JPS60145360A - Amorphous magnetic alloy and its manufacture - Google Patents
Amorphous magnetic alloy and its manufactureInfo
- Publication number
- JPS60145360A JPS60145360A JP59003205A JP320584A JPS60145360A JP S60145360 A JPS60145360 A JP S60145360A JP 59003205 A JP59003205 A JP 59003205A JP 320584 A JP320584 A JP 320584A JP S60145360 A JPS60145360 A JP S60145360A
- Authority
- JP
- Japan
- Prior art keywords
- amorphous
- iron loss
- amorphous magnetic
- magnetic
- magnetic alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Soft Magnetic Materials (AREA)
Abstract
Description
【発明の詳細な説明】 〔技術分野〕 この発明は高周波領域(とくに10 KHz以上)。[Detailed description of the invention] 〔Technical field〕 This invention applies to high frequency areas (especially 10 KHz or higher).
低動作磁速密度(とくに3 K Gauss以下)で低
鉄損の磁心材料として使用可能な非晶質磁性合金および
その製造方法に関するものである。The present invention relates to an amorphous magnetic alloy that can be used as a magnetic core material with low operating magnetic velocity density (especially 3 K Gauss or less) and low core loss, and a method for manufacturing the same.
現在、高周波用磁心材料としては、従来のソフトフェラ
イトに代わるものとしてアモルファス磁心の研究が進め
られている。アモルファス磁心ハ、飽和磁束密度が高く
、高動作磁束密度ではフェライトに比べて有利となるこ
とが知られている。しかしながら、使用周波数が高くな
ると、鉄損は周波数および動作磁束密度の二乗に比例し
て急激に増大するため、比較的低い動作磁束密度での使
用に制限され、アモルファスの高い飽和磁束重度は必ラ
スしも従来のフェライトに比べて有利とはならなかった
。Currently, research into amorphous magnetic cores as a magnetic core material for high-frequency applications is underway as an alternative to conventional soft ferrite. It is known that amorphous magnetic cores have a high saturation magnetic flux density and are advantageous compared to ferrite at high operating magnetic flux densities. However, as the operating frequency increases, iron loss increases rapidly in proportion to the frequency and the square of the operating magnetic flux density, so use is limited to relatively low operating magnetic flux densities, and the high saturation flux severity of amorphous is unavoidable. However, it was not advantageous compared to conventional ferrite.
一方、アモルファスで高周波鉄損を低減させる手段とし
ては、特開昭57−94554号公報に開示されている
熱処理によって微細結晶相を析出させることや特開昭5
7−169068号公報に開示されるような非磁性令属
添加による磁歪の減少が知られている。しかしながら、
これらの方法は必らずしも低磁束密度では有利とならな
かった。On the other hand, as a means for reducing high frequency iron loss in amorphous materials, there is a method to precipitate a fine crystalline phase by heat treatment as disclosed in JP-A No. 57-94554, and a method disclosed in JP-A No. 57-94554.
It is known that magnetostriction can be reduced by adding a non-magnetic metal as disclosed in Japanese Patent No. 7-169068. however,
These methods were not necessarily advantageous at low magnetic flux densities.
この発明は、高周波領埴、低動作磁束密度で低鉄損の非
晶質磁性合金およびその製造方法を提供することを目的
とする。SUMMARY OF THE INVENTION An object of the present invention is to provide an amorphous magnetic alloy with high frequency range, low operating magnetic flux density, and low iron loss, and a method for manufacturing the same.
この発明の非晶質磁性合金は、式:
%式%
(式中、w 、 x 、 y 、 zは各元素の原子係
であ仄Wが60〜85.Xが4〜10.yが10〜20
゜2が10以下、y+zが25以下である)の組成を有
する非晶質磁性薄帯にスクラッチ加工を施したことを特
徴とするものである。The amorphous magnetic alloy of this invention has the formula: % formula % (where w, x, y, z are the atomic ratios of each element, where W is 60 to 85, X is 4 to 10, y is 10 ~20
The present invention is characterized in that an amorphous magnetic ribbon having a composition in which ゜2 is 10 or less and y+z is 25 or less is subjected to scratch processing.
また、この発明の非晶質磁性合金の製造方法は、前記組
成を有する非晶質磁性薄帯にスクラッチ加工を施した後
、結晶化温度以下でかつキュリ一温度以上で熱処理する
ものである。Further, in the method for producing an amorphous magnetic alloy of the present invention, an amorphous magnetic ribbon having the above composition is subjected to scratch processing, and then heat-treated at a temperature below the crystallization temperature and above the Curie temperature.
