JPS63262412A - Method for cleaning molten steel - Google Patents

Method for cleaning molten steel

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Publication number
JPS63262412A
JPS63262412A JP9539787A JP9539787A JPS63262412A JP S63262412 A JPS63262412 A JP S63262412A JP 9539787 A JP9539787 A JP 9539787A JP 9539787 A JP9539787 A JP 9539787A JP S63262412 A JPS63262412 A JP S63262412A
Authority
JP
Japan
Prior art keywords
molten steel
molten
slag
steel
molten slag
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9539787A
Other languages
Japanese (ja)
Inventor
Kenichi Sasaki
健一 佐々木
Hiroyuki Aoki
青木 裕幸
Akihiko Kusano
昭彦 草野
Akio Aragai
昭男 新飼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP9539787A priority Critical patent/JPS63262412A/en
Publication of JPS63262412A publication Critical patent/JPS63262412A/en
Pending legal-status Critical Current

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  • Treatment Of Steel In Its Molten State (AREA)

Abstract

PURPOSE:To stably produce high clean steel by adding strong deoxidizer in molten slag on surface of molten steel just after refining, stirring the molten slag by gas to reduce FeO and MnO in the molten slag and then, stirring the molten steel by the gas, to float up and remove the deoxidation product. CONSTITUTION:The strong deoxidizer of Al, Al dross, etc., is added in the molten slag on the molten steel obtd. after desiliconizing, dephosphorizing, desulfurizing and decarbonizing by oxidizing refining to molten iron. Then, the lance for blowing gas is dipped at 0-500mm depth to the molten steel surface and the inert gas of Ar, CO2, N2, etc., in case of need, together with powdery CaO, is blown and the strong reducing agent on the molten slag are sufficiently stirred and reacted, to reduce FeO, MnO, etc., in the molten slag, and T, Fe in the molten slag is made to <=3%, to refine the molten steel. Successively, the lance is dipped at >=1,000mm depth from the molten steel surface and the inert gas is blown and stirred to aggregate and float up the dispersed grain of Al2O3 in non-metallic inclusion as the deoxidation product and collect in the molten slag, and the high clean molten steel is produced.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は溶鋼の清浄化方法に関し、詳しくは溶鋼表向に
浮上し几溶融スラグの改質による脱酸生成物の吸着除去
方法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a method for cleaning molten steel, and more particularly to a method for adsorbing and removing deoxidized products by modifying molten slag that floats on the surface of molten steel.

(従来の技術) 一般に、転炉等でm製された溶鋼は成分調整及び脱酸調
整を実施し、溶鋼中の酸素量を制御している。し力為し
、溶鋼上部に存在する酸化溶融スラグは完全には脱酸さ
れていない九め、脱酸剤添加η島らWj!IA凝固まで
の時間に溶鋼中の酸素との親和力の強い元素(例えばA
/等)と溶鋼上部に存在する酸化溶融スラグ(例えば酸
化Fe−Mn等)とが反応し、脱酸物を生成する。この
結果、鋼中酸素量制御が著しく損なわれると共に、生成
し九脱酸物が鋼の製品品質劣化の原因となっている。
(Prior Art) Generally, molten steel produced in a converter or the like is subjected to composition adjustment and deoxidization adjustment to control the amount of oxygen in the molten steel. However, the oxidized molten slag present at the top of the molten steel is not completely deoxidized. During the time until IA solidification, elements with a strong affinity for oxygen in molten steel (for example, A
/, etc.) and the oxidized molten slag (for example, oxidized Fe-Mn, etc.) present in the upper part of the molten steel to generate a deoxidized product. As a result, the control of the amount of oxygen in the steel is significantly impaired, and the produced nine-deoxidized products are the cause of deterioration in the quality of steel products.

従って1例えば特開昭60−162719号公報に示さ
れるように、取鍋あるいは精錬容器内の1WfI4上に
精錬スラグを形成し、容器底部からAr等の不活性ガス
を、上方よりスラグと溶鋼の近傍に浸漬ランスを浸漬し
て不活性ガスと精錬用フラックスとを吹込み、スラグ−
溶鋼間の反応効率を向上させる方法が提案されている。
Therefore, as shown in JP-A-60-162719, for example, refining slag is formed on 1WfI4 in a ladle or refining vessel, and an inert gas such as Ar is supplied from the bottom of the vessel to the slag and molten steel from above. An immersion lance is immersed nearby and inert gas and refining flux are blown into the slag.
Methods have been proposed to improve the reaction efficiency between molten steel.

