JPS6144833A - 塩水からのグリセリンの回収方法 - Google Patents
塩水からのグリセリンの回収方法Info
- Publication number
- JPS6144833A JPS6144833A JP60155864A JP15586485A JPS6144833A JP S6144833 A JPS6144833 A JP S6144833A JP 60155864 A JP60155864 A JP 60155864A JP 15586485 A JP15586485 A JP 15586485A JP S6144833 A JPS6144833 A JP S6144833A
- Authority
- JP
- Japan
- Prior art keywords
- stream
- glycerin
- water
- liquid phase
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title claims description 87
- 235000011187 glycerol Nutrition 0.000 title claims description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 32
- 150000003839 salts Chemical class 0.000 title claims description 25
- 238000000034 method Methods 0.000 claims description 27
- 239000012528 membrane Substances 0.000 claims description 26
- 239000007791 liquid phase Substances 0.000 claims description 18
- 238000001704 evaporation Methods 0.000 claims description 17
- 238000000909 electrodialysis Methods 0.000 claims description 15
- 230000008020 evaporation Effects 0.000 claims description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 13
- 239000012267 brine Substances 0.000 claims description 9
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 9
- 238000005341 cation exchange Methods 0.000 claims description 7
- 239000011780 sodium chloride Substances 0.000 claims description 7
- 238000010790 dilution Methods 0.000 claims description 5
- 239000012895 dilution Substances 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 238000005349 anion exchange Methods 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 3
- 238000004508 fractional distillation Methods 0.000 claims description 3
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 3
- 230000001376 precipitating effect Effects 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims 1
- 150000001450 anions Chemical class 0.000 description 7
- 150000001768 cations Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000003822 epoxy resin Substances 0.000 description 5
- 238000005194 fractionation Methods 0.000 description 5
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 5
- 229920000647 polyepoxide Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000003011 anion exchange membrane Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- -1 alkaline earth metal salt Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003010 cation ion exchange membrane Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/26—Further operations combined with membrane separation processes
- B01D2311/2642—Aggregation, sedimentation, flocculation, precipitation or coagulation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/26—Further operations combined with membrane separation processes
- B01D2311/2646—Decantation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/26—Further operations combined with membrane separation processes
- B01D2311/2669—Distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/26—Further operations combined with membrane separation processes
- B01D2311/2673—Evaporation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Urology & Nephrology (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Removal Of Specific Substances (AREA)
- Gas Separation By Absorption (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Detergent Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000487758A CA1237540A (en) | 1984-07-31 | 1985-07-30 | Method of adjusting radiation image read-out conditions |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US631125 | 1984-07-16 | ||
| US06/631,125 US4599178A (en) | 1984-07-16 | 1984-07-16 | Recovery of glycerine from saline waters |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6144833A true JPS6144833A (ja) | 1986-03-04 |