このように非晶W磁性薄帯にスクラ・ソチ加工を施す−
ことにより、比較的低い・助作磁束密度で鉄損を減少さ
せることができる。In this way, Sukura/Sochi processing is applied to amorphous W magnetic ribbon.
As a result, iron loss can be reduced with a relatively low auxiliary magnetic flux density.
なお、磁性材料にスクラ・ソチ加工を施すと鉄損が減少
することはこの出願前より知られているが、たとえば特
公昭57−94554 号公報に開示されている高周波
用材料Fe79B工。Si5にスクラッチ間−1を悔し
ても、はとんど鉄損は減少しない。これはFe、、9B
よ。Si5では熱処理によって結晶相が析出するため、
スクラッチ加工による磁区構造変化による鉄損低減効果
よりもむしろ鉄損低減への寄与が犬なるためと与えられ
る。これに対し、この発明の前記組成合金では、結晶化
温度以下の熱処理でほとんど結晶相を析出しないために
、スクラッチ加工効果が現われたものと考えられる。も
ちろん、他のpeusi系アモ/L’7了スでも、結晶
相を析出しナイ熱処理では、スクラッチ加工による鉄損
域71)効果は見られるが、それでも鉄損の絶対値は大
きい。It has been known before this application that iron loss is reduced when a magnetic material is subjected to SCR/Sochi processing, such as the high frequency material Fe79B processing disclosed in Japanese Patent Publication No. 57-94554. Even if the scratch distance is reduced by -1 to Si5, the iron loss will not be reduced for a long time. This is Fe,,9B
Yo. In Si5, a crystal phase is precipitated by heat treatment, so
This is given because the contribution to reducing iron loss is greater than the effect of reducing iron loss due to changes in magnetic domain structure due to scratching. On the other hand, in the alloy of the present invention, the scratching effect appears because almost no crystalline phase is precipitated by heat treatment below the crystallization temperature. Of course, even with other peusi-based ammonium/L'7 ryosu, the crystal phase is precipitated and the iron loss region 71) effect due to scratching is seen in the heat treatment, but the absolute value of iron loss is still large.
つぎに実施例および比較例をあげてより詳細に説明する
。Next, a more detailed explanation will be given with reference to Examples and Comparative Examples.
実施例1〜5: 大気中単ロール法によシ、第1表に示
す各組成の合金から厚さ25〜30μm。Examples 1 to 5: 25 to 30 μm thick alloys having the respective compositions shown in Table 1 were made by a single roll method in the air.
幅1cWIの非晶質薄帯をそれぞれ作製した。これを長
さ1.5 mに切り取り、やすシを用いて第1図および
第2図に示すように薄帯1の両面すなわち自由面3およ
びロール面4にスクラッチ2を入れた。Amorphous ribbons each having a width of 1 cWI were produced. This was cut into a length of 1.5 m, and scratches 2 were made on both sides of the ribbon 1, that is, on the free surface 3 and on the roll surface 4, as shown in FIGS. 1 and 2 using a knife.
このスクラッチ2は、はぼ薄帯の長さ方向に垂直方向に
あり、スクラッチ間の間隔dは約0.5 mである。こ
の薄帯1を用いて内径2釧のコアを作製し、チッ素雰囲
気中で60分間熱処理した。なお、スクラッチ加工をし
ない薄帯で同形状のコアを作製し同様に熱処理して、ス
クラッチ加工を施したものと比較した。熱処理後、U関
数針を用いて、50 KHz 、 I KGauss
テ鉄損を測定L タ結果ヲg1表に併せて示す。なお、
第1表に示す熱処理温間は結晶化温度以下10℃ステッ
プで行なったときの鉄損が最小となった温度である。The scratches 2 are approximately perpendicular to the length of the ribbon, and the distance d between the scratches is approximately 0.5 m. A core with an inner diameter of 2 was prepared using this ribbon 1, and heat treated for 60 minutes in a nitrogen atmosphere. In addition, a core of the same shape was made from a thin ribbon that was not scratched, and was heat-treated in the same way, and compared with a core that had been subjected to scratching. After heat treatment, using a U function needle, 50 KHz, I K Gauss
The iron loss was measured and the results are also shown in Table 1. In addition,
The warm heat treatment shown in Table 1 is the temperature at which iron loss is minimized when the heat treatment is performed in steps of 10° C. below the crystallization temperature.
比較例1〜5: 第1表に示す各組成の合金お(5)
よびフェライトを用りたほかは実施例1〜5と同様にし
てコアを作製した。これらの鉄損測定結果を第1表に併
せて示す。Comparative Examples 1 to 5: Cores were produced in the same manner as Examples 1 to 5, except that alloy (5) and ferrite having the respective compositions shown in Table 1 were used. These iron loss measurement results are also shown in Table 1.