しかし、この方法全前記の溶鋼の清浄化に用いても浮上
したスラグと溶鋼全体が反応し、容器内の溶鋼の汚染を
招く。ま7t、溶鋼中の8i、Mn、あるいはTi、B
等の有価元素の酸化消失を生じるとともに、処理時の温
度低下が大きく継続する連鋳工程において、ノズル絞り
による鋳造中断あるいは介在物に起因し九品質欠陥を生
じる等の欠点が有#る。
However, even if this method is used to clean the molten steel, the entire molten steel reacts with the floating slag, resulting in contamination of the molten steel in the container. 7t, 8i, Mn, or Ti, B in molten steel
In addition to oxidation loss of valuable elements such as, there are drawbacks such as quality defects due to interruption of casting due to nozzle throttling or inclusions in the continuous casting process where the temperature during treatment continues to decrease significantly.

(発明が解決しようとする問題点) 本発明は、スラグ改質による溶鋼の清浄化に際し、従来
方法の欠点であるスラグと溶鋼の全体的な攪拌と反応を
抑制し、溶鋼の汚染と有価元素の損失を防止するととも
に、迅速な改質および温度の低下の抑制により連鋳工程
の負荷をも解消する溶鋼の清浄化方法を′提供する。
(Problems to be Solved by the Invention) When cleaning molten steel by slag modification, the present invention suppresses the overall agitation and reaction of slag and molten steel, which are the drawbacks of conventional methods, and prevents contamination of molten steel and valuable elements. To provide a method for cleaning molten steel that prevents the loss of steel and also eliminates the burden of a continuous casting process by rapid reforming and suppressing a drop in temperature.

(問題点を解決する丸めの手段) 本発明は、精錬工程を経て溶融金属容器に出湯された溶
鋼の上面に浮上し九酸化溶融スラグの表面に強膜酸剤を
添加し、ランスを溶鋼瀞面に対し0〜5001111の
浸漬深さにして不活性ガスまたは不活性ガスと生石灰粉
を吹込みスラグ中のT、Peを3係以下とし1次いで該
溶融金属容器の溶鋼表面より1000圏以上の深さ力為
ら不活性ガスを吹込み前工程の脱酸生成物を浮上除去す
ることを特徴とする溶鋼の清浄化方法である。
(Means of rounding to solve the problem) The present invention involves adding a sclerotic acid to the surface of the molten slag that floats to the top of the molten steel poured into a molten metal container after the refining process, and then using a lance to remove the molten steel from the molten steel. Inert gas or inert gas and quicklime powder is blown into the slag to an immersion depth of 0 to 5001111 to reduce T and Pe in the slag to below 3 coefficients.1. This method of cleaning molten steel is characterized by blowing inert gas at a deep depth to float away the deoxidized products from the previous process.

(作用) 前述し丸ように、溶鋼中への脱酸剤添加(溶鋼中酸素量
制御)では1m鋼上部に存在する酸化性溶融スラグによ
って脱酸剤添加後から凝固(鋳造)完了点に鋼中酸素量
制御が著しく損なわれ、且つ生成しt脱酸物が鋼の製品
品質劣化の原因となる。
(Function) As mentioned above, when adding a deoxidizer to molten steel (controlling the amount of oxygen in molten steel), the oxidizing molten slag present at the top of the 1m steel causes the steel to reach the point of completion of solidification (casting) after the addition of the deoxidizer. Control of the amount of oxygen in the atmosphere is significantly impaired, and the deoxidized products that are generated cause deterioration in the quality of steel products.

これを解決する比めには、溶鋼上部の酸化性溶融スラグ
を改質し、溶鋼が脱酸生成物の影響を極力受けないよう
にする必要がある。しかも、溶融金属容器(以下取鍋と
称する)に浮上したスラグを溶鋼との攪拌接触を抑制し
次状態で迅速に改質する必要がある。そして、この浮上
スラグの改質後に溶鋼全体を攪拌し、Fj銅鋼中潜在し
皮膜酸生成物、あるいは耐火物の溶損による酸化物等か
らなる介在物を浮上させて改質スラグに吸着させること
により、従来の方法では得られない溶鋼の清浄化が達成
される。
To solve this problem, it is necessary to modify the oxidizing molten slag above the molten steel so that the molten steel is not affected by deoxidation products as much as possible. Moreover, it is necessary to prevent the slag floating in the molten metal container (hereinafter referred to as a ladle) from coming into contact with the molten steel while rapidly reforming the slag in the next state. After the floating slag is modified, the entire molten steel is stirred, and the inclusions, which are latent in the FJ copper steel and consist of film acid products or oxides caused by melting of the refractory, are brought to the surface and adsorbed to the modified slag. This achieves cleaning of the molten steel that cannot be achieved with conventional methods.

このため本発明は、精錬工程を経由してき文末脱酸ある
いは脱酸処理を施し九溶鋼の上部にある酸化溶融スラブ
の表面へ例えばA/、アルミドロス等の強脱酸剤II−
溶融スラグ中酸化Fe、Mn  を十分還元出来る量だ
け添加する。脱酸剤を酸化溶融スラグの表面に添加し、
これに浅浸漬(0〜500nm)ランスにより不活性ガ
スまたは不活性ガスと生石灰粉の吹込みを行なうことに
より、単に脱酸剤を浸漬吹込みする方法に比し脱酸剤の
飛散ロスを大巾に抑制し、シ〃為も反応は極めて迅速に
行ない得る。
For this reason, the present invention applies deoxidizing treatment or deoxidizing treatment to the surface of the oxidized molten slab located on the upper part of the molten steel through the refining process and applies a strong deoxidizing agent such as A/, aluminum dross, etc. to the surface of the oxidized molten slab.
Oxidized Fe and Mn are added in the molten slag in an amount sufficient to reduce them sufficiently. Adding a deoxidizing agent to the surface of the oxidized molten slag,
By injecting inert gas or inert gas and quicklime powder into this using a shallow immersion (0 to 500 nm) lance, the scattering loss of the deoxidizer is greatly reduced compared to the method of simply immersing and injecting the deoxidizer. Even if the reaction is suppressed to a large extent, the reaction can be carried out extremely quickly.

この浅浸漬ランスによる不活性ガスまtは不活性ガスと
生石灰粉の吹込みは、取鍋内にランスを田溶鋼表面より
0〜500鵡に浸漬させ、不活性ガス(Ar、 Co2
= N2等)ま九は不活性ガスと生石灰粉による強制攪
拌を実施し、溶融スラグと強膜酸剤との反応を促進させ
る。当工程で強制攪拌をさせるランスの浸漬位置及び不
活性ガス流量は。
The injection of inert gas and quicklime powder using this shallowly immersed lance is carried out by immersing the lance in the ladle at a depth of 0 to 500 m from the surface of the molten steel, and injecting inert gas (Ar, Co2) into the ladle.
= N2, etc.) Maku implements forced stirring using inert gas and quicklime powder to promote the reaction between the molten slag and the sclera acid agent. What is the immersion position of the lance used for forced stirring in this process and the flow rate of the inert gas?

溶融スラグと強膜酸剤との反応を促進させ、かつ極力溶
鋼への影響を避ける量とするのが重要である。これは、
溶融スラグと強膜酸剤との反応によって生成する脱酸生
成物が溶鋼中へ侵入するのを回避し1強制攪拌時の溶鋼
湯面変動による溶鋼の大気酸化を極力防止する九めに重
要である。
It is important to select an amount that promotes the reaction between the molten slag and the sclero-acid and avoids as much influence on the molten steel as possible. this is,
Ninth, it is important to avoid the intrusion of deoxidizing products produced by the reaction between molten slag and sclerotic acid into the molten steel, and to prevent as much as possible atmospheric oxidation of the molten steel due to fluctuations in the molten steel level during forced stirring. be.

脱酸生成物の侵入深さは@1図に示すようにランス浸漬
深さ500目η為ら急激に深くなる。一方。
As shown in Figure @1, the penetration depth of the deoxidized product becomes steeper from the lance immersion depth η of 500 mm. on the other hand.

溶鋼表面(浸漬深さ中O)より浅くなると攪拌が不十分
となり、スラグ改質が行なわれない。この几め浸漬深さ
LはO・〜500m11とすることが必要である。この
脱酸剤の添加と攪拌によってスラグは迅速還元されてス
ラグ中のToFeを3%以下。
If it becomes shallower than the molten steel surface (immersion depth O), stirring will be insufficient and slag modification will not be performed. This reduced immersion depth L needs to be 0.~500 m11. By adding this deoxidizing agent and stirring, the slag is quickly reduced to reduce the ToFe content in the slag to 3% or less.

好ましくti14以下とする。このT e Feが高い
と十分な浮上介在物の吸着ができず、逆に溶鋼汚染を招
く。
Preferably the ti is 14 or less. If this T e Fe is high, floating inclusions cannot be sufficiently adsorbed, and conversely, molten steel contamination occurs.

次に、取鍋の溶鋼表面よりt o o oIDI以上浸
漬した位置から不活性ガス(Ar、 002. N2等
)を溶鋼表面が改質し次溶融スラグ表面に露出しないガ
ス流量:50〜3001/−吹込んで攪拌し、溶鋼中へ
侵入し次脱酸生成物を浮上させる。最終のガス吹き込み
深さがt o o omより浅くなると、第1図に示す
ように溶鋼の全体攪拌が抑制され改質スラブの介在物吸
着と介在物の撹拌浮上の相乗効果が極めて小さくなる。
Next, the molten steel surface is modified with an inert gas (Ar, 002, N2, etc.) from a position immersed in the molten steel surface of the ladle at least t0o IDI, and then gas flow rate: 50 to 3001 / - Inject and stir to penetrate into the molten steel and float the deoxidized products. When the final gas injection depth becomes shallower than t o o om, as shown in FIG. 1, the overall stirring of the molten steel is suppressed, and the synergistic effect of adsorption of inclusions in the reforming slab and stirring and flotation of the inclusions becomes extremely small.

このように1本発明は初期においては溶鋼の汚染及び温
度ロス等を防止してスラグの迅速還元改質を行ない、継
続する溶鋼の全体攪拌による介在物浮上と改質スラグの
吸着により極めて効果的に溶鋼の清浄化を達成する。
In this way, the present invention prevents contamination of molten steel and temperature loss, etc. in the initial stage, performs rapid reduction reforming of slag, and is extremely effective due to the floating of inclusions and adsorption of reformed slag by continuous stirring of the entire molten steel. Achieve cleaning of molten steel.

(実施例) 転炉で精錬された溶5i/4を取締に出湯する際に。(Example) When tapping the molten 5i/4 refined in the converter for inspection.

所定の脱酸剤と合金鉄を施〃口し1表1に示すようなA
 / −K鋼を得次。この脱酸・成分調整後の溶鋼上部
にある酸化溶融スラグにA/系会合金鉄添加し−た。こ
の後金属パイプに耐火物被徨したうガスを溶鋼表面下5
00關に浸漬させ、不活性ガス(Ar)+OaO粉を吹
き込み、溶融スラグと添加AI!系合会合金鉄強制撹拌
させ、酸化溶融スラグを改質し友。その結果を従来法と
比較して第2図に示す。この後、取鍋底部に装備したポ
ーラスプラグを介して溶鋼表面よりtoooaw以上の
深さη為らArノ々ブリンダして溶鋼中に侵入し皮膜酸
生成物の除去を実f山シた。
Apply the specified deoxidizing agent and ferroalloy to obtain A as shown in Table 1.
/ - K steel is obtained next. A/type associated metal iron was added to the oxidized molten slag above the molten steel after deoxidation and composition adjustment. After this, the gas that had settled on the refractory was poured into the metal pipe under the surface of the molten steel.
It is immersed in 0.00°C, inert gas (Ar) + OaO powder is blown into it, and the molten slag and added AI! It is useful for modifying oxidized molten slag by forced stirring of alloyed iron alloys. The results are shown in FIG. 2 in comparison with the conventional method. Thereafter, an Ar nozzle was used to enter the molten steel from a depth η of more than 100 ft from the surface of the molten steel through a porous plug installed at the bottom of the ladle, thereby effectively removing the coating acid product.

この結果、製品介在物(処理後〜鋳造完了迄°の酸比溶
融スラグと溶鋼中の酸素親和力の強い元素との2次反応
による脱酸生成物、当品橿ではAJ?203)指数は、
第3図に示すように従来法より極めて向上した。まπ、
温厩低下も従来の約1/2であった。
As a result, the index of product inclusions (deoxidation products resulting from the secondary reaction between the acid ratio molten slag and elements with strong oxygen affinity in molten steel from after treatment to the completion of casting; for this product, AJ?203) is
As shown in Fig. 3, this was significantly improved over the conventional method. Mapi,
The temperature drop was also about 1/2 that of the conventional method.

なお、スラグ改質に際し浸漬ランスからArガスのみを
吹込んだ場合についても行なつ几が、殆んどAr+Oa
O粉と同等の結果で、bつto特にOaO粉は低塩基度
スラグの場合有効であった。
In addition, even when only Ar gas is blown from the immersion lance during slag reforming, most of the gas is Ar+Oa.
The results were similar to those of OaO powder, and OaO powder was particularly effective in the case of low basicity slag.

