JPH0471577B2 - - Google Patents
Info
- Publication number
- JPH0471577B2 JPH0471577B2 JP62312172A JP31217287A JPH0471577B2 JP H0471577 B2 JPH0471577 B2 JP H0471577B2 JP 62312172 A JP62312172 A JP 62312172A JP 31217287 A JP31217287 A JP 31217287A JP H0471577 B2 JPH0471577 B2 JP H0471577B2
- Authority
- JP
- Japan
- Prior art keywords
- oil
- hydrocracking
- molybdenum
- additive
- carbonaceous material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 claims description 95
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 86
- 239000000654 additive Substances 0.000 claims description 80
- 239000000843 powder Substances 0.000 claims description 76
- 150000002430 hydrocarbons Chemical class 0.000 claims description 68
- 229930195733 hydrocarbon Natural products 0.000 claims description 67
- 230000000996 additive effect Effects 0.000 claims description 64
- 239000004215 Carbon black (E152) Substances 0.000 claims description 63
- 239000003575 carbonaceous material Substances 0.000 claims description 58
- 239000000725 suspension Substances 0.000 claims description 54
- 239000005078 molybdenum compound Substances 0.000 claims description 40
- 150000002752 molybdenum compounds Chemical class 0.000 claims description 40
- 239000011164 primary particle Substances 0.000 claims description 40
- 229910052739 hydrogen Inorganic materials 0.000 claims description 39
- 239000001257 hydrogen Substances 0.000 claims description 38
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 36
- 239000002994 raw material Substances 0.000 claims description 32
- -1 transition metal salts Chemical class 0.000 claims description 32
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 31
- 239000007789 gas Substances 0.000 claims description 29
- 150000001875 compounds Chemical class 0.000 claims description 24
- 229910052750 molybdenum Inorganic materials 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 19
- 239000006229 carbon black Substances 0.000 claims description 19
- 239000011733 molybdenum Substances 0.000 claims description 19
- 229910052723 transition metal Inorganic materials 0.000 claims description 19
- 238000005292 vacuum distillation Methods 0.000 claims description 18
- 229910052717 sulfur Inorganic materials 0.000 claims description 15
- 239000011593 sulfur Substances 0.000 claims description 14
- 150000003464 sulfur compounds Chemical class 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 238000004064 recycling Methods 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000011964 heteropoly acid Substances 0.000 claims description 7
- 238000007327 hydrogenolysis reaction Methods 0.000 claims description 7
- 239000002798 polar solvent Substances 0.000 claims description 6
- 239000012298 atmosphere Substances 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 238000005979 thermal decomposition reaction Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 description 163
- 238000006243 chemical reaction Methods 0.000 description 56
- 239000003054 catalyst Substances 0.000 description 45
- 238000011282 treatment Methods 0.000 description 35
- 239000007864 aqueous solution Substances 0.000 description 33
- 238000004519 manufacturing process Methods 0.000 description 31
- 239000002253 acid Substances 0.000 description 28
- 230000000052 comparative effect Effects 0.000 description 23
- 239000000126 substance Substances 0.000 description 23
- 150000001450 anions Chemical class 0.000 description 21
- 239000007787 solid Substances 0.000 description 21
- 239000000243 solution Substances 0.000 description 18
- 235000019241 carbon black Nutrition 0.000 description 17
- 239000012018 catalyst precursor Substances 0.000 description 17
- 238000004821 distillation Methods 0.000 description 17
- 238000009835 boiling Methods 0.000 description 16
- 230000003197 catalytic effect Effects 0.000 description 16
- 239000002245 particle Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 15
- 239000007788 liquid Substances 0.000 description 14
- 150000007513 acids Chemical class 0.000 description 13
- 239000002904 solvent Substances 0.000 description 13
- 239000010779 crude oil Substances 0.000 description 12
- 239000008187 granular material Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 230000006870 function Effects 0.000 description 11
- 238000006068 polycondensation reaction Methods 0.000 description 11
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 241001168730 Simo Species 0.000 description 9
- 239000000571 coke Substances 0.000 description 9
- 239000000295 fuel oil Substances 0.000 description 9
- 238000005984 hydrogenation reaction Methods 0.000 description 9
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 9
- 238000005112 continuous flow technique Methods 0.000 description 8
- 238000000354 decomposition reaction Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- 239000003208 petroleum Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- 238000002441 X-ray diffraction Methods 0.000 description 7
- 125000004429 atom Chemical group 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000006722 reduction reaction Methods 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 125000005842 heteroatom Chemical group 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 238000004438 BET method Methods 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 239000003638 chemical reducing agent Substances 0.000 description 5
- 230000001747 exhibiting effect Effects 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- 150000003624 transition metals Chemical class 0.000 description 5
- 239000002956 ash Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000006477 desulfuration reaction Methods 0.000 description 4
- 230000023556 desulfurization Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000004939 coking Methods 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 238000009775 high-speed stirring Methods 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- 229910017464 nitrogen compound Inorganic materials 0.000 description 3
- 150000002830 nitrogen compounds Chemical class 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 229910003208 (NH4)6Mo7O24·4H2O Inorganic materials 0.000 description 2
- 229910000619 316 stainless steel Inorganic materials 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000002801 charged material Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 1
- BZYUMXXOAYSFOW-UHFFFAOYSA-N 2,3-dimethylthiophene Chemical compound CC=1C=CSC=1C BZYUMXXOAYSFOW-UHFFFAOYSA-N 0.000 description 1
- XQQBUAPQHNYYRS-UHFFFAOYSA-N 2-methylthiophene Chemical compound CC1=CC=CS1 XQQBUAPQHNYYRS-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- QENGPZGAWFQWCZ-UHFFFAOYSA-N Methylthiophene Natural products CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 1
- 229910003294 NiMo Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 238000001636 atomic emission spectroscopy Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000006231 channel black Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
- 229940005991 chloric acid Drugs 0.000 description 1
- 239000010724 circulating oil Substances 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000001944 continuous distillation Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000004845 hydriding Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- TYQCGQRIZGCHNB-JLAZNSOCSA-N l-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(O)=C(O)C1=O TYQCGQRIZGCHNB-JLAZNSOCSA-N 0.000 description 1
- 239000008206 lipophilic material Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 239000012053 oil suspension Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000002296 pyrolytic carbon Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000011163 secondary particle Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- JDVPQXZIJDEHAN-UHFFFAOYSA-N succinamic acid Chemical compound NC(=O)CCC(O)=O JDVPQXZIJDEHAN-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002641 tar oil Substances 0.000 description 1
- 239000011275 tar sand Substances 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910000299 transition metal carbonate Inorganic materials 0.000 description 1
- 229910002001 transition metal nitrate Inorganic materials 0.000 description 1
- 150000003657 tungsten Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 150000003658 tungsten compounds Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Landscapes
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62312172A JPS63270542A (ja) | 1986-12-12 | 1987-12-11 | 水素化分解用添加剤および重質炭化水素油の水素化分解法 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29498086 | 1986-12-12 | ||
JP61-294980 | 1986-12-12 | ||
JP62312172A JPS63270542A (ja) | 1986-12-12 | 1987-12-11 | 水素化分解用添加剤および重質炭化水素油の水素化分解法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63270542A JPS63270542A (ja) | 1988-11-08 |
JPH0471577B2 true JPH0471577B2 (zh) | 1992-11-16 |
Family
ID=26560073
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62312172A Granted JPS63270542A (ja) | 1986-12-12 | 1987-12-11 | 水素化分解用添加剤および重質炭化水素油の水素化分解法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63270542A (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4128647A1 (de) * | 1991-08-29 | 1993-03-11 | Henkel Kgaa | Verwendung von isopalmitinsaeureestern als schmiermittel fuer zweitaktmotoren |
US5320741A (en) * | 1992-04-09 | 1994-06-14 | Stone & Webster Engineering Corporation | Combination process for the pretreatment and hydroconversion of heavy residual oils |
US8679322B2 (en) * | 2009-11-24 | 2014-03-25 | Intevep, S.A. | Hydroconversion process for heavy and extra heavy oils and residuals |
US9168506B2 (en) | 2010-01-21 | 2015-10-27 | Intevep, S.A. | Additive for hydroconversion process and method for making and using same |
US20140166541A1 (en) * | 2012-12-14 | 2014-06-19 | Julie Chabot | Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units |
-
1987
- 1987-12-11 JP JP62312172A patent/JPS63270542A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS63270542A (ja) | 1988-11-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4863887A (en) | Additive for the hydroconversion of a heavy hydrocarbon oil | |
US5320741A (en) | Combination process for the pretreatment and hydroconversion of heavy residual oils | |
US4770764A (en) | Process for converting heavy hydrocarbon into more valuable product | |
CA1238289A (en) | Heavy oil hydroprocessing | |
JP6097224B2 (ja) | 水素化処理触媒を作製するための方法 | |
US6056935A (en) | Iron sulfide and process for producing the same | |
GB2066842A (en) | Hydrotreating heavy hydrocarbons | |
JP2014510615A5 (zh) | ||
Mochida et al. | Progresses of coal liquefaction catalysts in Japan | |
JPH0611403B2 (ja) | 水素化触媒の製造方法及びそれを用いる水素化変換方法 | |
Duan et al. | Preparing copper catalyst by ultrasound-assisted chemical precipitation method | |
CN103289722B (zh) | 一种费托合成铁基废催化剂再利用方法及一种煤直接液化反应催化剂 | |
US10358608B2 (en) | Process for hydrocracking heavy oil and oil residue | |
Prajapati et al. | Ultrafine reverse micelle catalysts for slurry-phase residue hydrocracking | |
US20170267937A1 (en) | Process for hydrocracking heavy oil and oil residue with a carbonaceouse additive | |
JPH0471577B2 (zh) | ||
JPH02107335A (ja) | 重油コークス操作に由来する石油コークスの存在下での重油の水素化分解 | |
JPS6126836B2 (zh) | ||
Tye et al. | Cold Lake bitumen upgrading using exfoliated mos 2 | |
JPS60120791A (ja) | 重質炭化水素の軽質化方法 | |
CA2221977C (en) | Resid hydroprocessing catalyst and method | |
JP4283988B2 (ja) | 原油の全酸価を低減させるためのプロセス | |
JPH0135035B2 (zh) | ||
JP3502221B2 (ja) | 硫化鉄及びその製造方法 | |
RU2674160C1 (ru) | Способ гидроконверсии остатка атмосферной дистилляции газового конденсата |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
LAPS | Cancellation because of no payment of annual fees |