JPS60229913A - ポリアルケニルエ−テルブロツク共重合体 - Google Patents
ポリアルケニルエ−テルブロツク共重合体Info
- Publication number
- JPS60229913A JPS60229913A JP8527984A JP8527984A JPS60229913A JP S60229913 A JPS60229913 A JP S60229913A JP 8527984 A JP8527984 A JP 8527984A JP 8527984 A JP8527984 A JP 8527984A JP S60229913 A JPS60229913 A JP S60229913A
- Authority
- JP
- Japan
- Prior art keywords
- polymerization
- ether
- molecular weight
- chains
- initiator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 229920001400 block copolymer Polymers 0.000 title description 9
- 229920001577 copolymer Polymers 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 18
- 239000003999 initiator Substances 0.000 abstract description 16
- -1 alkenyl ether Chemical compound 0.000 abstract description 9
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 229920000359 diblock copolymer Polymers 0.000 abstract description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 19
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 7
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 239000011630 iodine Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 238000010538 cationic polymerization reaction Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920000428 triblock copolymer Polymers 0.000 description 2
- QHMVQKOXILNZQR-ONEGZZNKSA-N (e)-1-methoxyprop-1-ene Chemical compound CO\C=C\C QHMVQKOXILNZQR-ONEGZZNKSA-N 0.000 description 1
- NYRDXHJSQIWIBZ-UHFFFAOYSA-N 1-(1-iodoethoxy)butane Chemical compound CCCCOC(C)I NYRDXHJSQIWIBZ-UHFFFAOYSA-N 0.000 description 1
- SWZSKZZXXULJHU-UHFFFAOYSA-N 1-ethenoxyheptane Chemical compound CCCCCCCOC=C SWZSKZZXXULJHU-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000002785 anti-thrombosis Effects 0.000 description 1
- 239000003146 anticoagulant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 238000010552 living cationic polymerization reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- LPNYRYFBWFDTMA-UHFFFAOYSA-N potassium tert-butoxide Chemical compound [K+].CC(C)(C)[O-] LPNYRYFBWFDTMA-UHFFFAOYSA-N 0.000 description 1
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 description 1
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920006250 telechelic polymer Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8527984A JPS60229913A (ja) | 1984-04-27 | 1984-04-27 | ポリアルケニルエ−テルブロツク共重合体 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8527984A JPS60229913A (ja) | 1984-04-27 | 1984-04-27 | ポリアルケニルエ−テルブロツク共重合体 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60229913A true JPS60229913A (ja) | 1985-11-15 |
| JPH058207B2 JPH058207B2 (enExample) | 1993-02-01 |
Family
ID=13854121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8527984A Granted JPS60229913A (ja) | 1984-04-27 | 1984-04-27 | ポリアルケニルエ−テルブロツク共重合体 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60229913A (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006131805A (ja) * | 2004-11-08 | 2006-05-25 | Maruzen Petrochem Co Ltd | 脂環式ビニルエーテル共重合体 |
| JP2008138177A (ja) * | 2006-11-10 | 2008-06-19 | Univ Of Fukui | Ａｂａ型トリブロック共重合体 |
| JP2009167283A (ja) * | 2008-01-16 | 2009-07-30 | Kansai Paint Co Ltd | 感熱応答性ａｂａトリブロックポリマーおよびそれを含有する水性塗料組成物。 |
| JP2009167282A (ja) * | 2008-01-16 | 2009-07-30 | Kansai Paint Co Ltd | 感熱応答性ａｂａトリブロックポリマーおよびそれを含有する水性塗料組成物。 |
| JP2010189654A (ja) * | 2010-04-21 | 2010-09-02 | Maruzen Petrochem Co Ltd | 脂環式ビニルエーテル共重合体 |
-
1984
- 1984-04-27 JP JP8527984A patent/JPS60229913A/ja active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006131805A (ja) * | 2004-11-08 | 2006-05-25 | Maruzen Petrochem Co Ltd | 脂環式ビニルエーテル共重合体 |
| JP2008138177A (ja) * | 2006-11-10 | 2008-06-19 | Univ Of Fukui | Ａｂａ型トリブロック共重合体 |
| JP2009167283A (ja) * | 2008-01-16 | 2009-07-30 | Kansai Paint Co Ltd | 感熱応答性ａｂａトリブロックポリマーおよびそれを含有する水性塗料組成物。 |
| JP2009167282A (ja) * | 2008-01-16 | 2009-07-30 | Kansai Paint Co Ltd | 感熱応答性ａｂａトリブロックポリマーおよびそれを含有する水性塗料組成物。 |
| JP2010189654A (ja) * | 2010-04-21 | 2010-09-02 | Maruzen Petrochem Co Ltd | 脂環式ビニルエーテル共重合体 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH058207B2 (enExample) | 1993-02-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |