JPS626592B2 - - Google Patents
Info
- Publication number
- JPS626592B2 JPS626592B2 JP53050718A JP5071878A JPS626592B2 JP S626592 B2 JPS626592 B2 JP S626592B2 JP 53050718 A JP53050718 A JP 53050718A JP 5071878 A JP5071878 A JP 5071878A JP S626592 B2 JPS626592 B2 JP S626592B2
- Authority
- JP
- Japan
- Prior art keywords
- dye
- formula
- mixture
- parts
- dyes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000975 dye Substances 0.000 claims description 135
- 239000000203 mixture Substances 0.000 claims description 96
- 238000000034 method Methods 0.000 claims description 49
- 229920000728 polyester Polymers 0.000 claims description 42
- 229920002678 cellulose Polymers 0.000 claims description 41
- 239000001913 cellulose Substances 0.000 claims description 41
- 125000003118 aryl group Chemical group 0.000 claims description 24
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims description 20
- 239000001257 hydrogen Substances 0.000 claims description 19
- 238000005859 coupling reaction Methods 0.000 claims description 18
- 230000008878 coupling Effects 0.000 claims description 16
- 238000010168 coupling process Methods 0.000 claims description 16
- 239000002657 fibrous material Substances 0.000 claims description 15
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 claims description 15
- 238000004043 dyeing Methods 0.000 claims description 14
- 239000000985 reactive dye Substances 0.000 claims description 14
- 239000000835 fiber Substances 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 11
- 229910052794 bromium Inorganic materials 0.000 claims description 10
- 239000000460 chlorine Substances 0.000 claims description 10
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 229910052801 chlorine Inorganic materials 0.000 claims description 9
- 125000000623 heterocyclic group Chemical group 0.000 claims description 9
- 238000007639 printing Methods 0.000 claims description 9
- 150000001412 amines Chemical class 0.000 claims description 8
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 8
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 150000001989 diazonium salts Chemical class 0.000 claims description 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 6
- 239000003086 colorant Substances 0.000 claims description 6
- 238000006193 diazotization reaction Methods 0.000 claims description 6
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000001246 bromo group Chemical group Br* 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 125000000714 pyrimidinyl group Chemical group 0.000 claims description 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 claims description 2
- 239000000982 direct dye Substances 0.000 claims description 2
- 239000000988 sulfur dye Substances 0.000 claims description 2
- 239000000984 vat dye Substances 0.000 claims description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 238000006467 substitution reaction Methods 0.000 claims 1
- -1 diimides Substances 0.000 description 27
- 239000006185 dispersion Substances 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 239000000463 material Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 238000011282 treatment Methods 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 150000002431 hydrogen Chemical class 0.000 description 8
- 238000005406 washing Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000986 disperse dye Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 5
- 238000007447 staining method Methods 0.000 description 5
- KWMDHCLJYMVBNS-UHFFFAOYSA-N 2-bromo-4,6-dinitroaniline Chemical compound NC1=C(Br)C=C([N+]([O-])=O)C=C1[N+]([O-])=O KWMDHCLJYMVBNS-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 235000010288 sodium nitrite Nutrition 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000000732 arylene group Chemical group 0.000 description 2
- 239000000987 azo dye Substances 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 2
- 229940008406 diethyl sulfate Drugs 0.000 description 2
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 125000001841 imino group Chemical group [H]N=* 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 1
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- GWEHVDNNLFDJLR-UHFFFAOYSA-N 1,3-diphenylurea Chemical compound C=1C=CC=CC=1NC(=O)NC1=CC=CC=C1 GWEHVDNNLFDJLR-UHFFFAOYSA-N 0.000 description 1
- LUYAMNYBNTVQJG-UHFFFAOYSA-N 1-chloro-2-(2-chloroethylsulfonyl)ethane Chemical compound ClCCS(=O)(=O)CCCl LUYAMNYBNTVQJG-UHFFFAOYSA-N 0.000 description 1
- HTSVYUUXJSMGQC-UHFFFAOYSA-N 2-chloro-1,3,5-triazine Chemical group ClC1=NC=NC=N1 HTSVYUUXJSMGQC-UHFFFAOYSA-N 0.000 description 1
- GRXZPSDBHFWQRM-UHFFFAOYSA-N 2-chloroethanesulfonamide Chemical compound NS(=O)(=O)CCCl GRXZPSDBHFWQRM-UHFFFAOYSA-N 0.000 description 1
- XCSGHNKDXGYELG-UHFFFAOYSA-N 2-phenoxyethoxybenzene Chemical compound C=1C=CC=CC=1OCCOC1=CC=CC=C1 XCSGHNKDXGYELG-UHFFFAOYSA-N 0.000 description 1
- RXQNKKRGJJRMKD-UHFFFAOYSA-N 5-bromo-2-methylaniline Chemical compound CC1=CC=C(Br)C=C1N RXQNKKRGJJRMKD-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical group O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical group [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical group [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 235000010407 ammonium alginate Nutrition 0.000 description 1
- 239000000728 ammonium alginate Substances 0.000 description 1
- KPGABFJTMYCRHJ-YZOKENDUSA-N ammonium alginate Chemical compound [NH4+].[NH4+].O1[C@@H](C([O-])=O)[C@@H](OC)[C@H](O)[C@H](O)[C@@H]1O[C@@H]1[C@@H](C([O-])=O)O[C@@H](O)[C@@H](O)[C@H]1O KPGABFJTMYCRHJ-YZOKENDUSA-N 0.000 description 1
- 229940040526 anhydrous sodium acetate Drugs 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical group OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 150000008049 diazo compounds Chemical class 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- VMGAPWLDMVPYIA-HIDZBRGKSA-N n'-amino-n-iminomethanimidamide Chemical compound N\N=C\N=N VMGAPWLDMVPYIA-HIDZBRGKSA-N 0.000 description 1
- OSAFFDYLMYICLO-UHFFFAOYSA-N n,n-diphenyl-1,3,5-triazin-2-amine Chemical compound C1=CC=CC=C1N(C=1N=CN=CN=1)C1=CC=CC=C1 OSAFFDYLMYICLO-UHFFFAOYSA-N 0.000 description 1
- SJWQCBCAGCEWCV-UHFFFAOYSA-N n-(3-amino-4-methoxyphenyl)acetamide Chemical compound COC1=CC=C(NC(C)=O)C=C1N SJWQCBCAGCEWCV-UHFFFAOYSA-N 0.000 description 1
- PEMGGJDINLGTON-UHFFFAOYSA-N n-(3-aminophenyl)acetamide Chemical compound CC(=O)NC1=CC=CC(N)=C1 PEMGGJDINLGTON-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- KUDPGZONDFORKU-UHFFFAOYSA-N n-chloroaniline Chemical compound ClNC1=CC=CC=C1 KUDPGZONDFORKU-UHFFFAOYSA-N 0.000 description 1
- VBEGHXKAFSLLGE-UHFFFAOYSA-N n-phenylnitramide Chemical compound [O-][N+](=O)NC1=CC=CC=C1 VBEGHXKAFSLLGE-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000005184 naphthylamino group Chemical group C1(=CC=CC2=CC=CC=C12)N* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 description 1
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 1
- 229940066675 ricinoleate Drugs 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- LJRGBERXYNQPJI-UHFFFAOYSA-M sodium;3-nitrobenzenesulfonate Chemical compound [Na+].[O-][N+](=O)C1=CC=CC(S([O-])(=O)=O)=C1 LJRGBERXYNQPJI-UHFFFAOYSA-M 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 125000005031 thiocyano group Chemical group S(C#N)* 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 238000001665 trituration Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/06—Monoazo dyes prepared by diazotising and coupling from coupling components containing amino as the only directing group
- C09B29/08—Amino benzenes
