JPS61279656A - Non-heattreated steel for hot forging - Google Patents
Non-heattreated steel for hot forgingInfo
- Publication number
- JPS61279656A JPS61279656A JP12167985A JP12167985A JPS61279656A JP S61279656 A JPS61279656 A JP S61279656A JP 12167985 A JP12167985 A JP 12167985A JP 12167985 A JP12167985 A JP 12167985A JP S61279656 A JPS61279656 A JP S61279656A
- Authority
- JP
- Japan
- Prior art keywords
- steel
- hot forging
- bainite
- less
- ferrite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- Heat Treatment Of Steel (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は非調質鋼に係り、特に靭性を向上し得る熱間鍛
造用非調質鋼に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to non-thermal treated steel, and particularly to non-thermal treated steel for hot forging which can improve toughness.
(従来の技術及び問題点)
非調質鋼は、熱間加工後に熱処理を施して所望の強度、
靭性を得る調質鋼に比べ、圧延、鍛造等の熱間加工のま
へで供されるものであり、その製造コストを低減化でき
る利点がある。特に熱間鍛造用非調質鋼は大型部品の製
造に多用され1機械的性質の向上の研究が盛んに行われ
ている。(Conventional technology and problems) Non-tempered steel is heat treated after hot working to achieve the desired strength and
Compared to tempered steel that obtains toughness, it is provided through hot processing such as rolling and forging, and has the advantage of reducing manufacturing costs. In particular, non-tempered steel for hot forging is frequently used in the manufacture of large parts, and research is being actively conducted to improve its mechanical properties.
従来の熱間鍛造用非調質鋼は、V、N等を添加してVの
炭窒化物を析出させ、フェライト+パーライト或いはフ
ェライト+パーライト+ベーナイトの混合組織を得て、
高強度化及び高靭性化が図られている。しかし、その強
度は約90 kgf / mm”以上の如く高レベルの
ものが得られるものの、逆に靭性が低下するという問題
がある。これは、焼入れ、焼もどし等の熱処理を施すこ
となく、熱間鍛造後の自然冷却の下で強度増大化元素の
添加によってのみ機械的性質を得ようとする非調質鋼の
一般的な欠点であり、特に高強度域で衝撃値が低いため
、その適用部品に自ずと制限があった。Conventional non-tempered steel for hot forging is made by adding V, N, etc. to precipitate V carbonitride to obtain a mixed structure of ferrite + pearlite or ferrite + pearlite + bainite.
Efforts are being made to increase strength and toughness. However, although a high level of strength of approximately 90 kgf/mm'' or more can be obtained, there is a problem in that the toughness decreases. This is a common drawback of non-tempered steels, which attempt to obtain mechanical properties only by adding strength-enhancing elements under natural cooling after forging, and its application is difficult due to its low impact value, especially in the high strength range. There were naturally limitations on parts.
(発明の目的)
本発明は、上記従来技術の欠点を解消するためになされ
たものであって、その目的とするところは、特に引張強
さ約90 kgf/ m+a”以上の高強度域において
高い衝撃値を得ることができ、その適用部品の拡大を可
能にする熱間鍛造用非調質鋼を提供することにある。(Object of the Invention) The present invention has been made in order to eliminate the drawbacks of the above-mentioned prior art, and its purpose is to improve The object of the present invention is to provide a non-tempered steel for hot forging that can obtain a high impact value and expand the range of parts to which it can be applied.
(発明の構成)
上記目的を達成するため、本発明は、添加元素の調整と
組織の改善によって可能にしたものである。(Structure of the Invention) In order to achieve the above object, the present invention has been made possible by adjusting the additive elements and improving the structure.
すなわち、本発明に係る熱間鍛造用非調質鋼は、C:0
.20〜0.50%、Si:0.10〜1.00%、M
n:1.0〜2.0%、V:0.05〜0.30%、N
b:0.01〜0.06%、5oQAQ:0.01〜0
.06%及びN:0.01〜0.03%を含むことを基
本組成とし、これに必要に応じて、Cr:・0.30〜
1.0%、Ni:0.3〜2.0%、MO=0.05〜
0.50%のうちの1種又は2種以上、及び/又は、被
剛性向上元素としてS:0.2%以下、Pb:0.4%
以下、Te:0.1%以下、Bi:0.1%以下及びC
a:0.01%以下のうちの1種又は2種以上を添加し
、残部が実質的にFeからなる組成を有し、熱間鍛造後
の冷却によってフェライト+ベーナイトの混合組織又は
ベーナイト一相組織からなる組織を有することを特徴と
するものである。That is, the non-temperature steel for hot forging according to the present invention has a C:0
.. 20-0.50%, Si: 0.10-1.00%, M
n: 1.0-2.0%, V: 0.05-0.30%, N
b: 0.01-0.06%, 5oQAQ: 0.01-0
.. The basic composition includes 0.06% and N: 0.01~0.03%, and if necessary, Cr: 0.30~0.30%.
1.0%, Ni: 0.3-2.0%, MO=0.05-
One or more of 0.50% and/or as stiffness improving elements S: 0.2% or less, Pb: 0.4%
Below, Te: 0.1% or less, Bi: 0.1% or less, and C
a: One or more of 0.01% or less is added, and the remainder has a composition consisting essentially of Fe, and by cooling after hot forging, a mixed structure of ferrite + bainite or a single bainite phase is formed. It is characterized by having an organization consisting of tissues.
以下に本発明を実施例に基づいて詳細に説明する。The present invention will be explained in detail below based on examples.
まず、本発明鋼における添加元素の上限値乃至下限値の
限定理由を以下に示す。First, the reasons for limiting the upper and lower limits of the additive elements in the steel of the present invention are shown below.
Cは強度を確保するために0.20%以上含有させる必
要がある。しかし、0.50%を超えると靭性を劣化さ
せるので、0.50%を上限値とする。C must be contained in an amount of 0.20% or more to ensure strength. However, if it exceeds 0.50%, the toughness deteriorates, so the upper limit is set at 0.50%.
下1
Siは脱酸元素であり、0.10%以上を添加する必要
があるが、1.00%以下で脱酸効果は十分に得られ、
それより多量に添加すると却って被削性を低下させるた
め、1.00%を上限値とする。Lower 1 Si is a deoxidizing element, and it is necessary to add 0.10% or more, but a sufficient deoxidizing effect can be obtained with 1.00% or less.
If added in a larger amount, the machinability will deteriorate, so the upper limit is set at 1.00%.
M旦
Mnは強度を増大するために適量添加する必要があり、
特に本発明では、熱間鍛造後の冷却によりフェライト+
ベーナイトの混合組織又はベーナイト一相組織を得てパ
ーライトが形成されないようにするため、1.0%以上
添加する。しかし、多量に添加するとマルテンサイトが
形成されるので、2.0%を上限値とする。It is necessary to add an appropriate amount of Mn to increase the strength.
In particular, in the present invention, ferrite +
It is added in an amount of 1.0% or more in order to obtain a bainite mixed structure or a bainite single-phase structure and to prevent the formation of pearlite. However, if added in a large amount, martensite will be formed, so the upper limit is set at 2.0%.
■
■は熱間鍛造後の冷却時に炭窒化物が析出して析出強化
を図ることができるので、0.05%以上を添加する必
要があるが、多量に添加すると却って靭性を低下させる
ので、0.30%を上限値とする。■■ Carbonitrides precipitate during cooling after hot forging and can strengthen precipitation, so it is necessary to add 0.05% or more, but adding too much will actually reduce toughness. The upper limit is 0.30%.
Nb、5oQAQ、N
Nb、 so Q A Q及びNは結晶粒を微細化して
靭性を向上させるのに効果的な元素であり、これらの3
種類の元素をバランスよく添加する必要がある。そのた
めには各元素とも0,01%以上添加するが、多量に添
加するとそのバランスが崩れ。Nb, 5oQAQ, N Nb, so Q A Q and N are effective elements for refining crystal grains and improving toughness, and these three
It is necessary to add various types of elements in a well-balanced manner. To achieve this, each element must be added in an amount of 0.01% or more, but adding too much will disrupt the balance.
却って靭性劣化を招くので、Nb及び5oQAQは各々
0.06%を上限値とし、Nは0003%を上限値とす
る。On the contrary, it causes toughness deterioration, so Nb and 5oQAQ each have an upper limit of 0.06%, and N has an upper limit of 0003%.
