JPS6214168B2 - - Google Patents
Info
- Publication number
- JPS6214168B2 JPS6214168B2 JP60026643A JP2664385A JPS6214168B2 JP S6214168 B2 JPS6214168 B2 JP S6214168B2 JP 60026643 A JP60026643 A JP 60026643A JP 2664385 A JP2664385 A JP 2664385A JP S6214168 B2 JPS6214168 B2 JP S6214168B2
- Authority
- JP
- Japan
- Prior art keywords
- anhydride
- epoxy
- lewis acid
- carboxylic acid
- epoxy resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000008064 anhydrides Chemical class 0.000 claims description 58
- 239000003822 epoxy resin Substances 0.000 claims description 56
- 229920000647 polyepoxide Polymers 0.000 claims description 56
- 239000000203 mixture Substances 0.000 claims description 40
- 239000011968 lewis acid catalyst Substances 0.000 claims description 24
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 16
- -1 carboxylic acid cation Chemical class 0.000 claims description 13
- 239000000376 reactant Substances 0.000 claims description 10
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 8
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 claims description 6
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 4
- 229910018287 SbF 5 Inorganic materials 0.000 claims description 3
- 229910003074 TiCl4 Inorganic materials 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 2
- JIYNFFGKZCOPKN-UHFFFAOYSA-N sbb061129 Chemical group O=C1OC(=O)C2C1C1C=C(C)C2C1 JIYNFFGKZCOPKN-UHFFFAOYSA-N 0.000 claims 1
- 238000001723 curing Methods 0.000 description 32
- 239000003795 chemical substances by application Substances 0.000 description 24
- 229920005989 resin Polymers 0.000 description 24
- 239000011347 resin Substances 0.000 description 24
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 22
- 239000004593 Epoxy Substances 0.000 description 16
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 16
- 238000002156 mixing Methods 0.000 description 15
- 239000000463 material Substances 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 239000011342 resin composition Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 8
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 7
- 239000007795 chemical reaction product Substances 0.000 description 7
- 150000002118 epoxides Chemical class 0.000 description 7
- 125000003700 epoxy group Chemical group 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000012212 insulator Substances 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- YXALYBMHAYZKAP-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethyl 7-oxabicyclo[4.1.0]heptane-4-carboxylate Chemical compound C1CC2OC2CC1C(=O)OCC1CC2OC2CC1 YXALYBMHAYZKAP-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000004020 conductor Substances 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 229940091173 hydantoin Drugs 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 238000013035 low temperature curing Methods 0.000 description 5
- 229920003986 novolac Polymers 0.000 description 5
- 238000004382 potting Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 239000002841 Lewis acid Substances 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- 239000011353 cycloaliphatic epoxy resin Substances 0.000 description 4
- 239000005009 epoxy-anhydride resin Substances 0.000 description 4
- 150000007517 lewis acids Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- KMOUUZVZFBCRAM-UHFFFAOYSA-N 1,2,3,6-tetrahydrophthalic anhydride Chemical compound C1C=CCC2C(=O)OC(=O)C21 KMOUUZVZFBCRAM-UHFFFAOYSA-N 0.000 description 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000001879 gelation Methods 0.000 description 3
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- KNDQHSIWLOJIGP-UMRXKNAASA-N (3ar,4s,7r,7as)-rel-3a,4,7,7a-tetrahydro-4,7-methanoisobenzofuran-1,3-dione Chemical compound O=C1OC(=O)[C@@H]2[C@H]1[C@]1([H])C=C[C@@]2([H])C1 KNDQHSIWLOJIGP-UMRXKNAASA-N 0.000 description 1
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 1
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- CHHZDIAJJPHFEO-UHFFFAOYSA-N 3,3-dimethyl-1,5-bis(oxiran-2-yl)pentane-2,4-diol Chemical compound O1CC1CC(C(C(CC1CO1)O)(C)C)O CHHZDIAJJPHFEO-UHFFFAOYSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- GRWFFFOEIHGUBG-UHFFFAOYSA-N 3,4-Epoxy-6-methylcyclohexylmethyl-3,4-epoxy-6-methylcyclo-hexanecarboxylate Chemical compound C1C2OC2CC(C)C1C(=O)OCC1CC2OC2CC1C GRWFFFOEIHGUBG-UHFFFAOYSA-N 0.000 description 1
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 1
- VQVIHDPBMFABCQ-UHFFFAOYSA-N 5-(1,3-dioxo-2-benzofuran-5-carbonyl)-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(C(C=2C=C3C(=O)OC(=O)C3=CC=2)=O)=C1 VQVIHDPBMFABCQ-UHFFFAOYSA-N 0.000 description 1
- NHJIDZUQMHKGRE-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-yl 2-(7-oxabicyclo[4.1.0]heptan-4-yl)acetate Chemical compound C1CC2OC2CC1OC(=O)CC1CC2OC2CC1 NHJIDZUQMHKGRE-UHFFFAOYSA-N 0.000 description 1
- BNDNAARXJVXTED-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-yl 4-methyl-7-oxabicyclo[4.1.0]heptane-4-carboxylate Chemical compound C1CC2OC2CC1OC(=O)C1(C)CC2OC2CC1 BNDNAARXJVXTED-UHFFFAOYSA-N 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 229920002732 Polyanhydride Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229910003910 SiCl4 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- NIYNIOYNNFXGFN-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol;7-oxabicyclo[4.1.0]heptane-4-carboxylic acid Chemical compound OCC1CCC(CO)CC1.C1C(C(=O)O)CCC2OC21.C1C(C(=O)O)CCC2OC21 NIYNIOYNNFXGFN-UHFFFAOYSA-N 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- VMPVEPPRYRXYNP-UHFFFAOYSA-I antimony(5+);pentachloride Chemical compound Cl[Sb](Cl)(Cl)(Cl)Cl VMPVEPPRYRXYNP-UHFFFAOYSA-I 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- NJJFVOQXYCEZLO-UHFFFAOYSA-N dialuminum;triberyllium;dioxido(oxo)silane Chemical compound [Be+2].[Be+2].[Be+2].[Al+3].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O NJJFVOQXYCEZLO-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- NJVOZLGKTAPUTQ-UHFFFAOYSA-M fentin chloride Chemical compound C=1C=CC=CC=1[Sn](C=1C=CC=CC=1)(Cl)C1=CC=CC=C1 NJVOZLGKTAPUTQ-UHFFFAOYSA-M 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 239000004845 glycidylamine epoxy resin Substances 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- FBUKVWPVBMHYJY-UHFFFAOYSA-N noncarboxylic acid Natural products CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- MHZDONKZSXBOGL-UHFFFAOYSA-L propyl phosphate Chemical compound CCCOP([O-])([O-])=O MHZDONKZSXBOGL-UHFFFAOYSA-L 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001868 water Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/40—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
- C08G59/4284—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof together with other curing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/72—Complexes of boron halides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Epoxy Resins (AREA)
- Organic Insulating Materials (AREA)
- Furan Compounds (AREA)
Description
æ¬çºæã¯ãšããã·æš¹èã®äœæž©ç¡¬åå€ãšããŠã®äº
ãåå¿ãããã«ã«ãã³é žç¡æ°Žç©é¯äœãå«æãããš
ããã·æš¹èå«æ絶çžçµæç©ã«é¢ãããã®ã§ããã ã¢ãã³ç¡¬åç³»ãšããã·æš¹èããè¯å¥œãªç©ççå
ã³é»æ°çç¹æ§ãæäŸããé«æž©ã«ãããå®å®æ§ãæ¹
è¯ããããã«ã¯ãç¡æ°Žã«ã«ãã³é žç¡¬åå€ãé«å§çµ¶
çžçšã®ãšããã·æš¹èã«ç¹ã«æçšã§ããããšãçºèŠ
ããããããçš®ã®ç°åŒèèªæãšããã·æš¹èã«ã€ã
ãŠã¯ãã¢ãã³ç¡¬åå€ã¯ãããã®ã¿ã€ãã®ãšããã·
ããšæ¯èŒçåå¿æ§ãç¡ãããã«ãç¡æ°Žã«ã«ãã³é ž
ã ãã硬åå€ãšããŠäœ¿çšãããŠããã ããããªãããç¡æ°Žã«ã«ãã³é žç¡¬åå€ã䜿çšã
ãå Žåã®ïŒã€ã®é倧ãªæ¬ ç¹ã¯å®€æž©ã«è¿ã枩床ã§ã¯
åå¿æ§ãéåžžã«äœãããšã§ãããéåžžãé«æž©ã«ã
ããŠè¯å¥œãªã²ã«åæéãåŸãããã«ã¯ãä¿é²å€ã
æ·»å ããããšãå¿ èŠã§ããã宀枩ã«ãããŠã¯ã¯ã
ãã«é«æ¿åºŠã®ä¿é²å€ãå¿ èŠã§ããã宀枩硬åã®æ¡
件äžã§ã¯ããšããã·âç¡æ°Žç©æš¹èç³»ã¯å®å šã«ç¡¬å
ããäžç²çæ§ã®ç¶æ ã«æçµçã«å°éããåã«æ°é±
éç²çæ§ãä¿ã€ããšãæ®éã§ãããæè¿ããšãã
ã·âç¡æ°Žç©æš¹èç³»ã®æ¹è¯ããã宀枩硬åå€ãéçº
ããããã«ããªãã®åªåãæãããŠæ¥ãããã®èŠ
æ±ã¯æè¿ã®å€©ç¶ã¬ã¹è³æºã®æ¶žæžã®èŠ³ç¹ãããéèŠ
ãªã€ãŠæ¥ãŠãããããã«ããã°å·¥æ¥çã«æš¹èã硬
åããã®ã«å¿ èŠãªç±ãšãã«ã®ãŒãç¯çŽã§ããã ç±³åœç¹èš±ç¬¬3281376å·ïŒProopsïŒã¯é žç¡æ°Žç©ç¡¬
åå€ãå«æãããšããã·ãã宀枩ã§ç¡¬åããåé¡
ã解æ¶ããããšã«ã€ããŠé瀺ããŠãããäžããå
ããŠçŽ åã³å¡©å第ïŒé«ãªã©ã®ã«ã€ã¹é žãšãšããã·
æš¹èãšã®äºååå¿ã«ã€ããŠç 究ãããããã®çµå
ããã¯çºç±åã³çºæ³¡ãå¶åŸ¡ã§ããªãããã«æŸæ£ã
ãåŸãProopsã¯ç¬¬ïŒé«ããã©ãã¹ããžïŒããã
ã«ïŒããªã¹ããšãŒãããªã©ã®é«ææ©ãªã³é žå¡©ãšãš
ããã·ããšãäºååå¿ãããæ¹æ³ãçºèŠãããã
ã®åå¿ãããšããã·ãã¯ãããåŸå®€æž©ã§åŸã ã«ç¡¬
åãããŠãè¯ãããããã¯ã¢ãã³ãŸãã¯ç¡æ°Žããª
ã«ã«ãã³é žãªã©ã®ææ©ç¡¬åå€ãšå ±éåãããŠãè¯
ããç±³åœç¹èš±ç¬¬4020017å·ïŒSmithçïŒã¯ãå¡©å
ããªããšãã«é«ãªã©ã®ææ©é«ååç©ãå°é䜿çšã
ãŠèŠããäžåå¿æ§ãšããã·åžéå€ãšé¯äœã圢æ
ãããããç°åŒèèªæåã³ã°ãªã·ãžã«ãšã¹ãã«ãš
ããã·æš¹èã®æ·»å å€ãšããŠäœ¿çšããé žç¡æ°Žç©ã䜿
çšããªãé»æ°çµ¶çžæš¹èçµæç©ãæäŸããããšãé
瀺ããŠãããããããªããããããã®çµæç©ã¯å°
ããšã120âã®ç¡¬å枩床ãå¿ èŠãšããã ç±³åœç¹èš±ç¬¬3799905å·ïŒHollowayçïŒã¯ç¡é žãŸ
ãã¯å¡©é žãªã©ã®åŒ·åãªéã«ã«ãã³é žäžŠã³ã«BF3ã
SbCl5ãTiCl4ãSiCl4ãFeCl3ãAlCl3ãŸãã¯SnCl4
é¯äœããæã硬åå€ã«ãã€ãŠç¡¬åãããäœæž©ç¡¬å
æ§è湿æ§æ¯ç§çšãšããã·ãã«ã€ããŠé瀺ããŠã
ããããã²ã³åç©ååç©ïŒéã«ã«ãã³é žã®ééæ¯
ã¯50ã25ïŒ100ã§ãã€ãã硬åã¯åŸ©å æ¯ç§æè¡ã§
䜿çšäžã圢ãäœãããã«æ¯èŒçããããã§ãã€
ããé»æ°ççŽã®ãšããã·ãã«é¢ããç±³åœç¹èš±ç¬¬
3728306å·åã³ç¬¬3622524å·ïŒMarkovitzïŒã¯ææ©
é«é žåã³ææ©é«é žåç©ãããããç¡æ°Žã«ã«ãã³é ž
ãšäºååå¿ãããŠã100âããäœã枩床ã§ãšãã
ã·æš¹èã硬åãããåå¿çæç©ãçæããããšã«
ã€ããŠé瀺ããŠãããããããªãããå°ããšãçŽ
10ééïŒ ã®ææ©é«ååç©ãå«æããé«âç¡æ°Žç©å
å¿çæç©ã¯æº¶è§£ããŠæçšãªãšããã·åå¿æ§äœæž©ç¡¬
åå€ãçæããã®ã«çŽ75ã250âã§ïŒãïŒæéå
ç±ããããšãå¿ èŠãšãããéåžžãçŽ80ã160âã§
液åãããšããã·ãšåå¿ãããã®ã«è解ãå¿ èŠãš
ããåºäœãçæããããã®æ¹æ³ã®å Žåããããªã
ã®éã®ç±ãå¿ èŠã§ãã€ãã åŸã€ãŠãå¿ èŠãšããããã®ã¯ãç©ççãç±çãŸ
ãã¯é»æ°çç¹æ§ãæ倱ãããªãã§ãå®å šã«æ··åã§
ããçŽ45â以äžã®æž©åºŠã§è¿ éã«ç¡¬åãããšããã·
âç¡æ°Žã«ã«ãã³é žç³»ã®ããã®ç¡¬åçšæ·»å å€ã§ã
ãã åŸã€ãŠãæ¬çºæã¯äžå®èœæ§ç¡æ°Žç©ãå€å®èœæ§ç¡
æ°Žç©åã³ãããã®æ··åç©ããéžæããã液äœææ©
ã«ã«ãã³é žç¡æ°Žç©ãšãSnCl4ãTiCl4ãSbCl5ã
SbF5ãBF3ãPF5åã³ãããã®æ··åç©ããéžæã
ããã«ã€ã¹é žè§Šåªã®æ··åç©ãšããæ¬è³ªçã«æãã
ã«ã«ãã³é žã«ããªã³äœã圢æããŠãªãé»è·ç§»åé¯
äœã硬åå€ãšããŠå«ã¿ã10ã45âã®æž©åºŠã§ç¡¬åã
åŸãããšãç¹åŸŽãšããäœæž©ç¡¬åæ§ãšããã·æš¹è絶
çžçµæç©ã«é¢ãããã®ã§ããã SnCl4ãªã©ã®éžæãããã«ã€ã¹é žè§Šåªã¯å°éã§
ã«ã«ãã³é žç¡æ°Žç©ãšäºãåå¿ãããå Žåã奜ãŸã
ãã¯10ã45âã®åå¿ç©æž©åºŠã§ãšããã·æš¹èã®ç¹ã«
å¹æçãªäœæž©ç¡¬åå€ã§ããé»è·ç§»åé¯äœåå¿æ§ç©
質ãçæããããšãçºèŠãããããã®åå¿çæç©
é¯äœã¯å¥œãŸããã¯çŽ10ã45âã®åå¿ç©æž©åºŠã§ãšã
ãã·æš¹èãšæ··åããå ŽåãçŽ10ã45âã§ãçŽïŒã
168æé以å ãéåžžçŽïŒã48æé以å ã«ãšããã·
æš¹èã硬åãããããã®ç¡¬åãããšããã·æš¹èã¯
åŸç¡¬åïŒãã¹ãããŠã¢ïŒãå¿ èŠãšãããèããç©
ççãç±çåã³é»æ°çç¹æ§ãä¿æãããéžæãã
ãã«ã€ã¹é žè§ŠåªïŒç¡æ°Žã«ã«ãã³é žã®ééæ¯ã¯å¥œãŸ
ããã¯0.0060ïŒïŒã0.0001ïŒïŒã§ãããç¡æ°Žã«ã«
ãã³é žã掻æ§åãããã®ã«æå¹ãªã«ã€ã¹é žè§Šåªã¯
奜ãŸããã¯TiCl4ãŸãã¯SnCl4ã§ããã ç¹å®ã®ã«ã€ã¹é žè§Šåªã¯ç¡æ°Žææ©ã«ã«ãã³é žãšå¹
æçã«åå¿ããŠé¯äœã圢æããçŽ45â以äžã®æž©åºŠ
ã§ãšããã·æš¹èç³»ã硬åããã®ã«ç¹ã«æå¹ãªåå¿
ç©è³ªãæããããšãçºèŠãããããããã®äœæž©ç¡¬
åæ§æš¹èã¯çš®ã ã®çšéãããšãã°é«é硬åçšå°åº
æ圢ææãäœç²åºŠç空å«æµžçšçµæç©åã³é«åºŠå å¡«
泚å°ææçã«æçšã§ããã æãŸããã¯ããããã®æçšãªç¹å®ã®ã«ã€ã¹é žè§Š
åªã¯ç¡æ°Žã«ã«ãã³é žãš10ã45âã®åå¿ç©æž©åºŠã奜
ãŸããã¯25âã§æ··åããç¡æ°Žç©ç°ãç Žå£ããªãã§
çžäºäœçšãããŠé»è·ç§»åé¯äœåå¿æ§ç©è³ªãããªã
ã¡æŽ»æ§åç¡æ°Žã«ã«ãã³é žãçæããããã®æŽ»æ§å
ç¡æ°Žç©ã¯ãããåŸçŽ10ã45âã®åå¿ç©æž©åºŠã§ãšã
ãã·ã«å ãããããç¹å®ã®ã«ã€ã¹é žè§ŠåªïŒç¡æ°Žã«
ã«ãã³é žã®å¥œãŸããééæ¯ã¯0.0060ã0.0001ïŒ
ïŒãããã«å¥œãŸããã¯0.004ã0.0001ïŒïŒã§ã
ãã ç¡æ°Žç©ïŒéšåœãã®ã«ã€ã¹é žè§Šåªã®éã0.0060éš
ããå€ããšãç¡æ°Žç©ãšæ··åäžã«é«åºŠã®çºç±ãçã
ãåŸåããããããã«ãã€ãŠç¡æ°Žç©ç°ãéããé»
è·ç§»åé¯äœç¡¬åå€ãç Žå£ããåŸåããããããã
ã®çºç±ã¯å¯åå¿ãããšãã°èžçºã«ããæåã®æ
倱ãåã³å€ç°å¯ç£ç©ã®çæãªã©ãèµ·ãããããã¯
ãšããã·æš¹èã®ç¡¬åã«æãŸãããªããããã«ãŸã
硬åå€ããšããã·æš¹èãšæ··åããæã«ãé«éå±æ¿
床ãçãã硬åããæš¹èã®é»æ°çç¹æ§ã«æªåœ±é¿ã
åãŒããç¡æ°Žç©ïŒéšåœãã®ã«ã€ã¹é žè§Šåªã®éãé
ã«0.0001éšããå°ãªããšãçæããé»è·ç§»åé¯äœ
åå¿æ§ç©è³ªç¡¬åå€ã®éãå°ãªéããŠå¹åãç¡ããª
ãã ã«ã€ã¹é žè§Šåªãç¡æ°Žç©ãš45âããå®è³ªçã«é«ã
枩床ã§æ··åããå Žåãç¡æ°Žç©ç°ãéããå¯åå¿ã
çããŠèžçºã«ãã€ãŠæåã倱ãããé»è·ç§»åé¯äœ
ã«ããªã³åå¿æ§ç¡¬åå€ãç Žå£ããã掻æ§åããç¡
æ°Žç©ããšããã·æš¹èãš45âããå®è³ªçã«é«ã枩床
ã§æ··åããå Žåãå³åº§ã«ã²ã«åãèµ·ãããå質ãª
æ··åãäžå¯èœã«ããã10âããäœã枩床ã§ã®åå¿
ã¯é©åœãªçžäºäœçšãèµ·ããåŸåãããã液äœç¡æ°Ž
ç©ã®çµæ¶åãèµ·ãããæåã®æ··åãé£ããããª
ãã ç¹å®ã®ã«ã€ã¹é žè§Šåªåã³æ¯äœãšããã·æš¹èãšå
å¿æ§ã®æçšãªææ©ã«ã«ãã³é žç¡æ°Žç©ã®äŸãšããŠã¯
åŸæ¥ã®äžå®èœåã³å€å®èœç¡æ°Žç©ããããã«ã€ã¹é ž
觊åªãšæ··åãããç¡æ°Žç©æåã¯æ¶²ç¶ã§ãªããã°ãª
ããªãã液ç¶ãä¿ã€ããã«ã¯ãåºäœç¡æ°Žç©ã¯ãã
ã溶解ãã液äœç¡æ°Žç©ãšæ··åããããäžå®èœæ§ç¡
æ°Žç©ã®ä»£è¡šçãªãã®ã¯ãç¡æ°Žãããµããããã¿ã«
é žãç¡æ°ŽïŒâã¡ãã«ãããµããããã¿ã«é žãç¡æ°Ž
ããã©ããããã¿ã«é žãç¡æ°ŽïŒâã¡ãã«ããã©ã
ãããã¿ã«é žãç¡æ°Žãã¿ã«é žãç¡æ°Žããžãã¯é žã
ç¡æ°Žããžãã¯é žã¡ãã«ãç¡æ°Žã³ãã¯é žããã»ã
ã«ãç¡æ°Žãã¬ã€ã³é žçãããã䜿çšãåŸãå€å®èœ
æ§ç¡æ°Žç©ã®äŸãšããŠã¯ããã¡ãªããé žãžç¡æ°Žç©ã
ããªã¢ãŒã©ã€ã³é žããªç¡æ°Žç©ãç¡æ°Žããªã¡ãªãã
é žãšã°ãªã³ãŒã«ãšã®åå¿çæç©ãåã³ãã³ãŸããš
ãã³ããã©ã«ã«ãã³é žãžç¡æ°Žç©ãããããããã®
ææ©ç¡æ°Žç©ã¯åç¬ã§ãããŸãã¯æ··åç©ãšããŠã䜿
çšã§ããæçµçã«æ¶²ç¶ã®ãã®ãæäŸãããéã«ã«
ãã³é žãŸãã¯éã«ã«ãã³é žç¡æ°Žç©ã¯ãã®ç³»ã«ãã
ãŠé©åœãªåå¿ãŸãã¯ç¡¬åãæäŸããã®ã«æçšã§ãª
ããæ¯äœæš¹èã«ã€ããŠã¯ãæš¹èæ··åç©ã®å šäœã®ç¡
æ°Žç©å«æçã¯ããããã®ãšããã·åœéïŒã«å¯ŸããŠ
ç¡æ°Žç©åœéã0.5ã1.5ã§ãªããã°ãªããªãã çŽ45â以äžã§ç¡æ°Žç©ã«ã«ã€ã¹é žè§Šåªãæ·»å ãã
å Žåã«çºçããè²ã¯ãç¡æ°Žã«ã«ãã³é žåºãšãšãã
ã·å®èœæ§ã«å¯ŸããŠéåžžã«åå¿æ§ã«å¯ãã SnCl4ãª
ã©ã®ã«ã€ã¹é žãšã®éã®åå¿ã«ãããŠé»è·ç§»åé¯äœ
åå¿æ§ã€ãªã³æ§ç¡¬åå€ãçæããããšã瀺ããå
èšåå¿æ§ç¡¬åå€ã¯ç Žå£ãããªãã§æ®ãç¡æ°Žç©ç°äž
ã®äžå€®ã®é žçŽ ããé»åãå¡©å第ïŒé«ããã®ä»ã®ã«
ã€ã¹é žè§Šåªã®ååã«ä»äžãããããšã«ãã€ãŠãªã
ãœããŠã åã«ããªã³ãçæããããã®ã§ãããã
ã®ã«ããªã³ç³»ç¡¬åå€ã¯äžèšã®åå¿åŒã«ãã€ãŠäžè¬
ã«çæããç Žå£ãããªãç¡æ°Žç©ç°ãæããé»è·ç§»
åé¯äœããæ¬è³ªçã«ãªãã äžåŒäžïŒžã¯SbCl5ãSbF5ãBF3ãPF5ãTiCl4å
ã³SnCl4ããæã矀ããéžæãããããã®ã«ã«ã
ã³é žã«ããªã³ç³»ç¡¬åå€ã¯ãšããã·å®èœæ§ã®äžååš
