employing with narrow distribution.So-called " normally " homologue distributes and is meant with alkali metal, alkali metal hydroxide or alkali alcoholate as the mixture of catalyst by the homologue of aliphatic alcohol and epoxyalkane reaction generation.But if use for example Hydrotalcite, ether carboxy acid alkali earth metal salt, the oxide of alkaline-earth metal, hydroxide or alcoholates are during as catalyst, to the surfactant of narrow homologue distribution, it may be preferred using the product with narrow homologue distribution.

The consumption of surfactant depends on the type of surfactant and the application target of prescription in the present invention's prescription.

Content cationic and/or nonionic surfactant is preferably 0.1-10%(weight in the gross weight of filling a prescription in the hair post-treatment agent), particularly preferred amount is a 0.1-3%(weight).

Hair care is cationic and (or) content of nonionic surfactant also be preferably 0.1-10%(weight in the gross weight of prescription) in the agent, is preferably 0.1-5%(weight especially).

Shampoo preferably contains anionic surfactant, preferably is preferably 3-20%(weight especially with both sexes and (or) nonionic surfactant combination, its content is counted 1-50%(weight with total formulation weight)).

The pH value of the present invention prescription is preferably 2.5-7,3-6 particularly,

Shampoo, hair post-treatment agent and hair care agent are optimization formulas of the present invention.Yet prescription also is used for continuing curly hair preparation, hair dye, does the agent for treatment of hair that scalds agent and other conventional usefulness.

This prescription can aqueous or water-alcohol solution, cream, lotion, jelly, Emulsion or the like dosage form be used for the cosmetics of general hair style.

Also contain other known composition about the prescription in agent for treatment of hair and the hair style agent field, these conventional compositions are:

-non-ionic polyalcohol, vinyl pyrrolidone/vinyl acrylate copolymer for example, polyvinyl pyrrolidone and vinyl pyrrolidone/vinyl acetate copolymer and polysiloxanes.

-anionic polymer, polyacrylic acid for example, cross linked polyacrylate, vinyl acetate/.beta.-methylacrylic acid copolymer, vinyl pyrrolidone/vinyl acetate copolymer, vinyl acetate/maleic acid butyl ester/isobornyl acrylate copolymer, methyl vinyl ether/copolymer-maleic anhydride/acrylic acid/ethyl acrylate/N-tert-butyl group acrylic acid amides terpolymer.

-other cationic surface active agent, for example quaternised cellulose ether contains the polysiloxanes of quaternary ammonium group, acrylic acid amides/chlorination dimethyl dialkyl copolymer, and the quaternised dimethylamino methyl acrylate/vinylpyrrolidone copolymer of dithyl sulfate

-thickening agent such as agar, guar gum, alginate, Xanthan-Gum(synthesising biological polymeric gel) and cellulose derivative,

-structural agent such as glucose and maleic acid,

-hair maintenance chemical compound such as phospholipid, soybean lecithin for example, lecithin and cephalin, and silicone oil,

-protein hydrolysate, particularly elastin laminin, collagen protein, keratin, lactoprotein, the hydrolyzate of soybean protein and wheat protein, the condensation product and the quaternised protein hydrolysate of they and fatty acid,

-perfumery oil, different sorbose of dimethyl and cyclodextrin,

-thickening agent, as ethanol, isopropyl alcohol, ethylene glycol, propylene glycol, glycerol and diethylene glycol,

-coloring agent,

-anti-dandruff medicament is decided zinc as Piroctone Olamine and smelly horse,

-other adjusting pH value material,

-active substance such as pantothenylol, allantoin, 2-pyrrolidone-5-carboxylic acid and salt thereof, plant extract and vitamin,

-opacifier,

-thickening agent, as sugar ester, polyol ester or polyol alkyl ether,

-fat and wax, as spermaceti, Cera Flava, montan wax, paraffin and aliphatic alcohol,

-Marlamid,

-chelating agent such as EDTA, NTA and phosphoric acid,

-swelling agent and penetrating agent such as glycerol, dihydroxypropane single-ether, carbonate, bicarbonate, guanidine, a urea and a generation, secondary, tertiary phosphate,

-clouding agent such as latex,

-pearling agent such as glycol monomethyl and two stearate,

-aerosol such as propane-butane gaseous mixture, N ₂O, dimethyl ether, CO ₂And air,

-antioxidant,

-direct dyes,

-as the what is called colour developing of oxidation dye precursors and the composition that adds lustre to,

-Reducing agent such as thiol acetic acid and derivant thereof, 2-mercaptopropionic acid, cysteamine, mercaptosuccinic acid. and alpha-mercapto ethyl sulfonic acid,

-oxidant such as hydrogen peroxide, Potassium bromate. and sodium bromate.

