JPS63270542A - 水素化分解用添加剤および重質炭化水素油の水素化分解法 - Google Patents
水素化分解用添加剤および重質炭化水素油の水素化分解法Info
- Publication number
- JPS63270542A JPS63270542A JP62312172A JP31217287A JPS63270542A JP S63270542 A JPS63270542 A JP S63270542A JP 62312172 A JP62312172 A JP 62312172A JP 31217287 A JP31217287 A JP 31217287A JP S63270542 A JPS63270542 A JP S63270542A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- hydrocracking
- additive
- molybdenum
- hydrocarbon oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 68
- 230000000996 additive effect Effects 0.000 title claims abstract description 67
- 238000004517 catalytic hydrocracking Methods 0.000 title claims abstract description 67
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims description 82
- 239000000843 powder Substances 0.000 claims abstract description 69
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 50
- 239000001257 hydrogen Substances 0.000 claims abstract description 49
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000000725 suspension Substances 0.000 claims abstract description 42
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000002994 raw material Substances 0.000 claims abstract description 28
- -1 transition metal salts Chemical class 0.000 claims abstract description 28
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 22
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- 239000011733 molybdenum Substances 0.000 claims abstract description 19
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 16
- 238000002156 mixing Methods 0.000 claims abstract description 15
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 150000001875 compounds Chemical class 0.000 claims description 20
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- 238000004064 recycling Methods 0.000 claims description 7
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
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- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 7
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- 239000012071 phase Substances 0.000 description 6
- 238000006722 reduction reaction Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 239000003638 chemical reducing agent Substances 0.000 description 5
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- 229910052785 arsenic Inorganic materials 0.000 description 4
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 4
- 239000002956 ash Substances 0.000 description 4
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- 229910010272 inorganic material Inorganic materials 0.000 description 3
- 239000011147 inorganic material Substances 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
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- 238000010008 shearing Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 229910000619 316 stainless steel Inorganic materials 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000010724 circulating oil Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
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- 239000013256 coordination polymer Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
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- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229940093920 gynecological arsenic compound Drugs 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
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- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 1
- BZYUMXXOAYSFOW-UHFFFAOYSA-N 2,3-dimethylthiophene Chemical compound CC=1C=CSC=1C BZYUMXXOAYSFOW-UHFFFAOYSA-N 0.000 description 1
- XQQBUAPQHNYYRS-UHFFFAOYSA-N 2-methylthiophene Chemical compound CC1=CC=CS1 XQQBUAPQHNYYRS-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- 101100495326 Dictyostelium discoideum cdk7 gene Proteins 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 241000234435 Lilium Species 0.000 description 1
- QENGPZGAWFQWCZ-UHFFFAOYSA-N Methylthiophene Natural products CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 1
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- 208000003028 Stuttering Diseases 0.000 description 1
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- ZSOFVYSMDYXSOA-UHFFFAOYSA-N [As].[Mo] Chemical compound [As].[Mo] ZSOFVYSMDYXSOA-UHFFFAOYSA-N 0.000 description 1
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- 229910052783 alkali metal Inorganic materials 0.000 description 1
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- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
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- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 1
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- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical class O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
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- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
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- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 229910002001 transition metal nitrate Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 150000003658 tungsten compounds Chemical class 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62312172A JPS63270542A (ja) | 1986-12-12 | 1987-12-11 | 水素化分解用添加剤および重質炭化水素油の水素化分解法 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61-294980 | 1986-12-12 | ||
| JP29498086 | 1986-12-12 | ||
| JP62312172A JPS63270542A (ja) | 1986-12-12 | 1987-12-11 | 水素化分解用添加剤および重質炭化水素油の水素化分解法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63270542A true JPS63270542A (ja) | 1988-11-08 |
| JPH0471577B2 JPH0471577B2 (zh) | 1992-11-16 |
Family
ID=26560073
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62312172A Granted JPS63270542A (ja) | 1986-12-12 | 1987-12-11 | 水素化分解用添加剤および重質炭化水素油の水素化分解法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63270542A (zh) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0641551A (ja) * | 1992-04-09 | 1994-02-15 | Stone & Webster Eng Corp | 重質残油の前処理及び水素化変換方法 |
| US5507964A (en) * | 1991-08-29 | 1996-04-16 | Henkel Kommanditgesellschaft Auf Aktien | Use of isopalmitic acid esters as lubricants for two-stroke engines |
| JP2011111620A (ja) * | 2009-11-24 | 2011-06-09 | Intevep Sa | 重質油、超重質油及び残留油の水素化分解法 |
| JP2011148969A (ja) * | 2010-01-21 | 2011-08-04 | Intevep Sa | 水素化分解法用添加物、その製造法及び使用法 |
| JP2016501946A (ja) * | 2012-12-14 | 2016-01-21 | シェブロン ユー．エス．エー． インコーポレイテッド | 水素化処理共触媒組成物及び水素化処理ユニット中へのそれらの導入方法 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3083992B1 (fr) * | 2018-07-23 | 2020-07-24 | Ifp Energies Now | Catalyseur comalaxe issu de solutions a base d'heteropolyanions, son procede de preparation et son utilisation en hydroconversion de charges hydrocarbonees lourdes |
-
1987
- 1987-12-11 JP JP62312172A patent/JPS63270542A/ja active Granted
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5507964A (en) * | 1991-08-29 | 1996-04-16 | Henkel Kommanditgesellschaft Auf Aktien | Use of isopalmitic acid esters as lubricants for two-stroke engines |
| JPH0641551A (ja) * | 1992-04-09 | 1994-02-15 | Stone & Webster Eng Corp | 重質残油の前処理及び水素化変換方法 |
| JP2011111620A (ja) * | 2009-11-24 | 2011-06-09 | Intevep Sa | 重質油、超重質油及び残留油の水素化分解法 |
| US8679322B2 (en) | 2009-11-24 | 2014-03-25 | Intevep, S.A. | Hydroconversion process for heavy and extra heavy oils and residuals |
| JP2014122365A (ja) * | 2009-11-24 | 2014-07-03 | Intevep Sa | 重質油、超重質油及び残留油の水素化分解法 |
| JP2011148969A (ja) * | 2010-01-21 | 2011-08-04 | Intevep Sa | 水素化分解法用添加物、その製造法及び使用法 |
| US8835351B2 (en) | 2010-01-21 | 2014-09-16 | Intevep, S.A. | Additive for hydroconversion process and method for making and using same |
| US9168506B2 (en) | 2010-01-21 | 2015-10-27 | Intevep, S.A. | Additive for hydroconversion process and method for making and using same |
| JP2016501946A (ja) * | 2012-12-14 | 2016-01-21 | シェブロン ユー．エス．エー． インコーポレイテッド | 水素化処理共触媒組成物及び水素化処理ユニット中へのそれらの導入方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0471577B2 (zh) | 1992-11-16 |
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