- C09B29/0805—Amino benzenes free of acid groups
- C09B29/0807—Amino benzenes free of acid groups characterised by the amino group
- C09B29/0809—Amino benzenes free of acid groups characterised by the amino group substituted amino group
- C09B29/081—Amino benzenes free of acid groups characterised by the amino group substituted amino group unsubstituted alkylamino, alkenylamino, alkynylamino, cycloalkylamino, aralkylamino or arylamino
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
æ¬çºæã¯ãåæ£ã¢ãŸææã詳述ããã°æ§é äžå¯
æ¥ãªé¢é£æ§ãæããïŒçš®ä»¥äžã®åæ£ã¢ãã¢ãŸææ
æ··åç©ã該混åç©ã®è£œé æ³ãªãã³ã«è©²æ··åç©ã䜿
çšããŠè³éŠæããªãšã¹ãã«ç¹ç¶ææåã³è³éŠæã
ãªãšã¹ãã«ïŒã»ã«ããŒã¹æ··çŽ¡ãæè²ããæ¹æ³ã«é¢
ããã æ¬çºæã«ãã€ãŠããããã次åŒïŒ ãäžèšåŒäžãã¯å¡©çŽ åååã¯èçŽ ååã§ããã
ãR1ãåã³ïŒºã¯ããããC1ã4âã¢ã«ãã«åº
ã§ãããã§ç€ºãããå°ãªããšãïŒçš®é¡ã®ææãå«
æããæ··åç©äžã®åŒïŒ¡ãšåŒïŒ¢ã®ææã®æ¯ã80ïŒ20
éééšã20ïŒ80éééšã§ãããïŒçš®ä»¥äžã®åæ£ã¢
ãã¢ãŸæææ··åç©ãæäŸãããã æ¬æ现æžãéããŠâäœçŽã¢ã«ãã«åºâã¯ãççŽ
ååæ°ïŒãïŒã®ã¢ã«ãã«åºãæå³ããã ãR1ãåã³ïŒºã§è¡šããããäœçŽã¢ã«ãã«
åºã®è©³çŽ°ãªäŸãšããŠã¯ãã¡ãã«åºããšãã«åºãïœ
âãããã«åºãã€ãœãããã«åºãïœâããã«åºã
secâããã«åºåã³ã€ãœããã«åºãæããããã å ã«å®çŸ©ããæææ··åç©ãïŒæåãããªãå Ž
åããããã®æåã¯95ïŒïŒéééšãïŒïŒ95éé
éšãç¹ã«20ïŒ80éééšã80ïŒ20éééšã®éæ¯ã§æ··
åç©äžã«ååšããããšãã§ããã ïŒçš®ä»¥äžã®æææåãæ··åç©äžã«ååšããå Ž
åãåã ã®ææã¯æ··åç©ã®å šééã«å¯ŸããŠïŒéé
ïŒ ãäžããªãã æ¬çºæã«ããããããæææ··åç©ã¯ãåŒ
ïŒïŒïŒ ãæããïŒçš®ã®ææããæãããã®å Žåãããã®
ïŒçš®ã®ææã¯ããããïŒBrãX1ïŒïŒšãåã³ïŒ·
ïŒBrãX1ïŒã¡ããã·ã§ããã æ¬çºæã«ããä»ã®ããããæææ··åç©ã¯ããã
ãããBrã§ãããã€X1ãã§ããåŒïŒïŒã®
ææãåã³ïŒ·ãBrã§ãããã€X1ããšããã·ã§ã
ãåŒïŒïŒã®ææã®ïŒçš®ã®ææããæãã æŽã«ãæ¬çºæã«ããä»ã®ããããæææ··åç©
ã¯ããããããClã§ãããã€X1ãã§ããåŒ
ïŒïŒã®ææãåã³ïŒ·ãClã§ãããã€X1ãã¡ãã
ã·ã§ããåŒïŒïŒã®ææã®ïŒçš®ã®ææããæãã æŽã«ãæ¬çºæã«ããä»ã®ããããæææ··åç©
ã¯ããããããClã§ãããã€X1ãã§ããåŒ
ïŒïŒã®ææãåã³ïŒ·ãClã§ãããã€X1ããšãã
ã·ã§ããåŒïŒïŒã®ææã®ïŒçš®ã®ææãããªãã æŽã«æå©ã«ã¯ãå ã«å®çŸ©ããããããã®æ··åç©
ã«ãããŠX1ãã§ããåŒïŒïŒã®ææåã³X1ã
ã¡ããã·åã¯ãšããã·ã§ããåŒïŒïŒã®ææã¯ã
ããããéæ¯ãçŽïŒïŒïŒéééšãçŽïŒïŒïŒéééš
ã®éã«ããã¹ãã§ããã ç¹ã«ããBrã§ãããã€X1ãã§ããåŒ
ïŒïŒã®ææãåã³ïŒ·ãBrã§ãããã€X1ãã¡ãã
ã·ã§ããåŒïŒïŒã®ææãããããçŽïŒïŒïŒéé
éšã®éæ¯ã§ååšããåŒïŒïŒã®ïŒçš®ã®ææãããª
ãæ··åç©ãããããŠããã æ¬çºæã®ä»ã®ç¹åŸŽã«ããã°ãåŒïŒïŒïŒ ãåŒäžãããåã³ïŒºã¯åèšã®ãã®ãè¡šã
ããã§ç€ºãããã«ãããªã³ã°æåå°ãªããšãïŒçš®
ããæãæ··åç©ããåŒïŒïŒïŒ ãåŒäžãã¯åèšã®ãã®ãè¡šãããã§ç€ºãããã¢
ãã³ã®ãžã¢ãŸåã«ããåŸãããå°ãªããšãïŒåã®
ãžã¢ãŸããŠã ååç©ãšã«ãããªã³ã°ããããã®é
ã«ãããªã³ã°æåã®æ··åç©ã¯ïŒžãæ°ŽçŽ ã§ããæå
å°ãªããšãïŒçš®ãšïŒžãOR1ã§ããæåå°ãªããšã
ïŒçš®ãšãå«ãããšãããªãåŒ(A)ã(B)ã®åæ£ã¢ãã¢
ãŸæææ··åç©ã®è£œé æ³ãåŸãããã ïŒåã®ãžã¢ãŸããŠã ååç©ãåèšæ¹æ³ã§äœ¿çšã
ãå Žåã該ååç©ã¯å¥åã«åã¢ãã³ããžã¢ãŸåã
ãã€ããããŠåŸããããžã¢ãŸããŠã ååç©ãåæ
ã«ãåã¯é£ç¶ããŠã«ãããªã³ã°æåã®æ··åç©ã«å
ããããšã«ãã䜿çšããããåã¢ãã³ãæ··åç©ã®
圢ã§ãžã¢ãŸåãã次ã«ããããŠåŸãããæ··åãžã¢
ãŸããŠã ååç©ãã«ãããªã³ã°æåã®æ··åç©ã«å
ãããããããã¯åã ã«è£œé ãããžã¢ãŸããŠã å
åç©ããã«ãããªã³ã°æåã®æ··åç©ã«å ããåã«
äžç·ã«æ··åããããšãã§ããã åŒïŒïŒã®ã¢ãã³ã¯ãïŒã»ïŒâãžãããâïŒâ
ã¯ãã«ã¢ããªã³åã¯ïŒã»ïŒâãžãããâïŒâãã
ã ã¢ããªã³ã§ããããšãã§ããã åŒïŒïŒã®ã«ãããªã³ã°æåã®äŸã¯ãïŒâã¢ã»
ãã«ã¢ããâïŒâã¡ããã·âã»ïŒ®âãžãšãã«ã¢
ããªã³ãã»ïŒ®âãžãšãã«âïœâã¢ããã¢ã»ãã¢
ããªãã§ããããžã¢ãŸååã³ã«ãããªã³ã°ã¯ã該
åå¿ã«äœ¿çšãããåžžæ³ã§å®æœããããšãã§ããã
ããªãã¡ãã¢ãã³åã¯åŒïŒïŒã®ã¢ãã³ã®ãžã¢ãŸ
åã¯ãå ¬ç¥æ¹æ³ã§ãããã·ã«ç¡«é žäžã§å®æœããã
ãšãã§ãã次ã«åŸããããžã¢ãŸååç©ã®æº¶æ¶²ãæ°Ž
äžãããã¯æ°Žãšæ··åå¯èœã®ææ©æ¶²äœãšæ°Žãšã®æ··å
ç©äžã®ã«ãããªã³ã°æåã®æº¶æ¶²åã¯æžæ¿æ¶²ã«å
ããå¿ èŠã«å¿ããŠã«ãããªã³ã°åå¿ãä¿é²ããã
ããã«æ··åç©ã®PHã調ç¯ããæåŸã«åŸãããææ
ãåžžæ³ã§åé¢ããã åèšããæ··åã«ãããªã³ã°æååã³åç¬ã®ãžã¢
ãŸæååã¯ãžã¢ãŸæåæ··åç©ããæ¬çºæã«ããæ
ææ··åç©ã補é ãã以å€ã«ããã®æ··åç©ã¯åŒ
ïŒïŒã®ã¢ãã³åã³åŒïŒïŒã®ã«ãããªã³ã°æå
ããæ®éã®ãžã¢ãŸååã³ã«ãããªã³ã°åå¿ã«ãã€
ãŠåŸãããåã ã«è£œé ããæææåãäžç·ã«æ··å
ããããšã«ãã€ãŠãåŸãããšãã§ããã 該ææã¯ãåžžæ³ã§ãäŸãã°æ°Žãªãã³ã«é©åœãªå
æ£å€äŸãã°ããã¿ãªã³âïŒâã¹ã«ãã³é žïŒãã«ã
ã¢ã«ãããçž®åç©ã®ãããªãŠã å¡©ã§ææãç²ç ã
ãããšã«ãã€ãŠè£œé ãããæ°Žåæ£æ¶²ã®åœ¢ã§æ°Žæ§æµž
ææ³ãããžã³ã°æ³åã¯æºææ³ã«ããããªãšã¹ãã«
ç¹ç¶ææã«æœããããšãã§ãã該æè²æ³ã¯æ¬çºæ
ã®ä»ã®ç¹åŸŽãæ§æããã æ¬çºæã«ããæææ··åç©ã¯è³éŠæããªãšã¹ãã«
ç¹ç¶ææã«æ¿çŽºè²ã®è²çžãçããããããã¯ææ
æ··åç©ã®ä»»æã®åç¬æåã該ææã«æœããããšã«
ãã€ãŠéæãããçµæãããããããŠããã極ã
ãŠè¯å¥œãªæçæ§åã³é«ãçè²åãæããã æŽã«ãæ¬çºæã®ä»ã®ç¹åŸŽã«ãã€ãŠãå ã«å®çŸ©ã
ãïŒçš®ä»¥äžã®åæ£ã¢ãã¢ãŸææã®æ··åç©ãæ°Žæ§æµž
ææ³ãããžã³ã°æ³åã¯æºææ³ã§è³éŠæããªãšã¹ã
ã«ïŒã»ã«ããŒã¹æ··çŽ¡ã«æœããããšãããªã該混玡
ã®æè²æ³ãåŸãããã åšç¥ã®ããã«ãããªãšã¹ãã«ïŒã»ã«ããŒã¹æ··çŽ¡
ã®ããªãšã¹ãã«æåã¯åæ£ææã§æè²ããããšã
ã§ãããã該ææã¯ãç¹ã«ããžã³ã°æ³åã¯æºææ³
ã§æœããå Žå該ææãã»ã«ããŒã¹æåã«ãä»çã
ããšããæ¬ ç¹ãæãããåæ£ææã¯ã»ã«ããŒã¹æ
æã«å¯ŸããŠäœãå ç¢æ§ãæããããšãããã»ã«ã
ãŒã¹ãçè²ããæææåã¯å®¹æã«æŽæµé€å»ããã
æ¥å ã«ããããéæ¥éã«éè²ããããã®çµæãšã
ãŠããã®ããã«çè²ãããããªãšã¹ãã«ïŒã»ã«ã
ãŒã¹æ··çŽ¡ã¯ãã»ã«ããŒã¹äžã®ææã解é¢ãããã
ãã«å ããªå ç¢æ§ãæããã«ãããªãã該çè²æ··
玡ãæ倧ã®å ç¢æ§ãæããããã«ã¯ãéåºçææ
ãé€å»ããããšãååã§ãããããã¯ãæ®éçè²
混玡ã®âéå æŽæµâåŠçïŒããªãã¡ãã€ãããµã«
ãã¢ã€ãã®ç±ãã¢ã«ã«ãªæ°Žæº¶æ¶²äžã§ã®åŠçïŒã«ã
ã€ãŠéæããããããããâéå æŽæµâåŠçã«ã
ã€ãŠçãã液äœã®åŠçã¯ãéå å€ãååšããããš
ããçæ åŠçè«žåé¡ãæ¹èµ·ãããæŽã«éå æŽæµåŠ
çã¯ã混玡ã®ã»ã«ããŒã¹æåã該åŠçã«ææãªæ
æã§æè²ãããåŸã«ãã€ãŠã¯äœ¿çšããããšãã§ã
ãªãã æŽã«ãâéå æŽæµâåŠçãå®æœããªããšãäŸã
ã°æ®éã®æŽæ¿¯åŠçã§é€å»ãããä»»æã®ææããç¹
ã«æºææ³ã®å Žåã«ãããã¯ã»ã¹ãã€ãã³ã°ãçã
ãããããšãããä»ã®ããªã³ãéšåã®æ±æåã¯æ
ãè²èª¿ãçããã äžèšããç·åé¡ã¯ãå ã«å®çŸ©ããåæ£ã¢ãã¢ãŸ
æææ··åç©ã䜿çšããããšã«ãã€ãŠæå°éã«çã
ããããã®çµæ混玡ã®ã»ã«ããŒã¹æåæ±æã¯æå°
ã«ãªãã 該æ¹æ³ã¯ãããªãšã¹ãã«ïŒã»ã«ããŒã¹æ··çŽ¡ãã
å ã«å®çŸ©ããïŒçš®ä»¥äžã®ã¢ãã¢ãŸææã®æ°Žåæ£æ¶²
ãããªããç¹ã«éã€ãªã³ãã«ããªã³åã³ïŒåã¯ã¢
ããªã³çé¢æŽ»æ§å€ãå«æããæ济äžã«æµžæŒ¬ããã
ã®åŸã«è©²æ济ãäžå®æéé©åœãªæž©åºŠã§å ç±ããã
ãšã«ãã€ãŠå®æœããããšãã§ããã浞ææ³ã¯æž©åºŠ
95âã100âã§ãç¹ã«ãžããšãã«ãïœâãããã
ã·ãžããšãã«ãã¡ãã«ããã¿ãªã³ããµãªãã«é žã¡
ãã«åã¯ããªã¯ãã«ãã³ãŒã³ã®ãããªãã€ãªã€ãŒ
ã®ååšäžã«å®æœããããšãã§ãããã枩床120â
ã140âã§éå§äžã«å®æœããããšãã§ããã æ¬çºææ¹æ³ã¯ãå ã«å®çŸ©ããïŒçš®ä»¥äžã®åæ£ã¢
ãã¢ãŸææã®æ°Žåæ£æ¶²ãããªãšã¹ãã«ïŒã»ã«ããŒ
ã¹æ··çŽ¡ã«ããžã³ã°ãã次ã«è©²ææã枩床100âã
180âã§çæéã¹ããŒãã³ã°ããããåã¯æž©åºŠ160
âã220âã§ããŒãã³ã°åŠçããŠæ··çŽ¡ã«åºçãã
ãããšã«ãã€ãŠå®æœããããšãã§ãããå¿ èŠã«å¿
ããŠããžã³ã°æ¶²ã¯æ®éã®æ·»å å€ãäŸãã°åæ£å€ã
æ¿çš åå€ã移æé²æ¢å€åã¯å°¿çŽ ãå«æããããšã
ã§ããã ïŒçš®ä»¥äžã®åæ£ã¢ãã¢ãŸææãåæ£ãã圢ã§å«
æããæ¿çš æºæç³ãæœããä»ã®æ¹æ³ãšããŠãæºæ
ç³ãç¹ç¶ææã«æœããã®ã«é垞䜿çšãããä»»æã®
æ¹æ³ã«ãã€ãŠããäŸãã°ãããã¯ãŒãã¹ã¯ãªãŒã³
âåã¯ããŒã©ãŒæºæã«ãã€ãŠããªãšã¹ãã«ïŒã»ã«
ããŒã¹æ··çŽ¡ã®è¡šé¢ã«æœããããšãã§ããã次ã«ã
ããªã³ãããç¹ç¶ææããå Žåã«ãã€ãŠã¯ä¹Ÿç¥ã
ãåŸã«æž©åºŠ100âã180âã§çæéã¹ããŒãã³ã°ã
ãããåã¯æž©åºŠ160âã220âã§ããŒãã³ã°ããã
æºæç³äžã«ååšããé©åœãªæ¿çš åå€ã¯ããã©ã¬ã«
ã³ããŽã ãã¢ã©ãã¢ãŽã ãã¢ã«ã®ã³é žå¡©ãäŸãã°
ã¢ã«ã®ã³é žãããªãŠã åã¯ã¢ã«ã®ã³é žã¢ã³ã¢ããŠ
ã ãæ°Žäžæ²¹åãšãã«ãžãšã³åã¯æ²¹äžæ°Žåãšãã«ãž
ãšã³ããããã¯ãšãã¬ã³ïŒç¡æ°Žãã¬ã€ã³é žå ±éå
äœåã¯ããªã¢ã¯ãªã«é žãããŒã¹ãšããåææ¿çš å
å€ãå å«ããã該æºæç³ã¯ãå°¿çŽ ãïœâãããã
ã³ãŒã³ã¹ã«ãã³é žãããªãŠã ããžã€ããã皮皮ã®
ææã®åºçãè£å©ããé žåã¯ã¢ã«ã«ãªã®ãããªæ®
éã®æ·»å å€ãå«æããããšãã§ããã 浞ææ³ãããžã³ã°æ³åã¯æºææ³ãå®æœããåŸã
æè²ãããç¹ç¶ææã次ã«æ°ŽæŽããã æ¬çºææ¹æ³ã§äœ¿çšãããè³éŠæããªãšã¹ãã«ïŒ
ã»ã«ããŒã¹æ··çŽ¡ã¯ãè³éŠæããªãšã¹ãã«ç¹ç¶ãšã»
ã«ããŒã¹ç¹ç¶ãšã®æ··åç©ã§ããä»»æã®ç¹ç¶ææã§
ããããšãã§ããããã®ãããªæ··çŽ¡ã¯ãæ®éç·š
ç©ãåã¯æå©ã«ã¯ç¹ç©ã®åœ¢ã§ãããè³éŠæããªãš
ã¹ãã«ç¹ç¶ã®å²åã¯ã混玡ã®ééã«å¯ŸããŠ20éé
ïŒ ã95ééïŒ ãæå©ã«ã¯30ééïŒ ã85ééïŒ ã®ç¯
å²å ã«ãããè³éŠæããªãšã¹ãã«ç¹ç¶ã¯ç¹ã«ããª
ãšãã¬ã³ãã¬ãã¿ã¬ãŒãç¹ç¶ã§ãããã»ã«ããŒã¹
ç¹ç¶ã¯ç¹ã«ç¶¿ç¹ç¶ãäºéº»ç¹ç¶ããã¹ã³ãŒã¹ã¬ãŒãš
ã³ç¹ç¶åã¯ããªããžãã¯ã¬ãŒãšã³ç¹ç¶ã§ããã å ã«å®çŸ©ããåæ£ã¢ãã¢ãŸæææ··åç©ãæ¬çºæ
æ¹æ³ã§äœ¿çšããå Žåãããªãšã¹ãã«ïŒã»ã«ããŒã¹
混玡ã®è³éŠæããªãšã¹ãã«éšã¯ã混玡ã®ã»ã«ããŒ
ã¹éšã«å¯ŸããŠããããé²ææ§ã§æ¿çŽºè²ã«æè²ãã
ããããªãã¡ã»ã«ããŒã¹éšã¯æè²ãããªãããå
ã¯æ®ãã©æè²ãããã«æ®ããå Žåã«ãã€ãŠã¯çã
ããã»ã«ããŒã¹ã®å ããªæ±æã¯æ®éã«äœ¿çšããã
åŠçãããèããç©ããªâéå æŽæµâåŠçã§é€å»
ããããšãã§ããåŸã€ãŠå ã®æµåºåŠçåé¡ã¯çžå¿
ããŠæžå°ããã æ¬çºææ¹æ³ã¯ãè³éŠæããªãšã¹ãã«åã³ã»ã«ã
ãŒã¹ãå«æãã混玡ã®æè²ã«æœããããšãã§ãã
ãã®å Žåå ã«å®çŸ©ããåæ£ã¢ãã¢ãŸæææ··åç©ã¯
ã»ã«ããŒã¹çšã®ïŒçš®ä»¥äžã®é©åœãªçè²å€ãšçµåã
ãŠæœãããããã®åŠçã¯æ¬çºæã®ä»ã®ç¹åŸŽãæ§æ
ããã ããªãšã¹ãã«ïŒã»ã«ããŒã¹æ··çŽ¡ã®ã»ã«ããŒã¹éš
ã«å¯Ÿããé©åœãªçè²å€ã¯ãçŽæ¥ææããããæ
æãç¡«åææãããããŒã«ææãåã¯åå¿ææã§
ããã 混玡ã®è³éŠæããªãšã¹ãã«éšçšã®åæ£ã¢ãã¢ãŸ
æææ··åç©ãªãã³ã«æ··çŽ¡ã®ã»ã«ããŒã¹éšçšã®äžèš
ããçš®é¡ã®ïŒã€ããæãçè²å€ã¯ãäžè¬ã«åžžæ³ã§
åæã«åã¯é£ç¶çã«æœããããšãã§ããã æ¬çºæã§äœ¿çšããææã¯ãå šãŠã®åžžæ³ã§åã³ã»
ã«ããŒã¹çšã®å šãŠã®çš®é¡ã®ææãšäžç·ã«ããªãšã¹
ãã«ïŒã»ã«ããŒã¹æ··çŽ¡ã«æœããããšãã§ãããã
該ææã®ç¹ã«åªããå©ç¹ã¯ããããè¯å¥œãªã»ã«ã
ãŒã¹é²ææ§ãæããããšãããéå æŽæµåŠçãå«
ãŸãªãæ¹æ³ã䜿çšããŠé«ãå ç¢åºŠã®æè²ãåŸãã
ãããšã§ããããã®ããšã¯ãäžèšã«äŸç€ºãããã
ã«ç°¡åãã€çµæžçãªæ¹æ³ã®äœ¿çšãå¯èœãšããã ããªãã¡ãããªãšã¹ãã«ïŒã»ã«ããŒã¹ææã¯ã
åæ£ææåã³åå¿ææãæãã液äœã§ããžã³ã°
ãã也ç¥ããé«æž©ã§ããŒãã³ã°åã¯ã¹ããŒãã³ã°
ããŠåæ£ææãããªãšã¹ãã«æåã«åºçãããã¢
ã«ã«ãªæ°Žæº¶æ¶²äžã§ããžã³ã°ããã¹ããŒãã³ã°ããŠ
åå¿ææãã»ã«ããŒã¹æåã«åºçãããæŽæµãã
也ç¥ããããšãã§ããã ããžã³ã°æ¶²ã¯ã¢ã«ã«ãªãå«æããããšãã§ãã
åå¿ææã®åºçã¯ããŒãã³ã°åã®ä¹Ÿç¥éçšã§éæ
ãããåŸã€ãŠã¢ã«ã«ãªãããã¹ããŒã åŠçã®å¿ èŠ
æ§ãåé¿ããããšãã§ããã ãããæ³ã§åŠçããå Žåãããªãšã¹ãã«æåã¯
ä»»æã®åžžæ³ã§ç©ããªéå æŽæµåŠçãè¡ãªããåã¯
ãã®åŠçãå¿ èŠãšããªã浞ææ³ã§æè²ãã次ãã§
ã»ã«ããŒã¹æåã¯ã»ã«ããŒã¹çšã®ä»»æã®çš®é¡ã®æ
æã䜿çšããŠä»»æã®æ¹æ³ã§æè²ããããšãã§ã
ãã ãŸãã»ã«ããŒã¹æåãåå¿ææã§æè²ãã該æ
æãäžæ§ã«ãªããŸã§æ°ŽæŽããã次ã«ããªãšã¹ãã«
æåãå§åäžã«ããããã¯ãã€ãªã€ãŒãçšããŠå¥
åã®æ济äžã§åæ£æææ··åç©ã§æè²ããæŽæµããŠ
也ç¥ããããšãã§ããããŸãã»ã«ããŒã¹ããŸãå
å¿ææã§æè²ãããã®åŸã«åæ£æææ··åç©ã浞æ
济ã«å ããPHã調ç¯ããä»»æã®å©å€ãå ããããª
ãšã¹ãã«æåããã€ãªã€ãŒãšäžç·ã«æ²žéš°ãããå
ã¯å§åäžã§æè²ããã æ¬çºææ¹æ³ã§äœ¿çšãããåå¿ææã¯ãå°ãªããš
ãïŒåã®ç¹ç¶åå¿åºãå«æããä»»æã®æ°Žæº¶æ§ææ
ã§ãã€ãŠããããã®åºã¯ãææååäžã«ååšãã
ããšã«ãã該ææãã»ã«ããŒã¹ç¹ç¶ææäžã«ååš
ããããããã·åºãšååŠçã«çµåå¯èœã«ãããã®
çµæææååãïŒå以äžã®å ±æååŠçµåãä»ããŠ
ã»ã«ããŒã¹ååã«çµåãããåºãšããŠå®çŸ©ãã
ããåç¹ç¶åå¿åºã¯ææååäžã«ååšããççŽ å
åã«çµåããŠãããæå©ã«ã¯ææååäžã«ååšã
ãè³éŠæç°ãç¹ã«ãã³ãŒã³ç°ã®ççŽ ååã«çµåã
ãŠããã該ææã¯ãç¹ã«å°ãªããšãïŒåã®ç¹ç¶å
å¿åºãæãããã¢ãã¢ãŸåã³ããªã¢ãŸãå«ãã¢ãŸ
ç³»åã³å«éå±ã¢ãŸææãã¢ã³ãã©ããã³ããã«ã
ã¶ã³ãããªããšã³ãžãªããµãžã³ããããåã³ãã¿
ãã·ã¢ãã³ç³»ã®ææã§ããã ç¹ç¶åå¿åºã®äŸãšããŠã¯ãã¢ã¯ãªãã€ã«ã¢ãã
åã³ã¯ãããã«ã¢ããã®ãããªãªã¬ãã€ã³æ§äžé£œ
åèèªæã«ã«ãã³é žããããã¯Î²âã¯ãã«ããã
ãªãã«ã¢ãããβâããã ããããªãã«ã¢ããã
βïŒÎ³ïŒÎ³âããªã¯ãã«ã¯ãããã«ã¢ããåã³ã
ãã©ãã«ãªã«ã·ã¯ãããã«ã¢ã¯ãªãã€ã«ã¢ããã®
ãããªããã²ã³çœ®æèèªæã«ã«ãã³é žããèªå°ã
ããã¢ã·ã«ã¢ããåºãæãããããç¹ç¶åå¿åº
ã¯ãéžæçã«ããã«ã¹ã«ãã³ãβâã¯ãã«ãšãã«
ã¹ã«ãã³ãβâã¹ã«ããšãŒããšãã«ã¹ã«ããã«ã
βâã¯ãã«ãšãã«ã¹ã«ãã³ã¢ããåã¯ïŒ®â眮æã
ããŠããŠãããβâã¢ãããšãã«ã¹ã«ããã«åºã§
ããããšãã§ããã ç¹ç¶åå¿åºã¯ãæå©ã«ã¯è€çŽ ç°åŒäžã®ïŒååã¯
ïŒåã®çªçŽ ååãªãã³ã«è€çŽ ç°åŒç°ã®ççŽ ååã«
çµåããå°ãªããšãïŒåã®ã¬ã€ãã«çœ®æåºãæã
ãè€çŽ ç°åŒåºã§ãããã¬ã€ãã«çœ®æåºã®äŸãšããŠ
ã¯ãå¡©çŽ ãèçŽ ãåŒçŽ ã第ïŒçŽã¢ã³ã¢ããŠã åºã
ããªã·ã¢ããã¹ã«ãã³é žããããã«ã«ãã«ã¹ã«ã
ãã«åºãåŒãåŒããäœããçªçŽ ååã¯çœ®æã ããŠãããçåæ°ŽçŽ åºåã¯è€çŽ ç°åŒåºãæããã
ã®åºããªãã³ã«åŒïŒ ãäœããç Žç·ã¯çœ®æãããŠããŠãããããåã¯çž®
åè€çŽ ç°åŒç°ã圢æããã®ã«å¿ èŠãªååãè¡šãã
ãŠãããã®åºãæããããã ãã®ãããªç¹ç¶åå¿è€çŽ ç°åŒåºã®è©³çŽ°ãªäŸãšã
ãŠã¯ãïŒïŒïŒâãžã¯ãã«ããªããžã³âïŒâã«ã«ã
ãã«ã¢ãããïŒïŒïŒâãžã¯ãã«ããããµãªã³âïŒ
âåã¯ïŒâïŒã¹ã«ããã«åã¯ã«ã«ããã«ïŒã¢ã
ããïŒïŒïŒâãžã¯ãã«ãããŸãªã³âïŒâåã¯ïŒâ
ã¹ã«ããã«ã¢ãããïŒïŒïŒïŒïŒâããªã¯ãã«ãã
ãŸãªã³âïŒâåã¯ïŒâã¹ã«ããã«ã¢ãããïŒïŒ
ïŒïŒïŒâåã¯ïŒïŒïŒïŒïŒâããªã¯ãã«ãããŸãªã³
âïŒâã¹ã«ããã«ã¢ãããïŒïŒïŒâãžã¯ãã«ãã
ãŸãªã³âïŒâã«ã«ããã«ã¢ãããïŒïŒïŒâãžã¯ã
ã«ãã¿ã©ãžã³âïŒâã«ã«ããã«ã¢ãããïŒïŒïŒâ
ãžã¯ãã«ããªããŸã³âïŒâã€ã«ã¢ãããïŒïŒïŒâ
ãžã¯ãã«ããªããâïŒâã€ã«âã«ã«ããã«ã¢ã
ããïŒâïŒããšãã«â4â²âã«ã«ããã«ã¢ããïŒâ
ïŒïŒïŒâãžã¯ãã«ããªããŸã³ãïŒïŒïŒâåã³ïŒå
ã¯ïŒïŒïŒâãžã¯ãã«âåã¯ããã âããªãâïŒâ
ïŒåã³ïŒåã¯âïŒïŒã€ã«ã¢ããããžãã«ãªã«ã¯ã
ã«ããªããžã«ã¢ãããããªã¯ãã«ããªããžã«ã¢ã
ããããªããã ããªããžã«ã¢ããããžã¯ãã«âïŒ
âïŒã·ã¢ããããããã¡ãã«åã¯ã«ã«ãã¡ãã
ã·ïŒããªããžã«ã¢ãããïŒâã¡ãã«ã¹ã«ããã«â
ïŒâã¯ãã«ããªããâïŒâã€ã«ã«ã«ããã«ã¢ãã
åã³ïŒâã¯ãã«âïŒâã¡ãã«âïŒâã¡ãã«ã¹ã«ã
ãã«ããªããâïŒâã€ã«ã¢ãããåã³ç¹ã«åŒçŽ å
ååã¯èçŽ ååããªããããå¡©çŽ ååãïŒäœåã³
ïŒäœã®å°ãªããšãïŒã€ã«å«æããïŒïŒïŒïŒïŒâã
ãªã¢ãžã³âïŒâã€ã«ã¢ããåºãäŸãã°ïŒïŒïŒâãž
ã¯ãã«âïŒïŒïŒïŒïŒâããªã¢ãžã³âïŒâã€ã«ã¢ã
ããæãããããããªã¢ãžã³æ žãïŒåã®ããã²ã³
ååãç¹ã«å¡©çŽ ååã®ã¿ãå«æããå Žåãããªã¢
ãžã³ç°ã®ç¬¬ïŒççŽ ååã¯ãã¡ãã«åã¯ããšãã«ã®
ãããªçåæ°ŽçŽ åºã«ãã€ãŠã詳述ããã°çœ®æãã
ãŠããŠãããããããã·åºãã¡ã«ã«ããåºåã¯ã¢
ããåºäŸãã°ã¡ããã·ãããšããã·ãαâåã³Î²
âããããã·ãã¡ãã«ã¡ã«ã«ãããããšãã«ã
ãªãã¡ãã«ã¢ããããžãšãã«ã¢ãããã·ã¯ããã
ã·ã«ã¢ãããåã³ã¢ããªã䞊ã³ã«ïŒ®âã¢ã«ãã«ã¢
ããªãåã³ãã®çœ®æèªå°äœäŸãã°ã¢ãã·ãžããã
ã«ã€ãžããã«ã«ããã·ã«ã¢ããªããã¹ã«ãã¢ããª
ãããžã¹ã«ãã¢ããªãåã³ã¹ã«ãã³åãããã«ã¢
ããã«ãã€ãŠçœ®æããããšãã§ããã ããããŠãããããçš®é¡ã®åå¿ææã¯ãç¹ç¶å
å¿åºãšããŠåŒïŒ ãåŒäžãïœã¯ïŒåã¯ïŒã§ãããã¯å¡©çŽ ååã眮
æãããŠããŠãããã¢ããåºåã¯ãšãŒãã«åãã
ããã·ã«åºã§ãããã§ç€ºãããåºãå«æãã該æ
æãããªãã ã§è¡šãããã眮æãããŠããŠãããã¢ããåº
ã¯ãç¹ã«çœ®æãããŠããŠãããã¢ã«ãã«ã¢ãã
åºãã¢ããªãåºãåã¯ïŒ®âã¢ã«ãã«ã¢ããªãåºã
äŸãã°ã¡ãã«ã¢ããããšãã«ã¢ãããβâããã
ãã·ãšãã«ã¢ããããžïŒÎ²âããããã·âãšã
ã«ïŒã¢ãããβâã¡ããã·ãšãã«ã¢ãããβâã¹
ã«ããšãŒããšãã«ã¢ãããïœâãïœâåã³ïœâã¹
ã«ãã¢ããªããïŒâåã³ïŒâã¹ã«ãâïŒâã¡ãã
ã·ã¢ããªããïŒâåã³ïŒâã¹ã«ãâïŒâã¡ãã«ã¢
ããªããïŒâåã³ïŒâã¹ã«ãâïŒâã¯ãã«ã¢ããª
ããïŒâåã³ïŒâã¹ã«ãâïŒâã¯ãã«ã¢ããªãã
ïŒã»ïŒâãïŒã»ïŒâåã³ïŒã»ïŒâãžã¹ã«ãã¢ããª
ããâã¡ãã«âïœâåã³ïœâã¹ã«ãã¢ããªãã§
ããã å¿ èŠã«å¿ããŠãç¹ç¶åå¿åºã¯æ¬¡åŒã§ç€ºãããšã
ã§ããïŒ âNHâJ1âïŒâJ2 åŒäžãJ1ã¯å Žåã«ãã€ãŠã¯ã¬ã€ãã«çœ®æåºãæ
ããŠããŠãããããªããžã³ç°åã¯ããªã¢ãžã³ç°ã§
ãããJ2ã¯å°ãªããšãïŒåã®ã¬ã€ãã«çœ®æåºãæ
ããããªããžã³ç°åã¯ããªã¢ãžã³ç°ã§ãããïŒã¯
眮æãããŠããŠãããã€ããåºïŒè©²ã€ããåºã¯ã
ãšãã¬ã³ãïŒïŒïŒâããšãã¬ã³åã¯ïŒâã¹ã«ãâ
ïŒïŒïŒâããšãã¬ã³ã®ãããªã¢ã«ãã¬ã³åºåã¯ã¢
ãªãŒã¬ã³åºãä»ããŠäžç·ã«çµåããŠããïŒãä»ã
ãŠJ1åã³J2ãšçµåããŠããæ¶æ©å¡ã§ããã ïŒã§è¡šããããç¹ã«éèŠãªä»ã®çµååºã¯ãåã
ã³ãŒã³æ žäžã«ã¹ã«ãã³é žåºãå«æãããã¹ãã«ã
ã³ããžããšãã«ããžããšãã«ãªãã·ãããžããšã
ã«ã¢ãã³ããžããšãã«å°¿çŽ ããžããšããã·ãšã¿ã³
åã³ãžããšãã«ã¢ããâïœâããªã¢ãžã³ã®ïŒäŸ¡ã®
åºã§ããã æå©ã«ã¯ãJ1åã³J2ãããããã¯ãã«âïœâã
ãªã¢ãžã³åºãè¡šããã¹ãã§ãããããªãã¡ãåå¿
ææã®ä»ã®çš®é¡ã¯ãç¹ç¶åå¿åºãšããŠæ¬¡åŒã®åºã
å«æããææãããªãïŒ åŒäžãïœãïœåã³ïœã¯ãããããç¬ç«ã«ïŒåã¯
ïŒã§ãããïŒåã³ïŒ±ã¯åèšã®ãã®ãè¡šããã åèšããããã«ïŒ±åºã¯ãå®çŸ©ããç¯å²å ã§â
NHâåã¯ââãä»ããŠããªã¢ãžã³ç°ã®ççŽ å
åãšçµåããçºè²å£ç³»ãå«æããåºãå å«ããã ãã®ãããªåå¿ææã¯ãåžžæ³ã§äŸãã°ç¬¬ïŒçŽå
ã¯ç¬¬ïŒçŽã¢ããåºãå«æãã氎溶æ§ææãåèšã®
ç¹ç¶åå¿åºãå«æããååç©ãšåå¿ãããããšã«
ãã€ãŠåŸãããšãã§ããããã®ãããªååç©ã®äŸ
ãšããŠã¯ãå¡©åã¢ã¯ãªãã€ã«ãå¡©åã·ã¢ãã«ã
ïŒïŒïŒïŒïŒâããªã¯ãã«ããªããžã³ãïŒïŒïŒïŒïŒ
âããªã¯ãã«âïŒâïŒã·ã¢ãâåã¯ã¯ãã«âïŒã
ãªããžã³åã³ïŒâã¡ããã·âïŒïŒïŒâãžã¯ãã«â
ïŒïŒïŒïŒïŒâããªã¢ãžã³ãæããããã ä»ã®ããããåå¿ææã¯ãïŒå以äžã®çé žåºã
ç¹ã«ãã¹ãã³é žåºãå«æãããã®ã§ããã該ææ
ã¯è±åœç¹èš±æ现æžç¬¬1411306å·ã«èšèŒã®æ¹æ³ã«ã
ã€ãŠã»ã«ããŒã¹ç¹ç¶ææã«æœããããã ãã®çºææ¹æ³ã«ãããè³éŠæããªãšã¹ãã«ïŒã»
ã«ããŒã¹æ··çŽ¡ã¯ããã®çš®ã®ç¹ç¶ææã«æ®éã«æœã
ãããè©Šéšã«å¯ŸããŠããããå ç¢åºŠãæããçš®ã
ã®è²çžã«æè²ãããç¹ç¶ææã®ããªã³ããããªã
çœè²éšåã®ããããé²æãååšããã æ¬çºæã«ããç¹ã«ããããæ··åç©çšã®èŠå®ã®ã«
ãããªã³ã°æååã³ææã®è£œé æ³ã次ã«èšèŒã
ããâéšâã¯ç¹ã«èšèŒããªãéãâéééšâãè¡š
ããããéééšãšã®æ¯ã¯Kgãšãšã®æ¯ã§ããã ïŒâã¢ã»ãã«ã¢ããâïŒâã¡ãªãã·âã»ïŒ®âãž
ãšãã«ã¢ããªã³ã®è£œé ïŒâã¢ã»ãã«ã¢ããâïŒâã¡ããã·ã¢ããªã³18
éšãæ°Ž50容ééšäžã§æ¹æãããæ°Žé žåãããªãŠã
氎溶液ïŒãã¯ãã«åºŠTw70ãïŒãå ããŠãPHãïŒ
ã10ã«èª¿ç¯ããã該混åç©ã65âã«å ç±ããåæ£
å€ïŒããªã°ãªã»ããŒã«ãªã·ãã¬ãšãŒãã0.5éšïŒ
ãå ããåŒç¶ãçé žæ°ŽçŽ ãããªãŠã 29.4éšïŒã¢ã
ãªã³åºçºç©è³ªïŒã¢ã«ããã3.5ã¢ã«ïŒãå ããã
次ã«ããžãšãã«ã¹ã«ããšãŒã54éšïŒïŒã¢ã«ããã
3.5ã¢ã«ïŒã65âã§ïŒæéã«ãããå ãããåå¿
ã¯åŸã ã«é²è¡ããããžãšãã«ã¹ã«ããšãŒãã®æ·»å
åŸã65âã§ã®æ··åç©ã®æ¹æãããã«ïŒæéç¶ç¶ã
ããŠåå¿ãçµããããåå¿æ··åç©ã宀枩ã«å·åŽ
ããïŒâã¢ã»ãã«ã¢ããâïŒâã¡ããã·âã»ïŒ®
âãžãšãã«ã¢ããªã³ãéããæ°ŽïŒ500容ééšïŒã§
æŽæµãã70âã§ä¹Ÿç¥ããã ã»ïŒ®âãžãšãã«âïœâã¢ããã¢ã»ãã¢ããªã
ã¯åãæ¹æ³ã§ïœâã¢ããã¢ã»ãã¢ããªããã補é
ãããã X1ãã¡ããã·ã§ããåŒïŒïŒã®ææã®è£œé 100ïŒ ç¡«é ž70ïŒå®¹éïŒéšãæ°ŽïŒéšã«å ããã次
ã«ãäºç¡é žãããªãŠã ïŒéšãæ··åç©ã®æž©åºŠã70â
±ïŒâã«äžæããã€ãã®å€ã«ç¶æããããããªé
床ã§æ¹æããè©²é žã«æç¶çã«æ·»å ãããäºç¡é žã
ããªãŠã ã®æ·»å åŸã«ããã®æº¶æ¶²ãïŒæéæ¹æãã
ãã®é枩床ã¯å®€æž©ã«äœäžãããïŒã»ïŒâãžããã
âïŒâããã ã¢ããªã³26.2éšã25âã28âã§æ¹æ
ããäºç¡é žãããªãŠã 溶液ã«30åéå ãããæ·»å
çµäºåŸã«ã溶液ã宀枩ã§ïŒæéæ¹æããã ïŒâã¢ã»ãã«ã¢ããâïŒâã¡ããã·âã»ïŒ®â
ãžãšãã«ã¢ããªã³23.6éšãæ°Ž500éšäžã§æ¹æãã
æ¿å¡©é ž10容ééšãå ãããæ°·ããã®æº¶æ¶²ã«å ããŠ
枩床ãïŒâã«äœäžãããç¡æ°Žé ¢é žãããªãŠã ãå
ããŠPHãïŒãïŒã«èª¿ç¯ããã次ã«ããžã¢ãŸåïœâ
ãããã¢ããªã³ãšã®æ··åç©ãè©Šéšããéã«è¡šãã
ãéå°ã®ã«ãããªã³ã°æåã®çè·¡ã®ã¿ãæ®åãã
ããã«ãªããŸã§ããžã¢ãŸåã¢ãã³æº¶æ¶²ãïŒâåã³
PHïŒïŒæ°·ãšé ¢é žãããªãŠã ãšã®æ·»å ã«ãã€ãŠèª¿
ç¯ïŒã§30åé滎å ããã該混åç©ãïŒâãïŒâã§
ããã«15åéæ¹æããææãéããæ°Žã§æŽæµããŠ
ç¡æ©ã®äžçŽç©ãé€å»ããã該ææã沞隰ããŠãã
ã¢ã»ãã³ã«æº¶ããããã®æº¶æ¶²ãæ¿Ÿéããæ°·åã³æ°Ž
ãã¢ã»ãã³æº¶æ¶²ã«å ããããšã«ãã€ãŠææãåã³
æ²æ®¿ããããçæç©ãåã³éããæ°Žã§æŽæµãã70
âã§ä¹Ÿç¥ããã X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææã®è£œé ïŒã»ïŒâãžãããâïŒâããã ã¢ããªã³ïŒ26.2
éšïŒããžã¢ãŸåããå ã®è£œé æ³ã§èšèŒããããã«
ã»ïŒ®âãžãšãã«âïœâã¢ããã¢ã»ãã¢ããªã
20.6éšãšã«ãããªã³ã°ãããã æ¬çºæã次ã®å®æœäŸã«ãã€ãŠè©³èª¬ãããããã
ã«éå®ããããã®ã§ã¯ãªããå®æœäŸäžã®âéšâå
ã³âïŒ âã¯âéééšâåã³âééïŒ âã§ããã äŸ ïŒ ïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ããåŒ
ïŒïŒã®ææåã³ïŒ·ãBrã§ãããã€X1ãæ°ŽçŽ ã§ã
ãåŒïŒïŒã®ææãããã10éšãå¥åã«ãè¬å€
39.2ééïŒ åã³æ°Ž77.2éšãå«æããåæ£å€ïŒãã
ã¿ãªã³âïŒâã¹ã«ãã³é žïŒãã«ã ã¢ã«ãããçž®å
ç©ã®ãããªãŠã å¡©ïŒã®æ°Žæº¶æ¶²12.8éšã§åŸ®ç²ç ã
ãã48æé埮ç²ç ããåŸã«ãã®åæ£æ¶²äžã®åææ
ã®ç²åŸã¯ïŒãïŒãã¯ãã³ã§ããã äžèšã®ããã«ããŠåŸãããäž¡åæ£æ¶²ãããªãã¡
ãBrã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®æ
æã®10ïŒ æ°Žåæ£æ¶²0.3éšãªãã³ã«ïŒ·ãBrã§ããã
ã€X1ãã¡ããã·ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Ž
åæ£æ¶²0.075éšãæè²å®¹åšã«ç§»ããç·©è¡æ¶²0.5容é
éšãå ããåŒç¶ãããªãšã¹ãã«ç¹ç¶ææçïŒéšã
å ããã次ã«è©²æ济ãæ°Žã§50éšã«ããéå§äžã«
130âã§ïŒæéæè²ãè¡ãªããæè²çµäºåŸã«ãæ
è²ãããææããã€ãããµã«ãã¢ã€ãïŒéšãæ°Žé ž
åãããªãŠã 溶液ïŒãã¯ãã«åºŠTw70ãïŒïŒå®¹é
éšãåæ£å€ïŒå®¹ééšåã³æ°Ž490容ééšãããªãé
å æŽæµæµŽäžã§70âã§30åéæ¹æããã次ã«ã該ç¹
ç¶ãç³é¹žæº¶æ¶²äžã§ååã«æŽæµããæ°Žã§ååã«æŽã
äžããŠä¹Ÿç¥ããã ããªãšã¹ãã«ã¯ã極ããŠè¯å¥œãªæçæ§åã³é«ã
çè²åãæãããã€ããŒãã«ãŒè²ã«æè²ãããã äŸ ïŒ äŸïŒã«èšèŒããæè²æ³ãç¹°ãè¿ããããBr
ã§ãããã€X1ãã§ããåŒïŒïŒã®ææã®10ïŒ
æ°Žåæ£æ¶²ãªãã³ã«ïŒ·ãBrã§ãããã€X1ãã¡ãã
ã·ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Žåæ£æ¶²ãã次ã®
éã§äœ¿çšããïŒ ãè¡šã ãã®å Žåãããããããªãšã¹ãã«ç¹ç¶ææã«ã¯
æ¿ããã€ããŒãã«ãŒè²ãåŸãããã äŸ ïŒ äŸïŒã«èšèŒããæè²æ³ãç¹°ãè¿ããããBr
ã§ãããã€X1ãã¡ããã·ã§ããåŒïŒïŒã®ææ
ã®10ïŒ æ°Žåæ£æ¶²0.075éšãã次ã®åŒ(A)ã(B)ã®ææ
ã®ããããïŒã€ã®10ïŒ æ°Žåæ£æ¶²0.1éšã§ä»£æ¿ã
ãã次衚ã®ïŒ·ãããåã³ïŒ²ã¯ãåŒ(A)ã(B)ã«
èšèŒããã®ãšåããã®ãè¡šããã ãè¡šã äŸïŒã«èšèŒã®ããã«è³éŠæããªãšã¹ãã«ç¹ç¶æ
æã«æœãããå Žåæææ··åç©ã¯ãããããæ¿ãã
ã€ããŒãã«ãŒè²ãçããã äŸ ïŒ äŸïŒã«èšèŒããæè²æ³ãç¹°ãè¿ããããBr
ã§ãããã€X1ãã¡ããã·ã§ããåŒïŒïŒã®ææ
ã®10ïŒ æ°Žåæ£æ¶²0.075éšããåãææåæ£æ¶²0.1éš
ã§ä»£æ¿ãããŸããBrã§ãããã€X1ãæ°ŽçŽ ã§ã
ãåŒïŒïŒã®10ïŒ æ°Žåæ£æ¶²0.3éšã次ã®åŒ(A)ã(B)
ã®äžèšææã®ããããïŒã€ã®10ïŒ æ°Žåæ£æ¶²0.3éš
ã§ä»£æ¿ããã次衚ã®ïŒ·ãããåã³ïŒ²ã¯ãåŒ
(A)ã(B)ãšåããã®ãè¡šããã ãè¡šã äŸïŒã«èšèŒããããã«è³éŠæããªãšã¹ãã«ç¹ç¶
ææã«æœãããå Žååæææ··åç©ã¯ãããããæ¿
ããã€ããŒãã«ãŒè²ãçããã äŸ ïŒ ïŒ·ãBrã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®
ææã®10ïŒ æ°Žåæ£æ¶²0.3éšããBrã§ãããã€X1
ãã¡ããã·ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Žåæ£æ¶²
0.05éšãªãã³ã«ïŒ·ãBrã§ãããã€X1ããšããã·
ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Žåæ£æ¶²0.05éšãäž
ç·ã«æ··åãããäŸïŒã«èšèŒããæ¹æ³ã§è³éŠæããª
ãšã¹ãã«ç¹ç¶ææã«æœãããå Žå該混åç©ã¯ãæ¿
ããã€ããŒãã«ãŒè²ãçããã ãBrã§ãããã€X1ããšããã·ã§ããåŒ
ïŒïŒã®ææãããèçŽ ã§ããããã¡ããã·
ã§ãããåã³ïŒºãããããïœâãããã«ã§ã
ãããã€ïŒ²ãã¡ãã«ã§ããåŒ(A)ã(B)ã®ææã«ä»£ã
ãå Žåã«ãåãçµæãåŸãããã äŸ ïŒ ïŒ¹åã³ïŒºããããããšãã«ã§ããããã¡ãã«
ã§ããããã€ïŒ·åã³ïŒžã次ã®ãã®ãè¡šããåŒ(A)ã
(B)ã®ïŒçš®é¡ã®ææã®10ïŒ æ°Žåæ£æ¶²ãã次ã®éæ¯ã§
æ··åç©ãäœãã   Br  1.5éš Cl  1.5éš Br OCH3 0.5éš Cl OCH3 0.5éš äŸïŒã«èšèŒããæ¹æ³ã§è³éŠæããªãšã¹ãã«ç¹ç¶
ææã«æœãããå Žå該混åç©ã¯ãæ¿ããã€ããŒã
ã«ãŒè²ãçããã äŸ ïŒ ïŒã»ïŒâãžãããâïŒâããã ã¢ããªã³26.2éš
ãåèšããæ¹æ³ã§ãžã¢ãŸåããããããŠåŸããã
ãžã¢ãŸããŠã ååç©ããåèšããæ¹æ³ã§ïŒâã¢ã»
ãã«ã¢ããâïŒâã¡ããã·âã»ïŒ®ãžãšãã«ã¢ã
ãªã³6.0éšãšïŒ®ã»ïŒ®âãžãšãã«âïœâã¢ããã¢ã»
ãã¢ããªã15.4éšãšã®æ··åç©ãšã«ãããªã³ã°ãã
ããããããŠåŸãããæ··åç©ææãäŸïŒã«èšèŒã
ãããã«æ°Žåæ£æ¶²ã®åœ¢ã§è³éŠæããªãšã¹ãã«ç¹ç¶
ææã«æœãããå Žåãæ¿ããã€ããŒãã«ãŒè²ãç
ããã äŸ ïŒ äŸïŒã«èšèŒããæè²æ³ãç¹°ãè¿ããããBr
ã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææã®10
ïŒ æ°Žåæ£æ¶²0.3éšãããClã§ãããã€X1ãæ°ŽçŽ
ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Žåæ£æ¶²0.3éšã«ã
ã€ãŠä»£ãããŸããBrã§ãããã€X1ãã¡ããã·
ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Žåæ£æ¶²0.075éš
ãã次ã®åŒ(A)ã(B)ã®ææã®ããããïŒã€ã®10ïŒ æ°Ž
åæ£æ¶²0.1éšã§ä»£æ¿ããã次衚ã®ïŒ·ããã
åã³ïŒ²ã¯ãåŒ(A)ã(B)ã«ããããšåããã®ãè¡šã
ãã ãè¡šã äŸ11ã«èšèŒããããã«è³éŠæããªãšã¹ãã«ç¹ç¶
ææã«æœãããå Žååæææ··åç©ã¯ãããããæ¿
ããã€ããŒãã«ãŒè²ãçããã äŸ ïŒ ããªãšã¹ãã«ïŒç¶¿ç¹ç¶ã®67ïŒ33ç¹ç©æ··çŽ¡ã次ã®
æ§é ã®ããã液äžã§ããžã³ã°ããããã®çµæ該æ
æã¯ããžã³ã°æ¶²ã®ééã®50ïŒ ãä¿æããïŒ ïŒ·ãBrã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®æ
æïŒ10ïŒ æ°Žåæ£æ¶²ãšããŠïŒ ïŒéš ãBrã§ãããã€X1ãã¡ããã·ã§ããåŒïŒïŒ
ã®ææïŒ10ïŒ æ°Žåæ£æ¶²ãšããŠïŒ ïŒéš å°¿ çŽ 10éš ãããã·ã«ïŒMatexilïŒFAâMIVïŒImperial
Chemical Industries Limitedããåžè²©ãããŠã
ã移ææå¶å€ïŒâMatexilâã¯ç»é²åæšã§ããïŒ
10éš ããã液1000éšãããçé žæ°ŽçŽ ãããªãŠã 10éš è©²ææã¯ãæå©ã«ã¯ããã¿ãªã³âïŒâã¹ã«ãã³
é žïŒãã«ã ã¢ã«ãããçž®åç©ã®ãããªãŠã å¡©ã®ã
ããªä¿è·å€éã®ååšäžã§ç²ç ããããæ°Žåæ£æ¶²ã®
圢ã§ããã ããžã³ã°åŠçãããææã110âã§30ç§é也ç¥
ãã210âã§60ç§éããŒãã³ã°ããç±æ°Žäžã§æ°ŽæŽ
ãããã·ã³ããããã¯ïŒSynperonicïŒBD
ïŒImperial Chemical Industries Limitedããåž
販ãããŠããåææŽå€ïŒâSynperonicâã¯ç»é²
åæšã§ããïŒïŒïœïŒãå«æãã溶液äžã§80âã§
30ç§éåŠçããå·æ°Žã§æŽãäžããŠä¹Ÿç¥ãããäžèš
ã®äžé£ã®åŠçã¯ãæ®éã«é£ç¶ããé åºã§å®æœãã
ããšãã§ããã 該混玡ã®ããªãšã¹ãã«æåã¯å®å šã«åž¯èµ€ãã€ã
ãŒè²ã«æè²ããã綿æåã¯å ãã«æ±æãããã«ã
ããªãã該ç¹ç¶ã¯ãæ¥å åã³æŽæ¿¯ã«å¯ŸããŠè¯å¥œãª
å ç¢åºŠãæããã äŸ 10 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææãª
ãã³ã«ïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ããåŒ
ïŒïŒã®ææã¯ã次ã®éæ¯ã§äœ¿çšãããïŒ ãè¡šã ããããã®å Žåã«ãäŸïŒã«èšèŒããããã®ãšå
ãçµæãåŸãããã äŸ 11 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒ
éšãïŒéšã«å¢å€§ãããBrã§ãããã€X1ãã¡ã
ãã·ã§ããåŒïŒïŒã®ææïŒéšãã次ã®åŒ(A)ã(B)
ã®ææã®ããããïŒã€ã®ïŒéšã«ãã€ãŠä»£ããã次
è¡šã®ïŒ·ãããåã³ïŒ²ã¯ãåŒ(A)ã(B)ã«ããã
ãšåããã®ãè¡šããã ãè¡šã ãã®å ŽåãããããäŸïŒã«èšèŒããã®ãšåãçµ
æãåŸãããã äŸ 12 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãã¡ããã·ã§ããåŒïŒïŒã®æ
æïŒéšãïŒéšã«æžå°ããããBrã§ãããã€X1
ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒéšã次ã®åŒ(A)ã(B)
ã®ææã®ããããïŒã€ïŒéšã«ãã€ãŠä»£ããã次衚
ã®ïŒ·ãããåã³ïŒ²ã¯ãåŒ(A)ã(B)ã«ããããš
åããã®ãè¡šããã ãè¡šã ãã®å ŽåãããããäŸïŒã«èŒããã®ãšåãçµæ
ãåŸãããã äŸ 13 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒ
éšãªãã³ã«ïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ã
ãåŒïŒïŒã®ææïŒéšãããBrã§ãããã€X1
ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒéšããBrã§ã
ããã€X1ãã¡ããã·ã§ããåŒïŒïŒã®ææ0.5éš
ãªãã³ã«ïŒ·ãBrã§ãããã€X1ããšããã·ã§ãã
åŒïŒïŒã®ææ0.5éšã«ãã€ãŠä»£ããã äŸïŒã«èšèŒããã®ãšåãçµæãåŸãããã ãBrã§ãããã€X1ããšããã·ã§ããåŒ
ïŒïŒã®ææãããèçŽ ã§ããããã¡ãã«ã§
ããããã¡ããã·ã§ããããã€ïŒ¹åã³ïŒºããã
ããïœâãããã«ã§ããåéã®åŒ(A)ã(B)ã®ææã«
代ããå ŽåãåãçµæãåŸãããã äŸ 14 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒ
éšãªãã³ã«ïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ã
ãåŒïŒïŒã®ææïŒéšããåã³ïŒºããããããš
ãã«ã§ããããã¡ãã«ã§ããããã€ïŒ·åã³ïŒžã
次ã®ãã®ãè¡šããåŒ(A)ã(B)ã®ïŒçš®é¡ã®ææã«ãã€
ãŠæ¬¡ã®éæ¯ã§ä»£ããïŒ ïŒ·  Br  1.5éš Cl  1.5éš Br OCH3 0.5éš Cl OCH3 0.5éš äŸïŒã«èšèŒããã®ãšåãçµæãåŸãããã äŸ 15 ãBrã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®
ææãšïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ããåŒ
ïŒïŒã®ææãšã®æ··åç©ããäŸïŒã«èšèŒãããã
ã«ããŠè£œé ãã10ïŒ æ°Žåæ£æ¶²ã«ç§»ãã 該åæ£æ¶²ãäŸïŒã«èšèŒããããã«ããªãšã¹ã
ã«ïŒç¶¿æ··çŽ¡ã«æœãããå ŽåãåãçµæãåŸãã
ãã äŸ 16 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒ
éšãªãã³ã«ïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ã
ãåŒïŒïŒã®ææïŒéšãããããããClã§ã
ããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒéšãªã
ã³ã«æ¬¡ã®åŒ(A)ã(B)ã®ææã®ããããïŒã€ïŒéšã«ã
ã€ãŠäœããã次衚ã®ïŒ·ãããåã³ïŒ²ã¯åŒ
(A)ã(B)ã«ããããšåããã®ãè¡šããã ãè¡šã ãã®å ŽåãããããäŸïŒã«èšèŒããã®ãšåãçµ
æãåŸãããã
æ¥ãªé¢é£æ§ãæããïŒçš®ä»¥äžã®åæ£ã¢ãã¢ãŸææ
æ··åç©ã該混åç©ã®è£œé æ³ãªãã³ã«è©²æ··åç©ã䜿
çšããŠè³éŠæããªãšã¹ãã«ç¹ç¶ææåã³è³éŠæã
ãªãšã¹ãã«ïŒã»ã«ããŒã¹æ··çŽ¡ãæè²ããæ¹æ³ã«é¢
ããã æ¬çºæã«ãã€ãŠããããã次åŒïŒ ãäžèšåŒäžãã¯å¡©çŽ åååã¯èçŽ ååã§ããã
ãR1ãåã³ïŒºã¯ããããC1ã4âã¢ã«ãã«åº
ã§ãããã§ç€ºãããå°ãªããšãïŒçš®é¡ã®ææãå«
æããæ··åç©äžã®åŒïŒ¡ãšåŒïŒ¢ã®ææã®æ¯ã80ïŒ20
éééšã20ïŒ80éééšã§ãããïŒçš®ä»¥äžã®åæ£ã¢
ãã¢ãŸæææ··åç©ãæäŸãããã æ¬æ现æžãéããŠâäœçŽã¢ã«ãã«åºâã¯ãççŽ
ååæ°ïŒãïŒã®ã¢ã«ãã«åºãæå³ããã ãR1ãåã³ïŒºã§è¡šããããäœçŽã¢ã«ãã«
