JPS62232103A - Fe base amorphous dust core and manufacture thereof - Google Patents

Fe base amorphous dust core and manufacture thereof

Info

Publication number
JPS62232103A
JPS62232103A JP7510186A JP7510186A JPS62232103A JP S62232103 A JPS62232103 A JP S62232103A JP 7510186 A JP7510186 A JP 7510186A JP 7510186 A JP7510186 A JP 7510186A JP S62232103 A JPS62232103 A JP S62232103A
Authority
JP
Japan
Prior art keywords
powder
magnetic core
coercive force
core
powder magnetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7510186A
Other languages
Japanese (ja)
Inventor
Katsuto Yoshizawa
克仁 吉沢
Kiyotaka Yamauchi
山内 清隆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Proterial Ltd
Original Assignee
Hitachi Metals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Metals Ltd filed Critical Hitachi Metals Ltd
Priority to JP7510186A priority Critical patent/JPS62232103A/en
Publication of JPS62232103A publication Critical patent/JPS62232103A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/147Alloys characterised by their composition
    • H01F1/153Amorphous metallic alloys, e.g. glassy metals
    • H01F1/15358Making agglomerates therefrom, e.g. by pressing
    • H01F1/15366Making agglomerates therefrom, e.g. by pressing using a binder

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  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Powder Metallurgy (AREA)
  • Soft Magnetic Materials (AREA)

Abstract

PURPOSE:To obtain a dust core which is more excellent in direct current superposition characteristics than a conventional Fe base amorphous dust core by electrically nearly insulating among the powder particles of a specific amorphous alloy and by making coercive force 0.5 Oe or less. CONSTITUTION:Among the powder particles of an amorphous alloy shown by a formula (Fe1-a Coa) 100-x-y-zMxWiyBzwherein M is one or more selected from Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Rn, Os, Rh, Pd, Pt, Cu, Ag, Au, Y and Ni and the conditions O <= a <= 0,3, 0.1 <= x <=10, O <= y <= 18, 5 <= z <= 30, 15 <= y + z <= 30 are satisfied is electrically and virtually insulated and coercive force is 0.5 Oe or less. The M is effective in reducing a core loss Hc and the reason why limited to 0.1 <= x <= 10 is that if the (x) exceeds 10 %, the density of saturated magnetic flux is reduced and is not practical and if lees than 0.1 %, there is almost no effect of the reduction of the core Loss Hc.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明はチョークコイル、ノイズフィルター等に好適な
直流重畳特性に優れたFe基アモルファス圧粉研心およ
び七の製造方法に関するものである0〔従来の技術〕 従来、チョークコイルやノイズフィルター等の磁心とし
ては鉄r MoパーマロイやFe −Si −AI圧粉
磁心等が用いられていた。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an Fe-based amorphous powder grinding core with excellent direct current superimposition characteristics suitable for choke coils, noise filters, etc., and a method for producing the same. [Prior Art] Conventionally, iron rMo permalloy, Fe-Si-AI powder magnetic cores, etc. have been used as magnetic cores for choke coils, noise filters, and the like.

鉄圧粉磁心はコア情夫が大きい、透磁率が低い。The iron powder magnetic core has a large core diameter and low magnetic permeability.

直流1畳特性が慈い等の問題点があり、Moパーマロイ
圧粉磁心やFe −St −Al圧粉磁心は飽和磁束密
度がやや低く、コア゛損失も比較的大きい等の問題点が
ある。
There are problems such as poor direct current characteristics, and Mo permalloy powder magnetic cores and Fe-St-Al powder magnetic cores have problems such as slightly low saturation magnetic flux density and relatively large core loss.

近年アモルファス合金が高透磁率、低損失、比抵抗が高
く周波数依存性に優れるため各種磁性部品への適用が行
なわれている。アモルファス合金を圧粉磁心にしようと
する試みはたとえば、時開55−L55507に記載さ
れている。
In recent years, amorphous alloys have been applied to various magnetic components because of their high magnetic permeability, low loss, high specific resistance, and excellent frequency dependence. An attempt to use an amorphous alloy as a powder magnetic core is described, for example, in Jikai No. 55-L55507.

FeJl−アモルファス合金は一般に飽和磁束密度が高
いため圧粉磁心にした場合、飽和磁界が大きくなる特徴
がある。
FeJl-amorphous alloy generally has a high saturation magnetic flux density, so when it is made into a powder magnetic core, it has a characteristic that the saturation magnetic field becomes large.