(発明の効果) 以上述べた如く1本発明にエリ浴鋼上部に存在する酸化
溶融スラグを容易に且つ効率良く改質でき、スラグ改質
の安定化が図られ%溶鋼の汚染を十分に抑制できるとと
もに溶鋼の有価元素の損失をも防止できる。ま几、処理
過程における温度低下が極めて小さく、連鋳工程の負荷
を解消し、高清浄鋼の溶製が簡皐な方法で可能となる。
(Effects of the Invention) As described above, according to the present invention, the oxidized molten slag present in the upper part of the bath steel can be easily and efficiently modified, the slag modification is stabilized, and the contamination of the molten steel is sufficiently suppressed. At the same time, loss of valuable elements in the molten steel can be prevented. The temperature drop during the treatment process is extremely small, eliminating the burden of the continuous casting process and making it possible to produce high-clean steel in a simple manner.

【図面の簡単な説明】[Brief explanation of drawings]

第1図はランス浸漬深さと脱酸生成物の溶鋼への侵入f
Rことの関係を示す図。 @2図は本法と従来法に於ける溶鋼上部に存在する溶融
スラグ中T−1’e量の差異を示す図。 @3図は本法と従来法に於ける製品介在物指数の差異を
示す図である。 代理人 弁理士 秋 沢 政 光 他1名 第1図 (mm) う〕ズ漫j責3尿さくmWL”) 第2図 才5図 伝   米 津
Figure 1 shows the lance immersion depth and the penetration of deoxidation products into molten steel.
A diagram showing the relationship between R. Figure @2 is a diagram showing the difference in the amount of T-1'e in the molten slag present in the upper part of the molten steel between this method and the conventional method. Figure @3 is a diagram showing the difference in product inclusion index between this method and the conventional method. Agent: Patent attorney Masamitsu Akizawa and 1 other person Figure 1 (mm) Uzumanji 3 Urine Collection (mWL) Figure 2 Sai 5 Biography Yonezu

Claims (1)

【特許請求の範囲】[Claims] (1)精錬工程を経て溶融金属容器に出湯された溶鋼の
上面に浮上した酸化溶融スラグの表面に強脱酸剤を添加
し、ランスを溶鋼浴面に対し0〜500mmの浸漬深さ
にして不活性ガスまたは不活性ガスと生石灰粉を吹込み
スラグ中のT、Feを3%以下とし、次いで該溶融金属
容器の溶鋼表面より1000mm以上の深さから不活性
ガスを吹込み前工程の脱酸生成物を浮上除去することを
特徴とする溶鋼の清浄化方法。
(1) A strong deoxidizing agent is added to the surface of the oxidized molten slag that floats to the top of the molten steel that has been tapped into the molten metal container after the refining process, and the lance is immersed to a depth of 0 to 500 mm into the molten steel bath surface. Inert gas or inert gas and quicklime powder is injected to reduce T and Fe in the slag to 3% or less, and then inert gas is injected from a depth of 1000 mm or more from the molten steel surface of the molten metal container to remove the previous process. A method for cleaning molten steel characterized by floating and removing acid products.
JP9539787A 1987-04-20 1987-04-20 Method for cleaning molten steel Pending JPS63262412A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9539787A JPS63262412A (en) 1987-04-20 1987-04-20 Method for cleaning molten steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9539787A JPS63262412A (en) 1987-04-20 1987-04-20 Method for cleaning molten steel

Publications (1)

Publication Number Publication Date
JPS63262412A true JPS63262412A (en) 1988-10-28

Family

ID=14136525

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9539787A Pending JPS63262412A (en) 1987-04-20 1987-04-20 Method for cleaning molten steel

Country Status (1)

Country Link
JP (1) JPS63262412A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01294817A (en) * 1988-05-23 1989-11-28 Kawasaki Steel Corp Method for cleaning molten metal
JPH02250915A (en) * 1989-03-23 1990-10-08 Kawasaki Steel Corp Method for producing high clean dead soft steel
JPH0356614A (en) * 1989-07-26 1991-03-12 Kawasaki Steel Corp Production of low-oxygen dead-soft carbon steel
JPH0472009A (en) * 1990-07-10 1992-03-06 Kawasaki Steel Corp Method for refining high cleanliness steel
JPH0488117A (en) * 1990-07-31 1992-03-23 Kawasaki Steel Corp Method for refining dead soft carbon steel

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01294817A (en) * 1988-05-23 1989-11-28 Kawasaki Steel Corp Method for cleaning molten metal
JPH02250915A (en) * 1989-03-23 1990-10-08 Kawasaki Steel Corp Method for producing high clean dead soft steel
JPH0356614A (en) * 1989-07-26 1991-03-12 Kawasaki Steel Corp Production of low-oxygen dead-soft carbon steel
JPH0472009A (en) * 1990-07-10 1992-03-06 Kawasaki Steel Corp Method for refining high cleanliness steel
JPH0488117A (en) * 1990-07-31 1992-03-23 Kawasaki Steel Corp Method for refining dead soft carbon steel

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