JPS6121232B2 - - Google Patents
Info
- Publication number
- JPS6121232B2 JPS6121232B2 JP1196578A JP1196578A JPS6121232B2 JP S6121232 B2 JPS6121232 B2 JP S6121232B2 JP 1196578 A JP1196578 A JP 1196578A JP 1196578 A JP1196578 A JP 1196578A JP S6121232 B2 JPS6121232 B2 JP S6121232B2
- Authority
- JP
- Japan
- Prior art keywords
- dicyano
- chloro
- formula
- pyrazine
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 7
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 230000002140 halogenating effect Effects 0.000 claims description 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- MQZGOHPDJLBDAP-UHFFFAOYSA-N 6-oxo-1h-pyrazine-2,3-dicarbonitrile Chemical class OC1=CN=C(C#N)C(C#N)=N1 MQZGOHPDJLBDAP-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 description 30
- 241000196324 Embryophyta Species 0.000 description 20
- -1 methoxy, ethoxy Chemical group 0.000 description 19
- 239000002689 soil Substances 0.000 description 15
- 238000012360 testing method Methods 0.000 description 13
- 240000007594 Oryza sativa Species 0.000 description 12
- 235000007164 Oryza sativa Nutrition 0.000 description 12
- 235000009566 rice Nutrition 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 230000002363 herbicidal effect Effects 0.000 description 11
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 241000234646 Cyperaceae Species 0.000 description 8
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 8
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000004009 herbicide Substances 0.000 description 7
- 125000001424 substituent group Chemical group 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 241000209504 Poaceae Species 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 241000219321 Caryophyllaceae Species 0.000 description 4
- 241000219050 Polygonaceae Species 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 238000005658 halogenation reaction Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XMUYZFOAVMMUNE-UHFFFAOYSA-N 5-chloropyrazine-2,3-dicarbonitrile Chemical class ClC1=CN=C(C#N)C(C#N)=N1 XMUYZFOAVMMUNE-UHFFFAOYSA-N 0.000 description 3
- 241000219317 Amaranthaceae Species 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 241000219991 Lythraceae Species 0.000 description 3
- 241000721692 Lythrum Species 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- DFRQYBQBGUHFHV-UHFFFAOYSA-N 5-chloro-6-phenylpyrazine-2,3-dicarbonitrile Chemical compound ClC1=NC(C#N)=C(C#N)N=C1C1=CC=CC=C1 DFRQYBQBGUHFHV-UHFFFAOYSA-N 0.000 description 2
- 244000296825 Amygdalus nana Species 0.000 description 2
- 235000003840 Amygdalus nana Nutrition 0.000 description 2
- 241000208838 Asteraceae Species 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 241000207782 Convolvulaceae Species 0.000 description 2
- 244000207740 Lemna minor Species 0.000 description 2
- 235000006439 Lemna minor Nutrition 0.000 description 2
- 240000007019 Oxalis corniculata Species 0.000 description 2
- 235000016499 Oxalis corniculata Nutrition 0.000 description 2
- 235000001855 Portulaca oleracea Nutrition 0.000 description 2
- 235000011432 Prunus Nutrition 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 230000035784 germination Effects 0.000 description 2
- 230000000887 hydrating effect Effects 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 235000014774 prunus Nutrition 0.000 description 2