Method with prescription treatment of hair of the present invention also is a content of the present invention.

Preferred usage is that the active component of the present invention's prescription is coated on the hair, through (generally be several seconds to 20 minute) water after certain action time or mainly be that the abluent of water washes it on hair.

The following examples further specify the present invention.

Embodiment

I. the mensuration of wet comb property and dried sulfur

Research method

The research of comb property is by J.Soc.Cosm.Chem.1973(24) 782 method carries out.

Sulfur is all in brown (Alkinco ^#6634, send out 12cm long, send out heavy 1g) go up and study, this relates to the hair (cold wave or dye golden hair) of slight pre-damage, and is desirable as domestic consumer, after zero mensuration hair is immersed 100ml and is subjected in the test solution, act on after 5 minutes with 1l/min38 ℃ of flushing of circulating water 1 minute, redeterminating hair to determine the comb property that wets, is to determine to do comb property, and it is that 20% drying redeterminated after 12 hours that hair is placed 30 ℃ of relative air humidities.

The result

Listed the composition that tried mixture and the measurement result of carding operation in the table 1, each measures accurate calculate with zero the carding operation value, and statistical reliability is 99.99%.

1.C ₁₆/ C ₁₈Aliphatic alcohol (HENKEL)

2. glyceryl monostearate (CTFA name: tristerin) (HEWKEL)

3. cetyl stearyl alcohol (the CTFA name: Ceteareth-12) (HENKEL) of the oxirane of about 12 molecules is arranged

4. cetyl stearyl alcohol (the CTFA name: Ceteareth-20) (HENKEL) of the oxirane of about 20 molecules is arranged

5. mainly be condensation product (the CTFA life: octyldodecanol) (HENKEL) of the saturated liquid aliphatic alcohol of 20 carbon alkanols by the Guerbet prepared in reaction

6. methoxyl group chlorination vinyl imidazole quinoline/vinyl pyrrolidone copolymerization product (50: 50) (mean molecule quantity: about 80000 dalton; 40% active substance, CTFA name: Polyquaternium-16) (BASF)

7. vinyl pyrrolidone/Dimethylaminoethyl Methacrylate copolymer, with dithyl sulfate quaternized (being 19% active substance in the water) (GAF) result show, use mixture of the present invention and can make wet carding operation reach desirable improvement degree (stick up upright value range approximately or be lower than 70), hair style is fixed in the optimization range of about 230-270 has raising to dried carding operation simultaneously.

II. Application Example

The labelled amount of following embodiment is in % weight

1) hair washing

Stenol ^R1618 1，8

Tegoamid ^Rs18 ⁸1，6

1,2-propylene glycol 1,0

Citric acid. 0,6

Luviquat ^RFC 550 1，0

Polymer P 1 is pressed DE 39 29 973 0,2

Spice, water adds to 100

8.N, N-dimethyl-N '-stearyl-1, (the CTFA name: stearoyl amido propyl group dimethylamine (GOLDSCHMIDT) of 3-diaminopropanes

2) hair washing

Stenol ^R1618 1，8

Stepantex ^RVS90 ⁹1，8

1,2-propylene glycol 0,7

Citric acid 0,2

Luviquat ^RHM 552 ^6a2，5

Polymer P 1 is pressed DE 39 29 973 0,4

Spice, coloring agent, water adds to 100

9.N-methyl-N(2-ethoxy)-and N, N-two (oils and fats acyl-oxygen ethyl) ammonium ethoxy sulfate (90% active substance is in isopropyl alcohol) is (STEPSAN)

9a. methoxyl group chlorination vinyl imidazole quinoline/vinyl pyrrolidone copolymerization product (50: 50) (mean molecule quantity: (about 800000 dalton; 20% active substance .CTFA names Polyquaternium16) (BASF)

3) hair washing

Stenol ^R1618 2，5

Eumulgin ^RB 1 1，0

Eumulgin ^RB 2 1，0

Cutina ^RCP ¹⁰1，0

Eutanol ^RG 0，5

Polawax ^RGP 200 ¹¹0，75

Abil ^RQuat 3270 ¹²0，5

Dow Corning ^R929-Emulsion ¹³2，6

Luviquat ^RFC 370 ¹⁴0，8

Amphomer ^R15 0，8

Citric acid 0,02

Water adds to 100

10. by saturated long-chain fat brain alcohol and the ester that fatty acid generates, mainly be cetin (CTFA name: cetin) (HENKEL)

11. stearyl alcohol-polyglycol distearate mixture (the CTFA name: stearyl alcohol (with) the PEG stearate) (CRODA)

12. two quaternised polymethyl siloxanes (CTFA name: Quaternium-80) (GOLDSCHMIDT)

13. polydimethylsiloxane (35% active substance (DOWCORNING) of amino functional base is arranged.

14. methoxyl group chlorination vinyl imidazole quinoline/vinyl pyrrolidone copolymerization product (30: 70) (40% active substance; CTFA name: Polyquaternium16) (BASF)

15. methyl methacrylate/methacrylic acid tert-butylamine base ethyl ester/methacrylic acid 2-hydroxypropyl ester/N-(1,1,3, the 3-tetramethyl butyl) acrylamide copolymer (DELFTNATLONAL)

4) shampoo

Rewoquat ^RW 7500 ¹⁶1，1

Lanette ^RO ¹⁷3，0

Eumulgin ^RB 1 0，8

Eumulgin ^RB 2 1，6

Cutina ^RGMS 0，5

Eutanol ^RG 1，0

Luviquat ^RHM 552 1，2

Polymer P 1 is pressed DE 39 29 973 0,4

Water adds to 100

16. methoxyl group sulphuric acid 1-methyl-2-falls oils and fats alkyl-3-fatty acid-amino ethyl imidazoline (about 75% active substance) (REWO)

17. high-carbon saturated fat alcohol mixture mainly is (the CTFA name: cetearyl alcohol) (HENKEL) of spermol and stearyl alcohol

5) shampoo

Texapon ^RN 25 ¹⁸43，0

Dehyton ^RK ¹⁹10，0

Plantaren ^R-1200 ²⁰4，0

Euperlan ^RPK 3000 ²¹1，6

Arquad ^R316 ²²0，5

Luviquat ^RFC 550 1，2

Polymer P 1 is pressed DE 39 29 973 0,2

Glucamate ^RDOE 120 ²³0，5

Sodium chloride 0,2

Water adds to 100

18. lauryl ether sulfate (about 28% active substance, CTFA name: the sulphuric acid moon cinoxate sodium) (HENKEL)

19. general formula is R-CONH(CH ₂) ₃N ⁺(CH ₃) ₂CH ₂COO ^-(about 30% active substance of the fatty acid amide derivant with betaine structure; CTFA name: cocoamide base propyl group betaine) (HENKEL)

20. oligomeric degree is 1.4 C ₁₂-C ₁₆-alkyl-glucoside (about 50% active substance, CTFA name: lauryl polysaccharide glycosides) (HENKEL)

21. the liquid dispersion of pearly-lustre material and amphoteric surfactant (about 62% active substance, CTFA name: diglycol stearate (with) glycerol (with) Laurel ether-4(and) coconut palm amidopropyl betaine) (HENKEL)

22. chlorination three-C ₁₆Alkyl first ammonium (AKZO)

23. the methyl glucosamine-dioleate of ethoxylation (CTFA name: PEG-120 methyl glucoside dioleate) (AMERCHOL)

6) shampoo

Texapon ^RN 70 ²⁴21，0

Plantaren ^R-1200 8，0

Genamin ^RDSAC ²⁵1，2

Cutina ^REGMS ²⁶0，6

Luviquat ^RFC 370 2，0

Polymer P 1 is pressed DE 39 29 973 0,3

Antil ^R141 liquid ²⁷1，3

Sodium chloride 0,2

Water adds to 100

24. sulphuric acid moon cinoxate sodium (about 72% active substance) (HENKEL)

25. chlorination dimethyl distearyl ammonium (HOECHST)

26. ethylene glycol monostearate (about 25-35% monoesters, 60-70% dibasic acid esters; CTFA name: glycol stearate) (HENKEL)

27. polyoxyethylene-Rikemal PO 200 (40% active substance; The CTFA name: propylene glycol (with) PEG-55 propylene glycol oleate) (GOLDSCHMIDT)

7) shampoo

Texapon ^RK 14 S ²⁸50，0

Dehyton ^RK 10，0

Akypo ^RRLM 100 NV ²⁹4，5

Cutina ^RAGS ³⁰2，0

D-panthenol 0,5

Glucose 1,0

Salicylic acid 0,4

Sodium nitride 0,5

Polymer P 1 is pressed DE 39 29 973 0,6

Luviquat ^RHM 552 1，0

Water adds to 100

28. sulphuric acid lauryl nutmeg base ether-ether sodium (about 28% active substance; CTFA name: bean ether-ether sodium in the sulphuric acid) (HENKEL)

29.C _12-14(22% active substance: the CTFA name: Laurel ether-11 carboxylate sodium (CHEM-Y) of the oxirane-acetic acid sodium salt of-aliphatic alcohol+10 molecules

30. ethylene glycol stearate (about 5-15% monoesters, 85-95% dibasic acid esters; CTFA name: diglycol stearate) (HENKEL)

8) shampoo

Texapon ^RK 14 S 25，0

Texapon ^RSB 3 ³¹7，5

Eucarol ^RTA ³²12，0

Akypo ^RRLM 100 NV 9，0

Dehyton ^RAB 30 ³³8，3

Elfacos ^RGT 282S ³⁴0，5

Sodium chloride 0,5

Polymer P 1 is pressed DE 39 29 973 0,6

Luviquat ^RFC 550 4，0

Water adds to 100

31. sulfo-succinic acid half-ester disodium salt (about 40% active substance based on alkyl polyglycol ether; CTFA name: sulfo-succinic acid moon cinoxate disodium) (HENKEL)

32. the oxirane of lauryl alcohol+7 molecules-Tartaric acid sodium salt (about 25% active substance; CTFA name: tartrate-7 sodium) (AUSICHEM)

33. have aliphatic amine derivative (about 30% active substance of betaine structure; CTFA-name: coconut palm-betaine) (HENKEL)

34. the oxirane of oils and fats alcohol+60 molecules-nutmeg base ether (CTFA name: oils and fats ether 60 nutmeg ethyl glycols) (AKZO)

9) soak hair care (flushable)

Stenol ^R1618 3，0

Eumulgin ^RB 1 0，5

Eumulgin ^RB 2 0，5

Cutina ^RCP 1，0

Eutanol ^RG 1，5

Carbopol 980 ³⁵0，004

Dow Corning ^R929-Emulsion 2，9

Polymer P 1 is pressed DE 39 29 973 0,3

Luviquat ^RFC 550 4，0

Triethylamine 0,09

Water adds to 100

35. polyacrylic acid (GOODRLCH)

10) soak hair care (keeping on the dried hair)

Celquat ^RL200 ³⁶0，6

Luviskol ^RK30 ³⁷0，2

D-panthenol 0,5

Dehyquart ^RSP ³⁸1，0

Nutrilan ^RI ³⁹1，0

Natrosol ^R250 HR ⁴⁰1，1

Luviquat ^RFC 370 0，7

Polymer P 1 is pressed DE 39 29 973 0,5

Water adds to 100

36. quaternised cellulose derivative (95% active substance; CTFA name: Polyquaternium-4) (DELFTVNATIONAL)

37. polyvinyl pyrrolidone (95% active substance; CTFA name: PVP) (BASF)

38. the aqueous solution of phosphoric acid oxygen ethyl alkylammonium (about 50% active substance CTFA name: Quaternium-52) (HENKEL)

39. collagen hydrolysate (about 39% active substance; CTFA name: hydrolytic collagen) (HENKEL)

40 hydroxyethyl-celluloses (AQUALON)

11) hair dyeing frost

C _12-18Aliphatic alcohol 1,2

Lanette ^RO 4，0

Eumulgin ^RB 2 0，8

Cutina ^RKD 16 ⁴¹2，0

Sodium sulfite 0,5

L(+) ascorbic acid 0,5

Ammonium sulfate 0,5

1,2-propylene glycol 1,2

Polymer JR ^R400 ⁴²0,3

Right-amino phenols 0,35

Right-toluenediamine 0,85

2-methylresorcinol 0,14

The 6-methyl--amino phenols 0,42

Polymer P 1 is pressed DE 39 29 973 0,7

Luviquat ^RFC 550 1，0

Ammonia 1,5

Water adds to 100

41. fatty acid list/double glyceride-emulsifier mixture (the CTFA name: oils and fats glyceride (with) tristerin (with) potassium stearate) (HENKEL)

42. quaternised hydroxyethyl-cellulose (Union Carbide)

12) hair dyeing frost 11) fixation Emulsion

Texapon ^RN25 2，1

Hydrogen peroxide (50%) 12,0

Turpinal ^RSL ⁴³1，7

Latekoll ^RD ⁴⁴12，0

Polymer P 1 is pressed DE 39 29 973 0,1

Luviquat ^RFC550 0，9

Water adds to 100

43.1-hydroxyl ethane-1,1-diphosphonic acid (60% active substance, CTFA name: Etidronic Acid) (HENKEL)

44. acrylate-methacrylic acid copolymer (25% active substance) (BASF) pH value of this hair dyeing frost is 10.0, the hair dyeing laking.

