JPS5992027A - 緩衝シユウ酸を用いる、触媒からの金属汚染物質の除去 - Google Patents

緩衝シユウ酸を用いる、触媒からの金属汚染物質の除去

Info

Publication number
JPS5992027A
JPS5992027A JP19514383A JP19514383A JPS5992027A JP S5992027 A JPS5992027 A JP S5992027A JP 19514383 A JP19514383 A JP 19514383A JP 19514383 A JP19514383 A JP 19514383A JP S5992027 A JPS5992027 A JP S5992027A
Authority
JP
Japan
Prior art keywords
catalyst
oxalic acid
iron
alumina
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP19514383A
Other languages
English (en)
Japanese (ja)
Other versions
JPH0424107B2 (de
Inventor
ゲアリ−・ビ−・マクヴイツカ−
ジエイムズ・エル・カ−タ−
ロ−レンス・エル・ミユ−レル
ジヨン・ジエイ・ジ−ミアク
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of JPS5992027A publication Critical patent/JPS5992027A/ja
Publication of JPH0424107B2 publication Critical patent/JPH0424107B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/20Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/96Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • B01J38/62Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids organic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04Oxides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04Oxides
    • C10G11/05Crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/468Iridium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/64Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656Manganese, technetium or rhenium
    • B01J23/6567Rhenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
JP19514383A 1982-10-18 1983-10-18 緩衝シユウ酸を用いる、触媒からの金属汚染物質の除去 Granted JPS5992027A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US43473082A 1982-10-18 1982-10-18
US434730 1982-10-18

Publications (2)

Publication Number Publication Date
JPS5992027A true JPS5992027A (ja) 1984-05-28
JPH0424107B2 JPH0424107B2 (de) 1992-04-24

Family

ID=23725431

Family Applications (1)

Application Number Title Priority Date Filing Date
JP19514383A Granted JPS5992027A (ja) 1982-10-18 1983-10-18 緩衝シユウ酸を用いる、触媒からの金属汚染物質の除去

Country Status (4)

Country Link
JP (1) JPS5992027A (de)
CA (1) CA1217468A (de)
DE (1) DE3337619C2 (de)
NL (1) NL191143C (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005515887A (ja) * 2002-01-29 2005-06-02 エクソンモービル リサーチ アンド エンジニアリング カンパニー 一酸化炭素水素添加用担持触媒の再生
JP2021528232A (ja) * 2018-06-18 2021-10-21 ノヴァ ケミカルズ(アンテルナショナル)ソシエテ アノニム 脱水素化触媒の除去および洗浄

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0285715A1 (de) * 1987-04-09 1988-10-12 Mobil Oil Corporation Reaktivierung von Edelmetall enthaltenden Zeolithkatalysatoren
US5141904A (en) * 1991-02-15 1992-08-25 Phillips Petroleum Company Reactivation of spent cracking catalysts
US5900383A (en) * 1996-01-02 1999-05-04 New Life Catalyst, Inc. Process for increasing the activity of zeolite containing particulate solids

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2380731A (en) * 1941-12-09 1945-07-31 Socony Vacuum Oil Co Inc Restoration of catalysts
GB589796A (en) * 1945-04-06 1947-06-30 George Frederick Horsley Improvements in and relating to the activation of catalysts
US2704281A (en) * 1953-04-30 1955-03-15 Universal Oil Prod Co Purification of noble metal-metal oxide composite
US3213033A (en) * 1962-11-09 1965-10-19 Air Prod & Chem Method of removing metallic contaminants from particulate solid catalyst
US3536637A (en) * 1968-09-03 1970-10-27 Betz Laboratories Process for the rejuvenation of fouled ion-exchange materials
GB1245358A (en) * 1968-11-05 1971-09-08 Inst Francais Du Petrole Process for regenerating catalysts used for hydro-treating hydrocarbons
US3791989A (en) * 1971-03-12 1974-02-12 Chevron Res Catalyst rejuvenation with oxalic acid
US4089806A (en) * 1977-04-01 1978-05-16 Union Oil Company Of California Method for rejuvenating hydroprocessing catalysts

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005515887A (ja) * 2002-01-29 2005-06-02 エクソンモービル リサーチ アンド エンジニアリング カンパニー 一酸化炭素水素添加用担持触媒の再生
JP2021528232A (ja) * 2018-06-18 2021-10-21 ノヴァ ケミカルズ(アンテルナショナル)ソシエテ アノニム 脱水素化触媒の除去および洗浄

Also Published As

Publication number Publication date
NL191143B (nl) 1994-09-16
DE3337619A1 (de) 1984-04-19
CA1217468A (en) 1987-02-03
DE3337619C2 (de) 1994-06-16
NL191143C (nl) 1995-02-16
JPH0424107B2 (de) 1992-04-24
NL8303596A (nl) 1984-05-16

Similar Documents

Publication Publication Date Title
US4522928A (en) Removal of metal comtaminants from catalysts using buffered oxalic acid
US3711422A (en) Cracking catalyst restoration with antimony compounds
CA1189847A (en) Process for hydrocracking heavy hydrocarbon oils and catalyst therefor
CA1175000A (en) Immobilization of vanadian deposited on sorbent materials during treatment of carbo-metallic oils
US4678764A (en) Reactivation of noble metal-zeolite catalysts
US2760907A (en) Hydrocarbon conversion process and catalyst
JPS6335197B2 (de)
US4485183A (en) Regeneration and reactivation of deactivated hydrorefining catalyst
JPS63265807A (ja) 鉱柱状の中間層から成る粘土の製造方法及びそれを用いるクラツキング方法
EP0882503A2 (de) Hoheaktieven Katalysatoren
JP2003510405A (ja) 流体接触分解法におけるガソリンの脱硫
JPS61209047A (ja) 有機化合物によつて安定化された過酸化水素の水溶液による、使用済触媒の再生方法
US10512906B2 (en) In-situ washing procedure to recover the catalytic activity of a deactivated hydrodesulfurization catalyst
US20150111720A1 (en) Regeneration of spent paraffin dehydrogenation catalyst
TW200800394A (en) Catalyst composition for reducing gasoline sulfur content in catalytic cracking process
US4192770A (en) Cracking catalyst restoration with boron compounds
AU645748B2 (en) Passivation of metal contaminants in the catalytic cracking of hydrocarbons
US4268415A (en) Regeneration of spent hydrodesulfurization catalysts with heteropoly acids and hydrogen peroxide
JPS5992027A (ja) 緩衝シユウ酸を用いる、触媒からの金属汚染物質の除去
US4317713A (en) In situ aluminum passivation process
US4581129A (en) Hydrorefining with a regenerated catalyst
US4272401A (en) Regeneration of spent hydrodesulfurization catalyst with heteropoly acids
US4826792A (en) Method of noble metal-zeolite catalyst activation with Bronsted acid compound
US4491636A (en) Process using halogen/oxygen for reactivating iridium and selenium containing catalysts
JP2711871B2 (ja) ヒドロゲルから水素処理触媒を製造する方法