JPS6158086B2 - - Google Patents
Info
- Publication number
- JPS6158086B2 JPS6158086B2 JP9494182A JP9494182A JPS6158086B2 JP S6158086 B2 JPS6158086 B2 JP S6158086B2 JP 9494182 A JP9494182 A JP 9494182A JP 9494182 A JP9494182 A JP 9494182A JP S6158086 B2 JPS6158086 B2 JP S6158086B2
- Authority
- JP
- Japan
- Prior art keywords
- polysilane
- group
- reaction
- silicon
- zirconium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000548 poly(silane) polymer Polymers 0.000 claims description 66
- 238000006243 chemical reaction Methods 0.000 claims description 27
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 19
- -1 acetylacetoxy group Chemical group 0.000 claims description 16
- 229910052719 titanium Inorganic materials 0.000 claims description 16
- 239000010936 titanium Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 12
- 229910052726 zirconium Chemical group 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 7
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
- 238000000034 method Methods 0.000 description 18
- 229910052710 silicon Inorganic materials 0.000 description 12
- 239000012298 atmosphere Substances 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- 230000009102 absorption Effects 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 8
- 238000005227 gel permeation chromatography Methods 0.000 description 8
- 150000003377 silicon compounds Chemical class 0.000 description 8
- 150000003609 titanium compounds Chemical class 0.000 description 8
- 150000003755 zirconium compounds Chemical class 0.000 description 8
- 238000000862 absorption spectrum Methods 0.000 description 7
- SLLGVCUQYRMELA-UHFFFAOYSA-N chlorosilicon Chemical compound Cl[Si] SLLGVCUQYRMELA-UHFFFAOYSA-N 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 150000002902 organometallic compounds Chemical class 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 4
- 238000010304 firing Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 4
- 229910003691 SiBr Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 229920006037 cross link polymer Polymers 0.000 description 3
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910000799 K alloy Inorganic materials 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000005048 methyldichlorosilane Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229920003257 polycarbosilane Polymers 0.000 description 2
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000005051 trimethylchlorosilane Substances 0.000 description 2
- RTCLHEHPUHREBC-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,5,5,6,6-dodecamethylhexasilinane Chemical compound C[Si]1(C)[Si](C)(C)[Si](C)(C)[Si](C)(C)[Si](C)(C)[Si]1(C)C RTCLHEHPUHREBC-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- 229910008045 Si-Si Inorganic materials 0.000 description 1
- 229910006411 Si—Si Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- UBLFYETXWGACQO-UHFFFAOYSA-N bis[dimethyl(trimethylsilyl)silyl]-dimethylsilane Chemical compound C[Si](C)(C)[Si](C)(C)[Si](C)(C)[Si](C)(C)[Si](C)(C)C UBLFYETXWGACQO-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- GNEPOXWQWFSSOU-UHFFFAOYSA-N dichloro-methyl-phenylsilane Chemical compound C[Si](Cl)(Cl)C1=CC=CC=C1 GNEPOXWQWFSSOU-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920000555 poly(dimethylsilanediyl) polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- ZGSOBQAJAUGRBK-UHFFFAOYSA-N propan-2-olate;zirconium(4+) Chemical compound [Zr+4].CC(C)[O-].CC(C)[O-].CC(C)[O-].CC(C)[O-] ZGSOBQAJAUGRBK-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- UVGLBOPDEUYYCS-UHFFFAOYSA-N silicon zirconium Chemical compound [Si].[Zr] UVGLBOPDEUYYCS-UHFFFAOYSA-N 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- ZOYFEXPFPVDYIS-UHFFFAOYSA-N trichloro(ethyl)silane Chemical compound CC[Si](Cl)(Cl)Cl ZOYFEXPFPVDYIS-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Silicon Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9494182A JPS58213023A (ja) | 1982-06-04 | 1982-06-04 | ポリメタロシランおよびその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9494182A JPS58213023A (ja) | 1982-06-04 | 1982-06-04 | ポリメタロシランおよびその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58213023A JPS58213023A (ja) | 1983-12-10 |
| JPS6158086B2 true JPS6158086B2 (sv) | 1986-12-10 |
Family
ID=14123970
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9494182A Granted JPS58213023A (ja) | 1982-06-04 | 1982-06-04 | ポリメタロシランおよびその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58213023A (sv) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4537942A (en) * | 1984-02-10 | 1985-08-27 | Minnesota Mining And Manufacturing Company | Polyhydridosilanes and their conversion to pyropolymers |
| US4611035A (en) * | 1984-02-10 | 1986-09-09 | Minnesota Mining And Manufacturing Company | Polyhydridosilanes and their conversion to pyropolymers |
| US4762895A (en) * | 1987-08-10 | 1988-08-09 | Dow Corning Corporation | Process for the preparation of preceramic metallopolysilanes and the polymers therefrom |
| US4906710A (en) * | 1988-10-31 | 1990-03-06 | Dow Corning Corporation | Preceramic metallopolysilanes |
| DE4036988A1 (de) * | 1990-11-20 | 1992-05-21 | Wacker Chemie Gmbh | Verfahren zur herstellung von metallopolysilanen und deren verwendung |
| US5292830A (en) * | 1991-06-20 | 1994-03-08 | Tonen Corporation | Thermosetting copolymers, silicon carbide-based fiber and processes for producing same |
| CA2493917C (en) * | 2002-07-23 | 2011-09-13 | Osaka Gas Co., Ltd. | Electrophotographic photosensitive element and electrophotographic apparatus using the same |
| JP4948666B2 (ja) * | 2010-08-17 | 2012-06-06 | キヤノン株式会社 | 帯電部材及びその製造方法 |
| EP3057925B1 (en) * | 2013-10-15 | 2019-11-27 | United Technologies Corporation | Manufacturing process of a preceramic polymer for ceramic including metal boride |
-
1982
- 1982-06-04 JP JP9494182A patent/JPS58213023A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58213023A (ja) | 1983-12-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4767876A (en) | Method for converting organosilicon polymers containing SIH repeat units and organopolysilazane precursors to new and useful preceramic polymers and silicon nitride enriched ceramic materials | |
| EP0152704B1 (en) | Polyhydridosilanes and their conversion to pyropolymers | |
| US4720532A (en) | Organopolysilazane precursors to silicon nitride-rich mixed SiC/Si3 N4 | |
| US4298559A (en) | High yield silicon carbide from alkylated or arylated pre-ceramic polymers | |
| EP0023096B1 (en) | Organometallic copolymers, process for their preparation, and shaped articles of an inorganic carbide obtained therefrom | |
| CA1171871A (en) | Preparing polysilanes and silicon carbide ceramics prepared thereby | |
| JP2507714B2 (ja) | 新規ポリチタノシラザン及びその製造方法 | |
| CA2189985A1 (en) | Ceramic materials fabricated from hydridosiloxane-based ceramic precursors and metal and/or ceramic powders | |
| US4359559A (en) | Novel polymetallocarbosilane, and process for its production | |
| EP0295062B1 (en) | Polysilacyclobutasilazanes | |
| JPS6337129A (ja) | ポリオルガノボロシランセラミック先駆物質重合体およびその製造方法 | |
| CA1281477C (en) | Method for converting si-h containing polysiloxanes to new and useful preceramic polymers and ceramic materials | |
| US4800221A (en) | Silicon carbide preceramic polymers | |
| JPH0363576B2 (sv) | ||
| US5256487A (en) | High char yield silazane derived preceramic polymers and cured compositions thereof | |
| JP2511074B2 (ja) | プリセラミツク重合体、セラミック材料及びそれらの製造方法 | |
| EP0266912B1 (en) | Novel preceramic polymers derived from cyclic silazanes and halogenated disilanes and a method for their preparation | |
| JPS6158086B2 (sv) | ||
| KR940007325B1 (ko) | 폴리실라메틸레노실란 중합체의 제조방법 | |
| Boury et al. | Stoichiometric silicon carbide from borate‐catalyzed polymethylsilane–polyvinylsilane formulations | |
| JPH0967160A (ja) | 一体形セラミック体の製造方法及び一体形セラミック体 | |
| JPS6260414B2 (sv) | ||
| JPS6123932B2 (sv) | ||
| JPH0233734B2 (ja) | Shinkinahorichitanokaruboshiran | |
| JP2760554B2 (ja) | 新規ポリメタロシラザン及びその製造方法 |