- 150000003216 pyrazines Chemical class 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- ZYVYEJXMYBUCMN-UHFFFAOYSA-N 1-methoxy-2-methylpropane Chemical compound COCC(C)C ZYVYEJXMYBUCMN-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- QPJGXXOJHGAEMY-UHFFFAOYSA-N 5-anilino-6-chloropyrazine-2,3-dicarbonitrile Chemical compound ClC1=NC(C#N)=C(C#N)N=C1NC1=CC=CC=C1 QPJGXXOJHGAEMY-UHFFFAOYSA-N 0.000 description 1
- FEPGBNKABMIKPA-UHFFFAOYSA-N 5-benzyl-6-chloropyrazine-2,3-dicarbonitrile Chemical compound ClC1=NC(C#N)=C(C#N)N=C1CC1=CC=CC=C1 FEPGBNKABMIKPA-UHFFFAOYSA-N 0.000 description 1
- MDXNKKBBAVUXSS-UHFFFAOYSA-N 5-butyl-6-chloropyrazine-2,3-dicarbonitrile Chemical compound CCCCC1=NC(C#N)=C(C#N)N=C1Cl MDXNKKBBAVUXSS-UHFFFAOYSA-N 0.000 description 1
- ZUHAKWKXZINFKV-UHFFFAOYSA-N 5-chloro-6-(2-methylpropyl)pyrazine-2,3-dicarbonitrile Chemical compound CC(C)CC1=NC(C#N)=C(C#N)N=C1Cl ZUHAKWKXZINFKV-UHFFFAOYSA-N 0.000 description 1
- MLQLFFHMFPUBPQ-UHFFFAOYSA-N 5-chloro-6-(4-methylphenyl)pyrazine-2,3-dicarbonitrile Chemical compound C1=CC(C)=CC=C1C1=NC(C#N)=C(C#N)N=C1Cl MLQLFFHMFPUBPQ-UHFFFAOYSA-N 0.000 description 1
- QZDUYDPDUKPHAY-UHFFFAOYSA-N 5-chloro-6-ethylpyrazine-2,3-dicarbonitrile Chemical compound CCC1=NC(C#N)=C(C#N)N=C1Cl QZDUYDPDUKPHAY-UHFFFAOYSA-N 0.000 description 1
- FMSRCHYXAOIQFU-UHFFFAOYSA-N 5-chloro-6-methylpyrazine-2,3-dicarbonitrile Chemical compound CC1=NC(C#N)=C(C#N)N=C1Cl FMSRCHYXAOIQFU-UHFFFAOYSA-N 0.000 description 1
- SKKHRWAXTYDQHV-UHFFFAOYSA-N 5-chloro-6-piperidin-1-ylpyrazine-2,3-dicarbonitrile Chemical compound ClC1=NC(C#N)=C(C#N)N=C1N1CCCCC1 SKKHRWAXTYDQHV-UHFFFAOYSA-N 0.000 description 1
- IRNHUICHRWGEBD-UHFFFAOYSA-N 5-chloro-6-propylpyrazine-2,3-dicarbonitrile Chemical compound CCCC1=NC(C#N)=C(C#N)N=C1Cl IRNHUICHRWGEBD-UHFFFAOYSA-N 0.000 description 1
- XJYQVAVMBFLVEU-UHFFFAOYSA-N 6-oxo-5-phenyl-1h-pyrazine-2,3-dicarbonitrile Chemical compound OC1=NC(C#N)=C(C#N)N=C1C1=CC=CC=C1 XJYQVAVMBFLVEU-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000134901 Amanitaceae Species 0.000 description 1
- 241000209524 Araceae Species 0.000 description 1
- 241000269837 Artemisia dubia Species 0.000 description 1
- 235000003261 Artemisia vulgaris Nutrition 0.000 description 1
- FIBMQEAFALNEAV-UHFFFAOYSA-N BrC=1N=C(C(=NC=1)C#N)C#N Chemical compound BrC=1N=C(C(=NC=1)C#N)C#N FIBMQEAFALNEAV-UHFFFAOYSA-N 0.000 description 1
- 240000008100 Brassica rapa Species 0.000 description 1
- 235000011292 Brassica rapa Nutrition 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- 241000219193 Brassicaceae Species 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- CSBWXHXHOYLKHZ-UHFFFAOYSA-N C1=CC(OC)=CC=C1NC1=NC(C#N)=C(C#N)N=C1Cl Chemical compound C1=CC(OC)=CC=C1NC1=NC(C#N)=C(C#N)N=C1Cl CSBWXHXHOYLKHZ-UHFFFAOYSA-N 0.000 description 1
- JGLMVXWAHNTPRF-CMDGGOBGSA-N CCN1N=C(C)C=C1C(=O)NC1=NC2=CC(=CC(OC)=C2N1C\C=C\CN1C(NC(=O)C2=CC(C)=NN2CC)=NC2=CC(=CC(OCCCN3CCOCC3)=C12)C(N)=O)C(N)=O Chemical compound CCN1N=C(C)C=C1C(=O)NC1=NC2=CC(=CC(OC)=C2N1C\C=C\CN1C(NC(=O)C2=CC(C)=NN2CC)=NC2=CC(=CC(OCCCN3CCOCC3)=C12)C(N)=O)C(N)=O JGLMVXWAHNTPRF-CMDGGOBGSA-N 0.000 description 1
- 235000011305 Capsella bursa pastoris Nutrition 0.000 description 1
- 240000008867 Capsella bursa-pastoris Species 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 240000005250 Chrysanthemum indicum Species 0.000 description 1
- 241000207892 Convolvulus Species 0.000 description 1
- 235000001602 Digitaria X umfolozi Nutrition 0.000 description 1
- 235000017898 Digitaria ciliaris Nutrition 0.000 description 1