Cr、 Ni、M。Cr, Ni, M.
Cr、 N i 、 Moは、Mnと同様、熱間鍛造後
の冷却によってパーライトが形成されるのを阻止するパ
ーライトフリー化元素であるが、Mnを必須成分として
添加するので、Cr、Ni、Moは必要に応じて添加す
ることができる。添加する場合には、Cr:0.30%
以上、Niの場合は0.3%以上、Moにおいては0.
05%以上でなければ上記効果が期待できず、しかし、
Cr1.0%、Ni2゜0%、Mo0.5%を超えると
マルテンサイトが形成されることになるので、Cr:0
.30〜1.0%、Ni:0.30〜2.0%、Mo:
0.05”0.50%の範囲で1種又は2種以上を添加
する6S、Pb、Te%Bi、Ca
S、Pb、Te、Bi、及びCaは切削性を顕著に向上
する元素であるので、必要に応じて添加することができ
る。添加する場合には、それらの元素□
の1種又は2種以上を添加すればよいが、各元素とも多
量に添加すると靭性の劣化を招くので、Sは0.2%、
pbは0.40%、Teは0.1%、Biは0.1%、
Caは0.01%を各々上限値とする。Cr, Ni, and Mo, like Mn, are pearlite-free elements that prevent pearlite from being formed by cooling after hot forging, but since Mn is added as an essential component, Cr, Ni, and Mo can be added as necessary. When added, Cr: 0.30%
Above, in the case of Ni, it is 0.3% or more, and in the case of Mo, it is 0.3% or more.
The above effect cannot be expected unless it is 0.5% or more, however,
If Cr exceeds 1.0%, Ni2゜0%, and Mo exceeds 0.5%, martensite will be formed, so Cr:0
.. 30-1.0%, Ni: 0.30-2.0%, Mo:
0.05" 6S, Pb, Te% Bi, Ca S, Pb, Te, Bi, and Ca added one or more in the range of 0.50% are elements that significantly improve machinability. Therefore, it can be added as necessary.If added, one or more of these elements □ may be added, but adding a large amount of each element will lead to deterioration of toughness. S is 0.2%,
pb is 0.40%, Te is 0.1%, Bi is 0.1%,
The upper limit of Ca is 0.01%.
上記成分組成の鋼は、熱間鍛造後、空冷乃至微風冷却に
よって冷却し、パーライトが形成されないようにしてフ
ェライト+ベーナイトの混合組織又はベーナイト一相組
織を得る。その際、MnやCr 、 Ni、 Moの量
と適用部品の質量効果に応じて、適宜冷却速度を決定す
る。After hot forging, the steel having the above-mentioned composition is cooled by air cooling or breeze cooling to obtain a mixed structure of ferrite + bainite or a single phase structure of bainite while preventing the formation of pearlite. At that time, the cooling rate is determined as appropriate depending on the amount of Mn, Cr, Ni, and Mo and the mass effect of the applied parts.
かくして、本発明鋼は上記の如く組成を調整して熱間鍛
造後の冷却によりフェライト士ベーナイト混合組織又は
ベーナイト一相組織を得ることができ、特にHRC25
(引張強さ約89 kgf / mn+2相当)以上の
高強度域で5kgt−m/ca+”(J I S 3号
試験片、室温)以上の高い衝撃値を得ることが可能とな
る。Thus, the steel of the present invention can have a ferritic-bainite mixed structure or a bainite single-phase structure by adjusting the composition as described above and cooling after hot forging.
It is possible to obtain a high impact value of 5 kgt-m/ca+" (JIS No. 3 test piece, room temperature) in a high strength range of 5 kgt-m/ca+" (equivalent to a tensile strength of about 89 kgf/mn+2) or more.
