JPS6148542B2 - - Google Patents
Info
- Publication number
- JPS6148542B2 JPS6148542B2 JP4973479A JP4973479A JPS6148542B2 JP S6148542 B2 JPS6148542 B2 JP S6148542B2 JP 4973479 A JP4973479 A JP 4973479A JP 4973479 A JP4973479 A JP 4973479A JP S6148542 B2 JPS6148542 B2 JP S6148542B2
- Authority
- JP
- Japan
- Prior art keywords
- acetylene
- polymer
- acetylene polymer
- electron
- electrical conductivity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 59
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 59
- 229920000642 polymer Polymers 0.000 claims description 57
- 150000001875 compounds Chemical class 0.000 claims description 16
- 239000004065 semiconductor Substances 0.000 claims description 16
- ILAHWRKJUDSMFH-UHFFFAOYSA-N boron tribromide Chemical compound BrB(Br)Br ILAHWRKJUDSMFH-UHFFFAOYSA-N 0.000 claims description 10
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 claims description 8
- PQLAYKMGZDUDLQ-UHFFFAOYSA-K aluminium bromide Chemical compound Br[Al](Br)Br PQLAYKMGZDUDLQ-UHFFFAOYSA-K 0.000 claims description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 27
- 239000003054 catalyst Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 150000003623 transition metal compounds Chemical class 0.000 description 4
- 239000011521 glass Substances 0.000 description 3
- 239000013081 microcrystal Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 239000012456 homogeneous solution Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- -1 5 - cyclopentadienyl Chemical group 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4973479A JPS55143702A (en) | 1979-04-24 | 1979-04-24 | High molecular semiconductor |
| GB8037339A GB2061291B (en) | 1979-03-29 | 1980-03-28 | Process for preparing highly conductive acetylene high polymer |
| DE3041420A DE3041420C1 (de) | 1979-03-29 | 1980-03-28 | Verfahren zur Herstellung von elektrisch leitenden Acetylenhochpolymeren |
| US06/224,518 US4487709A (en) | 1979-03-29 | 1980-03-28 | Process for producing electrically conductive high polymer of acetylene |
| PCT/JP1980/000052 WO1980002146A1 (en) | 1979-03-29 | 1980-03-28 | Process for preparing highly conductive acetylene high polymer |
| EP80900609A EP0026234B1 (en) | 1979-03-29 | 1980-10-23 | Process for preparing highly conductive acetylene high polymer |
| US06/657,266 US4594180A (en) | 1979-03-29 | 1984-10-03 | Process for producing electrically conductive high polymer of acetylene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4973479A JPS55143702A (en) | 1979-04-24 | 1979-04-24 | High molecular semiconductor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55143702A JPS55143702A (en) | 1980-11-10 |
| JPS6148542B2 true JPS6148542B2 (bs) | 1986-10-24 |
Family
ID=12839412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4973479A Granted JPS55143702A (en) | 1979-03-29 | 1979-04-24 | High molecular semiconductor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55143702A (bs) |
-
1979
- 1979-04-24 JP JP4973479A patent/JPS55143702A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55143702A (en) | 1980-11-10 |
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