JPS6020321B2 - 最少の溶剤を使用して二酸化硫黄，蟻酸ナトリウム及び炭酸ナトリウムから亜二チオン酸ナトリウムを製造する方法 - Google Patents
最少の溶剤を使用して二酸化硫黄，蟻酸ナトリウム及び炭酸ナトリウムから亜二チオン酸ナトリウムを製造する方法Info
- Publication number
- JPS6020321B2 JPS6020321B2 JP52075360A JP7536077A JPS6020321B2 JP S6020321 B2 JPS6020321 B2 JP S6020321B2 JP 52075360 A JP52075360 A JP 52075360A JP 7536077 A JP7536077 A JP 7536077A JP S6020321 B2 JPS6020321 B2 JP S6020321B2
- Authority
- JP
- Japan
- Prior art keywords
- sodium
- formate
- methanol
- sulfur dioxide
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 title claims description 100
- 229910000029 sodium carbonate Inorganic materials 0.000 title claims description 58
- 238000000034 method Methods 0.000 title claims description 46
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 title claims description 37
- 235000019254 sodium formate Nutrition 0.000 title claims description 37
- 239000004280 Sodium formate Substances 0.000 title claims description 33
- 230000008569 process Effects 0.000 title claims description 23
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 title claims description 18
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 title description 68
- 239000002904 solvent Substances 0.000 title description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 164
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 238000006243 chemical reaction Methods 0.000 claims description 32
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 16
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 239000002002 slurry Substances 0.000 claims description 7
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 5
- 229940001584 sodium metabisulfite Drugs 0.000 claims description 5
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 5
- 230000035484 reaction time Effects 0.000 claims description 4
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 3
- HWEFNRWYNIBQFD-UHFFFAOYSA-N methanol;sulfur dioxide Chemical compound OC.O=S=O HWEFNRWYNIBQFD-UHFFFAOYSA-N 0.000 claims 7
- 150000003388 sodium compounds Chemical class 0.000 claims 2
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 80
- 235000017550 sodium carbonate Nutrition 0.000 description 43
- 239000000243 solution Substances 0.000 description 33
- 235000011121 sodium hydroxide Nutrition 0.000 description 27
- 239000000428 dust Substances 0.000 description 22
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical group OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 239000000047 product Substances 0.000 description 14
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical class [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 13
- 239000011734 sodium Substances 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 239000003513 alkali Substances 0.000 description 9
- -1 alkali metal salts Chemical class 0.000 description 9
- 235000019253 formic acid Nutrition 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 239000003518 caustics Substances 0.000 description 3
- 229940075933 dithionate Drugs 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000012527 feed solution Substances 0.000 description 2
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 241000282836 Camelus dromedarius Species 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 206010062717 Increased upper airway secretion Diseases 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical class [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
- 208000026435 phlegm Diseases 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- PENRVBJTRIYHOA-UHFFFAOYSA-L zinc dithionite Chemical compound [Zn+2].[O-]S(=O)S([O-])=O PENRVBJTRIYHOA-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/64—Thiosulfates; Dithionites; Polythionates
- C01B17/66—Dithionites or hydrosulfites (S2O42-)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69946276A | 1976-06-24 | 1976-06-24 | |
| US80652777A | 1977-06-14 | 1977-06-14 | |
| US806527 | 1977-06-14 | ||
| US699462 | 1985-02-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5316388A JPS5316388A (en) | 1978-02-15 |
| JPS6020321B2 true JPS6020321B2 (ja) | 1985-05-21 |
Family
ID=27106430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52075360A Expired JPS6020321B2 (ja) | 1976-06-24 | 1977-06-24 | 最少の溶剤を使用して二酸化硫黄，蟻酸ナトリウム及び炭酸ナトリウムから亜二チオン酸ナトリウムを製造する方法 |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS6020321B2 (enrdf_load_stackoverflow) |
| CA (1) | CA1103888A (enrdf_load_stackoverflow) |
| DE (1) | DE2728316B2 (enrdf_load_stackoverflow) |
| FR (1) | FR2355775A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1584626A (enrdf_load_stackoverflow) |
| IT (1) | IT1143585B (enrdf_load_stackoverflow) |
| MX (1) | MX147264A (enrdf_load_stackoverflow) |
| NO (1) | NO149884C (enrdf_load_stackoverflow) |
| SE (1) | SE418490B (enrdf_load_stackoverflow) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3411875A (en) * | 1964-04-08 | 1968-11-19 | Mitsubishi Edogawa Kagaku Kk | Process for the production of anhydrous hydrosulfites |
| DE1592013B2 (de) * | 1966-05-16 | 1972-08-24 | Mitsubishi Edogawa Kagaku K K , Tokio | Verfahren zur herstellung eines wasserfreien natrium-hyposulfits |
| JPS4814316B1 (enrdf_load_stackoverflow) * | 1969-01-10 | 1973-05-07 | ||
| US3887695A (en) * | 1970-02-05 | 1975-06-03 | Virginia Chemicals Inc | Production of sodium hydrosulfite from formates |
| GB1461785A (en) * | 1973-03-30 | 1977-01-19 | Boc Ltd | Alkali metal dithionite manufacture |
-
1977
- 1977-06-17 CA CA280,843A patent/CA1103888A/en not_active Expired
- 1977-06-20 NO NO77772165A patent/NO149884C/no unknown
- 1977-06-21 GB GB25816/77A patent/GB1584626A/en not_active Expired
- 1977-06-22 SE SE7707235A patent/SE418490B/xx not_active IP Right Cessation
- 1977-06-23 FR FR7719337A patent/FR2355775A1/fr active Granted
- 1977-06-23 DE DE2728316A patent/DE2728316B2/de active Granted
- 1977-06-23 IT IT49962/77A patent/IT1143585B/it active
- 1977-06-24 MX MX169610A patent/MX147264A/es unknown
- 1977-06-24 JP JP52075360A patent/JPS6020321B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2728316A1 (de) | 1978-01-05 |
| DE2728316C3 (enrdf_load_stackoverflow) | 1990-08-23 |
| FR2355775B1 (enrdf_load_stackoverflow) | 1984-04-13 |
| GB1584626A (en) | 1981-02-18 |
| IT1143585B (it) | 1986-10-22 |
| NO772165L (no) | 1977-12-28 |
| DE2728316B2 (de) | 1980-10-23 |
| CA1103888A (en) | 1981-06-30 |
| SE7707235L (sv) | 1977-12-25 |
| FR2355775A1 (fr) | 1978-01-20 |
| JPS5316388A (en) | 1978-02-15 |
| MX147264A (es) | 1982-10-29 |
| NO149884B (no) | 1984-04-02 |
| SE418490B (sv) | 1981-06-09 |
| NO149884C (no) | 1984-07-11 |
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