(実施例)
第1表に示す成分組成(wt%)の鋼を電気炉溶解によ
り溶製し、炉外精錬を行った後、鋳造して鋳塊を得、分
解圧延−小型圧延によって鍛造用素材(80mmφ)を
製造した。次いでこれらを1050℃で熱間鍛造してジ
ャーナル径40mmφのクランクシャフトを製造し、熱
間鍛造後微風冷却(100℃/m1n)シた。得られた
鍛造材について機械的性質及び組織を調べた。その結果
を第2表に示す。なお、衝撃値は、鍛造材よりJISa
号シャルピー試験片を採取し、室温でシャルピー衝撃試
験を行ったものであり、強度は硬さくHRC)にて評価
し、硬さHRC25は引張強さ約89kgf/mad2
に換算でき、より高い硬さはより高い引張強さを示す。(Example) Steel having the composition (wt%) shown in Table 1 is melted by electric furnace melting, after which it is refined outside the furnace, and then cast to obtain an ingot, which is then decomposed and rolled to obtain a forging ingot. A material (80 mmφ) was manufactured. Next, these were hot forged at 1050° C. to produce a crankshaft with a journal diameter of 40 mmφ, and after the hot forging, the crankshaft was cooled in a breeze (100° C./m1n). The mechanical properties and structure of the obtained forged material were investigated. The results are shown in Table 2. In addition, the impact value is JISa than forged material.
A No. Charpy test piece was taken and a Charpy impact test was conducted at room temperature.The strength was evaluated by hardness HRC25, which has a tensile strength of approximately 89kgf/mad2.
higher hardness indicates higher tensile strength.
c以下余白】
第2表より明らかなように、■の添加によって高強度化
を図った従来鋼はHRC25の高強度にて衝撃値が2
kgf / cm”と劣るのに対し、本発明鋼はいずれ
もVR撃値が極めて優れており、しかも強度も高い。[Margin below c] As is clear from Table 2, the conventional steel, which has been increased in strength by adding ■, has an impact value of 2 at a high strength of HRC25.
kgf/cm", whereas all of the steels of the present invention have extremely excellent VR impact values and are also high in strength.
また、本発明鋼のうち、Cr、Ni、Moを添加したも
のではベーナイト組織が得られ、より高強度を示したが
、高強度化の割には衝撃値も高いレベルを維持しており
、また、被削性向上元素を添加したものは高強度域での
靭性を保持しっ\優れた被削性を有することを確認した
。Furthermore, among the steels of the present invention, those to which Cr, Ni, and Mo were added had a bainitic structure and exhibited higher strength, but the impact value remained at a high level considering the increased strength. In addition, it was confirmed that the material to which machinability-improving elements were added maintains toughness in the high strength range and has excellent machinability.
(発明の効果)
以上詳述したように、本発明の熱間鍛造用非調質鋼は、
添加成分の組成調整、特にMn等のパーライトフリー化
元素の添加並びにNb、 soΩAQ及びNの結晶粒微
細化元素の好バランスの下での添加によってフェライト
+ベーナイトの混合組織又はベーナイト一相組織とし、
パーライトが形成されないようにしたので、従来鋼の欠
点であった高強度域での靭性劣化を改善でき、優れた靭
性を付与することができ、更に被剛性を大幅しこ向上さ
せることも可能であるので、非調質鋼の低コスト化を十
分に発揮して熱間鍛造部品の適用拡大しこ寄与するとこ
ろが非常に大きい。(Effects of the Invention) As detailed above, the non-tempered steel for hot forging of the present invention has the following features:
A mixed structure of ferrite + bainite or a single phase structure of bainite is obtained by adjusting the composition of the additive components, especially adding pearlite-free elements such as Mn, and adding grain-refining elements such as Nb, soΩAQ, and N in a well-balanced manner,
Since pearlite is not formed, it is possible to improve toughness deterioration in the high strength range, which was a drawback of conventional steel, and it is possible to provide excellent toughness, and it is also possible to significantly improve stiffness. Therefore, the cost reduction of non-thermal treated steel can be fully utilized and the application of hot forged parts can be expanded.
1・ 1゜1・ 1゜
Claims (1)
%、Si:0.10〜1.00%、Mn:1.0〜2.
0%、V:0.05〜0.30%、Nb:0.01〜0
.06%、solAl:0.01〜0.06%及びN:
0.01〜0.03%を含み、残部がFe及び不可避的
不純物からなり、熱間鍛造後の冷却によってフェライト
+ベーナイトの混合組織又はベーナイト一相組織を有す
ることを特徴とする熱間鍛造用非調質鋼。 2 C:0.20〜0.50%、Si:0.10〜1.
00%、Mn:1.0〜2.0%、V:0.05〜0.
