JPS6189294A - コ−クス炉ガスの精製法 - Google Patents
コ−クス炉ガスの精製法Info
- Publication number
- JPS6189294A JPS6189294A JP21037284A JP21037284A JPS6189294A JP S6189294 A JPS6189294 A JP S6189294A JP 21037284 A JP21037284 A JP 21037284A JP 21037284 A JP21037284 A JP 21037284A JP S6189294 A JPS6189294 A JP S6189294A
- Authority
- JP
- Japan
- Prior art keywords
- coke oven
- oven gas
- catalyst
- palladium catalyst
- unsaturated hydrocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000571 coke Substances 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims description 21
- 239000007789 gas Substances 0.000 claims abstract description 56
- 239000003054 catalyst Substances 0.000 claims abstract description 49
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims abstract description 18
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 15
- 239000001301 oxygen Substances 0.000 claims abstract description 15
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 15
- 239000001257 hydrogen Substances 0.000 claims abstract description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000005406 washing Methods 0.000 claims abstract description 5
- 239000010457 zeolite Substances 0.000 claims abstract description 5
- 239000003463 adsorbent Substances 0.000 claims abstract 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 53
- 229910052763 palladium Inorganic materials 0.000 claims description 27
- 238000001816 cooling Methods 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 3
- 238000001179 sorption measurement Methods 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 2
- 238000007670 refining Methods 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- 238000002203 pretreatment Methods 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 abstract description 15
- 150000001993 dienes Chemical class 0.000 abstract description 11
- 150000003568 thioethers Chemical class 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 238000003786 synthesis reaction Methods 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 description 10
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 8
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 8
- 239000006227 byproduct Substances 0.000 description 7
- 150000002898 organic sulfur compounds Chemical class 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 150000001491 aromatic compounds Chemical class 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- 229910003294 NiMo Inorganic materials 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- 235000005985 organic acids Nutrition 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910002090 carbon oxide Inorganic materials 0.000 description 3
- 238000003763 carbonization Methods 0.000 description 3
- -1 dienes Natural products 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 125000002534 ethynyl group Chemical class [H]C#C* 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 125000001741 organic sulfur group Chemical group 0.000 description 2
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Industrial Gases (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21037284A JPS6189294A (ja) | 1984-10-09 | 1984-10-09 | コ−クス炉ガスの精製法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21037284A JPS6189294A (ja) | 1984-10-09 | 1984-10-09 | コ−クス炉ガスの精製法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6189294A true JPS6189294A (ja) | 1986-05-07 |
| JPH0349960B2 JPH0349960B2 (enrdf_load_stackoverflow) | 1991-07-31 |
Family
ID=16588258
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21037284A Granted JPS6189294A (ja) | 1984-10-09 | 1984-10-09 | コ−クス炉ガスの精製法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6189294A (enrdf_load_stackoverflow) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100446648B1 (ko) * | 2000-08-24 | 2004-09-04 | 주식회사 포스코 | 냉각에 의한 코크스 가스의 정제 방법 |
| JP2006257351A (ja) * | 2005-03-18 | 2006-09-28 | Toyota Motor Corp | ガス化ガス後処理用触媒反応器及び該触媒反応器を用いたシステム並びにガス化ガス後処理方法 |
| JP2008239443A (ja) * | 2007-03-28 | 2008-10-09 | Mitsubishi Chemicals Corp | 合成ガス製造方法及びシステム |
| CN109641176A (zh) * | 2016-09-01 | 2019-04-16 | 蒂森克虏伯工业解决方案股份公司 | 用于从富氢气体中除去有机硫化合物的方法和装置 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5367702A (en) * | 1976-11-30 | 1978-06-16 | Mitsubishi Kakoki Kaisha Ltd | Purification of coke oven gas |
| JPS57205483A (en) * | 1981-06-09 | 1982-12-16 | Sumitomo Chem Co Ltd | Selective hydrogenation without isomerization |
| JPS59230090A (ja) * | 1983-06-13 | 1984-12-24 | Tokyo Gas Co Ltd | ガスの精製方法 |
| JPS59232175A (ja) * | 1983-06-16 | 1984-12-26 | Tokyo Gas Co Ltd | ガスの精製法 |
-
1984
- 1984-10-09 JP JP21037284A patent/JPS6189294A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5367702A (en) * | 1976-11-30 | 1978-06-16 | Mitsubishi Kakoki Kaisha Ltd | Purification of coke oven gas |
| JPS57205483A (en) * | 1981-06-09 | 1982-12-16 | Sumitomo Chem Co Ltd | Selective hydrogenation without isomerization |
| JPS59230090A (ja) * | 1983-06-13 | 1984-12-24 | Tokyo Gas Co Ltd | ガスの精製方法 |
| JPS59232175A (ja) * | 1983-06-16 | 1984-12-26 | Tokyo Gas Co Ltd | ガスの精製法 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100446648B1 (ko) * | 2000-08-24 | 2004-09-04 | 주식회사 포스코 | 냉각에 의한 코크스 가스의 정제 방법 |
| JP2006257351A (ja) * | 2005-03-18 | 2006-09-28 | Toyota Motor Corp | ガス化ガス後処理用触媒反応器及び該触媒反応器を用いたシステム並びにガス化ガス後処理方法 |
| JP2008239443A (ja) * | 2007-03-28 | 2008-10-09 | Mitsubishi Chemicals Corp | 合成ガス製造方法及びシステム |
| CN109641176A (zh) * | 2016-09-01 | 2019-04-16 | 蒂森克虏伯工业解决方案股份公司 | 用于从富氢气体中除去有机硫化合物的方法和装置 |
| KR20190041520A (ko) * | 2016-09-01 | 2019-04-22 | 티센크루프 인더스트리얼 솔루션스 아게 | 수소-풍부 가스로부터 유기 황 화합물을 제거하기 위한 방법 및 장치 |
| JP2019529306A (ja) * | 2016-09-01 | 2019-10-17 | ティッセンクルップ インダストリアル ソリューションズ アクツィエンゲゼルシャフトＴｈｙｓｓｅｎＫｒｕｐｐ Ｉｎｄｕｓｔｒｉａｌ Ｓｏｌｕｔｉｏｎｓ ＡＧ | 水素富化ガスから有機硫黄化合物を除去するための方法および装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0349960B2 (enrdf_load_stackoverflow) | 1991-07-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |