CN1098901A

CN1098901A - The Haircare composition of conditioning and enhanced shine is provided

Info

Publication number: CN1098901A
Application number: CN93120377.5A
Authority: CN
Inventors: E·D·布罗克; M·T·多德; J·J·霍普金斯; E·J·格罗斯戈吉特; T·A·劳
Original assignee: Procter and Gamble Co
Current assignee: Procter and Gamble Co
Priority date: 1992-10-22
Filing date: 1993-10-22
Publication date: 1995-02-22
Also published as: WO1994008557A1; JPH08502491A; AU5363394A; MX9306599A; EP0665740A1; MY109092A; CA2147474A1

Abstract

The invention relates to the Haircare composition that conditioning and enhanced shine can be provided to hair, it contains the non-volatile polysiloxane fluid of high index, the non-volatile spreading agent compatible with this polysiloxane fluid and the supporting agent that is suitable for using on hair.More particularly, the Haircare composition that is provided contains: the mixture that (i) contains following component; (a) refractive index is at least about 1.46 non-volatile polysiloxane fluid; (b) with the mutually blended non-volatile spreading agent that is used for this polysiloxane fluid of described polysiloxane fluid; (ii) be suitable for the supporting agent on hair, used.

Description

The Haircare composition of conditioning and enhanced shine is provided

What the present invention relates to is the Haircare composition that hair is provided conditioning and light effect, and more particularly, what the present invention relates to is to provide the Haircare composition of nursing one's health and strengthening the brightness effect to hair.

Usually people adopt the known numerous surface activator composition that contains cleaning strength of prior art to have one's hair wash.How preparing the shampoo that can effectively clean hair has been known, is easy to combing and feels simultaneously and seem comfortable, healthy ask for something but only provide cleaning action can not satisfy hair that most consumers makes them in itself to hair.

Make a hair commonsense method more comfortable and easier combing be to use hair conditioner, as cationic, quaternary surfactant and polymer, (gathering) siloxanes fluids and hydrocarbon or other organic oils.

A general approach improving the hair outward appearance is to use hair light activating agent, as lac, dimethicone, oils and wax class and quaternary surfactant.Some hair care components can provide the benefit of conditioning and bright hair simultaneously as oil and wax, dimethicone and cationic surfactant.Yet, just can not cause harmful effect when they only use to the look and feel of hair under finite quantity.For example, too much oil can make the outward appearance of hair scribble greasy sensation.The dimethicone of high concentration, cationic surfactant and wax can make hair produce dirt, cated sensation and can become soft, shapeless, particularly when reusing.And lac can make the stiff or adhesion of hair feel on the contrary.

The purpose of hair light activating agent is the amount that increases from hair surface reflection bright dipping.Generally accepted hair gloss is defined as from the reflected light of hair fiber reflection and the contrast of diffused light.This contrast has produced sensation with " health of hair " closely-related " gloss " or " light " to consumer.

Though as discussed above, prior art has been known a large amount of various hairs activating agent that adds lustre to, can make highly ornamental Haircare composition but still be sought after providing, condition is not increase expense, preparation difficulty or the hair defective on attractive in appearance, and the latter only increases when hair adds lustre to the content of activating agent to cause in the known compositions of prior art.One object of the present invention promptly provides the Haircare composition of this class.

The Haircare composition that further also needs to be provided not only can make hair add lustre to as mentioned above, but also provides opsonic action to hair, particularly improves combing and hair feel.Thereby another object of the present invention provides the Haircare composition that conditioning and enhanced shine can be provided simultaneously to hair.

Can provide these and other benefit according to following the present invention, described other benefit is possible will discuss, and perhaps is conspicuous to those skilled in the art.

Except as otherwise noted, all percentage ratio of this paper is all in the weight of compositions.All except as otherwise noted ratio all is weight ratio.Except as otherwise noted, the percentage ratio of pointed here all components, ratio and content are benchmark with the actual amount of component all.Do not comprise solvent, filler or other material that may in the commercially available prod, combine with described component.

The present invention can comprise essential element as herein described and any preferred or other optional components as herein described, also can be made up of described these materials, or mainly be made up of these materials.

Find now, non-volatile polysiloxane fluid by high index, the nonvolatile spreading agent (Spreading agent) that adapts with described polysiloxanes and the combination that is applicable to the supporting agent of hair can provide the Haircare composition that hair is had conditioning and enhanced shine.It is necessary that described compositions contains spreading agent, though because the polysiloxane fluid here has high index, they can not provide the obtainable high gloss by the present invention when not having spreading agent.

More particularly, the invention provides the Haircare composition that comprises above component:

(a) refractive index is at least about 1.46 non-volatile polysiloxane fluid;

(b) with the blended non-volatile spreading agent that is used for described (gathering) siloxanes of described polysiloxane fluid; With

(c) be applicable to the supporting agent of hair.

Wherein said compositions contains the described spreading agent of q.s to reduce the surface tension of polysiloxane fluid.Preferably, it is about 5% that surface tension reduces at least, more preferably reduce at least about 10%, and the total amount of the mixture of described polysiloxane fluid and described spreading agent account for described composition weight at least about 0.1%.The present invention can also change kind of mode and be stated as the described spreading agent that contains q.s in addition.Make the gloss meter specular reflectivity that with respect to described polysiloxane fluid, can make described mixture improve at least about △ 1.0%.

In a preferred embodiment, described polysiloxane fluid is the polysiloxanes of height arylation, particularly polysiloxanes such as pentapheneyl trimethyl trisiloxanes or the diphenyl methyl phenyl siloxane copolymer or the diphenyl dimethylsiloxane copolymer of height phenylating.

The spreading agent that is suitable for comprises but and the nonessential organic surface active agent that is limited to organic siliconresin (particularly MQ organic siliconresin), surfactant such as polyether siloxane copolymer and does not contain polysiloxanes.

The invention still further relates to the method that conditioning and enhanced shine are provided by applying said compositions on hair.

The compositions and methods of the invention and various hair products on a large scale unite that to use be favourable, these products comprise the compositions of indwelling such as hair lotion, nourishing agent, hair jelly, evil spirit silk drench (mousses), hair spray, etc. and the compositions such as shampoo and the hair rinse agent that rinse.

Below in more detail the present invention is narrated, comprising various optional and preferred examples.

Key component of the present invention and aspect and various choosing wantonly with preferred ingredient and embodiments of the invention are narrated below.

The non-volatile polysiloxane fluid of high index

Compositions of the present invention contains non-volatile polysiloxane fluid (" siloxanes fluids ") as key component, the refractive index of described polysiloxane fluid is at least about 1.46, preferably be at least approximately 1.48, more preferably be at least approximately 1.52, most preferably be at least about 1.55.The refractive index of polysiloxane fluid is generally less than 1.70, be typically to be lower than 1.60, but this is not the qualification necessary to the present invention.Polysiloxanes " fluid " comprises fluid and resin (gum).

Known as prior art, refractive index is meant the change (bending in the performance) of light direction when a kind of medium enters another kind of medium.Refractive index described here is meant that light is from air admission polysiloxane fluid or polysiloxane fluid/spreading agent mixture.The refractive index of polysiloxane fluid can use the standard device of prior art widespread usage to measure, as Abbe (Abbe) refractometer.At the chemical microscopy handbook, the first volume-chemical method and inorganic qualitative analysis, Chemot and Mason compile, John Wiley ﹠amp; Sons, Inc, New York, 1958, narrated the technology of measuring refractive index among the PP311-334.

The meaning that " non-volatile " here used is that the material vapour pressure at room temperature of indication is very low or do not have a significant steam pressure, as is known in the art with understand like that.The vapour pressure of general nonvolatile matter under 25 ℃ and atmospheric pressure is no more than 0.2mmHg.Generally, the boiling point of nonvolatile matter under an atmospheric pressure also is at least 275 ℃, preferably is at least 300 ℃.

The viscosity of used here polysiloxane fluid generally is at least about 10 centistokes in the time of 25 ℃, be preferably about 20 to about 2,000,000 centistoke, and more preferably about 30 to about 500,000 centistokes.The present invention also can use the non-volatile polysiloxane fluid of other viscosity, as long as satisfy other condition as herein described.In general, if obtain conditioning and hair enhanced shine, then preferably use more full-bodied material, be higher than about 50,000, preferably be higher than about 100,000 as viscosity by polysiloxane fluid.Can use glass capillary tube viscometer to measure viscosity, as Dow Corning Corporate Test Methed CTM0004(1970 July 20) in pointed.

Here the polysiloxane fluid of Shi Yonging comprises by represented those of logical formula I:

Wherein each R replaces or unsubstituted aliphatic group (as alkyl or alkenyl), aryl, aryloxy group, alkaryl, alkoxyl, alkyl amino (for example alkyl or alkenylamino group), hydroxyl or hydrogen or their combination; N is typically about 1 to about 1,000 for being 1 integer at least.The R substituent group also can comprise the combination of ether, hydroxyl and amine groups and other functional group such as halogen and halogenated functional group such as halogenated aliphatic group and aromatic group.

But polysiloxane fluid ring-type or straight chain.Top formula I is the example of straight chain polysiloxanes.Also can use branched.Cyclic polysiloxanes comprises by represented those of formula II:

R such as top defined wherein, n is about 3 to about 7, preferred 3 to 5.

Substituent group on siloxane chain (R) can have any structure, as long as resulting polysiloxanes at room temperature is still fluid state, be hydrophobic, nonirritant, toxicity do not have other harm again when using on hair, with other component of compositions be compatible, under normal use and storage requirement, chemical stability is arranged, can be deposited on the hair, and resulting polysiloxane fluid has above-mentioned refractive index.

Preferred alkyl and alkenyl substitutents are C ₁-C ₅Alkyl and alkenyl, more preferably C ₁-C ₄, C most preferably ₁-C ₂.Other aliphatic series part that contains alkyl one, alkenyl one or alkynyl group (as alkoxyl, alkaryl and alkyl amino) can be straight chain or side chain, preferably has one to five carbon atom, more preferably one to four carbon atom, further more preferably one to three carbon atom, most preferably one or two carbon atom.As discussed above, the R substituent group here can also contain amido functional group, and as alkyl amino, they can be cypress, the second month in a season or tertiary amine or quaternary ammonium.These comprise single, 21 and 31 alkyl amino and alkoxy aminos, and the chain length of aliphatic series part wherein preferably as mentioned above.Described R substituent group can also be replaced by other group, for example halogen (as chlorine, fluorine and bromine), halogenated aliphatic or aromatic group and hydroxyl (as the aliphatic group of hydroxyl replacement).The halo R group that is suitable for for example can comprise that 31 halos (preferred fluoro) alkyl is as-R ¹-C(F) ₃, R wherein ¹Be C ₁-C ₃Alkyl.The example of this class polysiloxanes comprises poly-methyl-3,3,3 trifluoropropyl siloxanes.

What the polysiloxane fluid of the high index here contained q.s contains aryl R substituent group refractive index is increased to aforesaid required value.

The substituent group that contains aryl contains alicyclic ring and heterocycle five and six-membered aromatic ring, and substituent group contains and condenses five or six-membered ring.Aromatic ring itself can be that replace or unsubstituted.Substituent group comprises aliphatic substituent group, can also comprise alkoxy substituent, acyl substituent, ketone, halogen (as Cl and Br), amine, etc.The example that contains aromatic yl group comprises and replacing and unsubstituted aromatic hydrocarbons that for example phenyl and phenyl derivatives are as having C ₁-C ₅The phenyl of alkyl or alkenyl substitutents, as allyl phenyl, aminomethyl phenyl and ethylphenyl, ethenylphenyl such as styryl, and phenyl alkynes (phenyl C for example ₂-C ₄Alkynes).Heterocyclic aryl comprises by deutero-substituent groups such as furan, imidazoles, pyrroles, pyridines.The fused aromatic rings substituent group comprises for example naphthalene, coumarin, purine.

Generally, it is about 15% that the degree that the polysiloxane fluid here contains aryl substituent is at least, preferably at least about 20%, more preferably at least about 25%, further more preferably at least about 35%, optimum at least about 50%.Typically, it is about 90% that aryl replacement degree is less than, and is more typically to be less than approximately 85%, be preferably about 55% to about 80%, but this is not to be the restriction necessary to the present invention.

The polysiloxane fluid here also has high relatively capillary feature because their aryl replaces.Generally, the surface tension of the polysiloxane fluid here is at least about 24 dyne/cm ², typically be at least about 27 dyne/cm ²For the present invention, use the around-France surface tension instrument of de Nouy according to Dow Corning Corporate Test Method CTM 0461(1971 November 23) come surface tension.Can measure capillary change according to above method of testing or according to ASTM Method D 1331.

Here preferred polysiloxane fluid has phenyl or phenyl derivatives substituent group (preferred phenyl) and alkyl substituent, preferred C ₁-C ₄Alkyl (most preferable) hydroxyl, alkyl amino (particularly-R ¹NHR ²NH ₂, each R wherein ¹And R ²Be C independently ₁-C ₃Alkyl, alkenyl and/or alkoxyl) combined.

The polysiloxanes of high index commercial can be by Dow Corning Corporation(Midland, Michigan, U.S.A), Huls AMerica(Piscataway, New Jersey, U.S.A), General Electric Silicones(Waterford, New York U.S.A) obtains.

Spreading agent

Compositions of the present invention also can comprise non-volatile spreading agent, is used for polysiloxane fluid.The spreading agent here must be compatible with polysiloxanes.

The definition of " non-volatile " is with top identical.The meaning of " compatible " is meant that spreading agent is soluble in polysiloxane fluid, dispersible or dissolves each other with it, and these two kinds of components can keep mixing in mutually the same of compositions like this.In other words, spreading agent mixes a kind of mixture of formation with polysiloxane fluid in compositions, and spreading agent therein lowers the surface tension of polysiloxanes.Capillary reduction can be measured according to the foregoing method of this paper.The spreading agent here can be continuous or discontinuous phase in compositions of the present invention with polysiloxane fluid.

As one aspect of the present invention, the compositions here can be defined as the spreading agent that contains q.s, with the surface tension with polysiloxane fluid, reduction is at least about 5%, preferably at least about 10%, more preferably at least about 15%, further more preferably at least about 20%, most preferably at least about 25%.Polysiloxane fluid/capillary reduction of spreading agent mixture can provide improved enhanced shine to hair.Surface tension is general in preferred compositions of the present invention reduces about 20% to about 35%, is more generally about 25% to about 30%, but this be not be to surface tension reduce at utmost to the necessary qualification of what concrete amount.

Generally, spreading agent should make surface tension reduce at least about 2 dyne/cm ², preferably at least about 3 dyne/cm ², further preferably at least about 4 dyne/cm ², most preferably at least about 5 dyne/cm ²

According to the ratio in final products, the surface tension of polysiloxane fluid and spreading agent mixture is preferably 30 dyne/cm ²Or lower, 28 dyne/cm more preferably from about ²Or lower, 25 dyne/cm most preferably from about ²Or it is lower.Typically, surface tension is about 15 to 30, and more typical is about 18 to about 28, is generally about 20 most to 25 dyne/cm ²

Gloss is a kind of physical property that constitutes object light or honorable outward appearance.Gloss can measure by specular reflectivity.Specular reflectivity be meant incident illumination from a surface on the minute surface direction (being catoptrical direction) for becoming 180 ° by the direction of light source directive reflecting surface with light at the ratio or the percentage ratio of a concrete angular deviation range internal reflection.Specular reflectivity is the means that can be used for the gage outfit luminosity.The further background knowledge of specular reflectivity and its application in estimating the hair brightness can be referring to R.F.stamm, M.L.Garcia, and J.J.Fuchs, " optical characteristics-I. of Crinis Carbonisatus conceives and the goniophotometer curve substantially; and II. the gloss of Crinis Carbonisatus fiber; " J.Soc.Cosmet.Chem.28,571-599 and 601-609(1977 JIUYUE), here it all is incorporated herein by reference.

Relevant by the specular reflectivity that records in the coating that is coated with the present composition on the black pottery porcelain plate of collagen with the brightness of hair, and the doubt that the experiment that thus discordance of hair sample and the agent of deposition head luminance is caused changes the specular reflectivity data that cause reduces.The specular reflectivity of measuring in the present invention that scribbles on the black pottery porcelain plate of collagen layer in this class is determined according to following " experiment " program partly, and is referred to as the gloss meter specular reflectivity in this article.

The present invention can also be stated as the compositions that contains spreading agent and polysiloxane fluid mixture, wherein said composition contains the spreading agent of q.s to improve the gloss meter specular reflectivity of described mixture, with respect to polysiloxane fluid, improve at least about " delta 1.0% " (this paper back is called " △ 1.0% ", and wherein delta is meant with primary light density to be the change of the specular reflectivity of 100% benchmark).Preferably, the gloss meter specular reflectivity improves at least about △ 2.0%, more preferably at least about △ 5.0%, further more preferably at least about △ 7.5%, most preferably at least about △ 10.0%.

Measure the gloss meter specular reflectivity according to the described program of following " experiment " part.Generally, use 1.0% the solution of polysiloxane fluid in solvent, this solvent and polysiloxane fluid same solvent (if any) used in mutually in described compositions is identical.If polysiloxane fluid independently solvent of no use dilutes in compositions, then should use SILIBIONE OIL 70047 V20 DC-21330 DC21330 (Cyclomethicone) to prepare described 1.0% solution.If necessary, can use SILIBIONE OIL 70047 V20 DC-21330 DC21330/alcoholic solution to be formed for described test purpose 1.0% polysiloxanes.In contrast, do not comprise spreading agent.In addition, by the weight ratio of polysiloxane fluid in the compositions and spreading agent spreading agent is added in the described solution.Test solution is deposited on the black ceramic brick of collagenic coating and makes it dry.Measure specular reflectivity with gloss meter, it is a kind of spectrophotometer that is suitable for measuring the planar surface specular reflectivity.The gloss meter that is suitable for is commercial available and be that prior art is known, for example can be by BYK-Gardner, and " micro--gloss " gloss meter that Ind, Silver spring, MD, USA obtain.

Generally, the weight ratio of polysiloxane fluid and spreading agent is about 1000: 1 to about 1: 10, is preferably about 100: 1 to about 1: 1, more preferably about 50: 1 to about 2: 1, most preferably is about 25: 1 to about 2: 1.For hair rinse composition, preferred especially this ratio is about 10: 1 to about 2: 1.When using fluorizated surfactant, extra high polysiloxanes: effectively, this is the effectiveness that has benefited from this class surfactant to the spreading agent ratio.Thereby expectation can be used the ratio that was significantly higher than 1000: 1.

The preferred development agent of Shi Yonging here comprises polyorganosiloxane resin and surfactant, comprising polyether siloxane copolymer with do not contain the organic surface active agent of poly-silica silane.Particularly preferred spreading agent is a polyorganosiloxane resin.

Polyorganosiloxane resin

Polyorganosiloxane resin is highly cross-linked polymer siloxane system.In making the polyorganosiloxane resin process, cause crosslinked by introducing the trifunctional and the silane of four-functional group and the monomeric unit of simple function group or difunctional (or both all have).Known as prior art, for obtaining the required degree of cross linking of polyorganosiloxane resin, concrete silane unit changes in the polyorganosiloxane resin according to introducing.Generally, trifunctional and four-functional group siloxanyl monomers unit (thus, the crosslinked of enough degree being arranged) that the polysiloxanes material has q.s make that they can become hard film when dry, and such polysiloxanes material is considered to polyorganosiloxane resin.In a concrete polysiloxanes material, the ratio of oxygen atom and silicon atom is the sign of crosslinking degree.General each silicon atom of polyorganosiloxane resin has at least about 1.1 oxygen atoms.Preferably, oxygen: the ratio of silicon atom was at least about 1.2: 1.0.The typical silane that uses in the preparation polyorganosiloxane resin has: monomethyl one, dimethyl one, single phenyl one, diphenyl one, aminomethyl phenyl one, mono-vinyl one and methyl ethylene one chlorosilane, and tetrachloro silicane.Preferred resin is the methyl substituted polyorganosiloxane resin, for example those that are provided with GE SS4230 and SS4267 by general Electric.Commercially available polyorganosiloxane resin generally provides with non-hardened form, is low viscosity volatility or preferred non-volatile polysiloxane fluid.The polyorganosiloxane resin of Shi Yonging is non-hardened form existence in compositions of the present invention in this article, rather than is hardened resin existence, and this will be readily apparent to persons skilled in the art.

About the background material of polysiloxanes comprise the part that polysiloxane fluid, glue and resin and polysiloxanes make is discussed can be referring to " polymer science and engineering encyclopedia ", 15 volumes, second edition, PP204-308, John Wiley﹠Sons, Inc, 1989 and " polysiloxanes chemistry and technology ", walter Noll, Academic Press, Inc. (Harcourt Bruce Javanovich, Publishers, New York), 1968, PP282-287 and 409-426 all are incorporated herein by reference the two here.

According to well known to a person skilled in the art shorthand nomenclature polysiloxanes material particularly polyorganosiloxane resin can be defined as " MDTQ " name easily.In this system, polysiloxanes is narrated according to the various siloxanyl monomers unit of forming polysiloxanes.Say that concisely symbol M is represented simple function group unit (CH ₃) ₃SiO) ₅, D represents difunctional unit (CH ₃) ₂SiO, T represent trifunctional unit (CH ₃) Si _1.5, Q represents four-functional group cell S iO ₂The apostrophe of unit symbol is M ', D ', T ' and Q ' expression other substituent group except that methyl for example, and each the appearance must specifically limit.Typical alternative substituent group comprises for example group of vinyl, phenyl, amine, hydroxyl etc.Various unitary mol ratios, perhaps represent with the symbol footnote that shows the unitary total number of all kinds (or its meansigma methods) in polysiloxanes, perhaps be the ratio that combines with molecular weight and specifically indicate, make that the narration to the polysiloxanes material is complete in the MDTQ system.The mole of high T, Q, T ' and/or Q ' is the sign of high-crosslinking-degree with respect to D, D ' M and/or M ' in polyorganosiloxane resin.Then, as previously discussed, the ratio of oxygen and silicon also can be the sign of the overall degree of cross linking.