| JPH0542415B2 JPH0542415B2 (enExample) | 1993-06-28 |
Family
ID=24529868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60155864A Granted JPS6144833A (ja) | 1984-07-16 | 1985-07-15 | 塩水からのグリセリンの回収方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4599178A (enExample) |
| EP (1) | EP0168893B1 (enExample) |
| JP (1) | JPS6144833A (enExample) |
| AT (1) | ATE50511T1 (enExample) |
| CA (1) | CA1249239A (enExample) |
| DE (1) | DE3576122D1 (enExample) |
| ES (1) | ES8607201A1 (enExample) |
| ZA (1) | ZA855308B (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008540615A (ja) * | 2005-05-20 | 2008-11-20 | ソルヴェイ（ソシエテ アノニム） | ポリヒドロキシ化された脂肪族炭化水素をクロロヒドリンに転化させる方法 |
| CN104230046A (zh) * | 2014-08-21 | 2014-12-24 | 波鹰(厦门)科技有限公司 | 一种高盐含甘油高深度有机废水中氯化钠及甘油的分离装置 |
| US9309209B2 (en) | 2010-09-30 | 2016-04-12 | Solvay Sa | Derivative of epichlorohydrin of natural origin |
| US9663427B2 (en) | 2003-11-20 | 2017-05-30 | Solvay (Société Anonyme) | Process for producing epichlorohydrin |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3721474A1 (de) * | 1987-06-30 | 1989-01-12 | Huels Chemische Werke Ag | Verfahren zur herstellung von hexadiin(2,4)-diol-1,6 |
| US6023003A (en) * | 1998-01-13 | 2000-02-08 | Reading & Bates Development Co. | Process and system for recovering glycol from glycol/brine streams |
| DE19838425A1 (de) * | 1998-08-24 | 2000-03-02 | Degussa | Verfahren zur Abtrennung mehrfunktioneller Alkohole von wasserlöslichen Salzen aus wäßrigen Systemen |
| US7235183B2 (en) * | 2004-06-22 | 2007-06-26 | Crown Iron Works Company | Glycerine foots salt separation system |
| KR20080037613A (ko) | 2005-05-20 | 2008-04-30 | 솔베이(소시에떼아노님) | 폴리히드록실화 지방족 탄화수소의 클로로히드린으로의전환 방법 |
| DE102006028501A1 (de) * | 2006-06-21 | 2007-12-27 | Lurgi Ag | Verfahren und Vorrichtung zur Behandlung einer Rückstände enthaltenden glyzerinreichen Phase |
| US20080067069A1 (en) | 2006-06-22 | 2008-03-20 | Siemens Water Technologies Corp. | Low scale potential water treatment |
| US7744760B2 (en) * | 2006-09-20 | 2010-06-29 | Siemens Water Technologies Corp. | Method and apparatus for desalination |
| US20100032617A1 (en) * | 2007-02-20 | 2010-02-11 | Solvay (Societe Anonyme) | Process for manufacturing epichlorohydrin |
| FR2913684B1 (fr) * | 2007-03-14 | 2012-09-14 | Solvay | Procede de fabrication de dichloropropanol |
| TWI500609B (zh) * | 2007-06-12 | 2015-09-21 | Solvay | 含有環氧氯丙烷的產品，其製備及其不同應用中的用途 |
| FR2918058A1 (fr) * | 2007-06-28 | 2009-01-02 | Solvay | Produit a base de glycerol, procede pour sa purification et son utilisation dans la fabrication de dichloropropanol |
| US8715568B2 (en) * | 2007-10-02 | 2014-05-06 | Solvay Sa | Use of compositions containing silicon for improving the corrosion resistance of vessels |
| US8585882B2 (en) | 2007-11-30 | 2013-11-19 | Siemens Water Technologies Llc | Systems and methods for water treatment |
| TWI478875B (zh) * | 2008-01-31 | 2015-04-01 | Solvay | 使水性組成物中之有機物質降解之方法 |
| WO2009121853A1 (en) * | 2008-04-03 | 2009-10-08 | Solvay (Société Anonyme) | Composition comprising glycerol, process for obtaining same and use thereof in the manufacture of dichloropropanol |
| FR2935968B1 (fr) * | 2008-09-12 | 2010-09-10 | Solvay | Procede pour la purification de chlorure d'hydrogene |
| WO2010033817A2 (en) * | 2008-09-18 | 2010-03-25 | Redox Tech, Llc | Crude glycerol purification process |
| FR2939434B1 (fr) * | 2008-12-08 | 2012-05-18 | Solvay | Procede de traitement de glycerol. |
| DE102009017098B3 (de) * | 2009-04-15 | 2010-08-12 | Lurgi Gmbh | Verfahren zur kontinuierlichen Herstellung von Reinglycerin aus Kaliumsulfat enthaltendem Rohglycerin |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB845653A (en) * | 1958-03-12 | 1960-08-24 | Permutit Co Ltd | Improvements relating to electrodialytic cells |
| NL128859C (enExample) * | 1960-09-19 | |||
| CH489259A (de) * | 1968-06-08 | 1970-04-30 | Dietzsch Gmbh Hans Joachim | Verfahren zur Herstellung von kapillaren Austauschern |
| US3715402A (en) * | 1969-08-08 | 1973-02-06 | Basf Wyandotte Corp | Removal of catalysts from polyols |
| US4036749A (en) * | 1975-04-30 | 1977-07-19 | Anderson Donald R | Purification of saline water |
-
1984
- 1984-07-16 US US06/631,125 patent/US4599178A/en not_active Expired - Lifetime
-
1985
- 1985-06-17 CA CA000484239A patent/CA1249239A/en not_active Expired
- 1985-07-09 AT AT85201150T patent/ATE50511T1/de not_active IP Right Cessation
- 1985-07-09 DE DE8585201150T patent/DE3576122D1/de not_active Expired - Lifetime
- 1985-07-09 EP EP19850201150 patent/EP0168893B1/en not_active Expired - Lifetime
- 1985-07-15 ES ES545182A patent/ES8607201A1/es not_active Expired
- 1985-07-15 ZA ZA855308A patent/ZA855308B/xx unknown
- 1985-07-15 JP JP60155864A patent/JPS6144833A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9663427B2 (en) | 2003-11-20 | 2017-05-30 | Solvay (Société Anonyme) | Process for producing epichlorohydrin |
| JP2008540615A (ja) * | 2005-05-20 | 2008-11-20 | ソルヴェイ（ソシエテ アノニム） | ポリヒドロキシ化された脂肪族炭化水素をクロロヒドリンに転化させる方法 |
| US9309209B2 (en) | 2010-09-30 | 2016-04-12 | Solvay Sa | Derivative of epichlorohydrin of natural origin |
| CN104230046A (zh) * | 2014-08-21 | 2014-12-24 | 波鹰(厦门)科技有限公司 | 一种高盐含甘油高深度有机废水中氯化钠及甘油的分离装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0542415B2 (enExample) | 1993-06-28 |
| US4599178A (en) | 1986-07-08 |
| EP0168893A2 (en) | 1986-01-22 |
| EP0168893A3 (en) | 1987-08-19 |
| ES8607201A1 (es) | 1986-05-16 |
| ZA855308B (en) | 1986-02-26 |
| ATE50511T1 (de) | 1990-03-15 |
| ES545182A0 (es) | 1986-05-16 |
| CA1249239A (en) | 1989-01-24 |
| DE3576122D1 (de) | 1990-04-05 |
| EP0168893B1 (en) | 1990-02-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS6144833A (ja) | 塩水からのグリセリンの回収方法 | |
| EP1809408B1 (en) | Water desalination process and apparatus | |
| US5503729A (en) | Electrodialysis including filled cell electrodialysis (electrodeionization) | |
| US11912591B2 (en) | Electrodialysis processes using an organic solvent for separating dissolved species | |
| CN107381886B (zh) | 一种反渗透浓水近零排放的方法 | |
| Widiasa et al. | Performance of a novel electrodeionization technique during citric acid recovery | |
| US5352345A (en) | Ion exchange resin regenerant waste recovery and recycling via bipolar membranes | |
| US20150315055A1 (en) | Water Treatment Process | |
| US20100116663A1 (en) | Recovery of regenerant electrolyte | |
| EP2429678B1 (en) | Brine treatment scaling control method | |
| CN105254083A (zh) | 煤化工高盐废水的处理工艺及系统 | |
| JP3270244B2 (ja) | 廃液処理方法及び廃液処理装置 | |
| Comstock | Desal-5 membrane for water softening | |
| CN85105641A (zh) | 从盐水中回收甘油的方法 | |
| JP3066981B2 (ja) | 硫酸ナトリウムによる低濃度のフェノールの回収 | |
| EP0247670B1 (en) | A continuous process for the production of epichlorohydrin | |
| CA2779656A1 (en) | Electrodialysis-distillation hybrid process for the recovery of dimethylsulfoxide (dmso) solvent from industrial effluent | |
| JPH03146118A (ja) | Ａｌ材の表面処理廃液の処理方法 | |
| EP0229415B1 (en) | Process for the production of dichlorohydrin | |
| US20250100913A1 (en) | Electrodialysis process for high ion rejection in the presence of boron | |
| Winnicki et al. | Zinc recovery from the rayon industry wastes by combining the column ion-exchange method with electrodialysis processes | |
| JPH07171351A (ja) | 脱塩プロセスより排出される濃縮排水の再脱塩方法 |