JPS63107815A - 光触媒活性を有するニオビウム化合物 - Google Patents
光触媒活性を有するニオビウム化合物Info
- Publication number
- JPS63107815A JPS63107815A JP61254361A JP25436186A JPS63107815A JP S63107815 A JPS63107815 A JP S63107815A JP 61254361 A JP61254361 A JP 61254361A JP 25436186 A JP25436186 A JP 25436186A JP S63107815 A JPS63107815 A JP S63107815A
- Authority
- JP
- Japan
- Prior art keywords
- sulfurizing
- oxide
- treatment
- composite oxide
- compd
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 9
- 150000002822 niobium compounds Chemical class 0.000 title claims description 9
- 239000002131 composite material Substances 0.000 claims abstract description 7
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 239000010955 niobium Substances 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 3
- 238000005987 sulfurization reaction Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 abstract description 11
- 239000000203 mixture Substances 0.000 abstract description 6
- 239000002245 particle Substances 0.000 abstract description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 230000001590 oxidative effect Effects 0.000 abstract description 4
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 abstract description 3
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 abstract description 2
- 238000001354 calcination Methods 0.000 abstract 2
- 230000005855 radiation Effects 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 239000000126 substance Substances 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 230000031700 light absorption Effects 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 150000003568 thioethers Chemical class 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 238000007539 photo-oxidation reaction Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910000484 niobium oxide Inorganic materials 0.000 description 2
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229910019704 Nb2O Inorganic materials 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229910052977 alkali metal sulfide Inorganic materials 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 238000007540 photo-reduction reaction Methods 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- -1 sulfide ions Chemical class 0.000 description 1
Landscapes
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61254361A JPS63107815A (ja) | 1986-10-25 | 1986-10-25 | 光触媒活性を有するニオビウム化合物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61254361A JPS63107815A (ja) | 1986-10-25 | 1986-10-25 | 光触媒活性を有するニオビウム化合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63107815A true JPS63107815A (ja) | 1988-05-12 |
JPH0234891B2 JPH0234891B2 (enrdf_load_stackoverflow) | 1990-08-07 |
Family
ID=17263919
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61254361A Granted JPS63107815A (ja) | 1986-10-25 | 1986-10-25 | 光触媒活性を有するニオビウム化合物 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63107815A (enrdf_load_stackoverflow) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5643436A (en) * | 1992-09-22 | 1997-07-01 | Takenaka Corporation | Architectural material using metal oxide exhibiting photocatalytic activity |
AU679868B2 (en) * | 1994-08-30 | 1997-07-10 | Korea Research Institute Of Chemical Technology | Photocatalyst, method for preparing the same, and production of hydrogen using the same |
EP1127617A1 (en) | 2000-02-22 | 2001-08-29 | Korea Research Institute Of Chemical Technology | CdZnMS photocatalyst including cations for water decomposition and preparation thereof and method for producing hydrogen by use of the same |
CN1080587C (zh) * | 1995-09-18 | 2002-03-13 | 韩国化学技术研究所 | 新的光催化剂、其制备以及用该催化剂制备氢的方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021149678A1 (ja) | 2020-01-21 | 2021-07-29 | 三菱ケミカル株式会社 | 表示機器、車両内外装部材、照明灯用ランプ、表示用看板及び車両 |
-
1986
- 1986-10-25 JP JP61254361A patent/JPS63107815A/ja active Granted
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5643436A (en) * | 1992-09-22 | 1997-07-01 | Takenaka Corporation | Architectural material using metal oxide exhibiting photocatalytic activity |
AU679868B2 (en) * | 1994-08-30 | 1997-07-10 | Korea Research Institute Of Chemical Technology | Photocatalyst, method for preparing the same, and production of hydrogen using the same |
US5865960A (en) * | 1994-08-30 | 1999-02-02 | Korea Research Institute Of Chemical Technology | Photocatalyst, method for preparing the same, and production of hydrogen using the same |
CN1080587C (zh) * | 1995-09-18 | 2002-03-13 | 韩国化学技术研究所 | 新的光催化剂、其制备以及用该催化剂制备氢的方法 |
EP1127617A1 (en) | 2000-02-22 | 2001-08-29 | Korea Research Institute Of Chemical Technology | CdZnMS photocatalyst including cations for water decomposition and preparation thereof and method for producing hydrogen by use of the same |
Also Published As
Publication number | Publication date |
---|---|
JPH0234891B2 (enrdf_load_stackoverflow) | 1990-08-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EXPY | Cancellation because of completion of term |