äžã§ã¯ïŒžã«ãŠã³ã¿ãŒã¢ããªã³ã«ãã€ãŠå®å®åãã
ããäºå®èœæ§ç¡æ°Žç©ã䜿çšããå Žåãæåã¯ç¡
æ°Žç©åºã®äžæ¹ãŸãã¯äž¡æ¹ãšé¯äœã圢æããããšã
ãã·åºã®ååšäžã§ã¯ãè¿ éãªã«ããªã³éåãç¡æ°Ž
ç©åã³ãšããã·ååã®äž¡æ¹ãããã¿èŸŒããåè¿°ã®
æ§ã«ãç¡æ°Žç©åã³ã«ã€ã¹é žåå¿å€ãçŽ45âããé«
ãåå¿ç©è³ªæž©åºŠã§æ··åããå Žåãåèšé»è·ç§»åé¯
äœæ§é ã圢æããªããã«ããªã³ç³»ç¡¬åå€ãçæã
ãå Žåããã®æž©åºŠãå¶åŸ¡ããããšã¯æ¬çºæã«ãšã€
ãŠéèŠã§ããã ååŠéè«éããå°ãªãç¹å®ã®ã«ã€ã¹é žè§Šåªç¡æ°Ž
ç©ç¡¬åå€ããšããã·æš¹èã«ã€ããŠäœ¿çšã§ããè¯å¥œ
ãªå®€æž©ç¡¬åãéæããããšãã§ããäºå®ã«ãã€ãŠ
ãã®æ©æ§ãè£ä»ãããããããã¯éå°ã®ãšããã·
åºãåèšåå¿æ§ã«ããªã³ç©è³ªã«ããããŸãã¯ç¹å®
ã®ã«ã€ã¹é žè§Šåªã®çºçã«ããã«ããªã³æ©æ§ãçµãŠ
èªå·±åå¿ïŒç¡æ°Žç©ã¯äžååšïŒããå Žåã«ã®ã¿èµ·ã
ãã ãã®æ©æ§ã¯é«æž©ã§åå¿ããããªã«ã¬ãé«âç¡æ°Ž
ç©è§Šåªç©è³ªãåè¿°ã®ãããã®ïŒžç¡æ°Žç©åã®ãã®ã
ããªãåå¿æ§ãäœããã«ã€ããŠã説æãããã®ã§
ãããããªãã¡45âããã¯ããã«é«ãç±ãæœã
ãšãç¡æ°Žç©ç°ãéããåèšæ©æ§ã§ç€ºããã«ããªã³
ç³»ç©è³ªãç Žå£ããåå¿æ§ã®äœãé«ã«ã«ãã³é žãšã¹
ãã«ååç©ãçæããã æ¬çºæã«ãããŠæ¯äœæš¹èãšããŠäœ¿çšããããšã
ãã·æš¹èã®äžäŸã¯çŽ50âã§ã¢ã«ã«ãªæ§åªäœäžã§ãš
ãã¯ãã«ãããªã³ãïŒäŸ¡ããšããŒã«ãšåå¿ããã
ããšã«ãã€ãŠåŸãããïŒäŸ¡ããšããŒã«ïŒã¢ã«åœã
ïŒãïŒã¢ã«ä»¥äžã®ãšãã¯ãã«ãããªã³ã䜿çšãã
ãããã®å ç±ã¯åå¿ãè¡ãããã«æ°æéç¶ãã
ããçæç©ã¯ãããåŸå¡©åã³å¡©åºãç¡ããªããŸã§
æŽæµãããããã®çæç©ã¯åçŽãªåäžã®ååç©ã§
ã¯ãªããäžè¬ã«ã°ãªã·ãžã«ããªãšãŒãã«ã®è€éãª
æ··åç©ã§ãããããã®äž»èŠçæç©ã¯äžèšã®ååŠæ§
é åŒã«ãã€ãŠè¡šããããã äžåŒäžïœã¯é£ç¶æ°ïŒãïŒãïŒãïŒâŠâŠâŠâŠâŠã®
æŽæ°ã§ãããã¯ïŒäŸ¡ããšããŒã«ã®ïŒäŸ¡çåæ°ŽçŽ
åºã瀺ããã¯ä»£è¡šçã«ã¯ãã¹ããšããŒã«ïŒ¡åãš
ããã·æš¹èã®ãžã°ãªã·ãžã«ãšãŒãã«ãæäŸããã
ãã«ã¯ ã§ããããã¹ããšããŒã«ïŒŠåãšããã·æš¹èã®ãžã°
ãªã·ãžã«ãšãŒãã«ãæäŸããããã«ã¯ ã§ããã æ¬çºæã§äœ¿çšããããã¹ããšããŒã«ãšããã·æš¹
èã¯ïŒãã倧ããïŒã»ïŒâãšããã·äŸ¡ãæããã
ãããã¯äžè¬ã«ãžãšããã·ãã§ããããšããã·äŸ¡
ã¯ã°ãªã·ãžã«ãšãŒãã«ã®å¹³åååäžã«å«ãŸãã
ïŒã»ïŒâãšããã·åº ã®å¹³åæ°ãæå³ããã æ¬çºæã§æçšãªä»ã®ãšããã·æš¹èã®äŸã«ã¯ãã
ã©ãã¯ã®ããªã°ãªã·ãžã«ãšãŒãã«ããããæ¬çºæ
ã§äœ¿çšããã®ã«é©åœãªããã©ãã¯ã®ããªã°ãªã·ãž
ã«ãšãŒãã«ã¯ãšããããããªã³ãããšããŒã«ãã«
ã ã¢ã«ãããçž®åç©ãšåå¿ãããããšã«ãã€ãŠåŸ
ãããããã¹ããšããŒã«æ¯äœæš¹èã¯ïŒåååœãæ
é«ïŒåã®ãšããã·åºãæãããšããã·ããã©ãã¯
ã¯ïŒåååœãïŒå以äžãã®ãšããã·åºãæããã
ãšããã·ããã©ãã¯æš¹èã®è£œé ã®åºçºåæãšããŠ
ããšããŒã«ã®ä»ã«ïŒ¯âã¯ã¬ãŸãŒã«ãªã©ã®ã¢ã«ãã«
眮æããšããŒã«ã䜿çšãããã ä»ã®æçšãªãšããã·æš¹èã®äŸãšããŠã¯ã°ãªã·ãž
ã«ãšã¹ãã«ãããã³ãã€ã³ãšããã·æš¹èãç°åŒè
èªæãšããã·æš¹èãåã³èèªæãžãªãŒã«ã®ãžã°ãª
ã·ãžã«ãšãŒãã«ããããæ¬çºæã§äœ¿çšãããã°ãª
ã·ãžã«ãšã¹ãã«ãšããã·æš¹èã¯ïŒåååœãã®ïŒã»
ïŒâãšããã·åºãïŒåããå€ãéã°ãªã·ãžã«ãšãŒ
ãã«ãšããã·æš¹èã§ããããããã¯ãšãŒãã«çµå
ââããšã¹ãã«çµå
ãåå¿ãããã«ã«ãã³é žç¡æ°Žç©é¯äœãå«æãããš
ããã·æš¹èå«æ絶çžçµæç©ã«é¢ãããã®ã§ããã ã¢ãã³ç¡¬åç³»ãšããã·æš¹èããè¯å¥œãªç©ççå
ã³é»æ°çç¹æ§ãæäŸããé«æž©ã«ãããå®å®æ§ãæ¹
è¯ããããã«ã¯ãç¡æ°Žã«ã«ãã³é žç¡¬åå€ãé«å§çµ¶
çžçšã®ãšããã·æš¹èã«ç¹ã«æçšã§ããããšãçºèŠ
ããããããçš®ã®ç°åŒèèªæãšããã·æš¹èã«ã€ã
ãŠã¯ãã¢ãã³ç¡¬åå€ã¯ãããã®ã¿ã€ãã®ãšããã·
ããšæ¯èŒçåå¿æ§ãç¡ãããã«ãç¡æ°Žã«ã«ãã³é ž
ã ãã硬åå€ãšããŠäœ¿çšãããŠããã ããããªãããç¡æ°Žã«ã«ãã³é žç¡¬åå€ã䜿çšã
ãå Žåã®ïŒã€ã®é倧ãªæ¬ ç¹ã¯å®€æž©ã«è¿ã枩床ã§ã¯
åå¿æ§ãéåžžã«äœãããšã§ãããéåžžãé«æž©ã«ã
ããŠè¯å¥œãªã²ã«åæéãåŸãããã«ã¯ãä¿é²å€ã
æ·»å ããããšãå¿ èŠã§ããã宀枩ã«ãããŠã¯ã¯ã
ãã«é«æ¿åºŠã®ä¿é²å€ãå¿ èŠã§ããã宀枩硬åã®æ¡
件äžã§ã¯ããšããã·âç¡æ°Žç©æš¹èç³»ã¯å®å šã«ç¡¬å
ããäžç²çæ§ã®ç¶æ ã«æçµçã«å°éããåã«æ°é±
éç²çæ§ãä¿ã€ããšãæ®éã§ãããæè¿ããšãã
ã·âç¡æ°Žç©æš¹èç³»ã®æ¹è¯ããã宀枩硬åå€ãéçº
ããããã«ããªãã®åªåãæãããŠæ¥ãããã®èŠ
æ±ã¯æè¿ã®å€©ç¶ã¬ã¹è³æºã®æ¶žæžã®èŠ³ç¹ãããéèŠ
ãªã€ãŠæ¥ãŠãããããã«ããã°å·¥æ¥çã«æš¹èã硬
åããã®ã«å¿ èŠãªç±ãšãã«ã®ãŒãç¯çŽã§ããã ç±³åœç¹èš±ç¬¬3281376å·ïŒProopsïŒã¯é žç¡æ°Žç©ç¡¬
åå€ãå«æãããšããã·ãã宀枩ã§ç¡¬åããåé¡
ã解æ¶ããããšã«ã€ããŠé瀺ããŠãããäžããå
ããŠçŽ åã³å¡©å第ïŒé«ãªã©ã®ã«ã€ã¹é žãšãšããã·
æš¹èãšã®äºååå¿ã«ã€ããŠç 究ãããããã®çµå
ããã¯çºç±åã³çºæ³¡ãå¶åŸ¡ã§ããªãããã«æŸæ£ã
ãåŸãProopsã¯ç¬¬ïŒé«ããã©ãã¹ããžïŒããã
ã«ïŒããªã¹ããšãŒãããªã©ã®é«ææ©ãªã³é žå¡©ãšãš
ããã·ããšãäºååå¿ãããæ¹æ³ãçºèŠãããã
ã®åå¿ãããšããã·ãã¯ãããåŸå®€æž©ã§åŸã ã«ç¡¬
åãããŠãè¯ãããããã¯ã¢ãã³ãŸãã¯ç¡æ°Žããª
ã«ã«ãã³é žãªã©ã®ææ©ç¡¬åå€ãšå ±éåãããŠãè¯
ããç±³åœç¹èš±ç¬¬4020017å·ïŒSmithçïŒã¯ãå¡©å
ããªããšãã«é«ãªã©ã®ææ©é«ååç©ãå°é䜿çšã
ãŠèŠããäžåå¿æ§ãšããã·åžéå€ãšé¯äœã圢æ
ãããããç°åŒèèªæåã³ã°ãªã·ãžã«ãšã¹ãã«ãš
ããã·æš¹èã®æ·»å å€ãšããŠäœ¿çšããé žç¡æ°Žç©ã䜿
çšããªãé»æ°çµ¶çžæš¹èçµæç©ãæäŸããããšãé
瀺ããŠãããããããªããããããã®çµæç©ã¯å°
ããšã120âã®ç¡¬å枩床ãå¿ èŠãšããã ç±³åœç¹èš±ç¬¬3799905å·ïŒHollowayçïŒã¯ç¡é žãŸ
ãã¯å¡©é žãªã©ã®åŒ·åãªéã«ã«ãã³é žäžŠã³ã«BF3ã
SbCl5ãTiCl4ãSiCl4ãFeCl3ãAlCl3ãŸãã¯SnCl4
é¯äœããæã硬åå€ã«ãã€ãŠç¡¬åãããäœæž©ç¡¬å
æ§è湿æ§æ¯ç§çšãšããã·ãã«ã€ããŠé瀺ããŠã
ããããã²ã³åç©ååç©ïŒéã«ã«ãã³é žã®ééæ¯
ã¯50ã25ïŒ100ã§ãã€ãã硬åã¯åŸ©å æ¯ç§æè¡ã§
䜿çšäžã圢ãäœãããã«æ¯èŒçããããã§ãã€
ããé»æ°ççŽã®ãšããã·ãã«é¢ããç±³åœç¹èš±ç¬¬
3728306å·åã³ç¬¬3622524å·ïŒMarkovitzïŒã¯ææ©
é«é žåã³ææ©é«é žåç©ãããããç¡æ°Žã«ã«ãã³é ž
ãšäºååå¿ãããŠã100âããäœã枩床ã§ãšãã
ã·æš¹èã硬åãããåå¿çæç©ãçæããããšã«
ã€ããŠé瀺ããŠãããããããªãããå°ããšãçŽ
10ééïŒ ã®ææ©é«ååç©ãå«æããé«âç¡æ°Žç©å
å¿çæç©ã¯æº¶è§£ããŠæçšãªãšããã·åå¿æ§äœæž©ç¡¬
åå€ãçæããã®ã«çŽ75ã250âã§ïŒãïŒæéå
ç±ããããšãå¿ èŠãšãããéåžžãçŽ80ã160âã§
液åãããšããã·ãšåå¿ãããã®ã«è解ãå¿ èŠãš
ããåºäœãçæããããã®æ¹æ³ã®å Žåããããªã
ã®éã®ç±ãå¿ èŠã§ãã€ãã åŸã€ãŠãå¿ èŠãšããããã®ã¯ãç©ççãç±çãŸ
ãã¯é»æ°çç¹æ§ãæ倱ãããªãã§ãå®å šã«æ··åã§
ããçŽ45â以äžã®æž©åºŠã§è¿ éã«ç¡¬åãããšããã·
âç¡æ°Žã«ã«ãã³é žç³»ã®ããã®ç¡¬åçšæ·»å å€ã§ã
ãã åŸã€ãŠãæ¬çºæã¯äžå®èœæ§ç¡æ°Žç©ãå€å®èœæ§ç¡
æ°Žç©åã³ãããã®æ··åç©ããéžæããã液äœææ©
ã«ã«ãã³é žç¡æ°Žç©ãšãSnCl4ãTiCl4ãSbCl5ã
SbF5ãBF3ãPF5åã³ãããã®æ··åç©ããéžæã
ããã«ã€ã¹é žè§Šåªã®æ··åç©ãšããæ¬è³ªçã«æãã
ã«ã«ãã³é žã«ããªã³äœã圢æããŠãªãé»è·ç§»åé¯
äœã硬åå€ãšããŠå«ã¿ã10ã45âã®æž©åºŠã§ç¡¬åã
åŸãããšãç¹åŸŽãšããäœæž©ç¡¬åæ§ãšããã·æš¹è絶
çžçµæç©ã«é¢ãããã®ã§ããã SnCl4ãªã©ã®éžæãããã«ã€ã¹é žè§Šåªã¯å°éã§
ã«ã«ãã³é žç¡æ°Žç©ãšäºãåå¿ãããå Žåã奜ãŸã
ãã¯10ã45âã®åå¿ç©æž©åºŠã§ãšããã·æš¹èã®ç¹ã«
å¹æçãªäœæž©ç¡¬åå€ã§ããé»è·ç§»åé¯äœåå¿æ§ç©
質ãçæããããšãçºèŠãããããã®åå¿çæç©
é¯äœã¯å¥œãŸããã¯çŽ10ã45âã®åå¿ç©æž©åºŠã§ãšã
ãã·æš¹èãšæ··åããå ŽåãçŽ10ã45âã§ãçŽïŒã
168æé以å ãéåžžçŽïŒã48æé以å ã«ãšããã·
æš¹èã硬åãããããã®ç¡¬åãããšããã·æš¹èã¯
åŸç¡¬åïŒãã¹ãããŠã¢ïŒãå¿ èŠãšãããèããç©
ççãç±çåã³é»æ°çç¹æ§ãä¿æãããéžæãã
ãã«ã€ã¹é žè§ŠåªïŒç¡æ°Žã«ã«ãã³é žã®ééæ¯ã¯å¥œãŸ
ããã¯0.0060ïŒïŒã0.0001ïŒïŒã§ãããç¡æ°Žã«ã«
ãã³é žã掻æ§åãããã®ã«æå¹ãªã«ã€ã¹é žè§Šåªã¯
奜ãŸããã¯TiCl4ãŸãã¯SnCl4ã§ããã ç¹å®ã®ã«ã€ã¹é žè§Šåªã¯ç¡æ°Žææ©ã«ã«ãã³é žãšå¹
æçã«åå¿ããŠé¯äœã圢æããçŽ45â以äžã®æž©åºŠ
ã§ãšããã·æš¹èç³»ã硬åããã®ã«ç¹ã«æå¹ãªåå¿
ç©è³ªãæããããšãçºèŠãããããããã®äœæž©ç¡¬
åæ§æš¹èã¯çš®ã ã®çšéãããšãã°é«é硬åçšå°åº
æ圢ææãäœç²åºŠç空å«æµžçšçµæç©åã³é«åºŠå å¡«
泚å°ææçã«æçšã§ããã æãŸããã¯ããããã®æçšãªç¹å®ã®ã«ã€ã¹é žè§Š
åªã¯ç¡æ°Žã«ã«ãã³é žãš10ã45âã®åå¿ç©æž©åºŠã奜
ãŸããã¯25âã§æ··åããç¡æ°Žç©ç°ãç Žå£ããªãã§
çžäºäœçšãããŠé»è·ç§»åé¯äœåå¿æ§ç©è³ªãããªã
ã¡æŽ»æ§åç¡æ°Žã«ã«ãã³é žãçæããããã®æŽ»æ§å
ç¡æ°Žç©ã¯ãããåŸçŽ10ã45âã®åå¿ç©æž©åºŠã§ãšã
ãã·ã«å ãããããç¹å®ã®ã«ã€ã¹é žè§ŠåªïŒç¡æ°Žã«
ã«ãã³é žã®å¥œãŸããééæ¯ã¯0.0060ã0.0001ïŒ
ïŒãããã«å¥œãŸããã¯0.004ã0.0001ïŒïŒã§ã
ãã ç¡æ°Žç©ïŒéšåœãã®ã«ã€ã¹é žè§Šåªã®éã0.0060éš
ããå€ããšãç¡æ°Žç©ãšæ··åäžã«é«åºŠã®çºç±ãçã
ãåŸåããããããã«ãã€ãŠç¡æ°Žç©ç°ãéããé»
è·ç§»åé¯äœç¡¬åå€ãç Žå£ããåŸåããããããã
ã®çºç±ã¯å¯åå¿ãããšãã°èžçºã«ããæåã®æ
倱ãåã³å€ç°å¯ç£ç©ã®çæãªã©ãèµ·ãããããã¯
ãšããã·æš¹èã®ç¡¬åã«æãŸãããªããããã«ãŸã
硬åå€ããšããã·æš¹èãšæ··åããæã«ãé«éå±æ¿
床ãçãã硬åããæš¹èã®é»æ°çç¹æ§ã«æªåœ±é¿ã
åãŒããç¡æ°Žç©ïŒéšåœãã®ã«ã€ã¹é žè§Šåªã®éãé
ã«0.0001éšããå°ãªããšãçæããé»è·ç§»åé¯äœ
åå¿æ§ç©è³ªç¡¬åå€ã®éãå°ãªéããŠå¹åãç¡ããª
ãã ã«ã€ã¹é žè§Šåªãç¡æ°Žç©ãš45âããå®è³ªçã«é«ã
枩床ã§æ··åããå Žåãç¡æ°Žç©ç°ãéããå¯åå¿ã
çããŠèžçºã«ãã€ãŠæåã倱ãããé»è·ç§»åé¯äœ
ã«ããªã³åå¿æ§ç¡¬åå€ãç Žå£ããã掻æ§åããç¡
æ°Žç©ããšããã·æš¹èãš45âããå®è³ªçã«é«ã枩床
ã§æ··åããå Žåãå³åº§ã«ã²ã«åãèµ·ãããå質ãª
æ··åãäžå¯èœã«ããã10âããäœã枩床ã§ã®åå¿
ã¯é©åœãªçžäºäœçšãèµ·ããåŸåãããã液äœç¡æ°Ž
ç©ã®çµæ¶åãèµ·ãããæåã®æ··åãé£ããããª
ãã ç¹å®ã®ã«ã€ã¹é žè§Šåªåã³æ¯äœãšããã·æš¹èãšå
å¿æ§ã®æçšãªææ©ã«ã«ãã³é žç¡æ°Žç©ã®äŸãšããŠã¯
åŸæ¥ã®äžå®èœåã³å€å®èœç¡æ°Žç©ããããã«ã€ã¹é ž
觊åªãšæ··åãããç¡æ°Žç©æåã¯æ¶²ç¶ã§ãªããã°ãª
ããªãã液ç¶ãä¿ã€ããã«ã¯ãåºäœç¡æ°Žç©ã¯ãã
ã溶解ãã液äœç¡æ°Žç©ãšæ··åããããäžå®èœæ§ç¡
æ°Žç©ã®ä»£è¡šçãªãã®ã¯ãç¡æ°Žãããµããããã¿ã«
é žãç¡æ°ŽïŒâã¡ãã«ãããµããããã¿ã«é žãç¡æ°Ž
ããã©ããããã¿ã«é žãç¡æ°ŽïŒâã¡ãã«ããã©ã
ãããã¿ã«é žãç¡æ°Žãã¿ã«é žãç¡æ°Žããžãã¯é žã
ç¡æ°Žããžãã¯é žã¡ãã«ãç¡æ°Žã³ãã¯é žããã»ã
ã«ãç¡æ°Žãã¬ã€ã³é žçãããã䜿çšãåŸãå€å®èœ
æ§ç¡æ°Žç©ã®äŸãšããŠã¯ããã¡ãªããé žãžç¡æ°Žç©ã
ããªã¢ãŒã©ã€ã³é žããªç¡æ°Žç©ãç¡æ°Žããªã¡ãªãã
é žãšã°ãªã³ãŒã«ãšã®åå¿çæç©ãåã³ãã³ãŸããš
ãã³ããã©ã«ã«ãã³é žãžç¡æ°Žç©ãããããããã®
ææ©ç¡æ°Žç©ã¯åç¬ã§ãããŸãã¯æ··åç©ãšããŠã䜿
çšã§ããæçµçã«æ¶²ç¶ã®ãã®ãæäŸãããéã«ã«
ãã³é žãŸãã¯éã«ã«ãã³é žç¡æ°Žç©ã¯ãã®ç³»ã«ãã
ãŠé©åœãªåå¿ãŸãã¯ç¡¬åãæäŸããã®ã«æçšã§ãª
ããæ¯äœæš¹èã«ã€ããŠã¯ãæš¹èæ··åç©ã®å šäœã®ç¡
æ°Žç©å«æçã¯ããããã®ãšããã·åœéïŒã«å¯ŸããŠ
ç¡æ°Žç©åœéã0.5ã1.5ã§ãªããã°ãªããªãã çŽ45â以äžã§ç¡æ°Žç©ã«ã«ã€ã¹é žè§Šåªãæ·»å ãã
å Žåã«çºçããè²ã¯ãç¡æ°Žã«ã«ãã³é žåºãšãšãã
ã·å®èœæ§ã«å¯ŸããŠéåžžã«åå¿æ§ã«å¯ãã SnCl4ãª
ã©ã®ã«ã€ã¹é žãšã®éã®åå¿ã«ãããŠé»è·ç§»åé¯äœ
åå¿æ§ã€ãªã³æ§ç¡¬åå€ãçæããããšã瀺ããå
èšåå¿æ§ç¡¬åå€ã¯ç Žå£ãããªãã§æ®ãç¡æ°Žç©ç°äž
ã®äžå€®ã®é žçŽ ããé»åãå¡©å第ïŒé«ããã®ä»ã®ã«
ã€ã¹é žè§Šåªã®ååã«ä»äžãããããšã«ãã€ãŠãªã
ãœããŠã åã«ããªã³ãçæããããã®ã§ãããã
ã®ã«ããªã³ç³»ç¡¬åå€ã¯äžèšã®åå¿åŒã«ãã€ãŠäžè¬
ã«çæããç Žå£ãããªãç¡æ°Žç©ç°ãæããé»è·ç§»
åé¯äœããæ¬è³ªçã«ãªãã äžåŒäžïŒžã¯SbCl5ãSbF5ãBF3ãPF5ãTiCl4å
ã³SnCl4ããæã矀ããéžæãããããã®ã«ã«ã
ã³é žã«ããªã³ç³»ç¡¬åå€ã¯ãšããã·å®èœæ§ã®äžååš
äžã§ã¯ïŒžã«ãŠã³ã¿ãŒã¢ããªã³ã«ãã€ãŠå®å®åãã
ããäºå®èœæ§ç¡æ°Žç©ã䜿çšããå Žåãæåã¯ç¡
æ°Žç©åºã®äžæ¹ãŸãã¯äž¡æ¹ãšé¯äœã圢æããããšã
ãã·åºã®ååšäžã§ã¯ãè¿ éãªã«ããªã³éåãç¡æ°Ž
ç©åã³ãšããã·ååã®äž¡æ¹ãããã¿èŸŒããåè¿°ã®
æ§ã«ãç¡æ°Žç©åã³ã«ã€ã¹é žåå¿å€ãçŽ45âããé«
ãåå¿ç©è³ªæž©åºŠã§æ··åããå Žåãåèšé»è·ç§»åé¯
äœæ§é ã圢æããªããã«ããªã³ç³»ç¡¬åå€ãçæã
ãå Žåããã®æž©åºŠãå¶åŸ¡ããããšã¯æ¬çºæã«ãšã€
ãŠéèŠã§ããã ååŠéè«éããå°ãªãç¹å®ã®ã«ã€ã¹é žè§Šåªç¡æ°Ž
ç©ç¡¬åå€ããšããã·æš¹èã«ã€ããŠäœ¿çšã§ããè¯å¥œ
ãªå®€æž©ç¡¬åãéæããããšãã§ããäºå®ã«ãã€ãŠ
ãã®æ©æ§ãè£ä»ãããããããã¯éå°ã®ãšããã·
åºãåèšåå¿æ§ã«ããªã³ç©è³ªã«ããããŸãã¯ç¹å®
ã®ã«ã€ã¹é žè§Šåªã®çºçã«ããã«ããªã³æ©æ§ãçµãŠ
èªå·±åå¿ïŒç¡æ°Žç©ã¯äžååšïŒããå Žåã«ã®ã¿èµ·ã
ãã ãã®æ©æ§ã¯é«æž©ã§åå¿ããããªã«ã¬ãé«âç¡æ°Ž
ç©è§Šåªç©è³ªãåè¿°ã®ãããã®ïŒžç¡æ°Žç©åã®ãã®ã
ããªãåå¿æ§ãäœããã«ã€ããŠã説æãããã®ã§
ãããããªãã¡45âããã¯ããã«é«ãç±ãæœã
ãšãç¡æ°Žç©ç°ãéããåèšæ©æ§ã§ç€ºããã«ããªã³
ç³»ç©è³ªãç Žå£ããåå¿æ§ã®äœãé«ã«ã«ãã³é žãšã¹
ãã«ååç©ãçæããã æ¬çºæã«ãããŠæ¯äœæš¹èãšããŠäœ¿çšããããšã
ãã·æš¹èã®äžäŸã¯çŽ50âã§ã¢ã«ã«ãªæ§åªäœäžã§ãš
ãã¯ãã«ãããªã³ãïŒäŸ¡ããšããŒã«ãšåå¿ããã
ããšã«ãã€ãŠåŸãããïŒäŸ¡ããšããŒã«ïŒã¢ã«åœã
ïŒãïŒã¢ã«ä»¥äžã®ãšãã¯ãã«ãããªã³ã䜿çšãã
ãããã®å ç±ã¯åå¿ãè¡ãããã«æ°æéç¶ãã
ããçæç©ã¯ãããåŸå¡©åã³å¡©åºãç¡ããªããŸã§
æŽæµãããããã®çæç©ã¯åçŽãªåäžã®ååç©ã§
ã¯ãªããäžè¬ã«ã°ãªã·ãžã«ããªãšãŒãã«ã®è€éãª
æ··åç©ã§ãããããã®äž»èŠçæç©ã¯äžèšã®ååŠæ§
é åŒã«ãã€ãŠè¡šããããã äžåŒäžïœã¯é£ç¶æ°ïŒãïŒãïŒãïŒâŠâŠâŠâŠâŠã®
æŽæ°ã§ãããã¯ïŒäŸ¡ããšããŒã«ã®ïŒäŸ¡çåæ°ŽçŽ
åºã瀺ããã¯ä»£è¡šçã«ã¯ãã¹ããšããŒã«ïŒ¡åãš
ããã·æš¹èã®ãžã°ãªã·ãžã«ãšãŒãã«ãæäŸããã
ãã«ã¯ ã§ããããã¹ããšããŒã«ïŒŠåãšããã·æš¹èã®ãžã°
ãªã·ãžã«ãšãŒãã«ãæäŸããããã«ã¯ ã§ããã æ¬çºæã§äœ¿çšããããã¹ããšããŒã«ãšããã·æš¹
èã¯ïŒãã倧ããïŒã»ïŒâãšããã·äŸ¡ãæããã
ãããã¯äžè¬ã«ãžãšããã·ãã§ããããšããã·äŸ¡
ã¯ã°ãªã·ãžã«ãšãŒãã«ã®å¹³åååäžã«å«ãŸãã
ïŒã»ïŒâãšããã·åº ã®å¹³åæ°ãæå³ããã æ¬çºæã§æçšãªä»ã®ãšããã·æš¹èã®äŸã«ã¯ãã
ã©ãã¯ã®ããªã°ãªã·ãžã«ãšãŒãã«ããããæ¬çºæ
ã§äœ¿çšããã®ã«é©åœãªããã©ãã¯ã®ããªã°ãªã·ãž
ã«ãšãŒãã«ã¯ãšããããããªã³ãããšããŒã«ãã«
ã ã¢ã«ãããçž®åç©ãšåå¿ãããããšã«ãã€ãŠåŸ
ãããããã¹ããšããŒã«æ¯äœæš¹èã¯ïŒåååœãæ
é«ïŒåã®ãšããã·åºãæãããšããã·ããã©ãã¯
ã¯ïŒåååœãïŒå以äžãã®ãšããã·åºãæããã
ãšããã·ããã©ãã¯æš¹èã®è£œé ã®åºçºåæãšããŠ
ããšããŒã«ã®ä»ã«ïŒ¯âã¯ã¬ãŸãŒã«ãªã©ã®ã¢ã«ãã«
眮æããšããŒã«ã䜿çšãããã ä»ã®æçšãªãšããã·æš¹èã®äŸãšããŠã¯ã°ãªã·ãž
ã«ãšã¹ãã«ãããã³ãã€ã³ãšããã·æš¹èãç°åŒè
èªæãšããã·æš¹èãåã³èèªæãžãªãŒã«ã®ãžã°ãª
ã·ãžã«ãšãŒãã«ããããæ¬çºæã§äœ¿çšãããã°ãª
ã·ãžã«ãšã¹ãã«ãšããã·æš¹èã¯ïŒåååœãã®ïŒã»
ïŒâãšããã·åºãïŒåããå€ãéã°ãªã·ãžã«ãšãŒ
ãã«ãšããã·æš¹èã§ããããããã¯ãšãŒãã«çµå
ââããšã¹ãã«çµå
ãåŒãã§çœ®æãã
ããšã«ãã€ãŠç¹åŸŽã¥ããããäžèšã®ååŠæ§é åŒã
æããã äžåŒäžïŒ²ã¯Râ²ãRâ²ââRâ²ãRâ²âCOOâRâ²å
ã³ãããã®æ··åç©ïŒRâ²ã¯çŽïŒãïŒåã®ççŽ åå
ãæããã¢ã«ãã¬ã³åºãïŒãïŒåã®ççŽ ååã®ç°
ãæãã飜åã·ã¯ãã¢ã«ãã¬ã³åºåã³ãããã®æ··
åç©ããéžæããããã®ïŒããæã矀ããéžæã
ããïœã¯çŽïŒãïŒã§ããã æ¬çºæã§äœ¿çšã§ããããã³ãã€ã³ãšããã·æš¹è
ã¯æ§é åŒ ãæããçªçŽ å«æè€çŽ ç°ã§ããããã³ãã€ã³ã«åº
ã¥ããïŒå¡ããã³ãã€ã³ç°äžã®çªçŽ ã®äœçœ®ãåå¿
ãããããšã«ãã€ãŠåºç¯å²ã®çš®ã ã®ååç©ãçæ
ã§ãããããã³ãã€ã³ç°ã¯ã±ãã³ãæ°ŽçŽ ãã·ã¢ã³
åç©ãã¢ã³ã¢ãã¢ãäºé žåççŽ åã³æ°Žãã容æã«
åæãããããã®ãšããã·æš¹èã¯ããã³ãã€ã³ãš
ãšãã¯ãã«ãããªã³ãšã®åå¿ã«ãã€ãŠçæãã
ããããã³ãã€ã³ç°ã¯äžç·ã«çµåããŠæ§é ããã¹
ããšããŒã«ïŒ¡ã«é¡äŒŒããéã®å»¶ã³ãæš¹èãåŸãã
ããå€å®èœæ§æš¹èãæ°Žé žåºåã³æ®åçªçŽ ãã°ãªã·
ãžã«åããããšã«ãã€ãŠãããã®éã®å»¶ã³ãç©è³ª
ããçæã§ããããããã®è€çŽ ç°åŒã°ãªã·ãžã«ã¢
ãã³ãšããã·æš¹èã¯æ§é åŒã ã«ãã€ãŠè¡šããããã æ¬çºæã®æš¹èæåãšããŠäœ¿çšãããç°åŒèèªæ
ã¿ã€ããšããã·æš¹èã¯ïŒåååœãïŒåããå€ã
ïŒã»ïŒâãšããã·åºãæããéã°ãªã·ãžã«ãšãŒã
ã«ãšããã·æš¹èããéžæãããããããã¯äžè¬ã«
éå®æ¯éŠé žåã³éé ¢é žãªã©ã®éé žãããã¯éé žå
æ°ŽçŽ ã䜿çšããŠã·ã¯ããªã¬ãã€ã³ãªã©ã®äžé£œåè³
éŠæçåæ°ŽçŽ ååç©ããšããã·åããããšã«ãã€
ãŠè£œé ããããææ©éé žã¯äžè¬ã«éé žåæ°ŽçŽ ãã«
ã«ãã³é žãé žå¡©åç©ãŸãã¯ã±ãã³ãšåå¿ãããŠå
åç©ïŒ²âCOOOHãçæããããšã«ãã€ãŠè£œé ã
ããã ç°åŒèèªæãšããã·æš¹èã®äŸãšããŠã¯ïŒã»ïŒâ
ãšããã·ã·ã¯ãããã·ã«ã¡ãã«âïŒã»ïŒâãšãã
ã·ã·ã¯ããããµã³ã«ã«ããã·ã¬ãŒãïŒç°æ§é ã®äž
éšãæãïŒåã®ãšããã·åºåã³ãšã¹ãã«çµåãæ
ããïŒïŒäºé žåããã«ã¯ãããã»ã³ïŒïŒåã®ãšã
ãã·åºãæãããã®äžæ¹ã¯ç°æ§é ã®äžéšãæ
ãïŒïŒïŒã»ïŒâãšããã·âïŒâã¡ãã«ã·ã¯ããã
ã·ã«ã¡ãã«âïŒã»ïŒâãšããã·âïŒâã¡ãã«ã·ã¯
ããããµã³ã«ã«ããã·ã¬ãŒãåã³ãžã·ã¯ããã³ã¿
ãžãšã³ãããã ä»ã®æçšãªãšããã·æš¹èã®äŸãšããŠã¯ççŽ åå
æ°ãïŒã12åã®èèªæãžãªãŒã«ã®ãžã°ãªã·ãžã«ãš
ãŒãã«ãããããããã¯äœç²åºŠã®ãšããã·æš¹è
ã§ãéåžžã¢ãããŒã§ããããããã¯ã°ãªã·ãžã«ãš
ãŒãã«åäœéã«ççŽ ååæ°ãïŒã12åã®ã°ãªã³ãŒ
ã«ãé ãããžã°ãªã·ãžã«ãšãŒãã«ãããªãã¡ã°ãª
ã³ãŒã«åäœäžã®ççŽ ååæ°ãïŒã12åã§ãããã®
ã§ãããããšãã°ããªãã³ãã«ã°ãªã³ãŒã«ã®ãžã°
ãªã·ãžã«ãšãŒãã«ïŒDGENPGïŒãïŒã»ïŒâãã¿ã³
ãžãªãŒã«ã®ãžã°ãªã·ãžã«ãšãŒãã«ããšãã¬ã³ã°ãª
ã³ãŒã«ã®ãžã°ãªã·ãžã«ãšãŒãã«åã³ããªãšãŒãã«
ã°ãªã³ãŒã«ã®ãžã°ãªã·ãžã«ãšãŒãã«ãããšãã°ã
ãªãšãã¬ã³ã°ãªã³ãŒã«ã®ãžã°ãªã·ãžã«ãšãŒãã«å
ã³ããã©ãšãã¬ã³ã°ãªã³ãŒã«ã®ãžã°ãªã·ãžã«ãšãŒ
ãã«åã³ãããã®æ··åç©çãããã èèªæãžãªãŒã«ãšããã·ãã¯å šãŠäœç²åºŠç©è³ª
ïŒäžè¬ã«25âã§çŽïŒã60cpsïŒã§ãããå«æµžã®ç®
çã®ããã®æš¹èçµæç©ã®ç²åºŠãäœäžãããã®ã«åœ¹
ç«ã€ã®ã§ãå Žåã«ãã€ãŠã¯ãããã®èèªæãžãªãŒ
ã«ã®ãžã°ãªã·ãžã«ãšãŒãã«ã®ãããããä»ã®ãšã
ãã·æš¹èãšçµåãããŠäœ¿çšããã®ãæçšã§ããã
ãã®ãšããã·æš¹èç³»ã¯ã(A)äœç²åºŠïŒ25âã§çŽïŒã
60cpsïŒãæãã第ïŒãšããã·æš¹èãããªãã¡è
èªæãžãªãŒã«ã®ãžã°ãªã·ãžã«ãšãŒãã«åã³(B)é«ç²
床ïŒ25âã§çŽ250cps以äžãäžè¬ã«çŽ250ã