The preferred in this article polyorganosiloxane resin that uses is MQ, MT, MTQ and MDTQ resin.Like this, preferably the polysiloxanes substituent group is a methyl.Especially preferred MQ resin, particularly those M wherein: the Q mol ratio be the mean molecule quantity of about 0.5: 1.0 to about 1.5: 1.0 and resin be about 500 to about 10,000, be generally about 1,000 to about 10,000.

According to the concrete selection of spreading agent (particularly polyorganosiloxane resin) and polysiloxane fluid, having necessity maybe needs to introduce additional solvent to guarantee that described resin and polysiloxane fluid are mutually compatible.Like this, if at required polysiloxane fluid: polyorganosiloxane resin and polysiloxane fluid are inconsistent under the polyorganosiloxane resin part by weight, and then utilizable approach is to introduce dissolubility or the dispersion of a kind of solvent to improve these components at polysiloxanes/spreading agent in mutually.If the refractive index of solvent is lower than 1.46, or be lower than the refractive index of polysiloxane fluid, (vapour pressure of this material is greater than 0.2mmHg under 25 ℃ of atmospheric pressure then to use volatile solvent, and generally its boiling point is lower than 275 ℃) may be favourable, its noresidue and the performance of adding lustre to that obtains according to the present invention do not had potential damage on hair like this.The solvent that is suitable for comprises: SILIBIONE OIL 70047 V20 DC-21330 DC21330, other cyclosiloxane for example this paper narrate as carrier fluid those, the straight chain polysiloxane polymer is dimethicone for example, and other low viscosity analog of the polysiloxanes material of in formula I and II, narrating, be about 10 centistokes or lower preferably, compare the general degree that contains aryl substituent that has of this class material lower (or zero) with high arylation of the present invention, high index polysiloxanes 25 ℃ of viscosity; Volatile liquid hydrocarbon, for example straight or branched have about 4 hydrocarbon to about 16 carbon atoms (as, hexane, iso-butane, decane, dodecane, the tetradecane, tridecane); Lower alcohol is (as C ₂-C ₄Alcohol is ethanol and isopropyl alcohol for example); The hydrocarbon ester, preferably have an appointment altogether 10 carbon atoms or still less (for example ethyl acetate); Halogenated hydrocarbons (as fluorine Lyons); Volatility ketone (for example acetone); And their mixture.Especially preferred SILIBIONE OIL 70047 V20 DC-21330 DC21330.But the present invention does not get rid of the solvent of use non-volatile solvents as the polysiloxanes of resin/phenylating.

When using, as mentioned above, the typical amounts of solvent is, for the hair products that rinse, the weight ratio of (solvent) and (the non-volatile polysiloxanes of height arylation adds spreading agent) was up to about 100: 1, more typical is up to about 50: 1, and this weight ratio is preferably about 2: 1 to about 10: 1 for the hair rinse product.Product for keeping somewhere can use a high proportion of volatile solvent as the supporting agent component, narrates as the back.

Surfactant

Surfactant compatible with the polysiloxane fluid here and that be suitable for using on hair also can be used as spreading agent.Surfactant can be anionic, cationic, nonionic, amphoteric or amphoteric ion type.

Polyether siloxane copolymer

Polyether siloxane copolymer perhaps is called polysiloxanes " polyol (copolyols) altogether " sometimes, is the surfactant that contains polysiloxanes, can be as the spreading agent of polysiloxane fluid.The common polyol of polysiloxanes is to have hydrophobic polysiloxane chain and hydrophilic alkoxyl part as the feature of surfactant.

Operable polysiloxanes altogether polyol comprise structural formula following by the polydimethylsiloxane of polyalkylene oxide modification:

With

R′-Si--［-OSi(CH ₃) ₂］ _X-(OC ₂H ₄) _a-(OC ₃H ₆) _b-OR″

Wherein R is a hydrogen, has 1 alkyl to about 12 carbon atoms, has 1 alkoxyl or hydroxyl to about 6 carbon atoms; R ' and R " be to have 1 alkyl to about 12 carbon atoms, X is 1 to 100 integer, preferred 20 to 30; Y is 1 to 20 integer, preferred 2 to 10; A and b are 0 to 50 integers, preferred 20 to 30.

Comprise that the polysiloxanes that can use in this article is total to polyol and also is disclosed in the following patent literature, this paper all is incorporated herein by reference them here: the U.S. patent 4,122,029 that on October 24th, 1978 was authorized people such as Geen; Authorized the U.S. patent 4,265,878 of Keil on May 5th, 1981; Nineteen eighty-three, December authorized people's such as Dixon U.S. patent 4,421,769 on the 20th.The many alcohol matters of polysiloxanes copolymerization of this class also are disclosed in the compositions that is used for hair of following patent documentation, these documents are to be disclosed in the UK Patent Application 2 of on July 15th, 1981 by the Abe application, 066,659(this paper is introduced into as a reference) and authorized the Canadian Patent 727 of Kuehns on February 8th, 1966,588(this paper is introduced into as a reference).Can be total to polyol at commercially available polysiloxanes used herein and comprise Silwet surface active block copolymer (making) by Union Carbide Corp; With Dow Corning polysiloxane surfactant (making) by Dow Corning Corporation.

Operable a series of suitable organic surface active agent that does not contain siloxanes is in following narration.

Anionic surfactant

The anionic surfactant that can use in this article comprises alkyl and alkyl ether sulfate.This class material typically has corresponding formula R OSO ₃M and RO(C ₂H ₄O) _XSO ₃M, wherein R is that the about 10 alkyl or alkenyl X to about 20 carbon atoms are 1 to 10, M is water-soluble cation such as ammonium, sodium, potassium and triethanolamine.

Another kind of suitable anionic surfactant is water-soluble salt of Organic substance, sulfuric acid reaction product, and its general formula is as follows:

R wherein ₁Be from having about 8 groups of selecting to about 24, preferred about 12 straight or brancheds, the saturated fat hydrocarbyl group to about 18 carbon atoms; M is a cation.Important example is the salt of Organic substance sulfuric acid reaction product of the hydrocarbon of methane series, comprise have about 8 to about 24 carbon atoms, preferred about 12 to different one, new one and normal paraffin hydrocarbons of about 18 carbon atoms and sulfonating agent SO for example ₃, H ₂SO ₄, oleum comprises that according to known method of sulfonating bleaching and hydrolysis are obtained.Preferred sulfonation C _12-18The alkali metal of normal paraffin hydrocarbons and ammonium salt.

The example of other anionic surfactant for the present invention is that fatty acid is carried out esterification and used the neutral product of sodium hydroxide by isethionic acid, and wherein for example fatty acid is to be derived from Oleum Cocois; The sodium or the potassium salt of the fatty acid amide of methyl taurate (methyl tauride), fatty acid wherein for example is to be derived from Oleum Cocois.The visible U.S. patent 2,486,921 of other anionic surfactant of this class; 2,486,922; With 2,396,278.

Other again anionic surfactant comprises a class that is called succinamic acid (Succinamates) salt.Surfactant that this class comprises such as N-octadecyl sulfonation succinamide acid disodium; N-(1,2-dicarboxyl ethyl)-N-octadecyl sulfonation succinamic acid four sodium; The diamyl ester of sulfosuccinate sodium; Two basic esters of sulfosuccinate sodium; The dioctyl ester of sulfosuccinate sodium.

Available in this article other suitable anion surfactant is the alkene sulfonate with about 12 to 24 carbon atoms.The meaning that " alkene sulfonate " here uses is meant can carry out sulfonation by the sulfur trioxide of alpha-olefin by not complexation, then to the acid reaction mixture resulting chemical compound that neutralizes, the condition of wherein carrying out neutralization reaction is to make any sultone hydrolysis that forms in reaction generate corresponding hydroxyl-alkylsulfonate.The alpha-olefin of alkene sulfonate of deriving be have about 12 to about 24 carbon atoms, preferred about 14 monoolefines to about 16 carbon atoms.The anion organic surface active agent of an other class is a b-alkoxyalkyl sulfonate.

Nonionic surfactant

Nonionic surfactant can be broadly defined as the chemical compound that is generated by condensation reaction by alkylene oxide group (hydrophilic) and a kind of hydrophobic compound (it can be aliphatic or alkyl aromatic).The example of non-ionic surface active agent preferred classes has:

1. the polyethylene oxide condensation compound of alkyl phenol, for example have and contain about 6 to about 20 carbon atoms or be straight chain or be the alkyl phenol of alkyl of chain configuration and the condensation product of oxirane, wherein the amount of the described oxirane of Cun Zaiing equals every mole of alkyl phenol and has an appointment 10 to about 60 moles oxirane.

2. reacting products therefrom and oxirane by propylene oxide and ethylenediamine, to carry out condensation institute deutero-.

3. be having of straight or branched configuration about 8 to the aliphatic alcohol of about 18 carbon atoms and the condensation product of oxirane, for example have the coconut alcohol ethylene oxide condensate of every mole of coconut alcohol about 10 to about 30 moles of ethylene oxide, coconut alcohol partly has about 10 to about 14 carbon atoms.

4. the oxide of long chain tertiary amine is for example corresponding to following general formula:

R wherein ₁The alkyl, alkenyl or the monohydroxy alkyl group that contain 8 to 18 carbon atoms of having an appointment, 0 to about 10 ethylene oxide moieties and 0 to about 1 glyceryl part, R ₂And R ₃Contain have an appointment 1 to about 3 carbon atoms and 0 to about 1 hydroxyl, for example methyl, ethyl, propyl group, ethoxy or hydroxypropyl group (arrow in the formula is represented semi-polar bond).

5. corresponding to the long chain tertiary phosphine oxide of following general formula:

Wherein to contain chain length be about 8 alkyl to about 18 carbon atoms, alkenyl or monohydroxy alkyl group to R, and 0 to about 10 ethylene oxide moieties and 0 to 1 glyceryl part, R ' and R, and " each contains about 1 alkyl or monohydroxy alkyl to about 3 carbon atoms naturally.Arrow in the formula is represented semi-polar bond.

6. long-chain dialkyl sulphoxide, it contain one about 1 to the short-chain alkyl of about 3 carbon atoms (normally methyl) or hydroxy alkyl group and long hydrophobic chain comprising containing have an appointment 8 alkyl, alkenyl, hydroxy alkyl or ketone alkyl groups to about 20 carbon atoms, 0 to about 10 ethylene oxide moieties and 0 to about 1 glyceryl part.

7. Spheron MD 30/70, for example fatty acid cane sugar ester.This class material is described in U.S. patent 3,480,616, a kind of mixture of Sucrose Cocoate(coconut acid sucrose ester for example, mainly form, sell with trade (brand) name CRODESTA SL-40 with trade (brand) name GRILLOTEN LSE87K, Croda) by RITA by monoesters.