(6)
第1表から、実施例1〜5に示す各磁心はスクラッチ加
工を施すことによυ鉄損が小さくなることがわかる。ま
た、比較例1〜5に示す磁心はスクラッチ加工を施して
もそれほど鉄損の低減化が生じておらず、鉄損が高い数
値のままである。(6) From Table 1, it can be seen that the core loss of each of the magnetic cores shown in Examples 1 to 5 is reduced by scratching. Further, even when the magnetic cores shown in Comparative Examples 1 to 5 are subjected to scratch processing, the iron loss is not significantly reduced, and the iron loss remains at a high value.
この発明によれば、高周波、低磁束密度で従来の磁性材
料よυ低鉄損の非晶′a磁性合金を得ることができる。According to the present invention, it is possible to obtain an amorphous magnetic alloy having lower iron loss than conventional magnetic materials at high frequency and low magnetic flux density.
第1図はこの発明の実施例で得た薄帯の平面図、第2図
はそのト」線断面図である。
1・・・薄帯、2・・・スクラッチ
(7)
第2図
手続ネ甫正書(自発
1、事件の表示
暉1159年特許願第003−205号2、発明の名称
非晶質磁性合金およびその製造方法
3、補正をする者
事件との関係 11也九友
4、代理人
7、補正の内容
(])明細書第4頁第13行、「与えられる。」二ある
を「考えられる。」と訂正する。
(2)明細書第6頁の第1表において、実施例3の組成
がrFe7zcs B+eS is JとあるをrFe
tzcr5B+sS 45 Jと訂正する。
(2)FIG. 1 is a plan view of a thin ribbon obtained in an example of the present invention, and FIG. 2 is a cross-sectional view taken along a T-line. 1...Thin strip, 2...Scratch (7) Figure 2 Procedures Neho Seisho (Volunteer 1, Incident Indication 1159 Patent Application No. 003-205 2, Name of Invention Amorphous Magnetic Alloy and its manufacturing method 3, the person making the amendment Relationship with the case (2) In Table 1 on page 6 of the specification, the composition of Example 3 is rFe7zcs B+eS is J.
Corrected as tzcr5B+sS 45 J. (2)
Claims (2)
60〜85.Xが4〜10.yが10〜20゜2が10
以下、y+zが25以下である)の組成を有する非晶質
磁性薄帯にスクラッチ加工を施したことを特徴とする非
晶質磁性合金。(1) Formula: %Formula% (In the formula, w, x, y, z are the atomic ratios of each element, W is 60-85.X is 4-10.y is 10-20゜2 is 10
1. An amorphous magnetic alloy characterized by scratch-processing an amorphous magnetic ribbon having a composition (hereinafter, y+z is 25 or less).
であり、Wが60〜85.yが4〜10.yが10〜2
0゜2が10以下、y+zが25以下である)の組成を
有する非晶質磁性薄帯にスクラッチ加工を施した後、結
晶化温度以下でかつキュリ一温度以上で熱処理すること
を特徴とする非晶質磁性合金の製造方法。(2) Formula: % Formula % (In the formula, w, x, y, z are the atomic ratios of each element, W is 60-85.y is 4-10.y is 10-2
0°2 is 10 or less and y+z is 25 or less) is subjected to scratch processing, and then heat treated at a temperature below the crystallization temperature and above one Curie temperature. A method for producing an amorphous magnetic alloy.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59003205A JPS60145360A (en) | 1984-01-10 | 1984-01-10 | Amorphous magnetic alloy and its manufacture |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59003205A JPS60145360A (en) | 1984-01-10 | 1984-01-10 | Amorphous magnetic alloy and its manufacture |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS60145360A true JPS60145360A (en) | 1985-07-31 |
Family
ID=11550933
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59003205A Pending JPS60145360A (en) | 1984-01-10 | 1984-01-10 | Amorphous magnetic alloy and its manufacture |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60145360A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5338373A (en) * | 1991-08-20 | 1994-08-16 | Vonhoene Robert M | Method of encoding and decoding a glassy alloy strip to be used as an identification marker |
US7357844B2 (en) * | 2002-03-01 | 2008-04-15 | Japan Science And Technology Agency | Soft magnetic metallic glass alloy |
-
1984
- 1984-01-10 JP JP59003205A patent/JPS60145360A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5338373A (en) * | 1991-08-20 | 1994-08-16 | Vonhoene Robert M | Method of encoding and decoding a glassy alloy strip to be used as an identification marker |
US7357844B2 (en) * | 2002-03-01 | 2008-04-15 | Japan Science And Technology Agency | Soft magnetic metallic glass alloy |
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