åºã®è©³çŽ°ãªäŸãšããŠã¯ãã¡ãã«åºããšãã«åºãïœ
âãããã«åºãã€ãœãããã«åºãïœâããã«åºã
secâããã«åºåã³ã€ãœããã«åºãæããããã å ã«å®çŸ©ããæææ··åç©ãïŒæåãããªãå Ž
åããããã®æåã¯95ïŒïŒéééšãïŒïŒ95éé
éšãç¹ã«20ïŒ80éééšã80ïŒ20éééšã®éæ¯ã§æ··
åç©äžã«ååšããããšãã§ããã ïŒçš®ä»¥äžã®æææåãæ··åç©äžã«ååšããå Ž
åãåã ã®ææã¯æ··åç©ã®å šééã«å¯ŸããŠïŒéé
ïŒ ãäžããªãã æ¬çºæã«ããããããæææ··åç©ã¯ãåŒ
ïŒïŒïŒ ãæããïŒçš®ã®ææããæãããã®å Žåãããã®
ïŒçš®ã®ææã¯ããããïŒBrãX1ïŒïŒšãåã³ïŒ·
ïŒBrãX1ïŒã¡ããã·ã§ããã æ¬çºæã«ããä»ã®ããããæææ··åç©ã¯ããã
ãããBrã§ãããã€X1ãã§ããåŒïŒïŒã®
ææãåã³ïŒ·ãBrã§ãããã€X1ããšããã·ã§ã
ãåŒïŒïŒã®ææã®ïŒçš®ã®ææããæãã æŽã«ãæ¬çºæã«ããä»ã®ããããæææ··åç©
ã¯ããããããClã§ãããã€X1ãã§ããåŒ
ïŒïŒã®ææãåã³ïŒ·ãClã§ãããã€X1ãã¡ãã
ã·ã§ããåŒïŒïŒã®ææã®ïŒçš®ã®ææããæãã æŽã«ãæ¬çºæã«ããä»ã®ããããæææ··åç©
ã¯ããããããClã§ãããã€X1ãã§ããåŒ
ïŒïŒã®ææãåã³ïŒ·ãClã§ãããã€X1ããšãã
ã·ã§ããåŒïŒïŒã®ææã®ïŒçš®ã®ææãããªãã æŽã«æå©ã«ã¯ãå ã«å®çŸ©ããããããã®æ··åç©
ã«ãããŠX1ãã§ããåŒïŒïŒã®ææåã³X1ã
ã¡ããã·åã¯ãšããã·ã§ããåŒïŒïŒã®ææã¯ã
ããããéæ¯ãçŽïŒïŒïŒéééšãçŽïŒïŒïŒéééš
ã®éã«ããã¹ãã§ããã ç¹ã«ããBrã§ãããã€X1ãã§ããåŒ
ïŒïŒã®ææãåã³ïŒ·ãBrã§ãããã€X1ãã¡ãã
ã·ã§ããåŒïŒïŒã®ææãããããçŽïŒïŒïŒéé
éšã®éæ¯ã§ååšããåŒïŒïŒã®ïŒçš®ã®ææãããª
ãæ··åç©ãããããŠããã æ¬çºæã®ä»ã®ç¹åŸŽã«ããã°ãåŒïŒïŒïŒ ãåŒäžãããåã³ïŒºã¯åèšã®ãã®ãè¡šã
ããã§ç€ºãããã«ãããªã³ã°æåå°ãªããšãïŒçš®
ããæãæ··åç©ããåŒïŒïŒïŒ ãåŒäžãã¯åèšã®ãã®ãè¡šãããã§ç€ºãããã¢
ãã³ã®ãžã¢ãŸåã«ããåŸãããå°ãªããšãïŒåã®
ãžã¢ãŸããŠã ååç©ãšã«ãããªã³ã°ããããã®é
ã«ãããªã³ã°æåã®æ··åç©ã¯ïŒžãæ°ŽçŽ ã§ããæå
å°ãªããšãïŒçš®ãšïŒžãOR1ã§ããæåå°ãªããšã
ïŒçš®ãšãå«ãããšãããªãåŒ(A)ã(B)ã®åæ£ã¢ãã¢
ãŸæææ··åç©ã®è£œé æ³ãåŸãããã ïŒåã®ãžã¢ãŸããŠã ååç©ãåèšæ¹æ³ã§äœ¿çšã
ãå Žåã該ååç©ã¯å¥åã«åã¢ãã³ããžã¢ãŸåã
ãã€ããããŠåŸããããžã¢ãŸããŠã ååç©ãåæ
ã«ãåã¯é£ç¶ããŠã«ãããªã³ã°æåã®æ··åç©ã«å
ããããšã«ãã䜿çšããããåã¢ãã³ãæ··åç©ã®
圢ã§ãžã¢ãŸåãã次ã«ããããŠåŸãããæ··åãžã¢
ãŸããŠã ååç©ãã«ãããªã³ã°æåã®æ··åç©ã«å
ãããããããã¯åã ã«è£œé ãããžã¢ãŸããŠã å
åç©ããã«ãããªã³ã°æåã®æ··åç©ã«å ããåã«
äžç·ã«æ··åããããšãã§ããã åŒïŒïŒã®ã¢ãã³ã¯ãïŒã»ïŒâãžãããâïŒâ
ã¯ãã«ã¢ããªã³åã¯ïŒã»ïŒâãžãããâïŒâãã
ã ã¢ããªã³ã§ããããšãã§ããã åŒïŒïŒã®ã«ãããªã³ã°æåã®äŸã¯ãïŒâã¢ã»
ãã«ã¢ããâïŒâã¡ããã·âã»ïŒ®âãžãšãã«ã¢
ããªã³ãã»ïŒ®âãžãšãã«âïœâã¢ããã¢ã»ãã¢
ããªãã§ããããžã¢ãŸååã³ã«ãããªã³ã°ã¯ã該
åå¿ã«äœ¿çšãããåžžæ³ã§å®æœããããšãã§ããã
ããªãã¡ãã¢ãã³åã¯åŒïŒïŒã®ã¢ãã³ã®ãžã¢ãŸ
åã¯ãå ¬ç¥æ¹æ³ã§ãããã·ã«ç¡«é žäžã§å®æœããã
ãšãã§ãã次ã«åŸããããžã¢ãŸååç©ã®æº¶æ¶²ãæ°Ž
äžãããã¯æ°Žãšæ··åå¯èœã®ææ©æ¶²äœãšæ°Žãšã®æ··å
ç©äžã®ã«ãããªã³ã°æåã®æº¶æ¶²åã¯æžæ¿æ¶²ã«å
ããå¿ èŠã«å¿ããŠã«ãããªã³ã°åå¿ãä¿é²ããã
ããã«æ··åç©ã®PHã調ç¯ããæåŸã«åŸãããææ
ãåžžæ³ã§åé¢ããã åèšããæ··åã«ãããªã³ã°æååã³åç¬ã®ãžã¢
ãŸæååã¯ãžã¢ãŸæåæ··åç©ããæ¬çºæã«ããæ
ææ··åç©ã補é ãã以å€ã«ããã®æ··åç©ã¯åŒ
ïŒïŒã®ã¢ãã³åã³åŒïŒïŒã®ã«ãããªã³ã°æå
ããæ®éã®ãžã¢ãŸååã³ã«ãããªã³ã°åå¿ã«ãã€
ãŠåŸãããåã ã«è£œé ããæææåãäžç·ã«æ··å
ããããšã«ãã€ãŠãåŸãããšãã§ããã 該ææã¯ãåžžæ³ã§ãäŸãã°æ°Žãªãã³ã«é©åœãªå
æ£å€äŸãã°ããã¿ãªã³âïŒâã¹ã«ãã³é žïŒãã«ã
ã¢ã«ãããçž®åç©ã®ãããªãŠã å¡©ã§ææãç²ç ã
ãããšã«ãã€ãŠè£œé ãããæ°Žåæ£æ¶²ã®åœ¢ã§æ°Žæ§æµž
ææ³ãããžã³ã°æ³åã¯æºææ³ã«ããããªãšã¹ãã«
ç¹ç¶ææã«æœããããšãã§ãã該æè²æ³ã¯æ¬çºæ
ã®ä»ã®ç¹åŸŽãæ§æããã æ¬çºæã«ããæææ··åç©ã¯è³éŠæããªãšã¹ãã«
ç¹ç¶ææã«æ¿çŽºè²ã®è²çžãçããããããã¯ææ
æ··åç©ã®ä»»æã®åç¬æåã該ææã«æœããããšã«
ãã€ãŠéæãããçµæãããããããŠããã極ã
ãŠè¯å¥œãªæçæ§åã³é«ãçè²åãæããã æŽã«ãæ¬çºæã®ä»ã®ç¹åŸŽã«ãã€ãŠãå ã«å®çŸ©ã
ãïŒçš®ä»¥äžã®åæ£ã¢ãã¢ãŸææã®æ··åç©ãæ°Žæ§æµž
ææ³ãããžã³ã°æ³åã¯æºææ³ã§è³éŠæããªãšã¹ã
ã«ïŒã»ã«ããŒã¹æ··çŽ¡ã«æœããããšãããªã該混玡
ã®æè²æ³ãåŸãããã åšç¥ã®ããã«ãããªãšã¹ãã«ïŒã»ã«ããŒã¹æ··çŽ¡
ã®ããªãšã¹ãã«æåã¯åæ£ææã§æè²ããããšã
ã§ãããã該ææã¯ãç¹ã«ããžã³ã°æ³åã¯æºææ³
ã§æœããå Žå該ææãã»ã«ããŒã¹æåã«ãä»çã
ããšããæ¬ ç¹ãæãããåæ£ææã¯ã»ã«ããŒã¹æ
æã«å¯ŸããŠäœãå ç¢æ§ãæããããšãããã»ã«ã
ãŒã¹ãçè²ããæææåã¯å®¹æã«æŽæµé€å»ããã
æ¥å ã«ããããéæ¥éã«éè²ããããã®çµæãšã
ãŠããã®ããã«çè²ãããããªãšã¹ãã«ïŒã»ã«ã
ãŒã¹æ··çŽ¡ã¯ãã»ã«ããŒã¹äžã®ææã解é¢ãããã
ãã«å ããªå ç¢æ§ãæããã«ãããªãã該çè²æ··
玡ãæ倧ã®å ç¢æ§ãæããããã«ã¯ãéåºçææ
ãé€å»ããããšãååã§ãããããã¯ãæ®éçè²
混玡ã®âéå æŽæµâåŠçïŒããªãã¡ãã€ãããµã«
ãã¢ã€ãã®ç±ãã¢ã«ã«ãªæ°Žæº¶æ¶²äžã§ã®åŠçïŒã«ã
ã€ãŠéæããããããããâéå æŽæµâåŠçã«ã
ã€ãŠçãã液äœã®åŠçã¯ãéå å€ãååšããããš
ããçæ åŠçè«žåé¡ãæ¹èµ·ãããæŽã«éå æŽæµåŠ
çã¯ã混玡ã®ã»ã«ããŒã¹æåã該åŠçã«ææãªæ
æã§æè²ãããåŸã«ãã€ãŠã¯äœ¿çšããããšãã§ã
ãªãã æŽã«ãâéå æŽæµâåŠçãå®æœããªããšãäŸã
ã°æ®éã®æŽæ¿¯åŠçã§é€å»ãããä»»æã®ææããç¹
ã«æºææ³ã®å Žåã«ãããã¯ã»ã¹ãã€ãã³ã°ãçã
ãããããšãããä»ã®ããªã³ãéšåã®æ±æåã¯æ
ãè²èª¿ãçããã äžèšããç·åé¡ã¯ãå ã«å®çŸ©ããåæ£ã¢ãã¢ãŸ
æææ··åç©ã䜿çšããããšã«ãã€ãŠæå°éã«çã
ããããã®çµæ混玡ã®ã»ã«ããŒã¹æåæ±æã¯æå°
ã«ãªãã 該æ¹æ³ã¯ãããªãšã¹ãã«ïŒã»ã«ããŒã¹æ··çŽ¡ãã
å ã«å®çŸ©ããïŒçš®ä»¥äžã®ã¢ãã¢ãŸææã®æ°Žåæ£æ¶²
ãããªããç¹ã«éã€ãªã³ãã«ããªã³åã³ïŒåã¯ã¢
ããªã³çé¢æŽ»æ§å€ãå«æããæ济äžã«æµžæŒ¬ããã
ã®åŸã«è©²æ济ãäžå®æéé©åœãªæž©åºŠã§å ç±ããã
ãšã«ãã€ãŠå®æœããããšãã§ããã浞ææ³ã¯æž©åºŠ
95âã100âã§ãç¹ã«ãžããšãã«ãïœâãããã
ã·ãžããšãã«ãã¡ãã«ããã¿ãªã³ããµãªãã«é žã¡
ãã«åã¯ããªã¯ãã«ãã³ãŒã³ã®ãããªãã€ãªã€ãŒ
ã®ååšäžã«å®æœããããšãã§ãããã枩床120â
ã140âã§éå§äžã«å®æœããããšãã§ããã æ¬çºææ¹æ³ã¯ãå ã«å®çŸ©ããïŒçš®ä»¥äžã®åæ£ã¢
ãã¢ãŸææã®æ°Žåæ£æ¶²ãããªãšã¹ãã«ïŒã»ã«ããŒ
ã¹æ··çŽ¡ã«ããžã³ã°ãã次ã«è©²ææã枩床100âã
180âã§çæéã¹ããŒãã³ã°ããããåã¯æž©åºŠ160
âã220âã§ããŒãã³ã°åŠçããŠæ··çŽ¡ã«åºçãã
ãããšã«ãã€ãŠå®æœããããšãã§ãããå¿ èŠã«å¿
ããŠããžã³ã°æ¶²ã¯æ®éã®æ·»å å€ãäŸãã°åæ£å€ã
æ¿çš åå€ã移æé²æ¢å€åã¯å°¿çŽ ãå«æããããšã
ã§ããã ïŒçš®ä»¥äžã®åæ£ã¢ãã¢ãŸææãåæ£ãã圢ã§å«
æããæ¿çš æºæç³ãæœããä»ã®æ¹æ³ãšããŠãæºæ
ç³ãç¹ç¶ææã«æœããã®ã«é垞䜿çšãããä»»æã®
æ¹æ³ã«ãã€ãŠããäŸãã°ãããã¯ãŒãã¹ã¯ãªãŒã³
âåã¯ããŒã©ãŒæºæã«ãã€ãŠããªãšã¹ãã«ïŒã»ã«
ããŒã¹æ··çŽ¡ã®è¡šé¢ã«æœããããšãã§ããã次ã«ã
ããªã³ãããç¹ç¶ææããå Žåã«ãã€ãŠã¯ä¹Ÿç¥ã
ãåŸã«æž©åºŠ100âã180âã§çæéã¹ããŒãã³ã°ã
ãããåã¯æž©åºŠ160âã220âã§ããŒãã³ã°ããã
æºæç³äžã«ååšããé©åœãªæ¿çš åå€ã¯ããã©ã¬ã«
ã³ããŽã ãã¢ã©ãã¢ãŽã ãã¢ã«ã®ã³é žå¡©ãäŸãã°
ã¢ã«ã®ã³é žãããªãŠã åã¯ã¢ã«ã®ã³é žã¢ã³ã¢ããŠ
ã ãæ°Žäžæ²¹åãšãã«ãžãšã³åã¯æ²¹äžæ°Žåãšãã«ãž
ãšã³ããããã¯ãšãã¬ã³ïŒç¡æ°Žãã¬ã€ã³é žå ±éå
äœåã¯ããªã¢ã¯ãªã«é žãããŒã¹ãšããåææ¿çš å
å€ãå å«ããã該æºæç³ã¯ãå°¿çŽ ãïœâãããã
ã³ãŒã³ã¹ã«ãã³é žãããªãŠã ããžã€ããã皮皮ã®
ææã®åºçãè£å©ããé žåã¯ã¢ã«ã«ãªã®ãããªæ®
éã®æ·»å å€ãå«æããããšãã§ããã 浞ææ³ãããžã³ã°æ³åã¯æºææ³ãå®æœããåŸã
æè²ãããç¹ç¶ææã次ã«æ°ŽæŽããã æ¬çºææ¹æ³ã§äœ¿çšãããè³éŠæããªãšã¹ãã«ïŒ
ã»ã«ããŒã¹æ··çŽ¡ã¯ãè³éŠæããªãšã¹ãã«ç¹ç¶ãšã»
ã«ããŒã¹ç¹ç¶ãšã®æ··åç©ã§ããä»»æã®ç¹ç¶ææã§
ããããšãã§ããããã®ãããªæ··çŽ¡ã¯ãæ®éç·š
ç©ãåã¯æå©ã«ã¯ç¹ç©ã®åœ¢ã§ãããè³éŠæããªãš
ã¹ãã«ç¹ç¶ã®å²åã¯ã混玡ã®ééã«å¯ŸããŠ20éé
ïŒ ã95ééïŒ ãæå©ã«ã¯30ééïŒ ã85ééïŒ ã®ç¯
å²å ã«ãããè³éŠæããªãšã¹ãã«ç¹ç¶ã¯ç¹ã«ããª
ãšãã¬ã³ãã¬ãã¿ã¬ãŒãç¹ç¶ã§ãããã»ã«ããŒã¹
ç¹ç¶ã¯ç¹ã«ç¶¿ç¹ç¶ãäºéº»ç¹ç¶ããã¹ã³ãŒã¹ã¬ãŒãš
ã³ç¹ç¶åã¯ããªããžãã¯ã¬ãŒãšã³ç¹ç¶ã§ããã å ã«å®çŸ©ããåæ£ã¢ãã¢ãŸæææ··åç©ãæ¬çºæ
æ¹æ³ã§äœ¿çšããå Žåãããªãšã¹ãã«ïŒã»ã«ããŒã¹
混玡ã®è³éŠæããªãšã¹ãã«éšã¯ã混玡ã®ã»ã«ããŒ
ã¹éšã«å¯ŸããŠããããé²ææ§ã§æ¿çŽºè²ã«æè²ãã
ããããªãã¡ã»ã«ããŒã¹éšã¯æè²ãããªãããå
ã¯æ®ãã©æè²ãããã«æ®ããå Žåã«ãã€ãŠã¯çã
ããã»ã«ããŒã¹ã®å ããªæ±æã¯æ®éã«äœ¿çšããã
åŠçãããèããç©ããªâéå æŽæµâåŠçã§é€å»
ããããšãã§ããåŸã€ãŠå ã®æµåºåŠçåé¡ã¯çžå¿
ããŠæžå°ããã æ¬çºææ¹æ³ã¯ãè³éŠæããªãšã¹ãã«åã³ã»ã«ã
ãŒã¹ãå«æãã混玡ã®æè²ã«æœããããšãã§ãã
ãã®å Žåå ã«å®çŸ©ããåæ£ã¢ãã¢ãŸæææ··åç©ã¯
ã»ã«ããŒã¹çšã®ïŒçš®ä»¥äžã®é©åœãªçè²å€ãšçµåã
ãŠæœãããããã®åŠçã¯æ¬çºæã®ä»ã®ç¹åŸŽãæ§æ
ããã ããªãšã¹ãã«ïŒã»ã«ããŒã¹æ··çŽ¡ã®ã»ã«ããŒã¹éš
ã«å¯Ÿããé©åœãªçè²å€ã¯ãçŽæ¥ææããããæ
æãç¡«åææãããããŒã«ææãåã¯åå¿ææã§
ããã 混玡ã®è³éŠæããªãšã¹ãã«éšçšã®åæ£ã¢ãã¢ãŸ
æææ··åç©ãªãã³ã«æ··çŽ¡ã®ã»ã«ããŒã¹éšçšã®äžèš
ããçš®é¡ã®ïŒã€ããæãçè²å€ã¯ãäžè¬ã«åžžæ³ã§
åæã«åã¯é£ç¶çã«æœããããšãã§ããã æ¬çºæã§äœ¿çšããææã¯ãå šãŠã®åžžæ³ã§åã³ã»
ã«ããŒã¹çšã®å šãŠã®çš®é¡ã®ææãšäžç·ã«ããªãšã¹
ãã«ïŒã»ã«ããŒã¹æ··çŽ¡ã«æœããããšãã§ãããã
該ææã®ç¹ã«åªããå©ç¹ã¯ããããè¯å¥œãªã»ã«ã
ãŒã¹é²ææ§ãæããããšãããéå æŽæµåŠçãå«
ãŸãªãæ¹æ³ã䜿çšããŠé«ãå ç¢åºŠã®æè²ãåŸãã
ãããšã§ããããã®ããšã¯ãäžèšã«äŸç€ºãããã
ã«ç°¡åãã€çµæžçãªæ¹æ³ã®äœ¿çšãå¯èœãšããã ããªãã¡ãããªãšã¹ãã«ïŒã»ã«ããŒã¹ææã¯ã
åæ£ææåã³åå¿ææãæãã液äœã§ããžã³ã°
ãã也ç¥ããé«æž©ã§ããŒãã³ã°åã¯ã¹ããŒãã³ã°
ããŠåæ£ææãããªãšã¹ãã«æåã«åºçãããã¢
ã«ã«ãªæ°Žæº¶æ¶²äžã§ããžã³ã°ããã¹ããŒãã³ã°ããŠ
åå¿ææãã»ã«ããŒã¹æåã«åºçãããæŽæµãã
也ç¥ããããšãã§ããã ããžã³ã°æ¶²ã¯ã¢ã«ã«ãªãå«æããããšãã§ãã
åå¿ææã®åºçã¯ããŒãã³ã°åã®ä¹Ÿç¥éçšã§éæ
ãããåŸã€ãŠã¢ã«ã«ãªãããã¹ããŒã åŠçã®å¿ èŠ
æ§ãåé¿ããããšãã§ããã ãããæ³ã§åŠçããå Žåãããªãšã¹ãã«æåã¯
ä»»æã®åžžæ³ã§ç©ããªéå æŽæµåŠçãè¡ãªããåã¯
ãã®åŠçãå¿ èŠãšããªã浞ææ³ã§æè²ãã次ãã§
ã»ã«ããŒã¹æåã¯ã»ã«ããŒã¹çšã®ä»»æã®çš®é¡ã®æ
æã䜿çšããŠä»»æã®æ¹æ³ã§æè²ããããšãã§ã
ãã ãŸãã»ã«ããŒã¹æåãåå¿ææã§æè²ãã該æ