8. the alkyl polysaccharide nonionic surfactant is described in the U.S. patent 4 of authorizing Llenado on January 21st, 1986,565, in 647, it have one contain about 6 to about 30 carbon atoms, preferred about 10 to the hydrophobic group of about 16 carbon atoms and polysaccharide, for example poly glucoside, hydrophilic group.Described polysaccharide can contain has an appointment 1.0 to about 10, preferred about 1.3 to about 3, most preferably from about 1.3 to about 2.7 sugar units.Any reducing sugar that contains 5 or 6 carbon atoms all can use, for example glucose, galactose, and also the galactosyl part can be replaced by the glucosyl group part.(optional hydrophobic group can be connected in 2-, 3-, 4-, etc. on the position, obtain glucose or the galactose relative like this with glucoside or galactoside.) between sugar key (the intersaccharide bonds) can 2-, the 3-of position of for example additional sugar unit and aforementioned sugar unit, 4 and/or the 6-position between.Optional can also have a polyalkylene oxide (Polyalkyleneoxide) chain to connect hydrophobic part and polysaccharide part.Alkyl preferably contain about 3 hydroxyls of as many as and/or polyalkyleneimine chain can contain as many as about 10, preferably be lower than 5 alkylene parts.The alkyl polysaccharide that is suitable for is octyl group, nonyl, decyl, undecyl, dodecyl, tridecyl, myristyl, pentadecyl, cetyl, heptadecyl and octadecyl, 21,31,41, May Day and six glucosides, galactoside, lactoside (lactoside), glucose, fructoside, fructose and/or galactose.

9. Polyethylene Glycol (PEG) glycerin fatty ester (glyceryl fatty esters) is as by formula RC(O) OCH ₂CH(OH) CH ₂(OCH ₂CH ₂) nOH is represented, wherein n is about 5 to about 200, preferred about 20 to about 100, more preferably from about 30 to about 85, RC(O)-be a kind of ester, wherein R comprise have 7 to about 19 carbon atoms, preferred about 9 to about 17 carbon atoms, more preferably from about 11 to 17 carbon atoms, 11 aliphatic groups most preferably from about to about 14 carbon atoms.N is about 20 to about 100 and C ₁₂-C ₁₈Preferred C ₁₂-C ₁₅Fatty ester is combined to be preferred, can be used for the adverse effect to foaming is reduced to minimum.

Cationic surface active agent

The cationic expression activating agent that can use in compositions of the present invention, particularly conditioner composition contains amino or quaternary ammonium hydrophilic segment, and this is partly with positive charge when dissolving in Aquo-composition of the present invention.Comprised those that can use in the present invention in following document in the disclosed cationic surface active agent, all following document this paper all are incorporated herein by reference: M.C.Publishing Co., McCutcheon ' s Detergents; Emulsifiers, (North America version in 1979); Schwartz etc., surfactant, their chemistry and technology, New York, Interscience Publishers, 1949; Authorized the U.S. patent 3,155,591 of Hilfer on November 3rd, 1964; Decembers in 1975 were authorized the U.S. patent 3,929,678 of Laughlin etc. on the 30th; Authorized the U.S. patent 3,959,461 of Bailey etc. on May 25th, 1976; With authorize Bolich, the U.S. patent 4,387,090 of Jr. June 7 nineteen eighty-three.

In can be used for the cationic surface active agent material that contains quaternary ammonium of the present invention, represented those of following general formula are arranged:

R wherein ₁-R ₄Be about 1 aliphatic group independently, or have about 12 aromatics, alkoxyl, polyoxyalkylene, alkylamidoalkyl, hydroxy alkyl, aryl or kiki fang alkyl group to about 22 carbon atoms to about 22 carbon atoms; X is the anion that is selected from halogen, acetate root, phosphate root, nitrate root and alkyl sulfate foundation group.Outside de-carbon and the hydrogen atom, aliphatic group also can contain ether chain and as other amino group.Those groups of for example about 12 carbon atoms of long-chain aliphatic group or more carbon atoms can be saturated or unsaturated.

The primary, the salt of the second month in a season and uncle's aliphatic amine also is the cationic surface active agent material that is suitable for.The alkyl of this class amine preferably has about 12 to about 22 carbon atoms, can be substituent group or unsubstituted.This class amine that can use in this article comprises the amino propyl-dimethyl amine of stearoyl, diethylamino ethyl stearmide, dimethyl stearylamine, dimethyl Soyamine, Soyamine, tetradecylamine, tridecyl amine, ethyl stearylamine, N-cattle ester propanediamine, ethoxylation (5 moles of E.O.) stearylamine, dihydroxy ethyl stearylamine and Semen arachidis hypogaeae mountain Yu amine (arachidylbenhenylamine).The amine salt that is suitable for comprises halogen, acetate, phosphate, nitrate, citrate, lactate and alkyl sulfate.These salt comprise the amino propyl-dimethyl amine citrate of stearyl amine hydrochloride, Soyamine Chloride, stearylamine formates, N-cattle ester propanediamine dichloride and stearoyl.Authorize on June 23rd, 1981 comprised in the disclosed cationic amine surfactant in the U.S. patent 4,275,055 of Nachtigal etc. can be used for of the present invention those, the document is incorporated herein by reference here.

Amphoteric ion type and amphoteric surfactant

The example of the amphoteric ionic surfactant that can use in shampoo and conditioner is those of derivant that can broad sense be stated as aliphatic quaternary ammonium, Phosphonium, sulfonium compound, aliphatic group wherein can be a straight or branched, and one of them aliphatic substituent group contains and has an appointment 8 to about 18 carbon atoms, an aliphatic substituent group contains the water-soluble group of anionic, for example carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.The general formula of these chemical compounds is:

R wherein ²Contain have an appointment 8 alkyl, alkenyl or hydroxy alkyl group to about 18 carbon atoms, 0 to about 10 ethylene oxide moieties and 0 to about 1 glyceryl part; Y is selected from the group of being made up of nitrogen, phosphorus and sulphur atom; R ³Be to contain 1 alkyl or the monohydroxy alkyl of having an appointment to about 3 carbon atoms; X is 1 when Y is sulphur atom, and X is 2 when Y is nitrogen or phosphorus atoms; R ⁴Be about 1 alkylidene or hydroxy alkylidene to about 4 carbon atoms; Z is the group that is selected from the group of being made up of carboxylate radical, sulfonate radical, sulfate radical, phosphonate radical and phosphate groups.

The surfactant of other amphoteric ion type such as betanin also can be used for the present invention.Here the example of spendable betanin comprises high alkyl betaine, as coco group (COCO) dimethyl carboxymethyl betaine, dodecyl dimethyl carboxymethyl betaine, dodecyl dimethyl α-carboxyethyl betanin, hexadecyldimethyl benzyl ammonium carboxymethyl betaine, dodecyl two-(2-ethoxy) carboxymethyl betaine, stearyl be two-(2-hydroxypropyl) carboxymethyl betaine, oil base (oleyl) dimethyl γ-carboxylic CAB and dodecyl be two-(2-hydroxypropyl) α-carboxyethyl betanin.The representative example of sulfobetaines be coco group (COCO) dimethyl sulfo group ethyl betanin, stearyl dimethyl sulfopropyl betaine, dodecyl dimethyl sulfo group ethyl betanin, dodecyl two-(2-ethoxy) sulfopropyl betaine and analog; Amido betaine and amidosulfobetaines be RCONH(CH wherein ₂) ₃Group is connected also can use in the present invention on the nitrogen-atoms of betanin.

The examples of amphoteric surfactants that can use in the present composition is broadly to be stated as those of the secondary and tertiary amines derived thing of aliphatic series, wherein aliphatic group can be straight chain or side chain, and one of them aliphatic substituent group contains and has an appointment 8 to about 18 carbon atoms, and an aliphatic substituent group contains water-soluble anion base: as carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.Fall into examples for compounds within this definition and be 3-sodium dodecyl aminopropionitrile, 3-dodecyl amino propane sulfonic acid sodium, N-alkyl taurine (as according to U.S. patent 2; 658; 072 instruct lauryl amine and hydroxyethyl sulfonate are reacted prepare), N-senior alkyl aspartic acid is (as according to U.S. patent 2; 438; the preparation of 091 training centre) and sell and be described in U.S. patent 2 with trade mark " Miranol " by name; 528; product in 378, above-mentioned two pieces of patents all are incorporated herein by reference here.

Operable other surfactant comprises fluoro surfactants or other halo surfactant, and they can be anionic, nonionic, cationic, amphoteric or amphoteric ion type.

Fluoro surfactants comprises fluoridized chemical compound, and is for example represented by following formula:

Wherein Z is water-soluble organic or inorganic group, X be generally 2 to 17,7 to 11 integer particularly, Y is 0 to 4 integer, according to the difference of group (one or more) character that Z comprised, described chemical compound can be cationic, anionic, amphoteric or amphoteric ion type.The Z group can be or comprise sulfate, sulfonate, carboxylate, amine salt, quaternary ammonium salt, phosphate, phosphonate and their combination.Fluoridized chemical compound is well known in the art.These chemical compounds are described in the U.S. patent 4,176,176 of authorizing people such as Cella on November 27th, 1979; The U.S. patent 3,993,745 that on November 23rd, 1976 was authorized people such as Cella; Authorize in people's such as Cella the U.S. patent 3,993,744 with on November 23rd, 1976, this paper all is incorporated herein by reference these documents.

The typical amounts of fluoro surfactants is lower than other spreading agent of great majority in use.Generally their consumption is that the weight ratio of polysiloxanes and spreading agent is about 10,000: 1 to about 1: 1, and preferred about 1,000: 1 to about 10: 1.

Generally, compositions of the present invention contains and blended about 0.01% to the 100%(weight of polysiloxane fluid) spreading agent, be more generally about 0.05% to about 50%, preferred about 0.1% to about 15%, more preferably from about 0.2% to about 5%, can use any amount, be effective as long as said composition is added lustre to for hair.

Supporting agent

Compositions of the present invention also contains the supporting agent of polysiloxane fluid and spreading agent, and this supporting agent can be applicable to hair.The content of supporting agent in compositions is 0% to about 99.99%, is more generally about 50% to about 99.95%, is preferably about 85% to about 99.9%, most preferably from about 95% to about 99.8%.Here used " can be applicable to hair " is meant that supporting agent does not cause stimulation to the attractive in appearance harmless or harmful effect of hair or to skin.Select suitable supporting agent also will depend on used concrete polysiloxane fluid, depend on that also the product of being prepared is to stay (for example hair spray, foam silk drench (mousse), nourishing agent) or rinse (for example shampoo, conditioner) on the surface of being used after use.

Supporting agent used herein comprises solvent and general other supporting agent or media components in Haircare composition.

Be applicable to carrier fluid of the present invention including but not limited to water, lower alcohol (C for example ₁-C ₆-hydroxyl alcohol, for example ethanol and isopropyl alcohol), the mixture of water alcohol, hydrocarbon (iso-butane for example, hexane, decene, acetone), halogenated hydrocarbons (for example freon), linalool, hydrocarbon ester (ethyl acetate for example, dibutyl phthalate), volatility silicon derivative, particularly siloxanes (1,1,1,3,3-Pentamethyl-3-phenyldisiloxane for example, methoxy-propyl seven methyl cyclotetrasiloxanes, chloro propyl group pentamethyl disiloxane, the hydroxypropyl pentamethyl disiloxane, octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane, SILIBIONE OIL 70047 V20 DC-21330 DC21330 (cyclomethicone), dimethicone (for example having about 15 centistokes or lower viscosity) at 25 ℃, and their mixture.Preferred carrier fluid comprises water, ethanol, volatile siloxane derivant, and their mixture, and the fluid that uses in these mixture can be mutually miscible or immiscible.