20000cpsïŒãæãã第ïŒãšããã·æš¹èãããªã
ã¡ãã¹ããšããŒã«ïŒ¡ããã¹ããšããŒã«ïŒŠãããã©
ãã¯ãã°ãªã·ãžã«ãšã¹ãã«ãããã³ãã€ã³ãç°åŒ
èèªæåã³ãããã®æ··åç©ããæããåèšç¬¬ïŒãš
ããã·æš¹è(A)ïŒåèšç¬¬ïŒãšããã·æš¹è(B)ã®ééæ¯
ã¯çŽïŒïŒ0.5ãïŒã§ããã ãããã®ãšããã·æš¹èã®å šãŠã¯ïŒåååœãã®ãš
ããã·åºã®å¹³åæ°ã§æš¹èã®å¹³åååéãå²ã€ãå€
ã§ãããšããã·åœéã«ãã€ãŠç¹åŸŽã¥ãããããæ¬
çºæã«ãããŠãé©åœãªãšããã·æš¹èã®å šãŠã¯å¥œãŸ
ããã¯çŽ100ã500ããã奜ãŸããã¯çŽ150ã250ã®
ãšããã·åœéãæããããããã®ãšããã·æš¹èã®
å šãŠã¯å ¬ç¥ã§ãããåžè²©ãããŠããããããã®æ§
é åã³è£œé æ³ã®è©³çŽ°ã«ã€ããŠã¯Leeåã³Nevilleè
ã®âHandbook of Epoxy ResinsâïŒMcGrawâ
Hill瀟ã1967ãCh.2â10ãïŒâ27ïŒåã³ç±³åœç¹èš±
第4137275å·ãåç §ããããã ããã€ãã®ç¹å¥ãªç®çã®å Žåã«ã¯ãçŽéã®ãšã
ãã·âç¡æ°Žç©æš¹èç³»ã¯ããçš®ã®æ¬ ç¹ãæãããã
ããã®æ¬ ç¹ã¯è²»çšãé«ããå Žåã«ãã€ãŠã¯åæ§ã
倧ãéããããšã§ããããããã®ãšããã·æš¹èã¯
çš®ã ã®åžéå€ãæè»å€åã³å å¡«å€ã«ãã€ãŠå€æ§ã
ãŠãè¯ãã å«æµžç®çã®ããã«ã¯ããšããã·âç¡æ°Žç©æš¹èç³»
ã®ç²åºŠãäœäžãããã®ã«äœ¿çšã§ããç©è³ªã®äžäŸãš
ããŠã¯æ¶²ç¶ã¢ããšãã¬ã³ç³»äžé£œåããã«ã¢ãããŒ
ããããæçšãªããã«ã¢ãããŒã®äŸãšããŠã¯ã¹ã
ã¬ã³ãïœâããã«ã¹ãã¬ã³ãããã«ãã«ãšã³ãã¡
ãã«ã¡ã¿ã¯ãªã¬ãŒããã¡ãã«ããã«ã±ãã³åã³ã
ããã®æ··åç©çãããããããã¯ãšããã·æš¹è
100éšåœã300éšä»¥äžã奜ãŸããã¯50ã250éšã®é
ã§äœ¿çšãããããããã®ç©è³ªã®çµåããã¯25âã§
ïŒã25cpsã®ç²åºŠãæããå«æµžçšã¯ãã¹ãæäŸã
ãã ãŸããšããã·å倩ç¶æ²¹ãšãã¹ãã³ããŒãããšã
ã°ãšããã·åã¢ããæ²¹ãŸãã¯å€§è±æ²¹åã³ãªã¯ãã«
ãšããã·ã¿ã¬ãŒã䞊ã³ã«åå¿æ§å¯å¡å€ãããšãã°
åŸæ¥ã®ãã¿ã¬ãŒãåã³ããªã¹ããšãŒãããšããã·
æš¹è100éšåœãçŽ40éšä»¥äžã®å°éã§äœ¿çšããŠæè»
æ§ãé«ããŠãè¯ããããã«ãŸãSiO2ãªã©ã®ãã
ãœãããŒãå€åã³TiO2ãªã©ã®é¡æã䜿çšããŠçµ
æç©ã®æµåæ§ãæ¹è¯ãããã硬åããæš¹èã®è²èª¿
ãé«ããŠãè¯ããåæ§ã«ãå¹³åç²åãµã€ãºãçŽ10
ã300ãã¯ãã³ã®çš®ã ã®ç²ç¶ç¡æ©å å¡«å€ãããšã
ã°ã·ãªã«ãç³è±ãããªãªãŠã ã¢ã«ãããŠã ã·ãªã±
ãŒãããªããŠã ã¢ã«ãããŠã ã·ãªã±ãŒãåã³ãã
ãã®æ··åç©ããšããã·æš¹è100éšåœãçŽ100éšä»¥äž
ã®éã§äœ¿çšããŠæš¹èã®é»æ°çç¹æ§ãæ¹è¯ããã³ã€
ã«ããã©ã³ã¹ãããã·ã³ã°ã¹ã¿ããçã®æ³šå°ææ
ãæäŸããŠãè¯ãã æ¬çºæã§äœ¿çšããé»è·ç§»åé¯äœã¯æ¶²ç¶ã«ã«ãã³
é žç¡æ°Žç©ãç¹å®ã®ã«ã€ã¹é žè§Šåªãšåã«æ··åããã
ãšã«ãã€ãŠãéåžžåèšè§Šåªã氷济äžã§åå¿ç©æž©åºŠ
ã10ã45âã«èª¿ç¯ããªãã滎äžããããšã«ãã€ãŠ
掻æ§åãããç¶æ ã§åŸããããšããã·æš¹èã®ãã
ã®åå¿æ··åç©ã®é»è·ç§»åé¯äœåå¿æ§ç¡¬åå€ãçæ
ããã掻æ§åããç¡æ°Žç©ã®äºãåå¿ããåå¿æ··å
ç©ã¯ãããåŸå¥œãŸããã¯10ã45âãé垞宀枩ã®å
å¿ç©æž©åºŠã§ãšããã·æš¹èã«å ãããããã®æš¹èçµ
æç©ã¯ãããåŸçš®ã ã®å°é»æ§éšæãããšãã°é ãŸ
ãã¯ã¢ã«ãããŠã ã¯ã€ã€ãããªã€ã«ãããã¯ã¹ã¿
ããçã«å«æµžæš¹èããšãã¡ã«ã泚åãŸãã¯æ³šå°æ
æãããã¯é«éå°åºæ圢ææçãšããŠæœãããã
ãšããã·æš¹è100éééšåœãçŽ25ã200éééšã®æŽ»
æ§åç¡æ°Žç©é¯äœãå ãããããç¹å®ã®ã«ã€ã¹é žè§Š
åªããšããã·æš¹èãšæ··åããåã«ç¡æ°Žã«ã«ãã³é ž
ãšåå¿ããŠæŽ»æ§åç¡æ°Žç©ã圢æããããšãæ¬çºæ
ã®ç¹åŸŽã§ããããšããã·æŽ»æ§åç¡æ°Žç©çµæç©ã¯10
ã45âã§168æé以å ãäžè¬ã«ïŒã48æé以å ã«
ã段éããŸã§ç¡¬åããçŽ95ïŒ ã®äº€åçµå床ã®å®
質çã«å®å šã«ç¡¬åããäžèæ§ã§ã硬ããäžç²çæ§
ã§æé¢ãèããåããã§ãã絶çžäœãæäŸããã
ãã®ããã«äœæž©ã§ç¡¬åããæš¹èã¯åŸç¡¬åïŒãã¹ã
ããŠã¢ïŒããå¿ èŠãç¡ãã 第ïŒå³ã«ã¯ã絶çžãããé«é»å§é»æ°ã¢ãŒã¿ãŒãŸ
ãã¯çºé»æ©ãªã©ã®çµ¶çžãããé»é«å§é»æ°æ©æ¢°ã«æ¿
å ¥ããããã«è£œé ãããéã³ã€ã«10å šäœã瀺ãã
ãŠãããåèšã³ã€ã«ã¯éå±ã¢ãŒã¿ãŒé»æ©åãŸãã¯
çºé»æ©å転åãå²ãåºå®åã®ã¹ãããäžã«é 眮ã
ãããåèšã³ã€ã«ã¯ãã¿ã³ãžãšããïŒïŒãæ¥ç¶ã«
ãŒãïŒïŒåã³è£žãªãŒãç·ïŒïŒã延ã³ãŠããå¥ã®ã¿
ã³ãžãšã³ãïŒïŒããæã端éšãæãããåèšã³ã€
ã«ã®ã¹ãããéšåïŒïŒåã³ïŒïŒã¯å Žåã«ãã€ãŠã¯
ç±ãã¬ã¹ãããŠæš¹èãäºå硬åãããŠæå®ã®åœ¢ç¶
åã³ãµã€ãºã«ããããããã¿ã³ãžãšã³ãïŒïŒåã³
ïŒïŒã«æ¥ç¶ãããŠããããããã®ã¹ãããéšåã¯
ãŸãå¥ã®ã«ãŒãïŒïŒãéããŠæ¥ç¶ãããŠããä»ã®
ã¿ã³ãžãšã³ãïŒïŒåã³ïŒïŒã«æ¥ç¶ãããŠãããäž
è¬ã«ãçºé»æ©ã³ã€ã«ã¯å·»ãåã«å«æµžãããããã
åŸç±ãã¬ã¹ãããããã¢ãŒã¿ãŒã³ã€ã«ã¯äžè¬ã«ã
ã®å Žã§å«æµžãããã åèšã³ã€ã«ã¯é»æ°æ©æ¢°ã®åºå®åã®ã¹ãããäžã«
é 眮ããã端éšå·»ç·ã¯å ãŸããçµåãããã絶çž
ãããŠããªããªãŒãç·ã¯ãããåŸäºãã«ãŸãã¯æŽ
æµåã«ãã³ãã¥ãã溶æ¥ãŸãã¯ä»ã®æ¹æ³ã§æ¥ç¶ã
ãããã¢ãŒã¿ãŒã®å Žåãäžè¬ã«ã³ã€ã«ãæããã¢
ãŒã¿ãŒå šäœãæ¬çºæã®äœç²åºŠæš¹èãå ¥ããå«æµžæµŽ
äžã«å ¥ããããç空å«æµžãããããããåŸããã®
å«æµžããã¢ãŒã¿ãŒãå«æµžã¿ã³ã¯ããååºãã液ã
ããã空æ°ä¹Ÿç¥ãŸãã¯çŽ45â以äžã®äœæž©ã§å ç±
ããã³ã€ã«äžã®å åã«åå¿æ§ã®çµæç©ã硬åã
ãããŸãã¯æ¬çºæã®çµæç©ãé»æ°å·»ç·ã«ãããã
èœãšããŠãè¯ãã 第ïŒå³ã¯ç¡¬åãã泚å°çµ¶çžäœïŒïŒäžã§æ³šå°ãŸã
ã¯ã«ãã»ã«å°ãããå°äœïŒïŒãæããã³ã€ã«ïŒïŒ
ãªã©ã®çµ¶çžãããé»æ°éšæã瀺ããåèšæ³šå°çµ¶çž
äœã¯åèšé»æ°éšæã«æœããŠã宀枩ãŸãã¯çŽ45â以
äžã®äœæž©ã§å ç±ããŠç¡¬åããæ¬çºæã®æš¹èçµæç©
ã§ããã 第ïŒå³ã¯å å¡«æãå åã«å«ãæ¬çºæã®æš¹èçµæ
ç©ãå°äœã¹ã¿ããïŒïŒã®åšå²ã«æ³šå°ãããŠåŸãã
ãããã·ã³ã°çµ¶çžäœïŒïŒãæããããã·ã³ã°çµäœ
ã瀺ãã æ¬çºæã¯äžèšã®å®æœäŸã«ãã€ãŠããã«è©³ãã説
æãããã äŸ æ¯äœæš¹èãšããŠ25âã§350ã450cpsã®ç²åºŠãæ
ãã液äœãšããã·æš¹èã§ããïŒã»ïŒâãšããã·ã·
ã¯ãããã·ã«ã¡ãã«âïŒã»ïŒâãšããã·ã·ã¯ãã
ããµã³ã«ã«ããã·ã¬ãŒãïŒUnion Carbide瀟ãã
åžè²©ãããŠããåååãâERLâ4221âã®ç°åŒ
èèªæãšããã·æš¹èïŒ100éšãããããå«æãã
ïŒçš®ã®æš¹èçµæç©ã調補ããããµã³ãã«(A)ã«ãã
ãŠã¯ãå¡©å第ïŒé«ïŒSnCl4ïŒ0.2éšãïŒåéã«ãã
ã€ãŠæ»ŽäžããŠæ¶²äœç¡æ°Žããžãã¯é žã¡ãã«
ïŒNMAïŒ100éšãšæ··åãããã®åå¿æ··åç©ã氷济
äžã§çŽ20âã«ä¿ã€ããåè¿°ã®åå¿çæç©ã§ããé»
è·ç§»åé¯äœã®æŽ»æ§åããç¡æ°Žç©ã®æº¶æ¶²ã¯æ··ååŸã
æ·¡é»è²ãããã¯ãè²ã«å€ãã€ãããã®æŽ»æ§åãã
ç¡æ°Žç©100éšããããåŸ10åéã«ããã€ãŠ25âã®
æ··å枩床ã§100éšã®æ¶²äœERLâ4221ãšç©è³ªã«æ··å
ããããµã³ãã«(B)ã«ãããŠã¯ã0.14éšã®SnCl4ã
ïŒåéã«ããã€ãŠæ»ŽäžããŠïŒâã¡ãã«ããã©ãã
ããã¿ã«é žç¡æ°Žç©ïŒTHPAïŒ100éšãšæ··åããã
ã®åå¿æ··åç©ã¯æ°·æµŽäžã§çŽ20âã«ä¿ã€ããåå¿ç
æç©ã§ããé»è·ç§»åé¯äœã®æŽ»æ§åããç¡æ°Žç©ã®æº¶
液ã¯æ··ååŸãæ·¡é»è²ãããã¯ãè²ã«å€ãã€ããã
ã®æŽ»æ§åããç¡æ°Žç©100éšããããåŸ10åéã«ã
ãã€ãŠ25âã®æ··å枩床ã§100éšã®æ¶²äœERLâ4221
ãšç©è³ªã«æ··åããããµã³ãã«(C)ã«ãããŠã¯ãåå¡©
åãã¿ã³ïŒTiCl4ïŒ0.4éšã滎äžããŠæ¶²äœïŒâã¡ã
ã«ããã©ããããã¿ã«é žç¡æ°Žç©ïŒTHPAïŒ100éš
ãšæ··åãããã®åå¿æ··åç©ã¯æ°·æµŽäžã§çŽ20âã«ä¿
ã€ããåå¿çæç©ã§ããé»è·ç§»åé¯äœã®æŽ»æ§åã
ãç¡æ°Žç©ã®æº¶æ¶²ã¯æ··ååŸãæ·¡é»è²ãããã¯ãè²ã«
å€ãã€ãããã®æŽ»æ§åããç¡æ°Žç©100éšãããã
åŸ10åéã«ããã€ãŠ25âã®æ··å枩床ã§100éšã®æ¶²
äœERLâ4221ãšå質ã«æ··åããããµã³ãã«(D)ã«
ãããŠã¯ã0.56éšã®SnCl4ã滎äžããŠïŒâã¡ãã«
ããã©ããããã¿ã«é žç¡æ°Žç©ïŒTHPAïŒ100éšãš
æ··åãããã®åå¿æ··åç©ã氷济äžã§35âããäœã
枩床ã«ä¿ã€ãããã®åå¿çæç©ã§ããé»è·ç§»åé¯
äœã®æŽ»æ§åããç¡æ°Žç©ã®æº¶æ¶²ã¯æ··ååŸãæ·¡é»è²ã
ãéåžžã«æ¿ããã¯ãè²ã«å€ãããããªãã®çºç±ã
瀺ãå§ããããã®æŽ»æ§åããç¡æ°Žç©100éšããã
ãåŸ100éšã®æ¶²äœERLâ4221ãšæåçŽ25âã®æ··å
枩床ã§æ··åããããã®ç¡¬åå€âãšããã·æ··åç©ã¯
ç²åºŠãçŽã¡ã«é«ãŸãå§ãããã®æ··åç©ã®æž©åºŠã¯çŽ
40âã«é«ãŸã€ãããã®ãµã³ãã«ã¯å®å šã«å質ãªæ··
åãæãããåã«æ³šåããªããã°ãªããªãã€ãã æ¯èŒäŸãšããŠããµã³ãã«(E)ã補é ããããµã³ã
ã«(E)ã®è£œé ã«ãããŠã¯ãïœâããã«é«é ž
ïŒBSAïŒ172éšãç¡æ°Žããžãã¯é žã¡ãã«100éšãšã
100âã§ïŒæéãããã«150âã§çŽïŒæéæ··åãã
åèšææ©é«é žãåèšç¡æ°Žç©ã«æº¶è§£ãã溶液ãæäŸ
ããã25âã«å·åŽããåŸãåèšæ··åç©ã¯ååºäœã«
ãªã€ãããããåŸããã®æ··åç©100éšã100éšã®æ¶²
äœERLâ4221ãš25âã§20åéã«ããã€ãŠåäžã«
æ··åããããããã®ãµã³ãã«ããµã³ãã«(A)ã(B)å
ã³(C)ã®å Žåãšåæ§ã«çŽ50âã®ãšããã·æš¹èæ··åç©
枩床ã§æ··åããããã®çµæããšããã·æš¹èã¯å³åº§
ã«ããããã³ãŒã³ç¶ãã«ã²ã«åããå質ãªæ··åã
äžå¯èœã§ãã€ãã ãããåŸãããããã®ãµã³ãã«10ïœã5.1cm
ïŒïŒã€ã³ãïŒçŽåŸã®ã¢ã«ãããŠã ç¿äžã§æ³šåã
ããããããã®ãµã³ãã«ã¯çŽ2.54mmïŒ0.1ã€ã³
ãïŒã®åããæãããããããã®ãµã³ãã«ã硬ã
ç²çæ§ã«ãªããŸã§ã²ã«åããããããåŸå®è³ªçã«
å®å šã«ç¡¬åãããŸã§ãããªãã¡åºäœã§äžèæ§ã«ãª
ããŸã§æŸçœ®ããããããã¯å šãŠ25âã§è¡ã€ããã
ããåŸãèªé»çã®å€Îµâ²åã³60Hzã®åçã®å€
ïŒASTM D150â65TïŒããµã³ãã«(B)ã(C)åã³(D)ã«
ã€ããŠæž¬å®ããããããã®ãã¹ãçµæãäžèšã®è¡š
ïŒã«ç€ºãã
æããã äžåŒäžïŒ²ã¯Râ²ãRâ²ââRâ²ãRâ²âCOOâRâ²å
ã³ãããã®æ··åç©ïŒRâ²ã¯çŽïŒãïŒåã®ççŽ åå
ãæããã¢ã«ãã¬ã³åºãïŒãïŒåã®ççŽ ååã®ç°
ãæãã飜åã·ã¯ãã¢ã«ãã¬ã³åºåã³ãããã®æ··
åç©ããéžæããããã®ïŒããæã矀ããéžæã
ããïœã¯çŽïŒãïŒã§ããã æ¬çºæã§äœ¿çšã§ããããã³ãã€ã³ãšããã·æš¹è
ã¯æ§é åŒ ãæããçªçŽ å«æè€çŽ ç°ã§ããããã³ãã€ã³ã«åº
ã¥ããïŒå¡ããã³ãã€ã³ç°äžã®çªçŽ ã®äœçœ®ãåå¿
ãããããšã«ãã€ãŠåºç¯å²ã®çš®ã ã®ååç©ãçæ
ã§ãããããã³ãã€ã³ç°ã¯ã±ãã³ãæ°ŽçŽ ãã·ã¢ã³
åç©ãã¢ã³ã¢ãã¢ãäºé žåççŽ åã³æ°Žãã容æã«
åæãããããã®ãšããã·æš¹èã¯ããã³ãã€ã³ãš
ãšãã¯ãã«ãããªã³ãšã®åå¿ã«ãã€ãŠçæãã
ããããã³ãã€ã³ç°ã¯äžç·ã«çµåããŠæ§é ããã¹
ããšããŒã«ïŒ¡ã«é¡äŒŒããéã®å»¶ã³ãæš¹èãåŸãã
ããå€å®èœæ§æš¹èãæ°Žé žåºåã³æ®åçªçŽ ãã°ãªã·
ãžã«åããããšã«ãã€ãŠãããã®éã®å»¶ã³ãç©è³ª
ããçæã§ããããããã®è€çŽ ç°åŒã°ãªã·ãžã«ã¢
ãã³ãšããã·æš¹èã¯æ§é åŒã ã«ãã€ãŠè¡šããããã æ¬çºæã®æš¹èæåãšããŠäœ¿çšãããç°åŒèèªæ
ã¿ã€ããšããã·æš¹èã¯ïŒåååœãïŒåããå€ã
ïŒã»ïŒâãšããã·åºãæããéã°ãªã·ãžã«ãšãŒã
ã«ãšããã·æš¹èããéžæãããããããã¯äžè¬ã«
éå®æ¯éŠé žåã³éé ¢é žãªã©ã®éé žãããã¯éé žå
æ°ŽçŽ ã䜿çšããŠã·ã¯ããªã¬ãã€ã³ãªã©ã®äžé£œåè³
éŠæçåæ°ŽçŽ ååç©ããšããã·åããããšã«ãã€
ãŠè£œé ããããææ©éé žã¯äžè¬ã«éé žåæ°ŽçŽ ãã«
ã«ãã³é žãé žå¡©åç©ãŸãã¯ã±ãã³ãšåå¿ãããŠå
åç©ïŒ²âCOOOHãçæããããšã«ãã€ãŠè£œé ã
ããã ç°åŒèèªæãšããã·æš¹èã®äŸãšããŠã¯ïŒã»ïŒâ
ãšããã·ã·ã¯ãããã·ã«ã¡ãã«âïŒã»ïŒâãšãã
ã·ã·ã¯ããããµã³ã«ã«ããã·ã¬ãŒãïŒç°æ§é ã®äž
éšãæãïŒåã®ãšããã·åºåã³ãšã¹ãã«çµåãæ
ããïŒïŒäºé žåããã«ã¯ãããã»ã³ïŒïŒåã®ãšã
ãã·åºãæãããã®äžæ¹ã¯ç°æ§é ã®äžéšãæ
ãïŒïŒïŒã»ïŒâãšããã·âïŒâã¡ãã«ã·ã¯ããã
ã·ã«ã¡ãã«âïŒã»ïŒâãšããã·âïŒâã¡ãã«ã·ã¯
ããããµã³ã«ã«ããã·ã¬ãŒãåã³ãžã·ã¯ããã³ã¿
ãžãšã³ãããã ä»ã®æçšãªãšããã·æš¹èã®äŸãšããŠã¯ççŽ åå
æ°ãïŒã12åã®èèªæãžãªãŒã«ã®ãžã°ãªã·ãžã«ãš
ãŒãã«ãããããããã¯äœç²åºŠã®ãšããã·æš¹è
ã§ãéåžžã¢ãããŒã§ããããããã¯ã°ãªã·ãžã«ãš
ãŒãã«åäœéã«ççŽ ååæ°ãïŒã12åã®ã°ãªã³ãŒ
ã«ãé ãããžã°ãªã·ãžã«ãšãŒãã«ãããªãã¡ã°ãª
ã³ãŒã«åäœäžã®ççŽ ååæ°ãïŒã12åã§ãããã®
ã§ãããããšãã°ããªãã³ãã«ã°ãªã³ãŒã«ã®ãžã°
ãªã·ãžã«ãšãŒãã«ïŒDGENPGïŒãïŒã»ïŒâãã¿ã³
ãžãªãŒã«ã®ãžã°ãªã·ãžã«ãšãŒãã«ããšãã¬ã³ã°ãª
ã³ãŒã«ã®ãžã°ãªã·ãžã«ãšãŒãã«åã³ããªãšãŒãã«
ã°ãªã³ãŒã«ã®ãžã°ãªã·ãžã«ãšãŒãã«ãããšãã°ã
ãªãšãã¬ã³ã°ãªã³ãŒã«ã®ãžã°ãªã·ãžã«ãšãŒãã«å
ã³ããã©ãšãã¬ã³ã°ãªã³ãŒã«ã®ãžã°ãªã·ãžã«ãšãŒ
ãã«åã³ãããã®æ··åç©çãããã èèªæãžãªãŒã«ãšããã·ãã¯å šãŠäœç²åºŠç©è³ª
ïŒäžè¬ã«25âã§çŽïŒã60cpsïŒã§ãããå«æµžã®ç®
çã®ããã®æš¹èçµæç©ã®ç²åºŠãäœäžãããã®ã«åœ¹
ç«ã€ã®ã§ãå Žåã«ãã€ãŠã¯ãããã®èèªæãžãªãŒ
ã«ã®ãžã°ãªã·ãžã«ãšãŒãã«ã®ãããããä»ã®ãšã
ãã·æš¹èãšçµåãããŠäœ¿çšããã®ãæçšã§ããã
ãã®ãšããã·æš¹èç³»ã¯ã(A)äœç²åºŠïŒ25âã§çŽïŒã
60cpsïŒãæãã第ïŒãšããã·æš¹èãããªãã¡è
èªæãžãªãŒã«ã®ãžã°ãªã·ãžã«ãšãŒãã«åã³(B)é«ç²
床ïŒ25âã§çŽ250cps以äžãäžè¬ã«çŽ250ã
20000cpsïŒãæãã第ïŒãšããã·æš¹èãããªã
ã¡ãã¹ããšããŒã«ïŒ¡ããã¹ããšããŒã«ïŒŠãããã©
ãã¯ãã°ãªã·ãžã«ãšã¹ãã«ãããã³ãã€ã³ãç°åŒ
èèªæåã³ãããã®æ··åç©ããæããåèšç¬¬ïŒãš
ããã·æš¹è(A)ïŒåèšç¬¬ïŒãšããã·æš¹è(B)ã®ééæ¯
ã¯çŽïŒïŒ0.5ãïŒã§ããã ãããã®ãšããã·æš¹èã®å šãŠã¯ïŒåååœãã®ãš
ããã·åºã®å¹³åæ°ã§æš¹èã®å¹³åååéãå²ã€ãå€
ã§ãããšããã·åœéã«ãã€ãŠç¹åŸŽã¥ãããããæ¬
çºæã«ãããŠãé©åœãªãšããã·æš¹èã®å šãŠã¯å¥œãŸ
ããã¯çŽ100ã500ããã奜ãŸããã¯çŽ150ã250ã®
ãšããã·åœéãæããããããã®ãšããã·æš¹èã®
å šãŠã¯å ¬ç¥ã§ãããåžè²©ãããŠããããããã®æ§
é åã³è£œé æ³ã®è©³çŽ°ã«ã€ããŠã¯Leeåã³Nevilleè
ã®âHandbook of Epoxy ResinsâïŒMcGrawâ
Hill瀟ã1967ãCh.2â10ãïŒâ27ïŒåã³ç±³åœç¹èš±
第4137275å·ãåç §ããããã ããã€ãã®ç¹å¥ãªç®çã®å Žåã«ã¯ãçŽéã®ãšã
ãã·âç¡æ°Žç©æš¹èç³»ã¯ããçš®ã®æ¬ ç¹ãæãããã
ããã®æ¬ ç¹ã¯è²»çšãé«ããå Žåã«ãã€ãŠã¯åæ§ã
倧ãéããããšã§ããããããã®ãšããã·æš¹èã¯
çš®ã ã®åžéå€ãæè»å€åã³å å¡«å€ã«ãã€ãŠå€æ§ã
ãŠãè¯ãã å«æµžç®çã®ããã«ã¯ããšããã·âç¡æ°Žç©æš¹èç³»
ã®ç²åºŠãäœäžãããã®ã«äœ¿çšã§ããç©è³ªã®äžäŸãš
ããŠã¯æ¶²ç¶ã¢ããšãã¬ã³ç³»äžé£œåããã«ã¢ãããŒ
ããããæçšãªããã«ã¢ãããŒã®äŸãšããŠã¯ã¹ã
ã¬ã³ãïœâããã«ã¹ãã¬ã³ãããã«ãã«ãšã³ãã¡
ãã«ã¡ã¿ã¯ãªã¬ãŒããã¡ãã«ããã«ã±ãã³åã³ã
ããã®æ··åç©çãããããããã¯ãšããã·æš¹è
100éšåœã300éšä»¥äžã奜ãŸããã¯50ã250éšã®é
ã§äœ¿çšãããããããã®ç©è³ªã®çµåããã¯25âã§
ïŒã25cpsã®ç²åºŠãæããå«æµžçšã¯ãã¹ãæäŸã
ãã ãŸããšããã·å倩ç¶æ²¹ãšãã¹ãã³ããŒãããšã
ã°ãšããã·åã¢ããæ²¹ãŸãã¯å€§è±æ²¹åã³ãªã¯ãã«
ãšããã·ã¿ã¬ãŒã䞊ã³ã«åå¿æ§å¯å¡å€ãããšãã°
åŸæ¥ã®ãã¿ã¬ãŒãåã³ããªã¹ããšãŒãããšããã·
æš¹è100éšåœãçŽ40éšä»¥äžã®å°éã§äœ¿çšããŠæè»
æ§ãé«ããŠãè¯ããããã«ãŸãSiO2ãªã©ã®ãã
ãœãããŒãå€åã³TiO2ãªã©ã®é¡æã䜿çšããŠçµ
æç©ã®æµåæ§ãæ¹è¯ãããã硬åããæš¹èã®è²èª¿
ãé«ããŠãè¯ããåæ§ã«ãå¹³åç²åãµã€ãºãçŽ10
ã300ãã¯ãã³ã®çš®ã ã®ç²ç¶ç¡æ©å å¡«å€ãããšã
ã°ã·ãªã«ãç³è±ãããªãªãŠã ã¢ã«ãããŠã ã·ãªã±
ãŒãããªããŠã ã¢ã«ãããŠã ã·ãªã±ãŒãåã³ãã
ãã®æ··åç©ããšããã·æš¹è100éšåœãçŽ100éšä»¥äž
ã®éã§äœ¿çšããŠæš¹èã®é»æ°çç¹æ§ãæ¹è¯ããã³ã€
ã«ããã©ã³ã¹ãããã·ã³ã°ã¹ã¿ããçã®æ³šå°ææ
ãæäŸããŠãè¯ãã æ¬çºæã§äœ¿çšããé»è·ç§»åé¯äœã¯æ¶²ç¶ã«ã«ãã³
é žç¡æ°Žç©ãç¹å®ã®ã«ã€ã¹é žè§Šåªãšåã«æ··åããã
ãšã«ãã€ãŠãéåžžåèšè§Šåªã氷济äžã§åå¿ç©æž©åºŠ
ã10ã45âã«èª¿ç¯ããªãã滎äžããããšã«ãã€ãŠ
掻æ§åãããç¶æ ã§åŸããããšããã·æš¹èã®ãã
ã®åå¿æ··åç©ã®é»è·ç§»åé¯äœåå¿æ§ç¡¬åå€ãçæ
ããã掻æ§åããç¡æ°Žç©ã®äºãåå¿ããåå¿æ··å
ç©ã¯ãããåŸå¥œãŸããã¯10ã45âãé垞宀枩ã®å
å¿ç©æž©åºŠã§ãšããã·æš¹èã«å ãããããã®æš¹èçµ
æç©ã¯ãããåŸçš®ã ã®å°é»æ§éšæãããšãã°é ãŸ
ãã¯ã¢ã«ãããŠã ã¯ã€ã€ãããªã€ã«ãããã¯ã¹ã¿
ããçã«å«æµžæš¹èããšãã¡ã«ã泚åãŸãã¯æ³šå°æ
æãããã¯é«éå°åºæ圢ææçãšããŠæœãããã
ãšããã·æš¹è100éééšåœãçŽ25ã200éééšã®æŽ»
æ§åç¡æ°Žç©é¯äœãå ãããããç¹å®ã®ã«ã€ã¹é žè§Š
åªããšããã·æš¹èãšæ··åããåã«ç¡æ°Žã«ã«ãã³é ž
ãšåå¿ããŠæŽ»æ§åç¡æ°Žç©ã圢æããããšãæ¬çºæ
ã®ç¹åŸŽã§ããããšããã·æŽ»æ§åç¡æ°Žç©çµæç©ã¯10
ã45âã§168æé以å ãäžè¬ã«ïŒã48æé以å ã«
ã段éããŸã§ç¡¬åããçŽ95ïŒ ã®äº€åçµå床ã®å®
質çã«å®å šã«ç¡¬åããäžèæ§ã§ã硬ããäžç²çæ§
ã§æé¢ãèããåããã§ãã絶çžäœãæäŸããã
ãã®ããã«äœæž©ã§ç¡¬åããæš¹èã¯åŸç¡¬åïŒãã¹ã
ããŠã¢ïŒããå¿ èŠãç¡ãã 第ïŒå³ã«ã¯ã絶çžãããé«é»å§é»æ°ã¢ãŒã¿ãŒãŸ
ãã¯çºé»æ©ãªã©ã®çµ¶çžãããé»é«å§é»æ°æ©æ¢°ã«æ¿
å ¥ããããã«è£œé ãããéã³ã€ã«10å šäœã瀺ãã
ãŠãããåèšã³ã€ã«ã¯éå±ã¢ãŒã¿ãŒé»æ©åãŸãã¯
çºé»æ©å転åãå²ãåºå®åã®ã¹ãããäžã«é 眮ã
ãããåèšã³ã€ã«ã¯ãã¿ã³ãžãšããïŒïŒãæ¥ç¶ã«
ãŒãïŒïŒåã³è£žãªãŒãç·ïŒïŒã延ã³ãŠããå¥ã®ã¿
ã³ãžãšã³ãïŒïŒããæã端éšãæãããåèšã³ã€
ã«ã®ã¹ãããéšåïŒïŒåã³ïŒïŒã¯å Žåã«ãã€ãŠã¯
ç±ãã¬ã¹ãããŠæš¹èãäºå硬åãããŠæå®ã®åœ¢ç¶
åã³ãµã€ãºã«ããããããã¿ã³ãžãšã³ãïŒïŒåã³
ïŒïŒã«æ¥ç¶ãããŠããããããã®ã¹ãããéšåã¯
ãŸãå¥ã®ã«ãŒãïŒïŒãéããŠæ¥ç¶ãããŠããä»ã®
ã¿ã³ãžãšã³ãïŒïŒåã³ïŒïŒã«æ¥ç¶ãããŠãããäž
è¬ã«ãçºé»æ©ã³ã€ã«ã¯å·»ãåã«å«æµžãããããã
åŸç±ãã¬ã¹ãããããã¢ãŒã¿ãŒã³ã€ã«ã¯äžè¬ã«ã
ã®å Žã§å«æµžãããã åèšã³ã€ã«ã¯é»æ°æ©æ¢°ã®åºå®åã®ã¹ãããäžã«
é 眮ããã端éšå·»ç·ã¯å ãŸããçµåãããã絶çž
ãããŠããªããªãŒãç·ã¯ãããåŸäºãã«ãŸãã¯æŽ
æµåã«ãã³ãã¥ãã溶æ¥ãŸãã¯ä»ã®æ¹æ³ã§æ¥ç¶ã
ãããã¢ãŒã¿ãŒã®å Žåãäžè¬ã«ã³ã€ã«ãæããã¢
ãŒã¿ãŒå šäœãæ¬çºæã®äœç²åºŠæš¹èãå ¥ããå«æµžæµŽ
äžã«å ¥ããããç空å«æµžãããããããåŸããã®
å«æµžããã¢ãŒã¿ãŒãå«æµžã¿ã³ã¯ããååºãã液ã
ããã空æ°ä¹Ÿç¥ãŸãã¯çŽ45â以äžã®äœæž©ã§å ç±
ããã³ã€ã«äžã®å åã«åå¿æ§ã®çµæç©ã硬åã
ãããŸãã¯æ¬çºæã®çµæç©ãé»æ°å·»ç·ã«ãããã
èœãšããŠãè¯ãã 第ïŒå³ã¯ç¡¬åãã泚å°çµ¶çžäœïŒïŒäžã§æ³šå°ãŸã
ã¯ã«ãã»ã«å°ãããå°äœïŒïŒãæããã³ã€ã«ïŒïŒ
ãªã©ã®çµ¶çžãããé»æ°éšæã瀺ããåèšæ³šå°çµ¶çž
äœã¯åèšé»æ°éšæã«æœããŠã宀枩ãŸãã¯çŽ45â以
äžã®äœæž©ã§å ç±ããŠç¡¬åããæ¬çºæã®æš¹èçµæç©
ã§ããã 第ïŒå³ã¯å å¡«æãå åã«å«ãæ¬çºæã®æš¹èçµæ
ç©ãå°äœã¹ã¿ããïŒïŒã®åšå²ã«æ³šå°ãããŠåŸãã
ãããã·ã³ã°çµ¶çžäœïŒïŒãæããããã·ã³ã°çµäœ
ã瀺ãã æ¬çºæã¯äžèšã®å®æœäŸã«ãã€ãŠããã«è©³ãã説
æãããã äŸ æ¯äœæš¹èãšããŠ25âã§350ã450cpsã®ç²åºŠãæ
ãã液äœãšããã·æš¹èã§ããïŒã»ïŒâãšããã·ã·
ã¯ãããã·ã«ã¡ãã«âïŒã»ïŒâãšããã·ã·ã¯ãã
ããµã³ã«ã«ããã·ã¬ãŒãïŒUnion Carbide瀟ãã
åžè²©ãããŠããåååãâERLâ4221âã®ç°åŒ
èèªæãšããã·æš¹èïŒ100éšãããããå«æãã
ïŒçš®ã®æš¹èçµæç©ã調補ããããµã³ãã«(A)ã«ãã
ãŠã¯ãå¡©å第ïŒé«ïŒSnCl4ïŒ0.2éšãïŒåéã«ãã
ã€ãŠæ»ŽäžããŠæ¶²äœç¡æ°Žããžãã¯é žã¡ãã«
ïŒNMAïŒ100éšãšæ··åãããã®åå¿æ··åç©ã氷济
äžã§çŽ20âã«ä¿ã€ããåè¿°ã®åå¿çæç©ã§ããé»
è·ç§»åé¯äœã®æŽ»æ§åããç¡æ°Žç©ã®æº¶æ¶²ã¯æ··ååŸã