æãäžæ§ã«ãªããŸã§æ°ŽæŽããã次ã«ããªãšã¹ãã«
æåãå§åäžã«ããããã¯ãã€ãªã€ãŒãçšããŠå¥
åã®æ济äžã§åæ£æææ··åç©ã§æè²ããæŽæµããŠ
也ç¥ããããšãã§ããããŸãã»ã«ããŒã¹ããŸãå
å¿ææã§æè²ãããã®åŸã«åæ£æææ··åç©ã浞æ
济ã«å ããPHã調ç¯ããä»»æã®å©å€ãå ããããª
ãšã¹ãã«æåããã€ãªã€ãŒãšäžç·ã«æ²žéš°ãããå
ã¯å§åäžã§æè²ããã æ¬çºææ¹æ³ã§äœ¿çšãããåå¿ææã¯ãå°ãªããš
ãïŒåã®ç¹ç¶åå¿åºãå«æããä»»æã®æ°Žæº¶æ§ææ
ã§ãã€ãŠããããã®åºã¯ãææååäžã«ååšãã
ããšã«ãã該ææãã»ã«ããŒã¹ç¹ç¶ææäžã«ååš
ããããããã·åºãšååŠçã«çµåå¯èœã«ãããã®
çµæææååãïŒå以äžã®å ±æååŠçµåãä»ããŠ
ã»ã«ããŒã¹ååã«çµåãããåºãšããŠå®çŸ©ãã
ããåç¹ç¶åå¿åºã¯ææååäžã«ååšããççŽ å
åã«çµåããŠãããæå©ã«ã¯ææååäžã«ååšã
ãè³éŠæç°ãç¹ã«ãã³ãŒã³ç°ã®ççŽ ååã«çµåã
ãŠããã該ææã¯ãç¹ã«å°ãªããšãïŒåã®ç¹ç¶å
å¿åºãæãããã¢ãã¢ãŸåã³ããªã¢ãŸãå«ãã¢ãŸ
ç³»åã³å«éå±ã¢ãŸææãã¢ã³ãã©ããã³ããã«ã
ã¶ã³ãããªããšã³ãžãªããµãžã³ããããåã³ãã¿
ãã·ã¢ãã³ç³»ã®ææã§ããã ç¹ç¶åå¿åºã®äŸãšããŠã¯ãã¢ã¯ãªãã€ã«ã¢ãã
åã³ã¯ãããã«ã¢ããã®ãããªãªã¬ãã€ã³æ§äžé£œ
åèèªæã«ã«ãã³é žããããã¯Î²âã¯ãã«ããã
ãªãã«ã¢ãããβâããã ããããªãã«ã¢ããã
βïŒÎ³ïŒÎ³âããªã¯ãã«ã¯ãããã«ã¢ããåã³ã
ãã©ãã«ãªã«ã·ã¯ãããã«ã¢ã¯ãªãã€ã«ã¢ããã®
ãããªããã²ã³çœ®æèèªæã«ã«ãã³é žããèªå°ã
ããã¢ã·ã«ã¢ããåºãæãããããç¹ç¶åå¿åº
ã¯ãéžæçã«ããã«ã¹ã«ãã³ãβâã¯ãã«ãšãã«
ã¹ã«ãã³ãβâã¹ã«ããšãŒããšãã«ã¹ã«ããã«ã
βâã¯ãã«ãšãã«ã¹ã«ãã³ã¢ããåã¯ïŒ®â眮æã
ããŠããŠãããβâã¢ãããšãã«ã¹ã«ããã«åºã§
ããããšãã§ããã ç¹ç¶åå¿åºã¯ãæå©ã«ã¯è€çŽ ç°åŒäžã®ïŒååã¯
ïŒåã®çªçŽ ååãªãã³ã«è€çŽ ç°åŒç°ã®ççŽ ååã«
çµåããå°ãªããšãïŒåã®ã¬ã€ãã«çœ®æåºãæã
ãè€çŽ ç°åŒåºã§ãããã¬ã€ãã«çœ®æåºã®äŸãšããŠ
ã¯ãå¡©çŽ ãèçŽ ãåŒçŽ ã第ïŒçŽã¢ã³ã¢ããŠã åºã
ããªã·ã¢ããã¹ã«ãã³é žããããã«ã«ãã«ã¹ã«ã
ãã«åºãåŒãåŒããäœããçªçŽ ååã¯çœ®æã ããŠãããçåæ°ŽçŽ åºåã¯è€çŽ ç°åŒåºãæããã
ã®åºããªãã³ã«åŒïŒ ãäœããç Žç·ã¯çœ®æãããŠããŠãããããåã¯çž®
åè€çŽ ç°åŒç°ã圢æããã®ã«å¿ èŠãªååãè¡šãã
ãŠãããã®åºãæããããã ãã®ãããªç¹ç¶åå¿è€çŽ ç°åŒåºã®è©³çŽ°ãªäŸãšã
ãŠã¯ãïŒïŒïŒâãžã¯ãã«ããªããžã³âïŒâã«ã«ã
ãã«ã¢ãããïŒïŒïŒâãžã¯ãã«ããããµãªã³âïŒ
âåã¯ïŒâïŒã¹ã«ããã«åã¯ã«ã«ããã«ïŒã¢ã
ããïŒïŒïŒâãžã¯ãã«ãããŸãªã³âïŒâåã¯ïŒâ
ã¹ã«ããã«ã¢ãããïŒïŒïŒïŒïŒâããªã¯ãã«ãã
ãŸãªã³âïŒâåã¯ïŒâã¹ã«ããã«ã¢ãããïŒïŒ
ïŒïŒïŒâåã¯ïŒïŒïŒïŒïŒâããªã¯ãã«ãããŸãªã³
âïŒâã¹ã«ããã«ã¢ãããïŒïŒïŒâãžã¯ãã«ãã
ãŸãªã³âïŒâã«ã«ããã«ã¢ãããïŒïŒïŒâãžã¯ã
ã«ãã¿ã©ãžã³âïŒâã«ã«ããã«ã¢ãããïŒïŒïŒâ
ãžã¯ãã«ããªããŸã³âïŒâã€ã«ã¢ãããïŒïŒïŒâ
ãžã¯ãã«ããªããâïŒâã€ã«âã«ã«ããã«ã¢ã
ããïŒâïŒããšãã«â4â²âã«ã«ããã«ã¢ããïŒâ
ïŒïŒïŒâãžã¯ãã«ããªããŸã³ãïŒïŒïŒâåã³ïŒå
ã¯ïŒïŒïŒâãžã¯ãã«âåã¯ããã âããªãâïŒâ
ïŒåã³ïŒåã¯âïŒïŒã€ã«ã¢ããããžãã«ãªã«ã¯ã
ã«ããªããžã«ã¢ãããããªã¯ãã«ããªããžã«ã¢ã
ããããªããã ããªããžã«ã¢ããããžã¯ãã«âïŒ
âïŒã·ã¢ããããããã¡ãã«åã¯ã«ã«ãã¡ãã
ã·ïŒããªããžã«ã¢ãããïŒâã¡ãã«ã¹ã«ããã«â
ïŒâã¯ãã«ããªããâïŒâã€ã«ã«ã«ããã«ã¢ãã
åã³ïŒâã¯ãã«âïŒâã¡ãã«âïŒâã¡ãã«ã¹ã«ã
ãã«ããªããâïŒâã€ã«ã¢ãããåã³ç¹ã«åŒçŽ å
ååã¯èçŽ ååããªããããå¡©çŽ ååãïŒäœåã³
ïŒäœã®å°ãªããšãïŒã€ã«å«æããïŒïŒïŒïŒïŒâã
ãªã¢ãžã³âïŒâã€ã«ã¢ããåºãäŸãã°ïŒïŒïŒâãž
ã¯ãã«âïŒïŒïŒïŒïŒâããªã¢ãžã³âïŒâã€ã«ã¢ã
ããæãããããããªã¢ãžã³æ žãïŒåã®ããã²ã³
ååãç¹ã«å¡©çŽ ååã®ã¿ãå«æããå Žåãããªã¢
ãžã³ç°ã®ç¬¬ïŒççŽ ååã¯ãã¡ãã«åã¯ããšãã«ã®
ãããªçåæ°ŽçŽ åºã«ãã€ãŠã詳述ããã°çœ®æãã
ãŠããŠãããããããã·åºãã¡ã«ã«ããåºåã¯ã¢
ããåºäŸãã°ã¡ããã·ãããšããã·ãαâåã³Î²
âããããã·ãã¡ãã«ã¡ã«ã«ãããããšãã«ã
ãªãã¡ãã«ã¢ããããžãšãã«ã¢ãããã·ã¯ããã
ã·ã«ã¢ãããåã³ã¢ããªã䞊ã³ã«ïŒ®âã¢ã«ãã«ã¢
ããªãåã³ãã®çœ®æèªå°äœäŸãã°ã¢ãã·ãžããã
ã«ã€ãžããã«ã«ããã·ã«ã¢ããªããã¹ã«ãã¢ããª
ãããžã¹ã«ãã¢ããªãåã³ã¹ã«ãã³åãããã«ã¢
ããã«ãã€ãŠçœ®æããããšãã§ããã ããããŠãããããçš®é¡ã®åå¿ææã¯ãç¹ç¶å
å¿åºãšããŠåŒïŒ ãåŒäžãïœã¯ïŒåã¯ïŒã§ãããã¯å¡©çŽ ååã眮
æãããŠããŠãããã¢ããåºåã¯ãšãŒãã«åãã
ããã·ã«åºã§ãããã§ç€ºãããåºãå«æãã該æ
æãããªãã ã§è¡šãããã眮æãããŠããŠãããã¢ããåº
ã¯ãç¹ã«çœ®æãããŠããŠãããã¢ã«ãã«ã¢ãã
åºãã¢ããªãåºãåã¯ïŒ®âã¢ã«ãã«ã¢ããªãåºã
äŸãã°ã¡ãã«ã¢ããããšãã«ã¢ãããβâããã
ãã·ãšãã«ã¢ããããžïŒÎ²âããããã·âãšã
ã«ïŒã¢ãããβâã¡ããã·ãšãã«ã¢ãããβâã¹
ã«ããšãŒããšãã«ã¢ãããïœâãïœâåã³ïœâã¹
ã«ãã¢ããªããïŒâåã³ïŒâã¹ã«ãâïŒâã¡ãã
ã·ã¢ããªããïŒâåã³ïŒâã¹ã«ãâïŒâã¡ãã«ã¢
ããªããïŒâåã³ïŒâã¹ã«ãâïŒâã¯ãã«ã¢ããª
ããïŒâåã³ïŒâã¹ã«ãâïŒâã¯ãã«ã¢ããªãã
ïŒã»ïŒâãïŒã»ïŒâåã³ïŒã»ïŒâãžã¹ã«ãã¢ããª
ããâã¡ãã«âïœâåã³ïœâã¹ã«ãã¢ããªãã§
ããã å¿ èŠã«å¿ããŠãç¹ç¶åå¿åºã¯æ¬¡åŒã§ç€ºãããšã
ã§ããïŒ âNHâJ1âïŒâJ2 åŒäžãJ1ã¯å Žåã«ãã€ãŠã¯ã¬ã€ãã«çœ®æåºãæ
ããŠããŠãããããªããžã³ç°åã¯ããªã¢ãžã³ç°ã§
ãããJ2ã¯å°ãªããšãïŒåã®ã¬ã€ãã«çœ®æåºãæ
ããããªããžã³ç°åã¯ããªã¢ãžã³ç°ã§ãããïŒã¯
眮æãããŠããŠãããã€ããåºïŒè©²ã€ããåºã¯ã
ãšãã¬ã³ãïŒïŒïŒâããšãã¬ã³åã¯ïŒâã¹ã«ãâ
ïŒïŒïŒâããšãã¬ã³ã®ãããªã¢ã«ãã¬ã³åºåã¯ã¢
ãªãŒã¬ã³åºãä»ããŠäžç·ã«çµåããŠããïŒãä»ã
ãŠJ1åã³J2ãšçµåããŠããæ¶æ©å¡ã§ããã ïŒã§è¡šããããç¹ã«éèŠãªä»ã®çµååºã¯ãåã
ã³ãŒã³æ žäžã«ã¹ã«ãã³é žåºãå«æãããã¹ãã«ã
ã³ããžããšãã«ããžããšãã«ãªãã·ãããžããšã
ã«ã¢ãã³ããžããšãã«å°¿çŽ ããžããšããã·ãšã¿ã³
åã³ãžããšãã«ã¢ããâïœâããªã¢ãžã³ã®ïŒäŸ¡ã®
åºã§ããã æå©ã«ã¯ãJ1åã³J2ãããããã¯ãã«âïœâã
ãªã¢ãžã³åºãè¡šããã¹ãã§ãããããªãã¡ãåå¿
ææã®ä»ã®çš®é¡ã¯ãç¹ç¶åå¿åºãšããŠæ¬¡åŒã®åºã
å«æããææãããªãïŒ åŒäžãïœãïœåã³ïœã¯ãããããç¬ç«ã«ïŒåã¯
ïŒã§ãããïŒåã³ïŒ±ã¯åèšã®ãã®ãè¡šããã åèšããããã«ïŒ±åºã¯ãå®çŸ©ããç¯å²å ã§â
NHâåã¯ââãä»ããŠããªã¢ãžã³ç°ã®ççŽ å
åãšçµåããçºè²å£ç³»ãå«æããåºãå å«ããã ãã®ãããªåå¿ææã¯ãåžžæ³ã§äŸãã°ç¬¬ïŒçŽå
ã¯ç¬¬ïŒçŽã¢ããåºãå«æãã氎溶æ§ææãåèšã®
ç¹ç¶åå¿åºãå«æããååç©ãšåå¿ãããããšã«
ãã€ãŠåŸãããšãã§ããããã®ãããªååç©ã®äŸ
ãšããŠã¯ãå¡©åã¢ã¯ãªãã€ã«ãå¡©åã·ã¢ãã«ã
ïŒïŒïŒïŒïŒâããªã¯ãã«ããªããžã³ãïŒïŒïŒïŒïŒ
âããªã¯ãã«âïŒâïŒã·ã¢ãâåã¯ã¯ãã«âïŒã
ãªããžã³åã³ïŒâã¡ããã·âïŒïŒïŒâãžã¯ãã«â
ïŒïŒïŒïŒïŒâããªã¢ãžã³ãæããããã ä»ã®ããããåå¿ææã¯ãïŒå以äžã®çé žåºã
ç¹ã«ãã¹ãã³é žåºãå«æãããã®ã§ããã該ææ
ã¯è±åœç¹èš±æ现æžç¬¬1411306å·ã«èšèŒã®æ¹æ³ã«ã
ã€ãŠã»ã«ããŒã¹ç¹ç¶ææã«æœããããã ãã®çºææ¹æ³ã«ãããè³éŠæããªãšã¹ãã«ïŒã»
ã«ããŒã¹æ··çŽ¡ã¯ããã®çš®ã®ç¹ç¶ææã«æ®éã«æœã
ãããè©Šéšã«å¯ŸããŠããããå ç¢åºŠãæããçš®ã
ã®è²çžã«æè²ãããç¹ç¶ææã®ããªã³ããããªã
çœè²éšåã®ããããé²æãååšããã æ¬çºæã«ããç¹ã«ããããæ··åç©çšã®èŠå®ã®ã«
ãããªã³ã°æååã³ææã®è£œé æ³ã次ã«èšèŒã
ããâéšâã¯ç¹ã«èšèŒããªãéãâéééšâãè¡š
ããããéééšãšã®æ¯ã¯Kgãšãšã®æ¯ã§ããã ïŒâã¢ã»ãã«ã¢ããâïŒâã¡ãªãã·âã»ïŒ®âãž
ãšãã«ã¢ããªã³ã®è£œé ïŒâã¢ã»ãã«ã¢ããâïŒâã¡ããã·ã¢ããªã³18
éšãæ°Ž50容ééšäžã§æ¹æãããæ°Žé žåãããªãŠã
氎溶液ïŒãã¯ãã«åºŠTw70ãïŒãå ããŠãPHãïŒ
ã10ã«èª¿ç¯ããã該混åç©ã65âã«å ç±ããåæ£
å€ïŒããªã°ãªã»ããŒã«ãªã·ãã¬ãšãŒãã0.5éšïŒ
ãå ããåŒç¶ãçé žæ°ŽçŽ ãããªãŠã 29.4éšïŒã¢ã
ãªã³åºçºç©è³ªïŒã¢ã«ããã3.5ã¢ã«ïŒãå ããã
次ã«ããžãšãã«ã¹ã«ããšãŒã54éšïŒïŒã¢ã«ããã
3.5ã¢ã«ïŒã65âã§ïŒæéã«ãããå ãããåå¿
ã¯åŸã ã«é²è¡ããããžãšãã«ã¹ã«ããšãŒãã®æ·»å
åŸã65âã§ã®æ··åç©ã®æ¹æãããã«ïŒæéç¶ç¶ã
ããŠåå¿ãçµããããåå¿æ··åç©ã宀枩ã«å·åŽ
ããïŒâã¢ã»ãã«ã¢ããâïŒâã¡ããã·âã»ïŒ®
âãžãšãã«ã¢ããªã³ãéããæ°ŽïŒ500容ééšïŒã§
æŽæµãã70âã§ä¹Ÿç¥ããã ã»ïŒ®âãžãšãã«âïœâã¢ããã¢ã»ãã¢ããªã
ã¯åãæ¹æ³ã§ïœâã¢ããã¢ã»ãã¢ããªããã補é
ãããã X1ãã¡ããã·ã§ããåŒïŒïŒã®ææã®è£œé 100ïŒ ç¡«é ž70ïŒå®¹éïŒéšãæ°ŽïŒéšã«å ããã次
ã«ãäºç¡é žãããªãŠã ïŒéšãæ··åç©ã®æž©åºŠã70â
±ïŒâã«äžæããã€ãã®å€ã«ç¶æããããããªé
床ã§æ¹æããè©²é žã«æç¶çã«æ·»å ãããäºç¡é žã
ããªãŠã ã®æ·»å åŸã«ããã®æº¶æ¶²ãïŒæéæ¹æãã
ãã®é枩床ã¯å®€æž©ã«äœäžãããïŒã»ïŒâãžããã
âïŒâããã ã¢ããªã³26.2éšã25âã28âã§æ¹æ
ããäºç¡é žãããªãŠã 溶液ã«30åéå ãããæ·»å
çµäºåŸã«ã溶液ã宀枩ã§ïŒæéæ¹æããã ïŒâã¢ã»ãã«ã¢ããâïŒâã¡ããã·âã»ïŒ®â
ãžãšãã«ã¢ããªã³23.6éšãæ°Ž500éšäžã§æ¹æãã
æ¿å¡©é ž10容ééšãå ãããæ°·ããã®æº¶æ¶²ã«å ããŠ
枩床ãïŒâã«äœäžãããç¡æ°Žé ¢é žãããªãŠã ãå
ããŠPHãïŒãïŒã«èª¿ç¯ããã次ã«ããžã¢ãŸåïœâ
ãããã¢ããªã³ãšã®æ··åç©ãè©Šéšããéã«è¡šãã
ãéå°ã®ã«ãããªã³ã°æåã®çè·¡ã®ã¿ãæ®åãã
ããã«ãªããŸã§ããžã¢ãŸåã¢ãã³æº¶æ¶²ãïŒâåã³
PHïŒïŒæ°·ãšé ¢é žãããªãŠã ãšã®æ·»å ã«ãã€ãŠèª¿
ç¯ïŒã§30åé滎å ããã該混åç©ãïŒâãïŒâã§
ããã«15åéæ¹æããææãéããæ°Žã§æŽæµããŠ
ç¡æ©ã®äžçŽç©ãé€å»ããã該ææã沞隰ããŠãã
ã¢ã»ãã³ã«æº¶ããããã®æº¶æ¶²ãæ¿Ÿéããæ°·åã³æ°Ž
ãã¢ã»ãã³æº¶æ¶²ã«å ããããšã«ãã€ãŠææãåã³
æ²æ®¿ããããçæç©ãåã³éããæ°Žã§æŽæµãã70
âã§ä¹Ÿç¥ããã X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææã®è£œé ïŒã»ïŒâãžãããâïŒâããã ã¢ããªã³ïŒ26.2
éšïŒããžã¢ãŸåããå ã®è£œé æ³ã§èšèŒããããã«
ã»ïŒ®âãžãšãã«âïœâã¢ããã¢ã»ãã¢ããªã
20.6éšãšã«ãããªã³ã°ãããã æ¬çºæã次ã®å®æœäŸã«ãã€ãŠè©³èª¬ãããããã
ã«éå®ããããã®ã§ã¯ãªããå®æœäŸäžã®âéšâå
ã³âïŒ âã¯âéééšâåã³âééïŒ âã§ããã äŸ ïŒ ïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ããåŒ
ïŒïŒã®ææåã³ïŒ·ãBrã§ãããã€X1ãæ°ŽçŽ ã§ã
ãåŒïŒïŒã®ææãããã10éšãå¥åã«ãè¬å€
39.2ééïŒ åã³æ°Ž77.2éšãå«æããåæ£å€ïŒãã
ã¿ãªã³âïŒâã¹ã«ãã³é žïŒãã«ã ã¢ã«ãããçž®å
ç©ã®ãããªãŠã å¡©ïŒã®æ°Žæº¶æ¶²12.8éšã§åŸ®ç²ç ã
ãã48æé埮ç²ç ããåŸã«ãã®åæ£æ¶²äžã®åææ
ã®ç²åŸã¯ïŒãïŒãã¯ãã³ã§ããã äžèšã®ããã«ããŠåŸãããäž¡åæ£æ¶²ãããªãã¡
ãBrã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®æ
æã®10ïŒ æ°Žåæ£æ¶²0.3éšãªãã³ã«ïŒ·ãBrã§ããã
ã€X1ãã¡ããã·ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Ž
åæ£æ¶²0.075éšãæè²å®¹åšã«ç§»ããç·©è¡æ¶²0.5容é