13) tone shampoo

Texapon ^RN 70 14，0

Dehyton ^RK 10，0

Akypo ^RRLM 45 NV ⁴⁵14，7

Plantaren ^R-1200 4，0

Cremophor ^RRH 40 ⁴⁶0，8

Dyestuff C.I.12 719 0,02

Dyestuff C.I.12 251 0,02

Dyestuff C.I.12 250 0,04

Dyestuff C.I.56 059 0,03

PHB-ester 0,25

Luviquat ^RFC 370 1，6

Polymer P 1 is pressed DE 39 29 973 0,2

Spice q.s.

Water adds to 100

45. the oxirane-acetic acid sodium salt of lauryl alcohol+4.5 molecules (20.4% active substance) (CHEM-Y)

46. the oxirane of castor oil hydrogenated+45 molecules (CTFA name: the PEG-40 castor oil hydrogenated) (BASF)

After the hair washing of true qualities perfumery ripple, hair is that ball light is light brown.

14) prolonged curly hair frost

Wellcreme：

Plantaren ^R-800 ⁴⁷5，0

Thioglycolic acid 8,0

Turpinal ^RSL 0，5

Ammonia (25%) 7,3

Ammonium carbonate 3,0

Cetyl alcohol/stearyl alcohol 5,0

Guarbet-alcohol 4,0

Luviquat ^RHM 552 1，5

Polymer P 1 is pressed DE 39 29 973 0,1

Spice q.s.

Water adds to 100

47.C _8-10Alkyl-glucoside, its oligomeric degree are about 60% active substance of 1.6() (HENKEL)

Fixierloesung：

Plantaren ^R-800 5，0

Hardened Oleum Ricini 2,0

Potassium bromate. 3,5

Complexon I gsaeure 0,3

Citric acid 0,2

Polymer P 1 is pressed DE 39 29 973 0,2

Luviquat ^KFC 550 1，0

Spice q.s.

Water adds to 100

Claims (13)

1, a kind of water prescription that also has the treatment of hair of cation, both sexes or amphoteric ion type combination of polymers except that the cosmetic composition of routine that contains is characterized in that cationic polymer contains imidazolinyl.

2, according to the prescription of claim 1, it is characterized in that, contain a kind of non-ionic monomer in the cationic polymer at least.

According to the prescription of claim 2, it is characterized in that 3, this non-ionic monomer is a vinyl pyrrolidone.

4, according to a kind of prescription of claim 1 to 3, it is characterized in that, wherein contain amphoteric ion polymer.

5, according to the prescription of claim 4, it is characterized in that, the composition of this zwitterion polymerization mainly by:

α) the monomer with quaternary ammonium group of logical formula I

R in the formula ¹And R ²Represent hydrogen or methyl independently of one another, R ³, R ⁴And R ⁵Represent the alkyl of 1-4 carbon atom independently of one another, Z is-NH-base or oxygen atom that n is integer 2-5, A ^-Be the organic or inorganic acid ion,

β) the monomeric carboxylic acids of logical formula II, or these sour alkali metal, alkaline-earth metal, aluminum salt or ammonium salt

R in the formula ⁶And R ⁷Independent separately is hydrogen or methyl.

6, according to the prescription of claim 5, it is characterized in that, (α) monomer of the propylene dichloride amido propyl trimethyl ammonium of type and (β) monomer of type acryloyl or its alkali metal salt (particularly sodium salt) be acrylic acid.

According to the prescription of claim 5 or 6, it is characterized in that 7, the monomeric number of (α) type is greater than (β) type number of monomers in amphoteric ion polymer.

8, according to one prescription in the claim 1 to 7, it is characterized in that it contains

-0.01-10%(weight), both sexes 0.01-5%(weight particularly) or amphoteric ion polymer (in the prescription gross weight)

-0.01-10%(weight), cationic polymer 0.01-5%(weight particularly) (in the prescription gross weight).

9, according to one prescription in the claim 1 to 8, it is characterized in that, contain the surfactant that adds in addition.

10, according to the prescription of claim 9, it is characterized in that, surfactant be cation and (or) anion surfactant.

11, according to one prescription in the claim 1 to 10, it is characterized in that, between the pH value 2.5-7 of prescription, 3.0-6.0 particularly.

12, the method for treatment of hair is characterized in that, one prescription in the claim 1 to 11 is coated on the hair.

13, according to the method for claim 12, it is characterized in that last water or mainly be aqueous medicament flushing hair.