30%、Nb:0.01〜0.06%、solAl:0
.01〜0.06%及びN:0.01〜0.03%を含
み、更にCr:0.30〜1.0%、Ni:0.30〜
2.0%、Mo:0.05〜0.50%のうちの1種又
は2種以上を含み、残部がFe及び不可避的不純物から
なり、熱間鍛造後の冷却によってフェライト+ベーナイ
トの混合組織又はベーナイト一相組織を有することを特
徴とする熱間鍛造用非調質鋼。 3 C:0.20〜0.50%、Si:0.10〜1.
00%、Mn:1.0〜2.0%、V:0.05〜0.
30%、Nb:0.01〜0.06%、solAl:0
.01〜0.06%及びN:0.01〜0.03%を含
み、更にS:0.2%以下、Pb:0.40%以下、T
e:0.1%以下、Bi:0.1%以下及びCa:0.
01%以下のうちの1種又は2種以上を含み、残部がF
e及び不可避的不純物からなり、熱間鍛造後の冷却によ
ってフェライト+ベーナイトの混合組織又はベーナイト
一相組織を有することを特徴とする熱間鍛造用非調質鋼
。 4 C:0.20〜0.50%、Si:0.10〜1.
00%、Mn:1.0〜2.0%、V:0.05〜0.
30%、Nb:0.01〜0.06%、solAl:0
.01〜0.06%及びN:0.01〜0.03%を含
み、更にCr:0.30〜1.0%、Ni:0.30〜
2.0%、Mo:0.05〜0.50%のうちの1種又
は2種以上を含み、また更にS:0.2%以下、Pb:
0.4%以下、Te:0.1%以下、Bi:0.1%以
下及びCa:0.01%以下のうちの1種又は2種以上
を含み、残部がFe及び不可避的不純物からなり、熱間
鍛造後の冷却によってフェライト+ベーナイトの混合組
織又はベーナイト一相組織を有することを特徴とする熱
間鍛造用非調質鋼。[Claims] 1% by weight (the same applies hereinafter), C: 0.20 to 0.50
%, Si: 0.10-1.00%, Mn: 1.0-2.
0%, V: 0.05-0.30%, Nb: 0.01-0
.. 06%, solAl: 0.01-0.06% and N:
For hot forging, characterized by containing 0.01 to 0.03%, the remainder consisting of Fe and unavoidable impurities, and having a mixed structure of ferrite + bainite or a single phase structure of bainite by cooling after hot forging. Non-tempered steel. 2C: 0.20-0.50%, Si: 0.10-1.
00%, Mn: 1.0-2.0%, V: 0.05-0.
30%, Nb: 0.01-0.06%, solAl: 0
.. 01 to 0.06% and N: 0.01 to 0.03%, further Cr: 0.30 to 1.0%, Ni: 0.30 to
2.0%, Mo: 0.05 to 0.50%, the remainder consists of Fe and unavoidable impurities, and a mixed structure of ferrite + bainite is formed by cooling after hot forging. Or a non-temperature steel for hot forging characterized by having a bainitic single phase structure. 3C: 0.20-0.50%, Si: 0.10-1.
00%, Mn: 1.0-2.0%, V: 0.05-0.
30%, Nb: 0.01-0.06%, solAl: 0
.. 01 to 0.06% and N: 0.01 to 0.03%, further S: 0.2% or less, Pb: 0.40% or less, T
e: 0.1% or less, Bi: 0.1% or less, and Ca: 0.
01% or less, and the remainder is F.
1. A non-temperature steel for hot forging, characterized in that it is composed of E and unavoidable impurities and has a mixed structure of ferrite + bainite or a single phase structure of bainite by cooling after hot forging. 4C: 0.20-0.50%, Si: 0.10-1.
00%, Mn: 1.0-2.0%, V: 0.05-0.
30%, Nb: 0.01-0.06%, solAl: 0
.. 01 to 0.06% and N: 0.01 to 0.03%, further Cr: 0.30 to 1.0%, Ni: 0.30 to
2.0%, Mo: one or more of 0.05 to 0.50%, S: 0.2% or less, Pb:
0.4% or less, Te: 0.1% or less, Bi: 0.1% or less, and Ca: 0.01% or less, and the remainder consists of Fe and inevitable impurities. A non-temperature steel for hot forging, characterized in that it has a mixed structure of ferrite + bainite or a single phase structure of bainite due to cooling after hot forging.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12167985A JPS61279656A (en) | 1985-06-05 | 1985-06-05 | Non-heattreated steel for hot forging |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12167985A JPS61279656A (en) | 1985-06-05 | 1985-06-05 | Non-heattreated steel for hot forging |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS61279656A true JPS61279656A (en) | 1986-12-10 |
Family
ID=14817193
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12167985A Pending JPS61279656A (en) | 1985-06-05 | 1985-06-05 | Non-heattreated steel for hot forging |
Country Status (1)
Country | Link |
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JP (1) | JPS61279656A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01129953A (en) * | 1987-11-16 | 1989-05-23 | Kobe Steel Ltd | High strength non-heat treated steel and its manufacture |
JPH03211227A (en) * | 1990-01-17 | 1991-09-17 | Nippon Steel Corp | Production of hot forged non-heat-treated steel having high strength and high toughness |
JPH04176842A (en) * | 1990-07-27 | 1992-06-24 | Aichi Steel Works Ltd | Non-thermal refining steel for hot forging |
JPH059652A (en) * | 1991-07-04 | 1993-01-19 | Sanyo Special Steel Co Ltd | Non-heat-treated steel for forging having excellent machinability |
EP0632138A1 (en) * | 1993-06-30 | 1995-01-04 | Samsung Heavy Industry Co., Ltd | High toughness and high strength untempered steel and processing method thereof |
KR100368552B1 (en) * | 1998-09-16 | 2003-05-09 | 주식회사 포스코 | Hot forged steel with low material deviation and its manufacturing method |
KR100415653B1 (en) * | 1996-08-28 | 2004-04-08 | 주식회사 포스코 | Method for manufacturing micro-alloyed steel sheet having high strength and high ductility for hot-forging |
DE102007057421A1 (en) * | 2007-08-27 | 2009-03-05 | Georgsmarienhütte Gmbh | Steel for the production of massively formed machine components |
JP2010270390A (en) * | 2009-04-23 | 2010-12-02 | Kobe Steel Ltd | Steel forging and crankshaft |
US8617462B2 (en) * | 2005-03-24 | 2013-12-31 | Nippon Steel & Sumitomo Metal Corporation | Steel for oil well pipe excellent in sulfide stress cracking resistance |
-
1985
- 1985-06-05 JP JP12167985A patent/JPS61279656A/en active Pending
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01129953A (en) * | 1987-11-16 | 1989-05-23 | Kobe Steel Ltd | High strength non-heat treated steel and its manufacture |
JPH03211227A (en) * | 1990-01-17 | 1991-09-17 | Nippon Steel Corp | Production of hot forged non-heat-treated steel having high strength and high toughness |
JPH04176842A (en) * | 1990-07-27 | 1992-06-24 | Aichi Steel Works Ltd | Non-thermal refining steel for hot forging |
JPH059652A (en) * | 1991-07-04 | 1993-01-19 | Sanyo Special Steel Co Ltd | Non-heat-treated steel for forging having excellent machinability |
EP0632138A1 (en) * | 1993-06-30 | 1995-01-04 | Samsung Heavy Industry Co., Ltd | High toughness and high strength untempered steel and processing method thereof |
KR100415653B1 (en) * | 1996-08-28 | 2004-04-08 | 주식회사 포스코 | Method for manufacturing micro-alloyed steel sheet having high strength and high ductility for hot-forging |
KR100368552B1 (en) * | 1998-09-16 | 2003-05-09 | 주식회사 포스코 | Hot forged steel with low material deviation and its manufacturing method |
US8617462B2 (en) * | 2005-03-24 | 2013-12-31 | Nippon Steel & Sumitomo Metal Corporation | Steel for oil well pipe excellent in sulfide stress cracking resistance |
DE102007057421A1 (en) * | 2007-08-27 | 2009-03-05 | Georgsmarienhütte Gmbh | Steel for the production of massively formed machine components |
JP2010270390A (en) * | 2009-04-23 | 2010-12-02 | Kobe Steel Ltd | Steel forging and crankshaft |
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