éšãå ããåŒç¶ãããªãšã¹ãã«ç¹ç¶ææçïŒéšã
å ããã次ã«è©²æ济ãæ°Žã§50éšã«ããéå§äžã«
130âã§ïŒæéæè²ãè¡ãªããæè²çµäºåŸã«ãæ
è²ãããææããã€ãããµã«ãã¢ã€ãïŒéšãæ°Žé ž
åãããªãŠã 溶液ïŒãã¯ãã«åºŠTw70ãïŒïŒå®¹é
éšãåæ£å€ïŒå®¹ééšåã³æ°Ž490容ééšãããªãé
å æŽæµæµŽäžã§70âã§30åéæ¹æããã次ã«ã該ç¹
ç¶ãç³é¹žæº¶æ¶²äžã§ååã«æŽæµããæ°Žã§ååã«æŽã
äžããŠä¹Ÿç¥ããã ããªãšã¹ãã«ã¯ã極ããŠè¯å¥œãªæçæ§åã³é«ã
çè²åãæãããã€ããŒãã«ãŒè²ã«æè²ãããã äŸ ïŒ äŸïŒã«èšèŒããæè²æ³ãç¹°ãè¿ããããBr
ã§ãããã€X1ãã§ããåŒïŒïŒã®ææã®10ïŒ
æ°Žåæ£æ¶²ãªãã³ã«ïŒ·ãBrã§ãããã€X1ãã¡ãã
ã·ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Žåæ£æ¶²ãã次ã®
éã§äœ¿çšããïŒ ãè¡šã ãã®å Žåãããããããªãšã¹ãã«ç¹ç¶ææã«ã¯
æ¿ããã€ããŒãã«ãŒè²ãåŸãããã äŸ ïŒ äŸïŒã«èšèŒããæè²æ³ãç¹°ãè¿ããããBr
ã§ãããã€X1ãã¡ããã·ã§ããåŒïŒïŒã®ææ
ã®10ïŒ æ°Žåæ£æ¶²0.075éšãã次ã®åŒ(A)ã(B)ã®ææ
ã®ããããïŒã€ã®10ïŒ æ°Žåæ£æ¶²0.1éšã§ä»£æ¿ã
ãã次衚ã®ïŒ·ãããåã³ïŒ²ã¯ãåŒ(A)ã(B)ã«
èšèŒããã®ãšåããã®ãè¡šããã ãè¡šã äŸïŒã«èšèŒã®ããã«è³éŠæããªãšã¹ãã«ç¹ç¶æ
æã«æœãããå Žåæææ··åç©ã¯ãããããæ¿ãã
ã€ããŒãã«ãŒè²ãçããã äŸ ïŒ äŸïŒã«èšèŒããæè²æ³ãç¹°ãè¿ããããBr
ã§ãããã€X1ãã¡ããã·ã§ããåŒïŒïŒã®ææ
ã®10ïŒ æ°Žåæ£æ¶²0.075éšããåãææåæ£æ¶²0.1éš
ã§ä»£æ¿ãããŸããBrã§ãããã€X1ãæ°ŽçŽ ã§ã
ãåŒïŒïŒã®10ïŒ æ°Žåæ£æ¶²0.3éšã次ã®åŒ(A)ã(B)
ã®äžèšææã®ããããïŒã€ã®10ïŒ æ°Žåæ£æ¶²0.3éš
ã§ä»£æ¿ããã次衚ã®ïŒ·ãããåã³ïŒ²ã¯ãåŒ
(A)ã(B)ãšåããã®ãè¡šããã ãè¡šã äŸïŒã«èšèŒããããã«è³éŠæããªãšã¹ãã«ç¹ç¶
ææã«æœãããå Žååæææ··åç©ã¯ãããããæ¿
ããã€ããŒãã«ãŒè²ãçããã äŸ ïŒ ïŒ·ãBrã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®
ææã®10ïŒ æ°Žåæ£æ¶²0.3éšããBrã§ãããã€X1
ãã¡ããã·ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Žåæ£æ¶²
0.05éšãªãã³ã«ïŒ·ãBrã§ãããã€X1ããšããã·
ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Žåæ£æ¶²0.05éšãäž
ç·ã«æ··åãããäŸïŒã«èšèŒããæ¹æ³ã§è³éŠæããª
ãšã¹ãã«ç¹ç¶ææã«æœãããå Žå該混åç©ã¯ãæ¿
ããã€ããŒãã«ãŒè²ãçããã ãBrã§ãããã€X1ããšããã·ã§ããåŒ
ïŒïŒã®ææãããèçŽ ã§ããããã¡ããã·
ã§ãããåã³ïŒºãããããïœâãããã«ã§ã
ãããã€ïŒ²ãã¡ãã«ã§ããåŒ(A)ã(B)ã®ææã«ä»£ã
ãå Žåã«ãåãçµæãåŸãããã äŸ ïŒ ïŒ¹åã³ïŒºããããããšãã«ã§ããããã¡ãã«
ã§ããããã€ïŒ·åã³ïŒžã次ã®ãã®ãè¡šããåŒ(A)ã
(B)ã®ïŒçš®é¡ã®ææã®10ïŒ æ°Žåæ£æ¶²ãã次ã®éæ¯ã§
æ··åç©ãäœãã   Br  1.5éš Cl  1.5éš Br OCH3 0.5éš Cl OCH3 0.5éš äŸïŒã«èšèŒããæ¹æ³ã§è³éŠæããªãšã¹ãã«ç¹ç¶
ææã«æœãããå Žå該混åç©ã¯ãæ¿ããã€ããŒã
ã«ãŒè²ãçããã äŸ ïŒ ïŒã»ïŒâãžãããâïŒâããã ã¢ããªã³26.2éš
ãåèšããæ¹æ³ã§ãžã¢ãŸåããããããŠåŸããã
ãžã¢ãŸããŠã ååç©ããåèšããæ¹æ³ã§ïŒâã¢ã»
ãã«ã¢ããâïŒâã¡ããã·âã»ïŒ®ãžãšãã«ã¢ã
ãªã³6.0éšãšïŒ®ã»ïŒ®âãžãšãã«âïœâã¢ããã¢ã»
ãã¢ããªã15.4éšãšã®æ··åç©ãšã«ãããªã³ã°ãã
ããããããŠåŸãããæ··åç©ææãäŸïŒã«èšèŒã
ãããã«æ°Žåæ£æ¶²ã®åœ¢ã§è³éŠæããªãšã¹ãã«ç¹ç¶
ææã«æœãããå Žåãæ¿ããã€ããŒãã«ãŒè²ãç
ããã äŸ ïŒ äŸïŒã«èšèŒããæè²æ³ãç¹°ãè¿ããããBr
ã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææã®10
ïŒ æ°Žåæ£æ¶²0.3éšãããClã§ãããã€X1ãæ°ŽçŽ
ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Žåæ£æ¶²0.3éšã«ã
ã€ãŠä»£ãããŸããBrã§ãããã€X1ãã¡ããã·
ã§ããåŒïŒïŒã®ææã®10ïŒ æ°Žåæ£æ¶²0.075éš
ãã次ã®åŒ(A)ã(B)ã®ææã®ããããïŒã€ã®10ïŒ æ°Ž
åæ£æ¶²0.1éšã§ä»£æ¿ããã次衚ã®ïŒ·ããã
åã³ïŒ²ã¯ãåŒ(A)ã(B)ã«ããããšåããã®ãè¡šã
ãã ãè¡šã äŸ11ã«èšèŒããããã«è³éŠæããªãšã¹ãã«ç¹ç¶
ææã«æœãããå Žååæææ··åç©ã¯ãããããæ¿
ããã€ããŒãã«ãŒè²ãçããã äŸ ïŒ ããªãšã¹ãã«ïŒç¶¿ç¹ç¶ã®67ïŒ33ç¹ç©æ··çŽ¡ã次ã®
æ§é ã®ããã液äžã§ããžã³ã°ããããã®çµæ該æ
æã¯ããžã³ã°æ¶²ã®ééã®50ïŒ ãä¿æããïŒ ïŒ·ãBrã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®æ
æïŒ10ïŒ æ°Žåæ£æ¶²ãšããŠïŒ ïŒéš ãBrã§ãããã€X1ãã¡ããã·ã§ããåŒïŒïŒ
ã®ææïŒ10ïŒ æ°Žåæ£æ¶²ãšããŠïŒ ïŒéš å°¿ çŽ 10éš ãããã·ã«ïŒMatexilïŒFAâMIVïŒImperial
Chemical Industries Limitedããåžè²©ãããŠã
ã移ææå¶å€ïŒâMatexilâã¯ç»é²åæšã§ããïŒ
10éš ããã液1000éšãããçé žæ°ŽçŽ ãããªãŠã 10éš è©²ææã¯ãæå©ã«ã¯ããã¿ãªã³âïŒâã¹ã«ãã³
é žïŒãã«ã ã¢ã«ãããçž®åç©ã®ãããªãŠã å¡©ã®ã
ããªä¿è·å€éã®ååšäžã§ç²ç ããããæ°Žåæ£æ¶²ã®
圢ã§ããã ããžã³ã°åŠçãããææã110âã§30ç§é也ç¥
ãã210âã§60ç§éããŒãã³ã°ããç±æ°Žäžã§æ°ŽæŽ
ãããã·ã³ããããã¯ïŒSynperonicïŒBD
ïŒImperial Chemical Industries Limitedããåž
販ãããŠããåææŽå€ïŒâSynperonicâã¯ç»é²
åæšã§ããïŒïŒïœïŒãå«æãã溶液äžã§80âã§
30ç§éåŠçããå·æ°Žã§æŽãäžããŠä¹Ÿç¥ãããäžèš
ã®äžé£ã®åŠçã¯ãæ®éã«é£ç¶ããé åºã§å®æœãã
ããšãã§ããã 該混玡ã®ããªãšã¹ãã«æåã¯å®å šã«åž¯èµ€ãã€ã
ãŒè²ã«æè²ããã綿æåã¯å ãã«æ±æãããã«ã
ããªãã該ç¹ç¶ã¯ãæ¥å åã³æŽæ¿¯ã«å¯ŸããŠè¯å¥œãª
å ç¢åºŠãæããã äŸ 10 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææãª
ãã³ã«ïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ããåŒ
ïŒïŒã®ææã¯ã次ã®éæ¯ã§äœ¿çšãããïŒ ãè¡šã ããããã®å Žåã«ãäŸïŒã«èšèŒããããã®ãšå
ãçµæãåŸãããã äŸ 11 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒ
éšãïŒéšã«å¢å€§ãããBrã§ãããã€X1ãã¡ã
ãã·ã§ããåŒïŒïŒã®ææïŒéšãã次ã®åŒ(A)ã(B)
ã®ææã®ããããïŒã€ã®ïŒéšã«ãã€ãŠä»£ããã次
è¡šã®ïŒ·ãããåã³ïŒ²ã¯ãåŒ(A)ã(B)ã«ããã
ãšåããã®ãè¡šããã ãè¡šã ãã®å ŽåãããããäŸïŒã«èšèŒããã®ãšåãçµ
æãåŸãããã äŸ 12 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãã¡ããã·ã§ããåŒïŒïŒã®æ
æïŒéšãïŒéšã«æžå°ããããBrã§ãããã€X1
ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒéšã次ã®åŒ(A)ã(B)
ã®ææã®ããããïŒã€ïŒéšã«ãã€ãŠä»£ããã次衚
ã®ïŒ·ãããåã³ïŒ²ã¯ãåŒ(A)ã(B)ã«ããããš
åããã®ãè¡šããã ãè¡šã ãã®å ŽåãããããäŸïŒã«èŒããã®ãšåãçµæ
ãåŸãããã äŸ 13 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒ
éšãªãã³ã«ïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ã
ãåŒïŒïŒã®ææïŒéšãããBrã§ãããã€X1
ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒéšããBrã§ã
ããã€X1ãã¡ããã·ã§ããåŒïŒïŒã®ææ0.5éš
ãªãã³ã«ïŒ·ãBrã§ãããã€X1ããšããã·ã§ãã
åŒïŒïŒã®ææ0.5éšã«ãã€ãŠä»£ããã äŸïŒã«èšèŒããã®ãšåãçµæãåŸãããã ãBrã§ãããã€X1ããšããã·ã§ããåŒ
ïŒïŒã®ææãããèçŽ ã§ããããã¡ãã«ã§
ããããã¡ããã·ã§ããããã€ïŒ¹åã³ïŒºããã
ããïœâãããã«ã§ããåéã®åŒ(A)ã(B)ã®ææã«
代ããå ŽåãåãçµæãåŸãããã äŸ 14 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒ
éšãªãã³ã«ïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ã
ãåŒïŒïŒã®ææïŒéšããåã³ïŒºããããããš
ãã«ã§ããããã¡ãã«ã§ããããã€ïŒ·åã³ïŒžã
次ã®ãã®ãè¡šããåŒ(A)ã(B)ã®ïŒçš®é¡ã®ææã«ãã€
ãŠæ¬¡ã®éæ¯ã§ä»£ããïŒ ïŒ·  Br  1.5éš Cl  1.5éš Br OCH3 0.5éš Cl OCH3 0.5éš äŸïŒã«èšèŒããã®ãšåãçµæãåŸãããã äŸ 15 ãBrã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®
ææãšïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ããåŒ
ïŒïŒã®ææãšã®æ··åç©ããäŸïŒã«èšèŒãããã
ã«ããŠè£œé ãã10ïŒ æ°Žåæ£æ¶²ã«ç§»ãã 該åæ£æ¶²ãäŸïŒã«èšèŒããããã«ããªãšã¹ã
ã«ïŒç¶¿æ··çŽ¡ã«æœãããå ŽåãåãçµæãåŸãã
ãã äŸ 16 äŸïŒã«èšèŒããããžã³ã°æ³ãç¹°ãè¿ãããã
Brã§ãããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒ
éšãªãã³ã«ïŒ·ãBrã§ãããã€X1ãã¡ããã·ã§ã
ãåŒïŒïŒã®ææïŒéšãããããããClã§ã
ããã€X1ãæ°ŽçŽ ã§ããåŒïŒïŒã®ææïŒéšãªã
ã³ã«æ¬¡ã®åŒ(A)ã(B)ã®ææã®ããããïŒã€ïŒéšã«ã
ã€ãŠäœããã次衚ã®ïŒ·ãããåã³ïŒ²ã¯åŒ
(A)ã(B)ã«ããããšåããã®ãè¡šããã ãè¡šã ãã®å ŽåãããããäŸïŒã«èšèŒããã®ãšåãçµ
æãåŸãããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãããã次åŒïŒ ãäžèšåŒäžãã¯å¡©çŽ åååã¯èçŽ ååã§ããã
ãR1ãåã³ïŒºã¯ããããC1ã4âã¢ã«ãã«åº
ã§ãããã§ç€ºãããå°ãªããšãïŒçš®é¡ã®ææãå«
æããæ··åç©äžã®åŒïŒ¡ãšåŒïŒ¢ã®ææã®æ¯ã80ïŒ20
éééšã20ïŒ80éééšã§ããïŒçš®ä»¥äžã®åæ£ã¢ã
ã¢ãŸææã®æ··åç©ã ïŒ éæ¯ã95ïŒïŒéééšãïŒïŒ95éééšã®ïŒæå
ããæããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æææ··å
ç©ã ïŒ åŒïŒ ãåŒäžãã¯å¡©çŽ åååã¯èçŽ ååã§ãããX1ã¯
æ°ŽçŽ ååãã¡ããã·åºåã¯ãšããã·åºã®ãããã
ã§ããããæããææããéžæããïŒçš®ã®ææã
ãæããæ··åç©ã®ïŒæåã¯X1ãæ°ŽçŽ ã§ãããä»
ã®æåã¯X1ãã¡ããã·åã¯ãšããã·ã§ãããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æææ··åç©ã ïŒ X1ãæ°ŽçŽ ã§ããææãšX1ãã¡ããã·åã¯ãš
ããã·ã§ããææãšãããããçŽïŒïŒïŒéééšã
çŽïŒïŒïŒéééšã®éæ¯ã§ååšãããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé èšèŒã®æææ··åç©ã ïŒ ïŒ·ãèçŽ ã§ãããã€X1ãæ°ŽçŽ ã§ããææãš
ãèçŽ ã§ãããã€X1ãã¡ããã·ã§ããææãš
ããããããçŽïŒïŒïŒéééšã®éæ¯ã§ååšããïŒ
çš®ã®ææããæããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®
æææ··åç©ã ïŒ åŒïŒ ãåŒäžãã¯å¡©çŽ åååã³èçŽ ååã§ããïŒïŒžã¯
æ°ŽçŽ åååã¯OR1ã§ããããã€ïŒ²ãR1ãåã³ïŒº
ã¯äœçŽã¢ã«ãã«åºã§ãããã§ç€ºãããåæ£ã¢ãã¢
ãŸææïŒçš®ä»¥äžããæãããã§ããæåå°ãª
ããšãïŒçš®ãšïŒžãOR1ã§ããä»ã®æåãšãå«ãã
ïŒçš®ä»¥äžã®åæ£ã¢ãã¢ãŸææã®æ··åç©ã®è£œé æ³ã«
ãããŠåŒïŒ ãåŒäžãããåã³ïŒºã¯åèšã®ãã®ãè¡šã
ããã§ç€ºãããã«ãããªã³ã°æåå°ãªããšãïŒçš®
ããæãæ··åç©ããåŒïŒ ãåŒäžãã¯åèšã®ãã®ãè¡šãããã§ç€ºãããã¢
ãã³ã®ãžã¢ãŸåã«ããåŸãããå°ãªããšãïŒåã®
ãžã¢ãŸããŠã ååç©ãšã«ãããªã³ã°ããããã®é
ã«ãããªã³ã°æåã®æ··åç©ã¯ïŒžãæ°ŽçŽ ã§ããæå
å°ãªããšãïŒçš®ãšïŒžãOR1ã§ããæåå°ãªããšã
ïŒçš®ãšãå«ãããšãç¹åŸŽãšãããåæ£ã¢ãã¢ãŸæ
ææ··åç©ã®è£œé æ³ã ïŒ è³éŠæããªãšã¹ãã«ç¹ç¶ææåã³è³éŠæããª