- 235000005476 Digitaria cruciata Nutrition 0.000 description 1
- 235000006830 Digitaria didactyla Nutrition 0.000 description 1
- 235000005804 Digitaria eriantha ssp. eriantha Nutrition 0.000 description 1
- 235000010823 Digitaria sanguinalis Nutrition 0.000 description 1
- 244000025670 Eleusine indica Species 0.000 description 1
- 235000014716 Eleusine indica Nutrition 0.000 description 1
- 241000221017 Euphorbiaceae Species 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 241000254158 Lampyridae Species 0.000 description 1
- 241000209499 Lemna Species 0.000 description 1
- 244000133810 Montia fontana Species 0.000 description 1
- 235000008319 Montia fontana Nutrition 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 244000292697 Polygonum aviculare Species 0.000 description 1
- 235000006386 Polygonum aviculare Nutrition 0.000 description 1
- 241000206609 Porphyra Species 0.000 description 1
- 235000005733 Raphanus sativus var niger Nutrition 0.000 description 1
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 1
- 240000001970 Raphanus sativus var. sativus Species 0.000 description 1
- 241001107098 Rubiaceae Species 0.000 description 1
- 241000124033 Salix Species 0.000 description 1
- 241000208292 Solanaceae Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 244000269888 azena Species 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000009036 growth inhibition Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000003898 horticulture Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000006178 methyl benzyl group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 230000000144 pharmacologic effect Effects 0.000 description 1
- UXCDUFKZSUBXGM-UHFFFAOYSA-N phosphoric tribromide Chemical compound BrP(Br)(Br)=O UXCDUFKZSUBXGM-UHFFFAOYSA-N 0.000 description 1
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- OTVZGAXESBAAQQ-UHFFFAOYSA-N pyrazine-2,3-dicarbonitrile Chemical class N#CC1=NC=CN=C1C#N OTVZGAXESBAAQQ-UHFFFAOYSA-N 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000003419 tautomerization reaction Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1196578A JPS54106480A (en) | 1978-02-07 | 1978-02-07 | Novel 2,3-dicyano-5-halopyrazine derivative and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1196578A JPS54106480A (en) | 1978-02-07 | 1978-02-07 | Novel 2,3-dicyano-5-halopyrazine derivative and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54106480A JPS54106480A (en) | 1979-08-21 |
| JPS6121232B2 true JPS6121232B2 (ru) | 1986-05-26 |
Family
ID=11792322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1196578A Granted JPS54106480A (en) | 1978-02-07 | 1978-02-07 | Novel 2,3-dicyano-5-halopyrazine derivative and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS54106480A (ru) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6413446U (ru) * | 1987-07-13 | 1989-01-24 | ||
| JPH0198850A (ja) * | 1988-03-14 | 1989-04-17 | Toto Ltd | レンジ用フード |
| JPH09112986A (ja) * | 1995-10-19 | 1997-05-02 | Haiki:Kk | 排気用昇降フード |
-
1978
- 1978-02-07 JP JP1196578A patent/JPS54106480A/ja active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6413446U (ru) * | 1987-07-13 | 1989-01-24 | ||
| JPH0198850A (ja) * | 1988-03-14 | 1989-04-17 | Toto Ltd | レンジ用フード |
| JPH09112986A (ja) * | 1995-10-19 | 1997-05-02 | Haiki:Kk | 排気用昇降フード |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54106480A (en) | 1979-08-21 |
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