JPS6251134B2 - - Google Patents
Info
- Publication number
- JPS6251134B2 JPS6251134B2 JP57007192A JP719282A JPS6251134B2 JP S6251134 B2 JPS6251134 B2 JP S6251134B2 JP 57007192 A JP57007192 A JP 57007192A JP 719282 A JP719282 A JP 719282A JP S6251134 B2 JPS6251134 B2 JP S6251134B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- component
- nickel
- cerium
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 claims description 53
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 32
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 19
- 229910052759 nickel Inorganic materials 0.000 claims description 16
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 229910052684 Cerium Inorganic materials 0.000 claims description 11
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 11
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 11
- 229910052593 corundum Inorganic materials 0.000 claims description 10
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 10
- 229910001593 boehmite Inorganic materials 0.000 claims description 8
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 8
- 150000000703 Cerium Chemical class 0.000 claims description 7
- 238000000975 co-precipitation Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 150000002815 nickel Chemical class 0.000 claims description 7
- 238000000629 steam reforming Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 4
- 238000010304 firing Methods 0.000 claims description 3
- 150000002823 nitrates Chemical class 0.000 claims description 2
- 239000002244 precipitate Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- 239000000243 solution Substances 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 7
- 238000000465 moulding Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 238000001354 calcination Methods 0.000 description 6
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000012266 salt solution Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910003310 Ni-Al Inorganic materials 0.000 description 1
- 229910000943 NiAl Inorganic materials 0.000 description 1
- 229910021543 Nickel dioxide Inorganic materials 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57007192A JPS58124541A (ja) | 1982-01-20 | 1982-01-20 | 炭化水素の低温水蒸気改質用触媒の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57007192A JPS58124541A (ja) | 1982-01-20 | 1982-01-20 | 炭化水素の低温水蒸気改質用触媒の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58124541A JPS58124541A (ja) | 1983-07-25 |
| JPS6251134B2 true JPS6251134B2 (enrdf_load_stackoverflow) | 1987-10-28 |
Family
ID=11659169
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57007192A Granted JPS58124541A (ja) | 1982-01-20 | 1982-01-20 | 炭化水素の低温水蒸気改質用触媒の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58124541A (enrdf_load_stackoverflow) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7554097B2 (en) | 2003-10-16 | 2009-06-30 | Alis Corporation | Ion sources, systems and methods |
| US7554096B2 (en) | 2003-10-16 | 2009-06-30 | Alis Corporation | Ion sources, systems and methods |
| US7557361B2 (en) | 2003-10-16 | 2009-07-07 | Alis Corporation | Ion sources, systems and methods |
| US7557360B2 (en) | 2003-10-16 | 2009-07-07 | Alis Corporation | Ion sources, systems and methods |
| US7557358B2 (en) | 2003-10-16 | 2009-07-07 | Alis Corporation | Ion sources, systems and methods |
| US7557359B2 (en) | 2003-10-16 | 2009-07-07 | Alis Corporation | Ion sources, systems and methods |
| US9012867B2 (en) | 2003-10-16 | 2015-04-21 | Carl Zeiss Microscopy, Llc | Ion sources, systems and methods |
| US9159527B2 (en) | 2003-10-16 | 2015-10-13 | Carl Zeiss Microscopy, Llc | Systems and methods for a gas field ionization source |
-
1982
- 1982-01-20 JP JP57007192A patent/JPS58124541A/ja active Granted
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7554097B2 (en) | 2003-10-16 | 2009-06-30 | Alis Corporation | Ion sources, systems and methods |
| US7554096B2 (en) | 2003-10-16 | 2009-06-30 | Alis Corporation | Ion sources, systems and methods |
| US7557361B2 (en) | 2003-10-16 | 2009-07-07 | Alis Corporation | Ion sources, systems and methods |
| US7557360B2 (en) | 2003-10-16 | 2009-07-07 | Alis Corporation | Ion sources, systems and methods |
| US7557358B2 (en) | 2003-10-16 | 2009-07-07 | Alis Corporation | Ion sources, systems and methods |
| US7557359B2 (en) | 2003-10-16 | 2009-07-07 | Alis Corporation | Ion sources, systems and methods |
| US9012867B2 (en) | 2003-10-16 | 2015-04-21 | Carl Zeiss Microscopy, Llc | Ion sources, systems and methods |
| US9159527B2 (en) | 2003-10-16 | 2015-10-13 | Carl Zeiss Microscopy, Llc | Systems and methods for a gas field ionization source |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58124541A (ja) | 1983-07-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4159874B2 (ja) | 炭化水素の改質触媒及びそれを用いた炭化水素の改質方法 | |
| US3791993A (en) | Process for the production of a reforming catalyst | |
| EP1802394B1 (en) | Promoted calcium-aluminate supported catalysts for synthesis gas generation | |
| JPH09187649A (ja) | 連続する複数の接触帯域を含む接触燃焼方法 | |
| CN103191720B (zh) | 一种镁铝尖晶石负载的耐硫甲烷化催化剂 | |
| JPH0510133B2 (enrdf_load_stackoverflow) | ||
| CN102029162A (zh) | 一种宽温型完全甲烷化催化剂及其制备方法 | |
| KR20090042952A (ko) | 복합 세공 구조를 갖는 알루미나, 및 분해 가솔린의 선택적수소화 반응 촉매 및 그 방법 | |
| CN106866332B (zh) | 一种苯和甲醇烷基化催化剂及应用 | |
| JPS592537B2 (ja) | 一酸化炭素転化触媒及び該触媒の製造方法 | |
| US4026823A (en) | Hydrocarbon reforming catalyst and method for preparing same | |
| JPS63104B2 (enrdf_load_stackoverflow) | ||
| CN109331810A (zh) | 一种用于丙烷脱氢制丙烯的催化剂及其制备方法 | |
| KR101260454B1 (ko) | 디젤의 수증기 개질반응용 니켈계 하이드로탈사이트 촉매, 이의 제조방법 및 이를 이용한 디젤의 개질반응에 의한 수소의 제조방법 | |
| JP4648566B2 (ja) | オートサーマルリフォーミング触媒および燃料電池用燃料ガスの製造方法 | |
| JPS6251134B2 (enrdf_load_stackoverflow) | ||
| US4185967A (en) | Process for the production of methane-containing gases and catalyst used in process | |
| US4215998A (en) | Catalyst and process for production of methane-containing gases | |
| CN116020436B (zh) | 改性镁铝复合氧化物载体及其制备方法、用于甲烷干重整制成合成气的催化剂与方法 | |
| KR20010101612A (ko) | 니켈, 루테늄 및 란타늄을 담지한 촉매 담체 | |
| CN113058613B (zh) | 一种用于甲烷干气重整反应锆-锰-锌复合氧化物担载镍基催化剂及其制备和应用 | |
| CN109289831A (zh) | 具有高抗积碳性的丙烷脱氢制丙烯的催化剂及其制备方法 | |
| EA007454B1 (ru) | Катализатор с бимодальным распределением радиусов пор | |
| US3507811A (en) | Catalyst for the reaction of hydrocarbons with steam | |
| JPS5822252B2 (ja) | 炭化水素類のスチ−ムリホ−ミング触媒 |