ãšã¹ãã«ïŒã»ã«ããŒã¹æ··çŽ¡ã®æè²æ³ã«ãããŠåŒïŒ ãåŒäžãã¯å¡©çŽ åååã¯èçŽ ååã§ããïŒïŒžã¯
æ°ŽçŽ åååã¯OR1ã§ãããã€ïŒ²ãR1ãåã³ïŒºã¯
äœçŽã¢ã«ãã«åºã§ãããã§ç€ºãããåæ£ã¢ãã¢ãŸ
ææïŒçš®ä»¥äžããæãããã§ããæåå°ãªã
ãšãïŒçš®ãšïŒžãOR1ã§ããä»ã®æåãšãå«ãïŒçš®
以äžã®åæ£ã¢ãã¢ãŸæææ··åç©ãæ°Žæ§æµžææ³ãã
ãžã³ã°æ³åã¯æºææ³ã§åèšç¹ç¶ææã«æœãããšã
ç¹åŸŽãšãããè³éŠæããªãšã¹ãã«ç¹ç¶ææåã³è³
éŠæããªãšã¹ãã«ïŒã»ã«ããŒã¹æ··çŽ¡ã®æè²æ³ã ïŒ ïŒçš®ä»¥äžã®åæ£ã¢ãã¢ãŸæææ··åç©ãã混玡
ã®ã»ã«ããŒã¹æåçšã®ïŒçš®ä»¥äžã®çè²å€ãšçµåã
ãŠè³éŠæããªãšã¹ãã«ïŒã»ã«ããŒã¹æ··çŽ¡ã«æœãã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ æ··çŽ¡ã®ã»ã«ããŒã¹æåçšã®çè²å€ãçŽæ¥æ
æããããææãç¡«åææãããããŒã«ææåã¯
åå¿ææã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹
æ³ã ïŒïŒ 混玡ã®ã»ã«ããŒã¹æåçšã®çè²å€ããç¹ç¶
åå¿åºãšããŠè€çŽ ç°åŒç°äžã«ïŒååã¯ïŒåã®çªçŽ
ååãæããã€è€çŽ ç°åŒç°äžã®ççŽ ååãšçµåã
ãå°ãªããšãïŒåã®ã¬ã€ãã«çœ®æåºãæããè€çŽ
ç°åŒåºãå«æããåå¿ææã§ãããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒïŒ åå¿ææãã¬ã€ãã«çœ®æåºãšããŠå°ãªããš
ãïŒåã®å¡©çŽ ååãèçŽ åååã¯åŒçŽ ååãæã
ãããªã¢ãžã³ç°åã¯ããªããžã³ç°ãå«æãããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB17792/77A GB1582743A (en) | 1977-04-28 | 1977-04-28 | Mixtures of disperse azo dyestuffs |
| GB1779377 | 1977-04-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS53137229A JPS53137229A (en) | 1978-11-30 |
| JPS626592B2 true JPS626592B2 (ja) | 1987-02-12 |
Family
ID=26252927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5071878A Granted JPS53137229A (en) | 1977-04-28 | 1978-04-27 | Mixture of two or more dispersed monoazo dyes* method of making same and process for dyeing aromatic polyester fiber material and mixed spinning of aromatic polyester cellulose |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS53137229A (ja) |
| BR (1) | BR7802641A (ja) |
| CA (1) | CA1101154A (ja) |
| CH (1) | CH633576A5 (ja) |
| DE (1) | DE2818653A1 (ja) |
| ES (1) | ES469268A1 (ja) |
| FR (1) | FR2388861B1 (ja) |
| HK (1) | HK61981A (ja) |
| IT (1) | IT1094970B (ja) |
| MX (1) | MX148450A (ja) |
| NL (1) | NL7804338A (ja) |
| PT (1) | PT67962B (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0647686A1 (en) * | 1993-10-06 | 1995-04-12 | DyStar Japan Ltd. | Disperse dye composition and method for dyeing hydrophobic fibers with it |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3121320A1 (de) * | 1981-05-29 | 1982-12-16 | Hoechst Ag, 6000 Frankfurt | Neue faerbepraeparationen, verfahren zu deren herstellung und deren verwendung zum faerben und bedrucken von synthetischen fasermaterialien |
| DE3142609A1 (de) * | 1981-10-28 | 1983-05-05 | Basf Ag, 6700 Ludwigshafen | Marineblaue dispersionsfarbstoffmischungen |
| DE3347572A1 (de) * | 1983-12-30 | 1985-07-11 | Hoechst Ag, 6230 Frankfurt | Mischungen blauer dispersions-azofarbstoffe fuer das faerben von polyesterfasern |
| DE3539771A1 (de) * | 1985-11-09 | 1987-05-14 | Cassella Ag | Mischungen blauer dispersionsfarbstoffe und ihre verwendung fuer das faerben von polyester |
| GB8717309D0 (en) * | 1987-07-22 | 1987-08-26 | Ici Plc | Disperse dye |
| JPH01210465A (ja) * | 1988-02-17 | 1989-08-24 | Kiwa Kagaku Kogyo Kk | æ··åã¢ãã¢ãŸææçµæç© |
| DE3819563A1 (de) * | 1988-06-09 | 1989-12-14 | Hoechst Ag | Mehrkomponenten-mischungen blauer dispersions-azofarbstoffe fuer das faerben von synthetischen fasern |
| DE3908445A1 (de) * | 1989-03-15 | 1990-09-20 | Cassella Ag | Farbstoffmischung |
| DE4232558A1 (de) * | 1992-09-29 | 1994-03-31 | Basf Ag | Mischungen von Azofarbstoffen fÌr marineblaue bis schwarze Farbtöne |
| DE4330843A1 (de) * | 1993-09-11 | 1995-03-16 | Cassella Ag | Verfahren zum FÀrben von Polyester und polyesterhaltigen Textilmaterialien |
| DE102004018257B3 (de) * | 2004-04-15 | 2006-01-05 | Reitter, Gerd, Dipl.-Ing. (FH) | Mehrstössel-Presse |
| EP2995653A1 (en) | 2014-09-15 | 2016-03-16 | DyStar Colours Distribution GmbH | High wet-fast disperse dyes and mixtures thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE630388A (ja) * | 1962-03-31 | |||
| FR1382654A (fr) * | 1964-02-14 | 1964-12-18 | Sandoz Sa | Colorants mono-azoïques nitrés, leur fabrication et leurs applications |
-
1978
- 1978-04-18 MX MX173160A patent/MX148450A/es unknown
- 1978-04-24 NL NL7804338A patent/NL7804338A/xx not_active Application Discontinuation
- 1978-04-27 CH CH459178A patent/CH633576A5/de not_active IP Right Cessation
- 1978-04-27 PT PT67962A patent/PT67962B/pt unknown
- 1978-04-27 DE DE19782818653 patent/DE2818653A1/de active Granted
- 1978-04-27 BR BR7802641A patent/BR7802641A/pt unknown
- 1978-04-27 JP JP5071878A patent/JPS53137229A/ja active Granted
- 1978-04-27 FR FR7812501A patent/FR2388861B1/fr not_active Expired
- 1978-04-28 IT IT22839/78A patent/IT1094970B/it active
- 1978-04-28 ES ES469268A patent/ES469268A1/es not_active Expired
- 1978-04-28 CA CA302,224A patent/CA1101154A/en not_active Expired
-
1981
- 1981-12-10 HK HK619/81A patent/HK61981A/xx not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0647686A1 (en) * | 1993-10-06 | 1995-04-12 | DyStar Japan Ltd. | Disperse dye composition and method for dyeing hydrophobic fibers with it |
Also Published As
| Publication number | Publication date |
|---|---|
| MX148450A (es) | 1983-04-22 |
| NL7804338A (nl) | 1978-10-31 |
| ES469268A1 (es) | 1979-09-16 |
| HK61981A (en) | 1981-12-18 |
| DE2818653A1 (de) | 1978-11-02 |
| BR7802641A (pt) | 1979-01-02 |
| PT67962A (en) | 1978-05-01 |
| FR2388861A1 (fr) | 1978-11-24 |
| FR2388861B1 (fr) | 1985-06-07 |
| IT1094970B (it) | 1985-08-10 |
| CA1101154A (en) | 1981-05-19 |
| PT67962B (en) | 1979-11-14 |
| DE2818653C2 (ja) | 1988-01-07 |
| IT7822839A0 (it) | 1978-04-28 |
| CH633576A5 (en) | 1982-12-15 |
| JPS53137229A (en) | 1978-11-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3669951A (en) | Reactive azo dyestuffs containing a-fluoropyimidinyl group | |
| KR100297183B1 (ko) | ì¬ì ë°ìì± ìŒë£ ë° ìŽë¥Œ ì¬ì©íë ìŒì ë° ë ìŒë°©ë² | |
| JPH04258674A (ja) | æææ··åç©ããã³ãã®äœ¿çš | |
| JPH0748781A (ja) | äžè²æ³ã§ã»ã«ããŒã¹ç¹ç¶ææãæè²ãŸãã¯æºæããæ¹æ³ | |
| JPS626592B2 (ja) | ||
| US3993438A (en) | Process for coloring aromatic polyester-cellulose unions with a reactive dyestuff and a disperse dyestuff containing at least two carboxylic acid ester groups | |
| US3120507A (en) | Dyestuffs having a pyrimidine ring substituted by two halogen atoms and by a cyano group in the 5-position | |
| US5958086A (en) | Dye mixtures, process for their preparation and the use thereof | |
| US3910758A (en) | Dyeing wool with fluorine substituted pyrimidine containing azo reactive dyestuff | |
| KR100460561B1 (ko) | ë°ìì±ìŒë£,ìŽìì ì¡°ë°©ë²ë°ì¬ì ì¬ë£ììŒìëëë ìŒë°©ë² | |
| US20040117924A1 (en) | Disazo compound, reactive dye composition, and methods of dyeing cellulose or cellulose-containing fiber | |
| JPH0255553B2 (ja) | ||
| GB1582743A (en) | Mixtures of disperse azo dyestuffs | |
| CA1052777A (en) | Tetrareactive disazo dyestuffs, their manufacture and their use | |
| US5410041A (en) | Bisreactive dyes having a disulfophenylene bridging member | |
| CA1052776A (en) | Fibre-reactive disazo dyestuffs, their production and their use | |
| US4082739A (en) | Fibre-reactive dyestuff containing a bis-triazinylamino | |
| US4134723A (en) | Coloration process | |
| US5925746A (en) | Azo dyes, processes for their preparation and the use thereof | |
| US4153413A (en) | Coloration process | |
| US4169705A (en) | Coloration process | |
| KR940011840B1 (ko) | í ì€íìŒ ì¬ì ì¬ë£ë¥Œ ìì í ìììŒë¡ ìŒì ëë ë ìŒíë ë°©ë² | |
| EP0983321B1 (en) | Fiber-reactive disazo dyestuffs | |
| US3097910A (en) | Process for dyeing textiles with dyestuffs containing pyrimidine ring | |
| US4841034A (en) | Water-soluble azo compounds having a triazine moiety and dyeing method therewith |