〔発明が解決しようとする問題点〕 し、かじ、Fe基アモルファス合金は磁歪定数が大きい
ため圧粉するとひずみの影響を受け、保磁力の増加、透
磁率の他下、コア損失の増加が起こり、直流重畳時性も
Moパーマロイ圧粉磁心より劣ってしまう。
[Problems to be solved by the invention] Since Fe-based amorphous alloys have a large magnetostriction constant, they are affected by strain when pressed into powder, resulting in an increase in coercive force, magnetic permeability, and core loss. Also, the DC superposition property is inferior to that of the Mo permalloy powder magnetic core.

本発明の目的は、従来のFe基アモルファス圧粉磁心よ
り直流M*特性に優れたFe基アモルファス圧粉磁心お
よびその製造方法を提供することである0 〔問題点を解決するための手段〕 本発明は、組成式 %式% Y 、 Niから選ばれる少なくとも1種以上であり、
ここで 0≦a≦0.3 、0.1≦X≦10,0≦y
≦185≦2≦30 、15≦7 + z≦30なる条
件を満足するアモルファス合金からなり、粉末粒子間が
電気的にほぼ短縁され、かつ保磁力が0 、5Oe以下
であることを特徴とするFe基アモルファス圧粉磁心と
上記Fe基アモルファス圧粉磁心の製造方法である。
An object of the present invention is to provide an Fe-based amorphous powder magnetic core that has better DC M* characteristics than conventional Fe-based amorphous powder magnetic cores, and a method for manufacturing the same.0 [Means for solving the problems] This invention The invention is at least one selected from the composition formula % Y, Ni,
Here 0≦a≦0.3, 0.1≦X≦10, 0≦y
It is made of an amorphous alloy that satisfies the following conditions: ≦185≦2≦30, 15≦7 + z≦30, and is characterized by having substantially short electrical edges between powder particles and having a coercive force of 0.5 Oe or less. The present invention provides an Fe-based amorphous powder magnetic core and a method for producing the Fe-based amorphous powder magnetic core.

本発明においてMはコア損°失Heを下げる効果を有し
、0.1≦X≦10に限定したのはXが10%を越える
と飽和磁束密度が低下し実用的でなくなり 0.1%未
満ではコア損失r He低減の効果がほとんどないため
である。
In the present invention, M has the effect of lowering the core loss He, and the reason why it is limited to 0.1≦X≦10 is because if X exceeds 10%, the saturation magnetic flux density decreases and becomes impractical.0.1% This is because there is almost no effect of reducing the core loss rHe if it is less than that.

Coは飽和磁束密度を茜め直流重畳時性を改善する効果
を有するが、組成比aが0.3を越えると飽和磁束密度
が低下するため好ましくない。
Co has the effect of reducing saturation magnetic flux density and improving DC superimposition characteristics, but if the composition ratio a exceeds 0.3, the saturation magnetic flux density decreases, which is not preferable.

Si+Bはアモルファス形成のために必須の元素であシ
、5iiiO≦y≦18.B量5≦2≦60゜15≦y
十z≦60の関係にある場合、アモルファス形成が容易
であり好ましい結果が得られる。
Si+B is an essential element for amorphous formation, and 5iiiO≦y≦18. B amount 5≦2≦60゜15≦y
When the relationship satisfies 10z≦60, amorphous formation is easy and favorable results can be obtained.

粉末粒子間を電気的に龜は絶縁するのは、高周波磁気特
性時に透磁率の周波数特性を改善するためであり、保磁
力を0 、20e以下に限定したのは0 、5Oeを越
えると、コア損失が増加しコアの発熱が大きくなるとと
もに直流重畳特性も十分でなくなるためである。
The purpose of electrically insulating the powder particles is to improve the frequency characteristics of magnetic permeability during high-frequency magnetic properties. This is because loss increases, heat generation in the core increases, and DC superimposition characteristics become insufficient.

上記Fe基アモルファス圧粉磁心は次の様な方法で製造
される。
The Fe-based amorphous powder magnetic core described above is manufactured by the following method.

まず上記即成の溶融金属を急冷し、アモルファス合金粉
末を作製あるいは上記組成の溶融金属を急冷し、アモル
ファス合金薄帯を粉砕し粉末を作成した後、該粉末に耐
熱性バインダーを介在させ圧粉成形し粒子間が絶縁され
た圧粉体とし、更に結晶化温度以下の温度で熱処理を行
ない保磁力が0 、5Oe以下のFe基アモルファス圧
粉磁心を製造する。
First, the ready-made molten metal is quenched to produce an amorphous alloy powder, or the molten metal with the above composition is quenched, the amorphous alloy ribbon is pulverized to create a powder, and then a heat-resistant binder is interposed between the powder and the powder is pressed. The powder is molded into a powder body with insulation between particles, and then heat treated at a temperature below the crystallization temperature to produce an Fe-based amorphous powder magnetic core with a coercive force of 0.5 Oe or less.

特にバインダーとして変性アルキルシリケートを主成分
とするもの、あるいは水ガラスを主成分とするものを用
いた場合に、粒子間が良好に絶縁される。このため周波
数特性が特に良好となる。
Particularly when a binder containing a modified alkyl silicate as a main component or a binder containing water glass as a main component is used, good insulation between particles can be achieved. Therefore, the frequency characteristics are particularly good.

また、圧粉成形は結晶化温度以下の温度に加熱して行っ
ても良い。
Moreover, compaction may be performed by heating to a temperature below the crystallization temperature.

〔実施例〕 以下、本発明を実施例に従って説明する。〔Example〕 Hereinafter, the present invention will be explained according to examples.

実施例1 Fets、sCu r Mos 5its、sB*  
アモルファス合金粉末を超音波ガスアトマイズ法により
作製し、次にこの粉末に水ガラスを主成分とするバイン
タ′−を混ぜた後金型を420℃に加熱し、15 T/
iの圧力で60分保持し圧粉成形した後、更に440℃
で60分熱処理を行りた。得られた外径21.、内径1
2簡、高さ8馴の圧粉磁心Aをエポキシ樹脂で粉体コー
ティングし、10 KHzの直流重畳特性と直流B−H
カーブを測定した。得られた圧粉磁心の保磁力は0 、
5Oeであった。直流重畳特性を第1図に示す。比較の
ため圧粉成形後熱処理を行なわない従来の方法で作製さ
れたFeys 5i9Bus アモルファス圧粉磁心B
の直流重畳特性を示す。
Example 1 Fets, sCu r Mos 5its, sB*
Amorphous alloy powder was produced by ultrasonic gas atomization, and then a binder whose main component was water glass was mixed with the powder, and the mold was heated to 420°C and heated to 15 T/min.
After compacting and holding at a pressure of i for 60 minutes, the temperature was further increased to 440°C.
Heat treatment was performed for 60 minutes. Obtained outer diameter 21. , inner diameter 1
A powder magnetic core A of 2cm and 8cm in height is powder coated with epoxy resin, and has DC superimposition characteristics of 10 KHz and DC B-H.
The curve was measured. The coercive force of the obtained powder magnetic core is 0,
It was 5 Oe. Figure 1 shows the DC superposition characteristics. For comparison, Feys 5i9Bus amorphous powder magnetic core B produced by a conventional method without heat treatment after compaction
shows the DC superposition characteristics of

不発明方法によυ製造したFe基アモルファス圧粉磁心
Aは従来の方法で製造したFe基アモルファス圧粉磁心
より高い直流重畳磁界Hbcまで増分透at率が高く直
流重畳特性に優れている。このため平滑チョーク等に用
いた場合磁心を小型化することができる。
The Fe-based amorphous powder magnetic core A produced by the uninvented method has a higher incremental permeability up to a higher DC superimposed magnetic field Hbc than the Fe-based amorphous powder magnetic core produced by the conventional method, and has excellent DC superposition characteristics. Therefore, when used in a smooth choke, etc., the magnetic core can be made smaller.

$腫19112 Fets、5Cut Nbs 5its、s B*アモ
ルファス合金薄帯を単ロール法によシ作製し、次にこの
粉末を機械的に粉砕し、この粉末に変性アルキルシリケ
ートを主成分とするバインダーを混ぜた後金型を450
℃に加熱し、15T/mの圧力で60分保持し圧粉成形
した後、更に450℃で60分熱処理した。得られた外
径21鰭、内径12+o+、高さ8簡の圧粉磁心Cをフ
ェノール樹脂製のコアケースに入れ直流M費特性、直流
B−Hカーブを測定した。
$19112 Fets, 5Cut Nbs 5its, s B* Amorphous alloy ribbon was produced by a single roll method, then this powder was mechanically crushed, and a binder mainly composed of modified alkyl silicate was added to this powder. After mixing, mold the mold to 450
℃, held at a pressure of 15 T/m for 60 minutes, and compacted, followed by further heat treatment at 450° C. for 60 minutes. The obtained powder magnetic core C having an outer diameter of 21 fins, an inner diameter of 12+o+, and a height of 8 fins was placed in a core case made of phenol resin, and the DC M cost characteristics and DC B-H curve were measured.

直流B−Hカーブよシ求めた保磁力Hcは0.20eで
めった。直流重畳特性を第2図に示す。
The coercive force Hc obtained from the DC B-H curve was found to be 0.20e. Figure 2 shows the DC superposition characteristics.

比較のため従来の方法で製造したFe 5i1o B□
3アモルファス圧粉磁心りの直流重畳特性を示す。
For comparison, Fe 5i1o B□ produced by the conventional method
3 shows the DC superposition characteristics of the amorphous powder magnetic core.

本発明の磁心Cは、従来の方法で製造した圧粉磁心Eよ
り高い直流重畳磁界Hbcまで増分透磁率が高く直流重
畳特性に優れている。
The magnetic core C of the present invention has a higher incremental magnetic permeability up to a higher DC superimposed magnetic field Hbc than the powder magnetic core E manufactured by the conventional method, and has excellent DC superposition characteristics.

実測例3 第1表に本発明によるFe基アモルファス圧粉磁心と従
来の方法で製造したFe基アモルファス圧粉磁心の保磁
力Heと、直流重畳磁界がOOeの場合の10 KHz
の透磁率μΔを比較して示す。
Measurement Example 3 Table 1 shows the coercive force He of the Fe-based amorphous powder magnetic core according to the present invention and the Fe-based amorphous powder magnetic core manufactured by the conventional method, and the coercive force He of 10 KHz when the DC superimposed magnetic field is OOe.
A comparison of the magnetic permeability μΔ is shown.

第1表 図かられかる様に本発明によるFe基圧粉磁心は従来の
磁心よりHcが小さくμΔもひじように高くなりておシ
チョーク用磁心としてひじように優れていることがわか
る。
As can be seen from Table 1, the Fe-based powder magnetic core according to the present invention has a smaller Hc and a much higher μΔ than the conventional magnetic core, and is therefore extremely superior as a magnetic core for a choke.

〔発明の効果〕〔Effect of the invention〕

本発明によれば、従来不十分であったFe基アモルファ
ス圧粉磁心の直流重畳特性を大幅に改善できるため、そ
の効果は著しいものがある0
According to the present invention, it is possible to significantly improve the direct current superimposition characteristics of an Fe-based amorphous powder magnetic core, which has been insufficient in the past.

【図面の簡単な説明】[Brief explanation of drawings]

第1図、第2図は本発明に係る圧粉磁心と従来の圧粉磁
心の直流重畳特性を比較した図であるOA、C:本発明
磁心 B、D:従来の圧粉磁心 手続ネ市正−1L) +++Nu G!・7・2i日
Figures 1 and 2 are diagrams comparing the DC superimposition characteristics of the powder magnetic core according to the present invention and the conventional powder magnetic core. OA, C: magnetic core of the present invention B, D: conventional powder magnetic core procedure Positive -1L) +++Nu G!・7・2i days

Claims (1)

【特許請求の範囲】 1、組成式 (Fe_1_−_aCo_a)_1_0_0_−_x_
−_y_−_zM_xSi_yB_zで表わされ、ここ
でMはTi、Zr、Hf、V、Nb、Ta、Cr、Mo
、W、Mn、Re、Ru、Os、Rh、Pd、Pt、C
u、Ag、Au、Y、Niから選ばれる少なくとも1種
以上でありここで0≦a≦0.3、 0.1≦x≦10、0≦y≦18、5≦z≦3015≦
y+z≦30 なる条件を満足するアモルファス合金からなり、粉末粒
子間が電気的に実質的に絶縁されかつ保磁力が0.5O
e以下であることを特徴とするFe基アモルファス圧粉
磁心。 2、溶融金属を急冷し、上記アモルファス合金粉末を作
製あるいは溶融金属を急冷し上記アモルファス合金薄帯
を粉砕し粉末を作製した後、該粉末に耐熱性バインダー
を介在させ圧粉成形(粒子間が絶縁された圧粉体とし、
更に結晶化温度以下の温度で熱処理を行ない保磁力を0
.5Oe以下とすることを特徴とするFe基アモルファ
ス圧粉磁心の製造方法。 3、耐熱性バインダーとして変性アルキルシリケートを
主成分とするものを用いることを特徴とする特許請求の
範囲第2項に記載のFe基アモルファス圧粉磁心の製造
方法。 4、耐熱性バインダーとして、水ガラスを主成分とする
ものを用いることを特徴とする特許請求の範囲第2項に
記載のFe基アモルファス圧粉磁心の製造方法。
[Claims] 1. Composition formula (Fe_1_-_aCo_a)_1_0_0_-_x_
-_y_-_zM_xSi_yB_z, where M is Ti, Zr, Hf, V, Nb, Ta, Cr, Mo
, W, Mn, Re, Ru, Os, Rh, Pd, Pt, C
At least one selected from u, Ag, Au, Y, and Ni, where 0≦a≦0.3, 0.1≦x≦10, 0≦y≦18, 5≦z≦3015≦
It is made of an amorphous alloy that satisfies the following conditions: y+z≦30, and the powder particles are substantially electrically insulated and have a coercive force of 0.5O.
An Fe-based amorphous powder magnetic core characterized in that it is less than or equal to e. 2. After quenching the molten metal to produce the amorphous alloy powder or quenching the molten metal and pulverizing the amorphous alloy ribbon to produce a powder, the powder is interposed with a heat-resistant binder and compacted (the particles are As an insulated compact,
Furthermore, heat treatment is performed at a temperature below the crystallization temperature to reduce the coercive force to 0.
.. A method for producing an Fe-based amorphous powder magnetic core, characterized in that the core is 5 Oe or less. 3. The method for producing an Fe-based amorphous powder magnetic core according to claim 2, characterized in that a heat-resistant binder containing a modified alkyl silicate as a main component is used. 4. The method for producing an Fe-based amorphous powder magnetic core according to claim 2, characterized in that the heat-resistant binder is one containing water glass as a main component.
JP7510186A 1986-04-01 1986-04-01 Fe base amorphous dust core and manufacture thereof Pending JPS62232103A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7510186A JPS62232103A (en) 1986-04-01 1986-04-01 Fe base amorphous dust core and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7510186A JPS62232103A (en) 1986-04-01 1986-04-01 Fe base amorphous dust core and manufacture thereof

Publications (1)

Publication Number Publication Date
JPS62232103A true JPS62232103A (en) 1987-10-12

Family

ID=13566442

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7510186A Pending JPS62232103A (en) 1986-04-01 1986-04-01 Fe base amorphous dust core and manufacture thereof

Country Status (1)

Country Link
JP (1) JPS62232103A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0844623A1 (en) * 1996-11-26 1998-05-27 Kubota Corporation Pressed body of amorphous magnetically soft alloy powder and process for producing same
KR100374292B1 (en) * 2001-03-06 2003-03-03 (주)창성 Composite metal powder for power factor correction having good dc biased characteristics and method of processing soft magnetic core by thereof using
JPWO2005020252A1 (en) * 2003-08-22 2006-11-16 Necトーキン株式会社 High frequency magnetic core and inductance component using the same
GB2455211B (en) * 2006-06-19 2011-06-29 Vacuumschmelze Gmbh & Co Kg Magnet core and method for its production
US8287664B2 (en) 2006-07-12 2012-10-16 Vacuumschmelze Gmbh & Co. Kg Method for the production of magnet cores, magnet core and inductive component with a magnet core
JP2015517026A (en) * 2012-03-23 2015-06-18 アップル インコーポレイテッド Processing process of amorphous alloy powder raw material
US9987685B2 (en) 2012-03-23 2018-06-05 Apple Inc. Continuous moldless fabrication of amorphous alloy pieces
WO2019031463A1 (en) * 2017-08-07 2019-02-14 日立金属株式会社 Fe-BASED ALLOY, CRYSTALLINE Fe-BASED ALLOY ATOMIZED POWDER, AND MAGNETIC CORE

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0844623A1 (en) * 1996-11-26 1998-05-27 Kubota Corporation Pressed body of amorphous magnetically soft alloy powder and process for producing same
US6017490A (en) * 1996-11-26 2000-01-25 Kubota Corporation Pressed body of amorphous magnetically soft alloy powder and process for producing same
KR100374292B1 (en) * 2001-03-06 2003-03-03 (주)창성 Composite metal powder for power factor correction having good dc biased characteristics and method of processing soft magnetic core by thereof using
JPWO2005020252A1 (en) * 2003-08-22 2006-11-16 Necトーキン株式会社 High frequency magnetic core and inductance component using the same
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