æ·¡é»è²ãããã¯ãè²ã«å€ãã€ãããã®æŽ»æ§åãã
ç¡æ°Žç©100éšããããåŸ10åéã«ããã€ãŠ25âã®
æ··å枩床ã§100éšã®æ¶²äœERLâ4221ãšç©è³ªã«æ··å
ããããµã³ãã«(B)ã«ãããŠã¯ã0.14éšã®SnCl4ã
ïŒåéã«ããã€ãŠæ»ŽäžããŠïŒâã¡ãã«ããã©ãã
ããã¿ã«é žç¡æ°Žç©ïŒTHPAïŒ100éšãšæ··åããã
ã®åå¿æ··åç©ã¯æ°·æµŽäžã§çŽ20âã«ä¿ã€ããåå¿ç
æç©ã§ããé»è·ç§»åé¯äœã®æŽ»æ§åããç¡æ°Žç©ã®æº¶
液ã¯æ··ååŸãæ·¡é»è²ãããã¯ãè²ã«å€ãã€ããã
ã®æŽ»æ§åããç¡æ°Žç©100éšããããåŸ10åéã«ã
ãã€ãŠ25âã®æ··å枩床ã§100éšã®æ¶²äœERLâ4221
ãšç©è³ªã«æ··åããããµã³ãã«(C)ã«ãããŠã¯ãåå¡©
åãã¿ã³ïŒTiCl4ïŒ0.4éšã滎äžããŠæ¶²äœïŒâã¡ã
ã«ããã©ããããã¿ã«é žç¡æ°Žç©ïŒTHPAïŒ100éš
ãšæ··åãããã®åå¿æ··åç©ã¯æ°·æµŽäžã§çŽ20âã«ä¿
ã€ããåå¿çæç©ã§ããé»è·ç§»åé¯äœã®æŽ»æ§åã
ãç¡æ°Žç©ã®æº¶æ¶²ã¯æ··ååŸãæ·¡é»è²ãããã¯ãè²ã«
å€ãã€ãããã®æŽ»æ§åããç¡æ°Žç©100éšãããã
åŸ10åéã«ããã€ãŠ25âã®æ··å枩床ã§100éšã®æ¶²
äœERLâ4221ãšå質ã«æ··åããããµã³ãã«(D)ã«
ãããŠã¯ã0.56éšã®SnCl4ã滎äžããŠïŒâã¡ãã«
ããã©ããããã¿ã«é žç¡æ°Žç©ïŒTHPAïŒ100éšãš
æ··åãããã®åå¿æ··åç©ã氷济äžã§35âããäœã
枩床ã«ä¿ã€ãããã®åå¿çæç©ã§ããé»è·ç§»åé¯
äœã®æŽ»æ§åããç¡æ°Žç©ã®æº¶æ¶²ã¯æ··ååŸãæ·¡é»è²ã
ãéåžžã«æ¿ããã¯ãè²ã«å€ãããããªãã®çºç±ã
瀺ãå§ããããã®æŽ»æ§åããç¡æ°Žç©100éšããã
ãåŸ100éšã®æ¶²äœERLâ4221ãšæåçŽ25âã®æ··å
枩床ã§æ··åããããã®ç¡¬åå€âãšããã·æ··åç©ã¯
ç²åºŠãçŽã¡ã«é«ãŸãå§ãããã®æ··åç©ã®æž©åºŠã¯çŽ
40âã«é«ãŸã€ãããã®ãµã³ãã«ã¯å®å šã«å質ãªæ··
åãæãããåã«æ³šåããªããã°ãªããªãã€ãã æ¯èŒäŸãšããŠããµã³ãã«(E)ã補é ããããµã³ã
ã«(E)ã®è£œé ã«ãããŠã¯ãïœâããã«é«é ž
ïŒBSAïŒ172éšãç¡æ°Žããžãã¯é žã¡ãã«100éšãšã
100âã§ïŒæéãããã«150âã§çŽïŒæéæ··åãã
åèšææ©é«é žãåèšç¡æ°Žç©ã«æº¶è§£ãã溶液ãæäŸ
ããã25âã«å·åŽããåŸãåèšæ··åç©ã¯ååºäœã«
ãªã€ãããããåŸããã®æ··åç©100éšã100éšã®æ¶²
äœERLâ4221ãš25âã§20åéã«ããã€ãŠåäžã«
æ··åããããããã®ãµã³ãã«ããµã³ãã«(A)ã(B)å
ã³(C)ã®å Žåãšåæ§ã«çŽ50âã®ãšããã·æš¹èæ··åç©
枩床ã§æ··åããããã®çµæããšããã·æš¹èã¯å³åº§
ã«ããããã³ãŒã³ç¶ãã«ã²ã«åããå質ãªæ··åã
äžå¯èœã§ãã€ãã ãããåŸãããããã®ãµã³ãã«10ïœã5.1cm
ïŒïŒã€ã³ãïŒçŽåŸã®ã¢ã«ãããŠã ç¿äžã§æ³šåã
ããããããã®ãµã³ãã«ã¯çŽ2.54mmïŒ0.1ã€ã³
ãïŒã®åããæãããããããã®ãµã³ãã«ã硬ã
ç²çæ§ã«ãªããŸã§ã²ã«åããããããåŸå®è³ªçã«
å®å šã«ç¡¬åãããŸã§ãããªãã¡åºäœã§äžèæ§ã«ãª
ããŸã§æŸçœ®ããããããã¯å šãŠ25âã§è¡ã€ããã
ããåŸãèªé»çã®å€Îµâ²åã³60Hzã®åçã®å€
ïŒASTM D150â65TïŒããµã³ãã«(B)ã(C)åã³(D)ã«
ã€ããŠæž¬å®ããããããã®ãã¹ãçµæãäžèšã®è¡š
ïŒã«ç€ºãã
ãè¡šã
åèšè¡šãããããããã«ããµã³ãã«(A)åã³(B)ã¯
éåžžã«è¯å¥œãªã²ã«åæéåã³ç¡¬åæéãæäŸãã
ãµã³ãã«(C)ãåæ ŒãåŸãã²ã«åæéåã³ç¡¬åæé
ãæäŸããããµã³ãã«(B)åã³(C)ã¯ç±ç¡¬åã䌎ããª
ãæš¹èç³»ã«èããé»æ°çç¹æ§ãæäŸããããµã³ã
ã«(A)ã¯ãµã³ãã«(B)ãããããã«é«ãé»æ°çå€ãæ
äŸããã¯ãã§ãããé»æ°çµ¶çžçšã®å Žåã®åçã®å
æ Œå€ã¯25âã§5.0ããäœãå€ã§ãããèªé»çεâ²ã®
åæ Œå€ã¯25âã§8.0ããäœãå€ã§ããã SnCl4æ¿åºŠãæ¯èŒçé«ããµã³ãã«(D)ã¯èããé»
æ°çç¹æ§ãæäŸããããéåžžã«è¿ éã«ã²ã«åãã
粟巧ãªé«éã¹ãã¬ãŒæ··åå°åºæåçšã«å©çšãã
ãããµã³ãã«(D)ã«ãããŠãšããã·æš¹è100éšåœã
çŽ50éšã®æŽ»æ§åç¡æ°Žç©ã䜿çšããå Žåãã²ã«åæ
éåã³ç¡¬åæéã¯ãµã³ãã«(A)ã«é¡äŒŒããç¯å²ã«é·
ããªããé©åœéã®ææ©é«é žã䜿çšãããµã³ãã«(E)
ã¯ãåèšç¡æ°Žç©ã«æº¶è§£ããã®ã«ããªãé·æéç±ã
æœãå¿ èŠããããå€ãã®å Žåããšããã·æš¹èãšå
äžã«æ··åããã®ã«ç±ãæœãå¿ èŠãããã宀枩ã¿ã€
ãã®ãšããã·ç¡¬åå€ç³»ãšããŠã¯äžé©åœã§ããã åè¿°ã®ä»ã®ã¿ã€ãã®ã«ã€ã¹é žè§Šåªããšããã·
ããç¡æ°Žç©åã³ç¡æ°Žç©ã®æ··åç©ã25âã§é©åœãªã²
ã«åæéã硬åæéåã³é»æ°çç¹æ§ãæäŸããã®
ã«æçšã§ããããããã®ãµã³ãã«(A)ã(B)ã(C)åã³
(D)çµæç©ã®å šãŠã¯ããã€ã«ããŒãã®å«æµžæš¹èãã
ã©ã³ã¹çšã³ã€ã«ã®æ³šå°çšæš¹èãŸãã¯ããã·ã³ã°ã¹
ã¿ããã®ã«ãã»ã«å°ãçšæš¹èãªã©ã®ç¹å®ã®çšéã«
æçšãªçš®ã ã®æš¹èç³»ãæäŸããããã«åžéå€ãå
å¡«å€çã®çš®ã ã®æåãæ·»å ããããšãå¯èœã§ã
ãã
éåžžã«è¯å¥œãªã²ã«åæéåã³ç¡¬åæéãæäŸãã
ãµã³ãã«(C)ãåæ ŒãåŸãã²ã«åæéåã³ç¡¬åæé
ãæäŸããããµã³ãã«(B)åã³(C)ã¯ç±ç¡¬åã䌎ããª
ãæš¹èç³»ã«èããé»æ°çç¹æ§ãæäŸããããµã³ã
ã«(A)ã¯ãµã³ãã«(B)ãããããã«é«ãé»æ°çå€ãæ
äŸããã¯ãã§ãããé»æ°çµ¶çžçšã®å Žåã®åçã®å
æ Œå€ã¯25âã§5.0ããäœãå€ã§ãããèªé»çεâ²ã®
åæ Œå€ã¯25âã§8.0ããäœãå€ã§ããã SnCl4æ¿åºŠãæ¯èŒçé«ããµã³ãã«(D)ã¯èããé»
æ°çç¹æ§ãæäŸããããéåžžã«è¿ éã«ã²ã«åãã
粟巧ãªé«éã¹ãã¬ãŒæ··åå°åºæåçšã«å©çšãã
ãããµã³ãã«(D)ã«ãããŠãšããã·æš¹è100éšåœã
çŽ50éšã®æŽ»æ§åç¡æ°Žç©ã䜿çšããå Žåãã²ã«åæ
éåã³ç¡¬åæéã¯ãµã³ãã«(A)ã«é¡äŒŒããç¯å²ã«é·
ããªããé©åœéã®ææ©é«é žã䜿çšãããµã³ãã«(E)
ã¯ãåèšç¡æ°Žç©ã«æº¶è§£ããã®ã«ããªãé·æéç±ã
æœãå¿ èŠããããå€ãã®å Žåããšããã·æš¹èãšå
äžã«æ··åããã®ã«ç±ãæœãå¿ èŠãããã宀枩ã¿ã€
ãã®ãšããã·ç¡¬åå€ç³»ãšããŠã¯äžé©åœã§ããã åè¿°ã®ä»ã®ã¿ã€ãã®ã«ã€ã¹é žè§Šåªããšããã·
ããç¡æ°Žç©åã³ç¡æ°Žç©ã®æ··åç©ã25âã§é©åœãªã²
ã«åæéã硬åæéåã³é»æ°çç¹æ§ãæäŸããã®
ã«æçšã§ããããããã®ãµã³ãã«(A)ã(B)ã(C)åã³
(D)çµæç©ã®å šãŠã¯ããã€ã«ããŒãã®å«æµžæš¹èãã
ã©ã³ã¹çšã³ã€ã«ã®æ³šå°çšæš¹èãŸãã¯ããã·ã³ã°ã¹
ã¿ããã®ã«ãã»ã«å°ãçšæš¹èãªã©ã®ç¹å®ã®çšéã«
æçšãªçš®ã ã®æš¹èç³»ãæäŸããããã«åžéå€ãå
å¡«å€çã®çš®ã ã®æåãæ·»å ããããšãå¯èœã§ã
ãã
第ïŒå³ã¯æ¬çºæã®æš¹èçµæç©ã䜿çšããŠè£œé ã
ãå·»ãããæš¹èå«æµžã³ã€ã«ã瀺ãã第ïŒå³ã¯æ¬çº
æã®æš¹èçµæç©ã䜿çšããŠè£œé ããã«ãã»ã«å°ã
ãããé»æ°ç©åã瀺ãã第ïŒå³ã¯æ¬çºæã®æš¹èçµ
æç©ã䜿çšããŠè£œé ããããã·ã³ã°ã瀺ãã ïŒïŒïŒïŒïŒïŒïŒïŒåã³ïŒïŒâŠâŠã¿ã³ãžãšã³ãïŒ
ïŒïŒïŒïŒïŒâŠâŠã«ãŒãïŒïŒïŒâŠâŠè£žãªãŒãç·ïŒïŒ
ïŒïŒïŒïŒâŠâŠã¹ãããéšåïŒïŒïŒâŠâŠã³ã€ã«ïŒïŒ
ïŒâŠâŠå°äœïŒïŒïŒâŠâŠæ³šå°çµ¶çžäœïŒïŒïŒâŠâŠå°äœ
ã¹ã¿ããïŒïŒïŒâŠâŠããã·ã³ã°çµ¶çžäœã
ãå·»ãããæš¹èå«æµžã³ã€ã«ã瀺ãã第ïŒå³ã¯æ¬çº
æã®æš¹èçµæç©ã䜿çšããŠè£œé ããã«ãã»ã«å°ã
ãããé»æ°ç©åã瀺ãã第ïŒå³ã¯æ¬çºæã®æš¹èçµ
æç©ã䜿çšããŠè£œé ããããã·ã³ã°ã瀺ãã ïŒïŒïŒïŒïŒïŒïŒïŒåã³ïŒïŒâŠâŠã¿ã³ãžãšã³ãïŒ
ïŒïŒïŒïŒïŒâŠâŠã«ãŒãïŒïŒïŒâŠâŠè£žãªãŒãç·ïŒïŒ
ïŒïŒïŒïŒâŠâŠã¹ãããéšåïŒïŒïŒâŠâŠã³ã€ã«ïŒïŒ
ïŒâŠâŠå°äœïŒïŒïŒâŠâŠæ³šå°çµ¶çžäœïŒïŒïŒâŠâŠå°äœ
ã¹ã¿ããïŒïŒïŒâŠâŠããã·ã³ã°çµ¶çžäœã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (a)ãšããã·æš¹èïŒåã³(b)äžå®èœæ§ç¡æ°Žç©ãå€
å®èœæ§ç¡æ°Žç©åã³ãããã®æ··åç©ããæã矀ãã
éžæããã液äœææ©ã«ã«ãã³é žç¡æ°Žç©ãšSnCl4ã
TiCl4ãSbCl5ãSbF5ãBF3ãPF5åã³ãããã®æ··
åç©ããæã矀ããéžæãããã«ã€ã¹é žè§Šåªã®æ··
åç©ãšããæ¬è³ªçã«æããã«ã«ãã³é žã«ããªã³äœ
ã圢æããŠããé»è·ç§»åé¯äœç¡¬åå€ãå«ã絶çžçš
äœæž©ç¡¬åæ§ãšããã·æš¹èçµæç©ã§ã10ã45âã®æž©
床ã§ç¡¬åãåŸãããšãç¹åŸŽãšãã絶çžçšäœæž©ç¡¬å
æ§ãšããã·æš¹èçµæç©ã ïŒ ã«ã€ã¹é žè§ŠåªãSnCl4ãTiCl4åã³ãããã®
æ··åç©ããæã矀ããéžæãããç¹èš±è«æ±ã®ç¯å²
第ïŒé èšèŒã®çµæç©ã ïŒ ã«ã€ã¹é žè§ŠåªïŒåèšã«ã«ãã³é žç¡æ°Žç©ã®éé
æ¯ã0.006ã0.0001ïŒïŒã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®çµæç©ã ïŒ ç¡æ°Žç©åã³åèšã«ã€ã¹é žè§Šåªã10ã45âã®å
å¿ç©æž©åºŠã§æ··åãããŠã«ã«ãã³é žã«ããªã³äœãç
æããŠãããåèšã«ã«ãã³é žã«ããªã³äœã¯ç ŽããŠ
ããªãç¡æ°Žç©ç°ãæããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èš
èŒã®çµæç©ã ïŒ é»è·ç§»åé¯äœã®ç¡æ°Žç©æåãããžãã¯é žã¡ã
ã«ç¡æ°Žç©åã³ïŒâã¡ãã«ããã©ããããã¿ã«é žç¡
æ°Žç©ããæã矀ããéžæãããã«ã€ã¹é žè§Šåªæå
ãSnCl4åã³TiCl4ããæã矀ããéžæãããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµæç©ã ïŒ é»è·ç§»åé¯äœããšããã·æš¹è100éééšåœã
25ã200éééšã®éã§äœ¿çšãããç¹èš±è«æ±ã®ç¯å²
第ïŒé èšèŒã®çµæç©ã ïŒ åèšã«ã€ã¹é žè§ŠåªïŒåèšã«ã«ãã³é žç¡æ°Žç©ã®
ééæ¯ã0.004ã0.0001ïŒïŒã§ããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé èšèŒã®çµæç©ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/127,615 US4273914A (en) | 1980-03-06 | 1980-03-06 | Pre-reacted carboxylic acid anhydride complexes as low temperature curing agents for epoxy resins |
| US127615 | 1980-03-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60192723A JPS60192723A (ja) | 1985-10-01 |
| JPS6214168B2 true JPS6214168B2 (ja) | 1987-04-01 |
Family
ID=22431010
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56031445A Expired JPS6040451B2 (ja) | 1980-03-06 | 1981-03-06 | ãšããã·æš¹èçšç¡¬åå€ãšããŠæçšãªé»è·ç§»åé¯äœ |
| JP60026643A Granted JPS60192723A (ja) | 1980-03-06 | 1985-02-15 | é»è·ç§»åé¯äœç¡¬åå€ãå«æãã絶çžçšäœæž©ç¡¬åæ§ãšããã·æš¹èçµæç© |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56031445A Expired JPS6040451B2 (ja) | 1980-03-06 | 1981-03-06 | ãšããã·æš¹èçšç¡¬åå€ãšããŠæçšãªé»è·ç§»åé¯äœ |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4273914A (ja) |
| EP (1) | EP0035880B1 (ja) |
| JP (2) | JPS6040451B2 (ja) |
| CA (1) | CA1174793A (ja) |
| DE (1) | DE3170979D1 (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019188814A1 (ja) * | 2018-03-28 | 2019-10-03 | ç©æ°ŽååŠå·¥æ¥æ ªåŒäŒç€Ÿ | é»åææçšçµæç©ã液æ¶è¡šç€ºçŽ åçšã·ãŒã«å€ãäžäžå°éææãåã³ã液æ¶è¡šç€ºçŽ å |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4335179A (en) * | 1981-02-02 | 1982-06-15 | Westinghouse Electric Corp. | Impregnated high voltage spacers |
| US4637197A (en) * | 1984-10-15 | 1987-01-20 | Epoxy Technology, Inc. | Method and compositions for removal of moisture |
| US4663072A (en) * | 1984-12-24 | 1987-05-05 | Ford Motor Company | Acid anhydride mixtures in paste form useful for curing epoxy resins and a dual catalyst system therefor |
| US4845166A (en) * | 1987-03-04 | 1989-07-04 | Westinghouse Electric Corp. | Compositions containing a mixture of a polyhydric alcohol and charge transfer complex of irradiated anhydrides and cyclic ethers, used to cure epoxy resins |
| US6680119B2 (en) * | 2001-08-22 | 2004-01-20 | Siemens Westinghouse Power Corporation | Insulated electrical coil having enhanced oxidation resistant polymeric insulation composition |
| ITMI20091980A1 (it) * | 2009-11-12 | 2011-05-13 | Imast S C A R L | Polimeri rinforzati con fibre, composizioni polimeriche a base epossidica e loro impiego |
| IT1402046B1 (it) * | 2010-10-18 | 2013-08-28 | Ansaldo Energia Spa | Struttura e metodo di bloccaggio di testate di avvolgimenti statorici di macchine elettriche, in particolare di generatori elettrici |
| US9309637B2 (en) | 2012-12-19 | 2016-04-12 | Potters Industries, Llc | Method for marking a transportation corridor |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL204817A (ja) * | 1955-02-24 | |||
| US2839495A (en) * | 1955-11-07 | 1958-06-17 | Shell Dev | Process for resinifying polyepoxides and resulting products |
| US3352826A (en) * | 1958-06-23 | 1967-11-14 | Celanese Coatings Co | Increased heat distortion ethoxyline resins |
| US3281376A (en) * | 1961-12-29 | 1966-10-25 | Union Carbide Corp | Epoxide compositions containing a catalytic amount of a stannic organophosphate |
| ES305034A1 (es) * | 1963-10-18 | 1965-04-01 | Ciba Geigy | Procedimiento para endurecer compuestos poliepoxidos cicloalifaticos |
| US3622524A (en) * | 1968-09-03 | 1971-11-23 | Gen Electric | Compositions of epoxy resins cured with organotin compounds |
| US3799905A (en) * | 1970-09-24 | 1974-03-26 | Nat Res Dev | Dental epoxides |
| US3769226A (en) * | 1971-07-27 | 1973-10-30 | Gen Electric | Organostannoic acid and carboxylic acid anhydride reaction product epoxy curing agent |
| US3728306A (en) * | 1971-07-27 | 1973-04-17 | Gen Electric | Composition comprising an epoxy resin with an organostannoic acid-carboxylic acid anhydride reaction product |
| US4020017A (en) * | 1975-05-08 | 1977-04-26 | Westinghouse Electric Corporation | Epoxides containing organo-tin compounds and electrical members insulated therewith |
-
1980
- 1980-03-06 US US06/127,615 patent/US4273914A/en not_active Expired - Lifetime
-
1981
- 1981-02-20 CA CA000371326A patent/CA1174793A/en not_active Expired
- 1981-03-06 EP EP81300935A patent/EP0035880B1/en not_active Expired
- 1981-03-06 DE DE8181300935T patent/DE3170979D1/de not_active Expired
- 1981-03-06 JP JP56031445A patent/JPS6040451B2/ja not_active Expired
-
1985
- 1985-02-15 JP JP60026643A patent/JPS60192723A/ja active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019188814A1 (ja) * | 2018-03-28 | 2019-10-03 | ç©æ°ŽååŠå·¥æ¥æ ªåŒäŒç€Ÿ | é»åææçšçµæç©ã液æ¶è¡šç€ºçŽ åçšã·ãŒã«å€ãäžäžå°éææãåã³ã液æ¶è¡šç€ºçŽ å |
| JP6630871B1 (ja) * | 2018-03-28 | 2020-01-15 | ç©æ°ŽååŠå·¥æ¥æ ªåŒäŒç€Ÿ | é»åææçšçµæç©ã液æ¶è¡šç€ºçŽ åçšã·ãŒã«å€ãäžäžå°éææãåã³ã液æ¶è¡šç€ºçŽ å |
| JP2020042307A (ja) * | 2018-03-28 | 2020-03-19 | ç©æ°ŽååŠå·¥æ¥æ ªåŒäŒç€Ÿ | é»åææçšçµæç©ã液æ¶è¡šç€ºçŽ åçšã·ãŒã«å€ãäžäžå°éææãåã³ã液æ¶è¡šç€ºçŽ å |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1174793A (en) | 1984-09-18 |
| JPS60192723A (ja) | 1985-10-01 |
| EP0035880B1 (en) | 1985-06-19 |
| JPS56147782A (en) | 1981-11-16 |
| EP0035880A1 (en) | 1981-09-16 |
| DE3170979D1 (en) | 1985-07-25 |
| US4273914A (en) | 1981-06-16 |
| JPS6040451B2 (ja) | 1985-09-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1110393A (en) | Latent accelerators for curing epoxy resins | |
| US4113791A (en) | Fluid solventless epoxy-anhydride compositions containing metal acetylacetonate accelerators and organic carboxylic acid co-accelerators | |
| US4254351A (en) | Metal acetylacetonate latent accelerators for an epoxy-styrene resin system | |
| US4204181A (en) | Electrical coil, insulated by cured resinous insulation | |
| US4224541A (en) | Fluid solventless epoxy-anhydride compositions containing metal acetylacetonate accelerators and organic carboxylic acid co-accelerators for use on an electrical member | |
| US4349651A (en) | Resinous copolymer insulating compositions | |
| US3784583A (en) | Latent organic phosphonium salt catalysts for curing glycidyl ether epoxy resins | |
| JPH0377203A (ja) | é»æ°çµ¶çžç·èŒªãå転é»æ©åã³ãã®è£œé æ¹æ³ | |
| US6384152B2 (en) | Insulating resin of epoxy resin, epoxy diluent, phenolic accelerator and organotin catalyst | |
| US3324081A (en) | Polyepoxy resin-biaryl anhydride composition | |
| JPS6214168B2 (ja) | ||
| US3434087A (en) | Crack-resistant casting composition | |
| JPS6231766B2 (ja) | ||
| US4246161A (en) | Carbonyl latent accelerators for curing epoxy resins | |
| US4020017A (en) | Epoxides containing organo-tin compounds and electrical members insulated therewith | |
| KR840001788B1 (ko) | ê°ìì± ìŽëªšì ì° í ìŽíì ì ì¡°ë°©ë² | |
| JPH0799915B2 (ja) | å転é»æ©ã®å転ååã³ãã®çµ¶çžæ¹æ³ | |
| US4467072A (en) | Resinous copolymer insulating compositions | |
| US3979355A (en) | Arsonium latent catalysts for curing epoxy resins | |
| JP4322047B2 (ja) | é»æ°çµ¶çžçšæ³šåãšããã·æš¹èçµæç©åã³ç¡¬åç© | |
| JP2570210B2 (ja) | ããªãã¬ã° | |
| US4755580A (en) | Epoxy coating compositions containing a dual mixture of a boron trihalide complex and an irradiated charge transfer complex as curing agent | |
| JP2011246553A (ja) | ã¯ãã¹çµæç©ããã³ã³ã€ã«è£ 眮 | |
| JPH0452703B2 (ja) | ||
| JPH0345483B2 (ja) |