JPS60137853A - 高強度結晶化ガラスおよびその製造方法 - Google Patents
高強度結晶化ガラスおよびその製造方法Info
- Publication number
- JPS60137853A JPS60137853A JP58240968A JP24096883A JPS60137853A JP S60137853 A JPS60137853 A JP S60137853A JP 58240968 A JP58240968 A JP 58240968A JP 24096883 A JP24096883 A JP 24096883A JP S60137853 A JPS60137853 A JP S60137853A
- Authority
- JP
- Japan
- Prior art keywords
- crystals
- glass
- crystallized glass
- apatite
- temperature range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims abstract description 124
- 239000013078 crystal Substances 0.000 title claims abstract description 106
- 229910052586 apatite Inorganic materials 0.000 title claims abstract description 60
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 title claims abstract description 60
- 238000004519 manufacturing process Methods 0.000 title claims description 16
- 239000000843 powder Substances 0.000 claims abstract description 37
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 238000005245 sintering Methods 0.000 claims abstract description 22
- 239000000654 additive Substances 0.000 claims abstract description 21
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052637 diopside Inorganic materials 0.000 claims abstract description 21
- 238000010438 heat treatment Methods 0.000 claims abstract description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052839 forsterite Inorganic materials 0.000 claims abstract description 15
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims abstract description 15
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 11
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims abstract description 8
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims abstract description 8
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 claims abstract description 8
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 claims abstract description 4
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims abstract 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 19
- 238000000465 moulding Methods 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 229910019704 Nb2O Inorganic materials 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052681 coesite Inorganic materials 0.000 abstract description 5
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 5
- 239000002245 particle Substances 0.000 abstract description 5
- 229910052682 stishovite Inorganic materials 0.000 abstract description 5
- 229910052905 tridymite Inorganic materials 0.000 abstract description 5
- 229910011255 B2O3 Inorganic materials 0.000 abstract description 4
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000377 silicon dioxide Substances 0.000 abstract description 3
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 3
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 abstract 1
- 238000002513 implantation Methods 0.000 abstract 1
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 abstract 1
- 210000000988 bone and bone Anatomy 0.000 description 15
- 238000002441 X-ray diffraction Methods 0.000 description 11
- 238000005452 bending Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 3
- -1 acamanite Chemical compound 0.000 description 3
- 239000005312 bioglass Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004455 differential thermal analysis Methods 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 238000001727 in vivo Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000010456 wollastonite Substances 0.000 description 2
- 229910052882 wollastonite Inorganic materials 0.000 description 2
- 208000006386 Bone Resorption Diseases 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 241000994644 Diopsis Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910019695 Nb2O6 Inorganic materials 0.000 description 1
- 239000006061 abrasive grain Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000012237 artificial material Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000024279 bone resorption Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 239000000788 chromium alloy Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 238000001513 hot isostatic pressing Methods 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 238000000462 isostatic pressing Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007582 slurry-cast process Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940078499 tricalcium phosphate Drugs 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 235000019731 tricalcium phosphate Nutrition 0.000 description 1
Landscapes
- Dental Preparations (AREA)
- Glass Compositions (AREA)
- Materials For Medical Uses (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58240968A JPS60137853A (ja) | 1983-12-22 | 1983-12-22 | 高強度結晶化ガラスおよびその製造方法 |
US06/678,977 US4560666A (en) | 1983-12-20 | 1984-12-06 | High strength glass-ceramic containing apatite and alkaline earth metal silicate crystals and process for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58240968A JPS60137853A (ja) | 1983-12-22 | 1983-12-22 | 高強度結晶化ガラスおよびその製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60137853A true JPS60137853A (ja) | 1985-07-22 |
JPH0153211B2 JPH0153211B2 (enrdf_load_stackoverflow) | 1989-11-13 |
Family
ID=17067328
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58240968A Granted JPS60137853A (ja) | 1983-12-20 | 1983-12-22 | 高強度結晶化ガラスおよびその製造方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60137853A (enrdf_load_stackoverflow) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6360126A (ja) * | 1986-08-30 | 1988-03-16 | Hoya Corp | ガラス射出成形用組成物 |
JPS63174909A (ja) * | 1987-01-09 | 1988-07-19 | Nippon Electric Glass Co Ltd | 歯牙模型及びその製造方法 |
JPH01171560A (ja) * | 1987-12-28 | 1989-07-06 | Kyocera Corp | 生体用リン酸カルシウム系結晶化ガラス |
JPH02239131A (ja) * | 1988-08-17 | 1990-09-21 | Samsung Corning Co Ltd | 建材用結晶化ガラスの製造方法 |
WO1993013030A1 (en) * | 1988-01-30 | 1993-07-08 | Ryo Enomoto | Fiber-reinforced calcium phosphate compound ceramics and process for their production |
CN1305801C (zh) * | 2005-07-01 | 2007-03-21 | 中国科学院上海硅酸盐研究所 | 镁橄榄石陶瓷材料作为生物力学材料的应用 |
-
1983
- 1983-12-22 JP JP58240968A patent/JPS60137853A/ja active Granted
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6360126A (ja) * | 1986-08-30 | 1988-03-16 | Hoya Corp | ガラス射出成形用組成物 |
JPS63174909A (ja) * | 1987-01-09 | 1988-07-19 | Nippon Electric Glass Co Ltd | 歯牙模型及びその製造方法 |
JPH01171560A (ja) * | 1987-12-28 | 1989-07-06 | Kyocera Corp | 生体用リン酸カルシウム系結晶化ガラス |
WO1993013030A1 (en) * | 1988-01-30 | 1993-07-08 | Ryo Enomoto | Fiber-reinforced calcium phosphate compound ceramics and process for their production |
JPH02239131A (ja) * | 1988-08-17 | 1990-09-21 | Samsung Corning Co Ltd | 建材用結晶化ガラスの製造方法 |
CN1305801C (zh) * | 2005-07-01 | 2007-03-21 | 中国科学院上海硅酸盐研究所 | 镁橄榄石陶瓷材料作为生物力学材料的应用 |
Also Published As
Publication number | Publication date |
---|---|
JPH0153211B2 (enrdf_load_stackoverflow) | 1989-11-13 |
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