Described supporting agent also can comprise the gel media material.This gel media comprises two kinds of necessary components: a kind of lipoid medium material and a kind of cationic surface active agent medium material.The cationic surface active agent material is described in detail above.In following document, gel media has been done general narration, here it all is incorporated herein by reference: Barry, " the self-bodying effect of blended emulsifier sodium lauryl sulphate/hexadecanol ", 28J.of Colloid and Interface Science82-91 (1968); Barry etc., " the self-bodying effect of the pure blended emulsifier of alkyl trimethyl ammonium bromide/cetearyl alcohol (Cetostearyl): season chain length influence ", 35J.of Colloid and Inter face Science689-708(1971); And Barry etc., " rheology that contains the pure system of Cetomacrogol000-cetearyl alcohol (Cetostearyl), the effect of I. self-bodying ", 38J.of Colloid and Interfaces Science616-625(1972).Gel media is useful especially for hair rinse composition and Haircare composition example gel conditioner of keeping somewhere and optical brightener.

Also can comprise one or more lipoid medium materials in the supporting agent, described material is water-fast basically, and contains hydrophobic and hydrophilic segment.Lipoid medium material comprises natural or synthetic deutero-acid, acid derivative, alcohol, ester, ether, ketone and amide, its carbon chain lengths be about 12 to about 22, preferred about 16 to about 18 carbon atoms.Aliphatic alcohol and aliphatic (acid) ester are preferred, particularly preferably are aliphatic alcohol.

At Bailey's Industrial Oil and Fat Products, (the third edition, D.Swern compiles, 1979) comprised the described lipoid medium material that can use in the present invention in the disclosed lipoid medium material in, here the document has been incorporated herein by reference.Disclosed aliphatic alcohol has comprised and can be used for of the present inventionly in following document, here they all is incorporated herein by reference: authorized the U.S. patent 3,155,591 of Hilfer on November 3rd, 1964; The U.S. patent 4,165,369 that on August 21st, 1979 was authorized people such as Watanabe; The U.S. patent 4,269,824 that on May 26th, 1981 was authorized people such as Villamarin; Be disclosed in the british patent specification (British Specification) 1,532,585 on November 15th, 1978; " influence of cetearyl alcohol in the cosmetic emulsions " of FuKushima etc., 98 Cosmetics﹠amp; Toiletries 89-112(1983).Authorized on the 12nd JIUYUE in 1976 that disclosed aliphatic (acid) ester has comprised (document being incorporated herein by reference) that can use in the present invention here in people's such as Kaufman the U.S. patent 3,341,465.If be included in the compositions of the present invention, the choosing of fine quality of lipoid dielectric object accounts for about 0.1% to about 10.0% of compositions; The choosing of fine quality of cationic surface active agent dielectric object accounts for about 0.05% to about 5.0% of compositions.

Preferred lipoid is an ester, for example Palmic acid palmityl ester and glyceryl monostearate.Hexadecanol and octadecanol are preferred alcohol.Particularly preferred lipoid medium material is made up of the mixture of hexadecanol and octadecanol, wherein contains to have an appointment 55% to about 65%(mixture weight meter) hexadecanol.

The preferred supporting agent that uses in compositions of the present invention, particularly hair rinse composition comprises the hydroxyethyl-cellulose material that carries out hydrophobically modified and the compositions of thickening agent (for example locust bean gum), special surfactant, quaternary ammonium compound (for example two Adeps Bovis seu Bubalis (ditallow) dimethyl ammonium chloride) and/or chelating agent (for example EDTA).These media are described in detail in following patent: the U.S. patent 5,106,609 that on April 21st, 1992 was authorized people such as Bolich; The U.S. patent 5,100,658 that on March 31st, 1992 was authorized people such as Bolich; The U.S. patent 5,104,646 that on April 14th, 1992 was authorized people such as Bolich; The U.S. patent 5,100,657 that on March 31st, 1992 was authorized people such as Ansher-Jackson; Here every piece of document all is incorporated herein by reference.

Suspending agent also can be used as that the supporting agent component suspends that polysiloxane fluid/spreading agent hair brightener and/or other can not be miscible or extraordinary component (undissolvable antistatic cationic surface active agent in compositions for example, and anti-dandruff activating agent (for example Zinc Pyrithione (Zinc Pyridinethione)), etc.Suspending agent is a particular importance in dumpable liquid formulation, for example shampoo.

The example of the suspending agent that can use in compositions of the present invention comprises the mixture of any long acyl derivant material or these materials; for example long acyl derivant, long-chain amine oxide and their mixture, wherein this class suspending agent exists with crystalline form in compositions.These suspending agents are described in to be authorized in the U.S. patent 4,741,855 of Grote and Russell on May 3rd, 1988, was introduced into as a reference here.Comprising having about 16 glycol esters to the fatty acid of about 22 carbon atoms.Preferably glycol stearate comprises list and distearate, but particularly contains the distearate that is lower than about 7% monostearate.Find that spendable other suspending agent is to have about 16 to about 22 carbon atoms, preferred about 16 Marlamids to about 18 carbon atoms.Preferred alkanolamide is stearic acid monoethanolamide, Stearic acid diethanolamine salt, stearic acid list isopropanol amide and stearic acid monoethanolamide stearate.Other long acyl derivant comprises the long-chain ester (for example stearmide DEA distearate, stearmide MEA stearate) of long-chain ester (for example stearic stearolactone, Palmic acid cetyl ester, etc.), glyceride (for example tristerin) and the long-chain alkanolamide of long-chain fatty acid.

Other suspending agent that is suitable for is alkyl (C again ₁₆-C ₂₂) dimethyl amine oxide stearyl dimethyl amine oxide for example.If contain amine oxide or long acyl derivant in the compositions, then also can provide the suspension function, if just do not needed additional suspending agent when these materials exist with the following minimum flow that provides at least by these surfactants as surfactant.

Operable other long acyl derivant comprises N, N-dialkyl (dihydrocarbyl) amino benzoic Acid and soluble-salt thereof (for example Na and K salt), the particularly N of this compounds of group, N-two (hydrogenation) C ₁₆, C ₁₈With Adeps Bovis seu Bubali acylamino-benzoic acids, they commercial can (Northfield, Illinois USA) obtain by Stepan Company.

Long acyl derivant material typical content in dumpable liquid formulation when being used as suspending agent is about 0.1% to about 5.0%, preferred about 0.5% to about 3.0%.Suspending agent is used for making the polysiloxanes material to suspend and can gives the sense of product Margarita.The mixture of suspending agent also is suitable in compositions of the present invention.

Operable another kind of type suspending agent is HANSHENGJIAO (Xanthan gum).The compositions of using HANSHENGJIAO to make the suspending agent of polysiloxanes hair conditioning component is described in authorized in the U.S. patent 4,788,006 of Bolich and Williams on November 29th, 1988, and the document is incorporated herein by reference here.HANSHENGJIAO is a kind of biosynthetic colloidal substance, it commercial be available.It is that a kind of molecular weight surpasses 100 ten thousand heteropolysaccharide.It is considered to contain D-glucose, D-mannose and D-glucuronic acid, and the mol ratio between this three is 2.8: 2.0: 2.0.The acetyl group part acyl groupization of this glycocalix 4.7%.These knowledge and other can be referring to Whistler, Roy L.Editor Industrial Gums-Polysaccharides and Their Derivatives New York:Academic Press, 1973.Kelco, Merck ﹠amp; Co., Inc. branch company sells HANSHENGJIAO with KeltrolR.This colloid is when being used as the suspending agent of polysiloxanes hair conditioning component, and its typical content in dumpable liquid formulation is to account for about 0.3% to about 3%, preferred about 0.4% to about 1.2% of the present composition.

The U.S. patent 4 that on November 3rd, 1987 was authorized people such as Oh; 704; disclose in 272 the suspending agent of long acyl derivant and HANSHENGJIAO combination as the polysiloxanes hair conditioner, the document is incorporated herein by reference here, and also can use equally in compositions of the present invention.When being used as when bringing main means like gel viscosity to compositions, to compare with dumpable, liquid formulation, the gel ingredients has the suspending agent of higher concentration.In this based composition, the typical content of suspending agent is about 1 to about 5%.Also can use other material to come to bring like gel viscosity, for example gellant (as hydroxyethyl-cellulose), thickening agent, viscosity modifier etc. in addition to compositions.Also can use the mixture of these materials.

Can use Haircare composition of the present invention and comprise that also for example nourishing agent, foam silk drench (mousses), gel and hair spray.Nourishing agent, gel and non--aerosol spray hair jelly use the solvent as water or alcohol, and the foam silk drenches (mousses) and aerosol class hair spray has also used propellant in addition, as three chloro fluomethanes, dichloro-difluoro acute pyogenic infection of nails alkane, Difluoroethane, dimethyl ether, propane, normal butane or iso-butane.Low viscous nourishing agent or hair spray product also can use emulsifying agent.The example of suitable emulsifier comprises nonionic, cationic, anionic surfactant or their mixture.If used such emulsifying agent, preferably its content in compositions is about 0.01% to about 7.5%.The content of propellant can be adjusted to required value, but generally be the foam silk drench (mousses) compositions about 3% to about 30%, be about 15% to about 50% of aerosol class hair spray compositions.

The hair spray container that is suitable for is that prior art is known, comprising general, non-aerosol pump or aerosol apparatus i.e. " nebulizer ", gaseous solvents container or have the jar of propellant as mentioned above and use compressed air to make the pump formula aerosol container of propellant.Pump formula aerosol container is disclosed in the following document: authorized the U.S. patent 4 of Olofsson on March 7th, 1978,077, authorized the U.S. patent 4 of Terstege on July 25th, 441 and 1989,850,577, these two pieces of documents all are incorporated herein by reference here, also have Gosselin, Lund, Sojka and the Lefebvre U.S. application number No.07/839 in application on February 21st, 1992,648, " packing that comprises the consumer products of the sprayer device that utilizes the major diameter bubble ".Use compressed-air actuated pump formula aerosol class hair spray also can obtain from the market at present, by the trade (brand) name VIDAL SASSOON AIRSPRAY of The Procte﹠Gamble Company with them ^RHair spray is sold.

Optional components

Compositions of the present invention can be mixed with various types of products on a large scale, comprises that the foam silk drenches (mousses), hair jelly, washing liquid, nourishing agent, spray, shampoo and conditioner.Preparing the annexing ingredient that these products require except that supporting agent or need changes along with the type of product, the technical staff in hair products field can select by customary mode, for example shampoo also will contain detergent surfactant, and its various on a large scale types are known.Can not contain the surfactant of polysiloxanes comprising anionic, nonionic, both sexes and amphoteric ion type as the example of the surfactant of detergent surfactant as mentioned above.Except that the polysiloxane fluid of high index, hair conditioner can contain other hair conditioner, low refractive index polysiloxane fluid for example, those that the degree that as described herein but aryl replaces is lower, for example dimethicone, cationic surface active agent and cation type polymer, organic oil and wax such as hydrocarbon ils and fatty acid ester and alcohol.

