JPS63222005A - 粗製液体硫黄の精製方法 - Google Patents
粗製液体硫黄の精製方法Info
- Publication number
- JPS63222005A JPS63222005A JP62051997A JP5199787A JPS63222005A JP S63222005 A JPS63222005 A JP S63222005A JP 62051997 A JP62051997 A JP 62051997A JP 5199787 A JP5199787 A JP 5199787A JP S63222005 A JPS63222005 A JP S63222005A
- Authority
- JP
- Japan
- Prior art keywords
- liquid sulfur
- storage tank
- contact
- catalyst
- sweep gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 102
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 101
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 100
- 239000011593 sulfur Substances 0.000 title claims abstract description 100
- 238000000746 purification Methods 0.000 title description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 55
- 239000007789 gas Substances 0.000 claims abstract description 53
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims abstract description 53
- 238000003860 storage Methods 0.000 claims abstract description 45
- 239000011949 solid catalyst Substances 0.000 claims abstract description 18
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003054 catalyst Substances 0.000 claims description 50
- 238000000034 method Methods 0.000 claims description 20
- 230000003197 catalytic effect Effects 0.000 abstract description 7
- 238000007599 discharging Methods 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000000354 decomposition reaction Methods 0.000 description 9
- 238000010926 purge Methods 0.000 description 5
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229910017464 nitrogen compound Inorganic materials 0.000 description 3
- 150000002830 nitrogen compounds Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910003296 Ni-Mo Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000011197 physicochemical method Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/027—Recovery of sulfur from material containing elemental sulfur, e.g. luxmasses or sulfur containing ores; Purification of the recovered sulfur
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/0232—Purification, e.g. degassing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00477—Controlling the temperature by thermal insulation means
- B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Treating Waste Gases (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62051997A JPS63222005A (ja) | 1987-03-09 | 1987-03-09 | 粗製液体硫黄の精製方法 |
| GB8805128A GB2203732B (en) | 1987-03-09 | 1988-03-03 | An apparatus for refining crude liquid sulfur. |
| KR1019880002402A KR950011826B1 (ko) | 1987-03-09 | 1988-03-08 | 미정제 액체유황의 정제장치 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62051997A JPS63222005A (ja) | 1987-03-09 | 1987-03-09 | 粗製液体硫黄の精製方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63222005A true JPS63222005A (ja) | 1988-09-14 |
| JPH0522642B2 JPH0522642B2 (enExample) | 1993-03-30 |
Family
ID=12902487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62051997A Granted JPS63222005A (ja) | 1987-03-09 | 1987-03-09 | 粗製液体硫黄の精製方法 |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS63222005A (enExample) |
| KR (1) | KR950011826B1 (enExample) |
| GB (1) | GB2203732B (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5911819A (en) * | 1995-03-16 | 1999-06-15 | Mbt Holding Ag | Cement spraying admixture |
| JP2013522162A (ja) * | 2010-03-22 | 2013-06-13 | ティッセンクルップ ウーデ ゲゼルシャフト ミット ベシュレンクテル ハフツング | Clausプラントにおいて液体硫黄を凝縮、分離および貯留する装置および方法 |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5080695A (en) * | 1990-10-12 | 1992-01-14 | Marathon Oil Company | Method of removing hydrogen sulfide from liquid sulfur |
| NL1003085C2 (nl) * | 1995-09-15 | 1997-03-20 | Stork Comprimo Bv | Werkwijze en inrichting voor het ontgassen van zwavel. |
| NL1001216C2 (nl) * | 1995-09-15 | 1997-03-20 | Stork Comprimo Bv | Werkwijze voor het ontgassen van zwavel. |
| FR2846959B1 (fr) * | 2002-11-08 | 2006-06-30 | Air Liquide | Procede d'inertage du soufre liquide |
| US8361432B2 (en) * | 2010-12-08 | 2013-01-29 | Fluor Enterprises, Inc. | Reactor, a retained catalyst structure, and a method for improving decomposition of polysulfides and removal of hydrogen sulfide in liquid sulfur |
| RU2014101632A (ru) * | 2011-06-21 | 2015-07-27 | Якобс Недерланд Б.В. | Каталитическая дегазация серы |
| EP2607304B1 (de) * | 2011-12-23 | 2015-03-25 | Air Liquide Global E&C Solutions Germany GmbH | Verfahren und Vorrichtung zur Entgasung von flüssigem Schwefel |
| US9757677B2 (en) * | 2013-06-21 | 2017-09-12 | Phillips 66 Company | Apparatus for in-situ production of low dissolved hydrogen sulfide, degassed, sulfur from Claus sulfur recovery |
| US10059588B2 (en) | 2015-10-05 | 2018-08-28 | Fluor Technologies Corporation | Systems and methods for degassing of sulfur |
| US11713246B2 (en) | 2019-03-15 | 2023-08-01 | Fluor Technologies Corporation | Liquid sulfur degassing |
| CN111983134B (zh) * | 2019-05-24 | 2022-08-05 | 中国石油天然气股份有限公司 | 液体硫磺中硫化氢和多硫化氢含量的测定方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5319990A (en) * | 1976-08-02 | 1978-02-23 | Standard Oil Co | Method of eliminating hydrogen sulfide and poly hydrogen sulfide from liquidefied sulfur |
| JPS61256904A (ja) * | 1985-05-09 | 1986-11-14 | Jgc Corp | 液体硫黄の精製方法 |
-
1987
- 1987-03-09 JP JP62051997A patent/JPS63222005A/ja active Granted
-
1988
- 1988-03-03 GB GB8805128A patent/GB2203732B/en not_active Expired - Fee Related
- 1988-03-08 KR KR1019880002402A patent/KR950011826B1/ko not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5319990A (en) * | 1976-08-02 | 1978-02-23 | Standard Oil Co | Method of eliminating hydrogen sulfide and poly hydrogen sulfide from liquidefied sulfur |
| JPS61256904A (ja) * | 1985-05-09 | 1986-11-14 | Jgc Corp | 液体硫黄の精製方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5911819A (en) * | 1995-03-16 | 1999-06-15 | Mbt Holding Ag | Cement spraying admixture |
| JP2013522162A (ja) * | 2010-03-22 | 2013-06-13 | ティッセンクルップ ウーデ ゲゼルシャフト ミット ベシュレンクテル ハフツング | Clausプラントにおいて液体硫黄を凝縮、分離および貯留する装置および方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR950011826B1 (ko) | 1995-10-11 |
| KR880011011A (ko) | 1988-10-25 |
| GB2203732A (en) | 1988-10-26 |
| GB2203732B (en) | 1991-04-03 |
| GB8805128D0 (en) | 1988-03-30 |
| JPH0522642B2 (enExample) | 1993-03-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |