JPS61171583A - 石油系燃焼灰の処理方法 - Google Patents
石油系燃焼灰の処理方法Info
- Publication number
- JPS61171583A JPS61171583A JP60009154A JP915485A JPS61171583A JP S61171583 A JPS61171583 A JP S61171583A JP 60009154 A JP60009154 A JP 60009154A JP 915485 A JP915485 A JP 915485A JP S61171583 A JPS61171583 A JP S61171583A
- Authority
- JP
- Japan
- Prior art keywords
- gypsum
- ammonia
- slurry
- metal
- sludge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003208 petroleum Substances 0.000 title claims description 10
- 238000011282 treatment Methods 0.000 title claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 154
- 239000010440 gypsum Substances 0.000 claims abstract description 79
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 79
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 71
- 239000010802 sludge Substances 0.000 claims abstract description 71
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000002002 slurry Substances 0.000 claims abstract description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000007788 liquid Substances 0.000 claims abstract description 34
- 229910052742 iron Inorganic materials 0.000 claims abstract description 30
- 150000003682 vanadium compounds Chemical class 0.000 claims abstract description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 claims abstract description 23
- 239000002184 metal Substances 0.000 claims abstract description 23
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000007800 oxidant agent Substances 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 106
- 229910052759 nickel Inorganic materials 0.000 claims description 52
- 238000002485 combustion reaction Methods 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 24
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 23
- 239000000920 calcium hydroxide Substances 0.000 claims description 23
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 23
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 claims description 12
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 12
- 150000004692 metal hydroxides Chemical class 0.000 claims description 12
- 239000000292 calcium oxide Substances 0.000 claims description 7
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 7
- 239000000428 dust Substances 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- 239000000446 fuel Substances 0.000 claims description 4
- 150000004679 hydroxides Chemical class 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229910001385 heavy metal Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 12
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract description 10
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract description 10
- 235000011130 ammonium sulphate Nutrition 0.000 abstract description 10
- 239000000706 filtrate Substances 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000012716 precipitator Substances 0.000 abstract 1
- 238000005273 aeration Methods 0.000 description 26
- 235000011116 calcium hydroxide Nutrition 0.000 description 22
- 239000007789 gas Substances 0.000 description 14
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 13
- 229910052720 vanadium Inorganic materials 0.000 description 12
- 230000003647 oxidation Effects 0.000 description 10
- 238000007254 oxidation reaction Methods 0.000 description 10
- 238000000926 separation method Methods 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000004090 dissolution Methods 0.000 description 6
- 238000004062 sedimentation Methods 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 5
- 238000001914 filtration Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 238000010979 pH adjustment Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052925 anhydrite Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000012717 electrostatic precipitator Substances 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000008235 industrial water Substances 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 150000002816 nickel compounds Chemical class 0.000 description 2
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 229910003206 NH4VO3 Inorganic materials 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 210000000941 bile Anatomy 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- 239000011334 petroleum pitch coke Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Processing Of Solid Wastes (AREA)
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60009154A JPS61171583A (ja) | 1985-01-23 | 1985-01-23 | 石油系燃焼灰の処理方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60009154A JPS61171583A (ja) | 1985-01-23 | 1985-01-23 | 石油系燃焼灰の処理方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61171583A true JPS61171583A (ja) | 1986-08-02 |
JPH0513718B2 JPH0513718B2 (enrdf_load_stackoverflow) | 1993-02-23 |
Family
ID=11712696
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60009154A Granted JPS61171583A (ja) | 1985-01-23 | 1985-01-23 | 石油系燃焼灰の処理方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61171583A (enrdf_load_stackoverflow) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0852220A1 (en) * | 1996-12-25 | 1998-07-08 | Kashima-Kita Electric Power Corporation | A wet-processing method for combustion ashes of petroleum fuels, containing ammonium sulfate and a method of utilizing ammonia components recovered by the wet-processing method |
JP2002241857A (ja) * | 2001-02-15 | 2002-08-28 | Kashima Kita Electric Power Corp | ニッケル粉末の製造方法 |
WO2003072275A1 (fr) * | 2002-02-27 | 2003-09-04 | Kashima-Kita, Electric Power Corporation | Procede par voie humide de traitement de cendres de combustion provenant de petrole |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002113442A (ja) * | 2000-10-10 | 2002-04-16 | Kashima Kita Electric Power Corp | 石油系燃焼灰の湿式処理方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54127867A (en) * | 1978-03-27 | 1979-10-04 | Fumio Watanabe | Method of treating e*p dust |
-
1985
- 1985-01-23 JP JP60009154A patent/JPS61171583A/ja active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54127867A (en) * | 1978-03-27 | 1979-10-04 | Fumio Watanabe | Method of treating e*p dust |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0852220A1 (en) * | 1996-12-25 | 1998-07-08 | Kashima-Kita Electric Power Corporation | A wet-processing method for combustion ashes of petroleum fuels, containing ammonium sulfate and a method of utilizing ammonia components recovered by the wet-processing method |
JP2002241857A (ja) * | 2001-02-15 | 2002-08-28 | Kashima Kita Electric Power Corp | ニッケル粉末の製造方法 |
WO2003072275A1 (fr) * | 2002-02-27 | 2003-09-04 | Kashima-Kita, Electric Power Corporation | Procede par voie humide de traitement de cendres de combustion provenant de petrole |
US7052660B2 (en) * | 2002-02-27 | 2006-05-30 | Kashima-Kita, Electric Power Corporation | Wet-processing method for combustion ashes of petroleum fuels |
Also Published As
Publication number | Publication date |
---|---|
JPH0513718B2 (enrdf_load_stackoverflow) | 1993-02-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EXPY | Cancellation because of completion of term |