JPS62161843A - 着色発泡性スチレン系樹脂粒子の製造法 - Google Patents
着色発泡性スチレン系樹脂粒子の製造法Info
- Publication number
- JPS62161843A JPS62161843A JP388986A JP388986A JPS62161843A JP S62161843 A JPS62161843 A JP S62161843A JP 388986 A JP388986 A JP 388986A JP 388986 A JP388986 A JP 388986A JP S62161843 A JPS62161843 A JP S62161843A
- Authority
- JP
- Japan
- Prior art keywords
- dye
- resin particles
- styrenic resin
- styrene resin
- colored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title abstract description 43
- 239000012508 resin bead Substances 0.000 title 1
- 239000002245 particle Substances 0.000 claims abstract description 43
- 239000012736 aqueous medium Substances 0.000 claims abstract description 12
- 239000004088 foaming agent Substances 0.000 claims abstract description 7
- 239000004014 plasticizer Substances 0.000 claims abstract description 7
- 229920001890 Novodur Polymers 0.000 claims description 21
- 239000004604 Blowing Agent Substances 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 abstract description 20
- 239000011347 resin Substances 0.000 abstract description 20
- 238000000034 method Methods 0.000 abstract description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract description 8
- 238000005470 impregnation Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 239000001273 butane Substances 0.000 abstract description 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000011248 coating agent Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 abstract description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract description 3
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 abstract description 2
- 239000001294 propane Substances 0.000 abstract description 2
- 239000000975 dye Substances 0.000 description 45
- 239000011324 bead Substances 0.000 description 30
- 239000004793 Polystyrene Substances 0.000 description 13
- 229920006248 expandable polystyrene Polymers 0.000 description 13
- 238000005187 foaming Methods 0.000 description 13
- 229920002223 polystyrene Polymers 0.000 description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 6
- 230000004927 fusion Effects 0.000 description 6
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 5
- 238000003795 desorption Methods 0.000 description 4
- 238000010097 foam moulding Methods 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 239000001506 calcium phosphate Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 3
- 229940078499 tricalcium phosphate Drugs 0.000 description 3
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 3
- 235000019731 tricalcium phosphate Nutrition 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- -1 alicyclic hydrocarbons Chemical class 0.000 description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- FNYLWPVRPXGIIP-UHFFFAOYSA-N Triamterene Chemical compound NC1=NC2=NC(N)=NC(N)=C2N=C1C1=CC=CC=C1 FNYLWPVRPXGIIP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229920013820 alkyl cellulose Polymers 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000004181 carboxyalkyl group Chemical group 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- ZNAOFAIBVOMLPV-UHFFFAOYSA-N hexadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(C)=C ZNAOFAIBVOMLPV-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP388986A JPS62161843A (ja) | 1986-01-10 | 1986-01-10 | 着色発泡性スチレン系樹脂粒子の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP388986A JPS62161843A (ja) | 1986-01-10 | 1986-01-10 | 着色発泡性スチレン系樹脂粒子の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62161843A true JPS62161843A (ja) | 1987-07-17 |
| JPH0464623B2 JPH0464623B2 (enrdf_load_stackoverflow) | 1992-10-15 |
Family
ID=11569747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP388986A Granted JPS62161843A (ja) | 1986-01-10 | 1986-01-10 | 着色発泡性スチレン系樹脂粒子の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62161843A (enrdf_load_stackoverflow) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4979963A (en) * | 1988-03-25 | 1990-12-25 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Process for coloring expandable polystyrene beads |
| KR100433191B1 (ko) * | 2002-01-05 | 2004-05-27 | 주식회사 삼우기술에이엔씨 | 고 탄성 칼라 스티로폴 평판의 제조방법 |
| JP2006213850A (ja) * | 2005-02-04 | 2006-08-17 | Sekisui Plastics Co Ltd | 発泡性スチレン系樹脂粒子 |
| WO2010095444A1 (ja) * | 2009-02-19 | 2010-08-26 | 積水化成品工業株式会社 | 低倍成形用発泡性ポリスチレン系樹脂粒子とその製造方法、低倍発泡粒子、低倍発泡成形体及びヒューム管用クッション材、低倍発泡成形体及びヒューム管用クッション材の製造方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5222062A (en) * | 1975-08-09 | 1977-02-19 | Fuorei Patsukeejingu Ltd | Process for porducing colored polystyrene foam |
| JPS58109538A (ja) * | 1981-12-24 | 1983-06-29 | Hitachi Chem Co Ltd | 発泡性スチレン系樹脂粒子の製造法 |
| JPS60250047A (ja) * | 1984-05-25 | 1985-12-10 | Badische Yuka Co Ltd | 着色した発泡性スチレン系樹脂粒子の製造方法 |
-
1986
- 1986-01-10 JP JP388986A patent/JPS62161843A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5222062A (en) * | 1975-08-09 | 1977-02-19 | Fuorei Patsukeejingu Ltd | Process for porducing colored polystyrene foam |
| JPS58109538A (ja) * | 1981-12-24 | 1983-06-29 | Hitachi Chem Co Ltd | 発泡性スチレン系樹脂粒子の製造法 |
| JPS60250047A (ja) * | 1984-05-25 | 1985-12-10 | Badische Yuka Co Ltd | 着色した発泡性スチレン系樹脂粒子の製造方法 |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4979963A (en) * | 1988-03-25 | 1990-12-25 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Process for coloring expandable polystyrene beads |
| KR100433191B1 (ko) * | 2002-01-05 | 2004-05-27 | 주식회사 삼우기술에이엔씨 | 고 탄성 칼라 스티로폴 평판의 제조방법 |
| JP2006213850A (ja) * | 2005-02-04 | 2006-08-17 | Sekisui Plastics Co Ltd | 発泡性スチレン系樹脂粒子 |
| WO2010095444A1 (ja) * | 2009-02-19 | 2010-08-26 | 積水化成品工業株式会社 | 低倍成形用発泡性ポリスチレン系樹脂粒子とその製造方法、低倍発泡粒子、低倍発泡成形体及びヒューム管用クッション材、低倍発泡成形体及びヒューム管用クッション材の製造方法 |
| CN102405253A (zh) * | 2009-02-19 | 2012-04-04 | 积水化成品工业株式会社 | 低倍成形用发泡性聚苯乙烯系树脂颗粒及其制造方法、低倍发泡颗粒、低倍发泡成形体及休谟管用缓冲材料、低倍发泡成形体及休谟管用缓冲材料的制造方法 |
| JP5552112B2 (ja) * | 2009-02-19 | 2014-07-16 | 積水化成品工業株式会社 | 低倍成形用発泡性ポリスチレン系樹脂粒子とその製造方法、低倍発泡粒子、低倍発泡成形体及びヒューム管用クッション材、低倍発泡成形体及びヒューム管用クッション材の製造方法 |
| KR101498336B1 (ko) * | 2009-02-19 | 2015-03-03 | 세키스이가세이힝코교가부시키가이샤 | 저배성형용 발포성 폴리스티렌계 수지 입자와 그 제조방법, 저배발포 입자, 저배발포 성형체 및 흄관용 쿠션재, 저배발포 성형체 및 흄관용 쿠션재의 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0464623B2 (enrdf_load_stackoverflow) | 1992-10-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR920001625B1 (ko) | 발포성 폴리올레핀 입자의 제조방법 | |
| US2950261A (en) | Process of making expansible particulate styrene polymer by diffusion of a volatile liquid hydrocarbon into said polymer particles | |
| US3484262A (en) | Polymer pigmentation | |
| JPS62161843A (ja) | 着色発泡性スチレン系樹脂粒子の製造法 | |
| JP4935110B2 (ja) | 着色した発泡性スチレン系樹脂粒子の製造法 | |
| JPH07179647A (ja) | 寸法安定性のよい難燃性発泡体製造用樹脂粒子及びその製造方法 | |
| JPH06122781A (ja) | 発泡性スチレン系樹脂粒子及びその製造方法 | |
| US3399025A (en) | Process for dyeing thermoplastic styrene polymer granules | |
| JPH02247234A (ja) | 着色発泡性熱可塑性樹脂粒子及び着色発泡成形品の製造方法 | |
| JP3278347B2 (ja) | 発泡性着色樹脂粒子及びその製造方法 | |
| JPH0218329B2 (enrdf_load_stackoverflow) | ||
| KR0163433B1 (ko) | 내화성 및 발포성을 가진 열가소성 비이드의 제조 방법 | |
| JPH06157805A (ja) | 着色発泡性樹脂粒子の製造方法 | |
| JPS58109538A (ja) | 発泡性スチレン系樹脂粒子の製造法 | |
| JPS6031536A (ja) | 発泡性スチレン系樹脂粒子の製造法 | |
| JPS59152933A (ja) | 着色された発泡ポリスチレンビ−ズ | |
| US3576770A (en) | Flame-retardant resin compositions | |
| US3850860A (en) | Process for dyeing expandable thermoplastic polymers | |
| JPH08151471A (ja) | 耐衝撃性発泡体製造用の発泡性粒子及びその製造方法 | |
| JPH0623266B2 (ja) | 着色した発泡性スチレン系樹脂粒子の製造方法 | |
| JPH0572923B2 (enrdf_load_stackoverflow) | ||
| JPH08100006A (ja) | 単分散ポリマー粒子の製造方法 | |
| JPS5842212B2 (ja) | 熱膨脹性樹脂組成物 | |
| JPS58204034A (ja) | 発泡ポリスチレン粒の着色法 | |
| JPS6337139A (ja) | 発泡性共重合樹脂粒子の製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |