JPS6140343B2 - - Google Patents
Info
- Publication number
- JPS6140343B2 JPS6140343B2 JP55174249A JP17424980A JPS6140343B2 JP S6140343 B2 JPS6140343 B2 JP S6140343B2 JP 55174249 A JP55174249 A JP 55174249A JP 17424980 A JP17424980 A JP 17424980A JP S6140343 B2 JPS6140343 B2 JP S6140343B2
- Authority
- JP
- Japan
- Prior art keywords
- sulfur
- metal
- sulfide
- standard electrode
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 57
- 229910052717 sulfur Inorganic materials 0.000 claims description 57
- 239000011593 sulfur Substances 0.000 claims description 57
- 239000002184 metal Substances 0.000 claims description 38
- 229910052751 metal Inorganic materials 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 26
- 229910052976 metal sulfide Inorganic materials 0.000 claims description 19
- 239000000126 substance Substances 0.000 claims description 15
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 13
- 239000002203 sulfidic glass Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 18
- 229910052760 oxygen Inorganic materials 0.000 description 18
- 239000001301 oxygen Substances 0.000 description 18
- 230000003647 oxidation Effects 0.000 description 11
- 238000007254 oxidation reaction Methods 0.000 description 11
- 239000007789 gas Substances 0.000 description 9
- 238000005259 measurement Methods 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 6
- -1 alkaline earth metal sulfides Chemical class 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 239000003779 heat-resistant material Substances 0.000 description 5
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229910000805 Pig iron Inorganic materials 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000006477 desulfuration reaction Methods 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 150000003568 thioethers Chemical class 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 238000009529 body temperature measurement Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000012733 comparative method Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229910000915 Free machining steel Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/411—Cells and probes with solid electrolytes for investigating or analysing of liquid metals
- G01N27/4112—Composition or fabrication of the solid electrolyte
- G01N27/4114—Composition or fabrication of the solid electrolyte for detection of gases other than oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55174249A JPS5797441A (en) | 1980-12-10 | 1980-12-10 | Rapid measuring method for quantity of sulfur |
US06/246,944 US4406754A (en) | 1980-03-28 | 1981-03-24 | Method and probe for the rapid determination of sulfur level |
DE3112218A DE3112218C2 (de) | 1980-03-28 | 1981-03-27 | Meßvorrichtung zur Schwefelbestimmung in Gas und Metallschmelzen |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55174249A JPS5797441A (en) | 1980-12-10 | 1980-12-10 | Rapid measuring method for quantity of sulfur |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5797441A JPS5797441A (en) | 1982-06-17 |
JPS6140343B2 true JPS6140343B2 (enrdf_load_stackoverflow) | 1986-09-09 |
Family
ID=15975317
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55174249A Granted JPS5797441A (en) | 1980-03-28 | 1980-12-10 | Rapid measuring method for quantity of sulfur |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5797441A (enrdf_load_stackoverflow) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9300435D0 (en) * | 1993-01-12 | 1993-03-03 | Cookson Group Plc | Sensors for the analysis of molten metals |
AT400440B (de) * | 1993-12-06 | 1995-12-27 | Vianova Kunstharz Ag | Verfahren zur herstellung von wasserverdünnbaren lackbindemitteln und deren verwendung |
JP4620503B2 (ja) * | 2005-03-08 | 2011-01-26 | 三井造船株式会社 | 酸素濃度センサ |
-
1980
- 1980-12-10 JP JP55174249A patent/JPS5797441A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5797441A (en) | 1982-06-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3723279A (en) | Apparatus for oxygen determination | |
TW200417731A (en) | Measurement device for determining oxygen activity in molten metal or slag | |
JPS6140343B2 (enrdf_load_stackoverflow) | ||
White | Equilibrium at high temperatures in systems containing iron oxides | |
JPS63286760A (ja) | 溶融鉄中の不純物元素の濃度測定用複合プロ−ブ | |
Du Plessis et al. | Reducing diffusible hydrogen contents of shielded metal arc welds through addition of flux-oxidizing ingredients | |
Maramba et al. | Phosphide capacities of ferromanganese smelting slags | |
Nekhoroshev et al. | Reoptimization of the CaO–FeO–Fe2O3–SiO2 system integrated with EPMA studies (part I—experimental results) | |
Enaka et al. | Chemical potentials of oxygen within 3‐phase assemblages of the system CaO+ SiO2+ FexO | |
KR101190592B1 (ko) | 고체 전해질관 및 이를 포함한 고온 융체의 황 농도 측정용 센서팁 | |
JPS59136652A (ja) | 溶鋼成分推定方法 | |
Russell et al. | Probing for more than temperature | |
JPS59109852A (ja) | 溶融金属用酸素センサ−の酸素基準極 | |
US6328867B1 (en) | Sensors for measuring the solute contents of liquid ferrous and non-ferrous metals | |
Geldenhuis | Development of electrochemical sensing techniques for the determination of activity-composition relations in liquid alloys and slags at 1873 K | |
Iwase et al. | Measurements of the ferrous oxide activities in slags to reduce steelmaking slag volume | |
JPH0650296B2 (ja) | 溶銑の燐濃度測定方法 | |
Matsushita et al. | The Application of Oxygen Concentration Cells with the Solid Electrolyte, ZrO2· CaO to Basic Research Works in Iron and Steel Making | |
EP4265743B1 (en) | Method for desulfurizing molten metal | |
Iwase et al. | The electrochemical determination of FeO activities in molten slags and the reduction of steel making slag volume | |
Yamada et al. | Determination of mixed ionic and electronic conduction in commercial-grade magnesia-stabilized zirconia electrolyte | |
SU1583449A1 (ru) | Способ определени массы твердых оксидов, провзаимодействовавших с расплавом металла | |
Langová et al. | Electrochemical measurement of oxygen in liquid Fe O S/CaO Al2O3 Fe2O3 CaS system | |
SU556126A1 (ru) | Огнеупорна масса дл изготовлени вакуумплотных изделий | |
JPS6318015A (ja) | 転炉吹錬におけるマンガン濃度の推定方法 |