The specific category of operable low refractive index (be that refractive index is lower than 1.46, generally be lower than approximately 1.44, be preferably about 1.38 to about 1.42) polysiloxane fluid is a silicone gums." silicone gums " is meant that 25 ℃ of viscosity be 1,000,000CP or higher polysiloxane fluid.Preferred this viscosity is 1,000,000 to about 100,000 at 25 ℃, 000CP.Especially preferred polydimethylsiloxane glue.The general consumption of low refractive index polysiloxanes conditioner be composition weight about 0.01% to about 10%, preferred about 0.1% to about 5%, more preferably from about 0.5% to about 5%, most preferably from about 1% to about 4%.

The compositions decapacitation that the present invention is contained high index and spreading agent provides outside the hair conditioning benefit, also finds low refractive index silicone gums and the hair conditioning effect that combines even can provide excellence under the situation that does not contain spreading agent of high index polysiloxane fluid and the improvement that acts on unexpected light.Low refractive index silicone gums and high index polysiloxane fluid use by the disclosed content in front.At this one side low refractive index glue of the present invention and the fluidic weight ratio of high index is about 1: 100 to about 100: 1, preferred about 1: 10 to about 10: 1, and more preferably from about 1: 5 to about 5: 1.

The cation type polymer that is suitable for comprises vinyl monomer and the monomeric copolymer of water solublity interval dose that for example has cationic amine or quaternary ammonium functional group, and described interval dose monomer is acrylamide, Methacrylamide, alkyl and dialkyl group acrylamide, alkyl and dialkyl methyl acrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone and vinyl pyrrolidone for example.The monomer that alkyl and dialkyl group replace preferably has C ₁-C ₇Alkyl, more preferably C ₁-C ₃Alkyl.Other interleaving agent monomer that is suitable for comprises vinyl acetate, vinyl alcohol (being prepared by the polyvinyl acetate hydrolysis), maleic anhydride, propylene glycol and ethylene glycol.Other cationic polymer comprises cation-modified polysaccharide, as the cellulose of ammonium cation modification.The cationic surface active agent that is suitable for is narration in the above totally, and especially preferred is two (C ₁₂-C ₁₈, C particularly ₁₆-C ₁₈) alkyl and alkenyl, dimethyl ammonium (particularly chloride salt).

Hair fixing (hair setting) compositions for example hair spray, the pouring of foam silk, gel and hair rinse agent can to contain film forming polymer be adhesion polymer, this is that prior art is known.

The example of adhesion polymer comprises the copolymer and the polyvinyl alcohol (PVA) of copolymer, PVP and the vinyl acetate (VA) of polyvinyl pyrrolidone (PVP), particularly poly N-vinyl pyrrolidone, PVP and methyl methacrylate.

The example of adhesion polymer also comprises the copolymer of VA and .beta.-methylacrylic acid, the copolymer of methyl vinyl ether and Malaysia half ester (for example ethyl maleate and maleic acid butyl ester), hydroxypropyl cellulose, hydroxypropyl melon ear (tree) glue, poly styrene sulfonate, acrylic acid polymer is the polymer and the copolymer of acrylic acid and methacrylic acid for example, acrylic acid and/or methacrylic acid and acrylamide and/or vinylpyrrolidone copolymers and terpolymer be the terpolymer of vinyl pyrrolidone/methyl methacrylate/methacrylic acid for example, the terpolymer of vinyl pyrrolidone/ethyl methacrylate/methacrylic acid, tert-butyl group acrylamide/ethyl acrylate/acrylic acid terpolymer, terpolymer with VA/ .beta.-methylacrylic acid/vinyl neodecanoate.

Other example that keeps the anionic polymer of hair is the vinyl esters vinyl neodecanoate for example of the representative examples of saturated aliphatic monocarboxylic acid of .beta.-methylacrylic acid and α-side chain; With the copolymer of methyl vinyl ether and maleic anhydride (for example mol ratio is 1: 1), wherein this analog copolymer 50% is contained the radical of saturated aliphatic alcohol of 1 to 4 carbon atom as ethanol or the esterification of butanols institute; With contain acrylic or methacrylic acid as the acrylic copolymer that contains the anionic group part and terpolymer for example with the copolymer of butyl acrylate, ethyl methacrylate etc.

Hair keeps polymer also to comprise amphiphilic polymers.An operable class amphiphilic polymers is the acrylic resin that has cation and carboxyl.The example comprises octyl group and the acrylamide/acrylic acid/terpolymer/acrylic acid/betanin methacrylate copolymer of metering system acid butyl amino-ethyl ester and the copolymer of octyl acrylamide/acrylate.

Also have polysiloxane-grafted cohesiveness copolymer also can use, for example wherein said is to contain the monomer of polysiloxanes and the monomeric copolymer that does not contain polysiloxanes, make the mean molecule quantity of described sticker at least about 20,000, and contain have an appointment 1% to about 50%(weight) contain the monomer of polysiloxanes.

Most preferred polymer comprises an organic main chain, especially carbon backbone chain polyvinyl main chain for example, but also preferred grafting polydimethylsiloxane macromole (macromer) on this main chain, that described macromolecular mean molecule quantity is at least is about 500, be preferably about 1000 to about 100,000, more preferably about 2,000 to about 50,000, most preferably is about 5,000 to about 20,000.Here organic main chain of indication comprise by polymerisable, that ethylene insatiable hunger key is arranged monomer institute deutero-those.These comprise vinyl monomer and other condensation monomer (for example, polymerizable generates those of polyamide and polyester) and open loop monomer (for example ethyl oxazoline and caprolactone).

The preferred polymerisable example that contains the monomer (C monomer) of polysiloxanes can be represented by following general formula: X(Y) nSi(R) _3-mZm

Wherein X is the vinyl that can carry out copolymerization with A and B monomer; Y is a divalent linker; R is hydrogen, hydroxyl, low alkyl group (C for example ₁-C ₄), aryl, alkaryl, alkoxyl or alkyl amino; Z is that mean molecule quantity is at least about 500 monovalence siloxane polymer part, and it is nonreactive basically under the condition of copolyreaction, and as above-mentioned dangling on the vinyl polymerization main chain; N is 0 or 1; M is 1 to 3 integer.

The example of spendable polymer and their preparation method are described in detail the U.S. patent 4 of authorizing Mazurek on the 15th in JIUYUE in 1987, the U.S. patent 4,728 that on March 1st, 693,935 and 1988 was authorized people such as Clemens, in 571, these two pieces of documents all are incorporated herein by reference here.

The polymer that is suitable for also is disclosed in: people such as Hayama apply for 0408311A on January 11st, 1991 with EPO ₂Disclosed EPO application 90307528.1, the U.S. patent 5 that on October 29th, 1991 was authorized people such as Suzuki, authorized people's such as Bolich U.S.5 on April 21st, 061,481,1992,106, the U.S. patent 5,100 that on March 31st, 609,1992 was authorized people such as Bolich, 658, authorized the U.S. patent 5,100,657 of Ansher-Jackson etc. on March 31st, 1992, the U.S. patent 5 that on April 14th, 1992 was authorized people such as Bolich, 104,646, and people such as Bolich is in the U.S. application number No.08/104 of application on August 10th, 1993, in 232, all these documents all are incorporated herein by reference here.Preferred these polymer are the copolymers that contain tert-butyl acrylate and/or metering system tert-butyl acrylate and vinyl monomer, and described vinyl monomer has the polydimethylsiloxane macromole, and covalency is continuous with it.

Compositions of the present invention can contain make these compositionss make up or aesthetic feeling on easier acceptance or provide the additional various suitable optional components of using benefit to them.The optional components that this class is general is known for those skilled in the art, and for example Margarita is felt auxiliary agent, as diglycol stearate; Antiseptic is as benzyl alcohol, methyl butex, propylparaben and miaow ureine; Thickening agent and viscosity modifier are as diglycollic amide (for example PEG3 Laurel diglycollic amide), Cortex cocois radicis single ethanol amide, guar gum, methylcellulose, starch and the starch derivatives of long-chain fatty acid; Aliphatic alcohol is as Cetearyl alcohol; Sodium chloride; Sodium sulfate; Polyvinyl alcohol; Ethanol; The PH regulator is as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt, in general, as potassium acetate and sodium chloride; Coloring agent, as any FD﹠C or D﹠C dyestuff, hair oxidation (bleaching) agent is as hydrogen peroxide, perborate and persulfate; The hair Reducing agent is as the sulfo-glycolate; Spice; Chelating agen is as disodiumedetate; Polymeric plasticizer, for example glycerol, adipic acid diisobutyl ester, butyl stearate and propylene glycol.These optional components general consumption separately is about 0.01% to about 10.0%, preferred about 0.05% to about 5.0% of a compositions.

The PH of the present composition is generally about 3 to about 9, preferred about 4 to about 8.

As to all compositionss, the performance that the present composition should not contain compositions has dysgenic component.

Can use general preparation and hybrid technology to prepare Haircare composition of the present invention.The example for preparing the method for all kinds cosmetic composition also will more specifically be narrated in following embodiment.

Using method

Haircare composition of the present invention uses so that the conditioning of the present invention and the benefit of adding lustre to be provided according to general mode.This class using method depends on the type of the compositions that is adopted, but the product that generally comprises effective dose is administered on the hair, it can be rinsed (as under the situation of shampoo and some conditioner products) or makes it to remain on (as under the situation of hair spray, the pouring of foam silk, gel, lotion and nourishing agent product) on the hair from hair or skin then." effective dose " is meant is enough to provide the hair required amount of performance of adding lustre to.Preferably, before the dry hair hair rinse, the pouring of foam silk and gel products are being administered on the wet or moist hair.After these compositionss are administered on the hair, make hair dry and according to the common mode cutting ﹠ styling of user.Hair spray is typically at hair drying and after finishing hair style and is applied on the dry hair.The pouring of foam silk, nourishing agent and lotion are typically on dry or wet hair and use, and this depends on the concrete application according to the determined face of general occupation mode, skin or the eye of these product types.

Experiment

Following program is used for determining the gloss meter specular reflectivity.

Under 155 ℃ of stirring conditions, 10.0g gelatin (175 blooms (bloom)) is dissolved in the dual reverse osmosis of 83.0gDRO() prepare collagen solution in the water.Then, the 0.05g propyl parabene is dissolved in this gelatin solution.Then, add 4.5g1MNaOH, add the mixture of 3.0g Ceraphyl GA-D(10-15% Oleum Glycines and 85-90% maleation (maleated) Oleum Glycines subsequently, by VanDykInc, Belleville, NJ, USA sells) stable to form, the emulsion of white.Then, 1.2g lactic acid is stirred in this emulsion, after this this paper is called A solution.

Prepare a kind of 3.0%(weight) solution of formaldehyde in water, B solution, it and the A solution container of independently packing into respectively.

The ceramic tile that has prepared the size of about 7.3cm * 7.3cm, it has the glazing surface of black, and average peak height (" roughness ") is that the 5.0-7.0 micron (can be used Rodenstock RM 600-2D/3-D Measuring Station(Rodenstock Meterology, Munich, W. Germany) measure), and on the upper surface of described ceramic tile, be coated with collagen.There is the gloss meter specular reflectivity of the ceramic tile of collagenic coating to should be 8.0-12.0%.

Use gloss meter such as the measurement of BYK-Gardner " low-light " gloss meter that the specular reflectivity of the ceramic tile of collagenic coating is arranged.According to the described measurement of carrying out specular reflectivity with 60 ℃ angle of incidence of ASTM method D523.The specular reflectivity this paper of Ce Lianging is referred to as " gloss meter specular reflectivity " according to the method.Ceramic tile can prepare as described below.Syringe A charges into the A solution of 3.0cc.Syringe B charges into the B solution of 0.2cc.The content of syringe B is come on the upper surface of ceramic tile.The content of syringe A comes on the B of ceramic tile upper surface solution.Described solution mixed for 5 seconds and uses the upper surface uniform distribution of spatula at ceramic tile.After mixing for 30 seconds, be that 1.0 inches beckets are placed on the upper surface of ceramic tile with internal diameter.Made collagem membrane dry 8 hours.Remove becket.There is the roughness of the ceramic tile surface of collagenic coating to should be 3.0 to 5.0 microns.

By the mixture of top described preparation polysiloxanes and spreading agent, concentration is 1.00% in compatible diluent, and the weight ratio of described polysiloxane fluid and described spreading agent is corresponding to the analog value in the compositions.Use syringe that the mixture of 0.05cc is deposited on the ceramic tile surface of collagenic coating by the center of area that ring surrounds.Make this mixture drying.Measure the gloss meter specular reflectivity.

Embodiment

Following embodiment further specifies preferred implementation within the scope of the present invention.The embodiment that provides is illustrative purposes, can not think limitation of the invention, because can also carry out various changes to the present invention under the condition that does not depart from its essence and scope.

Premixing embodiment 1-6

Below be the various examples that can be used for polysiloxane fluid of the present invention/spreading agent mixture.This mixture can be directly used in treatment of hair, perhaps more preferably, and can be as the component of the various Haircare compositions that contain other cosmetic or medicine activity component, supporting agent component or other component.

Component (weight %) EXAMPLE Example embodiment

1????????2????????3

Pentapheneyl trimethyl trisiloxanes (1) 57.00 0.00 50.00

Aminomethyl phenyl diphenyl siloxane copolymer (2) 38.00 0.00 0.00

Diphenyl dimethylsiloxane copolymer (3) 0.00 45.00 0.00

Dimethicone (4) 0.00 50.00 0.00

MQ polyorganosiloxane resin/volatility SILIBIONE OIL 70047 V20 DC-21330 DC21330 5.00 5.00 0.00

Dimethicone is polyol (6) 0.00 0.00 50.00 altogether

Fluoro surfactants (7) 0.00 1.00 0..00

SILIBIONE OIL 70047 V20 DC-21330 DC21330 (8) 0.00 0.00 0.00

Component (weight %) EXAMPLE Example embodiment

4????????5????????6

Pentapheneyl trimethyl trisiloxanes (1) 99.00 15.00 27.00

Aminomethyl phenyl diphenyl siloxane copolymer (2) 0.00 0.00 12.00

Diphenyl dimethylsiloxane copolymer (3) 0.00 0.00 0.00

Dimethicone (4) 0.00 0.00 0.00

MQ polyorganosiloxane resin/volatility SILIBIONE OIL 70047 V20 DC-21330 DC21330 0.00 5.00 5.00

(5)

Dimethicone is polyol (6) 0.00 0.00 0.00 altogether

Fluoro surfactants (7) 1.00 0.00 1.00

SILIBIONE OIL 70047 V20 DC-21330 DC21330 (8) 0.00 80.00 55.00

1.Dow????Corning????705，Dow????Corning

2.PS????162，Huls

3.SF????1265，General????Electric

4.SE????76，General????Electric

5.SS4320, the poly-trimethyl hydrogenation silicyl silicate/decamethylcyclopentaandoxane of General Electric(50%/50%)

6.Dow????Corning????190，Dow????Corning

7.FC-171????Fluorad，3M

8.Dow????Corning????344，Dow????Corning

The described mixture that gives is at room temperature whole components to be mixed to stir 1/2 hour and preparation.

Following Haircare composition example can adopt top any polysiloxane fluid/spreading agent to give mixture embodiment 1-6(this paper back and be referred to as " polysiloxanes gives mixture embodiment ") prepare.

Embodiment I-III

It below is representative hair spray compositions of the present invention.

Component embodiment 3 (weight %)

I????????II????????III

Polysiloxanes premix 4.5 4.5 4.5

Ethanol 79.0 79.0 86.4

Adipic acid diisobutyl ester 0.7----

Potassium hydroxide solution (45% concentration) 1.0 1.0 1.0

Spice 0.2 0.2 0.2

Water ... in right amount to 100%

This product by the polysiloxanes premix is dissolved in ethanol and mix several hours until premix all dissolving prepare.Add plasticizer (in the time can using) then.Add potassium hydroxide then.In the time can using, add water or water/surfactant.Add spice at last.All the interpolation of component is all carried out under stirring condition.This product can be packaged in the general non-aerosol pump formula automiser spray and compressed air pump spraying aerosol container in.

The embodiment IV

Below be that representative hair of the present invention is modified the nourishing agent compositions.

Composition weight %

Polysiloxanes premix 0.70

Spice 0.10

Ethanol is an amount of

Said composition prepares by said components is mixed by general mode.

The embodiment V

It below is representative shampoo Compositions of the present invention.

Composition weight %

Ammonium lauryl sulfate 4.00

Laureth ammonium sulfate 12.00

Ammonium xylene sulfonate 1.50

Diglycol stearate 2.00

Cortex cocois radicis single ethanol amide 2.00

Three (cetyl) ammonio methacrylate 0.50

Hexadecanol 0.42

Octadecanol 0.18

Polysiloxanes premix (seeing embodiment) 1.50

Antiseptic 0.03

Spice 1.20

Distilled water is an amount of

At about 15 ℃ ammonium lauryl sulfate and citric acid be added in the distilled water.This mixture heated to 70 is ℃ to 80 ℃.Add coconut monoethanolamide MEA and diglycol stearate in this.Laureth-3 ammonium sulfate, hexadecanol, octadecanol and polysiloxanes premix are mixed at 70 ℃ to 90 ℃.After distearyl acid diol ester, this mixture is added in the blender of this batch of material.Add antiseptic then.This batch of material mixing was cooled to room temperature (15 ℃ to 25 ℃) in 5 minutes then.Add spice, use general lapping device under high shear to grind this batch mixing compound at least 5 minutes then.

The embodiment VI

It below is representative hair style gel combination of the present invention.

Composition weight %

Polysiloxanes premix 2.00

Carbopol????9401????????0.75

Triethanolamine 1.00

Dye solution 0.05

Spice 0.10

Laureth-23????????0.10

DRO H ₂O is an amount of

1. cross linked polyacrylate is sold by B.F.Goodrich.

This batch mixing compound is by general mode listed component to be mixed and prepared.

The embodiment VII

Below be that representative hair foam silk of the present invention drenches compositions.

Composition weight %

Polysiloxanes premix 3.00

Ethanol 15.00

Coconut amine oxide (Cocamine Oxide) 0.60

Coconut monoethanolamide DEA 0.30

Spice 0.10

Iso-butane 7.00

DRO H ₂O is an amount of

1. dimethicone is total to polyol, is sold by Dow Corning.

The preparation of said composition is to realize by will the whole components except that iso-butane at room temperature admixing until good mixing.Pack in aluminum aerosol can then this batch mixing compound of 95 parts afterwards with addition of a valve, is enclosed within its volume on the position, and pressurization at last charges into 5 parts iso-butane.

Embodiment VIII-X

It below is representative conditioning rinse composition of the present invention.

Component EXAMPLE Example embodiment

VIII????????IX????????X

Hydroxyethyl-cellulose 0.400 0.200 0.000

Cetyl hydroxyethyl cellulose 0.000 0.400 0.500

Crotein????Q????????1.000????????1.000????????1.000

The amino propyl-dimethyl amine 1.000 1.000 1.000 of stearoyl

Two tallow dimethyl ammonium chlorides 0.750 0.750 0.750

Glyceryl monostearate 0.250 0.000 0.000

Isoceteth-20 acetic acid dipropylene glycol ester 0.000 0.250 0.250

Hexadecanol 0.900 1.700 1.700

Octadecanol 0.600 0.000 0.000

Emulsifing wax 0.500 0.000 0.000

Cinnamic acid octyl group methoxyl group ester 0.000 1.000 1.000

Polysiloxanes premix (seeing embodiment) 2.600 2.200 2.200

Trimethyl silyl amo dimethicone (1) 0.000 0.000 0.200

Spice 0.300 0.300 0.300

Citric acid 0.220 0.220 0.220

Antiseptic 0.030 0.030 0.030

Distilled water is an amount of an amount of

1.Dow????Corning????Q2-8820,Dow????Corning

Under 15 ℃ to 40 ℃ temperature, hydroxyethyl-cellulose is added in the distilled water.This mixture carries out good dispersion, is heated to 60 ℃ and be heated to 90 ℃ from this temperature then.Temperature is remained on this scope adds material 2 to 10 in the blender of this batch of material to.Mixture stir about 10 minutes is cooled to about 50 ℃ then.Remaining material adds under this temperature.Use general lapping device under high shear mixture to be ground about 2 minutes, be cooled to room temperature and collection then.In addition, the component of polysiloxanes premix can be in advance without premix superincumbent same phase add simultaneously.

The embodiment XI

Aerosol spray Hairspray compositions of the present invention is by being prepared as follows:

Composition weight %

Polysiloxanes premix 4.00

Water 10.60

Ethanol 63.50

KOH(45% solution) 0.90

Iso-butane 15.00

Difluoroethane 6.00

Whole components except that propellant at room temperature mix, until polymer dissolution.Mixture is inserted in the aerosol can, general aerosol spray pot valve is installed then, this valve vacuum volume is enclosed within on the position.By this valve propellant is charged into then, and aerosol spray jar activator is installed on jar.

Embodiment XII-XV

Hair rinse composition of the present invention is by being prepared as follows:

Component (weight %) EXAMPLE Example EXAMPLE Example

XII????????XIII????????XIV????????XV

Oleyl alcohol 1.0 1.0 1.0 0.2

Salcare ^RSC95 ¹2.2 0.8 0.8 0.8

Citric acid trioctylphosphine dodecyl ester 1.0---

Polydimethylsiloxane ²3.5 4.2 4.2 4.2

Organic siliconresin ³0.2 0.2 0.2 0.2

Pentapheneyl trimethyl trisiloxanes ⁴0.4 0.4 0.4 0.4

DL panthenol 0.04 0.04 0.04 0.04

Pantoyl ether 0.3 0.3 0.3 0.3

Spice 0.3 0.3 0.3 0.3

Kathon ^TMCG ⁵0.03 0.03 0.03 0.03

Carboxylic propyl group guar gum 0.5---

Hydroxyethyl-cellulose--0.2 0.2

Hexadecanol-1.2 1.8 1.8

Octadecanol-0.8 1.2 1.2

Two tallow dimethyl ammonium chlorides 1.0 0.8 0.8 0.8

The amino propyl-dimethyl amine-1.0 0.8 0.8 of stearoyl

Glyceryl monostearate-0.2 0.8 0.8

Citric acid-0.2 0.2 0.2

Water is an amount of

1.Polyquaternium 37(and) mineral oil (and with) PPG-1 Trideceth6, by Allied Colloids Ltd, (Norfolk, VA USA) sell.

2.D ₅SILIBIONE OIL 70047 V20 DC-21330 DC21330 and SKTV-M 85%/15%(weight) mixture (weight average molecular weight is about 400,000 to about 600,000).

3. poly-trimethyl hydrogenation silicyl esters of silicon acis is with 50%(weight in decamethylcyclopentaandoxane) solution add General Electric Silicone Products, SS4320.

4.Dow????Corning????705，Dow????Corning????Corp（Midland，MI，USA）。

Methyl chloride for isothiazoline (with) the methyl isothiazoline, by Rohm﹠Haas Co., (Philadelphia, PA, USA) antiseptic of Chu Shouing.

For each embodiment, in one jar, prepare the polysiloxanes premix by mixing polydimethylsiloxane, MQ resin and pentapheneyl trimethicone.For the embodiment XII, heat water to about 80 ℃.In water, add hydroxypropyl guar gum and quaternary ammonium and mixing with it subsequently.Mixture is cooled to about 28 ℃.Then by the following order that provides with following component in turn good mixing go in this mixture, each interpolation all will be stirred: 1.0%(is benchmark with the gross weight) Salcare ^TMSC95, citric acid trioctylphosphine dodecyl ester, oleyl alcohol, pantoyl ether, panthenol, polysiloxanes premix, spice, Kathon ^TMCG and remaining Salcare ^TMSC95.

For embodiment XI V and X V, water is heated to about 25 ℃, and under agitation adds hydroxyethyl-cellulose.Water is heated to about 80 ℃, adds following component in turn, between each the interpolation, stir: quaternary ammonium salt, hexadecanol, octadecanol, stearoyl aminopropyl dimethyl amine and glyceryl monostearate.This mixture is cooled to about 49 ℃, adds following component in turn; Stir between each the interpolation: polysiloxanes premix, citric acid, panthenol, pantoyl ether, spice, Kathon ^TMCG, Salcare ^TMSC95 and oleyl alcohol.Be cooled to 25 ℃.

For embodiment X III, heat water to about 80 ℃, under agitation quaternary ammonium salt is mixed with it.Then add following component in turn, between each the interpolation, stir: hexadecanol, octadecanol, oleyl alcohol, stearoyl aminopropyl dimethyl amine and glyceryl monostearate.This mixture is cooled to about 49 ℃.Then add following component, stir between each the interpolation: polysiloxanes premix, citric acid, panthenol, pantoyl ether, spice, Kathon ^TMCG and Salcare ^TMSC95.Be cooled to 25 ℃.

Claims

1, a kind of Haircare composition that enhanced shine can be provided to hair, described compositions is characterised in that it comprises:

(a) refractive index is at least about 1.46 non-volatile polysiloxane fluid;

(b) be used for the non-volatile spreading agent of described polysiloxane fluid, it mixes mutually with described polysiloxane fluid;

(c) be suitable for being applied to the supporting agent of hair;

Wherein said compositions contains the described spreading agent of q.s, so that the surface tension of polysiloxane fluid reduces at least about 5%, and the total amount of described polysiloxane fluid and described spreading agent is at least about 0.1% of composition weight.

2, Haircare composition as claimed in claim 1, the refractive index of wherein said non-volatile polysiloxane fluid is at least about 1.48.

3, it is about 1.50 that Haircare composition as claimed in claim 2, the refractive index of wherein said non-volatile polysiloxanes body are at least, and described surface tension reduces about 15% at least.

4, it is about 1.52 that Haircare composition as claimed in claim 3, the refractive index of wherein said non-volatile polysiloxane fluid are at least, and described surface tension reduces about 20% at least.

5, Haircare composition as claimed in claim 4, the refractive index of wherein said non-volatile polysiloxane fluid is at least about 1.55.

6, Haircare composition as claimed in claim 5, wherein said surface tension reduces about 25% at least.

7, Haircare composition as claimed in claim 1, the surface tension of the mixture of wherein said polysiloxane fluid and spreading agent are about 30 dyne/cm ²Or it is littler.

8, Haircare composition as claimed in claim 3, the surface tension of the mixture of wherein said polysiloxane fluid and spreading agent are about 28 dyne/cm ²Or it is littler.

9, Haircare composition as claimed in claim 5, the surface tension of the mixture of wherein said polysiloxane fluid and spreading agent are about 25 dyne/cm ²Or it is littler.

10, Haircare composition as claimed in claim 1, wherein said spreading agent are organic siliconresin, a kind of surfactant or its mixture.

11, Haircare composition as claimed in claim 10, wherein said spreading agent is an organic siliconresin.

12, Haircare composition as claimed in claim 11, wherein said organic siliconresin are the MQ resins.

13, Haircare composition as claimed in claim 1, the aryl replacement degree of wherein said non-volatile polysiloxane fluid is at least about 20%.

14, Haircare composition as claimed in claim 13, the aryl replacement degree of wherein said non-volatile polysiloxane fluid is at least about 35%.

15, Haircare composition as claimed in claim 14, the aryl replacement degree of wherein said non-volatile polysiloxane fluid is at least about 50%.

16, Haircare composition as claimed in claim 13, the degree that contains phenyl substituent of wherein said polysiloxane fluid is at least about 50%.

17, a kind of method that provides light to act on to hair is included in the compositions of using claim 1 on the hair.

18, method as claimed in claim 17, wherein said compositions are used the back and are rinsed on hair.

19, a kind of Haircare composition that provides light to act on to hair, described compositions comprises:

(1) a kind of mixture, it contains:

(a) refractive index is at least about 1.46 non-volatile polysiloxane fluid;

(b) be used for the non-volatile spreading agent of described polysiloxanes, it mixes mutually with described polysiloxane fluid, and described thus spreading agent reduces the surface tension of described polysiloxane fluid; With

(ⅱ) be suitable for the supporting agent on hair, used;

The described spreading agent that wherein said compositions contains q.s increases the gloss meter specular reflectivity of described mixture, increases at least about △ 1.0% with respect to described polysiloxane fluid.

20, Haircare composition as claimed in claim 19, the gloss meter specular reflectivity of wherein said mixture is than the high at least about △ 2.0% of gloss meter specular reflectivity of described polysiloxane fluid.

21, Haircare composition as claimed in claim 20, the gloss meter specular reflectivity of wherein said mixture is than the high at least about △ 5.0% of gloss meter specular reflectivity of described polysiloxane fluid.

22, Haircare composition as claimed in claim 21, the gloss meter specular reflectivity of wherein said mixture is than the high at least about △ 5.0% of gloss meter specular reflectivity of described polysiloxane fluid.

23, Haircare composition as claimed in claim 22, the gloss meter specular reflectivity of wherein said mixture is than the high at least about △ 7.5% of gloss meter specular reflectivity of described polysiloxane fluid.

24, Haircare composition as claimed in claim 23, the gloss meter specular reflectivity of wherein said mixture is than the high at least about △ 10.0% of specular reflectivity of described polysiloxane fluid.

25, a kind of Haircare composition as claimed in claim 19, wherein said refractive index is at least about 1.48.

26, a kind of Haircare composition as claimed in claim 20, wherein said refractive index is at least about 1.48.

27, a kind of Haircare composition as claimed in claim 26, wherein said refractive index is at least about 1.50.

28, a kind of Haircare composition as claimed in claim 27, wherein said refractive index is at least about 1.52.

29, a kind of Haircare composition as claimed in claim 19, wherein said spreading agent is an organic siliconresin, a kind of surfactant or their mixture.

30, a kind of Haircare composition as claimed in claim 29, wherein said spreading agent is an organic siliconresin.

31, a kind of Haircare composition as claimed in claim 30, wherein said organic siliconresin is the MQ resin.

32, a kind of Haircare composition as claimed in claim 19, the aryl replacement degree of wherein said non-volatile polysiloxane fluid is at least about 20%.

33, a kind of Haircare composition as claimed in claim 32, the aryl replacement degree of wherein said non-volatile polysiloxane fluid is at least about 35%.

34, a kind of Haircare composition as claimed in claim 33, the aryl replacement degree of wherein said non-volatile polysiloxane fluid is at least about 50%.

35, a kind of Haircare composition as claimed in claim 34, the degree that contains phenyl substituent of wherein said polysiloxane fluid is at least about 50%.

36, a kind of method that provides light to act on to hair is included in and uses the described compositions of claim 19 on the hair.

37, a kind of method as claimed in claim 36, wherein said compositions are used the back and are rinsed on hair.

38, a kind of Haircare composition that provides light to act on to hair, described compositions comprises:

(1) a kind of mixture, it contains:

(a) refractive index is at least about 1.46 non-volatile polysiloxane fluid;

(b) a kind of nonvolatile spreading agent, it be selected from by organic siliconresin, surfactant, and composition thereof the group of forming, wherein said spreading agent reduces the surface tension of described polysiloxane fluid;

(ⅱ) a kind of supporting agent that is suitable on hair, using;

Wherein the weight ratio at polysiloxane fluid described in the described compositions and described spreading agent is about 1000: 1 to 1: 10.

39, a kind of Haircare composition as claimed in claim 38, wherein said spreading agent is an organic siliconresin.

40, a kind of Haircare composition as claimed in claim 39, wherein the described weight ratio of polysiloxane fluid and described spreading agent is about 100: 1 to about 2: 1.

41, Haircare composition as claimed in claim 40, the refractive index of wherein said polysiloxane fluid are about 1.48.

42, Haircare composition as claimed in claim 41, the refractive index of wherein said polysiloxane fluid is at least about 1.52.

43, Haircare composition as claimed in claim 42, the refractive index of wherein said polysiloxane fluid is at least about 1.55.

44, Haircare composition as claimed in claim 43, wherein the described weight ratio of polysiloxane fluid and spreading agent is about 50: 1 to about 2: 1.

45, a kind of Haircare composition that provides light to act on to hair, described compositions comprises:

(ⅰ) a kind of mixture, it contains:

(a) refractive index is at least about 1.46 non-volatile polysiloxane fluid;

(b) be used for the non-volatile spreading agent of described polysiloxanes, it mixes mutually with described polysiloxane fluid, and described thus spreading agent reduces the surface tension of described polysiloxane fluid;

(c) refractive index is lower than 1.46 non-volatile polyorganosiloxane resin, and wherein (a) is about 1: 10 to about 10: 1 with (c) weight ratio;

(ⅱ) a kind of supporting agent that is suitable on hair, using;

Wherein said mixture contains the described spreading agent of q.s to increase the gloss meter specular reflectivity of described mixture, increases about △ 1.0% with respect to described polysiloxane fluid at least.

46, a kind of Haircare composition that provides light to act on to hair, described compositions contains:

(ⅰ) a kind of mixture, contain:

(a) refractive index is at least about 1.46 non-volatile polysiloxane fluid;

(b) refractive index is lower than 1.46 non-volatile silicone gums, and wherein (a) and weight ratio (b) are about 1: 5 to about 5: 1;

(ⅱ) a kind of supporting agent that is suitable on hair, using.